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    امتحان الميكانيكا اعدادي واجابته النموذجية هندسة الفيوم 2008/2009

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    امتحان الميكانيكا اعدادي واجابته النموذجية هندسة الفيوم 2008/2009

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    Attribution Non-Commercial (BY-NC)
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    68 views6 pages

    Prep Chemistry

    Uploaded by

    talaba4fayoum
    امتحان الميكانيكا اعدادي واجابته النموذجية هندسة الفيوم 2008/2009

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 6
    Final Engineering chemistry Exam for Pre-Engineering Students 2009 Model Answer Question one 1-b)6.5L 2- b) 440.25 mm.Hg Py 4-a) 0.0" 5-b)Ke > Kb nan 7-b) pH = pk, 8-c) AG= oN yh 10- d) 1.7.x 10° uest mn two a) Definition i. Boiling Pee in dynes acting along the surfaace of a liquid \fo ny tine Lem in lengoh and has the units dyne Cm-1 J as the work in ergs necessary to generate 1Cm2 of surface area. iii- Molar heat of vaporization is the quantity of heat absorbed in converting one gm of a liquid into one gm of vapour at constant temperature iv- Standard Electrode potential is the potential of electrode obtained in solution of 1.0M of their ions and at 25 C’. ) Th where p=125mm_— 1; =30+273 =303 k px= 500mm — T; =67+273 =340 k R= 1.987 cal T, =57+273 =330k I 500 AHy 340-330, \ - og ( }) Pp 2.303x1.987° 340x330 a \ Hg/Hg.Cl/KCI ©) fillng hole satd KC] solution Hg/HaCly emulsion Hg,Cl; = Hey + 2CT Hg?) +2e = 2Hg Hg2Cl, . 2e si 2Hg+ 2CT E= Be, 295" og [Hg2Cl}- [Hg] = 1 E= E°. 0.039 log [CI] on \X Oxygen electrode — Pt /(O;/H,0 /OH O2.2H,0 +4 Ee og li.0 Tro, ] 4 lou } ew = E= E’_ 0.059 log [OH] Question three Zn +20H'= Zn(OH),+2e- anodic reacton Ag.O + H,0 + 2e = 2Ag + 20H’ cathodic reaction Zn+ Ag,O+H,0= Zn(OH): + 2Ag cell reaction Zn / OH // H,0/ Ag,0 the cell Cd + 20H = Cd(OH); + 2e- anodic reaction NiO, +2 H,O + 2e° = Ni(OH), + 20H’ cathodic reaction Cd + NiO; +2H,0 = Ni(OH); + Cd(OH), cell reaction Cd / OH // H2O/ NiO) the cell Wa= a+ YB “Yaa S= Wa-We San= Wa ~ Wea Sna= Wa- Way \ San= Yat YerYan-2Ya San= Ya-¥ arty ~Y 3. Al = Al’ #3e Ahodic) 3Ag’ +3e = 3Ag Cathodic reaction Al+3 Ag’ =AP +3Ag cell reaction AL/AP oom / Ag | tog 0.1 2 log 0.1 Where E.M.F = Ee- Ea Question four a) Hind = H’ + Ind” lH Jina ] [Hing | [HY =K jy Wet] [int] PH=PpK ing + 10g Ln] [Hind | For [Ind] color pH = pK + log e =pK+1 For [HInd] color pH = pK + log is =pK-1 pH = pk#1 f b) PCI; = PCh+Ch Cla) Ca Ca Ke= ed Poets Pas Kpo op Total P= P pes Po Ra Kren Total AS rate 1. Pres = Pow = oo Pt + Peas = “Pt lea Lisa ase) kp= ea) a)” co = Kp # Ke \ NS 2194 3p pamenyoyy> pomny. .» a ree = Hd Tan 10 . —) too P+ tlt = Hd \ “~ re peat Sol +d = Hd “mu ) ol=Hd Hod-p1 = Hd [.Ho]80]- = Hod W,.01 = 10°0 X 10°0 = 99 = LHO] + =ud Hod-p1 = Hd

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