BS 4

th
Year
Semester-VII
Title of the Course: Inorganic Chemistry Paper: I
Credit Hours: 03 ar!s: "00
Objective of the Program
#fter completing this program students $ill %e a%le to learn the follo$ing: 1,Periodic
Anomalies and Bonding in Electron deficient Compounds
2. inetics and !eaction "echanism of #norganic !eactions
$. Electron %ransfer !eaction
Periodic Anomalies and Bonding in Electron
deficient Compounds
&irst' and second' ro( anomalies) the use of d' orbitals b* non'metals) reactivit*
and d' orbital participation) p+'d+ bonds) the use of p' orbitals in +' bonding)
periodic anomalies of non'metals and post'transition metals. "ulticenter bonding
in electron deficient molecules, three centre t(o electron bond ,$c'2e- and three'
center, four'electron ,$c'.e- bond model.
Kinetics and Reaction Mechanism of Inorganic actions
Re
Classification of reaction mechanisms) rate la(s) stead* state appro/imation)
inert and labile comple/es) substitution reactions) octahedral comple/es0 acid
h*drol*sis, acid catal*1ed a2uation, anation reactions, base h*drol*sis, attac3 on
ligands, steric effects of inert ligands) s2uare planar comple/es0 nucleophilic
reactivit*, trans'effect, cis'effect, effect of leaving group, mechanism of
substitution, racemi1ation reactions.
Electron Transfer Reactions
Electron transfer reactions in co'ordination compounds, mechanism of electron
transfer reactions, outer sphere or tunneling mechanism, inner sphere or ligand
bridge mechanism, factors effecting the rate of electron transfer reactions, t(o
electrons transfer reactions, complementar* or non complementar* electron
transfer reactions, o/idation reduction reactions of metal ions
Recommended Books
1. Basolo, &., and Pearson, !. 4., 5"echanism of #norganic !eactions6, 7ile*,
8e( 9or3, 1:;2.
2. <uhee*, =. E, eiter, E. A. and eiter, !. >., 5#norganic Chemistr*0 Principles of
?tructure and !eactivit*6, .th Ed., <arper @ !o(, 8e( 9or3, 2AA1.
$. Benson, B., "echanisms of #norganic !eactions in solution0 "c4ra( <ill.
1:C;.
.. Purcell, .&. and ot1, =.C., 5#norganic Chemistr*6 7.B. ?aunders Compan*
<olt'?aunders #nternal editions 1:DD.

E. ?hirve B.&. At3ins P.7. and >angford C.<. 5#norganic Chemistr*6, O/ford
Fniversit* Press 1::A.
C. 7il3ins !.4. 5inetics and "echanism of !eactions of %ransition "etal
Comple/6 GC< Publishers, #nc., 1::1.
D. 7illiam. =., "odern inorganic chemistr* second edition "c4ra( <ill Compan* 1::1.
;. Porter &ield. 7.7., #norganic Chemistr* a Fnified Approach 2
nd
ed. Elsevier
Publishers, 2AAE Bouglas, "cBaniel @ =ohn Ale/ander. 5Concepts and
"odels of #norganic Chemistr*6 b* =ohn 7ille* and ?ons, 1::..
:. !.B. =ordan, !eaction "echanisms of #norganic and Organomettalics
?*stems. O/ford Fniversit* Press, 8e( 9or3, 1::1. An e/cellent
introduction.
1A. !.4. 7il3ins, %he stud* of 3inetics and "echanisms of !eactions of transition
metal comple/es 2
nd
ed., GC< Publishers, 8e( 9or3, 1::1. E/cellent
discussions of rate la(s, their interpretation and e/perimental
establishment.
BS 4
th
ear
Semester-VII
%itle of the Course0 #norganic Chemistr* PAPE!0 ##
Credit <ours0 A$ "ar3s0 1AA
Objective of the Program
After completing this program students (ill be able to learn and had a sound
3no(ledge of the follo(ing0
1. Organic !eagents used in #norganic Anal*sis, their selectivit*, specificit* etc.
2. Pol*mer Chemistr*
!rganic Reagents "sed in Inorganic Anal#sis
%*pes of reagent, specificit* and sensitivit* of the reagents, methods of
application (ith specific e/amples, comple/ometric and gravimetric methods
involving various reagents, chelates and chelate'effect.
Polymer Chemistry
"olecular species0 #ntroduction, homoatomic and heteroatomic inorganic
pol*mers, chains and cages of Boron, ?ilicon, 8itrogen, Phosphorous and
?ulphur) their s*nthesis, reactivit* and applications, metal clusters.
Pol*ionic species0 #sopl* and heteropol* anions of transition metals, ?ilicates,
borates, condensed phosphates, 1eolites.
Recommended Books
1. "alcoim, P.?. 5Pol*mer Chemistr*6 O/ford Fniversit* Press 2AAE.
2. "andel3ern 5An #ntroduction to "acromolecules6 2
nd
?pringer 1:;$
$. !avue, 5Principles of Pol*mer Chemistr*6 2
nd
edition Plenum Publishers 2AAA.
.. Emeleus and ?harpe., 5"odern Aspects of #norganic Chemistr*6.
E. <uhee*, =. E, eiter, E. A. and eiter, !. >., 5#norganic Chemistr*0 Principles of
?tructure and !eactivit*6, .th Ed., <arper @ !o(, 8e( 9or3, 2AA1.
C. &. 7. Billme*er. 5A %e/t boo3 of Pol*mer ?cience6 =ohn 7ille* @ ?ons, 8e(
Belhi, 2AAA2.
D. P.Po(ell. 58on "etal Chemistr*6, Chopman @ <all., 1:D.
;. "iessler 4.>. and %ar Bonald, A. 5#norganic Chemistr*6 Prentice <all #nt.
edition, 1::1.
:. Bouglas, "cBaniel @ =ohn Ale/ander. 5Concepts and "odels of #norganic
Chemistr*6 b* =ohn 7ille* and ?ons, 1::..
BS 4
th
ear
Semester-VII
%itle of the Course 0 #norganic Chemistr* PAPE!0 ###
Credit <ours 0 A$ "ar3s0 1AA
!$%ecti&e of the Program
After completing this program students (ill be able to learn and able to interpret
simple spectra.
1. 8uclear "agnetic !esonance ?pectroscop*.
2. Fltra violet spectroscop*
$. #nfrared spectroscop*
.. "ass ?pectrometr*
E. %hermal Anal*sis
Instrumental Methods of Analysis
Ph*sical methods in #norganic Chemistr*, %4A @ B%A, 8"!, #!, FG
?pectroscop*, "ass ?pectroscop*) Basic principles, #nstrumentation and
Applications
Recommended Books
1. Gogel, A. #., 5A %e/t boo3 of Huantitative #norganic Anal*sis6, English language
Boo3 ?ociet* .
th
edition, 1:D;.
2. Baniels, %., 5%hermal Anal*sis6 1::;.
$. Pavia, B. >., >ampman, 4. ". and ri1, 4.?., 5#ntroduction to ?pectroscop*6,
?aunders College Publishing, 1:;A
.. ?ilverstein, !. "., Barler, C. 4. and "ogrill, %. C., 5?pectrometric #dentification
of Organic Compounds6,
E. emp, 7., 58"! in Chemistr* A "ulti 8uclear #ntroduction6, "c"illan Press
>td., 1:;C.
C. Brago, !. ?., 5Ph*sical "ethod in #norganic Chemistr*6, 7.B. ?aunders
Compan*, 1::D.
D. Bassetta, =., Benne*, C., =effer*, 4. <. and "endham, =., 5GogelIs %e/tboo3 of
Huantitative #norganic Anal*sis including Elementar* #nstrumental Anal*sis6,
English language boo3 societ* .
th
edition, 1:D;.
;. Bouglas, A. ?3oog, &. =ames <oller, %rmoth*, A., 5Principles of #nstrumental
Anal*sis6, E
th
edition, ?aunders College Publishing, 8e( 9or3, 1::D.
:. E(ing, 4.7., 5#nstrumental "ethods of Chemical Anal*sis6, E
th
edition,
"c4ra( <ill, 8e( 9or3, 1:;E.
BS 4
th
ear
Semester-VII
%itle of the Course0 #norganic Chemistr* PAPE!0 # ,P!AC%#CA>-
Credit <ours0 A1 "ar3s0 1AA
J Fse of some organic reagents for the estimation of various elements
J Preparation of at least si/ compoundsKorganometallic compounds in a pure
state and determination of their state of purit*
J %he e/periments ma* be set ma3ing use of conductivit* meter and
potentiometer depending upon the availabilit*.
Recommended Books
1. Bassette, =., Benne*, 4. <. and "endham, =., 5GogelIs %e/tboo3 of
Huantitative #norganic Anal*sis #ncluding Elementar* #nstrumental
Anal*sis6 English >anguage Boo3 ?ociet*, .
th
Edition, 1:;1.
2. &rit1, =. ?. and ?chen3, 4. <., 5Huantitative Anal*tical Chemistr*6, All*n and
Bacon #nc., .
th
Edition, 1:D:
Pass, 4 and ?utcliffe, <., 5Practical #norganic Chemistr*6, Gan 8ostrand !einhold
Compan*, 1:D2
BS 4
th
ear
Semester-VII
%itle of the Course0 Chemistr* PAPE!0 #
Credit <ours0 A$ "ar3s0 1AA
!'idation and Reduction
Oxidation( #ntroduction) reactions involving elimination of h*drogen, cleavage of
C'C bond, replacement of h*drogen b* o/*gen and addition of o/*gen to the
substrate) o/idative coupling.
Reduction( #ntroduction) reactions involving replacement of o/*gen b* h*drogen,
removal of o/*gen from the substrate and reduction (ith cleavage) reductive
coupling.
Protecti&e )roups
Fse of h*dro/*l', amino', carbo/*l' and carbon*l' protecting groups in organic
s*nthesis.
Peric#clic Reactions
Principles) c*cloadditions) electroc*clic reactions) cheletrophic reactions)
sigmatropic rearrangements) the ene'reaction and related reactions.
Recommended *iterature
,>atest available editions of the follo(ing boo3s-
1. 8orman, !. O.C. and Co/on, =. "., 5Principles of Organic ?*nthesis6, 8elson
%hornes, Cheltenham.
2. !inehart =r., . >., 5O/idation and !eduction of Organic Compounds6,
Prentice'<all, >ondon.
$. >oudon, 4. "., 5Organic Chemistr*6, O/ford Fniversit* Press, 8e( 9or3.
.. ?mith, ". B., 5Organic ?*nthesis6, "c4ra('<ill, 8e( 9or3.
E. "arch, =., 5Advanced Organic Chemistr*6, =ohn 7ile* @ ?ons, 8e( 9or3.
C. ?*3es, P., 5A 4uide Boo3 to "echanism in Organic Chemistr*6, >ongman,
>ondon.
D. Cla*den, =., 4reeves, 8., 7arren, ?. and 7others, P., 5Organic Chemistr*6,
O/ford Fniversit* Press, 8e( 9or3.
;. Care*, &. A. and ?undberg, !. =. 5Advanced Organic Chemistr* Part B0
!eactions and ?*nthesis6, Plenum Press, 8e( 9or3.
:. "orrison, !. %. and Bo*d, !. 8., 5Organic Chemistr*6, Prentice'<all of #ndia,
8e( Belhi.
Supplementar# *iterature
,>atest available editions of the follo(ing boo3s-
1. Bruc3ner, !., 5Advanced Organic Chemistr*'!eaction "echanisms6, <arcourt
?cience @ %echnolog* Compan*, 8e( 9or3.
2. "arch, =., 5Advanced Organic Chemistr*6, =ohn 7ile* @ ?ons, 8e( 9or3.
$. <ouse, <. O., 5"odern ?*nthetic !eactions6, %he BenjaminKCummings
Publishing Compan*, California.
.. &inar, #. >., 5Organic Chemistr*6, Gol. 1, Pearson Education, Belhi.
E. 4reene, %. 7., 5Protective 4roups in Organic ?*nthesis6, =ohn 7ile* @ ?ons,
8e( 9or3.