TIU CHUN VIT NAM TCVN 6089 :1995

CAO SU THIN NHIN - XC NH HM LNG CHT BN

Natural rubber Determination of dirt content


1. Phm vi p dng
Tiu chun ny qui nh phng php xc nh hm lng cht bn ca cc loi cao su
thin nhin trong c cao su SVR dng th, khng p dng i vi s nhim cht bn trn
b mt cao su.
2. Tiu chun trch dn
TCVN 3769 : 1995 Cao su thin nhin SVR
TCVN 6086 :1995 Cao su thin nhin- Ly mu v chun b mu th
3. Nguyn tc ca phng php
Ho tan cao su trong dung mi c im si nhit khong t 160 n 190
0
C, sau
lc dung dch qua ry c kch thc l 45 m.Cht bn cn li trn ry c ra k, sy kh
v cn.
4.Thuc th
4.1 Dung mi l white spirit ( mineral turpentine) c im si t 155 n 196
0
C.
4.2 Cht peptic RPA3 ( xylyl mercaptan 36 %).
trnh bn v nc ln vo, trc khi dng white spirit v RPA3 phi c lc qua
giy lc. Nu RPA3 c mu vng, chng t b ln nc.
5. Thit b
5.1 My cn cao su hai trc, loi dng cho cc phng th nghim
5.2 Cn phn tch c chnh xc n 0,1 mg
5.3 Bp bng n hng ngoi , nhit t 100 n 150
0
C
5.4 Ry c kch thc l l 45 m.
Khung ry bng thp khng r hoc ng thau, ng knh trong 24 mm, ng knh
ngoi 28 mm, chiu cao 15 mm (xem hnh 1)
5.5 Ga ry bng thp khng r hoc ng thau
5.6 Bnh nn, dung tch 250 cm
3
hoc 500 cm
3

5.7 Bnh lc thu tinh, dung tch 2000 cm
3

5.8 My ra ry bng siu m
5.9 My ht chn khng
5.10 T sy c th sy n 160
0
C
6. Phng php th
6.1 Chun b th
Ly khong 20 g n 30 g mu A theo TCVN 6086:1995 em cn hai ln qua my
cn(5.1) lm ngui bng nc si ti nhit phng. Khe h gia hai trc cn l 0,5 mm
0,1 mm
Cn khong 10 g mu, chnh xc n 0,1 mg. Dng ko ct mu thnh si nh( khong
10-15 si). Cho cc si mu vo bnh nn ( 5.6) c cha sn khong t 150 n 200 cm
3
dung
mi ( 4.1) v 1 cm
3
cht peptic(4.2).
6.2 Tin hnh th
6.2.1 Ho tan cao su
bnh nn chun b theo iu 6.1 ln bp ( 5.3) c t nng trc. Xp cc
bnh nn thng hng theo s th t, Lc u bnh nn cao su nhanh tan hon ton v khng
b chy y bnh. Khong t 15 n 30 pht lc mt ln. Khi lc, phi em bnh ra khi bp
v khng ming bnh i din vi mt bp.
6.2.2 Lc cao su
bnh lc( 5.7) ln a nhm c ng knh bng khong 1,5 ln ng knh y
bnh. Gn gi ry ( 5.5) vo ming bnh lc- t ry ( 5.4) ( sy kh v cn trc) ln
gi . Phun ln ry mt t dung mi ( 4.1) nng.
Dng kp gp bnh nn ( 5.6) ra khi bp. Cn thn v t t rt dung dch vo ry. Khi
rt, khng dung dch trn ra ngoi hoc dnh ln ming ry
Khi dung dch chy ht, dng khong 100 cm
3
dung mi( 4.1) nng ra bnh nn,
ra ry v ra tp cht nhiu ln
C th dng my ht chn khng ( 5.9) trong qu trnh lc
Trng hp cao su khng tan hon toanmf to thnh cht keo dnh vo ry trong v sau
khi lc, phi ho tan li bng cch cho ton b ry v cht dnh trong ry vo mt cc thu
tinh cha dung mi( 4.1) nng vi 1 ml hoc 2 ml cht peptic. Khi tan ht, tin hnh lc li.
6.2.3 Sy
Sau khi lc, sy ry cng vi tp cht 100
0
C 5
0
C

trong t

sy( 5.10) khong 1 gi.
Sau ngui trong bnh ht m 30 pht, ri cn chnh xc n 0,1 mg.
Ch thch
1) NNhng dng c tip xc vi dung dch cao su phi c ra sch, sy kh v
kim tra k trc khi s dng m bo chnh xc v trnh ho hon.
2) Nn ra ry bng my siu m (5.8) tin hnh nh sau: Xp ry vo b ra
n ngp ry ra cao su. Ch vn hnh my khi ct cht lng tnh t y b ra ti thiu l
7 cm. Cho my chy 15 pht. Thay hn hp ra bng dung dch x phng v chy my 15
pht na.Ra xong sy ry 100
0
C trong 30 pht v lm ngui trong bnh ht m trc khi
cn.
3) Dng n chiu kim tra tnh trng ca ry

7. Tnh kt qu
Hm lng cht bn ( X
1
) c tnh bng phn trm, theo cng thc:
m
2
m
1

X
1
= x 100
m
0


Trong
m
0
l khi lng mu th, tnh bng gam;
m
1
l khi lng ry, tnh bng gam;
m
2
l khi lng ry v cht bn, tnh bng gam.