14 Mn: Ha hc - Lp 8

Thi gian lm bi: 120 pht (Khng k thi gian giao )

H!"H TH#
Bi 1: (2,5 im)
H$n thnh c%c ph&'ng t()nh ph*n +ng ,a-:
1. ./
2
0
1
2 0
2. 3g"0
1
2 3l 3l4"0
1
5
1
2 6
3. Hl 2 a0
1
al
2
2 H
2
0 2 6
4.
7
H
10
2 0
2
0
2
2 H
2
0
5. "a0H 2 ./
2
480
7
5
1
./40H5
1
2 "a
2
80
7
9
6. ./8
2
2 0
2
./
2
0
1
2 80
2

7. :0H 2 3l
2
480
7
5
1
:
2
80
7
2 3l40H5
1

8. H
7
2 0
2
2 H
2
0 0
2
2 H
2

9. 3l 2 ./
1
0
7
3l
2
0
1
2 ./
10. ./
;
0
<
2 0 ./0 2 0
2

Bi 2: (2,5 im)
=t c>c 3 ?@ng A-ng ABch Hl C c>c D ?@ng A-ng ABch H
2
80
7
l$Eng C$ 2 ?Fa cGn ,a$ ch$
cGn H CB t(I cGn bJng9 8a- ? lm thI nghiKm nh& ,a-:
- h$ 11L2g ./ C$ c>c ?@ng A-ng ABch Hl9
- h$ m gam 3l C$ c>c ?@ng A-ng ABch H
2
80
7
9
:hi c* ./ C 3l ?M- tan h$n t$n thN< cGn H CB t(I thOng bJng9 TInh mP
Bi 3: (2,5 im)
h$ l-Qng RhI hi?($ ?i S-a >ng th-T tinh ch+a 20 g bUt ?Qng 4VV5 $;it H 700
0
9 8a- ph*n
+ng th- ?&Wc 1XL8 g chNt (Yn9
a5 "Z- hiKn t&Wng ph*n +ng ;*< (a9
b5 TInh th[ tIch RhI hi?($ tham gia ph*n +ng t(Zn H ?Rtc9
Bi 4: (2,5 im)
Th@c hiKn n-ng a gam :l0
1
C b gam :Mn0
7
?[ th- RhI ;i9 8a- Rhi ph*n +ng ;*< (a
h$n t$n th) thN< Rh>i l&Wng c%c chNt c\n l]i ,a- ph*n +ng bJng nha-9
a9 TInh tT lK
b
a
9
b9 TInh tT lK th[ tIch RhI ;i t]$ thnh c^a hai ph*n +ng9
HNG DN CHM 14
Bi 1: (2,5 im)
H$n thnh c%c ph&'ng t()nh ph*n +ng ,a-:
1. ./
2
0
1
2 10 2./ 2 10
2
2. 13g"0
1
2 3l 3l4"0
1
5
1
2 13g
3. 2Hl 2 a0
1
al
2
2 H
2
0 2 0
2
4. 2
7
H
10
2 110
2
80
2
2 10H
2
0
5. X"a0H 2 ./
2
480
7
5
1
2./40H5
1
2 1"a
2
80
7
9
6. 7./8
2
2 110
2
2./
2
0
1
2 8 80
2

7. X:0H 2 3l
2
480
7
5
1
1:
2
80
7
2 23l40H5
1

8. 2H
7
2 0
2
2 2H
2
0 20
2
2 XH
2

9. 83l 2 1./
1
0
7
73l
2
0
1
2_./
10. ./
;
0
<
2 4<-;50 ;./0 2 4<-;50
2

(Hon thnh mi phng trnh cho 0,25 im)
Bi 2: (2,5 im)
- n
./
`
aX
2 L 11
` 0L2 m$l
n
3l
`
2b
m
m$l
0L2a
- :hi thZm ./ C$ c>c ?@ng AA Hl 4c>c 35 c ph*n +ng:
./ 2 2Hl ./l
2
2H
2

0L2 0L2
0L2a
- Th/$ ?Bnh l-ct b*$ t$n Rh>i l&WngL Rh>i l&Wng c>c ?@ng Hl tOng thZm:
11L2 - 40L2925 ` 10L8g
0Lba
- :hi thZm 3l C$ c>c ?@ng AA H
2
80
7
c

ph*n +ng:
23l 2 1 H
2
80
7
3l
2
480
7
5
1
2 1H
2

2b
m
m$l
2 9 2b
9 1 m
m$l
0L2a
- :hi ch$ m gam 3l C$ c>c DL c>c D tOng thZm m -
2 9
2 9 2b
9 1 m
0La0
- [ cGn thOng bJngL Rh>i l&Wng H c>c ?@ng H
2
80
7
cdng ph*i tOng thZm
10L8g9 : m -
2 9
2 9 2b
9 1 m
` 10L8
0L2a
- ei*i ?&Wc m ` 4g5 0L2a
Bi 3: (2,5 im)
fTfg: -0 2 H
2

700
0
- 2 H
2
0 0L2a
"h- ph*n +ng ;*< (a h$n t$nL l&Wng - th- ?&Wc
g 1X
80
X7 9 20
=
0L2a
1XL8 i 1X `i -0 A&9 0L2a
HiKn t&Wng fg: hNt (Yn A]ng bUt -0 c m- ?/n Ajn Ajn ch-<[n ,ang m- ?k 4ch&a
h$n t$n59
0L2a
=t ; l ,> m$l -0 fgL ta c m
l ,a- fg
` m
-
2 m
-0 c\n A&

` m
-
2 4m
-0 ban ?j-
m m
-0 fg
5 0La0
X7; 2 420-80;5 `1XL8 1X; ` 1L2 ;` 0L29 0La0
n
H2
` n
-0
` ;` 0L2 m$l9 nc<: n
H2
` 0L2922L7` 7L78 lIt 0La0
Bi 4: (2,5 im)
2:l0
1
2:l 2 10
2

a L 122
a

5 b7La 4
a L 122
a
2
7 L 22 9
2
1a
0La0
2:Mn0
7
:
2
Mn0
7
2 Mn0
2
2 0
2


1a8
b

1_b
1a8 9 2
b
2
8b
1a8 9 2
b
2
7 L 22 9
2
b
0La0

8b
1a8 9 2
1_b
1a8 9 2
b7La
a L 122
b b a
+ =
0La0

b8 L 1
a L b7 9 1a8 9 2
5 8b 1_b 4 a L 122

+
=
b
a
0La0

7971 1 7 L 22 9
2
: 7 L 22 9
2
1
=
b
a b a
0La0
1a Mn: Ho hc m lp 89
Thi gian lm bi: 90 pht
Bi 1: 1) h$ c%c fTHH ,a- fTHH n$ ?ngL fTHH n$ ,aiP n) ,a$P
a5 2 3l 2 X Hl 2 3ll
1
2 1H
2
o
b5 2 ./ 2 X Hl 2 ./l
1
2 1H
2

c5 - 2 2 Hl -l
2
2 H
2
o
A5 H
7
2 2 0
2
80
2
2 2 H
2
0
2) hn cG- ph%t bi[- ?ng C ch$ CI Ap:
a5 0;it a;it th&ng l $;it c^a phi Rim C t&'ng +ng Ci mUt a;it9
b5 0;it a;it l $;it c^a phi Rim C t&'ng +ng Ci mUt a;it9
c5 0;it baq' th&ng l $;it c^a Rim l$]i C t&'ng +ng Ci mUt baq'9
A5 0;it baq' l $;it c^a Rim l$]i C t&'ng +ng Ci mUt baq'9
3) H$n thnh c%c fTHH ,a-:
a5
7
H
_
0H 2 0
2
0
2
2 H
2
0 o
b5
n
H
2n - 2
2 P 0
2
2 H
2
0
c5 :Mn0
7
2 P :l 2 Mnl
2
2 l
2
2 H
2
0
A5 3l 2 H
2
80
7
4?=cL nng5 3l
2
480
7
5
1
2 80
2
2 H
2
0
Bi 2: TInh ,> m$l ng-<Zn tr C ,> m$l phGn tr $;i c t($ng 1XL0 g RhI ,-ns-(ic9
(gi s ! ng"#$n t o%i t&ong kh' s"n("&i t!h &a ) li$n k*t )+i nha" t,o thnh ! ph-n t
o%i)9
Bi 3: >t ch%< h$n t$n RhI 3 cjn Atng hht 8L_X Am
1
RhI $;i th- ?&Wc 7L78 Am
1
RhI 0
2
C
bL2g h'i n&c9
a5 3 A$ nhung ng-<Zn t> n$ t]$ nZnP TInh Rh>i l&Wng 3 ?E ph*n +ng9
b5 Diht tT Rh>i c^a 3 ,$ Ci hi?($ l 89 HE< ;%c ?Bnh cng th+c phGn tr c^a 3 C gi tZn 39
Bi 4: h$ l-Qng RhI hi?($ ?i S-a >ng th-T tinh ch+a 20 g bUt ?Qng4VV5 $;it H 700
0
9 8a- ph*n
+ng th- ?&Wc 1XL8 g chNt (Yn9
a5 "Z- hiKn t&Wng ph*n +ng ;*< (a9
b5 TInh hiK- ,-Nt ph*n +ng9
c5 TInh ,> lIt RhI hi?($ ?E tham gia Rhr ?Qng4VV5 $;it t(Zn H ?Rtc9
====================== H t =======================
15 p n 15 thi chn HSG d thi cp th|
Mn: Ho hc m lp 89
.h /: i[m c th[ chia nhk chInh ;%c ?hn 0L12a- 0L2a- 0La - 6
Bi p n Thang im
1(3) 1(0
)
a5 ngL C) ?ng tInh chNt 0L12a 2 012a
b5 8aiL C) fg n< Rhng t]$ (a ./l
1
m l ./l
2
ha< l ,ai 1 ,*n phvm
0L12a 2 012a
c5 8aiL C) Rhng c fg ;*< (a 0L12a 2 012a
A5 8aiL C) bihn thnh 8 l Rhng ?ng Ci L
DT:L
0L12a 2 012a
2(0
)
a5 9 nw: 0;it A$ f: t]$ nZn l 80
1
t&'ng +ng Ci
a;it H
2
80
7
0;it A$ :L H t(]ng th%i h$% t(B ca$ t]$ nZn l (0
1
t&'ng +ng Ci a;it H
2
(0
7
0L2a 2 0L2a
A5 9 nw: "a
2
0 t&'ng +ng Ci baq' "a0H
./0 t&'ng +ng Ci baq' ./40H5
2
0L2a 2 0L2a
3(0
)
a5
7
H
_
0H 2 6 0
2
4 0
2
2 5 H
2
0
0L2a
b5 2
n
H
2n - 2
2 (3n - 1) O
2
2n 0
2
2
2(n-1) H
2
0
0L2a
c5 2 :Mn0
7
2 16 HCl 2 :l 2 2 Mnl
2
2
5 l
2
2 8 H
2
0
0L2a
A5 2 3l 2 6 H
2
80
7
(12 n3ng) 3l
2
480
7
5
1

2 3 80
2
2 6 H
2
0
0L2a
2(1) n
801
` 1X: 80 ` 0L2 m$lo n
0
` 0L2 91 ` 0LX m$l9 0L2a 2 0L2a
+ 2 0 liZn Rht Ci nha- t]$ nZn 1 0
2
`i 2 m$l 0 ---------------------------- 1 m$l 0
2

nc<: n
02
` 40LX915: 2 ` 0L1 m$l
0L2a 2 0L2a
3(3) !" H#: c$ % & '(n ) 0,5 * 3 +
x 8' ?Q fg ch%<: 3 2 0
2
0
2
2 H
2
0 o m
0

t($ng 0
2
`
g 8 L 12 1X 59 2 9
7 L 22
_X L 8
4 =
o
x m
0 ,a- fg
` m
0
4t($ng 0
2
2 t($ng H
2
05 `
g 8 L 12 1X 59 1 9
18
2 L b
4 1X 59 2 9
7 L 22
78 L 7
4 = +
a) 8a- ph*n +ng th- ?&Wc 0
2
C H
2
0 `i t(&c fg c c%c
ng-<Zn t> L H C 0 t]$ nZn c%c chNt fg9
Th/$ tInh t$%n t(Zn: tyng m
0 ,a- fg
` 12L8 g ` tyng m
0

t($ng 0
2
9
0La
0La
0La
0La
0La
nc< 3 Rhng ch+a 0 m chz A$ 2 ng-<Zn t> l C H
t]$ nZn9
m
3

?E fg
` m

2 m
H
`
g 2 L 1 1 59 2 9
18
2 L b
4 12 59 1 9
7 L 22
78 L 7
4 = +
b5 Ta c: M
3
` 892 ` 1X go =t TfT cjn t)m l
;
H
<
Ci
;L < ng-<Zn A&'ng
M
3
` 12; 2 < ` 1Xg `i ph&'ng t()nh: 12; 2 < ` 1X
4x5
TT lK ;: <` n

: n
H
`
; 7 <
7
1
<
;
ha< 7 : 1 8 L 0 : 2 L 0 5 2 9
18
2 L b
4 : 5 1 9
7 L 22
78 L 7
4 = => = = =
tha< C$
4x5:
12; 2 7; ` 1X ;` 1 `i < ` 79 nc< TfT c^a 3 l
H
7
L tZn gi l m/tan9
0La
4(3) fTfg: -0 2 H
2

700
0
- 2 H
2
0 o
a5 HiKn t&Wng fg: hNt (Yn A]ng bUt -0 c m- ?/n Ajn
Ajn bihn thnh m- ?k4-5
0La
0La
b5 m ei* ,r 20 g -0 fg hht th) ,a- fg ,{ th- ?&Wc
g 1X
80
X7 9 20
=
chNt (Yn A-< nhNt 4-5 | 1XL8 g chNt (Yn th-
?&Wc th4o 5" bi `i -0 ph*i c\n A&9
- =t ; l ,> m$l -0 fgL ta c m
l ,a- fg
` m
-
2 m
-0 c\n A&
`
;9X7 2 4m
-0 ban ?j-
m m
-0 fg
5
` X7; 2 420 m 80;5
` 1XL8 g9
`i fh&'ng t()nh: X7; 2 420-80;5 `1XL8 1X; ` 1L2 ;`
0L29 `i m
-0 fg
` 0L2980` 1X g
Vy H ` 41X9100}5:20` 80}9
0La
0La
0La
c5 Th/$ fTfg: n
H2
` n
-0
` ;` 0L2 m$l9 nc<: n
H2
` 0L2922L7`
7L78 lIt
0La
E 16
KHAO SAT CHAT LONG HOC SINH GIOI 8
NM HOC 2008 - 2009
Mn: Hoa hoc
(Th67i gian la7m ba7i: 080 ph"9t)
Bai 1.
a5 Ti~nh ,~ m$l c-a 11 gam n Ca ?$~ la Rh~i l&'ng c-a ba$ nhiZ- ng-<Zn t& nP
b5 fhai lG~ < ba$ nhiZ- gam - ?Z c$~ ,~ ng-<Zn t& ?-~ng bOng ng-<Zn t& n ' t(ZnP
Bai 2.
a5 niZ~t ph&'ng t(inh phan &~ng h$an thanh ,' ? ch-<Zn h$~a ,a-P
1 2 3 4 5 6 7
3 4 2 2 3 2 4 4
Fe Fe O H O O SO2 SO H SO ZnSO

./80
7
b5 $~ a chG~t (O~n ma- t(O~ng la a01L a0L f20aL "al Ca "a20 9 Ha < t(inh ba < ph&'ng pha~p
h$~a h$c ?Z phGn biZt ca~c chG~t t(Zn9 niZ~t ph&'ng t(inh phan &~ng 4nZ~- c$~ 5P
Bai 3.
Ti~nh ti lZ thZ ti~ch A-ng Aich Hl 18L2a} 4w ` 1L2 gml5 Ca thZ ti~ch A-ng Aich Hl 11} 4w `
1L121 gml5 ?Z pha thanh A-ng Aich Hl 7La M P
Bai 4.
Z ?~ t cha~< h$an t$an 0LXb2 gam Rim l$ai l chi cGn A-ng 80} l&'ng $;i ,inh (a Rhi phGn h-<
aLa1 gam :Mn0
7
9 Ha < ;a~c ?inh Rim l$ai lP
Bai 5.
Mt hn h'p gm n Ca ./ c$~ Rh~i l&'ng la 1bL2 gam 9 H$a tan hn h'p na < t($ng 2 li~t A-ng
Aich H
2
80
7
0LaM
a5 h&~ng t$ (Ong hn h'p na< tan hZ~t P
b5 "Z~- A-ng mt l&'ng hn h'p n Ca ./ gG~p ?i t(&'ng h'p t(&'~cL l&'ng H
2
80
7
CGn nh& c- thi
hn h'p m'~i na< c$~ tan hZ~t ha< RhngP
c5 T($ng t(&'ng h'p 4a5 ha< ti~nh Rh~i l&'ng mi Rim l$ai t($ng hn h'p biZ~t (Ong l&'ng H
2
,inh
(a t($ng phan &~ng C&a ?- ta~c A-ng C'~i 78 gam -0P
--------------------- HZ~t ---------------------
BIU IM VA HONG DA N CHAM 16
Mn: Hoa hoc
Dai 1: 42 ?iZm5
a5 1 ?iZm 9
Ta c$~ : ( )
Zn
13
n 0,2 mol
65
= = (0,5 im)
8~ ng-<Zn t& n ` 0L2 9 X910
21
` 1L2910
21
40La ?iZm5
b5 1 ?iZm
8~ ng-<Zn t& - ` ,~ ng-<Zn t& n ` 1L2910
21
40L2a ?iZm5

23
23 Cu
1,2.10
n 0,2 (mol)
6.10
= = 40La ?iZm5
m- ` 0L2 9 X7 ` 12L8 gam 40L2a ?iZm5
Dai 2: 4XLa ?iZm5
a5 1 ?iZm
19
o
t
2 3 4
3Fe 2O Fe O +
29
o
t
3 4 2 2
Fe O 4H 3Fe 4H O + +
19
dien!"n
2 2 2
2H O 2H O +
79
o
t
2 2
S O SO +
a9
o
2 5
t ,# O
2 2 3
SO O SO +
8
_
X9 80
1
2 H
2
0 H
2
80
7
b9 n 2 H
2
80
7
n80
7
2 H
2
89 ./ 2 H
2
80
7
./80
7
2 H
2
_9 ./80
7
2 n n80
7
2 ./
- niZ~t ?-~ng L ?- ?iZ- RiZn L cGn bOng ?-~ng ca~c ph&'ng t(inh 1,3,4,6,7,8 mi ph&'ng t(inh
?&'c 0,25 im L c$n fTfg 2,5,9 mi ph&'ng t(inh ?&'c 0,5 im
- "Z~- thiZ~- ?iZ- RiZn h$Oc cGn bOng ,ai thi Rhng ch$ ?iZm
b5 1La ?i[m
- LN< ljn l&Wt a chNt (Yn ch$ C$ a >ng nghiKm c ?@ng n&c cNt (Qi lYc ?M- (0,25im)
2 "h- chNt n$ Rhng tan t($ng n&c a0
1
(0,25 im)
2 7 chNt c\n l]i ?M- tan t($ng n&c t]$ thnh A-ng ABch9
- wtng 7 mv- giN< S- tIm nhng ljn l&Wt C$ 7 >ng nghiKm (0,25 im)
2 "h- >ng nghiKm n$ lm S- tIm ch-<[n ,ang m- ?k c ?@ng f
2
0
a
(0,25im)
f
2
0
a
2 H
2
0 H
1
f0
7
(0,25 im)
2 "h- >ng nghiKm n$ lm ch$ S- tIm ch-<[n ,ang m- ;anh l hai >ng nghiKm c
?@ng a0 C "a
2
0 (0,25 im)
a0 2 H
2
0 a40H5
2
(0,25 im)
"a
2
0 2 H
2
0 "a0H (0,25 im)
2 \n l]i Rhng lm S- tIm Ah-<[n m- >ng nghiKm c ?@ng "al (0,25 im)
- wn ljn l&Wt RhI 0
2
?i S-a 2 A-ng ABch lm S- tIm ch-<[n ;anh (0,25 im)
2 "h- >ng nghiKm n$ bB Cvn ?pc l A-ng ABch a40H5
2
ha< chInh l a0(0,25im)
a40H5
2
2 0
2
a0
1
2 H
2
0 (0,25 im)
2 \n l]i l A-ng ABch "a0H ha< chInh l "a
2
0 (0,25 im)
2"a0H 2 0
2
"a
2
0
1
2 H
2
0 (0,25 im)
Di 1 : 41 ?i[m5
3wT
$
10%
C C&.
$
=
Ta c:
$
C
c^a A-ng ABch Hl 18L2a} l :
10.1,2
18, 25. 6$
$(1)
36,5
C = = (0,5 im)

$
C
c^a A-ng ABch Hl 11} l :
10.1,123
13. 4$
$(1)
36,5
C = = (0,5 im)
ei n
1
L n
1
L n
2
L n
2
ljn l&Wt l th[ tIch L ,> m$l c^a 2 A-ng ABch XM C 7M (0,25 im)
:hi ?:
n
1
` M
1
9 n
1
` Xn
1
(0,25 im)
n
2
` M
2
9 n
2
` 7n
2
(0,25 im)
:hi pha hai A-ng ABch t(Zn Ci nha- th) ta c
n
AA mi
` n
1
2 n
2
(0,25 im)
n
mi
` n
1
2 n
2
` Xn
1
2 7n
2
(0,25 im)
M M
AAm'I
` 7La M
1 2 1
1 2 2
6# 4# # 1
4,5
# # # 3
+
= =
+
(0,75 im)
Di 7 : 41La ?i[m5
Ta c
( )
4
'$nO
5,53
n 0,035 mol
158
= = (0,25 im)
ftp& :
:Mn0
7

o
t

:
2
Mn0
7
2 Mn0
2
2 0
2
415 (0,25 im)
Th/$ ptp& 415:
2 4
'$nO
O
1 1
n n 0,035 0,0175 (mol)
2 2
= = = (0,25 im)
8> m$l $;i tham gia ph*n +ng l :
2 O
n
p&
` 80} 9 0L01ba ` 0L017 4m$l5 (0,5 im)
ei n l ha t(B c^a l n c th[ nhcn c%c gi% t(B 1L 2L 1 4x5 (0,5 im)
fTfg ?>t ch%< 9
7l 2 n0
2

o
t

2l
2
0
n
425 (0,25 im)
Th/$ ptp& 425
2
O
(
4 4 0,056
n .n .0,014 mol
n n n
= = = (0,25 im)
M Rh>i l&Wng c^a l ?/m ?>t l : m
l
` 0LXb2 gam

(
(
(
m
0,672
$ 12n
0,056
n
n
= = =
4xLx5 (0,5 im)
T 4x5 C 4xx5 ta c b*ng ,a- (0,5 im)
n 1 2 1
M
l
124l$]i5 274nhcn5 1X4l$]i5
nc< l l Rim l$]i c ha t(B VV C c ng-<Zn tr Rh>i l 27 R l Magie: Mg (0,25 im)
Di a: 4a ?i[m5
a5 1La ?i[m
Ta gi* ,r hn hWp chz gQm c ./ 4Rim l$]i c Rh>i l&Wng nhk nhNt t($ng hn hWp5
(0,25 im)

Fe
37,2
n 0,66mol
56
= = (0,25 im)
ftp& : ./ 2 H
2
80
7
./80
7
2 H
2
415 (0,25 im)
Th/$ ptp& 415 :
2 4
H SO
Fe
n n 0,66 (mol ) = =
M th/$ ?M bi:
2 4
H SO
n 2.05 1mol = =
(0,25 im)
nc< n
./
|
2 4
H SO
n
(0,25 im)
M=t Rh%c t($ng hn hWp c\n c n nZn ,> m$l hn hWp chYc chYn c\n nhk h'n 0LXX m$l9 h+ng tk
Ci 1 m$l H
2
80
7
th) a;it ,{ A& hn hp 2 kim loi tan ht (0,25 im)
b5 1La ?i[m
Th/$ ?M : m
hh
` 1bL292 ` b7L2 gam (0,25 im)
ei* ,r t($ng hn hWp chz c Rim l$]i n 4Rim l$]i c Rh>i l&Wng ln nhNt t($ng hn hWp5
(0,25 im)

Zn
74,4
n 1,14 mol
65
= = (0,25 im)
ftp& : n 2 H
2
80
7
n80
7
2 H
2
425 (0,25 im)
Th/$ ptp& 415 :
2 4
H SO
Zn
n n 1,14 (mol ) = =
M th/$ ?M bi :
2 4
H SO
n
?E Atng
` 1 4m$l5
nc< n
n
i
2 4
H SO
n
?E Atng
(0,25 im)
nc< Ci 1 m$l H
2
80
7
th) Rhng ?^ ?[ h\a tan 1L17 m$l n
M t($ng th@c th ,> m$l c^a hn hWp chYc chYn ln h'n mUt 1L17 m$l C) c\n c ./
h+ng tk a;it thih- hn hp khng tan ht (0,25 im)
c) 2 im
ei ;L < ljn l&Wt l ,> m$l c^a n C ./
Ta c Xa; 2 aX< ` 1bL2 4x5 (0,25 im)
Th/$ fTfg 415 C 425: n
H2
` n
hh
` ; 2 < (0,25 im)
H
2
2 -0 - 2 H
2
0 415 (0,25 im)
Th/$ 415:
2 H -0
78
n n 0L X m$l
80
= = =
(0,25 im)
nc< ; 2 < ` 0LX 4xx5 (0,25 im)
T 4x5L4xx5 c hK ph&'ng t()nh
Xa; 2 aX< ` 1bL2
; 2 < ` 0LX

(0,25 im)
ei*i hK ph&'ng t()nh t(Zn ta c ; ` 0L7 : < ` 0L2 (0,25 im)
m
n
` 0L7 9 Xa ` 2Xg
m
./
` 0L2 9 aX ` 11L2g (0,25 im)
thi 17 hc sinh gioi lp 8- nm hc 2008-2009
Mn : ho hc - Thi gian lm bi 150 pht
G- 1: 41 ?i[m5
H$n thnh c%c ph&'ng t()nh h$% hc ,a-L ghi thZm ?iM- RiKn ph*n +ng nh- c9
a5 :Mn0
7
:
2
Mn0
7
2 Mn0
2
2 0
2
)) Fe
3
O
4
* CO Fe * CO
2
+) 'ClO
3
'Cl * O
2
d) ,l(OH)
3
* H
2
SO
4
,l
2
(SO
4
)
3
* H
2
O
e) FeS
2
* O
2
Fe
2
O
3
* SO
2

-) Cu(.O
3
)
2
CuO * .O
2
* O
2
G- 2: 47 ?i[m5
DJng c%c ph&'ng ph%p h$% hc hE< nhcn biht 7 RhI l 0
2
L H
2
L 0
2
L 0 ?@ng t($ng 7 b)nh
(iZng biKt9 niht ph&'ng t()nh ph*n +ng9
G- 1: 42 ?i[m5
>t chNt 3 t($ng RhI $;iL ,inh (a RhI cacb$nic Ca n&c9 h$ biht ng-<Zn t> h$% hc n$ bYt
b-Uc ph*i c t($ng thnh phjn c^a chNt 3P "g-<Zn t> h$% hc n$ c th[ c h$=c Rhng t($ng
thnh phjn c^a chNt 3P ei*i thIch P
G- 7: 4a ?i[m5
D>n b)nh c th[ tIch C Rh>i l&Wng bJng nha-L mi b)nh ?@ng 1 t($ng c%c RhI ,a-: hi?($L $;iL
nit'L cacb$nic9 HE< ch$ biht :
a5 8> phjn tr c^a mi RhI c t($ng b)nh c bJng nha- RhngP ei*i thIchP
b5 8> m$l chNt c t($ng mi b)nh c bJng nha- RhngP ei*i thIchP
c5 :h>i l&Wng RhI c t($ng c%c b)nh c bJng nha- RhngP "- Rhng bJng nha- th) b)nh ?@ng
RhI n$ c Rh>i l&Wng ln nhNtL nhk nhNtP
Diht c%c RhI t(Zn ?M- H ctng nhiKt ?U C %p ,-Nt9
G- a: 4X ?i[m5
n lIt hn hWp RhI gQm 0 C H
2
9 hia hn hWp thnh 2 phjn bJng nha-9
>t ch%< h$n t$n phjn th+ nhNt bJng $;i9 8a- ? An ,*n phvm ?i S-a n&c Ci t($ng 4 A& 5
th- ?&Wc 20g Rht t^a t(Yng9
wn phjn th+ 2 ?i S-a bUt ?Qng $;it nng A&9 fh*n +ng ;$ng th- ?&Wc 1_L2g Rim l$]i ?Qng9
a5 niht ph&'ng t()nh ph*n +ng ;*< (a9
b5 TInh th[ tIch c^a n lIt hn hWp RhI ban ?j- 4 H ?Rtc 5
c5 TInh thnh phjn } c^a hn hWp RhI ban ?j- th/$ Rh>i l&Wng C th/$ th[ tIch9
x x x x x x x x x
h ng d n ch m 17 h c sinh gi i l p 8
Mn: ho h c
C/u10 (3 1i m)
$ i ! n2 t34n! ! n n2 5i t 16n2 +!o 0,51.
") 2 '$nO
4

t
'
2
$nO
4
* $nO
2
* O
2
)) Fe
3
O
4
* 4 CO 3 Fe * 4 CO
2
+) 'ClO
3

t ,7t
2 'Cl * 3 O
2
d) 2 ,l(OH)
3
* 3 H
2
SO
4
,l
2
(SO
4
)
3
* 6 H
2
O
e) 4 FeS
2
* 11 O
2
2 Fe
2
O
3
* 8 SO
2

-) 2 Cu(.O
3
)
2
2 CuO * 4 .O
2
* O
2
C/u 20 (4 1i m)
8 %9n2 :ue 1;m +<n t!"n ! n2 1 n! n )i t =!> O
2
( t!"n ! n2 )9n2 +!?@)
C * O
2
CO
2
(11)
8 '!> =!An2 +!?@ lB CO
2
.
8 '!> +!?@ 1 + lB H
2
5B CO.
2 H
2
* O
2
2 H
2
O

2 CO * O
2
2 CO
2
(1,51)
8 S"u ! n n2 +!?@ + " H
2
5B CO, 1 dun2 d +! C"(OH)
2
5Bo. %un2 d +! nBo t o
= t t " t3 n2 lB CO
2
, t" n! n )i t 1 + CO.
CO
2
* C"(OH)
2
C"CO
3
* H
2
O (1.51)
C/u 30 (2 1i m)
.2u@Cn t !o? ! + )u + ! i +; t3on2 +! t , lB C?+)on 5B Hi13o. .2u@Cn t !o?
! + +; t! +; !o + =!An2 +; t3on2 t!Bn! ! n +! t , lB o7i. (0,51)
C! t , ! i +; C 54 =!i +!?@ t o 3" CO
2
. (0,51)
C! t , ! i +; H 54 =!i +!?@ t o 3" H
2
O. (0,51)
C! t , +; t! =!An2 +; o7i, =!i 1; o7i + " =!An2 =!> D = t ! 5 i C 5B H t o 3"
CO
2
5B H
2
O. (0,51)
C/u 40 (5 1i m)
") C?+ =!> H
2
, O
2
, .
2
, CO
2
+; t! t>+! ) n2 n!"u +9n2 1i u =i n n!i t 1 5B ? Du t
nCn +!6n2 +; D ! n t ) n2 n!"u. #4 t! t>+! +! t =!> =!An2 ! t!u + 5Bo =>+!
t! + !/n t mB +! ! t!u + 5B =!o n2 +?+! 2i " +?+ !/n t . .! 5 @, D
!/n t +; ) n2 n!"u t!4 t! t>+! + " +!6n2 m i ) n2 n!"u. (2,01)
)) S mol =!> t3on2 m i )4n! lB ) n2 n!"u, 54 D ! n t n! n!"u D +; D mol +! t
) n2 n!"u. (1,01)
+) '! i l n2 =!> t3on2 +?+ )4n! =!An2 ) n2 n!"u 54 tu@ +; D mol ) n2 n!"u, n! n2
=! i l n2 mol =!?+ n!"u nCn =! i l n2 =!?+ n!"u.
E4n! +; =! i l n2 l n n! t lB )4n! 1 n2 CO
2
.
E4n! +; =! i l n2 n! n! t lB )4n! 1 n2 H !
2
. (2,01)
C/u 50 (6 1i m)
") F! n 10 2 CO * O
2
2 CO
2
(1) (0,251)

2 H
2
* O
2
2 H
2
O (2) (0,251)
CO
2
* C"(OH)
2
C"CO
3
* H
2
O (3) (0,51)
0,2mol 0,2mol

G (1) 5B (3) 0 n "
CO
= n
CO2
= n
C"CO3
= 0,2 mol (0,51)
F! n 20 CuO * CO Cu * CO
2
(4) (0,51)

CuO * H
2
Cu * H
2
O (5) (0,51)

19,2
G (4) 5B (5) 0 n "
CO
* n
H2
= n
Cu
= = 0,3 mol (0,51)

64
)) #
!!
= 0,3 . 2 . 22,4 = 13,44 (l>t) (0,51)
+) #
CO
= 0,2 . 2 . 22,4 = 8,96 (l>t) (0,51)

8,96 . 100&
& #
CO
= = 66,67 & (0,51)

13,44

& #
H2
= 100 H 66,67 = 33,33 & (0,51)

28 . 0,4 . 100&
&m
CO
= = 96,55 & (0,51)

(28 . 0,4) * (2 . 0,2)
&m
H2
= 100 H 96,55 = 3,45 &. (0,51)
Tr ng THCS Quang Trung thi 18 h c sinh gi i kh i 8
Mn : Ho h c (9ph!t"
#$i :
%h n I 0 Tr c nghi m
Cu 1 : (2 i m )
J t o t!Bn! !/n t + " 1 ! +! t t!4 t i t!i u + n +; )"o n!iCu lo i n2u@Cn t 0
,. H"i lo i n2u@Cn t
E. $ t lo i n2u@Cn t
C. E" lo i n2u@Cn t
%. ,,E,C, 1 u 16n2 .
Cu 2 : (2 i m )
G3on2 m t ! n n2 !o? ! + +?+ +! t ! n n2 5B +! t t o t!Bn! ! i +9n2 0
,. S n2u@Cn t + " m i n2u@Cn t
E. S n2u@Cn t t3on2 m i +! t
C. S !/n t m i +! t
%. S n2u@Cn t t o 3" +! t .
Cu 3 : (2 i m )
C!o m i ! n ! 2 m !"i mu i ,
2
SO
4
5B E"SO
4
+; =! i l n2 lB 44,2 2 t?+ d n2 5 " "
1 5 i 62,4 2 E"Cl
2
t!4 +!o 69,9 2 = t t " E"SO
4
5B !"i mu i t"n . '! i l n2 !"i mu i
t"n ! n n2 lB 0
,. 36,8 2
E . 36,7 2
C . 38 2
% . 40 2
%h n && : T lu n
Cu 1 : (4i m )G>n! D !/n t +; t3on2 34,2 2 n!AmDun-"t ,l
2
(SO
4
)
3
1=t+ , )"o
n!iCu l>t =!> A7i D +; D !/n t ) n2 D !/n t +; t3on2 ,l
2
(SO
4
)
3
t3Cn .
Cu 2 : (5 i m )
G3Cn 2 1K" +/n 1 !"i + + 1 n2 dun2 d +! HCl 5B H
2
SO
4
D"o +!o +/n 5 t3> t!Ln2
) n2 0
- C!o 5Bo + + 1 n2 dun2 d +! HCl 25 2 C"CO
3

- C!o 5Bo + + 1 n2 dun2 d +! H
2
SO
4
" 2 ,l .
C/n 5 t3> t!Ln2 ) n2 . G>n! " , )i t +; +?+ ! n n2 7 @ 3" !oBn toBn t!eo ! n2
t34n! 0
C"CO
3
* 2 HCl C"Cl
2
* H
2
O * CO
2
2 ,l * 3H
2
SO
4
,l
2
(SO
4
)
3
* 3H
2

Cu 3 : (5 i m )
C; ! n ! =!> CO 5B CO
2
. . u +!o ! n ! =!> 1i :u" dun2 d +! C"(OH)
2
d t!4
t!u 1 + 1 2 +! t = t t " mBu t3 n2 . . u +!o ! n ! =!> nB@ 1i :u" ) t CuO n;n2
d t!4 t!u 1 + 0,46 2 Cu .
")#i t ! n2 t34n! ! n n2 7 @ 3" M
)) G>n! t! t>+! + " ! n ! =!> 1=t+ 5B t! t>+! + " m i =!> +; t3on2 ! n ! .



J? ?n !o? ! + 1 18
%h n I 0 Tr c nghi m
Cu 1 : (2 i m )
,
Cu 2 : (2 i m )
,
Cu 3 : (2 i m )
E
%h n && : T lu n
Cu 1 : (4i m ) * G3on2 34.2 2 ,l
2
(SO
4
)
3
+; +! " 0
n
,l2(SO4)3
=
172
2 9 17
= 0.2 mol 1 1

S !/n t ,l
2
(SO
4
) lB 0
0N1 . 6.10
23
= 0,6.10
23
11
S !/n t O
2
= S !/n t ,l
2
(SO
4
) = 0,6.10
23
1 1
n
O2
= 0,6.10
23
O6.10
23
= 0,1 mol 1 1
Cu 2 : (5 i m
C"CO
3
* 2 HCl C"Cl
2
* H
2
O * CO
2
(1 )
2 ,l * 3H
2
SO
4
,l
2
(SO
4
)
3
* 3H
2
(2 )
S"u =!i ! n n2 = t t!6+ , +/n 5 n 5 t3> +/n ) n2 +! n2 t m # !
CO2
= m
H2
(1 1)
#4 t!eo 1 )Bi t" +; 0 n
C"CO3
=
100
2a
= 0,25 mol ( 1 1)
G!eo (1) n
CO2
= n
C"CO3
= 0,25 mol

m
CO2
= 0,25 .44 = 11 2 (1 1)
#4 0 m
CO2
= m
H2
= 11 2

n
H2
=
2
11
= 5,5 mol (0.51)
G!eo (2) n
,l
=
1
2
n
H2
=
1
2
.5,5 = 3,67 mol

" = m
,l
= 3,67 . 27 = 99 2 (1,5 1)
# @ ! i d9n2 99 2 ,l 5Bo d d H
2
SO
4
t!4 +/n 2i 5 t3> t!Ln2 ) n2.
Cu 3 : (5 i m )
FGF 0 CO $
2
* C"(OH)
2
C"CO
3
* H
2
O (1) (0,5 1)
CO
2
* CuO Cu * CO
2
(2) (0,5 1)
)) n
C"CO3
=
100
1

= 0,01 mol (0,5 1)

n
Cu
=
X7
7X L 0
= 0,01 mol (0,5 1)
G!eo (1) n
CO2 ! n n2
= n
C"CO3 Din! 3"
= 0,01 mol

#
CO2
= 0,01 . 22,4 = 0,224 l>t (1 1)
G!eo (2) n
CO ! n n2
= n
Cu Din! 3"
= 0,01 mol

#
CO
= 0,01 . 22,4 = 0,224 l>t (1 1)
# @ #
!!
= #
CO
* #
CO2
= 0,224 * 0,224 = 0,448 l>t (1 1)




F!<n2 P%QJG ) m D n =R t!i ! + Din! 2i i l 8 nLm ! + 2008H2009 !
Mn ho h c
Th i gian lm bi: 150 pht (Khng k pht )

C'u 1(2 ): C; 4 ! n2 !? 5 t lS t! n2 d9n2 1 t?+! +?+ +! t 3" =! i n!"u % !
H F! n2 !? )"@ ! i H F! n2 !? +! n2 + t
H F! n2 !? = t tin! t3 l i H F! n2 !? +!i t
Tm !U@ l @ +?+ 5> d + t! , 1 min! !o +!o t n2 ! n2 !? t?+! t3Cn M "
C'u ( ( 5!5 ): #i t +?+ ! n2 t34n! !o? ! + 5B 2!i 1 @ 1 1i u =i n ! n n2
(n u +;) M
1O C!o =!> o7i t?+ d n2 l n l t 5 i0 S t, n!Am, 1 n2, l u !uRn!, +"+)on, !At!o
2O C!o =!> !i13o 1i :u" +?+ n2 m + n i ti , nun2 n;n2, +! " l n l t +?+ +! t0
$2O, C"O, CuO, ."
2
O, F
2
O
5
3O C!o dun2 d +! "7it HCl t?+ d n2 l n l t 5 i +?+ +! t0 .!Am, D t, m"2ie, 1 n2,
= m.
4O C; m @ lo i ! +! t 5A + M $ i lo i l @ 2 5> d 5 +An2 t! + !o? ! +M J +
tCn +!6n2M
C'u ) ( 2!5)0 Tm !U@ t n2 t34n! l i t!> n2!i m 1i u +! o7i t3on2 !<n2 t!> %
n2!i mM C; m @ +?+! t!u =!> o7iM #i t FGHH 7 @ 3"M
C'u * (35)
1O G3 n t l 5 t! t>+! (1o +9n2 1i u =i n) n! t! nBo, 2i " O &
2
5B .
2
1 n2 i %
t" t!u 1 + m t ! n ! =!> +; t =! i Do 5 i H &
2
) n2 14,75 M
2O J t +!?@ !oBn toBn m t ! +! t V, + n d9n2 ! t 10,08 l>t O
2
(J'GC). S"u =!i
= t t!6+ ! n ! n n2, +! t!u 1 + 13,2 2"m =!> CO
2
5B 7,2 2"m n +.
"H G4m +An2 t! + !o? ! + + " V (Ei t +An2 t! + d n2 1 n 2i n +!>n! lB +An2 t! +
!o? ! + + " V)
)H #i t ! n2 t34n! !o? ! + 1 t +!?@ V t3Cn M
C'u + (45 )
1O C!o " 2"m ! n ! 2 m 2 =im lo i , 5B E (+! " 3W !o? t3 ) t?+ d n2 ! t 5 i dd
HCl (+ , 5B E 1 u ! n n2). S"u =!i ! n n2 = t t!6+, n2 i t" +! t!u 1 + 67 2"m %
mu i 5B 8,96 l>t H
2
(J'GC).
"H #i t +?+ ! n2 t34n! !o? ! + M
)H G>n! " M
2O %9n2 =!> CO 1 =! !oBn toBn 20 2"m m t ! n ! ( ! n ! X ) 2 m CuO 5B
Fe
2
O
3
n!i t 1 +"o. S"u ! n n2, t!u 1 + +! t 3 n +! lB +?+ =im lo i, l n2 =im
lo i nB@ 1 + +!o ! n n2 5 i dd H
2
SO
4
loUn2 (l @ d ), t!4 t! @ +; 3,2 2"m m t =im
lo i mBu 1 =!An2 t"n. !
"H G>n! & =! i l n2 +?+ +! t +; t3on2 ! n ! X M
)H . u d9n2 =!> D n ! m +?+ ! n n2 =! X, +!o 1i :u" dun2 d +! C"(OH) '
2
d
t!4 t!u 1 + )"o n!iCu 2"m = t t ". Ei t !i u Du t + " ! n n2 nB@ +! 1 t 80& M
C'u , (15 ): C n l @ )"o n!iCu 2"m tin! t! CuSO
4
.5H
2
O 5B )"o n!iCu 2"m
n +, 1 !" +! 1 + 500 2"m dun2 d +! CuSO
4
5&
Ch": Cu # $4% & # 14% ' # 1$% ( # 32% Ca # 40% )* # 5$% C # 12
Th+ ,inh - ./ng m0 t+nh b ti th*" 1ui nh - a 2 3i" . - 4 5" t "
( 5 thi g m 01 t6ang)
1 +!>n! t! + 19
H t
H ng d n ch m 19
Mn0 Ho h c 8
C/uOS . i dun2 +!>n! + n t3 l i % Ji m
C'u 1
( ( i m "
H + Din! l @ 16n2 +?+ #%, t34n! )B@ ! n2 !? t?+! =!o"
! +, +! t +! t!4 +!o m i #% 0,5 1i m
C'u (
( +-7+ i m "
1O ( 1,5 1)
2O (0,751)
3O ( 1 1)
4O ( 2,5 1)
C'u ) ((-7+ "
H #i t 16n2 m i FGHH +!o 0,25 1i m
H % n =!> H #
2
1i :u" +?+ n2 D m + n i ti
FGHH0 H
2
* CuO
0
t
Cu * H
2
O
H
2
O * ."
2
O

2."OH
3H
2
O * F
2
O
5

2H
3
FO
4
- #i t 16n2 m i FGHH +!o 0,25 1i m
- .Cu 16n2 +; 4 lo i ! +! t 5A + 0 O7it, "7it, )"Y , $ u i
- Z @ 16n2 , 1 , 1 + tCn +!>n! 7?+ +?+ 5> d , +!o 0,25 1O5d
- .Cu 1 + +?+! ti n !Bn!, +!>n! +?+ =!o" ! +
- C?+! t!u =!> o7i
- #i t 16n2 FGHH
0,25
0,25
0,25
0,5
2
1,751
0,5 1
0,5
C'u*()-+ i m
"
1O(1,51i m)
2O ( 2 1)
G" +;0 '! i l n2 mol t3un2 )4n! + " ! n ! =!> lB0 $ =
14,75.2 =29,5
H P i D mol + " O
2
lB 7, D mol + " .
2
lB @
$ =
a L 2_
28 12
=
+
+
# %
# %
327 * 28 @ = 29,57 * 29,5@
2,57 = 1,5 @ =[ 7 0 @ = 3 0 5
H %o +?+ t! t>+! 1o +9n2 1i u =i n nCn0 #
O
2
0 #
.
2
= 3 0 5
H G" +; D 1 + " ! n n2 lB0
, * O
2

0
t
CO
2
* H
2
O
H G3on2 , +; +! + +! n 2 n2u@Cn t 0 C 5B H
n
O
2
=
7 L 22
08 L 10
= 0,45 mol =[ n
O
= 0,9 mol
n
CO
2
=
77
2 L 11
= 0,3 mol, =[ n
C
= 0,3 mol, n
O
= 0,6 mol
n
H
2
O
=
18
2 L b
= 0,4 mol, =[ n
H
= 0,8 mol, n
O
= 0,4 mol
H G n2 D mol n2u@Cn t O +; t3on2 D n ! m lB0 0,6 * 0,4 '
=1mol [ 0,9 mol

0,25
1
0,25
0,25
0,75
C'u +(*-+ "
1O(1,5 1)
2O ( 3,01)
# @ t3on2 , +; n2u@Cn t O 5B +;0 1 \ 0,9 = 0,1 mol O
H Coi CGHH + " , lB C
7
H
@
O
Y
N t!4 t" +;0
7 0 @ 0 Y = 0,3 0 0,8 0 0,1 = 3 0 8 0 1. # @ , lB0 C
3
H
8
O
"O FGHH0 , * 27HCl

2,Cl
7
* 7H
2
E * 2@HCl

2ECl
@
* @H
2
)O H S mol H
2
0 n
H
2
=
7 L 22
_X L 8
= 0,4 mol, n
H
2
= 0,4.2 = 0,8 2"m
H G!eo FGHH =[ n
HCl
= 0,4.2 = 0,8 mol, m
HCl
= 0,8.36,5 = 29,2
2"m
H ? d n2 1 n! lu t ) o toBn =! i l n2, t" +;0
" = 67 * 0,8 \ 29,2 = 38,6 2"m
"O( 1,751) FGHH0 CO * CuO
0
t
Cu * CO
2
(1)
3CO * Fe
2
O
3

0
t
2Fe * 3CO
2
(2)
Fe * H
2
SO
4

FeSO
4
* H
2
(3)
- C! t 3 n mBu 1 =!An2 t"n 1; +!>n! lB Cu, =! i l n2 lB !
3,2 2"m. n
Cu
=
X7
2 L 1
= 0,05 mol, t!eo FGHH(1) =[ n
CuO
=
0,05 mol,
=! i l n2 lB0 0,05.80 = 4 2.# @ =! i l n2 Fe0 20 \ 4 = 16 2"m
H F! m t3Lm =! i l n2 +?+ =im lo i0
& Cu =
20
7
.100 = 20&, & Fe =
20
1X
.100 = 80&
)O (1,251)'!> D n ! m ! n n2 1 + 5 i C"(OH) '
2
lB0 CO
2
CO
2
* C"(OH)
2

C"CO
3
* H
2
O (4)
n
Fe
2
O
1
=
1X0
1X
= 0,1 mol,
- G!eo FGHH (1),(2) =[ D mol CO
2
lB0 0,05 * 3.0,1 = 0,35
mol
- G!eo FGHH(4) =[ D mol C"CO
3
lB0 0,35 mol.
'! i l n2 t>n! t!eo lS t!u@ t0 0,35.100 = 35 2"m
'! i l n2 t>n! t!eo !i u Du t0 35.0,8 = 28 2"m
0,5
0,5
0,5
0,25
0,25
0,5
0,75
0,5
0,5
0,25
0,5
0,5
C'u ,: (1-+ "
H '! i l n2 CuSO
4
+; t3on2 5002"m dd CuSO
4
4 & lB0
100
7 9 a00
=
20 2
# @ =! i l n2 CuSO
4
.5H
2
O + n l @ lB0
1X0
2a0 9 20
= 31,25 2"m
H '! i l n2 n + + n l @ lB0 500 \ 31,25 = 468,75 2"m
0,5
0,5
0,5
P!i +!60 H H + Din! +; t! 2i i to?n Ho? ! + ) n2 +?+! =!?+, mB =!o" ! +, l lu n
+! t +! , 16n2 = t :u , t!4 +!o 1i m t i 1" )Bi @.
H G3on2 +?+ FGHH0 #i t D"i CGHH =!An2 +!o 1i m, t!i u 1i u =i n ! n n2
+!o D 1i m. . u =!An2 +; t3 n2 t!?i +?+ +! t t3 1 1i m O t n2 1i m. ( " "
( ch n i tu. n h c sinh gi i l p 8
n m h c (1/(11
Mn: H0a h c H G! i 2i"n0 120 !6t %
C'u 1: (30 i m)
C!o D 1 ! n n2 D"u0 Zn * HCl HHH[ ZnCl
2
* H
2
"O HU@ l t!Bn! ! n2 t34n! !;" ! + 5B n;i 3W + D 1 5i t t!Bn! FGHHM
)O HU@ 5 D 1 t n2 t3 n2 +!o ! n n2 !;" ! + n;i t3Cn 5B 2i i t!>+! t i D"o l i +;
D t o t!Bn! +! t m i D"u ! n n2 !;" ! +M
C'u (: ( 40 i m )
C; n! n2 +! t D"u0 Zn, Cu, ,l, H
2
O, C
12
H
22
O
11
, '$nO
4
, HCl , 'ClO
3
, '.O
3
, H
2
SO
4

loUn2 , $nO
2
.
") .! n2 +! t nBo +; t! 1i u +! 1 + =!> 0 H
2
, O
2
.

)) #i t ! n2 t34n! !o? ! + 7 @ 3" =!i 1i u +! n! n2 +! t =!> n;i t3Cn (ghi i u
ki n
n u -7) .
+) G34n! )B@ n2 n 2 n +?+! t!u +?+ =!> t3Cn 5Bo l .
C'u )0( 40 i m)
C"+ )on o7it CO t?+ d n2 5 i =!> o7i t o 3" +"+)on 1io7it. HU@ 1i n 5Bo n! n2 A t3 n2
D mol +?+ +! t ! n n2 5B D n ! m +; n! n2 t! i 1i m =!?+ n!"u. Ei t ! n ! ' %
CO 5B O
2
)"n 1 u 1 + l @ 16n2 t l 5 D mol +?+ +! t t!eo ! n n2. &
Cc th i i m
S mol
Cc ch t ph n ng S n ph m
CO O
2
CO
2
G! i 1i m )"n %
1 u t
0
20 ... ...
G! i 1i m t %
1
15 ... ...
G! i 1i m t %
2
... 1,5 ...
G! i 1i m = t t!6+ % ... ... 20
C'u *: (30 i m)
$ t n2u@Cn t ( +; t n2 D +?+ ! t t3on2 , n, e lB 115. S ! t m"n2 1i n n!i u ! n
D ! t =!An2 m"n2 1i n lB 25 ! t. HU@ 7?+ 1 n! tCn n2u@Cn t ( M
C'u + : ( $0 i m)
"O HoB t"n !oBn toBn 3,6 2 m t =im lo i , !;" t3 II ) n2 dun2 d +! "7it +lo!i13i+ t!u
1 + 3,36 l>t =!> !i13o (1=t+). V?+ 1 n! tCn =im lo i ,M
)O . u +!o l n2 =im lo i , n;i t3Cn 5Bo 14,6 2 "7it +lo!i13i+, t>n! =! i l n2 +?+ +! t
t!u 1 + D"u =!i ! n n2M
(2i t: 5i n t+-h h t nhn - a 1 , ngu08n t : K: 19 : % ;n : 30 : % 26 : 35 : % <g : 4! :
&gu08n t kh i: Ca # 40% &a # 23% =g # 24% <l # 2!% > # 1% Cl # 355% C # 12%
' # 1$?)
1i u i m ch m ( : h0a 8
C'u 2 i dung i m
C/u
1
( 3
1)
H Z FGHH
H C D 0 ? d n2 t!eo JlEG'Z
H # D 1
H Pi i t!>+!0 t3 t t liCn = t +?+ n2t t!"@ 1 i...
05
05
10
1?0
C/u
2
(4
1)
")
.! n2 +! t d9n2 1i u +! =!> H
2
0 Zn, ,l, H
2
O, HCl, H
2
SO
4
.! n2 +! t d9n2 1i u +! =!> O
2
0 '$nO
4
, 'ClO
3
, '.O
3
, $nO
2
)) C?+ FGHH0
Zn * 2HCl HH[ ZnCl
2
* H
2
2,l * 6HCl HH[ 2,lCl
3
* 3H
2
Zn * H
2
SO
4
HH[ ZnSO
4
* H
2
2,l * 3H
2
SO
4
HH[ ,l
2
(SO
4
)
3
* 3H
2
2H
2
O
:p
2H
2
* O
2
2'$nO
4
0
t
'
2
$.O
4
* $nO
2
* O
2
2'ClO
3

o
t 2'Cl * 3O
2
2'.O
3

0
t
2'.O
2
* O
2
+) C?+! t!u0
* G!u '!> H
2
0 H J @ n + '
H J @ =!An2 =!> ( 6 )4n! t!u) '
* G!u '!> O
2
0 H J @ n + '
H J @ =!An2 =!> (n2 " )4n! t!u) '
10
0.5
0.5
20
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
10
0.5
0.5
C/u
3 (4
1)
Cc th i i m
S mol
C?+ +! t ! n n2 S n ! m '
CO O2 CO2
G! i 1i m )"n 1 u t % 0 20 1
G! i 1i m t % 1 15 7-+ +
G! i 1i m t % 2
) 1,5 17
G! i 1i m = t t!6+ % 20
5i n
ng
m i
4 t6+
-
05 ?
C/u
4 (3
1)
H Z )i u t! + t>n! 0 D ! t m"n2 1i n = D ! t =!An2 m"n2 1i n.
H G D =[ 1i n t>+! ! t n!/n =[ tCn 2nu@Cn t "
15
15
C/u "O #i t FG0 , *2 HCl HH[ ,Cl
2
* H
2
30
5 (6
1)
G>n! , = 24 =[ , lB $2
)O So D?n! 1 = t lu n HCl d
S"u ! n n2 t!u 1 + $2Cl
2
, H
2
5B HCl d
15
15