TRNG CAO NG CNG NGHIP HU

70
II. PHNG PHP NGHIN CU
Vt liu CAO: Eu
2+
c ch to bng phng php n dung dch ur-nitrat.
Thnh phn hp thc ca hn hp cht oxi ha - kh c tnh ton da vo phng
trnh phn ng:
(1 - x - y)Ca(NO
3
)
2
+ 2Al(NO
3
)
3
+ xEu(NO
3
)
3
+ 6.68(NH
2
)
2
CO CaAl
2
O
4
:
xEu
2+
+ sn phm ph
Quy trnh ch to vt liu c biu din hnh 1. Thnh phn ban u l
cc mui nitrat kim loi Al(NO
3
)
3
.9H
2
O

(Merck), Ca(NO
3
)
2
.4H
2
O

(Merck), v cc
oxit t him Eu
2
O
3
(Merck), B
2
O
3
(AR), ur ((NH
2
)
2
CO) (AR), v HNO
3
(AR).
u tin, cc oxit Eu
2
O
3
c nitrat ha bng axit HNO
3
a v dng dung dch
mui nitrat Eu(NO
3
)
3
. Hn hp cc mui nitrat kim loi c ha tan vi nc ct
hai ln nng thch hp. (NH
2
)
2
CO c s dng lm nhin liu cho qu trnh
n v ng thi lm cht kh. B
2
O
3
ng vai tr l cht chy. Hn hp cc dung
dch mui kim loi cng vi ur v B
2
O
3
c khuy gia nhit 70
o
C to thnh
gel. Gel c sy trong 4h 80
o
C, sau c n 580
o
C trong 5 pht. Sn phm
thu c c dng xp mu trng.













Hnh 1: Quy trnh ch to vt liu CaAl
2
O
4
: Eu
2+
bng phng php n
Ca(NO
3
)
2
.4H
2
O,
Al(NO
3
)
3
.9H
2
O
Eu
2
O
3

Dung dch cc mui
nitrat
H
2
O HNO
3

Dung dch cc cht
oxi ha v cht kh
Cht chy B
2
O
3
Nhin liu (NH
2
)
2
CO
Gel
Khuy gia nhit
Sy 4h 80
o
C
Gel trng c
N 580
o
C trong 5 pht
Sn phm CaAl
2
O
4
: Eu
2+