1. a) Write the structure of a homogeneous organometallic catalyst for hydrogenation reaction.

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mechanism using this catalyst giving emphasis on stereochemistry of the product. 1+3 = 4
b) What is the industrial process for synthesis of acetic acid? Give account of complete catalytic cycle for
continuous synthesis of acetic acid. 1+3 = 4
c) What is the role of copper salt in Wacker process? What will be the product of Wacker oxidation of
1-butene? 1+1 = 2

2. a) Write the structure and function of Zieglar-Natta Catalyst. Give mechanism for initiation,
propagation and termination step using this catalyst. What is the role of alkyl aluminum compound?
1+2+1 = 4
b) What is the best procedure to achieve following transformation? Write appropriate reagent and show
complete catalytic mechanism for product formation. What is the role of copper salt? 1+2+2+1 = 6
Br