Tp san KHOA HC & CNG NGH * S 2-2014

71

S mol ur c tnh theo l thuyt l 6,68 ln s mol sn phm (nur =

6,68nCAO). Tuy nhin, cc kt qu thc nghim chng t rng s mol ur ln hn
nhiu, ty thuc vo quy trnh v nhit n [5], [6], [7], [8]. Trong bo co ny,
chng ti chn nng ur nur = 18 nCAO v nhit n l 580oC.
III. KT QU V THO LUN
Cu trc ca vt liu CAO: Eu2+ c kho st thng qua gin nhiu x
tia X v c th hin trn hnh 2. Gin nhiu x th hin cc vch c trng ca
vt liu CaAl2O4, khng xut hin cc thnh phn pha ph khc. Hm lng ion t
him Eu2+ pha tp nh khng nh hng n cu trc ca vt liu. Vt liu c cu
trc n pha n t.
Faculty of Chemistry, VNU, D8 ADVANCE-Bruker - CAO18
CAO20
300
290
280
270
260
250
240
230

d=2.968

220
210
200
190

Lin (Cps)

180
170
160
150
140
130
120

40

d=1.455

50

d=1.528

d=4.670

d=2.864

60

d=1.922

70

d=2.600

80

d=2.023

90

d=2.333

d=2.518

100

d=2.405

110

30
20
10
0
15

20

30

40

50

60

2-Theta - Scale
File: Hung(ManhSon) CAO20.raw - Type: Locked Coupled - Start: 15.000 - End: 65.010 - Step: 0.030 - Step time: 0.3 s - Temp.: 25 C (Room) - Time Started: 10 s - 2-Theta: 15.000 - Theta: 7.500 - C
01-070-0134 (C) - Calcium Aluminum Oxide - CaAl2O4 - Y: 73.28 % - d x by: 1. - WL: 1.5406 - Monoclinic - a 8.70000 - b 8.09200 - c 15.19100 - alpha 90.000 - beta 90.170 - gamma 90.000 - Primitive - P21/

Hnh 2: Gin XRD ca vt liu CAO: Eu2+(1% mol),

Vt liu CaAl2O4: (x % mol) Eu2+ vi x = 0,5; 1,0; 1,5; 2,0 (CAO: Eu2+)
c ch to bng phng php n. Cng pht quang ca mu c kho st
thng qua ph pht quang v c m t hnh 3. Ph pht quang ca cc mu u
c dng di rng vi cc i bc x 444 nm do chuyn di in t t cu hnh
4f65d1 sang 4f7 ca ion Eu2+ trong mng nn CaAl2O4, khng quan st thy cc vch
c trng ca Eu3+, chng t rng cc ion Eu3+ c kh hon ton thnh ion Eu2+
[2], [3], [6], [8]. Cng pht quang tng khi nng Eu2+ tng, v t cc i
khi nng Eu2+ bng 1,5 % mol. Tuy nhin, nu nng Eu2+ ln hn 1,5 % mol
th cng pht quang gim. iu ny l do khi tng nng Eu2+ th mt tm