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Trang 1
QUY TRNH LM THI

+ Bc 01: Chn ni yn tinh, chun b giy nhp, my tnh, ct ht sch v v bng tun hon cc nguyn t ha hc
+ Bc 02: Bm thi gian lm thi.
+ Bc 03: Lm ht thi gian, sau so snh vi p n.
+ Bc 04: c k cc cu cha lm c tho lun li vi bn b nu cha r th gi vn thc mc qua mail
: bandoc@hoahoc.org

Nn lm theo nhm - t n 3 5 ngi

THI GIAN BIU HC HC TI HI DNG

Thi gian
bt u
Th 2 Th 3 Th 4 Th 5 Th 6 Th 7 Ch nht

13h15
n
19h30
13h15
n
19h30
13h15
n
19h30
13h15
n
19h30

THI GIAN BIU HC HC TI H NI

Thi gian
bt u
Th 2 Th 3 Th 4 Th 5 Th 6 Th 7 Ch nht
7h15
n
19h30
7h15
n
15h30

7h15
n
19h3

19h30

* GHI CH *
Nu nh bn mun ng k hc hy lin lc vi thy qua s in thoi: 0979.817.885
a ch ng k hc ti
H Ni: S 56/113 Khng H Mi Thanh Xun H Ni

Hi Dng: 18A/88 Ph inh Vn T - TP. Hi Dng
LP BI DNG KIN THC & LUYN THI H HA HC: 0979.817.885
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Trang 2
TRNG THPT LONG CHU SA

THI KHO ST CHT LNG LN 1
NM HC 2013 - 2014
LP: 12 - MN: HA HC
Thi gian lm bi: 90 pht (Khng k thi gian giao )

M thi 132
H, tn th sinh:..................................................................... .SBD: ........................

Cu 1: Cho hn hp X gm hai hp cht hu c c cng cng thc phn t C
2
H
7
NO
2
tc dng va vi dung dch
NaOH v un nng, thu c dung dch Y v 4,48 l hn hp Z( ktc) gm hai kh u lm xanh giy qu m. T
khi hi ca Z i vi H
2
bng 13,75. C cn dung dch Y thu c khi lng mui khan l
A. 15,7 gam B. 8,9 gam C. 16,5 gam D. 14,3 gam
Cu 2: Cho dy cc cht: Ca(HCO
3
)
2
, NH
4
Cl, (NH
4
)
2
CO
3
, ZnSO
4
, Al(OH)
3
, Zn(OH)
2
. S cht trong dy c tnh cht
lng tnh l:
A. 5 B. 2 C. 4 D. 3
Cu 3: Cho 0,1 mol anehit X tc dng vi lng d AgNO
3
/NH
3
, ung nng thu c 43,2 gam Ag. Hiro ha X thu
c Y, bit Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l
A. OHC-CHO B. HCHO C. CH
3
CH(OH)CHO D. CH
3
CHO
Cu 4: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton, c
cn dung dch thu c cht rn khan c khi lng l
Cu 5: Ha tan hon ton 12 gam hn hp Fe, Cu(t l mol 1:1) bng axit HNO
3
, thu c V lt ( ktc) hn hp kh
X(gm NO v NO
2
) v dung dch Y(ch cha hai mui v axit d). T khi ca X i vi hiro bng 19. Gi tr ca V
A. 4,48 B. 3,36 C. 5,60 D. 2,24
Cu 6: Cho tng oxit: Al
2
O
3
, SO
2
, Fe
3
O
4
, N
2
O
5
, Cl
2
O
7
, Cl
2
O, NO
2
, NO, CO
2
, SiO
2
, P
2
O
5
, N
2
O, ZnO vo dung dch
NaOH. S trng hp c th xy ra phn ng l:
A. 6 B. 7 C. 9 D. 8
Cu 7: Cho cc cht sau: sec-butyl clorua; neo-pentyl clorua; benzyl clorua; 3-clobut-1-en; p-clotoluen. S cht b thy
phn khi un vi nc v b thy phn khi un vi dung dch NaOH long, ln lt l:
A. 2 v 4 B. 1 v 4 C. 1 v 5 D. 2 v 3
Cu 8: t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO
2
, 1,4 lt kh N
2
(cc kh u o ktc) v
10,125 gam H
2
O. Cng thc phn t ca X l
A. C
2
H
7
N B. C
4
H
9
N C. C
3
H
7
N D. C
3
H
9
N
Cu 9: Cho hn hp A gm ba hirocacbon X, Y, Z thc ba dy ng ng v hn hp B gm O
2
, O
3
. Trn A vi B
theo t l th tch V
A
:V
B
= 1,5 : 3,2 ri t chy. Hn hp sau phn ng thu c ch gm CO
2
v H
2
O(hi) c t l th
tch CO
2
v H
2
O(hi) l 1,3 : 1,2. Bit t khi hi ca B so vi H
2
l 19. T khi hi ca A so vi H
2
l:
A. 15 B. 13,5 C. 12 D. 11,5
Cu 10: chng minh trong phn t glucoz c nhiu nhm hiroxyl, ngi ta cho dung dch glucoz phn ng vi:
A. AgNO
3
/NH
3
, un nng. B. Cu(OH)
2
/NaOH, un nng. C. kim loi Na. D. Cu(OH)
2
nhit thng.
Cu 11: Mnh khng ng l:
A. CH
3
CH
2
COOCH=CH
2
cng dy ng ng vi CH
2
=CHCOOOCH
3
.
B. CH
3
CH
2
COOCH=CH
2
c th trng hp to polime.
C. CH
3
CH
2
COOCH=CH
2
tc

dng c vi dung dch Br
2
.
D. CH
3
CH
2
COOCH=CH
2
tc

dng vi dung dch NaOH thu c anehit v mui.
Cu 12: Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H
2
SO
4
0,5M, thu
c 5,32 lt H
2
( ktc) v dung dch Y (coi th tch khng i). Dung dch Y c pH l:
A. 7 B. 1 C. 2 D. 6
Cu 13: Trong t nhin clo c hai ng v bn:
37
17
Cl chim 24,23% tng s nguyn t, cn li l
35
17
Cl. Thnh phn %
theo khi lng ca
37
17
Cl trong HClO
4
l
A. 8,79% B. 8,56% C. 8,92% D. 8,43%
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Trang 3
Cu 14: Trong phng th nghim, iu ch mt lng nh kh X tinh khit, ngi ta un nng dung dch amoni
nitrit bo ha. Kh X l:
A. NO B. NO
2
C. N
2
D. N
2
O
Cu 15: Hirat ha hai anken ch to thnh hai ancol. Hai anken l:
A. eten v but 1- en B. eten v but 2- en
C. propen v but 2- en D. 2-metylpropen v but- 1- en
Cu 16: Pht biu khng ng l:
A. Dung dch natri phenolat phn ng vi kh CO
2
, ly kt ta va to ra cho tc dng vi dung dch NaOH li thu
c natri phenolat.
B. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu c anilin.
C. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li thu c phenol.
D. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO
2
li thu c axit
axetic.
Cu 17: Dung dch CH
3
COOH c in li o = 1%, nng x mol/l v pH= n. Dung dch NH
3
c in li | =
0,1%, nng y mol/l v pH = m. Cho m = n + 9. Mi quan h gia x v y l:
A. x = 8y B. x =
1
y
C. x = 9y D. x = y + 5
Cu 18: Trong phng th nghim, ngi ta thng iu ch clo bng cch
A. in phn dung dch NaCl c mng ngn. B. in phn nng chy NaCl.
C. cho dung dch HCl c tc dng vi MnO
2
ung nng. D. cho F
2
y Cl
2
ra khi dung dch NaCl.
Cu 19: Cho 6,9 gam Na vo 100,0 ml dung dch HCl thu c dung dch X cha 14,59 gam cht tan. Cho dung dch
X vo dung dch AgNO
3
d thu c bao nhiu gam kt ta
A. 37,58 B. 38,65 C. 39,20 D. 40,76
Cu 20: S tripeptit mch h ti a thu c khi trng ngng hn hp ch gm glyxin v alanin l:
A. 8 B. 6 C. 9 D. 4
Cu 21: Trong phng trnh phn ng Al v HNO
3
khng to ra kh (h s nguyn dng ti gin), h s ca H
2
O l:
A. 30 B. 18 C. 9 D. 15
Cu 22: Cho lung kh H
2
(d) qua hn hp cc oxit CuO, Fe
2
O
3
, Al
2
O
3
, MgO nung nhit cao. Sau phn ng hn
hp rn cn li l:
A. Cu, Fe, Al
2
O
3
, MgO B. Cu, FeO, Al, MgO C. CuO, FeO, Al
2
O
3
, MgO D. Cu, Fe, Al, MgO
Cu 23: Cho s phn ng:
Este X( C
4
H
n
O
2
)
0
NaOH
t C
+
Y
3 3
0
/ AgNO NH
t C
+
Z
0
NaOH
t C
+
C
2
H
3
O
2
Na.
Cng thc cu to ca X tha mn s cho l:
A. CH
2
=CHCOOOCH
3
B. CH
3
COOCH
2
CH
3
C. HCOOCH
2
CH
2
CH
3
D. CH
3
COOCH=CH
2

Cu 24: Mt hirocacbon X cng hp vi axit HCl theo t l 1:1 to sn phm c thnh phn khi lng clo l
45,223%. Cng thc phn t ca X l
A. C
3
H
4
B. C
2
H
4
C. C
4
H
8
D. C
3
H
6

Cu 25: Cho tng cht: Fe, FeO, Fe(OH)
2
, Fe(OH)
3
, Fe
3
O
4
, Fe
2
O
3
, Fe(NO
3
)
2
, Fe(NO
3
)
3
, FeSO
4
, Fe
2
(SO
4
)
3
, FeCO
3
ln
lt phn ng vi HNO
3
c, nng. S phn ng thuc loi phn ng oxi ha kh l:
A. 5 B. 8 C. 7 D. 6
Cu 26: Cho 4,48 lt hn hp kh X ( ktc) gm hai hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br
2

0,5M. Sau khi phn ng hon ton, s mol Br
2
gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn
t ca hai hirocacbon l
A. C
3
H
4
v C
4
H
8
B. C
2
H
2
v C
4
H
8
C. C
2
H
2
v C
3
H
8
D. C
2
H
2
v C
4
H
6

Cu 27: Cho E
0
( ) pin Zn Cu
= 1,10V; E
2
0
/ Zn Zn
+
= - 0,76V v E
0
/ Ag Ag
+
= + 0,80V. Sut in ng ca pin in ha Cu Ag l:
A. 0,46V B. 1,14V C. 0,56V D. 0,34V
Cu 28: Ha tan 5,6 gam Fe bng dung dch H
2
SO
4
long, d, thu c dung dch X. Dung dch X phn ng va
vi V ml dung dch KMnO
4
0,5M. Gi tr ca V l
A. 40 B. 80 C. 60 D. 20
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Trang 4
Cu 29: Dy gm cc ion X
+
, Y
v nguyn t Z u c cu hnh electron 1s

2
2s
2
2p
6
l:
A. Li
+
, F
, Ne B. Na
+
, F
, Ne C. K
+
, Cl
, Ar D. Na
+
, Cl
, Ar
Cu 30: nhn bit ba axit c, ngui: HCl, H
2
SO
4
, HNO
3
ng ring bit trong ba l b mt nhn, ta dng thuc th
A. Fe B. Cu C. CuO D. Al
Cu 31: Hp th hon ton 2,688 lt kh CO
2
( ktc) vo 2,5 lt dung dch Ba(OH)
2
nng a mol/l, thu c 15,76
gam kt ta. Gi tr ca a l
A. 0,032 B. 0,04 C. 0,048 D. 0,06
Cu 32: Hn hp X gm axit HCOOH v axit CH
3
COOH(t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75
gam C
2
H
5
OH (c xc tc H
2
SO
4
c) thu c m gam hn hp este (hiu sut ca cc phn ng este ha u bng
80%). Gi tr ca m l
A. 16,20 B. 6,48 C. 8,10 D. 10,12
Cu 33: Khi tch nc t mt cht X c cng thc phn t C
4
H
10
O to thnh ba anken l ng phn ca nhau (tnh c
ng phn hnh hc). Cng thc cu to thu gn ca X l:
A. CH
3
CH(OH)CH
2
CH
3
B. (CH
3
)
3
OH
C. CH
3
CH(CH
3
)CH
2
OH D. CH
3
OCH
2
CH
2
CH
3
.
Cu 34: in phn dung dch CuCl
2
vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catt v mt lng
kh X ant. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH ( nhit thng). Sau phn ng,
nng NaOH cn li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u ca dung dch NaOH l
A. 0,1M B. 0,2M C. 0,5M D. 0,15M
Cu 35: Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO
3
/NH
3
, un nng. Lng Ag
sinh ra cho phn ng ht vi axit HNO
3
long, thot ra 2,24 lt kh khng mu ha nu ngoi khng kh (sn phm kh
duy nht, o ktc). Cng thc cu to ca X l
A. CH
3
CH
2
CHO B. HCHO C. CH
2
=CH-CHO D. CH
3
CHO
Cu 36: nhn bit cc dung dch ring bit, khng mu: NH
3
, NaOH, BaCl
2
, NaCl, cn chn thuc th l:
A. FeCl
3
B. H
2
SO
4
C. AgNO
3
D. CuSO
4

Cu 37: Ha tan hon ton 2,81 gam hn hp gm Fe
2
O
3
, MgO, ZnO trong 500 ml dung dch H
2
SO
4
0,1M (va ).
Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l
Cu 38: Nung hn hp cc cht Fe(NO
3
)
2
, Fe(OH)
3
v FeCO
3
trong khng kh n khi lng khng i, thu c
cht rn l:
A. Fe B. FeO C. Fe
3
O
4
D. Fe
2
O
3

Cu 39: Cho 15,6 gam hn hp hai ancol n chc, k tip nhau trong dy ng ng tc dng ht vi 9,2 gam Na,
thu c 24,5 gam cht rn. Hai ancol l
A. C
3
H
7
OH v C
4
H
9
OH B. C
2
H
5
OH v C
3
H
7
OH C. C
3
H
5
OH v C
4
H
7
OH D. CH
3
OH v C
2
H
5
OH
Cu 40: Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng CO
2
sinh ra c hp th
hon ton vo dung dch Ca(OH)
2
, thu c 550 gam kt ta v dung dch X. un k dung dch X thu thm c 100
gam kt ta na. Gi tr ca m l
A. 650 B. 550 C. 810 D. 750
Cu 41: Nilon 6,6 l mt loi
A. t poliamit B. t axetat C. polieste D. t visco
Cu 42: Clo ha PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh phn t clo phn ng vi k mt
xch trong mch PVC. Gi tr ca k l
A. 5 B. 2 C. 4 D. 3
Cu 43: Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na
2
CO
3
ng thi khuy u, thu c V lt
kh ( ktc) v dung dch X. Khi cho d nc vi trong vo dung dch X thy c xut hin kt ta. Biu thc lin h
gia V vi a, b l:
A. V = 22,4(a + b) B. 11,2(a +b) C. V = 11,2(a b) D. V = 22,4(a-b)
Cu 44: Dy gm cc cht u tc dng vi AgNO
3
/NH
3
l:
A. anehit axetic, axetilen, but 2-in. B. anehit axetic, but- 1-in, etilen.
C. axit fomic, vinylaxetilen, propin. D. anehit fomic, axetilen, etilen.
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Trang 5
Cu 45: Mnh khng ng l:
A. Tnh oxi ha ca cc ion tng theo th t: Fe
2+
, H
+
, Cu
2+
, Ag
+
. B. Fe kh c Cu
2+
trong dung dch.
C. Fe
2+
oxi ha c Cu. D. Fe
3+
c tnh oxi ha mnh hn Cu
2+
.
Cu 46: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu
c hn hp kh Y. Cho Y qua dung dch H
2
SO
4
c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng
thc phn t ca X l
A. C
4
H
8
B. C
3
H
4
C. C
3
H
6
D. C
3
H
8

Cu 47: t chy hon ton mt hp cht hu c X thu c 3,36 lt kh CO
2
, 0,56 lt N
2
(cc kh u o ktc) v
3,15 gam H
2
O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H
2
N-CH
2
-COONa. Cng thc cu to
ca X l
A. H
2
NCH
2
COOC
3
H
7
B. H
2
NCH
2
COOCH
3
C. H
2
NCH
2
COOC
2
H
5
D. H
2
NCH
2
CH
2
COOH
Cu 48: Thy phn hon ton 444 gam mt lipit thu c 46 gam glixerol v hai loi axit bo. Hai loi axit bo l
A. C
17
H
31
COOH v C
17
H
33
COOH B. C
17
H
33
COOH v C
17
H
35
COOH
C. C
17
H
33
COOH v C
15
H
31
COOH D. C
15
H
31
COOH v C
17
H
35
COOH
Cu 49: o -aminoaxit X cha mt nhm NH
2
. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui
khan. Cng thc cu to thu gn ca X l
A. CH
3
CH(NH
2
)COOH B. CH
3
CH
2
CH(NH
2
)COOH
C. H
2
NCH
2
COOH D. H
2
NCH
2
CH
2
COOH
Cu 50: Este no sau y khi phn ng vi dung dch NaOH d, un nng khng to ra hai mui?
A. C
6
H
5
COOC
6
H
5
B. CH
3
COO(CH
2
)
2
OOCCH
2
CH
3

C. CH
3
COOC
6
H
5
D. CH
3
OOC-COOCH
3

-----------------------------------------------
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Trang 6
----------- HT ----------
M : 132
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A
B
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Trang 7
S GD-T H TNH
TRNG THPT CM BNH
( thi c 04 trang)
THI TH I HC LN I
Mn thi: HO HC
Thi gian lm bi: 90 pht

M thi 172
H, tn th sinh:..........................................................................
Cho bit nguyn t khi (theo vC) ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56;
Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137.

Cu 1: Cho cc dung dch c cng nng mol/lit: CH
3
COOH; KHSO
4
; CH
3
COONa; NaOH. Th t sp
xp cc dung dch theo chiu pH tng dn l:
A. KHSO
4
; CH
3
COOH; CH
3
COONa; NaOH. B. KHSO
4
; CH
3
COOH; NaOH; CH
3
COONa
C. CH
3
COOH; CH
3
COONa; KHSO
4
; NaOH. D. CH
3
COOH; KHSO
4
; CH
3
COONa; NaOH.
Cu 2: Cho hn hp gm 0,01 mol Al v 0,02 mol Mg tc dng vi 100ml dung dch cha AgNO
3
v
Cu(NO
3
)
2
, sau khi phn ng xy ra hon ton thu c m gam cht rn X gm 3 kim loi, X tc dng hon
ton vi HNO
3
c, d thu c V lt NO
2
( ktc v duy nht ). Gi tr ca V l:
A. 1,232. B. 1,568. C. 1,904. D. 1,586.
Cu 3: Ho tan hon ton 2,05 gam hn hp X gm cc kim loi Al, Mg, Zn vo mt va dung dch HCl.
Sau phn ng, thu c 1,232 lt kh ktc v dung dch Y. C cn dung dch Y, khi lng mui khan thu
c l:
A. 4,0025g. B. 6,480g. C. 6,245g. D. 5,955g.
Cu 4: Tnh kh ca cc halogenua tng dn theo dy
A. F
-
, Br
-
, Cl
-
, I
-
. B. Cl
-
, F
-
, Br
-
, I
-
. C. I
-
, Br
-
, Cl
-
, F
-
. D. F
-
, Cl
-
, Br
-
, I
-
.
Cu 5: Trong t nhin Ag c hai ng v bn l
107
Ag v
109
Ag. Nguyn t khi trung bnh ca Ag l 107,87.
Hm lng
107
Ag c trong AgNO
3
l
A. 35,56%. B. 43,12%. C. 35,59%. D. 62,99%.
Cu 6: Cho cc cht sau: axit glutamic; valin, lysin, alanin, trimetylamin, anilin. S cht lm qu tm chuyn
mu hng, mu xanh, khng i mu ln lt l:
A. 3, 1, 2. B. 2, 1,3. C. 1, 1, 4. D. 1, 2, 3.
Cu 7: Thm 250 ml dung dch NaOH 2M vo 200 ml dung dch H
3
PO
4
1,5M. Sn phm thu c l hn
hp
A. NaOH; Na
3
PO
4
. B. H
3
PO
4
; NaH
2
PO
4
. C. NaH
2
PO
4
; Na
2
HPO
4
. D. Na
3
PO
4
; Na
2
HPO
4
.
Cu 8: Saccaroz c tnh cht no trong s cc tnh cht sau:
1/ polisaccarit. 2/ khi tinh th khng mu.
3/ khi thu phn to thnh glucoz v frutoz. 4/ tham gia phn ng trng gng.
5/ phn ng vi Cu(OH)
2
.
Nhng tnh cht no ng
A. 1, 2, 3, 5. B. 3, 4, 5. C. 1, 2, 3, 4. D. 2, 3, 5.
Cu 9: un nng dung dch c cha 36 gam hn hp cha glucoz v fructoz (t l mol 1:1) vi mt lng
va dung dch AgNO
3
/NH
3
thy Ag tch ra . Lng Ag thu c v khi lng AgNO
3
cn dng l(tnh
theo gam)
A. 21,6; 68. B. 43,2; 34. C. 43,2; 68. D. 21,6; 34
Cu 10: Cho 0,2 mol cht X (C
2
H
8
O
3
N
2
) tc dng vi dung dch cha 0,3 mol NaOH un nng thu c
cht kh lm xanh giy qu tm tm t v dung dch Y. C cn dung dch Y c m gam cht rn khan. Gi
tr ca m l :
A. 21. B. 25,5. C. 17. D. 12.
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Trang 8
Cu 11: Cho m gam butan qua xc tc ( nhit thch hp), thu c hn hp gm 5 hirocacbon. Cho
hn hp kh ny sc qua bnh ng dung dch nc brom d th lng brom tham gia phn ng l 25,6 gam
v sau th nghim bnh brom tng 5,32 gam. Hn hp kh cn li sau khi qua dung dch nc brom c t khi
so vi metan l 1,9625. Gi tr ca m l
A. 17,4. B. 9,28. C. 5,32. D. 11,6.
Cu 12: Cho hn hp X gm 0,01 mol HCOOH; 0,02 mol HCHO v 0,01 mol HCOOCH
3
tc dng vi
AgNO
3
/NH
3
(d) thu c m gam Ag. Gi tr ca m l
A. 8,64. B. 12,96. C. 4,32. D. 10,8.
Cu 13: Dung dch X cha 0,01 mol Fe(NO
3
)
3
v 0,15 mol HCl c kh nng ha tan ti a bao nhiu gam Cu kim
loi? (Bit NO l sn phm kh duy nht)
A. 3,92 gam. B. 3,2 gam. C. 5,12 gam. D. 2,88 gam.
Cu 14: Trong phng th nghim, kh hiro halogenua c iu ch t phn ng:
NaX
rn
+ H
2
SO
4 c

0
t
HX| + NaHSO
4

Phng php trn c dng iu ch hiro halogenua no?
A. HCl B. HCl v HBr C. HBr D. HI
Cu 15: Cho cc pht biu sau:
(1) CaOCl
2
l mui kp.
(2) Lin kt kim loi l lin kt c hnh thnh gia cc nguyn t v ion kim loi trong mng tinh th do s
tham gia ca cc electron t do.
(3) Supephotphat kp c thnh phn ch yu l Ca(H
2
PO
4
)
2
.
(4) Trong cc HX (X: halogen) th HF c tnh axit yu nht.
(5) Bn nhiu phn m amoni s lm cho t chua.
(6) Kim loi c nhit nng chy thp nht l thy ngn (Hg).
(7) CO
2
l phn t phn cc.
S pht biu ng l:
A. 7. B. 4. C. 6. D. 5.
Cu 16: Cho cc cht: Glixerol, etylen glicol, gly-ala-gly, glucoz, axit axetic, saccaroz, anehit fomic,
anilin. S cht tc dng c vi Cu(OH)
2
( iu kin thch hp) l:
A. 7. B. 8. C. 6 . D. 5.
Cu 17: C cc dung dch ring bit sau:
H
2
N-CH
2
-CH
2
-CH(NH
2
)-COOH, HOOC-CH
2
-CH
2
-CH(NH
2
)-COOH
H
2
N-CH
2
-COONa, ClH
3
N-CH
2
-COOH, C
6
H
5
-NH
3
Cl.
S lng cc dung dch c pH < 7 l:
A. 2. B. 5. C. 3. D. 4.
Cu 18: Qu trnh iu ch t no di y l qu trnh trng hp?
A. T lapsan t etylen glicol v axit terephtalic. B. T capron t axit =-amino caproic.
C. T nilon-6,6 t hexametyleniamin v axit aipic. D. T nitron (t olon) t acrilonitrin.
Cu 19: Khi un nng 25,8 gam hn hp ru (ancol) etylic v axit axetic c H
2
SO
4
c lm xc tc thu c 14,08
gam este. Nu t chy hon ton lng hn hp ban u thu c 23,4 g nc. Hiu sut ca phn ng
este ha l:
A. 70%. B. 80%. C. 75%. D. 85%.
Cu 20: t chy hon ton ancol X thu c CO
2
v H
2
O theo t l mol l 3: 4. S ancol c th c ca X l:
A. 2. B. 5. C. 3. D. 4.
Cu 21: Mt dung dch X c cha 0,01 mol Ba
2+
; 0,01 mol NO
3
-
; a mol OH
-
v b mol Na
+
. trung ho 1/2 dung
dch X ngi ta cn dng 200ml dung dch HCl 0,1M. Khi lng cht rn thu c khi c cn dung dch X l:
A. 4 gam B. 1,68 gam C. 13,5 gam D. 3,36 gam
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Trang 9
Cu 22: Cho 45 gam hn hp bt Fe v Fe
3
O
4
vo V lt dung dch HCl 1M, khuy u cc phn ng xy ra
hon ton, thy thot ra 4,48 lt kh (ktc) v 5 gam kim loi khng tan. Gi tr ca V l
A. 1,2 lt B. 1,392 lt C. 0,4 lt D. 0,6 lt
Cu 23: Cho s phn ng sau: X axit axetic. X c th l
A. CH
3
COONa, CH
3
COOC
2
H
5
, CH
3
CH=O. B. CH
3
COONa, CH
3
COOC
2
H
5
, C
2
H
5
OH.
C. CH
3
COONa, CH
3
COOC
2
H
5
, CH
3
CCl
3
. D. CH
3
COONa, CH
3
COOC
2
H
5
, CH
3
COONH
4
.
Cu 24: Khi nhit phn hon ton hn hp NH
4
NO
3
, Cu(NO
3
)
2
, AgNO
3
, Fe(NO
3
)
2
th cht rn thu c sau phn
ng gm:
A. CuO, Fe
2
O
3
, Ag B. CuO, FeO, Ag C. NH
4
NO
2
, CuO, Fe
2
O
3
, Ag D. CuO, Fe
2
O
3
, Ag
2
O
Cu 25: Thy phn m gam tinh bt, sn phm thu c em ln men sn xut ancol etylic, ton b kh CO
2
sinh
ra cho qua dung dch Ca(OH)
2
d, thu c 850 gam kt ta. Bit hiu sut giai on thy phn v ln men u l
85%. Gi tr ca m?
A. 952,9. B. 810,0. C. 688,5. D. 497,4.
Cu 26: Cho cc cht: FeCO
3
, Fe(NO
3
)
2
, Fe
2
(SO
4
)
3
, FeSO
4
, FeS, FeS
2
, CuS. S lng cht c th c kh thot ra
khi cho vo dung dch HCl v un nng nh l:
A. 6. B. 7. C. 5. D. 4.
Cu 27: in phn 100ml dung dch Fe
2
(SO
4
)
3
1M (in cc tr), vi cng dng in I = 2,68A trong thi gian
t gi th bt u c kh thot ra catot (hiu sut ca qu trnh in phn l 100%). Gi tr ca t l
A. 2. B. 1. C. 4. D. 6.
Cu 28: Cho 15 gam hn hp bt cc kim loi Fe, Al, Mg, Zn vo 100 ml dung dch hn hp H
2
SO
4
1M v HCl
1M, sau khi cc phn ng xy ra hon ton, ton b kh sinh ra cho qua ng s ng m gam CuO (d) nung nng.
Phn ng xong, trong ng cn li 17,6 gam cht rn. Vy m bng
A. 20. B. 15,6. C. 13,56. D. 16,4.
Cu 29: Hn hp X gm CH
3
CHO v C
2
H
3
CHO. Oxi ha hon ton m gam X bng oxi c xc tc thu c (m +
1,6) gam hn hp 2 axit. Cho m gam X tham gia ht vo phn ng trng bc c a gam Ag kt ta. Gi tr ca a l:
A. 5,4. B. 21,6. C. 43,2. D. 10,8.
Cu 30: Thy phn 25,65 gam mantoz vi hiu sut 82,5% thu c dung dch X. Cho X tc dng vi dung dch
AgNO
3
/NH
3
d thu c lng kt ta Ag l :
Cu 31: Nguyn t nguyn t X c s th t l 16 trong bng tun hon, cng thc phn t ca X vi oxi v
hiro ln lt l:
A. XO v XH
2
B. XO
3
v XH
2
. C. X
2
O v X D. X
2
O v XH
2
.
Cu 32:Trong cc phn t N
2
, HCl, NaCl, MgO. Cc phn t c lin kt cng ha tr l:
A. NaCl v MgO B. HCl v MgO. C. N
2
v NaCl D. N
2
v HCl.
Cu 33: Nguyn t R c tng s cc ht c bn l 52, s ht khng mang in ln gp 1,059 ln s ht mang
in dng. Kt lun no sau y khng ng vi R?
A. R c s khi l 35. B. Trng thi c bn ca R c 3 electron c thn.
C. in tch ht nhn ca R l 17+. D. R l phi kim.
Cu 34: Cho s phn ng sau:
Al + H
2
SO
4
Al
2
(SO
4
)
3
+ H
2
S + H
2
O
Tng h s ti gin ca cc cht tham gia phn ng l:
A. 18 B. 30 C. 42 D. 45
Cu 35: Kim loi no sau y khi tc dng vi dung dch HCl v kh clo cho ng mt loi mui?
A. Cu B. Ag C. Fe D. Zn
Cu 36: un nng mt ancol no, n chc, mch h X vi H
2
SO
4
c nhit thch hp thu c cht
hu c Y. T khi hi ca Y so vi X bng 0,609. X c cng thc phn t l:
A. C
3
H
7
OH. B. CH
3
OH. C. C
4
H
9
OH. D. C
2
H
5
OH.
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Trang 10
Cu 37. Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol d. Cho
ton b X tc dng vi dung dch NaHCO
3
(d), thu c 0,56 lt kh CO
2
( ktc). Khi lng etanol
b oxi ho to ra axit l:
Cu 38: un nng 0,01 mol cht X vi dung dch NaOH d thu c 1,34 gam mt mui ca 1 axt hu c
Y v 0,92 gam 1 ru n chc Z. Cng thc cu to ca X l:
A. C
2
H
5
OCO-COOC
2
H
5
B. CH
2
(COOC

H
3
)
2
C. CH
3
COOC
2
H
5
D. CH
3
COOC
3
H
7

Cu 39: X phng ho 3,52 gam este X c to ra t axit n chc v ancol n chc bng dung dch
NaOH va c mui Y v ancol Z. Nung nng Y vi oxi thu c 2,12 gam Natri cacbonat, kh CO
2
v
hi nc. Ancol Z c chia lm hai phn bng nhau. Phn 1 cho tc dng vi Na va thu c kh H
2
c
s mol bng s mol ancol phn ng v 1,36 gam mui. Phn 2 cho tc dng vi CuO d, nung nng c
cht hu c T c phn ng trng bc. Cng thc cu to ca X l:
A.Etylaxetat B.Metylpropionat C.Metylaxetat D.propylfomat
Cu 40: Khi x phng ho 0,9 gam cht bo cn 24 ml dung dch KOH 0,25 M. Ch s x phng ho ca
mu cht bo l:
A. 0,336 B. 336 C. 0,3733 D. 373,33
Cu 41: Dung dch c pH=4 s c nng ion OH
-
bng:
A. 10
4
B. 10
-10
C. 4 D. 10
-4

Cu 42: Nung 8,42g hn hp X gm Al, Mg, Fe trong oxi sau mt thi gian thu c 11,62g hn hp Y.
Ha tan hon ton Y trong dung dch HNO
3
d thu c 1,344 lt NO (ktc) l sn phm kh duy nht. S
mol HNO
3
phn ng l:
A. 0,56 mol B. 0,64 mol C. 0,48 mol D. 0,72 mol
Cu 43: Cho cc cht: FeS, Cu
2
S, FeSO
4
, H
2
S, Ag, Fe, KMnO
4
, Na
2
SO
3
, Fe(OH)
2
. S cht c th phn ng
vi H
2
SO
4
c nng to ra SO
2
l:
A. 9 B. 8 C. 6 D. 7
Cu 44: Ly dung dch axit c pH = 5 v dung dch baz c pH = 9 theo t l no thu c dung dch c
pH = 8?
A.
9
11
=
axit
bazo
V
V
. B.
11
9
=
axit
bazo
V
V
. C. V
baz
= V
ax
. D. Khng xc nh c.
Cu 45: Este X c CTPT C
5
H
8
O
2
khi tc dng vi NaOH to ra 2 sn phm u c kh nng tham gia phn
ng trng gng. S cht X tha mn iu kin trn l:
A. 2 B. 1 C. 3 D. 4
Cu 46: Ha tan a mol Fe trong dung dch H
2
SO
4
thu c 12,32 lt SO
2
(ktc) l sn phm kh duy nht v
dung dch X. C cn dung dch X thu c 75,2 gam mui khan. Gi tr ca a l:
A. 0,4 B. 0,1 C. 0,3 D. 0,5
Cu 47: Dy no sau y gm cc kim loi u c th iu ch c bng phng php nhit luyn:
A. Zn, Mg, Ag B. Ba, Fe, Cu C. Al, Cu, Ag D. Cr, Fe, Cu
Cu 48: Mt o - aminoaxit no X ch cha 1 nhm -NH
2
v 1 nhm -COOH. Cho 3,56 gam X tc dng va
vi HCl to ra 5,02 gam mui. Tn gi ca X l:
A. Alanin B. Valin C. Lysin D. Glyxin
Cu 49: Khi thy phn mt octapetit X mch h, c cng thc cu to l Gly-Phe-Tyr-Lys-Gly-Phe-Tyr-Ala
th thu c bao nhiu tripeptit c cha Gly?
A. 4. B. 3. C. 5. D. 6.
Cu 50: Ha tan hon ton 15,2 gam cht rn X gm Cu, CuS, Cu
2
S v S bng HNO
3
d thy thot ra 10,08
lt kh NO duy nht (ktc) v dung dch Y. Thm dung dch Ba(OH)
2
d vo dung dch Y c m gam kt
ta. Gi tr ca m l:
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Trang 11
TRNG THPT MINH KHAI
T HO HC
( thi c 05 trang)
THI TH I HC LN 1 NM 2014
Mn thi: Ho hc
Thi gian lm bi: 90 pht; (50 cu trc nghim)

- Th tch cc cht kh u cho iu kin tiu chun
Cho bit: H = 1; He = 4; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr =
52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137.

PHN CHUNG CHO TT C CC TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: Cho m(g) hn hp X gm Na, Ca tan ht vo dung dch Y cha 0,08 mol NaHCO
3
v 0,04 mol
CaCl
2
, sau phn ng thu c 7 gam kt ta v thy thot ra 0,896 lt kh. Gi tr ca m l
A. 1,66 g. B. 1,72 g. C. 1,2 g. D. 1,56 g.
Cu 2: Cho cc phn ng sau trong iu kin thch hp
(a) Cl
2
+ KI d (b) O
3
+ KI d (c) H
2
SO
4
+ Na
2
S
2
O
3

(d) NH
3
+ O
2

0
t
(e) MnO
2
+ HCl (f) KMnO
4

0
t

S phn ng to ra n cht l
A. 3. B. 4. C. 5. D. 6.
Cu 3: Mt bnh kn cha hn hp X gm 0,06 mol axetilen; 0,09 mol vinylaxetilen; 0,16 mol H
2
v mt t
bt Ni. Nung hn hp X thu c hn hp Y gm 7 hirocacbon(khng cha but-1-in) c t khi hi i vi
H
2
l 328/15. Cho ton b hn hp Y i qua bnh ng dung dch AgNO
3
/NH
3
d, thu c m gam kt ta
vng nht v 1,792 lt hn hp kh Z thot ra khi bnh. lm no hon ton hn hp Z cn va ng 50 ml
dung dch Br
2
1M. Cc phn ng xy ra hon ton. Gi tr ca m l
A. 28,71. B. 14,37. C. 13,56. D. 15,18.
Cu 4: Cho n cht lu hunh tc dng vi cc cht: O
2
; H
2
; Hg; HNO
3
c, nng; H
2
SO
4
c, nng trong
iu kin thch hp. S phn ng trong lu hunh th hin tnh kh l
A. 2. B. 3. C. 4. D. 5.
Cu 5: Thy phn m (gam) tinh bt trong mi trng axit(gi s s thy phn ch to glucozo). Sau mt thi
gian phn ng, em trung ha axit bng kim, sau cho tc dng hon ton vi dung dch AgNO
3
trong
NH
3
d thu c m (gam) Ag. Hiu sut ca phn ng thy phn tinh bt l
A. 66,67%. B. 80%. C. 75%. D. 50%.
Cu 6: Cho 0,896 lt Cl
2
hp th ht vo dung dch X cha 0,06 mol NaCl; 0,04 mol Na
2
SO
3
v 0,05 mol
Na
2
CO
3
. Sau khi cc phn ng xy ra hon ton thu c dung dch Y. C cn dung dch Y thu c m(g)
mui khan. Gi tr ca m l
A. 21,6g. B. 16,69g. C. 14,93g. D. 13,87g.
Cu 7: Tin hnh hirat ho 2,24 lt C
2
H
2
vi hiu sut 80% thu c hn hp sn phm Y. Cho Y qua
lng d AgNO
3
/NH
3
thu c m(g) kt ta. Gi tr ca m l
A. 21,6g. B. 23,52g. C. 24 g. D. 22,08g.
Cu 8: Cho cc cht: Ba; BaO; Ba(OH)
2
; NaHCO
3
; BaCO
3
; Ba(HCO
3
)
2
; BaCl
2
. S cht tc dng c vi
dung dch NaHSO
4
to ra kt ta l
A. 4. B. 5. C. 6. D. 7.
Cu 9: X l mt amino axit no (phn t ch c 1 nhm NH
2
v 1 nhm -COOH). Cho 0,03 mol X tc dng
vi dung dch cha 0,05 mol HCl thu c dung dch Y. Thm 0,1 mol NaOH vo Y sau phn ng em c
cn thu c 7,895 gam cht rn. X l
A. Glixin. B. Alanin. C. Valin. D. Lysin.
Cu 10: Nung 18,1 gam cht rn X gm Al, Mg v Zn trong oxi mt thi gian c 22,9 gam hn hp cht
rn Y. Ho tan ht Y trong dung dch HNO
3
long d c V lt NO(sn phm kh duy nht) v dung dch
cha 73,9 gam mui. Gi tr ca V l
A. 6,72. B. 3,36. C. 2,24. D. 5,04.
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Trang 12
Cu 11: Cht hu c X c cng thc phn t C
9
H
12
. Khi cho X tc dng vi clo c mt bt st hoc tc dng
vi clo khi chiu sng u thu c 1 dn xut monoclo duy nht. Tn gi ca X l
A. Cumen. B. Propylbenzen. C. 1-etyl-3-metylbenzen. D. 1,3,5-trimetylbenzen.
Cu 12: Trn V(ml) dung dch H
3
PO
4
0,08M vi 250 ml dung dch NaOH 0,32M d thu c dung dch X
cha 2 cht tan c cng nng mol. Gi tr ca V l
A. 250 ml. B. 2000 ml. C.
2000
.
3
ml D. 400 ml.
Cu 13: Thu phn hon ton 0,1 mol 1 pptt X (mch h, c to bi cc o - amino axit c 1 nhm NH
2

v 1 nhm -COOH) bng dung dch HCl va thu c dung dch Y. C cn dung dch Y thu c cht
rn c khi lng ln hn khi lng ca X l 52,7 gam. S lin kt pptt trong X l
A. 14. B. 9. C. 11. D. 13.
Cu 14: Ion M
3+
c cu hnh e ca kh him Ne. V tr ca M trong bng h thng tun hon l
A. Chu k 2, nhm VIIIA. B. Chu k 2, nhm VA. C. Chu k 3, nhm IIIA. D. Chu k 3, nhm IVA.
Cu 15: Hn hp X gm 2 axit no. t chy hon ton a mol hn hp X thu c a mol H
2
O. Mt khc, cho
a mol hn hp X tc dng vi NaHCO
3
d thu c 1,4 a mol CO
2
. % khi lng ca axit c khi lng mol
nh hn trong X l
A. 26,4% B. 27,3% C. 43,4% D. 35,8%
Cu 16: Cho cc cht: Glucoz; Saccaroz; Tinh bt; Glixerol v cc pht biu sau:
(a) C 3 cht tc dng c vi dung dch AgNO
3
/NH
3

(b) C 2 cht c phn ng thu phn trong mi trng axit
(c) C 3 cht ho tan c Cu(OH)
2

(d) C 4 cht u c nhm OH trong phn t.
S pht biu ng l
A. 1. B. 2. C. 4. D. 3.
Cu 17: Cho s phn ng:
CH
4

0
1500 C
X
2
2
H O
Hg
+
Y
2
H
Ni
Z
2 4
0
180
H SO dac
C
G
2
Br
M
2
O
Y.
S phn ng oxi ho kh trong s trn l
A. 3. B. 4. C. 5. D. 6.
Cu 18: Polime no sau y c tng hp bng phn ng trng ngng
A. poliacrilonitrin B. poli(metyl metacrylat) C. polistiren D. poli(etylen terephtalat)
Cu 19: Ho tan m(g) hn hp X gm Fe, FeS, FeS
2
v S vo dung dch HNO
3
c, nng thu c dung
dch Y (khng cha mui amoni) v 49,28 lt hn hp kh NO, NO
2
nng 85,2 (g). Cho Ba(OH)
2
d vo Y,
ly kt ta nung trong khng kh n khi lng khng i thu c 148,5 gam cht rn khan. Gi tr ca m
l
A. 38,4 (g). B. 9,36 (g). C. 24,8. D. 27,4.
Cu 20: Mt hn hp M gm 0,06 mol axit cacboxylic X v 0,04 mol ancol no a chc Y. t chy hon
ton hn hp M trn thu c 3,136 lt CO
2
. % khi lng ca Y trong hn hp M l
A. 52,67%. B. 66,91%. C. 33,09%. D. 47,33%.
Cu 21: Hn hp A gm hirocacbon X v cht hu c Y (C, H, O) c t khi so vi H
2
bng 13,8. t
chy hon ton 1,38 g A cn 0,095 mol O
2
, sn phm chy thu c c 0,08 mol CO
2
v 0,05 mol H
2
O. Cho
1,38 g A qua lng d AgNO
3
/NH
3
thu c m(g) kt ta. Gi tr ca m l
A. 11,52 (g). B. 12,63 (g). C. 15,84 g. D. 8,31.
Cu 22: Th nghim no sau y thu c kt ta sau khi cc phn ng kt thc.
A. Cho t t n d dung dch NH
3
vo dung dch CuSO
4
.
B. Cho t t n d dung dch NaOH vo dung dch AlCl
3
.
C. Cho t t n d CO
2
vo dung dch Ca(OH)
2
.
D. Cho t t n d Ba(OH)
2
vo dung dch Al
2
(SO
4
)
3
.
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Trang 13
C
6
H
12
O
6

Men
X + CO
2
; X + O
2
Y + H
2
O; X + Y
0
, H t
+
Z + H
2
O.
Tn gi ca Z l
A. Metylpropionat. B. Axt butanoic. C. Etyl axetat. D. Propylfomat.
Cu 24: Cht hu c X no ch cha 1 loi nhm chc c cng thc phn t C
4
H
10
O
x
. Cho a mol X tc dng
vi Na d thu c a mol H
2
, mt khc khi cho X tc dng vi CuO, t
0
thu c cht Y a chc. S ng
phn ca X tho mn tnh cht trn l
A. 2. B. 3. C. 4. D. 5.
Cu 25: Cho V lt kh CO
2
hp th t t vo dung dch X cha 0,04 mol NaOH v 0,03 mol Na
2
CO
3
. Khi
cho CO
2
hp th ht thu c dung dch Y. Lm bay hi cn thn dung dch Y thu c 6,85 gam cht rn
khan. Gi tr ca V l
A. 2,133 lt. B. 1,008 lt. C. 0,896 lt. D. 1,344 lt.
Cu 26: Loi phn ng ho hc no sau y lun l phn ng oxi ho kh
A. Phn ng th. B. Phn ng trao i. C. Phn ng ho hp. D. Phn ng phn hu.
Cu 27: Tin hnh cc th nghim sau:
(a). Sc H
2
S vo dung dch nc clo (b). Sc kh SO
2
vo dung dch thuc tm
(c). Cho H
2
S vo dung dch Ba(OH)
2
(d). Thm H
2
SO
4
long vo nc Javen
(e). t H
2
S trong oxi khng kh.
S th nghim xy ra phn ng oxi ho kh l
A. 2. B. 3. C. 4. D. 5.
Cu 28: Chia m(g) hn hp X gm Al, Zn, Mg thnh 2 phn bng nhau
- Phn 1 cho vo dung dch HCl d thu c 1,344 lt H
2

- Phn 2 nung trong khng kh n khi lng khng i thu c 3,04 gam cht rn.
Gi tr ca m l
A. 4,16 gam. B. 5,12 gam. C. 2,08 gam. D. 2,56 (g).
Cu 29: Cho 4,32 gam hn hp X gm Fe, Cu dng bt vo 100 ml dung dch AgNO
3
1M thu c dung
dch Y v 12,08 gam cht rn Z. Thm NaOH d vo Y, ly kt ta nung trong khng kh n khi lng
khng i thu c m(g) cht rn. Gi tr ca m l
A. 5,6. B. 4. C. 3,2. D. 7,2 gam.
Cu 30: X l mt loi phn bn ho hc. Khi cho X tc dng vi dung dch NaOH un nng c kh thot ra.
Nu cho X vo dung dch H
2
SO
4
long sau thm bt Cu vo thy c kh khng mu ho nu trong khng
kh thot ra. X l
A. NaNO
3
. B. (NH
4
)
2
SO
4
. C. (NH
2
)
2
CO. D. NH
4
NO
3
.
Cu 31: Phenol phn ng c vi tt c cc cht trong dy no sau y
A. Na; NaOH; NaHCO
3
. B. Na; Br
2
; CH
3
COOH. C. Na; NaOH; (CH
3
CO)
2
O. D. Br
2
; HCl; KOH.
Cu 32: Cho phn ng :
N
2
(k) + 3H
2
(k) 2NH
3
(k) H A = -92 kJ.
Hai bin php u lm cn bng chuyn dch theo chiu thun l
A. gim nhit v gim p sut. B. tng nhit v tng p sut.
C. gim nhit v tng p sut. D. tng nhit v gim p sut.
Cu 33: Hai kim loi no sau y phn ng c vi dung dch H
2
SO
4
long nhng khng phn ng vi
H
2
SO
4
c, ngui
A. Cu, Ag. B. Zn, Al. C. Al, Fe. D. Mg, Fe.
Cu 34: Trn 250 ml dung dch HCl 0,1M vi 250 ml dung dch NaOH aM thu c 500 ml dung dch X c
pH = 13. Gi tr ca a l
A. 0,3M. B. 0,2M. C. 0,1M. D. 0,5M.
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Trang 14
(a) Pptt Gly Ala c phn ng mu biure (b) Trong phn t ipptt c 2 lin kt pptt
(c) C th to ra ti a 4 ipeptt t cc amino axt Gly; Ala. (d) Dung dch Glyxin lm i mu qu tm
S pht biu ng l
A. 1. B. 2. C. 3. D. 4.
Cu 36: in phn dung dch c cha 0,1 mol CuSO
4
v 0,2 mol FeSO
4
trong thng in phn khng c
mng ngn. Sau mt thi gian thu c 2,24 lt kh anot th dng li, yn bnh in phn n khi catot
khng thay i. Khi lng kim loi thu c catot l
A. 12g. B. 6,4g. C. 17,6g. D. 7,86 g.
Cu 37: Cng thc phn t ca metylmetacrylat l
A. C
5
H
10
O
2
. B. C
4
H
8
O
2
. C. C
5
H
8
O
2
. D. C
4
H
6
O
2
.
Cu 38: Amin n chc X c % khi lng nit l 23,73%. S ng phn cu to ca X l
A. 2. B. 3. C. 5. D. 4.
Cu 39: Hn hp A gm 2 este n chc X, Y. Cho 0,05 mol A tc dng va vi dung dch NaOH thu
c hn hp sn phm hu c B. t chy ht ton b B thu c 2,688 lt CO
2
; 3,18 gam Na
2
CO
3
. Khi
lm bay hi B thu c m(g) cht rn. Gi tr ca m l
A. 4,56 (g). B. 3,4(g). C. 5,84 (g) D. 5,62 (g).
Cu 40: Dy no sau y gm cc cht kh u lm mt mu dung dch nc brom.
A. Cl
2
; CO
2
; H
2
S. B. H
2
S; SO
2
; C
2
H
4
. C. SO
2
; SO
3
; N
2
. D. O
2
; CO
2
; H
2
S.
PHN RING
A. Chng trnh chun (t cu 41 n cu 50)
Cu 41: Cht hu c X c cng thc phn t C
2
H
8
N
2
O
3
. Cho 3,24 gam X tc dng vi 500 ml dung dch
KOH 0,1M. Sau khi kt thc phn ng thu c cht hu c Y v dung dch Z. C cn Z thu c khi
lng cht rn l
A. 3,03. B. 4,15. C. 3,7 D. 5,5.
Cu 42: Hn hp X gm 2 amino axit no (ch c nhm chc COOH v NH
2
trong phn t), trong t l
m
O
: m
N
= 128 : 49. tc dng va vi 7,33 gam hn hp X cn 70 ml dung dch HCl 1M. Mt khc,
t chy hon ton 7,33 gam hn hp X cn 0,3275 mol O
2
. Sn phm chy thu c gm CO
2
, N
2
v m
gam H
2
O. Gi tr ca m l
Cu 43: Trong s cc cht: Metanol; axt fomic; glucoz; saccaroz; metylfomat; axetilen; tinh bt. S cht
phn ng c vi dung dch AgNO
3
/NH
3
sinh ra Ag kim loi l
A. 2. B. 3. C. 4. D. 5.
Cu 44: Pht biu no sau y ng
A. hn hp CuS; PbS c th tan ht trong dung dch HNO
3
long.
B. Hn hp BaCO
3
; BaSO
4
c th tan ht trong dung dch H
2
SO
4
long.
C. Hn hp Ag
3
PO
4
; AgCl c th tan ht trong dung dch HNO
3
long.
D. Hn hp Cu; Fe(NO
3
)
2
c th tan ht trong dung dch H
2
SO
4
long.
Cu 45: Cht rn X tc dng vi dung dch HNO
3
long, d thu c dung dch Y ch cha 1 mui, axit d
v sinh ra kh NO (sn phm kh duy nht). Dy cc cht no sau y ph hp vi X
A. Cu; CuO; Fe(OH)
2
. B. CuFeS
2
; Fe
3
O
4
; FeO. C. FeCO
3
; Fe(OH)
2
; Fe(OH)
3
. D. Fe; Cu
2
O; Fe
3
O
4
.
(a). Kh NO
2
; SO
2
gy ra hin tng ma axt
(b). Kh CH
4
; CO
2
gy ra hin tng hiu ng nh knh
(c). Ozon trong kh quyn l nguyn nhn gy nhim khng kh
(d). Cht gy nghin ch yu trong thuc l l nicotin.
S pht biu ng l
A. 1. B. 2. C. 3. D. 4.
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Trang 15
Cu 47: X l anht mch h. Cho V lt hi X tc dng vi 3V lt H
2
c mt Ni, t
0
, sau phn ng thu c
hn hp sn phm Y c th tch 2V (cc th tch o cng iu kin). Ngng t Y thu c ancol Z, cho Z tc
dng vi Na d thu c s mol H
2
bng s mol Z phn ng. Cng thc tng qut ca X l
A. C
n
H
2n 4
O
2
, n > 2. B. C
n
H
2n 2
O
2
, n > 2. C. C
n
H
2n 4
O
2
, n > 3. D. C
n
H
2n 4
O, n > 4.
Cu 48: Cho dy cc cht: C
6
H
5
NH
2
(1), CH
3
NH
2
(2), (C
6
H
5
)
2
NH (3), (CH
3
)
2
NH (4), NH
3
(5) (C
6
H
5
- l gc
phenyl). Dy cc cht sp xp theo th t lc baz gim dn l
A. (4), (1), (5), (2), (3). B. (3), (1), (5), (2), (4).
C. (4), (2), (3), (1), (5). D. (4), (2), (5), (1), (3).
Cu 49: Cho phn ng:
FeS
2
+ HNO
3
Fe
2
(SO
4
)
3
+ NO + H
2
SO
4
+ H
2
O.
H s ca HNO
3
sau khi cn bng (s nguyn ti gin) l
A. 8. B. 10. C. 12. D. 14.
Cu 50: Dn mt lung kh CO d qua ng s ng m gam Fe
3
O
4
v CuO nung nng n khi phn ng hon
ton thu c 2,32 gam hn hp kim loi. Kh thot ra khi bnh c dn qua dung dch nc vi trong d
thu c 5,00 gam kt ta. Gi tr ca m l
A. 6,24. B. 5,32. C. 4,56. D. 3,12.
B. Chng trnh Nng cao (t cu 51 n cu 60)
Cu 51: Hai phn t no sau y u c dng lai ho sp
A. C
2
H
2
v BF
3
. B. BeH
2
v BeCl
2
. C. H
2
O v NH
3
. D. C
2
H
2
v CH
4
.
Cu 52: Cho H
2
O
2
ln lt tc dng vi: KNO
2
; KI; Ag
2
O; SO
2
; hn hp (KMnO
4
+ H
2
SO
4
long). S phn
ng trong H
2
O
2
th hin tnh oxi ho l
A. 5. B. 4. C. 3. D. 2.
Cu 53: Cho phn ng:
SO
2
+ Fe
2
(SO
4
)
3
+ H
2
O H
2
SO
4
+ FeSO
4
.
Pht biu no sau y ng
A. H
2
O l cht oxi ho. B. Fe
2
(SO
4
)
3
l cht kh.
C. SO
2
l cht b oxi ho. D. SO
2
l cht b kh.
Cu 54: Ho tan m(g) hn hp X gm m Ure v NH
4
NO
3
vo lng d dung dch Ca(OH)
2
un nng. Sau
khi kt thc phn ng thu c 9 gam kt ta v thot ra 4,256 lt kh. Phn trm khi lng ca Ure trong X
l
A. 12,91%. B. 83,67%. C. 91,53%. D. 87,09%.
Cu 55: Bit E
0
pin (Ni-Ag) = 1,06V v E
0
Ni
2+
/Ni = -0,26V. Th in cc chun ca cp E
0
Ag
+
/Ag l
A. 0,76 (V). B. 1,32 (V). C. 0,8 (V). D. 0,85 (V).
Cu 56: S ng phn cu to ca C
4
H
8
c kh nng tham gia phn ng cng vi dung dch Br
2
l
A. 2. B. 3. C. 4. D. 5.
Cu 57: Thu phn m(g) mantoz trong mi trng axit vi hiu sut 75% thu c hn hp X. Cho X phn
ng vi lng d dung dch AgNO
3
/NH
3
thu c 113,4 gam Ag. Gi tr ca m l
A. 102,6 gam. B. 179,55 g. C. 119,7. D. 85,5.
Cu 58: Mt loi cao su buna-N c phn trm khi lng ca nit l 19,72%. T l mt xch butaien v
vinyl xianua l
A. 1 : 2. B. 2 : 1 . C. 1 : 3. D. 3 : 1.
Cu 59: nhn bit 3 dung dch ring bit: Glyxin, axt glutamic v lysin ta ch cn dng 1 thuc th l
A. HCl. B. NaOH. C. CaCO
3
. D. Qu tm.
Cu 60: ipptt X v tetrapptt Y u c to thnh t 1 amino axit no (trong phn t ch c 1 nhm
NH
2
v 1 nhm -COOH). Cho 19,8 gam X tc dng va vi dung dch HCl thu c 33,45 gam mui.
t chy hon ton 0,1 mol Y cn dng s mol O
2
l
A. 1,15. B. 0,5 C. 0,9. D. 1,8.
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Trang 16
S GD & T QUNG NAM
TRNG THPT NGUYN DUY HIU

( C 5 TRANG)
KIM TRA CHT LNG-LP 12
NM HC: 2013-2014
Mn : HA HC
( Thi gian lm bi: 90 pht,khng k thi gian pht )

M thi 134
H, tn th sinh:..........................................................................
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t:
Mg = 24;Al = 27;P = 31;S =32; Cl =35,5; K =39; Ca = 40; Fe =56; Cu = 64; Zn = 65;As = 75;Br = 80; Rb =
85,5;Ag =108;Ba =137,Pb =207,I =127,H = 1; Li = 7;C =12; N = 14;O = 16;Na = 23; He = 4

I . PHN CHUNG CHO TT C TH SI NH : t cu 1 n cu 40
Cu 1: Hn hp X gm saccaroz v mantoz c khi lng 68,4 gam ( T l s mol 1:1 ).Thy phn X mt
thi gian vi hiu sut mi cht tng ng ln lt bng 50% v 75%. Cho hn hp sn phm tc dng vi
lng d dung dch AgNO
3
/NH
3
thu c m gam kt ta. Gi tr ca m l?
Cu 2: Loi t no di y c iu ch bng phn ng trng hp?
A. T Olon. B. T Lapsan. C. T nilon-6,6. D. T nilon-7.
Cu 3: Bit cc cp Oxi ha-kh xp theo tnh Oxi ha ca ion kim loi tng dn t tri qua phi sau:
Mg
2+
Fe
2+
Cu
2+
Fe
3+
Ag
+
Mg Fe Cu Fe
2+
Ag .
Hy cho bit phn ng no di y khng ng?
A. Mg (d) + 2Fe
3+
Mg
2+
+ 2Fe
2+
B. Fe + 3Ag
+
(d)

Fe
3+
+ 3Ag
C. Fe + 2Fe
3+
3Fe
2+
D. Cu + 2Fe
3+
Cu
2+
+ 2Fe
2+

Cu 4: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: K
2
O v Al
2
O
3
; Cu v FeCl
3
;
BaCl
2
v CuSO
4
; Ba v NaHCO
3
. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l:
A. 3. B. 1. C. 4. D. 2.
Cu 5: Hn hp X gm : CH
3
COOH, HCOOCH
3
v CH
3
CH(OH)COOH. t chy hon ton hn hp X
cn dng va ht V lt O
2
(kc) sau phn ng thu c CO
2
v H
2
O. Hp th ht sn phm chy vo nc
vi trong th thu c 18,6 gam kt ta , ng thi nhn thy khi lng dung dch nc vi khng thay i
Vy gi tr ca V tng ng l:
A. 11,2 lt B. 6,72 lt C. 8,40 lt D. 4,1664 lt
Cu 6: Pht biu no sau y khng ng:
A. Glucoz ch yu tn ti dng mch vng. B. Khi thu phn mantoz ch cho glucoz
C. xenluloz p vi anhirit axetic cho t visco. D. Glucoz phn ng vi CH
3
OH trong HCl.
Cu 7: Cu no sau y m t ng s bin i tnh cht ca cc kim loi kim theo chiu in tch ht nhn
tng dn?
A. Nng lng ion ha (I
1
) ca nguyn t gim dn. B. Khi lng ring ca n cht gim dn.
C. Nhit nng chy tng dn. D. Bn knh nguyn t gim dn.
Cu 8: T 1 tn saccaroz nguyn cht iu ch c bao nhiu lt Ancol etylic 50
o
(T trng ca ancol bng
0,8 g/ml). Bit hiu sut ton b qu trnh t 60%.
A. 516,48 lt. B. 116,14 lt. C. 129,12 lt. D. 403,50 lt.
Cu 9: Loi thch cao no di y c trong phn vit bng?
A. CaSO
4
( khan). B. CaSO
4
.2H
2
O. C. CaSO
4
.5H
2
O. D. CaSO
4
.H
2
O.
Cu 10: S lng ng phn amin bc 1 ca hp cht c cng thc phn t C
4
H
11
N bng ?
A. 4. B. 6. C. 5. D. 3.
Cu 11: Ngi ta iu ch Anilin bng cch Nitro ha 500 gam benzen ,hiu sut mi giai on l
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Trang 17
78%. Khi lng Anilin thu c l?
Cu 12: Phn ng no sau y chuyn glucozo v fructozo thnh cng mt sn phm duy nht?
A. Phn ng vi Cu(OH)
2
un nng. B. Phn ng trng gng.
C. Phn ng vi H
2
/Ni,.t
o
. D. Phn ng vi Natri.
Cu 13: Cho cc cht sau y:
(1) CH
3
CH(NH
2
)-COOH (2) HO-CH
2
COOH (3) CH
2
O v C
6
H
5
OH
(4) C
2
H
4
(OH)
2
v p-C
6
H
4
(COOH)
2
(5) (CH
2
)
6
(NH
2
)
2
v (CH
2
)
4
(COOH)
2
.
Cc cht c kh nng tham gia phn ng trng ngng l?
A. (1),(2). B. (3),(4). C. (3),(5). D. (1),(2),(3),(4),(5).
Cu 14: iu khng nh no sau y l sai?
A. Amino acid l cht hu c tp chc, phn t c cha ng thi nhm NH
2
v nhm COOH.
B. Amino acid l hp cht lng tnh.
C. Poliamit l sn phm trng ngng ca amino acid.
D. Dung dch cc Amino acid u khng i mu qu tm.
Cu 15: t chy hon ton 0,05 mol hn hp M gm anehit X v este Y, cn dng va 0,155 mol O
2
,
thu c 0,13 mol CO
2
v 2,34 gam H
2
O. Mt khc, cho 0,1 mol M phn ng vi lng d dung dch
AgNO
3
trong NH
3
, kt thc cc phn ng thu c 21,6 gam Ag. CT cu to thu gn ca X, Y ln lt l
A. HCHO v CH
3
COOCH
3
. B. CH
3
CHO v HCOOC
2
H
5
.
C. CH
3
CHO v HCOOCH
3
. D. CH
3
CHO v CH
3
COOCH
3
.
1. Thy phn hon ton mt este n chc trong dung dch NaOH,lun thu c mui v ancol
2. Cht git ra tng hp c th git ra trong nc cng.
3. Saccaroz phn ng c vi H
2
(Ni,t
0
)
4. Khng th phn bit c glucoz v fructoz bng dung dch AgNO
3
/NH
3
.
5. Tinh bt v xenluloz l ng phn ca nhau.
6. phn bit anilin v phenol,ta c th dng dung dch brm.
7. Cc peptit u d b thy phn trong mi trng axit hoc kim
S pht biu lun lun ng l:
A. 3. B. 6. C. 5. D. 4.
Cu 17: Trn dung dch cha 2 mol NaHCO
3
vi dung dch cha 1 mol Ba(HSO
4
)
2
th nhn thy?
A. Dung dch sau phn ng lm qu tm ho hng. B. Si bt kh v dung dch vn c.
C. Ch thy c kt ta trng. D. Khng c hin tng g xy ra.
Cu 18: t chy hon ton mt cacbohydrat X thu c 5,28 gam CO
2
v 1,98 gam H
2
O. Cng thc phn
t ca cht X l?
A. C
6
H
10
O
5.
B. C
12
H
22
O
11.
C. (CH
2
O)
n
. D. C
6
H
12
O
6.

Cu 19: Cho m gam bt Fe vo l ng dung dch HNO
3
, sau kh phn ng kt thc th thu c 1,568 lt
NO(kc).Thm dung dch cha 0,15 mol H
2
SO
4
(long) vo l th thy kh NO tip tc thot ra v cui cng
thu c dung dch Y. phn ng ht vi cc cht trong dung dch Y cn va ht 300 ml dung dch KOH
1,5M.( Bit NO l sn phm kh duy nht ca N
+5
). Gi tr ca m l?
Cu 20: Nhn nh no di y khng ng?
A. Ester n chc c cng thc R
1
COOR
2
.
B. Ester l hp cht hu c trong phn t c nhm COOR vi R l gc Hydrocacbon.
C. Khi thay th nguyn t H nhm cacboxyl ca acid cacboxylic bng gc hydrocacbon th ta c este
D. Ester ca acid cacboxylic no,n chc v ancol no n chc c cng thc l C
n
H
2n
O
2
(n>1).
Cu 21: bo qun kim loi Natri trong phng th nghim,ngi ta dng cch no sau y?
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Trang 18
A. Ngm chm Na trong nc. B. Ngm chm Na trong Ancol.
C. Ngm chm Na vo du ha D. Bo qun trong kh NH
3
.
Cu 22: T l th tch CO
2
: H
2
O (hi) sinh ra khi t chy hon ton mt ng ng (X) ca Glyxin l 6 : 7
(phn ng chy sinh ra kh Nit). X tc dng vi Glyxin cho sn phm l mt ipeptit. Cng thc ca X l?
A. H
2
NCH
2
CH
2
COOH. B. CH
3
-CH(NH
2
)-COOH.
C. C
6
H
5
NH
2
. D. C
2
H
5
-CH(NH
2
)-COOH.
Cu 23: C 1,05 gam cao su buna-S phn ng va ht vi 0,8 gam brom trong CCl
4
. Tnh t l mt xch
butadien v styren trong cao su l bao nhiu?
A. 3 : 4. B. 1 : 1 C. 1 : 2. D. 2 : 3.
Cu 24: Cho lung kh Hydro (d) i qua hn hp cc Oxid CuO.Fe
2
O
3
,Al
2
O
3
,MgO nung nng nhit
cao n phn ng hon ton. Hi cht rn cn li sau phn ng l?
A. Cu,Fe, Al
2
O
3
,Mg. B. Cu,Fe, Al
2
O
3
,MgO. C. Cu,Fe, Al,Mg. D. Cu,FeO, Al ,MgO.
Cu 25: in phn (in cc tr,c mng ngn) dung dch hn hp NaCl v CuSO
4
(t l s mol tng ng
l 1:1) khi catod xut hin bt kh th ngng in phn .Sn phm kh thu c Anod l ?
A. kh Cl
2
. B. kh Cl
2
v O
2
. C. kh Cl
2
v H
2
. D. kh H
2
v kh O
2
.
Cu 26: Cho hn hp gm Fe v Zn vo dung dch AgNO
3
n khi cc phn ng xy ra hon ton, thu c
dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X l?
A. Fe(NO
3
)
3
v Zn(NO
3
)
2
. B. AgNO
3
v Zn(NO
3
)
2
.
C. Fe(NO
3
)
2
v AgNO
3
. D. Zn(NO
3
)
2
v Fe(NO
3
)
2
.
Cu 27: Mt dung dch c tnh cht:
* Ha tan c Cu(OH)
2
cho dung dch mu xanh lam.
* B thy phn trong mi trng Acid.
* Khng kh c dung dch AgNO
3
/NH
3
v Cu(OH)
2
/NaOH.
Dung dch l?
A. Sacaroz. B. Fructoz. C. Mantoz. D. Glucoz.
Cu 28: Phng php c bn iu ch kim loi kim th l?
A. in phn mui Clorua ca chng. B. in phn mui Nitrat nng chy ca chng.
C. in phn dung dch mui Clorua D. in phn mui Clorua nng chy ca chng.
Cu 29: Trong cc cc vt liu sau y:
(1) T tm , (2) si bng , (3) len , (4) t enng, (5) t Visco, (6) nilon-6,6 ; (7) t acetat.
Loi t c ngun gc t Xenlulo l?
A. (1),(2),(6). B. (2),(3),(7). C. (2),(5),(7). D. (2),(3),(5).
Cu 30: C cc ion ring bit trong dung dch l : Ni
2+
, Zn
2+
, Ag
+
, Sn
2+
, Pb
2+
. Ion c tnh oxi ha mnh nht
v ion c tnh oxi ha yu nht ln lt l?
A. Pb
2+
v Ni
2+
. B. Pb
2+
v Zn
2+
. C. Ag
+
v Zn
2+
. D. Ni
2+
v Sn
2+
.
Cu 31: Trng hp no sau y to ra kim loi?
A. t FeS
2
trong Oxi d. B. t FeS trong khng kh.
C. Kh CuO bng H
2
d nhit cao. D. Nung hn hp MgCO
3
.CaCO
3
.
Cu 32: Trong mt loi nc cng khi c un si th mt tnh cng.Trong loi nc cng ny c ha tan
nhng hp cht no sau y?
A. Ca(HCO
3
)
2
, Mg(HCO
3
)
2
. B. CaCl
2
, Mg(HCO
3
)
2
. C. Ca(HCO
3
)
2
, MgCl
2
. D. MgCl
2
, CaSO
4
.
Cu 33: Hn hp X gm Al v Fe
2
O
3
. Nung 54,75 gam hn hp X trong iu kin khng c khng kh mt
thi gian thu c hn hpY.Chia Y thnh 2 phn bng nhau.
Phn 1: Cho tc dng vi dung dch NaOH long nng d,thy c 21,6 gam cht rn khng tan v
ng thi c 0,84 lt kh thot ra kc.
Phn 2: Tc dng vi dung dch HCl d thu c V lt kh (kc).
Tnh V?
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Trang 19
A. 3,92 lt. B. 3,08 lt. C. 2,8 lt. D. 5,04 lt.
Cu 34: un nng polime [-CH
2
-CH(OOCCH
3
)-]
n
vi dung dch HCl long. Sn phm thu c l?
A. [-CH
2
-CH(COOH)-]
n
v CH
3
OH. B. CH
2
=CH
2
v CH
3
COOH.
C. [-CH
2
-CH(COOH)-]
n
v CH
3
COOH. D. [-CH
2
-CHOH-]
n
v CH
3
COOH.
Cu 35: Cho dung dch cha cc cht : Anilin(1) ; metylamin(2) ; aminoacetic(3) ; Acid glutamic(4) acid
2,6-iaminohecxanoic(5).Hexa metylendiamin(6). Nhng dung dch lm qu tm ha xanh l?
A. (2),(5). B. (2),(3),(4). C. (1),(2),(5). D. (2),(5),(6).
Cu 36: Khi thy phn hon ton 41,1 gam mt Peptit X (mch h) thu c 26,7 gam alanin v 22,5 gam
glixin. Vy X l mt?
A. pentapeptit. B. ipeptit. C. tripeptit. D. tetrapeptit.
Cu 37: So snh pin in ha v n mn in ha, iu no sau y khng ng ?
A. Tn cc in cc ging nhau : catod l cc m v anod l cc dng
B. in cc c tnh kh mnh hn th b n mn
C. Pin in ha v n mn in ha u pht sinh dng in.
D. Kim loi c tnh kh mnh hn lun l cc m
Cu 38: Cho hn hp gm ipeptit Ala-Gly v tetrapeptit Ala-Gly-Ala-Val c t l s mol 1:2 tng ng tc
dng va vi 0,1 lt dung dch NaOH 0,5M, c cn dung dch sau phn ng c th thu
c m gam cht rn khan. Gi tr ca m l?
Cu 39: Mt loi cht bo c phn t khi 890 vC. T 10 kg cht bo ny s iu ch c m kg x phng
72% . Gi tr ca m l?
A. 12,228. B. 13,378. C. 15,326. D. 14,326.
Cu 40: S hp cht va tc dng vi HCl va tc dng vi NaOH , ng vi Cng thc phn t C
2
H
7
O
2
N
l?
A. 2. B. 3. C. 4. D. 1.
I I . PHN RI NG [10 cu]. Th sinh ch c lm mt trong hai phn (phn A hoc B)
A/ Theo chng trnh Chun: t cu 41 n cu 50
Cu 41: Cu hi sau y gm hai mnh ,mi mnh nu ln mt s d kin hay mt tnh cht....
Mnh 1: t chy 1 cht hu c X ch sinh ra CO
2
v H
2
O vi s mol CO
2
bng s mol H
2
O,
Mnh 2: th cng thc phn t ca cht X phi c dng tng qut C
n
H
2n
O
m
vi n >1 , m >0.
Nhn xt no di y hon ton ng?
A. Mnh 1 sai ,mnh 2 ng.
B. C hai mnh trn u ng,tng quan nhn qu ng.
C. Mnh 1 ng ,mnh 2 sai.
D. C hai mnh trn u ng nhng tng quan nhn qu cha hn ng
Cu 42: Cho m gam bt nhm tc dng vi dung dch HCl 18,25% va thu c dung dch X v kh
hydro.Thm m gam Na vo dung dch X thu c 3,51g kt ta. Khi lng ca dung dch X l?
Cu 43:
Hn hp X gm 2 ancol c cng s nguyn t cacbon. Cho 0,3 mol hn hp X tc dng vi Natri kim loi d
thu c 0,2 mol H
2
.Mt khc t chy hon ton 0,15 mol hn hp X thu c 6,72 lt CO
2
(kc). Thnh
phn trm khi lng ca ancol c khi lng t hn trong hn hp X bng
A. 40,26%. B. 40,25%. C. 59,75%. D. 59,74%.
Cu 44: Cho m gam hn hp X gm Na
2
O v Al ha tan ht vo nc d thu c 200 ml dung dch A ch
cha mt cht tan duy nht c nng 0,2M. Tnh m?
Cu 45: S ha cht m bnh nhm khng th cha c trong cc ha cht cho sau:
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Trang 20
NaOH,Ca(OH)
2
, Na
2
CO
3
,NaCl,Na
2
SO
4
,NH
4
Cl, HCl, NaHSO
4
.
A. 6. B. 5. C. 4. D. 7.
Cu 46: Nhn xt no di y khng ng?
A. u im ca cht git ra tng hp l dng c vi nc cng.
B. Cht git ra tng hp cha cc gc hydrocacbon phn nhnh nn gy nhim mi trng.
C. X phng hay cht git ra tng hp l mt.
D. Cht git ra tng hp c iu ch t cc sn phm ca du m.
Cu 47: in phn 500 ml dung dch hn hp CuSO
4
a mol/l v NaCl 1 mol/l vi in cc tr, mng ngn
xp, cng dng in khng i 5A trong thi gian 96,5 pht (hiu sut qu trnh in phn l 100%,
nc bay hi khng ng k) thu c dung dch c khi lng gim so vi ban u l 17,15 gam. Gi tr
ca a l
A. 0,4. B. 0,5. C. 0,2. D. 0,3.
Cu 48: t chy hon ton a mol hn hp 2 ester cng dy ng ng th thu c n
1
mol CO
2
v n
2
mol
H
2
O. Nu n
1
n
2
= a th l? Chn cu ng nht.
A. hai ester vng no n chc.
B. hai ester n chc cha no c 1 lin kt pi mch cacbon hay ester vng no n chc.
C. hai ester hai chc cha no.
D. hai ester no n chc,mch h.
Cu 49: Thi t t cho n ht V(lt) CO
2
vo 400 ml dung dch Ba(OH)
2
0,6M,thu c a gam kt ta v
dung dch X.Dn tip 0,7V(lt) CO
2
vo X , thu c thm 0,3a gam kt ta,(cc kh kc).Gi tr ca V?
A. 3,840 lt. B. 3,584 lt. C. 3,360 lt. D. 3,136 lt.
Cu 50: Dy no di y va tc dng c vi dung dch acid va tc dung vi dung dch kim?
A. AlCl
3
v Al
2
(SO
4
)
3
. B. Al(NO
3
)
3
v Al(OH)
3
.
C. Al(OH)
3
v Al
2
O
3
. D. Al
2
(SO
4
)
3
v Al
2
O
3
.
B/ Theo chng trnh Nng cao : t cu 51 n cu 60
Cu 51: t chy hon ton hn hp X gm hai amin n chc X
1
, X
2
(u bc1,cng s nguyn t cacbon
trong phn t. X
1
l amin no, mch h v phn t X
1
nhiu hn phn t X
2
hai nguyn t hydro) thu c 0,1
mol CO
2
. Mt khc, cho ton b lng X trn tc dng ht vi HNO
2
, sinh ra 0,05 mol N
2
. Khng nh no
sau y l sai?
A. X
2
phn ng vi HNO
2
cho sn phm hu c tham gia p trng bc.
B. Trong phn t X
2
c 7 lin kt o v 1 lin kt t.
C. Lc baz ca X
2
ln hn lc baz ca X
1
.
D. X
1
v X
2
u c hai nguyn t cacbon trong phn t.
Cu 52: Cu no pht biu i y khng ng?
A. Dung dch saccaroz trong mi trng acid ,un nng s tham gia phn ng trng gng.
B. Dung dch saccaroz tham gia phn ng vi Cu(OH)
2
nhit phng.
C. Saccaroz do 2 gc | - glucoz v | - fructoz lin kt vi nhau.
D. Saccaroz ch tn ti dng vng.
Cu 53: Phenyl axetat c iu ch trc tip t
A. axit axetic v phenol. B. anhirit axetic v phenol.
C. axit phenic v ancol metylic. D. ancol benzoic v axit axetic .
Cu 54: Cho hn hp X gm CH
2
=CHOCH
3
; CH
2
=CHCH
2
OH v CH
3
CH
2
CHO (s mol mi cht u bng
nhau) phn ng vi lng d dung dch AgNO
3
trong NH
3
, kt thc phn ng thu c 5,4 gam Ag. Mt
khc, nu cho ton b lng X trn tc dng ht vi dung dch KMnO
4
(d) th khi lng cht hu c sinh
ra l
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Trang 21
Cu 55: Axit salixylic (axit o-hiroxibenzoic) tc dng vi cht X c xc tc H
2
SO
4
to ra metyl salixylat
dng lm thuc xoa bp, cn tc dng vi cht Y to ra axit axetyl salixylat (aspirin) dng lm thuc cm.
Cc cht X v Y ln lt l:
A. C
2
H
5
OH+(CH
3
CO)
2
O B. CH
3
OH+CH
3
CH
2
OH C. CH
3
OH+CH
3
COOH D. CH
3
OH+(CH
3
CO)
2
O
Cu 56: Trong cc pht biu sau :
(1) Theo chiu tng dn in tch ht nhn, cc kim loi kim th (t Be n Ba) c nhit nng chy gim
dn.
(2) Kim loi Cs c dng ch to t bo quang in.
(3) Kim loi Mg c kiu mng tinh th lp phng tm din.
(4) Cc kim loi kim v mt s kim loi kim th tc dng mnh lit vi nc nhit thng.
(5) Kim loi Be khng tc dng vi nc d nhit cao.
Cc pht biu ng l?
A. (1), (2), (5). B. (2), (3), (4). C. (2), (3), (5). D. (2), (4), (5)
Cu 57: Nhn xt no sau y khng ng?
A. in cc ca pin in ha tri du vi in cc ca bnh in phn
B. in phn dung dch CuSO
4
vi anot bng ng th nng Cu
2+
khng i
C. Cc electron di chuyn c hng trong cu mui
D. o th in cc chun ca kim loi, in cc chun hiro lun t bn tri vn k
Cu 58: Kh m gam Fe
2
O
3
bng CO mt thi gian thu c cht rn X.Ha tan ht X trong dung dch HNO
3

d thu c 0,224 lt NO(sn phm kh duy nht kc).C cn dung dch sau phn ng thu c 18,15 gam
mui khan. Hiu sut phn ng kh Oxid st bng ?
A. 13,33%. B. 25,00%. C. 33,33%. D. 26,67%.
Cu 59: X l dung dch hn hp cha CH
2
(COOH)
2
c nng mol aM v CH
2
=CHCOOH c
nng mol bM. Trung ha 100 ml dung dch X cn 250 ml dung dch NaOH 1M. Mt khc, 75 ml dung
dch X lm mt mu va ht dung dch cha 18 gam Br
2
. Gi tr ca a v b ln lt l?
A. 1M v 1M B. 0,5M v 1,5M C. 1M v 1,5M D. 0,5M v 1M
Cu 60: Cho cc th in cc chun : E
0
(Fe
2+
/Fe) = - 0,44V ; E
0
(Pb
2+
/Pb) = - 0,13V ; E
0
(Ni
2+
/Ni) = -
0,26V ; E
0
(Sn
2+
/Sn) = - 0,14V . Trong cc Pin sau y pin no c sut in ng chun ln nht?
A. Pin Ni-Sn. B. Pin Ni-Pb. C. Pin Fe-Pb. D. Pin Fe-Ni.
---------------------------------------------- HT ----------------------------------------

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Trang 22
S GIO DC V O TO NGH AN
TRNG THPT QUNH LU 1

KIM TRA CHT LNG N THI I HC LN 1
MN HA HC
Thi gian lm bi: 90 pht 50 cu trc nghim

M thi 135
H v tn: .Lp
Cu 1: t chy hon ton 0,3 mol hn hp X gm 2 hidrocacbon mch h c s mol bng nhau thu c 0,75 mol CO
2
v
0,9 mol H
2
O. S cp cht tha mn X l?
A. 3 B. 5 C. 6 D. 4
Cu 2: Nung mt hn hp X gm SO
2
v O
2
c t khi so vi O
2
l 1,6 vi xc tc V
2
O
5
thu c hn hp Y . Bit t
khi ca X so vi Y l 0,8. Hiu sut ca phn ng tng hp SO
3
l
A. 50% B. 80% C. 66,7% D. 75%
Cu 3: Hp cht thm X c CTPT C
8
H
10
O
2
. X tc dng vi NaOH v Na u theo t l 1:1. Xc nh s ng phn X
tha mn?
A. 10 B. 3 C. 13 D. 15
Cu 4: in phn 200 ml dung dch cha NaCl 0,5M; Fe(NO
3
)
3
0,3M v Cu(NO
3
)
2
0,3M bng in cc tr c mng ngn xp
n khi khi lng dung dch gim 5,63 gam th dng li. Dung dch sau in phn c cha
A. NaNO
3
, Cu(NO
3
)
2
v HNO
3
. B. NaNO
3
v NaCl.
C. NaNO
3
, Fe(NO
3
)
2
, Cu(NO
3
)
2
v HNO
3
. D. NaNO
3
v NaOH.
Cu 5: Th nghim no sau y khi tin hnh xong thu c dung dch c PH < 7?
A. Cho 50 ml dd H
2
SO
4
1M phn ng vi 100 ml dd Ba(OH)
2
0,5M
B. Cho 50 ml dd KHSO
4
2M phn ng vi 100 ml dd NH
3
1M
C. Cho 50 ml dd KHSO
4
2M phn ng vi 100 ml dd KOH 1M
D. Cho 50 ml dd H
2
SO
4
1M phn ng vi 150 ml dd Na
2
CO
3
1M
Cu 6: Cho ln lt cc cht : FeCl
2
, FeSO
4
, Na
2
SO
3
, MgSO
4
, FeS, KI ln lt vo H
2
SO
4
c, un nng. S trng
hp c xy ra phn ng oxi ho - kh l
A. 4 B. 5 C. 6 D. 3
Cu 7: Cho dung dch Ba(HCO
3
)
2
ln lt vo cc dung dch: CaCl
2
, Ca(NO
3
)
2
, NaOH, Na
2
CO
3
, KHSO
4
, Na
2
SO
4
,
Ca(OH)
2
, H
2
SO
4
, HCl. S trng hp ng thi to ra kt ta v c kh bay ra l
A. 5. B. 2. C. 6. D. 3.
Cu 8: X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m (gam) hn hp cha X v Y c t l
s mol ca X v Y tng ng l 1:3 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn
cn thn dung dch T thu c 23,745 gam cht rn khan. Gi tr ca m l
A. 17,025. B. 68,1. C. 19,455. D. 78,4
Cu 9: Cho hp cht hu c A c cng thc phn t C
5
H
8
O
2
tc dng vi NaOH, sau phn ng thu c mt mui ca
axit hu c B v mt hp cht hu c D khng phn ng vi Na. S ng phn A tho mn iu kin trn l
A. 6. B. 8. C. 10 D. 7.
Cu 10: Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng
NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X
tho mn cc tnh cht trn l
A. 2. B. 4. C. 5. D. 6.
Cu 11: Cho 7,36 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H
2
SO
4
20% thu c 4,48 lt
kh H
2
( ktc). Khi lng dung dch thu c sau phn ng l
Cu 12: Nguyn t R to c cation R
+
. Cu hnh electron phn lp ngoi cng ca R
+
( trng thi c bn) l 3p
6
.
Tng s ht mang in trong R
+
l
A. 19. B. 38 C. 37. D. 18.
Cu 13: Cho 2-metylpropan-1,2-diol tc dng vi CuO un nng th thu c cht c CTPT no sau y?
A. C
4
H
8
O
2
B. C
4
H
8
O
3
C. C
4
H
6
O
3
D. C
4
H
6
O
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Trang 23
Cu 14: Hn hp X gm 0,03 mol Fe v 0,12/n mol kim loi R (ha tr n khng i, khng tan trong nc v ng
trc hiro trong dy in ho). Cho X vo dung dch AgNO
3
d. Khi lng Ag thu c l
Cu 15: Cho mt ipeptit Y c cng thc phn t C
6
H
12
N
2
O
3
. S ng phn peptit ca Y mch h l
A. 5. B. 7. C. 6. D. 4.
Cu 16: Hp cht X cha vng benzen, c cng thc phn t C
x
H
y
N. Khi cho X tc dng vi dung dch HCl thu c
mui Y c cng thc dng RNH
3
Cl (R l gc hirocacbon). Phn trm khi lng ca nit trong X l 13,084%. S
ng phn cu to ca X tha mn cc iu kin trn l
A. 6. B. 5. C. 3. D. 4.
Cu 17: Xt cn bng ho hc ca mt s phn ng
1) Fe
2
O
3
(r) + 3CO(k)
2Fe(r) + 3CO
2
(k) 2) CaO(r) + CO
2
(k)
CaCO
3
(r)
3) N
2
O
4
(k)
2NO
2
(k) 4)H
2
(k) + I
2
(k)
2HI(k)
5) 2SO
2
(k) + O
2
(k)
2SO
3
(k)
Khi tng p sut, cn bng ho hc khng b dch chuyn cc h
A. 1, 2, 4, 5. B. 1, 4. C. 1, 2, 4. D. 2, 3, 5.
Cu 18: Hp cht X c cng thc phn t l C
5
H
8
O
2
. Cho 10 gam X tc dng hon ton, va vi dung dch NaOH
thu c dung dch Y. Ly ton b dung dch Y tc dng hon ton vi dung dch AgNO
3
trong NH
3
un nng thu
c 43,2 gam Ag. S ng phn cu to ca X tha mn cc iu kin trn l
A. 2. B. 1. C. 3 D. 4.
Cu 19: C dung dch X gm (KI v t h tinh bt). Cho ln lt tng cht sau: O
3
, Cl
2
, H
2
S, FeCl
3
, KClO
4
tc dng
vi dung dch X. S cht lm dung dch X chuyn sang mu xanh l:
A. 4 cht B. 2 cht C. 1 cht D. 3 cht
Cu 20: Dung dch X c pH ~5 gm cc ion NH
4
+
, Na
+
, Ba
2+
v 1 anion Y. Y c th l anion no sau y?
A. NO
3
-
B. CH
3
COO
-
C. SO
4
2-
D. CO
3
2-

Cu 21: C bao nhiu ng phn cu to, mch h c cng thc phn t C
5
H
8
tc dng vi H
2
d (xc tc thch hp)
thu c sn phm isopentan?
A. 3. B. 1. C. 2. D. 4.
Cu 22: un nng hn hp X tt cc cc ancol no, h, n chc c khng qu 3 nguyn t C trong phn t vi H
2
SO
4
c
140
o
C th c hn hp Y (gi s ch xy ra phn ng to ete). S cht ti a trong Y l?
A. 14 B. 10 C. 11 D. 15
Cu 23: Khi tin hnh ng trng ngng axit e -amino hexanoic v axit e -amino heptanoic c mt loi t poli
amit X. Ly 48,7 gam t X em t chy hon ton vi O
2
va th thu c hn hp Y. Cho Y qua dung dch
NaOH d th cn li 4,48 lt kh (ktc). Tnh t l s mt xch ca mi loi trong A
A. 4:5 B. 3:5 C. 4:3 D. 2:1
Cu 24: X l hp cht bn mch h, c cng thc phn t l C
4
H
8
O. X tc dng vi H
2
d (xt Ni, t
0
) thu c butan-
1ol. S ng phn X tha mn l?
A. 3 B. 5 C. 4 D. 6
Cu 25: xi ha 4,8 gam ancol X n chc, bc 1 thnh axit tng ng bng O
2
, ly ton b hn hp sau phn ng
(hn hp Y) cho tc dng vi Na d th thu c 2,8 lt kh (ktc). Hn hp Y tc dng va vi 100ml dung dch
NaOH xM. Gi tr ca x l?
A. 1 M B. 0,5 M C. 1,25 M D. 2,5 M
Cu 26: Nhit phn hon ton hn hp gm m
1
gam Fe(NO
3
)
2
v m
2
gam Al(NO
3
)
3
thu c hn hp kh X Trn hn
hp kh X vi 112 ml kh O
2
(ddktc) c hn hp kh Y. Hp th hon ton hn hp kh Y vo 3,5 lt H
2
O (khng
thy c kh thot ra) c dung dch c pH = 1,7. Gi tr m
1
v m
2
ln lt l
A. 4,5 v 6,39 B. 2,700 v 3,195 C. 3,60 v 2,130 D. 1,80 v 0,260
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Trang 24
Cu 27: Cho 0,1 mol -amino axit X tc dng va vi 50 ml dung dch HCl 2M. Trong mt th nghim khc, cho
26,7 gam X vo dung dch HCl d, sau c cn cn thn dung dch thu c 37,65 gam mui khan. Vy X l:
A. Glyxin. B. Valin. C. Axit glutamic. D. Alanin.
Cu 28: Cho cc cht: AgNO
3
, Cu(NO
3
)
2
, MgCO
3
, Ba(HCO
3
)
2
, NH
4
HCO
3
, NH
4
NO
3
v Fe(NO
3
)
2
. Nu nung cc cht
trn n khi lng khng i trong cc bnh kn khng c khng kh, ri cho nc vo cc bnh, s bnh c th to li
cht ban u sau cc th nghim l
A. 6 B. 5 C. 3 D. 4
Cu 29: im ging nhau ca glucoz v saccaroz l
A. u phn ng vi H
2
c xc tc Ni nung nng cng thu c mt ancol a chc.
B. u phn ng vi dung dch AgNO
3
trong NH
3
to Ag.
C. u b thu phn trong dung dch axit.
D. u phn ng vi Cu(OH)
2
to dung dch mu xanh lam.
Cu 30: C 6 dung dch mt nhn, khng mu: Na
2
CO
3
; Ba(HCO
3
)
2
; NaBr; BaBr
2
; MgCl
2
; CH
3
COOK. Nu ch dng
thm H
2
SO
4
c th nhn bit c my cht:
A. 3 B. 6. C. 2 D. 4
Cu 31: Cho hn hp X gm x mol NaOH v y mol Ba(OH)
2
t t vo dung dch cha z mol AlCl
3
thy kt ta xut
hin, kt ta tng dn v tan i mt phn. Lc thu c m gam kt ta. Gi tr ca m l :
A. 78(2z - x - 2y) B. 78(4z - x - y) C. 78(4z - x - 2y) D. 78(2z - x - y)
Cu 32: Cho cc cht: andehit acrylic, axit fomic, phenol, poli etilen, stiren, toludin, vinyl axetilen. S cht c kh nng
tham gia phn ng cng vi dung dch nc brom l?
A. 6 B. 3 C. 4 D. 5
Cu 33: Vt lm bng hp kim Zn-Cu trong mi trng khng kh m (hi nc c ho tan O
2
) xy ra qu trnh n
mn in ho. Ti anot xy ra qu trnh
A. Kh O
2
B. Kh Zn C. xi ho Cu D. xi ho Zn
Cu 34: Khi cho 13,8 gam glixerol (X) tc dng vi axit fomic th thu c hp cht hu c (Y) c khi lng bng 1,18 ln khi
lng cht (X) ban u. Bit hiu sut ca phn ng l 73,35 %. Vy tng s nguyn t c trong (Y) l:
A. 20 B. 14 C. 16 D. 18
Cu 35: Cho 5,12 gam ng phn ng hon ton vi 50,4 gam dung dch HNO
3
60% thu c dung dch X. Hy xc
nh nng % ca mui tan trong X bit rng nu thm 210ml dung dch KOH 2M vo X ri c cn v nung sn
phm thu c ti khi lng khng i th c 20,76 gam cht rn.
A. 26,15% B. 17,67% C. 28,66% D. 75,12%
Cu 36: Chia 18,2 gam hn hp 2 ancol no mch h thnh 2 phn bng nhau.
- Phn 1 phn ng vi Na d c V lt H
2
(ktc).
- Phn 2 t chy hon ton ri dn sn phm chy vo dung dch nc vi trong d thy xut hin 37,5gam kt ta,
ng thi khi lng dung dch gm 12 gam so vi ban u . Gi tr ca V
A. 2,8 B. 5,04 C. 5,6 D. 2,52
Cu 37: Hn hp X gm MgO, CaO, Mg v Ca. Ha tan 10,72 gam X vo dung dch HCl va thu c 3,248 lit
kh (ktc) v dung dch Y trong c 12,35 gam MgCl
2
v x gam CaCl
2
. Gi tr x l
A. 15,54 B. 16,98 C. 21,78 D. 31,08
Cu 38: t chy hon ton mt anehit X mch h, n chc, c mt lin kt i trong gc hidrocacbon thu c tng s
mol CO
2
v H
2
O gp 1,4 ln s mol O
2
phn ng. S cht X tha mn bi l
A. 1 B. 3 C. 2 D. 4
Cu 39: ho tan ht mt mu Al trong dung dch axt HCl 30
o
C cn 20 pht. Cng mu Al tan ht trong dung
dch axt ni trn 50
o
C trong 5 pht. ho tan ht mu Al trong dung dch ni trn 80
o
C th cn thi gian l:
A. 187,5 s. B. 37,5 s. C. 30 s. D. 44,6 s.
Cu 40: Pht biu no sau y sai ?
A. Ha tan Al
2
(SO
4
)
3
khan vo nc lm dung dch nng ln do b hirat ha
B. C cht lng khi pha long (thm nc) th nng tng.
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Trang 25
C. Cc kim loi Na, K , Ba c mng tinh th lp phng tm khi.
D. Tt c cc m chy u dp tt bng CO
2

Cu 41: t chy hon ton mt este no 2 chc mch h X. Sc ton b sn phm chy vo dung dch Ca(OH)
2
d,
sau phn ng thu c 25 gam kt ta v khi lng dung dch gim 10,4 gam. Bit khi x phng ho X ch thu c
mui ca axit cacboxylic v ancol. S ng phn ca X l:
A. 5. B. 6. C. 3. D. 4.
Cu 42: Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng
NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X
tho mn cc tnh cht trn l
A. 6. B. 4. C. 5. D. 2.
Cu 43: Cho m gam Fe vo dung dch cha ng thi H
2
SO
4
v HNO
3
thu c dung dch X v 4,48 lt NO, Thm
tip H
2
SO
4
vo X th li thu c thm 1,792 lt kh NO na v dung dch Y (Kh NO l sn phm kh duy nht).
Dung dch Y ho tan va ht 8,32 gam Cu khng c kh bay ra (cc kh o ktc). Gi tr ca m l:
A. 11,2 B. 9,6 g. C. 16,8 D. 16,24
Cu 44: Cho 4,8 (g) Br
2
nguyn cht vo dung dch cha 12,7 (g) FeCl
2
thu c dung dch X. Cho dung dch
AgNO
3
d vo X thu c a(g) kt ta . Gi tr a l
A. 39,98(g) B. 55,58(g) C. 44,3(g) D. 28,5 (g)
Cu 45: Cho hn hp A gm 0,15 mol Mg, 0,35 mol Fe phn ng vi V lt HNO
3
2M, thu c hn hp X gm 0,05
mol N
2
O, 0,1 mol NO v cn li 2,8 gam kim loi. Gi tr ca V lt l:
A. 0,45 B. 0,55 C. 0,575 D. 0,61
Cu 46: Bn kim loi Na; Al; Fe v Cu c n nh khng theo th t X, Y, Z, T bit rng:
- X; Y c iu ch bng phng php in phn nng chy
- X y c kim loi T ra khi dung dch mui
- Z tc dng c vi dung dch H
2
SO
4
c nng nhng khng tc dng c vi dung dch H
2
SO
4
c ngui.
X, Y, Z, T theo th t l:
A. Al; Na; Cu; Fe B. Na; Fe; Al; Cu C. Na; Al; Fe; Cu D. Al; Na; Fe; Cu
Cu 47: C cc nhn nh
(1). S
2-
< Cl
-
< Ar < K
+
l dy c sp xp theo chiu tng dn bn knh nguyn t.
(2). C 3 nguyn t m nguyn t ca n trng thi c bn c cu trc electron lp v ngoi cng l 4s
1
.
(3). Cacbon c hai ng v, Oxi c 3 ng v. S phn t CO
2
c to ra t cc ng v trn l 12.
(4). Cho cc nguyn t: O, S, Cl, N, Al. Khi trng thi c bn: tng s electron c thn ca chng l: 11
(5). Cc nguyn t: F, O, S, Cl u l nhng nguyn t p.
(6). Nguyn t X to c hp cht kh vi hidro c dng HX. Vy X to c oxit cao X
2
O
7
.
S nhn nh khng chnh xc l?
A. 5 B. 4 C. 2 D. 3
Cu 48: Trong s cc loi t sau: t lapsan, t nitron, t visco, t nilon-6,6, t axetat, t capron, t nilon-7. C bao
nhiu loi t thuc loi t nhn to ?
A. 2. B. 1. C. 4. D. 3.
Cu 49: Thm t t tng git 100 ml dung dch cha Na
2
CO
3
1,2M v NaHCO
3
0,6 M vo 200 ml dung dch HCl 1M.
Sau khi phn ng hon ton thu c dung dch X. Cho dung dch BaCl
2
n d vo X thu c m gam kt ta. Gi tr
m bng:
A. 9,85 B. 11,82 C. 23,64 D. 7,88
Cu 50: Cho cc cht sau: phenol, kh sunfur, toluen, ancol benzylic, isopren, axit metacrylic, vinyl axetat, phenyl
amin, axit benzoic. S cht phn ng c vi dung dch nc brom nhit thng l
A. 6. B. 5. C. 4. D. 3.
----------- HT ----------

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Trang 26
TRNG THPT NINH GIANG

THI TH I HC CAO NG LN I
MN HA HC
NM HC 2013 - 2014
Thi gian lm bi:90 pht khng tnh thi gian pht

M thi 647
H, tn th sinh:..........................................................................

Cu 1: Hn hp X gm K v Al. Cho m (g) X tc dng vi H
2
O d thu c 0,4 mol H
2
. Cho m (g) X tc dng vi
dung dch KOH d thu c 0,475 mol H
2
. Xc nh gi tr ca m?
A. 15,55 B. 14,55 C. 15,45 D. 14,45
Cu 2: Dung dch H
2
S lu trong khng kh s c hin tng:
A. Vn c mu en B. Vn c mu vng C. Chy D. Khng c hin tng g
Cu 3: T NH
2
(CH
2
)
6
NH
2
v mt cht hu c X c th iu ch t Nilon-6,6. CTCT ca X l:
A. CHO(CH
2
)
4
CHO B. HOOC(CH
2
)
6
COOH C. HOOC(CH
2
)
4
COOH D. HOOC(CH
2
)
5
COOH
Cu 4: Dung dch X cha NaOH 1M v Ba(OH)
2
0,02M. Hp th 0,5 mol kh CO
2
vo 500 ml dung dch X. Hi thu
c bao nhiu gam kt ta?
A. 39,4 B. 19,7 C. 1,97 D. 3.94
Cu 5: C 4 cht: Axit axetic, Glixerol, ancol Etylic, Glucoz. Ch dng thm cht no sau y nhn bit?
A. Cu(OH)
2
/OH
-
B. Qu tm C. CaCO
3
D. CuO
Cu 6: Cho 5,6 gam Fe v 6,4 gam Cu vo mt cc ng dung dch H
2
SO
4
long, rt d. Sau khi H
2
bay ra ht, tip tc
thm NaNO
3
d vo cc. S mol kh NO (sn phm kh duy nht) ti a c th bay ra l:
A. 0,1/3 B. 0,4/3 C. 0,2/3 D. 0.1
Cu 7: Trong phng th nghim, ngi ta thng iu ch Clo bng cch
A. Cho dung dch HCl c tc dng vi MnO
2
, un nng. B. in phn nng chy NaCl.
C. Cho F
2
y Cl
2
ra khi dung dch NaCl. D. in phn dung dch NaCl c mng ngn.
Cu 8: Cho 50ml dung dch FeCl
2
1M vo dung dch AgNO
3
d, khi lng kt ta thu c sau phn ng l bao
nhiu gam. (Cho bit cp oxi ho - kh Fe
3+
/Fe
2+
ng trc Ag
+
/Ag).
Cu 9: Cp ancol no sau y khi un vi H
2
SO
4
c, 170
0
C ch to ra 1 Anken duy nht v khng c sn phm hu
c khc?
A. CH
3
OH v C
2
H
5
OH B. CH
3
-CH(CH
3
)-CH
2
-OH v (CH
3
)
3
-C-CH
2
-OH
C. CH
3
-CH
2
CH
2
- CH
2
-OH v CH
3
-C(CH
3
)
2
-OH D. CH
3
-CH
2
-CH
2
-OH v CH
3
-CH(OH)-CH
3

Cu 10: Pht biu no sau y khng ng?
A. Phn chua c cng thc K
2
SO
4
.Al
2
(SO
4
)
3
.24H
2
O
B. Phn m cung cp Nit ho hp cho cy di dng ion nitrat v ion amoni
C. Supephotphat n cha hm lng P
2
O
5
cao hn Supephotphat kp v thnh phn ca n ch cha Ca(H
2
PO
4
)
2

D. Phn ur c cng thc l (NH
2
)
2
CO
Cu 11: Nguyn t ca nguyn t X to c oxit cao nht l R
2
O
5
. Phn trm khi lng ca R trong hp cht vi
Hiro l 82,353%. Nguyn t R l:
A. P B. N C. S D. Cl
Cu 12: Cho mt ming Fe vo cc ng H
2
SO
4
long. Bt kh H
2
s bay ra nhanh hn khi thm vo cc trn dung
dch no trong cc dung dch sau:
A. HgSO
4
B. Na
2
SO
4
C. Al
2
(SO
4
)
3
D. MgSO
4

Cu 13: Cho dung dch HCl c pH=3. Hi phi pha thm th tch H
2
O bao nhiu ln so vi th tch dung dch ban u
c c dung dch HCl c pH=5?
A. 999 B. 100 C. 1000 D. 99
Cu 14: C mt loi oxit st dng luyn gang. Nu kh oxit st ny bng Cacbon oxit nhit cao, ngi ta thu
c 0,84 gam St v 0,448 lt kh CO
2
(ktc). Cng thc ho hc ca loi oxit st ni trn l:
A. Fe
3
O
4
B. Fe
2
O
4
C. FeO D. Fe
2
O
3

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Cu 15: Trong cc cht sau: Anehit axetic, anlyl clorua, ng Glucoz, Metyl axetat, ng Saccaroz, tinh bt. S
cht tham gia phn ng thu phn l:
A. 2 B. 4 C. 5 D. 3
Cu 16: Nhng kim loi no sau y c th c iu ch theo phng php nhit luyn (bng cht kh CO) t oxit
kim loi tng ng l:
A. Fe, Ni B. Al, Cu C. Ca, Cu D. Mg, Fe
Cu 17: t chy hon ton m gam hn hp X gm 2 Anehit no n chc mch h thu c 0,4 mol CO
2
. Mt khc,
hiro ho hon ton cng lng hn hp X trn cn 0,2 mol H
2
v thu c hn hp 2 ancol. t chy hon ton hn
hp 2 ancol trn th thu c s mol H
2
O

l:
A. 0,6 B. 0,8 C. 0,4 D. 0,2
Cu 18: Yu t no sau y khng nh hng n cn bng phn ng ny :
CO
2
(k) + H
2
(k) CO (k) + H
2
O (k) ; H > 0
A. p sut B. Nng sn phm C. Nng cc cht D. Nhit
Cu 19: Cho hn hp X gm hai Ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton hn hp X,
thu c 13,2 gam CO
2
v 7,2 gam H
2
O. Hai Ancol l:
A. C
2
H
5
OH v C
4
H
9
OH B. C
2
H
4
(OH)
2
v C
3
H
6
(OH)
2

C. C
3
H
5
(OH)
3
v C
4
H
7
(OH)
3
D. C
2
H
4
(OH)
2
v C
4
H
8
(OH)
2

Cu 20: Este X c CTPT C
7
H
12
O
4
, khi cho 16 gam X tc dng va vi 200 gam dung dch NaOH c nng 4%
th thu c mt ancol Y v 17,8 gam hn hp 2 mui. CTCT thu gn ca X l cng thc no di y?
A. C
2
H
5
COOCH
2
CH
2
CH
2
OOCH B. CH
3
COOCH
2
CH
2
CH
2
OOCCH
3

C. HCOOCH
2
CH
2
CH
2
CH
2
OOCCH
3
D. CH
3
COOCH
2
CH
2
OOCC
2
H
5

Cu 21: Cho Glucoz ln men thnh Ancol etylic. Ton b kh CO
2
sinh ra trong qu trnh ny c hp th ht vo
dung dch Ca(OH)
2
d to ra 50 gam kt ta, bit hiu sut qu trnh ln men t 80%. Vy khi lng Glucoz cn
dng l
A. 56,25 gam B. 20 gam C. 33,7 gam D. 90 gam
Cu 22: Cho lung kh CO i qua ng s ng m gam Fe
2
O
3
nhit cao mt thi gian, ngi ta thu c 6,72 gam
hn hp gm 4 cht rn khc nhau. em ho tan hon ton hn hp rn ny vo dung dch HNO
3
d to thnh 0,448 lt
kh NO (ktc). Gi tr m l:
A. 8,2 B. 8 C. 7,2 D. 6,8
Cu 23: Dung dch X cha 0,1 mol NaCl v 0,15 mol NaF. Cho dung dch X tc dng vi dung dch AgNO
3
d. Kt
ta sinh ra c khi lng l:
Cu 24: S ng phn ca amin ng vi CTPT C
3
H
9
N l:
A. 3 B. 2 C. 4 D. 1
Cu 25: Cation R
2+
c cu hnh electron phn lp ngoi cng l 2p
6
. Cu hnh electron ca nguyn t R l
A. 1s
2
2s
2
2p
4
B. 1s
2
2s
2
2p
5
C. 1s
2
2s
2
2p
6
3s
2
D. 1s
2
2s
2
2p
6
3s
1

Cu 26: X phng ho 26,4 gam hn hp 2 Este CH
3
COOC
2
H
5
v HCOOC
3
H
7
bng dung dch NaOH va . S gam
NaOH tham gia phn ng l:
A. 15 B. 12 C. 8 D. 18
Cu 27: Ch dng nc, c th phn bit cc cht trong cc dy sau:
A. Na, Al, Zn, Mg B. Na, Mg, Al, Al
2
O
3
C. Na, Zn, ZnO, Al
2
O
3
D. Ba, Al, Fe, Mg
Cu 28: Cho Mg vo dung dch cha FeSO
4
v CuSO
4
. Sau phn ng thu c cht rn X ch c 1 kim loi v dung
dch Y cha 2 mui. Phn ng kt thc khi no?
A. CuSO
4
v FeSO
4
ht, Mg d B. FeSO
4
d, CuSO
4
cha phn ng, Mg ht.
C. CuSO
4
ht, FeSO
4
cha tham gia phn ng, Mg ht. D. CuSO
4
d, FeSO
4
cha phn ng, Mg ht.
Cu 29: t chy hon ton mt Hirocacbon X thu c 0,11 mol CO
2
v 0,132 mol H
2
O. Khi X tc dng vi kh
Clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l:
A. 2-Metylpropan B. 2,2-imetylpropan C. 2-Metylbutan D. Etan
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Trang 28
Cu 30: Trong s cc Este mch h C
4
H
6
O
2
:
HCOO-CH=CH-CH
3
(1) HCOO-CH
2
-CH=CH
2
(2) HCOO-C(CH
3
)=CH
2
(3)
CH
3
COO-CH=CH
2
(4) CH
2
=CH-COO-CH
3
(5)
Cc Este c th iu ch trc tip t Axit v ancol l:
A. (2) v (4) B. (2) v (5) C. (1) v (3) D. (3) v (4)
Cu 31: Hn hp X gm 0,02 mol C
2
H
2
v 0,03 mol H
2
vo bnh kn c Ni l xc tc. Nung bnh mt thi gian c
hn hp Y. Cho Y li qua dung dch Br
2
d thy bnh Br
2
tng m gam v c 448 ml kh Z bay ra (ktc). Bit d
Z/H2
=
4,5. Gi tr ca m l:
A. 4 gam B. 0,62g C. 0,58g D. 0,4g
Cu 32: So snh nhit si ca cc cht sau: Ancol etylic (1), Etyl clorua (2), ietyl ete (3) v Axit axetic (4).
A. (4) > (3) > (2) > (1 ) B. (1 ) > (2) > (3) > (4) C. (1) > (2) > (3) > (4) D. (4) > (1) > (3) > (2)
Cu 33: in phn 100ml dung dch CuSO
4
0,2M vi cng dng in I=9,65A. Tnh khi lng Cu bm vo catt
sau khong thi gian in phn l t
1
=200 giy v t
2
=500 giy (gi thit hiu sut phn ng in phn l 100%, ton b
kim loi sinh ra u bm vo catot).
A. 0,64 gam v 1,6 gam B. 0,32 gam v 0,64 gam C. 0,32 gam v 1,28 gam D. 0,64 gam v 1,28 gam
Cu 34: Cho 14 gam hn hp gm Etanol v Phenol tc dng va vi 100 ml dung dch NaOH 1M . Thnh phn %
khi lng ca mi cht c trong hn hp ban u l
A. 32, 86 % v 67,14 % B. 33 % v 67 % C. 61,8 % v 38,2 % D. 32,9% v 67,1%
Cu 35: Dn kh NH
3
vo dung dch cha CuSO
4
v Al
2
(SO
4
)
3
n d th:
A. Xut hin kt ta trng v kt ta xanh lam, sau kt ta xanh lam tan
B. Xut hin kt ta trng v kt ta xanh lam sau kt ta trng tan
C. Xut hin kt ta trng v kt ta xanh lam
D. Xut hin kt ta trng
Cu 36: Dy no sau y c sp xp theo trt t s oxi ho ca Oxi tng dn?
A. F
2
O H
2
O O
3
H
2
O
2
B. H
2
O H
2
O
2
O
3
F
2
O
C. F
2
O O
3
H
2
O
2
H
2
O D. H
2
O
2
H
2
O O
3
F
2
O
Cu 37: t chy hon ton 17,6 gam mt Axit cacboxylic no n chc X c sn phm chy l CO
2
v H
2
O. Cho
ton b sn phm chy vo bnh ng dung dch Ca(OH)
2
d thy to c 80 gam kt ta v khi lng dung dch
trong bnh gim so vi khi lng dung dch Ca(OH)
2
ban u l 30,4 gam. Xc nh s ng phn cu to ca X?
A. 1 B. 4 C. 3 D. 2
Cu 38: Trn 0,54 gam bt Al vi hn hp bt Fe
2
O
3
v CuO ri tin hnh phn ng nhit nhm nhit cao trong
iu kin khng c khng kh thu c hn hp rn X. Ho tan X trong dung dch HNO
3
thu c 0,896 lt (ktc) hn
hp kh Y gm NO
2
v NO. T khi ca X so vi H
2
l:
A. 20 B. 22 C. 23 D. 21
Cu 39: Cht lm i mu c giy qu m l:
A. Phenol B. Anilin C. imetyl amin D. Glyxin
Cu 40: Rt t t 250 ml dung dch CH
3
COOH 1M vo 200 ml dung dch K
2
CO
3
1M sau khi phn ng hon ton thu
c V lt kh ktc. V c gi tr?
A. 1,008 B. 1,12 C. 0,896 D. 1,344
Cu 41: t chy hon ton 0,02 mol hi 1 Axit no, n chc, mch h trong 0,1 mol O
2
, thu c hn hp kh v hi
X. Cho X qua H
2
SO
4
c, thy cn 0,09 mol kh khng b hp th. Axit c cng thc l:
A. HCOOH B. CH
3
COOH C. C
3
H
7
COOH D. C
2
H
5
COOH
Cu 42: Hn hp X gm hai kim loi kim c cng s mol. Ho tan 2,3 gam X trong 50 gam nc thu c 52,2 gam
dung dch. Hai kim loi kim l:
A. Li v Rb B. Na v K C. Li v K D. Li v Na
Cu 43: X l mt o-aminoaxit cha mt nhm NH
2
v mt nhm COOH. Cho 8,9 gam X tc dng vi HCl d thu
c 12,55 gam mui. Cng thc cu to ca A l:
A. H
2
NCH
2
CH
2
COOH B. CH
3
CH
2
CH(NH
2
)COOH
C. CH
3
CH(NH
2
)COOH D. CH
3
CH(NH
2
)CH
2
COOH
Cu 44: Cho H
2
SO
4
trung ho 6,84 gam mt Amin n chc X thu c 12,72 gam mui. Cng thc ca Amin X l:
A. C
2
H
5
NH
2
B. C
3
H
7
NH
2
C. C
3
H
5
NH
2
D. CH
3
NH
2

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Cu 45: Hp cht hu c X tc dng c vi dung dch NaOH, dung dch NaHCO
3
v lm mt mu dung dch Brom.
Tn gi ca X l:
A. Metyl metacrylat B. Phenol C. Axit metacrylic D. Axit axetic
Cu 46: Cho phng trnh ho hc: Fe
x
O
y
+ HNO
3
Fe(NO
3
)
3
+ NO
2
+ H
2
O. Sau khi cn bng phng trnh ho hc
trn vi h s ca cc cht l nhng s nguyn ti gin th h s ca HNO
3
l:
A. 3x+2y B. 6x+2y C. 3x-2y D. 6x-2y
Cu 47: Crackinh V (lt) Butan vi hiu sut 75% c hn hp X l 5 Hirocacbon. t chy hon ton X, cn va
2,6 mol O
2
. V (lt) Butan ktc c gi tr l:
A. 11,2 B. 8,96 C. 5,6 D. 6,72
Cu 48: Nitro ho Benzen thu c 2 cht X, Y hn km nhau 1 nhm NO
2
. t chy hon ton 19,4 gam hn hp
X, Y thu c CO
2
, H
2
O v 2,24 lt N
2
(ktc). CTCT ng ca X, Y l:
A. C
6
H
5
NO
2
v C
6
H
4
(NO
2
)
2
B. C
6
H
5
NO
2
v C
6
H
3
(NO
2
)
3

C. C
6
H
3
(NO
2
)
3
v C
6
H
2
(NO
2
)
4
D. C
6
H
4
(NO
2
)
2
v

C
6
H
3
(NO
2
)
3

Cu 49: Cho m gam Fe tc dng vi dung dch HNO
3
thy sinh ra 0,1 mol NO l sn phm kh duy nht ca HNO
3
v
cn li 1,6 gam Fe khng tan. Gi tr ca m l:
A. 5,6 B. 7,2 C. 8,4 D. 10
Cu 50: Dy m tt c cc cht u thc hin c phn ng vi AgNO
3
trong NH
3
l:
A. Axetilen, Anehit axetic, Saccaroz B. Etanol, Glucoz, Metyl fomiat
C. Axetilen, glucoz, Axit focmic D. Metanol, Phenol, Glucoz

-----------------------------------------------
----------- HT ----------

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Trang 30
S GD&T HI DNG
TRNG THPT ON THNG

THI TH I HC LN 1
NM HC 2013-2014
Mn: HA HC
Thi gian lm bi: 90 pht;
H, tn th sinh:................................................................. SBD: .............................

M thi 150
Cho bit nguyn t khi ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; P = 31; Li = 7; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca= 40
Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108.

Cu 1: Mui X c cc tnh cht sau:
-X tc dng vi dung dch HCl to ra kh Y, kh Y lm c nc vi trong, khng lm mt mu dung dch brom
-X tc dng vi Ba(OH)
2
c th to 2 mui.
Chn cng thc ph hp ca X
A. NaHCO
3
B. Na
2
SO
3
C. Na
2
CO
3
D. Na
2
S
Cu 2: S cht n chc ng vi cng thc C
3
H
6
O
2
l
A. 2. B. 1. C. 4. D. 3.
Cu 3: Hp cht hu c X c cng thc phn t l C
7
H
8
O. S ng phn cha vng benzen ca X tc dng c vi
Na v NaOH l:
A. 2 B. 3 C. 4 D. 5
Cu 4: Cho cc phn ng sau trong iu kin thch hp :
(1) NH
3
d + dd AlCl
3
(2) NaHCO
3
+ ddBaCl
2
v un nng
(3) NH
3
d + dd CuSO
4
(4) H
2
S + ddZnCl
2

(5) Zn
3
P
2
+ dd HCl d

(6) K
3
PO
4
+ dd CaCl
2

S th nghim thu c kt ta sau phn ng
A. 5 B. 3 C. 4 D. 2
Cu 5: Xt cc h cn bng sau y trong mt bnh kn
(1) 2NaHCO
3

(r)
Na
2
CO
3(r)
+ H
2
O
(k)
+ CO
2(k)
(3) CO
2(k)
+ CaO
(r)
CaCO
3(r)

(2) C
(r)
+ CO
2(k)
2CO
(k)
(4) CO
(k)
+ H
2
O
(k)
CO
2(k)
+ H
2

(k)

Khi thm CO
2
vo h th s cn bng chuyn dch theo chiu thun l:
A. 2. B. 4. C. 1. D. 3.
Cu 6: t chy hon ton m gam hn hp G gm 2 amino axit: no, mch h, hn km nhau 2 nguyn t C(1 NH
2
; 1
COOH) bng 8,4 lt O
2
(va , ktc) thu c hn hp sn phm X. Cho X li t t qua dung dch NaOH d nhn
thy khi lng dung dch tng ln 19,5 gam. Gi tr gn ng nht ca %khi lng amino axit ln trong G l.
A. 44, 5% B. 54, 5% C. 56, 7% D. 50%.
Cu 7: Cho 2,721 gam cao su buna-S tc dng va ht vi dung dch cha 3,53 gam brom trong CCl
4
. T l s mt
xch gia butaien v stiren trong loi cao su l
A. 1 : 2. B. 2 : 1. C. 1 : 1. D. 3 : 2.
Cu 8: Cht trong phn t va cha lin kt cng ha tr va cha lin kt ion l
A. CO
2
. B. MgCl
2
. C. HNO
3
. D. NH
4
Cl.
Cu 9: Ho tan hon ton m gam Al vo dung dch NaOH va thu c dung dch X. Chia X thnh 2 phn bng
nhau.
Phn 1: Nh 200 ml HCl 1,3M vo thu c 1,8a gam cht rn.
Phn 2: Nh 200 ml HCl 2,5M vo thu c a gam cht rn.
Gi tr ca m l
A. 2,7 B. 5,4 C. 10,8 D. 8,1
Cu 10: C cc cp dung dch sau :
(1) NaCl v AgNO
3
; (2) NaHSO
4
v BaCl
2
(3) Na
2
CO
3
v HCl;
(4) NaOH v MgCl
2
; (5) BaCl
2
v NaOH; (6) CaCl
2
v NaHCO
3

Nhng cp no khng xy ra phn ng khi trn cc dung dch trong cc cp vi nhau?
A. 2, 4,5, B. 2, 4,5, C. 5,6 D. 2,5,6
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Trang 31
Cu 11: S lin kt n trong phn t metyl oleat l
A. 56 B. 52 C. 54 D. 58
Cu 12: Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung
dch NaHCO
3
. X c th l:
A. metyl axetat. B. axit acrylic. C. phenol. D. anilin.
(1) cumen (2) benzyl amin (3) anehit axetic (4) ancol anlylic (5) phenol
(6) Vinyl axetat (7) fructoz (8) axit stearic (9) axit fomic
S cht lm mt mu nc brm trong cc cht sau l bao nhiu?
A. 7. B. 4. C. 6. D. 5.
Cu 14: Cho 2,67 gam mt amino axit X (cha 1 nhm axit) vo 100 ml HCl 0,2M thu c dung dch Y. Y phn ng
va vi 200 ml KOH 0,25M. Cng thc ca X l
A. H
2
N C
2
H
4
COOH B. (H
2
N)CHCOOH C. H
2
N C
5
H
10
COOH D. (H
2
N)C
4
H
7
COOH
Cu 15: Dy gm cc kim loi c th iu ch bng phng php in phn dung dch l
A. Zn, Fe, Ni, Na. B. Cu, Zn, Mg, Ag. C. Pb, Sn, Al, Ag. D. Cu, Fe, Ag, Sn.
Cu 16: Trong y hc, hp cht no sau y c dng lm thuc tr bnh d dy
A. NaCl B. Na
2
SO
4
C. NaHSO
3
D. NaHCO
3

Cu 17: Cho cc cht: Al, ZnO, Al
2
(SO
4
)
3
, Al(OH)
3
, NaHSO
4
, CH
3
COONH
4
, axit glutamic, KHCO
3; CH
3
NH
3
Cl;
Alanin
. S cht lng tnh l
A. 5. B. 6. C. 4. D. 7.
Cu 18: Cng thc ho hc ca amophot, mt loi phn bn phc hp l:
A. (NH
4
)
2
HPO
4
v Ca(H
2
PO
4
)
2
. B. NH
4
H
2
PO
4
v (NH
4
)
2
HPO
4
.
C. NH
4
H
2
PO
4
v Ca(H
2
PO
4
)
2
. D. Ca(H
2
PO
4
)
2
.
Cu 19: Cho (CH
3
)
2
C=CH- CH
3
cng nc thu c sn phm chnh c tn l
A. 1,1-imetylpropan-2-ol. B. 2-metylbutan-2-ol.
C. 3-metylbutan-2-ol. D. 1,1-imetylpropan-1-ol.
Cu 20: Ha tan ht 38,4 gam Mg trong dung dch HNO
3
long, d. Sau phn ng thu c 8,96 lt kh Z c cng thc
N
x
O
y
(sn phm kh duy nht ktc). Kh Z l
A. N
2
O B. NO
2
C. N
2
D. NO
Cu 21: Cho 4,0 gam hn hp A gm Fe v 3 oxit st trong dung dch axit HCl (d) thu c dung dch X. Sc kh Cl
2

cho n d vo X thu c dung dch Y cha 9,75 gam mui tan. Nu cho 4 gam A tc dng vi dung dch HNO
3

long d th thu c V lt NO(sn phm kh duy nht, ktc). Gi tr ca V l
A. 0,896. B. 1,120. C. 0,726. D. 0,747.
Cu 22: Cation X
2+
c tng s ht c bn (p, n, e) bng 80, trong t s ht electron so vi ht ntron l
5
4
. Trong
bng tun hon cc nguyn t ho hc, nguyn t X thuc
A. chu k 4, nhm VIIIB. B. chu k 4, nhm VIA.
C. chu k 4, nhm IIA. D. chu k 4, nhm IIB.
Cu 23: in phn dung dch hn hp gm: ZnCl
2
; CuSO
4
v Fe
2
(SO
4
)
3
, thu c cht rn catt theo th t ln lt
l:
A. Cu, Fe, Zn. B. Fe, Zn, Cu. C. Cu, Zn, Fe. D. Fe, Cu, Zn.
Cu 24: S ancol bc I ng vi cng thc C
4
H
10
O l
A. 3. B. 5. C. 4. D. 2.
Cu 25: Cho 2,2 gam anehit n chc Y tc dng vi mt lng d AgNO
3
/NH
3
thu c 10,8 gam Ag. Xc nh
CTCT ca Y ?
A. C
2
H
3
CHO B. HCHO C. CH
3
CHO D. C
2
H
5
CHO
Cu 26: Cho p:
Fe
3
O
4
+ H
2
SO
4
(c) ....+ SO
2
+ ....
Tng h s nguyn ti gin ca cc cht sn phm trong phn ng sau l
A. 14. B. 21. C. 26. D. 12.
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Trang 32
Cu 27: Mt loi phn ur c 10% tp cht tr khng cha N. dinh dng ca phn ny l
A. 21% B. 23,335% C. 42% D. 46,67%
Cu 28: Cho cn bng sau trong bnh kn: 2NO
2
(k) N
2
O
4

(k).

(mu nu ) (khng mu)
Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c:
A. H > 0, phn ng ta nhit B. H > 0, phn ng thu nhit
C. H < 0, phn ng thu nhit D. H < 0, phn ng ta nhit
Cu 29: t chy hon ton a mol axit cacboxylic Y thu c 2a mol CO
2
. Mt khc trung ha ht a mol Y cn 2a
mol NaOH. Gi tn Y ?
A. Axit metacrylic B. Axit oleic C. Axit oxalic D. Axit acrylic
Cu 30: S amin ng vi cng thc phn t C
4
H
11
N m khi cho vo dung dch HNO
2
khng c kh bay ra l
A. 3. B. 2. C. 5. D. 4.
Cu 31: X. Y l hai nguyn t thuc thuc cng mt phn nhm v 2 chu k lin tip trong bng tun hon. Bit Z
X
+
Z
Y
= 32. S proton trong nguyn t nguyn t X, Y ln lt l :
A. 7 v 25 B. 8 v 24 C. 12 v 20 D. 15 v 17
Cu 32: Nh 147,5 ml dung dch H
2
SO
4
2M vo 200ml dung dch Y gm: KAlO
2
1M v NaOH 1,5M thu c a gam
kt ta. Xc nh
A. 13,26 B. 15,8 C. A. 4,46 D. 8,58
- Cho Cu vo dung dch Fe
2
(SO
4
)
3
. - Cho dung dch AgNO
3
d vo dung dch FeCl
2
.
- Cho Fe
3
O
4
vo dung dch H
2
SO
4
long d. - Sc H
2
S vo dung dch CuCl
2
.
- Sc H
2
S vo dung dch FeCl
3
. - Cho Fe
2
O
3
vo dung dch HI.
S th nghim xy ra phn ng oxi ha kh l
A. 4. B. 3. C. 5. D. 2.
Cu 34: S th nghim xy ra n mn in ha trong cc th nghim sau l bao nhiu?
(1) Nhng thanh Zn vo dung dch AgNO
3
. (4) Cho vt bng gang vo dung dch HCl.
(2) ming tn( Fe trng Zn) c vt xc su ngoi khng kh m (5) Cho Na vo dung dch CuSO
4
.
(3) Cho inh st vo dung dch H
2
SO
4
2M.
Cho Mg vo dung dch FeCl
3
d A. 3 B. 2 C. 4 D. 5
(1) Stiren (2) propoilen (3) Glucoz (4) Vinyl axetilen (5) saccaroz
(6) metyl acrylat (7) etyl xiclopropan (8) xiclohexan (9) axit fomic
S cht tc dng c vi H
2
trong iu kin thch hp trong cc cht sau l bao nhiu?
A. 6. B. 8. C. 7. D. 5.
Cu 36: Nung 16 gam hn hp G gm: Al, Mg, Zn, Cu trong bnh ng oxi d thu c m gam hn hp oxit X. Ha
tan hon ton m gam hn hp oxit cn 160 ml dung dch HCl 3,5M. Gi tr m l
A. 27,6. B. 20,48. C. 18,24. D. 24,96.
Cu 37: Chia m gam hn hp G gm: 0,01 mol fomanehit; 0,02 mol anehit oxalic; 0,04 mol axit acrylic; 0,02 mol
Vinyl fomat thnh 2 phn bng nhau.
Phn 1: Cho vo AgNO
3
/NH
3
(d, un nng) thu c a gam Ag.
Phn 2: Lm mt mu va b lt nc Br
2
0,5M.
Cc phn ng u xy ra hon ton, gi tr ca a, b ln lt l
A. 8,64 v 0,16 B. 8,64 v 0,14 C. 10,8 v 0,16 D. 10,8 v 0,14
Cu 38: in phn c mng ngn 100 ml dung dch cha hn hp gm CuCl
2
0,5M v NaCl 2,5M (in cc tr,
hiu sut in phn 100%) vi cng dng in 7,5A trong 3860 giy thu c dg X. X c kh nng ho tan m
gam Zn. Gi tr ln nht ca m l
A. 6,5. B. 13. C. 3,25. D. 9,75.
Cu 39: Cho 1 ancol n chc X vo H
2
SO
4
c, un nng thu c sn phm hu c Y (khng cha S). T khi ca X so vi Y
l 4/3. Cng thc phn t ca X l
A. C
3
H
6
O B. C
3
H
8
O C. C
4
H
8
O D. C
4
H
10
O
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Trang 33
Cu 40: Ln men m gam glucoz thnh ancol etylic th thu c 100 ml ancol 46
0
. Khi lng ring ca ancol nguyn cht l 0,8
gam/ml. Hp th ton b kh CO
2
sinh ra trong qu trnh ln men vo dung dch NaOH d thu c a gam mui (cc phn ng
xy ra hon ton). Gi tr ca a l
A. 106 gam. B. 84,8 gam. C. 169,6 gam. D. 212 gam.
Cu 41: Dy gm cc kim loi tc dng nhiu c vi hi nc khi nung nng l:
A. Ca, Zn, Mg, Ag. B. Mg, Be, Sn, K. C. Pb, Sn, Al, Zn. D. Zn, Fe, Ba, Na.
Cu 42: E l este thun chc, mch khng nhnh. un nng m gam E vi 150 ml dung dch NaOH 2M n hon ton
thu c dung dch X. Trung ho X cn 200 ml dung dch HCl 0,3M thu c dung dch Y. C cn Y thu c 22,95
gam hn hp hai mui khan v 11,04 gam hn hp 2 ancol n chc. Cng thc cu to ca E l
A. CH
3
-CH
2
-OOC-CH
2
COOCH
3
B. HCOOCH
3
v CH
3
COOC
2
H
5

C. C
2
H
5
-COO-C
2
H
5
D. CH
3
CH
2
CH
2
-OOC-CH
2
CH
2
COOCH
3

Cu 43: Ha tr cao nht trong hp cht vi oxi ca nguyn t R gp 3 ln ha tr ca n trong hp cht kh vi hiro.
Phn trm khi lng ca R trong hp cht kh vi hiro nhiu hn trong hp cht c ha tr cao nht vi oxi l 54,11%.
Nguyn t R l
A. P. B. S. C. N. D. Cl.
Cu 44: Cho 1,792 lt hn hp X gm: propin, H
2
( ktc, t khi ca X so vi H
2
bng 65/8) i qua xc tc nung nng
trong bnh kn thu c hn hp kh Y c t khi ca Y so vi He bng a. Y lm mt mu va 160 gam nc brom
2%. Gi tr gn ng nht ca a l
A. 8,12 B. 32,58 C. 10,8 D. 21,6
Cu 45: Cho 7, 46 gam 1 pept i t c cng t hc: Al a-Gl y-Val -Lys vo 200 ml HCl 0, 45M un nng
n phn ng hon t on t hu c dung d ch X. C cn X t hu c a gam cht r n khan Y. Gi
t r ca a l
A. 11, 717 B. 10, 745 C. 10, 971 D. 11, 825
Cu 46: Cho 9, 27 gam pept i t X c cng t hc: Val -Gl y-Val vo 200 ml NaOH 0, 33M un nng
n phn ng hon t on t hu c dung d ch Y. C cn Y t hu c m gam cht r n khan Z. Gi
t r ca m l
A. 11, 802 B. 11, 514 C. 11, 37 D. 11, 3286
Cu 47: Cho 8, 88 gam 1 cht cha nhn t hm A c cng t hc C
2
H
3
OOCC
6
H
3
( OH) OOCCH
3
vo
200 ml KOH 0, 9M un nng n phn ng hon t on t hu c dung d ch B. C cn B t hu c
b gam cht r n khan. Gi t r ca b l
A. 17, 2 B. 15, 76 C. 16, 08 D. 14, 64
Cu 48: Sc 6,72 lt CO
2
(ktc) vo 100ml dung dch X gm: Na
2
ZnO
2
1M v NaOH 2M thu c a gam kt ta. Gi
tr ca a l. A. 14,85 B. 4,95 C. 7,8 D. 9,9
Cu 49: Tn quc t (theo IUPAC) ca hp cht c cng thc CH
3
CH(C
2
H
5
)CH(OH)CH
3
l
A. 3-etyl hexan-5-ol. B. 4-etyl pentan-2-ol.
C. 3-metyl pentan-2-ol. D. 2-etyl butan-3-ol.
Cu 50: Cho 16,8 gam Fe vo 2 lt dung dch AgNO
3
, phn ng xy ra hon ton th thy to thnh 86,4 gam kt
ta. Nng ca AgNO
3
trong dung dch ban u l
A. 0,35M B. 0,3 M C. 0,2 M D. 0,4M
M 150
Cu A
1 A 16 D 31 C 46 A
2 D 17 B 32 A 47 B
3 B 18 B 33 A 48 B
4 B 19 B 34 A 49 C
5 A 20 A 35 A 50 D
6 C 21 D 36 B
7 D 22 A 37 C
8 D 23 A 38 A
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Trang 34
9 C 24 A 39 C
10 C 25 C 40 B
11 C 26 A 41 D
12 C 27 C 42 D
13 C 28 D 43 B
14 A 29 C 44 A
15 D 30 D 45 D
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Trang 35
S GD & T VNH PHC

( thi c 05 trang)
KTCL N THI I HC LN 1 NM HC 2013-2014
Mn: Ha hc; Khi A
Thi gian lm bi: 90 pht; khng k thi gian giao

M thi 104

H, tn th sinh:.................................................................................................S bo danh:.........................

Cho: H = 1; C = 12; N = 14; O = 16; F = 19; Na = 23; Mg = 24; Al = 27; Si = 28; P = 31; S = 32; Cl = 35,5; K = 39
Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Sn = 119; Ba = 137; Pb = 207.

I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: Trn 400 ml dung dch X cha Na
+
, K
+
v x mol OH
(tng s mol Na
+
v K
+
l 0,06) vi 600 ml dung dch Y
cha 0,01 mol
2
4
SO

, 0,03 mol Cl
, y mol H
+
. pH ca dung dch thu c sau phn ng l
A. 1,0. B. 2,0. C. 12,0. D. 13,0.
Cu 2: Dy cc cht no sau y ch c lin kt cng ha tr trong phn t?
A. K
2
O, SO
2
, H
2
S. B. H
2
SO
4
, NH
3
, H
2
. C. NH
4
Cl, CO
2
, H
2
S. D. CaCl
2
, H
2
O, N
2
.
Cu 3: Ha tan ht 26,5 gam hn hp bt gm Mg, Al, Al
2
O
3
v MgO bng 800 ml dung dch hn hp gm HCl 0,5M v
H
2
SO
4
0,75M (va ). Sau phn ng thu c dung dch X v 4,48 lt (ktc) H
2
. C cn dung dch X thu c khi lng
mui khan l
Cu 4: C th dng cht no sau y phn bit 3 cht lng khng mu l benzen, toluen, stiren?
A. Dung dch KMnO
4
. B. Dung dch H
2
SO
4
. C. Dung dch brom. D. Dung dch NaOH.
Cu 5: Cho hn hp A gm 0,15 mol Mg, 0,35 mol Fe phn ng vi V lt dung dch HNO
3
2M, thu c hn hp X
gm 0,05 mol N
2
O, 0,1 mol NO v cn li 2,8 gam kim loi. Gi tr ca V l
A. 0,610. B. 0,575. C. 0,450. D. 0,550.
Cu 6: Khi thy phn hon ton 0,1 mol peptit X mch h (X to bi cc amino axit c mt nhm amino v mt nhm
cacboxylic) bng lng dung dch NaOH gp i lng cn phn ng, c cn dung dch thu c hn hp cht rn c
khi lng tng so vi X l 78,2 gam. S lin kt peptit trong X l
A. 12. B. 11. C. 9. D. 10.
Cu 7: Cho 80 gam mt loi cht bo c ch s axit bng 7 tc dng va vi dung dch NaOH thu c 83,02 gam
hn hp mui. Khi lng NaOH tham gia phn ng l
Cu 8: Hn hp X gm vinyl axetat, metyl axetat v etyl fomat, c t khi hi so vi heli l 19,25. t chy hon
ton 3,08 gam X, tng khi lng CO
2
v H
2
O thu c l a gam. Gi tr ca a l
A. 7,56. B. 8,48. C. 7,88. D. 8,20.
Cu 9: Hai cht hu c X, Y c thnh phn phn t gm C, H, O (M
X
<M
Y
<70). C X v Y u c kh nng tham gia
phn ng trng bc v u phn ng c vi dung dch KOH sinh ra mui. T khi hi ca Y so vi X bng
A. 1,300. B. 1,403. C. 1,333. D. 1,304.
Cu 10: Hn hp X gm glixerol v hai ancol no, n chc, k tip trong dy ng ng. Cho 8,75 gam X tc dng
vi Na d thu c 2,52 lt (ktc) H
2
. Mt khc 14 gam X tc dng va vi 3,92 gam Cu(OH)
2
. Hai ancol trong X
A. C
4
H
9
OH v C
5
H
11
OH. B. C
2
H
5
OH v C
3
H
7
OH.
C. CH
3
OH v C
2
H
5
OH. D. C
3
H
7
OH v C
4
H
9
OH.
Cu 11: Cho cc cht v ion sau: Zn, S, Cl
2
, SO
2
, FeO, Fe
2
O
3
, Fe
2+
, Cu
2+
, Cl
-
. S cht v ion va c tnh oxi ha, va
c tnh kh l
A. 5. B. 7. C. 6. D. 4.
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Trang 36
X + H
2
SO
4 c

0
t
Fe
2
(SO
4
)
3
+ SO
2
+ H
2
O.
Trong s cc cht: Fe, FeCO
3
, FeO, Fe
2
O
3
, Fe
3
O
4
, Fe(OH)
3
, Fe(OH)
2
, FeS, FeS
2
, Fe
2
(SO
4
)
3
th s cht X tha mn s
phn ng trn l
A. 5. B. 7. C. 8. D. 6.
Cu 13: Cho hirocacbon X mch khng phn nhnh phn ng vi dung dch brom theo t l mol 1:1 thu c cht
hu c Y (cha 74,074% brom v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau.
Tn gi ca X l
A. but-1-en. B. but-2-en. C. propilen. D. isobutilen.
Cu 14: Tin hnh 5 th nghim sau:
- TN 1: Nhng thanh st vo dung dch FeCl
3
.
- TN 2: Nhng thanh km vo dung dch CuSO
4
.
- TN 3: Cho thanh st tip xc vi thanh ng ri nhng c hai vo dung dch HCl.
- TN 4: Nhng thanh nhm vo dung dch NaOH.
- TN 5: mt vt lm bng thp trong khng kh m.
S th nghim xy ra s n mn in ha hc l
A. 2. B. 3. C. 4. D. 5.
Cu 15: Cho hn hp X gm hai cht hu c no n chc tc dng va vi 100 ml dung dch KOH 0,4 M thu c
mt mui v 336 ml (ktc) hi mt ancol. Nu t chy hon ton hn hp X trn, sau hp th ht sn phm chy
vo bnh ng dung dch Ca(OH)
2
d th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht trong X l
A. HCOOH v HCOOC
2
H
5
. B. HCOOH v HCOOC
3
H
7
.
C. C
2
H
5
COOH v C
2
H
5
COOCH
3
. D. CH
3
COOH v CH
3
COOC
2
H
5
.
Cu 16: in phn (c mng ngn, in cc tr) 400 ml dung dch hn hp CuSO
4
aM v NaCl 1M, vi cng
dng in 5A trong 3860 giy. Dung dch to thnh c khi lng gim so vi ban u l 10,4 gam. Gi tr ca a l
A. 0,100. B. 0,200. C. 0,125. D. 0,129.
Cu 17: Cho cc th nghim sau :
(1) Cho SiO
2
tc dng vi dung dch HF.
(2) Cho kh SO
2
tc dng vi kh H
2
S.
(3) Cho CaOCl
2
tc dng vi dung dch HCl c.
(4) Cho kh O
3
tc dng vi Ag.
(5) Cho dung dch NH
4
Cl tc dng vi dung dch NaNO
2
un nng.
S th nghim to ra n cht l
A. 2. B. 4. C. 5. D. 3.
Cu 18: Trng hp no sau y khng thu c mui Fe
3+
?
A. Cho kim loi Fe vo dung dch H
2
SO
4
c, nng, d. B. Cho kim loi Fe vo dung dch CuSO
4
d.
C. Cho kim loi Fe vo dung dch AgNO
3
d. D. Cho kim loi Fe vo dung dch HNO
3
long, d.
Cu 19: Thu phn 1 mol este X cn dung dch cha 3 mol NaOH, un nng. Hn hp sn phm thu c gm:
glixerol, mui ca axit axetic v axit propionic. S cht X tha mn l
A. 6. B. 12. C. 4. D. 2.
Cu 20: Cho cc cht sau: ivinyl, toluen, etilen, propan, stiren, vinylaxetilen, propilen, benzen. S cht lm mt mu
dung dch KMnO
4
nhit thng l
A. 4. B. 7. C. 5. D. 6.
Cu 21: Ln men 360 gam glucoz trong iu kin thch hp (gi s ch c phn ng to thnh ancol etylic). Cho ton
b lng kh CO
2
sinh ra hp th ht vo dung dch NaOH, thu c 106 gam Na
2
CO
3
v 168 gam NaHCO
3
. Hiu sut
ca phn ng ln men glucoz l
A. 80%. B. 62,5%. C. 50%. D. 75%.
Cu 22: Dung dch X cha 0,1 mol FeCl
2
v 0,2 mol FeSO
4
lm mt mu va ht V ml dung dch KMnO
4
0,2 M
trong mi trng H
2
SO
4
d. Gi tr ca V l
A. 400. B. 300. C. 500. D. 200.
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Trang 37
Cu 23: Cho cc cht: axit 6-aminohexanoic, caprolactam, acrilonitrin, anehit fomic, axit aipic, etylenglicol. S cht
c kh nng tham gia phn ng trng ngng l
A. 4. B. 3. C. 2. D. 5.
Cu 24: Dy gm cc dung dch u tc dng c vi dung dch Ba(HCO
3
)
2
l
A. HNO
3
, Ca(OH)
2,
KHSO
4
, Na
2
SO
4
. B. NaCl, Na
2
SO
4
, Ca(OH)
2
, KHSO
4
.
C. HNO
3
, Ca(OH)
2
, KHSO
4
, Mg(NO
3
)
2
. D. HNO
3
, NaCl, Na
2
SO
4
, Ca(OH)
2
.
Cu 25: Khi ni v peptit v protein, pht biu no sau y l ng?
A. Tripeptit l cc peptit c 3 lin kt peptit trong phn t.
B. Tt c cc peptit v protein u c phn ng mu biure.
C. Lin kt CO-NH gia hai n v amino axit c gi l lin kt peptit.
D. Thy phn hon ton protein n gin thu c cc o-amino axit.
Cu 26: Tng s ht proton trong ion M
2+
l 24. V tr ca M trong bng h thng tun hon l
A. chu k 4, nhm VIB B. chu k 4, nhm IIA C. chu k 4, nhm VIIIB D. chu k 4, nhm IA
Cu 27: Nhit phn hon ton hn hp 2 mui KNO
3
v Fe(NO
3
)
2
trong bnh chn khng. Sau phn ng thu c hn
hp X gm 2 kh c t khi so vi H
2
bng 21,6. Phn trm khi lng ca Fe(NO
3
)
2
trong hn hp ban u l
A. 40,00%. B. 60,00%. C. 34,30%. D. 78,09%.
Cu 28: Hp th hon ton 3,36 lt (ktc) CO
2
vo 100ml dung dch X gm KOH 1M v K
2
CO
3
2M thu c dung
dch Y c tng khi lng cht tan l
Cu 29: Hn hp X gm SO
2
v khng kh (cha 20% th tch O
2
v 80% th tch N
2
) c t l s mol l 1:5. Nung
nng X c xc tc V
2
O
5
th thu c hn hp kh Y. T khi hi ca X so vi Y l 0,93. Hiu sut ca phn ng trn l
A. 42%. B. 84%. C. 26%. D. 80%.
Cu 30: Cho cc mnh sau:
(1) Metylamin, imetylamin, trimetylamin v etylamin l nhng cht kh c mi kh chu, c.
(2) Cc amin ng ng ca metylamin c tan trong nc gim dn theo chiu tng ca khi lng phn t.
(3) Anilin c tnh baz v lm xanh qu tm m.
(4) Tt c cc amin u c tnh baz mnh hn amoniac.
Cc mnh ng l
A. (1), (2), (4). B. (2), (3), (4). C. (1), (2). D. (1), (2), (3).
Cu 31: t chy hon ton 29,16 gam hn hp X gm C
x
H
y
COOH, C
2
H
3
COOH, v (COOH)
2
thu c m gam H
2
O
v 21,952 lt (ktc) CO
2
. Mt khc 29,16 gam hn hp X phn ng hon ton vi NaHCO
3
d thu c 11,2 lt (ktc)
CO
2
. Gi tr ca m l
A. 10,8. B. 9,0. C. 12,6. D. 8,1.
Cu 32: Hn hp X gm axit fomic v axit axetic (t l mol 1:1). Ly 7,42 gam hn hp X tc dng vi 5,75 gam ancol
etylic (c xc tc H
2
SO
4
c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi
tr ca m l
A. 9,072. B. 10,125. C. 8,10. D. 6,48.
Cu 33: Cho cc cht sau: dung dch NaOH; dung dch HNO
3
; nc Br
2
; dung dch HCl c; HCHO; dung dch
NaHCO
3
, Na. S trng hp phn ng vi phenol trong iu kin thch hp l
A. 5. B. 3. C. 4. D. 6.
Cu 34: Cht hu c X mch h tc dng vi AgNO
3
/NH
3
, un nng thu c Ag. Mt khc, hiro ha hon ton X
thu c 2,3-imetylbutan-1-ol. S cht X ph hp l
A. 6. B. 3. C. 4. D. 5.
Cu 35: Cho phn ng sau:
K
2
SO
3
+ KMnO
4
+ KHSO
4
K
2
SO
4
+ MnSO
4
+ H
2
O.
Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho hc ca phn ng trn l
A. 27. B. 24. C. 30. D. 31.
Cu 36: Cho 2,16 gam bt nhm tan ht trong dung dch HNO
3
long lnh th thu c 0,448 lt (ktc) N
2
v mt
dung dch X. Khi lng mui nitrat to ra trong dung dch X l
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Trang 38
Cu 37: Ba cht hu c cng chc c cng thc phn t ln lt l: CH
2
O
2
, C
2
H
4
O
2
, C
3
H
6
O
2
. C ba cht ny khng
ng thi tc dng vi
A. C
2
H
5
ONa. B. AgNO
3
/NH
3
. C. C
2
H
5
OH/H
2
SO
4 c
. D. NaHCO
3
.
Cu 38: Dung dch Br
2
mu nu , chia thnh 2 phn. Dn kh X d khng mu qua phn 1 thy dung dch mt mu.
Dn kh Y khng mu qua phn 2 thy dung dch mu m hn. X v Y l
A. H
2
S v SO
2
. B. HI v CO
2
. C. SO
2
v HI. D. SO
2
v H
2
S.
Cu 39: Cho m gam bt Zn vo 500 ml dung dch Fe
2
(SO
4
)
3

0,24M. Sau khi cc phn ng xy ra hon ton, khi
lng dung dch tng thm 9,6 gam so vi khi lng dung dch ban u. Gi tr ca m l
A. 48,75. B. 20,80. C. 29,25. D. 32,50.
Cu 40: Cho cc phn ng sau:
(1) Fe(OH)
2
+ H
2
SO
4

c

o
t
(2) Fe + H
2
SO
4

long

(3) Fe(OH)
3
+ H
2
SO
4

c

o
t
(4) Fe
3
O
4
+ H
2
SO
4

long

(5) Cu + H
2
SO
4

long
+ dung dch NaNO
3
(6) FeCO
3
+ H
2
SO
4

c

o
t

S phn ng ha hc trong H
2
SO
4
ng vai tr l cht oxi ha l
A. 2. B. 4. C. 5. D. 3.

II. PHN RING (10 cu)
Th sinh ch c lm mt trong hai phn (phn A hoc B)
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: Ha tan hon ton 6,44 gam hn hp X gm Fe, Mg v Zn bng mt lng va dung dch H
2
SO
4
long,
thu c 2,688 lt (ktc) hiro v dung dch cha m gam mui. Gi tr ca m l
A. 17,96. B. 14,50. C. 19,04. D. 20,54.
Cu 42: t chy hon ton a mol axit cacboxylic X no, mch h thu c a mol H
2
O. Mt khc, cho a mol X tc
dng vi NaHCO
3

d thu c 2a mol CO
2
. Tng s nguyn t c trong phn t X l
A. 5. B. 8. C. 6. D. 7.
Cu 43: Trong qu nho chn rt giu hm lng
A. fructoz. B. glucoz. C. saccaroz. D. xenluloz.
Cu 44: Cho dy cc cht: CH
4
, C
2
H
2
, C
2
H
4
, C
2
H
5
OH, CH
2
=CH-COOH, C
6
H
5
NH
2
(anilin), C
6
H
5
OH (phenol), C
6
H
6
(benzen),
CH
3
CHO. S cht trong dy phn ng c vi nc brom l
A. 7. B. 8. C. 5. D. 6.
Cu 45: Cho cc cp oxi ha - kh c sp xp theo th t tng dn tnh oxi ha ca cc ion kim loi: Al
3+
/Al;
Fe
2+
/Fe, Sn
2+
/Sn; Cu
2+
/Cu. Tin hnh cc th nghim sau:
(a) Cho st vo dung dch ng(II) sunfat. (b) Cho ng vo dung dch nhm sunfat.
(c) Cho thic vo dung dch ng(II) sunfat. (d) Cho thic vo dung dch st(II) sunfat.
Cc th nghim c xy ra phn ng l
A. (b) v (d). B. (b) v (c). C. (a) v (b). D. (a) v (c).
Cu 46: C th dng dung dch NH
3
phn bit 2 dung dch mui no sau y?
A. CaSO
4
v BaCl
2
. B. NH
4
NO
3
v KCl. C. CuSO
4
v FeSO
4
. D. NaCl v KNO
3
.
Cu 47: Cho 0,3 mol hn hp kh X gm HCHO v C
2
H
2
tc dng hon ton vi lng d dung dch AgNO
3
trong
NH
3
to ra 91,2 gam kt ta. Nu cho ton b lng X trn vo bnh ng dung dch brom trong CCl
4
th khi lng
brom phn ng ti a l
A. 96 gam. B. 128 gam. C. 80 gam. D. 64 gam.
Cu 48: Cho cc cht sau: CH
3
CH
2
COOH (1); HCOOCH
3
(2); CH
3
CH
2
OH (3); CH
3
CH
2
CH
2
OH (4). Th t gim dn
nhit si cc cht l
A. (3) > (1) > (2) > (4). B. (1) > (2) > (3) > (4). C. (2) > (3) > (1) > (4). D. (1) > (4) > (3) > (2).
Cu 49: Ancol v amin no sau y cng bc?
A. C
6
H
5
CH(OH)CH
3
v C
6
H
5
NHCH
3
. B. (CH
3
)
3
COH v (CH
3
)
3
CNH
2
.
C. C
6
H
5
CH
2
OH v (C
6
H
5
)
2
NH. D. (CH
3
)
2
CHOH v (CH
3
)
2
CHNH
2
.
Cu 50: Cho cc dung dch sau: C
6
H
5
NH
2
(1), KCl (2), NH
3
(3), CH
3
NH
2
(4), NaHSO
4
(5), (CH
3
)
2
NH (6). Cc dung
dch c kh nng lm i mu phenolphtalein l
A. (3), (5). B. (1), (4), (6). C. (3), (4), (6). D. (1), (3), (4), (6).
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Trang 39
B. Theo chng trnh nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Cho cc dung dch c nh s th t nh sau:
(1) KCl; (2) Na
2
CO
3
; (3) CuSO
4
; (4) CH
3
COONa; (5) Al
2
(SO
4
)
3
; (6) NH
4
Cl; (7) NaNO
3
; (8) K
2
S.
Dy gm cc dung dch u c gi tr pH > 7 l
A. (3), (7), (8). B. (2), (4), (6). C. (2), (4), (8). D. (1), (5), (6).
Cu 52: Cho 18 gam hn hp bt Mg v Cu c t l mol 2:3 vo dung dch cha 500 ml Fe
2
(SO
4
)
3
0,4M. Sau khi cc
phn ng xy ra hon ton thu c m gam kim loi. Gi tr ca m l
A. 8. B. 14,6. C. 12,8 . D. 11,2.
Cu 53: Dy gm cc cht c th iu ch trc tip c axeton l
A. C
2
H
5
OH, CH
3
CHO, CH
3
COOH. B. C
2
H
5
OH, CH
3
CH=CHBr, C
6
H
5
CH(CH
3
)
2
.
C. C
6
H
5
CH(CH
3
)
2
, CH
3
CH
2
CH
2
OH, HCOOCH
3
. D. CH
3
CH(OH)CH
3
, (CH
3
COO)
2
Ca, CH
2
=CBr-CH
3
.
Cu 54: X c CTPT C
4
H
11
O
2
N. Khi cho X tc dng vi dung dch NaOH thu c etanamin. X l
A. HCOONH
3
C
3
H
7
. B. CH
3
COONH
3
C
2
H
5
.
C. C
2
H
5
COOCH
2
NHCH
3
. D. C
2
H
3
COONH
3
C
2
H
5
.
Cu 55: Cho sut in ng chun ca cc pin in ho: Mg-Ni l 2,11 V; Ni-Ag l 1,06 V. Bit th in cc chun
ca cp Ag
+
/Ag bng 0,8 V. Th in cc chun ca cp Mg
2+
/Mg v cp Ni
2+
/Ni ln lt l
A. -1,87 V v +0,26 V. B. -0,76 V v -0,26 V. C. -1,46 V v -0,34 V. D. -2,37 V v -0,26 V.
Cu 56: Trng hp no sau y khng xy ra s n mn in ho?
A. Nhng thanh Cu trong dung dch Fe
2
(SO
4
)
3
c nh vi git dung dch H
2
SO
4
.
B. S g ca gang trong khng kh m.
C. S n mn v tu trong nc bin.
D. Nhng thanh Zn trong dung dch H
2
SO
4
c nh vi git CuSO
4
.
Cu 57: X l hp cht thm c cng thc phn t C
7
H
8
O
2
tc dng vi dung dch Br
2
to ra c dn xut tribrom. X
tc dng c vi dung dch NaOH theo t l mol 1:1. S cht X tha mn l
A. 2. B. 6. C. 5. D. 4.
Cu 58: C dung dch X gm KI v h tinh bt. Cho ln lt tng cht sau: O
3
, Cl
2
, H
2
O
2
, FeCl
3
, AgNO
3

tc dng vi dung dch X. S cht lm dung dch X chuyn sang mu xanh en l
A. 2. B. 4. C. 5. D. 3.
Cu 59: X c cng thc phn t l C
4
H
8
Cl
2
. Thy phn X trong dung dch NaOH un nng thu c cht hu c Y
c kh nng tc dng vi Cu(OH)
2
to dung dch mu xanh lam. S ng phn cu to ca X tha mn l
A. 5. B. 3. C. 4. D. 2.
Cu 60: Thy phn dung dch cha 34,2 gam mantoz mt thi gian. Ly ton b sn phm thu c sau phn ng
thy phn cho tc dng vi lng d dung dch AgNO
3
trong NH
3
, sau phn ng hon ton thu c 31,32 gam Ag.
Hiu sut ca phn ng thy phn mantoz l
A. 55%. B. 25%. C. 50%. D. 45%.
-----------------------------------------------
----------- HT ----------
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Trang 40
104 Cu
C 1 D 48
B 2 A 49
A 3 C 50
A 4 C 51
B 5 D 52
C 6 D 53
B 7 B 54
C 8 D 55
D 9 A 56
B 10 A 57
A 11 B 58
D 12 B 59
A 13 D 60
B 14
D 15
C 16
B 17
B 18
C 19
C 20
D 21
C 22
A 23
A 24
D 25
A 26
D 27
A 28
B 29
C 30
C 31
C 32
A 33
C 34
A 35
A 36
B 37
C 38
B 39
D 40
A 41
B 42
B 43
D 44
D 45
C 46
D 47
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Trang 41
S GD&T VNH PHC

thi gm 06 trang
KTCL N THI I HC LN 1 NM HC 2013 2014
Mn: Ha hc; Khi B
Thi gian lm bi: 90 pht, khng k thi gian giao

M thi 357
H, tn th sinh:......................................................................SBD:............................................

Cho bit khi lng nguyn t ca cc nguyn t :
H=1; C=12; N=14; O=16; Na=23; Mg=24; Al=27; S=32; Cl=35,5; K=39; Mn=55; Fe=56; Cu=64; Zn=65; Br=80;
Ag=108; Ba=137; Ca=40.
I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: Cho tng cht: Fe, FeO, Fe(OH)
2
, Fe(OH)
3
, Fe
3
O
4
, Fe
2
O
3
, Fe(NO
3
)
2
, Fe(NO
3
)
3
, FeSO
4
, Fe
2
(SO
4
)
3
, FeCO
3
ln
lt phn ng vi HNO
3
c, nng, d. S phn ng thuc loi phn ng oxi ha kh l
A. 9. B. 7. C. 8. D. 10.
Cu 2: Dung dch X cha NaOH 0,2M, Ba(OH)
2
0,05M; dung dch Y cha Al
2
(SO
4
)
3
0,4M, H
2
SO
4
aM. Trn 10 ml
dung dch Y vi 100 ml dung dch X ta c 1,633 gam kt ta. Gi tr ca a l
A. 0,1 M. B. 0,3 M. C. 0,2 M. D. 0,25 M.
Cu 3: Cho gi tr m in ca cc nguyn t: Mg (1,31); H (2,20); Cl (3,16); C (2,55). Hp cht ion l
A. CCl
4
. B. MgCl
2
. C. CH
4
. D. HCl.
Cu 4: Thm 3,0 gam P
2
O
5
vo 12,5 ml dung dch H
3
PO
4
6,0% (d=1,03 g/ml). Nng phn trm ca H
3
PO
4
trong
dung dch thu c l
A. 30,95%. B. 29,75%. C. 26,09%. D. 35,25%.
Cu 5: t chy hon ton 0,1 mol hn hp X gm CH
4
, C
2
H
4
v C
4
H
10
thu c 0,14 mol CO
2
v 0,23 mol H
2
O. S
mol ca ankan v anken trong hn hp X ln lt l
A. 0,08 mol v 0,02 mol. B. 0,09 mol v 0,01 mol.
C. 0,03 mol v 0,07 mol. D. 0,01 mol v 0,09 mol.
Cu 6: Cho bt Fe vo dung dch NaNO
3
v H
2
SO
4
n phn ng hon thu c dung dch A (khng cha mui
amoni), hn hp kh X gm NO v H
2
v cht rn khng tan. Trong dung dch A cha cc mui
A. FeSO
4
, Fe(NO
3
)
2
, Na
2
SO
4
, NaNO
3
. B. FeSO
4
, Fe(NO
3
)
2
, Na
2
SO
4
.
C. FeSO
4
, Fe
2
(SO
4
)
3
, NaNO
3
, Na
2
SO
4
. D. FeSO
4
, Na
2
SO
4
.
Cu 7: Cho V lt (ktc) hn hp kh X gm C
2
H
2
v H
2
i qua ng cha xc tc Ni, un nng thu c hn hp gm 3
hirocacbon c t khi so vi H
2
bng 13,5. Phn trm th tch kh C
2
H
2
trong X l
A. 40%. B. 66,67%. C. 33,33%. D. 60%.
Cu 8: Cho hp cht hu c X tc dng vi dung dch AgNO
3
/NH
3
(d) thu c sn phm Y. Cho Y tc dng vi
dung dch HCl hoc dung dch NaOH u sinh ra cht kh v c. X l
A. CH
3
COONH
4
. B. C
2
H
2
. C. CH
3
CHO. D. HCOONH
4
.
Cu 9: Hn hp bt X gm BaCO
3
, Fe(OH)
2
, Al(OH)
3
, CuO, MgCO
3
. Nung X trong khng kh n khi lng khng
i c hn hp rn Y. Cho Y vo nc d, khuy u c dung dch Z cha 2 cht tan v phn khng tan T. Cho
kh CO d qua bnh cha T nung nng c hn hp rn E. Cc phn ng xy ra hon ton. E cha ti a
A. 3 n cht. B. 2 n cht v 1 hp cht.
C. 1 n cht v 2 hp cht. D. 2 n cht v 2 hp cht.
Cu 10: Cho cc cn bng sau:
(1) 2HI (k)
H
2
(k) + I
2
(k)
(2) CaCO
3
(r)
CaO (r) + CO
2
(k)
(3) FeO (r) + CO (k)
Fe (r) + CO
2
(k)
(4) 2SO
2
(k) + O
2
(k)
2SO
3
(k)
Khi gim p sut ca cc h cn bng trn, s cn bng b chuyn dch theo chiu nghch l
A. 2. B. 4. C. 3. D. 1.
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Trang 42
Cu 11: Chia hn hp X gm 2 axit hu c n chc, mch h, l ng ng k tip thnh 3 phn bng nhau.
Phn 1: Tc dng vi dung dch NaHCO
3
d, thu c 2,24 lt kh CO
2
(ktc).
Phn 2: t chy hon ton X thu c 6,272 lt CO
2
(ktc).
Phn 3: Tc dng va vi etylen glycol thu c m gam hn hp 3 este khng cha nhm chc khc. Gi tr ca
m l
A. 9,82. B. 8,47. C. 9,32. D. 8,42.
Cu 12: Cho cc loi t sau: t tm, t visco, t nilon-6,6, t xenluloz axetat, t capron. Nhng t thuc loi t bn
tng hp l
A. t tm v t capron. B. t nilon-6,6 v t capron.
C. t visco v t xenluloz axetat. D. t nilon-6,6 v t visco.
Cu 13: Hn hp kh X gm clo v oxi. X phn ng va ht vi 10,5 gam hn hp gm Mg v Al (t l mol tng ng
l 1:3) to ra 27,55 gam hn hp cc mui clorua v oxit. Thnh phn % theo s mol ca cc kh trong X l
A. 25% v 75%. B. 62,46% v 37,54%. C. 42,86% v 57,14%. D. 40% v 60%.
Cu 14: Cho cc cht sau: (1) NH
3
; (2) CH
3
NH
2
; (3) (CH
3
)
2
NH; (4) C
6
H
5
NH
2
; (5) (C
6
H
5
)
2
NH. Th t tng dn tnh
baz ca cc cht trn l
A. (1) < (4) < (5) < (2) < (3). B. (5) < (4) < (1) < (2) < (3).
C. (4) < (5) < (1) < (2) < (3). D. (1) < (5) < (2) < (3) < (4).
Cu 15: Dn mt lung kh CO d qua ng s ng m gam hn hp Fe
3
O
4
v CuO nung nng n khi phn ng hon
ton thu c 2,32 gam hn hp kim loi. Kh thot ra khi bnh c dn qua dung dch nc vi trong d, thu c
5 gam kt ta. Gi tr ca m l
A. 5,32. B. 3,12. C. 4,56. D. 6,24.
Cu 16: Hp cht khng ha tan c Cu(OH)
2
l
A. etylen glicol. B. propan-1,2-iol. C. glixerol. D. propan-1,3-iol.
Cu 17: Tng s ht proton, ntron, electron trong 2 nguyn t kim loi A v B l 142, trong tng s ht mang
in nhiu hn tng s ht khng mang in l 42. S ht mang in ca nguyn t B nhiu hn ca A l 12. Hai kim
loi A v B ln lt l
A. Al, Zn. B. Na, Mg. C. K, Cu. D. Ca, Fe.
Cu 18: t chy hon ton m gam hn hp X gm 2 este ng phn cn dng 4,704 lt kh O
2
, thu c 4,032 lt kh
CO
2
v 3,24 gam H
2
O. Nu cho m gam X tc dng ht vi 110 ml dung dch KOH 1M. C cn dung dch sau phn ng
th thu c 7,98 gam cht rn khan, trong c a mol mui Y v b mol mui Z (M
Y
> M
Z
). Cc th tch kh u o
ktc. T l a : b l
A. 3 : 2. B. 2 : 3. C. 2 : 1. D. 1 : 5.
Cu 19: Cho hn hp X gm 0,05 mol CaCl
2
; 0,03 mol KHCO
3
; 0,05 mol NaHCO
3
; 0,04 mol Na
2
O; 0,03 mol
Ba(NO
3
)
2
vo 437,85 gam nc. Sau khi phn ng xy ra hon ton thu c kt ta Z v m gam dung dch Y. Gi tr
ca m l
A. 420. B. 450. C. 440. D. 400.
Cu 20: Nhng mt thanh Mg vo 200 ml dung dch ( )
3
3
Fe NO 1M, sau mt thi gian ly thanh kim loi ra cn li
thy khi lng tng 0,8 gam. Khi lng Mg tan vo dung dch l
Cu 21: X gm lysin (axit 2,6-iaminohexanoic) v axit glutamic (axit 2-aminopentanioic). Cho X tc dng vi dung
dch HCl (va ) thu c 5,12 gam mui. Cng lng X trn, khi tc dng vi dung dch KOH (va ), thu c
4,99 gam mui. Phn trm khi lng lysin c trong hn hp ban u l
A. 59,84%. B. 60,16%. C. 40,16%. D. 39,84%.
Cu 22: Cho 0,92 gam mt hn hp gm C
2
H
2
v CH
3
CHO tc dng va vi dung dch AgNO
3
trong NH
3
thu
c 5,64 gam hn hp rn. Phn trm khi lng ca C
2
H
2
v CH
3
CHO trong hn hp tng ng l
A. 26,74% v 73,26%. B. 27,95% v 72,05%. C. 25,73% v 74,27%. D. 28,26% v 71,74%.
Cu 23: Cho m gam hn hp Mg, Al, Zn tc dng vi 0,448 lt Cl
2
(ktc), sau phn ng xy ra hon ton thu c cht
rn X. Cho X tc dng vi dung dch axit HCl d thu c dung dch Y v 0,672 lt H
2
(ktc). Lm kh dung dch Y
thu c 4,98 gam cht rn khan. Gi tr ca m l
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Trang 43
A. 2,14. B. 1,43. C. 2,86. D. 3,12.
Cu 24: Cho cc cht sau: axetilen, etilen, but-1-in, axit fomic, fomanehit, phenyl fomat, axit axetic, glucoz, anehit
axetic, metyl axetat, natri fomat, axeton. S cht c th tham gia phn ng trng bc l
A. 6 B. 9 C. 8 D. 7
(a) Ngi ta thng ng axit flohiric trong cc l bng thy tinh.
(b) Tnh axit ca cc dung dch axit halogenhiric tng dn t HF n HI.
(c) Cc mui bc halogenua u kt ta nn ngi ta thng dng dung dch AgNO
3
phn bit dung dch c
cha anion halogenua.
(d) Trong cng nghip, ngi ta iu ch flo bng cch in phn hn hp KF v HF nng chy.
(e) Flo l phi kim mnh nht.
Trong cc pht biu trn, s pht biu ng l
A. 4. B. 2. C. 1. D. 3.
Cu 26: Este no sau y tc dng vi dung dch NaOH d cho 2 mui?
A. phenyl axetat. B. vinyl benzoat. C. vinyl fomat. D. etyl metyl oxalat.
Cu 27: Cho cc tnh cht sau: (1) khng lm i mu giy qu tm m; (2) tham gia phn ng trng bc; (3) lm mt
mu dung dch nc brom; (4) oxi ho hiro; (5) c nhit si thp hn ancol etylic. Cht tho mn c 5 tnh cht
trn l
A. HCOOCH
3
. B. H
2
NCH
2
COOH. C. CH
3
CHO. D. CH
2
=CHCOOH.
Cu 28: Hn hp X gm Na, K, Ba. Ha tan hon ton hn hp X vo nc thu c dung dch Y v 2,688 lt (ktc)
kh H
2
. trung ha ht dung dch Y cn dng V ml dung dich HCl 1M. Gi tr ca V l
A. 150. B. 120. C. 240. D. 300.
Cu 29: Cho cc phn ng: AgNO
3
+ Fe(NO
3
)
2
Ag + Fe(NO
3
)
3
v Fe + 2HCl FeCl
2
+ H
2
. Dy cc ion c sp
xp theo chiu gim dn tnh oxi ho l
A. Ag
+
; Fe
3+
; H
+
; Fe
2+
. B. Fe
2+
; H
+
; Fe
3+
; Ag
+
. C. Fe
2+
; H
+
; Ag
+
; Fe
3+
. D. Fe
2+
; Fe
3+
; H
+
; Ag
+
.
Cu 30: t chy hon ton 5,80 gam cht X thu c 2,65 gam Na
2
CO
3
; 2,25 gam H
2
O v 12,10 gam CO
2
. Cng
thc phn t ca X l
A. C
7
H
7
O
2
Na. B. C
6
H
5
O
2
Na. C. C
6
H
5
ONa. D. C
7
H
7
ONa.
Cu 31: Cho 9,55 gam hn hp gm Mg, Al v Zn tc dng va vi 870 ml dung dch HNO
3
1M, thu c dung
dch cha m gam mui v 0,06 mol hn hp kh X gm N
2
v N
2
O, t khi ca X so vi H
2
bng 20,667. Gi tr ca m
l
A. 40,55. B. 54,95. C. 42,95. D. 42,55.
Cu 32: C 5 dung dch long ca cc mui: BaCl
2
, CuCl
2
, ZnCl
2
, FeCl
2
, FeCl
3
. Khi sc kh H
2
S d vo cc dung dch
mi mui trn th s trng hp c phn ng to kt ta l
A. 3. B. 1. C. 2. D. 4.
Cu 33: Hn hp X gm tinh bt v glucoz. Chia hn hp X thnh 2 phn bng nhau.
Phn 1: Cho phn ng ht vi dung dch AgNO
3
/NH
3
d thu c 21,6 gam bc.
Phn 2: un nng vi H
2
SO
4
long, sau trung ho bng NaOH (va ), ri cho phn ng ht vi dung dch
AgNO
3
/NH
3
d thu c 32,4 gam bc.
Phn trm khi lng glucoz c trong A l
A. 66,78%. B. 68,97%. C. 69,98%. D. 67,45%.
Cu 34: Cho cc phn ng:
(1) Zn + HCl (4) Fe
2
O
3
+ HNO
3

(2) MnO
2
+ HCl (c) (5) C + H
2
SO
4
(c)
(3) Fe + H
2
SO
4
(long) (6) FeO + HCl
Cc phn ng trong axit ng vai tr cht oxi ha l
A. (1), (3), (5). B. (1),(2),(3),(5),(6). C. (1), (3), (4). D. (1),(2),(4),(6).
Cu 35: Cht M c cng thc phn t l C
3
H
12
N
2
O
3
. Cht Q c cng thc phn t l CH
8
N
2
O
3
. Cho M, Q ln lt
phn ng vi dung dch HCl cng cho ra mt kh Z. Mt khc khi cho M, Q tc dng vi dung dch NaOH th M cho
kh X cn Q cho kh Y. Pht biu ng l
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A. X, Y, Z phn ng c vi dung dch NaOH.
B. M
Z
>M
Y
>M
X
.
C. X, Y lm qu m ha xanh.
D. Z va phn ng c vi NaOH va phn ng c vi HCl.
Cu 36: Cho vi git cht lng X tinh khit vo ng nghim c sn 2 ml nc, lc u sau yn mt thi gian
thy xut hin cht lng phn thnh hai lp. Cho 1,0 ml dung dch HCl vo v lc mnh th thu c mt dung dch
ng nht. Cho tip vi ml dung dch NaOH vo lc, sau yn li thy xut hin cht lng phn thnh hai lp. X l
A. benzen. B. phenol lng. C. lng trng trng. D. anilin.
Cu 37: Ha tan hon ton m gam hn hp gm Na, Na
2
O, NaOH v Na
2
CO
3
trong dung dch axt H
2
SO
4
40% (va
) thu c 8,96 lt (ktc) hn hp kh c t khi i vi H
2
bng 16,75 v dung dch Y c nng 51,449%. C
cn Y thu c 170,4 gam mui. Gi tr ca m l
A. 37,2. B. 23,8. C. 50,4. D. 50,6.
Cu 38: Cho 0,5 mol mt anehit mch h X phn ng vi lng d dung dch AgNO
3
trong NH
3
thu c 108 gam
Ag. Mt khc, kh hon ton 0,25 mol X th cn 0,5 mol H
2
. Cht X c cng thc chung l
A. C
n
H
2n
(CHO)
2
(n>0). B. C
n
H
2n+1
CHO (n>0). C. C
n
H
2n-3
CHO (n>2). D. C
n
H
2n-1
CHO (n>2).
Cu 39: Cch nhn bit no sau y l khng chnh xc?
A. nhn bit CO v CO
2
ta dng nc vi trong.
B. nhn bit kh NH
3
v kh CH
3
NH
2
ta dng axit HCl c.
C. nhn bit SO
2
v SO
3
ta dng dung dch nc brom.
D. nhn bit O
2
v O
3
ta dng dung dch KI c ln h tinh bt.
Cu 40: Ho tan a mol Fe
3
O
4
bng dung dch H
2
SO
4
long, va , thu c dung dch X. in phn X vi in cc
tr, c mng ngn, bng dng in c cng 9,65 (A). Sau 1000 giy th kt thc in phn v khi trn catot bt
u thot ra bt kh. Gi tr ca a l
A. 0,0125 mol. B. 0,025 mol. C. 0,075 mol. D. 0,050 mol.

II. PHN RING (10 cu). Th sinh ch c lm mt trong hai phn (phn A hoc B).
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)

Cu 41: Dung dch X cha 0,1 mol Mg
2+
; 0,1 mol Ca
2+
; 0,1 mol Cl
-
v x mol HCO
3
-
lm kh dung dch X bng cch
un nng thu c m gam cht rn khan. Gi tr ca m l
A. 18,95. B. 25,28. C. 15,98. D. 28,25.
Cu 42: un nng 16,6 gam hn hp X gm 3 ancol no, n chc vi H
2
SO
4
c 140
o
C thu c 13,9 gam hn hp
6 ete c s mol bng nhau. Mt khc, un nng X vi H
2
SO
4
c 170
0
C thu c sn phm ch gm 2 olefin v nc.
Cc phn ng xy ra hon ton. Tn gi ca 3 ancol l
A. metanol, etanol v propan-1-ol. B. propan-1-ol, butan-1-ol v propan-2-ol.
C. etanol, propan-2-ol v propan-1-ol. D. metanol, butan-1-ol v butan-2-ol.
Cu 43: Xt cc cht: imetylete (1), ancol metylic (2), ancol etylic (3), axit axetic (4), axeton (5).
Cc cht trn c xp theo nhit si tng dn (t tri sang phi) l
A. 2, 3, 4, 5, 1 B. 1, 2, 3, 4, 5 C. 1, 5, 2, 3, 4 D. 1, 5, 3, 2, 4
Cu 44: Trong s cc cht sau: H
2
S, Cl
2
, H
2
SO
3
, NaHCO
3
, C
6
H
12
O
6
(glucoz), Ca(OH)
2
, HF, NaClO, C
6
H
6
. S cht in li l
A. 7. B. 9. C. 8. D. 6.
Cu 45: nhn bit cc dung dch ring bit, khng mu: NH
3
, NaOH, BaCl
2
, NaCl, cn chn thuc th l
A. H
2
SO
4
. B. FeCl
3
. C. CuSO
4
. D. AgNO
3
.
Cu 46: Dung dch X cha ng thi 0,02 mol Cu(NO
3
)
2
v 0,1 mol H
2
SO
4
. tc dng ht vi dung dch X cn ti
a m gam Fe (bit sn phm kh ca NO
3
-
l kh NO duy nht). Gi tr ca m l
A. 3,36. B. 4,48. C. 5,6. D. 2,24.
Cu 47: Tripeptit X v pentapeptit Y u c to ra t aminoaxit X no, mch h, c 1 nhm amino v 1 nhm
cacboxyl. t chy hon ton 0,01 mol X ri cho sn phm chy vo bnh ng dung dch nc vi trong d thy to
thnh 6 gam kt ta. Nu t chy hon ton 0,02 mol Y th thu c N
2
v m gam hn hp CO
2
v H
2
O. Gi tr ca m
l
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Trang 45
A. 5,93. B. 6,65. C. 11,86. D. 13,3.
Cu 48: S ng phn (k c ng phn hnh hc) ng vi cng thc phn t C
4
H
8
l
A. 3. B. 6. C. 5. D. 4.
Cu 49: Cho axit hu c X tho mn iu kin sau: a gam X tc dng vi NaHCO
3
d thu c V lt (ktc) kh CO
2
.
t chy hon ton a gam X thu c V lt (ktc) kh CO
2
. X l
A. axit fomic hoc axit oxalic. B. axit oxalic hoc axit aipic.
C. axit axetic hoc axit stearic. D. axit fomic hoc axit axetic.
Cu 50: T nhng cht sau: Ag, S, C, K
2
SO
3
, FeS, O
2
, H
2
SO
4
c. Cho cc cht phn ng vi nhau tng i mt. S
phng trnh phn ng to ra lu hunh ioxit l
A. 7. B. 5. C. 6. D. 8.

B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)

Cu 51: Cho 300 ml dung dch AgNO
3
vo 200ml dung dch Fe(NO
3
)
2
sau khi phn ng kt thc thu uc 19,44 gam
cht rn v dung dch X trong s mol Fe(NO
3
)
3
gp ba ln s mol Fe(NO
3
)
2
cn d. Dung dch X c th tc dng ti
a vi m gam hn hp bt kim loi gm Al v Mg c t l mol n
Al
: n
Mg
=1:3. Gi tr ca m l
A. 7,26. B. 11,88. C. 5,94. D. 8,91.
Cu 52: in phn dung dch hn hp gm HCl, NaCl, CuCl
2
, FeCl
3
. Th t nhn electron trn catot l
A. Fe
3+
Cu
2+
H
+
Fe
2+
H
2
O. B. Fe
3+
Cu
2+
H
+
Na
+
H
2
O.
C. Cu
2+
Fe
3+
Fe
2+
H
+
H
2
O. D. Cu
2+
Fe
3+
H
+
Na
+
H
2
O.
Cu 53: ng vi cng thc C
4
H
y
s cht tc dng vi dung dch AgNO
3
/NH
3
to kt ta mu vng l
A. 1. B. 2. C. 3. D. 4.
Cu 54: Th t tng dn mc linh ng ca nguyn t H trong nhm -OH ca cc hp cht: phenol, etanol, nc l
A. Nc < phenol < etanol. B. Etanol < phenol < nc.
C. Etanol < nc < phenol. D. Phenol < nc < etanol.
Cu 55: Cc cht u b thy phn trong dung dch NaOH long, nng l
A. Nilon-6,6, tinh bt, saccaroz, t visco, anlyl clorua, poliacrilonitrin, phenyl bromua.
B. Phenyl clorua, glyxylalanin, poli(etylen-terephtalat), poli(vinyl axetat), nilon-6,6.
C. Protein, poli(etylen-terephtalat), poli(vinyl axetat), tinh bt, phenyl bromua.
D. Nilon-6,6, protein, poli(metyl metacrylat), anlyl clorua, vinyl axetat.
Cu 56: C cc dung dch sau: Phenylamoniclorua, axit aminoaxetic, ancol benzylic, metyl axetat, anilin, glyxin,
etylamin, natri axetat, metylamin, alanin, axit glutamic, natri phenolat, lysin. S cht c kh nng lm i mu qu tm
l
A. 6. B. 7. C. 8. D. 5.
(a) Cho dung dch Ba(OH)
2
vo dung dch NaHCO
3
. (b) Sc kh NH
3
ti d vo dung dch FeCl
3
.
(c) Sc kh propilen vo dung dch KMnO
4
(d) Sc kh CO
2
vo dung dch Na
2
SiO
3
.
(e) Sc kh H
2
S vo dung dch SO
2
. (g) Sc kh NH
3
ti d vo dung dch AgNO
3
.

Sau khi cc phn ng kt thc, s th nghim thu c kt ta l
A. 5. B. 6. C. 3. D. 4.
Cu 58: Cho phng trnh ion: Fe
2+
+ H
+
+ MnO
4
-
Fe
3+
+ Mn
2+
+ H
2
O. Tng h s nguyn ti gin ca
phng trnh ion ny l
A. 20. B. 24. C. 26. D. 30.
Cu 59: Hn hp A gm 0,1 mol propenal (anehit acrylic) v 0,3 mol kh hiro. Cho hn hp A qua ng s nung
nng c cha Ni lm xc tc, thu c hn hp B gm bn cht gm: propanal, propan-1-ol, propenal v hiro. T khi
hi ca hn hp B so vi metan bng 1,55. S mol H
2
trong hn hp B l
A. 0,15. B. 0,10. C. 0,05. D. 0,20.
Cu 60: Xt phn ng phn hy N
2
O
5
trong dung mi CCl
4
45
0
C: 2N
2
O
5
2N
2
O
4
+ O
2
. Ban u nng ca N
2
O
5

l 2,33M, sau 184 giy nng ca N
2
O
5
l 2,08M. Tc trung bnh ca phn ng tnh theo N
2
O
5
l
A. 2,72.10
-3
mol/(l.s). B. 6,80.10
-4
mol/(l.s). C. 6,80.10
-3
mol/(l.s). D. 1,36.10
-3
mol/(l.s).
H

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Trang 46
Cu 357
1 B 31 B
2 C 32 C
3 B 33 B
4 A 34 A
5 B 35 C
6 D 36 D
7 B 37 D
8 D 38 D
9 B 39 B
10 D 40 A
11 D 41 A
12 C 42 C
13 C 43 C
14 B 44 D
15 B 45 C
16 D 46 C
17 D 47 C
18 D 48 B
19 B 49 A
20 A 50 A
21 A 51 A
22 D 52 A
23 B 53 C
24 A 54 C
25 D 55 D
26 A 56 B
27 C 57 A
28 C 58 B
29 A 59 A
30 C 60 D

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v nguyn t Z u c cu hnh electron 1s

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