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BG Polyme Ch3 Mach Polyme
BG Polyme Ch3 Mach Polyme
n
g
S thay i nng lng ca 1,2-
dicloetan khi mt phn phn t
quay so vi phn kia. Pha di l
cc hnh chiu phn t ng vi
cc gc quay
9
Trong thc t, s quay ni ti ca phn t polyme b cn tr do:
Lc tc dng gia cc phn t (intramolecular interation): lc
lin kt hydro, lc Vandevan, lc phn tc, lc nh hng
Lc tc dng gia cc nguyn t (intermolecular interation)
trong cng mt mch (lc ni phn t):
Tc dng tng h khong cch gn gia cc nguyn t
ca cc mt xch ln cn cn tr quay t do.
Tc dng tng h khong cch xa l lc tc dng tng
h gia cc nguyn t hoc nhm nguyn t ca cc mt
xch cch xa nhau.
10
mm do ca polyme
Phn t phi ph
v tmthi lin
kt quay ri
mi khi phc li
khi quay xong.
V tr tng i ca cc nguyn
t v nhm nguyn t trong
phn t khng th thay i
c nu khng ph v cc
lin kt ho hc, gi l hnh
thi cu to ca phn t.
11
3.1.3. mm nhit ng v mm ng hc
i-1
i
i+1
E
o
E
1 E
2
E
E