61

LAMPIRAN 1
Perhitungan
1. Penentuan Kadar Air dalam MEG
% H2O = 0,0246%
2. Penentuan Kadar Asiditas dalam MEG
Perhitungan Manual :
A =0,093 ml
N NaOH =O,05 N
W MEG =30,0 gram
ppm =
AN601000
w

ppm =
0,093ml 0,05N 60
gr
mol
, 1000
30gr

ppm =9,37 ppm
%ociJity =
ppm
10000

%ociJity =9,37 10
-4
%
3. Penentuan Kadar Abu
A =65,0586 gram
B =65,0586 gram
=1,1154
62

%obu =
(65,058 65,058)gr 100
100 ml 1,1154
gr
ml
,

%obu =0%
4. Penentuan Kadar Aldehid
Tabel 3. Hasil spektroskopi kandungan Aldehid = 655 nm
Sampel No. Abs Conc (ppm)
1 0,0387 0,9971
ppm totol olJciJ =
pg olJciJ Jori spcktro
ml sp.gr sompcl

Dimana,
sp.gr =
w3w1
w2w1

sp.gr =
101,4735 44,2990
95,556044,2990
=1,1154
Sehingga,

ppm totol olJciJ =
0,9971
1 1,1154

ppm totol olJciJ =0,8939
% aldehid =8,939x10
-5
%

63

5. Penentuan Klorida dalam Sampel
Tabel 4. Hasil spektroskopi pengukuran Klorida pada = 650 nm
Sampel No. Abs Conc (ppm)
1 -0,0002 -0,0372

ppm Cl =undetected
% Cl =0%
6. Penentuan Kadar Besi
Tabel 5. Hasil pengukuran spektroskopi Fe pada = 510 nm
Sampel No. Abs Conc (ppm)
1 0,0010 0,0004

W dari spektra =0,0004 mg
S=berat sampel = 80,3 gr
ppm Fc =
w
s
1000
ppm Fc =
0,0004
80,3
1000
ppm Fc =0,0049
64

% Fe =4,9x10
-7
%
7. Penentuan DEG content
Hasil kromatogram

Gambar 11. Hasil Kromatogram
Tabel 6. Data Kromatogram
Number Component Retention Area External
1 DEG 5,050 1,3820 0,0113



65

Perhitungan menggunakan metode kalibrasi
Tabel 7. Data Kalibrasi Alat bulan J anuari 2014
% Berat Item Area
0,05349
DEG
65880
66490
66195
Average 65307,3

oktor =
umount (%wt)110000
ucu ucugc

oktor =
(0,05349%) 110000
65307,3

oktor = 0,008192
rcsult =
ucu pcuk ]ukto
10000

rcsult =
13820 0,008192
10000

rcsult = 0,01132%

8. Penentuan Kemurnian MEG
%=100% (%E0 +%E
2
0 +%AciJ +%AlJciJ +%As +%Fc +%Cl)
%=100% (0,01132%+0,0246%+(9,37 10
-4
)%+(9,97110
-5
)%
+0%+(4,910
-7
)%+0%)
%=99,963%
66

LAMPIRAN 2
Gambar Alat









Gambar 12. Neraca analit Gambar 13. Instrumen Karl Fischer



Gambar 14. Spektrofotometer Uv-Vis Gambar 15. Piknometer


67



Gambar 16. Alat Kromatografi Gas