CNG HA X HI CH NGHA VIT NAM

QCVN 07: 2009/BTNMT

QUY CHUN K THUT QUC GIA
V NGNG CHT THI NGUY HI
National Technical Regulation on Hazardous Waste
Thresholds





















H NI - 2009


QCVN 07: 2009/BTNMT
2


Li ni u

QCVN 07: 2009/BTNMT do Ban son tho quy chun
k thut quc gia v cht thi rn bin son, Tng cc
Mi trng, V Khoa hc v Cng ngh, V Php ch
trnh duyt v c ban hnh theo Thng t
s 25/2009/TT-BTNMT ngy 16 thng 11 nm 2009
ca B Ti nguyn v Mi trng.

QCVN 07: 2009/BTNMT
3
QUY CHUN K THUT QUC GIA
V NGNG CHT THI NGUY HI
National Technical Regulation on Hazardous Waste Thresholds

1. QUY NH CHUNG
1.1. Phm vi iu chnh
Quy chun ny quy nh ngng cht thi nguy hi i vi cc cht thi
v hn hp ca cc cht thi (tr cht thi phng x, cht thi th kh v
hi) c tn tng ng trong Danh mc cht thi nguy hi do B Ti nguyn v
Mi trng ban hnh.
1.2. i tng p dng
Quy chun ny p dng i vi: cc t chc, c nhn pht sinh cht
thi; cc n v c hot ng thu gom, vn chuyn, lu gi, x l, tiu hu,
chn lp cht thi; cc c quan qun l nh nc; n v ly mu, phn tch
v cc t chc, c nhn khc c hot ng lin quan n cht thi.
1.3. Gii thch t ng
Trong quy chun ny, cc t ng di y c hiu nh sau:
1.3.1. Cht thi nguy hi (CTNH) l nhng cht thi c tn (mi tn cht
thi tng ng vi mt m CTNH) trong Danh mc CTNH do B Ti nguyn
v Mi trng ban hnh (sau y gi tt l Danh mc CTNH), c chia
thnh hai loi sau:
a) L CTNH trong mi trng hp (c k hiu ** trong Danh mc
CTNH);
b) C kh nng l CTNH (c k hiu * trong Danh mc CTNH) c t nht
mt tnh cht nguy hi hoc mt thnh phn nguy hi vt ngng CTNH
theo quy nh ti Phn 2 ca Quy chun ny.
1.3.2. Ngng CTNH (cn gi l ngng nguy hi ca cht thi) l gii
hn nh lng tnh cht nguy hi hoc thnh phn nguy hi ca mt cht thi
lm c s phn nh, phn loi v qun l CTNH.
1.3.3. Cht thi ng nht (homogeneous) l cht thi c thnh phn v
tnh cht ho-l tng i ng nht ti mi im trong khi cht thi.

QCVN 07: 2009/BTNMT
4
1.3.4. Hn hp cht thi l hn hp ca t nht hai loi cht thi ng
nht, k c trng hp c ngun gc do kt cu hay cu thnh c ch nh
(nh cc phng tin, thit b thi). Cc cht thi ng nht cu thnh nn
hn hp cht thi c gi l cht thi thnh phn.
Hn hp cht thi m cc cht thi thnh phn c ho trn vi
nhau mt cch tng i ng nht v tnh cht ho-l ti mi im trong khi
hn hp cht thi th c coi l cht thi ng nht.
1.3.5. Tp cht bm dnh l cc cht lin kt cht trn b mt (vi
dy trung bnh khng qu 01 mm hoc hm lng khng qu 01% trn tng
khi lng cht thi, khng b ri ra trong iu kin bnh thng) ca cht thi
hoc hn hp cht thi nn dng rn v khng c coi l cht thi thnh
phn trong hn hp cht thi.
1.3.6. Hm lng tuyt i l hm lng phn trm (%) hoc phn triu
(ppm) ca mt thnh phn nguy hi trong cht thi. Ngng hm lng tuyt
i (H
tc
) l ngng CTNH tnh theo hm lng tuyt i.
1.3.7. Nng ngm chit (eluate/leaching) l nng (mg/l) ca mt
thnh phn nguy hi trong dung dch sau ngm chit, c thi ra t cht thi
khi tin hnh chun b mu phn tch bng phng php ngm chit. Ngng
nng ngm chit (C
tc
) l ngng CTNH tnh theo nng ngm chit.
1.3.8. Phng php ngm chit l phng php EPA 1311 hoc ASTM
5233-92 quy nh ti Phn 4 ca Quy chun ny.
1.3.9. Dung dch ngm chit l dung dch c pha ch s dng cho
vic ngm chit cht thi theo phng php ngm chit.
1.3.10. Dung dch sau ngm chit l dung dch thu c t qu trnh
ngm chit mu cht thi theo phng php ngm chit.

2. QUY NH K THUT V NGNG CTNH
2.1. Nguyn tc chung
2.1.1. Mt cht thi c k hiu * trong Danh mc CTNH c phn nh
l CTNH nu c t nht mt trong cc iu kin sau y:
QCVN 07: 2009/BTNMT
5
a) C t nht mt tnh cht nguy hi vt ngng CTNH (nhit chp
chy, kim hoc axit tng ng vi cc mc gi tr quy nh ti ct
Ngng CTNH trong Bng 1);
b) C t nht mt thnh phn nguy hi v c hoc hu c m ng thi
gi tr hm lng tuyt i v gi tr nng ngm chit u vt ngng
CTNH (ln hn hoc bng mc gi tr ngng hm lng tuyt i (H
tc
) v
ngng nng ngm chit (C
tc
) quy nh ti im 2.1.5).
Trng hp khng s dng c hai gi tr hm lng tuyt i hoc
nng ngm chit (i vi cc thnh phn nguy hi khng c c hai ngng
H
tc
v C
tc
hoc khng c iu kin s dng c hai ngng) th vic phn nh
CTNH s ch p dng theo mt ngng c s dng.
2.1.2. Mt cht thi c k hiu * trong Danh mc CTNH c phn nh
khng phi l CTNH nu tt c cc tnh cht hoc thnh phn nguy hi u
khng vt ngng CTNH (hay cn gi l di ngng CTNH), c th nh
sau:
a) Nhit chp chy, kim hoc axit khng tng ng vi
cc mc gi tr quy nh ti ct Ngng CTNH trong Bng 1;
b) Tt c cc thnh phn nguy hi u c gi tr nh hn mt trong hai
ngng hm lng tuyt i (H
tc
) hoc ngng nng ngm chit (C
tc
) quy
nh ti im 2.1.5.
2.1.3. Trng hp mt cht thi c phn nh l CTNH, bt k
thuc loi * hoc ** trong Danh mc CTNH th ch c phn loi theo tn v
m CTNH ca loi c cha mt (hoc mt nhm) thnh phn nguy hi nht
nh khi thnh phn ny (hoc t nht mt thnh phn trong nhm thnh phn)
vt ngng hm lng tuyt i (H
tc
) quy nh ti im 2.1.5; nu khng
vt ngng hm lng tuyt i (H
tc
) th khng phn loi theo thnh phn
nguy hi ny, hay mt cch biu kin, thnh phn nguy hi ny c coi l
khng c trong cht thi ( mc nguy hi).
2.1.4. Mt CTNH sau khi c x l m tt c cc tnh cht hoc thnh
phn nguy hi u di mt trong hai ngng H
tc
hoc C
tc
th khng cn l
CTNH v khng phi qun l theo cc quy nh i vi CTNH.
2.1.5. Ngng hm lng tuyt i (H
tc
) v ngng nng ngm chit
(C
tc
) c xc nh theo nguyn tc nh sau:
QCVN 07: 2009/BTNMT
6
a) Ngng nng ngm chit (C
tc
, mg/l) c quy nh ti ct Nng
ngm chit, C
tc
ca Bng 2 v 3;
b) Ngng hm lng tuyt i (H
tc
, ppm) c tnh bng cng thc
sau:
H
tc
=
H.(1+19.T)
20
Trong :
- H (ppm) l gi tr quy nh trong ct Hm lng tuyt i c s, H
ca Bng 2 v 3 ca Quy chun lm c s tnh ton gi tr H
tc
;
- T l t s gia khi lng thnh phn rn kh trong mu cht thi trn
tng khi lng mu cht thi.
2.2. Gi tr ngng CTNH
2.2.1. Cc tnh cht nguy hi
Bng 1: Cc tnh cht nguy hi
TT Tnh cht nguy hi Ngng CTNH
1 Tnh d bt chy Nhit chp chy 60
0
C


2 Tnh kim pH 12,5
3 Tnh axt pH 2,0

QCVN 07: 2009/BTNMT
7
2.2.2. Cc thnh phn nguy hi v c
Bng 2: Cc thnh phn nguy hi v c
TT Thnh phn nguy hi
(1)

Cng thc
ho hc
Ngng CTNH
Hm lng
tuyt i c
s, H (ppm)
Nng
ngm chit,
C
tc
(mg/l)
Nhm kim loi nng v hp cht v c ca chng
(tnh theo nguyn t kim loi)
1 Antimon (Antimony)
(2)
Sb 20 1
2 Asen (Arsenic)
(#)
As 40 2
3
Bari (Barium) tr bari
sunphat (barium sulfate)
Ba 2.000 100
4 Bc (Silver)
(#)(2)
Ag 100 5
5 Beryn (Beryllium)
(#)
Be 2 0,1
6 Cadmi (Cadmium)
(#)
Cd 10 0,5
7 Ch (Lead)
(2)
Pb 300 15
8 Coban (Cobalt) Co 1.600 80
9 Km (Zinc)
(2)
Zn 5.000 250
10
Molybden (Molybdenum)
tr molybden disunphua
(molybdenum disulfide)
Mo 7.000 350
11 Nicken (Nickel)
(2)
Ni 1.400 70
12 Selen (Selenium)
(#)
Se 20 1
13 Tali (Thallium) Ta 140 7
14 Thy ngn (Mercury)
(#)
Hg 4 0,2
15 Crom VI (Chromium VI)
(#)(2)
Cr 100 5
16 Vanadi (Vanadium) Va 500 25
Cc thnh phn v c khc
17
Mui florua (Fluoride) tr
canxi florua (calcium
floride)
F
_
3.600 180
18
Xyanua hot ng
(Cyanides amenable)
(#)

CN- 30
19
Tng Xyanua
(Total cyanides)
(4)

CN- 590
20 Aming (Abestos)
(5)
10.000
QCVN 07: 2009/BTNMT
8
2.2.3. Cc thnh phn nguy hi hu c
Bng 3: Cc thnh phn nguy hi hu c
TT Thnh phn nguy hi
(1)
S CAS
(3)

Cng thc
ho hc
Ngng CTNH
Hm
lng
tuyt
i
c s,
H (ppm)
Nng

ngm
chit,
C
tc

(mg/l)
Cresol/Phenol
1a o-Cresol (o-Cresol) 95-48-7 CH
3
C
6
H
4
OH 4.000 200
1b m-Cresol (m-Cresol) 108-39-4 CH
3
C
6
H
4
OH 4.000 200
1c p-Cresol (p-Cresol) 106-44-5 CH
3
C
6
H
4
OH 4.000 200
1 Tng Cresol
(4)
CH
3
C
6
H
4
OH 4.000 200
2 2-4-Dimetyl phenol (2,4-Dimethyphenol) 105-67-9 C
6
H
3
(CH
3
)
2
OH 1.400 70
3 2-6-Dimetyl phenol (2,6-Dimethyphenol) 576-26-1 C
6
H
3
(CH
3
)
2
OH 400 20
4 Phenol (Phenol) 108-95-2 C
6
H
5
OH 20.000 1.000
Clophenol
5 2-Clophenol (2-Chlorophenol) 95-57-8 C
6
H
5
ClO 400 20
6 2,4-Diclophenol (2,4-Dichlorophenol) 120-83-2 C
6
H
3
Cl
2
OH 200 10
7 2,6-Diclophenol (2,6-Dichlorophenol) 87-65-0 C
6
H
3
Cl
2
OH 3.000
8 Pentaclophenol (Pentachlorophenol) 87-86-5 C
6
OHCl
5
2.000 100
QCVN 07: 2009/BTNMT
9
9 2,3,4,6-Tetraclophenol (2,3,4,6-Tetrachlorophenol) 58-90-2 C
6
HCl
4
OH 2.000 100
10 2,4,5-Triclophenol (2,4,5-Trichlorophenol) 95-95-4 C
6
H
2
Cl
3
OH 8.000 400
11 2,4,6-Triclophenol (2,4,6-Trichlorophenol)
(#)
88-06-2 C
6
H
2
Cl
3
OH 40 2
Nitrophenol
12
2-Butyl-4,6-dinitrophenol
(2-sec-Butyl-4,6-dinitrophenol/Dinoseb)
(#)

88-85-7 C
10
H
12
N
2
O
5
70 3,5
13 2,4-Dinitrophenol (2,4-Dinitrophenol) 51-28-5 C
6
H
3
OH(NO
2
)
2
140 7
14a o-Nitrophenol (o-Nitrophenol) 88-75-5 C
6
H
4
OHNO
2
10.000
14b p-Nitrophenol (p-Nitrophenol) 100-02-7 C
6
H
4
OHNO
2
10.000
14 Tng Nitrophenol
(4)
C
6
H
4
OHNO
2
10.000
Dn xut halogen ca hydrocacbon d bay hi
15 Bromdiclometan (Bromodichloromethane)
(#)
75-27-4 CHBrCl
2
6 0,3
16 Brommetan/Metyl bromua (Bromomethane/Methyl bromide)
(#)
74-83-9 CH
3
Br 100 5
17 Cacbon tetraclorua (Carbon tetrachloride)
(#)
56-23-5 CCl
4
10 0,5
18 Clobenzen (Chlorobenzene) 108-90-7 C
6
H
5
Cl 1.400 70
19 Clodibrommetan (Chlorodibromomethane) 124-48-1 CHClBr
2
3.000
20 Cloetan (Chloroethane) 75-00-3 C
2
H
5
Cl 1.000
21 Clorofom (Chloroform)
(#)
67-66-3 CHCl
3
100 5
22 Clometan/Methyl clorua (Chloromethane/Methyl chloride) 74-87-3 CH
3
Cl 1.000
23
1,2-Dibrometan/Etylen dibromua
(1,2-Dibromoethane/Ethylene dibromide)
(#)

106-93-4 C
2
H
4
Br
2
0,2 0,01
QCVN 07: 2009/BTNMT
10
24 Dibrommetan (Dibromomethane) 74-95-3 CH
2
Br
2
20.000
25 Diclodiflometan (Dichlorodifluoromethane) 75-71-8 CCl
2
F
2
1.400 700
26a 1,1-Dicloetan (1,1-Dichloroethane)
(#)
75-34-3 C
2
H
4
Cl
2
10 0,5
26b 1,2-Dicloetan (1,2-Dichloroethane)
(#)
107-06-2 C
2
H
4
Cl
2
10 0,5
26 Tng Dicloetan
(#)(4)
C
2
H
4
Cl
2
10 0,5
27 1,1-Dicloetylen (1,1-Dichloroethylene)
(#)
75-35-4 C
2
H
2
Cl
2
10 0,5
28a m-Diclobenzen (m-Dichlorobenzene)
(#)
541-73-1 m-C
6
H
4
Cl
2
100 5
28b o-Diclobenzen (o-Dichlorobenzene)
(#)
95-50-1 o-C
6
H
4
Cl
2
100 5
28c p-Diclobenzen (p-Dichlorobenzene)
(#)
106-46-7 p-C
6
H
4
Cl
2
100 5
28 Tng Diclobenzen
(#)(4)
100 5
29 1,3-Diclopropen (1,3-Dichloropropene)
(#)
542-75-6 C
3
H
4
Cl
2
20 1
30 cis-1,3-Diclopropylen (cis-1,3-Dichloropropylene) 10061-01-5 C
3
H
4
Cl
2
3.000
31 trans-1,2-Dicloetylen (trans-1,2-Dichloroethylene) 156-60-5 C
2
H
2
Cl
2
20.000
32 trans-1,3-Diclopropylen (trans-1,3-Dichloropropylene) 10061-02-6 C
3
H
4
Cl
2
3.000
33 Metylen clorua (Methylene chloride) 75-09-2 CH
2
Cl
2
1.000 50
34 1,1,1,2-Tetracloetan (1,1,1,2-Tetrachloroethane)
(#)
630-20-6 C
2
H
2
Cl
4
100 5
35 1,1,2,2-Tetracloetan (1,1,2,2-Tetrachloroethane)
(#)
79-34-5 C
2
H
2
Cl
4
40 2
36 Tetracloetylen (Tetrachloroethylene)
(#)
127-18-4 C
2
Cl
4
10 0,5
37 Tribrommetan/Bromofom (Tribromomethane/Bromoform) 75-25-2 CHBr
3
1.400 70
38 1,1,1-Tricloetan (1,1,1-Trichloroethane) 71-55-6 C
2
H
3
Cl
3
6.000 300
39 1,1,2-Tricloethan (1,1,2-Trichloroethane)
(#)
79-00-5 C
2
H
3
Cl
3
100 5
QCVN 07: 2009/BTNMT
11
40 Tricloetylen (Trichloroethylene)
(#)
79-01-6 C
2
HCl
3
20 1
41 Vinyl clorua (Vinyl chloride)
(#)
75-01-4 C
2
H
3
Cl 4 0,2
Hydrocacbon d bay hi
42 Benzen (Benzene)
(#)
71-43-2 C
6
H
6
10 0,5
43 Etyl benzen (Ethyl benzene) 100-41-4 C
6
H
5
C
2
H
5
8.000 400
44 Toluen (Toluene) 108-88-3 C
6
H
5
CH
3
20.000 1.000
45
Xylen-cc ng phn (tng nng ca o-, m-, p-xylen)
[Xylenes-mixed isomers (sum of o-, m-, and p-xylene
concentrations)]
1330-20-7 C
6
H
4
(CH
3
)
2
20.000 1.000
Hydrocacbon thm a vng (PAH)
46 Antraxen (Anthracene)
(#)
120-12-7 C
14
H
10
100
47 Axenapten (Acenaphthene) 83-32-9 C
12
H
10
4.000 200
48 Benzantraxen (Benz(a)anthracene)
(#)
56-55-3 C
18
H
12
100
49 Dibenz(a,h)antraxen (Dibenz(a,h)anthracene)
(#)
53-70-3 C
22
H
14
100
50 Benzo(j)fluoranten (Benzo(j)fluoranthene) 205-82-3 C
20
H
12
3.000
51 Benzo(k)floanten (Benzo(k)fluoranthene)
(#)
207-08-9 C
20
H
12
100
52 Benzo(a)pyren (Benzo(a)pyrene)
(#)
50-32-8 C
20
H
12
100
53 Crysen (Chrysene)
(#)
218-01-9 C
18
H
12
100
54 Floanten (Fluoranthene) 206-44-0 C
16
H
10
3.000 150
55 Floren (Fluorene) 86-73-7 C
13
H
10
3.000 150
56 Naptalen (Naphthalene) 91-20-3 C
10
H
8
1.000
QCVN 07: 2009/BTNMT
12
57 Phenantren (Phenanthrene) 85-01-8 C
14
H
10
200
58 Pyren (Pyrene)
(#)
129-00-0 C
16
H
10
100 5
Phtalat
59 Butyl benzyl phtalat (Butyl benzyl phthalate) 85-68-7 C
19
H
20
O
4
10.000 500
60 Dietyl phtalat (Diethyl phthalate) 84-66-2 C
6
H
4
(COOC
2
H
5
)
2
20.000 1.000
61 Dietyl hexyl phtalat [Bis(2-ethylhexyl) phthalate] 117-81-7 C
24
H
38
O
4
600 30
62 Dimetyl phtalat (Dimethyl phthalate) 131-11-3 C
6
H
4
(COOCH
3
)
2
1.000
63 Di-n-butyl phtalat (Di-n-butyl phthalate) 84-74-2 C
6
H
4
(COOC
4
H
9)2
8.000 400
64 Di-n-octyl phtalat (Di-n-octyl phthalate) 117-84-0 C
6
H
4
(COOC
8
H
17
)
2
1.000
Ho cht bo v thc vt c clo (OCP)
65 Andrin (Aldrin)
(#)
309-00-2 C
12
H
8
Cl
6
10 0,5
66a -BHC (-BHC)
(#)
319-84-6 C
6
H
6
Cl
6
6 0,3
66b -BHC (-beta-BHC)
(#)
319-85-7 C
6
H
6
Cl
6
6 0,3
66c -BHC (-BHC)
(#)
319-86-8 C
6
H
6
Cl
6
6 0,3
66d -BHC/Lindan (-BHC/Lindane)
(#)
58-89-9 C
6
H
6
Cl
6
6 0,3
66 Tng BHC
(#)(4)
C
6
H
6
Cl
6
6 0,3
67 Clodan (Chlordane)
(#)
57-74-9 C
10
H
6
Cl
8
0,6 0,03
68a o,p'-DDD
(#)
53-19-0 C
14
H
10
Cl
4
20 1
68b p,p'-DDD
(#)
72-54-8 C
14
H
10
Cl
4
20 1
68c o,p'-DDE
(#)
3424-82-6 C
14
H
8
Cl
4
20 1
68d p,p'-DDE
(#)
72-55-9 C
14
H
8
Cl
4
20 1
QCVN 07: 2009/BTNMT
13
68e o,p'-DDT
(#)
789-02-6 C
14
H
9
Cl
5
20 1
68g p,p'-DDT
(#)
50-29-3 C
14
H
9
Cl
5
20 1
68 Tng DDD, DDE, DDT
(#)(4)
20 1
69
2,4-Diclophenoxyaxetic axit/2,4-D
(2,4-Dichlorophenoxyacetic acid/2,4-D)
(#)

94-75-7 C
6
H
3
Cl
2
OCH
2
COOH 100 5
70 Dieldrin (Dieldrin)
(#)
60-57-1 C
12
H
8
Cl
6
O 0,4 0,02
71a Endosulfan I (Endosulfan I)
(#)
959-98-8 C
9
H
6
Cl
6
O
3
S 4 0,2
71b Endosulfan II (Endosulfan II)
(#)
33213-65-9 C
9
H
6
Cl
6
O
3
S 4 0,2
71 Tng Endosulfan
(#)(4)
C
9
H
6
Cl
6
O
3
S 4 0,2
72 Endosulfan sulfat (Endosulfan sulfate)
(#)
1031-07-8 C
9
H
6
Cl
6
O
4
S 100
73 Endrin (Endrin)
(#)
72-20-8 C
12
H
8
Cl
6
O 0,4 0,02
74 Endrin aldehyt (Endrin aldehyde)
(#)
7421-93-4 C
12
H
8
Cl
6
O 0,4 0,02
75 Heptaclo (Heptachlor)
(#)
76-44-8 C
10
H
5
Cl
7
0,2 0,01
76 Heptaclo epoxit (Heptachlor epoxide)
(#)
1024-57-3 C
10
H
5
Cl
7
O 0,8 0,04
77 Hexaclobenzen (Hexachlorobenzene)
(#)
118-74-1 C
6
Cl
6
3 0,15
78 Hexaclobutadien (Hexachlorobutadiene)
(#)
87-68-3 C
4
Cl
6
8 0,4
79 Hexaclocyclopentadien (Hexachlorocyclopentadiene)
(#)
77-47-4 C
5
Cl
6
100 5
80 Hexacloetan (Hexachloroethane)
(#)
67-72-1 C
2
Cl
6
60 3
81 Hexaclophen (Hexachlorophene)
(#)
70-30-4 C
13
H
6
Cl
6
O
2
20 1
82 Isodrin (Isodrin)
(#)
465-73-6 C
12
H
8
Cl
6
10
83 Kepon (Kepone)
(#)
143-50-0 C
10
H
10
O 40 2
QCVN 07: 2009/BTNMT
14
84 Metoxyclo (Methoxychlor) 72-43-5 C
16
H
15
Cl
3
O 200 10
85 Mirex (Mirex)
(#)
2385-85-5 C
10
Cl
12
14 0,7
86 Pentaclobenzen (Pentachlorobenzene)
(#)
608-93-5 C
6
HCl
5
60 3
87 Toxaphen (Toxaphene)
(#)
8001-35-2 C
10
H
10
Cl
8
6 0,3
88 1,2,4-Triclobenzen (1,2,4-Trichlorobenzene) 120-82-1 C
6
H
3
Cl
3
1.400 70
Ho cht bo v thc vt c photpho
89 Disulfoton (Disulfoton)
(#)
298-04-4 C
8
H
19
O
2
PS
3
2 0,1
90 Metyl paration (Methyl parathion)
(#)
298-00-0
(CH
3
O)
2
PSO-
C
6
H
4
NO
2

20 1
91 Phorat (Phorate)
(#)
298-02-2 C
7
H
17
O
2
PS
3
100
Ho cht bo v thc vt cacbamat
92 Paration (Parathion) 56-38-2 C
10
H
14
NO
5
PS 400 20
93 Propoxua (Propoxur)
(#)
114-26-1 C
11
H
15
NO
3
100
Cc ho cht bo v thc vt khc
94 Silvex/2,4,5-TP (Silvex/2,4,5-TP)
(#)
93-72-1 C
9
H
7
Cl
3
O
3
20 1
95
2,4,5-Triclophenoxyaxetic axit/2,4,5-T
(2,4,5-Trichlorophenoxyacetic acid/2,4,5-T)
(#)

93-76-5
C
6
H
2
Cl
3
O-
CH
2
COOH
100
Ete
96 Di-Clo etyl ete [bis(2-Chloroethyl)ether]
(#)
111-44-4 C
4
H
8
Cl
2
O 6 0,3
97 Clo metyl ete [bis (Chloromethyl) ether]
(#)
524-88-1 C
2
H
4
Cl
2
O 10
98 Di-Clo isopropyl ete [bis(2-Chloroisopropyl)ether]
(#)
39638-32-9 C
6
H
12
Cl
2
O 100
QCVN 07: 2009/BTNMT
15
99 Dietyl ete (Diethyl ether) 60-29-7 C
2
H
5
OC
2
H
5
20.000
100 Metyl clo metyl ete (Methyl chloromethyl ether)
(#)
107-30-2 CH
3
OCH
2
Cl 10
PCB v Dioxin/Furan
101 PCB (Tng tt c ng phn PCB hoc tt c Aroclo)
(#)
1336-36-3 5
102a 2,3,7,8-TCDD
(#)
1746-01-6 C
12
H
4
Cl
4
O
2
0,1 0,005
102b 1,2,3,7,8-PeCDD
(#)
40321-76-4 C
12
H
3
Cl
5
O
2
0,2 0,01
102c 1,2,3,4,7,8-HxCDD
(#)
57653-85-7 C
12
H
2
Cl
6
O
2
1 0,05
102d 1,2,3,6,7,8-HxCDD
(#)
34465-46-8 C
12
H
2
Cl
6
O
2
1 0,05
102 Tng Dioxin (TCDD, PeCDD, HxCDD)
(#)(6)
0,1 0,005
103a 2,3,7,8-TCDF
(#)
51207-31-9 C
12
H
4
Cl
4
O 1 0,05
103b 1,2,3,7,8-PeCDF
(#)
57117-41-6 C
12
H
3
Cl
5
O 2 0,1
103c 2,3,4,7,8-PeCDF
(#)
57117-31-4 C
12
H
3
Cl
5
O 0,2 0,01
103d 1,2,3,4,7,8-HxCDF
(#)
70648-26-9 C
12
H
2
Cl
6
O 1 0,05
103e 1,2,3,6,7,8-HxCDF
(#)
57117-44-9 C
12
H
2
Cl
6
O 1 0,05
103 Tng Furan (TCDF, PeCDF, HxCDF)
(#)(7)
0,2 0,01
Du (tr loi c ngun gc thc phm)
104a Du hydrocacbon <C
10
1.000 50
104b Du hydrocacbon C
10
-C
16
3.000 150
104c Du hydrocacbon C
17
-C
34
5.000 250
104d Du hydrocacbon C
35
10.000 500
104 Tng du
(8)
1.000 50
QCVN 07: 2009/BTNMT
16
Hp cht c kim
105 Tng thu ngn hu c
(#)
100
106 Tng ch hu c
(#)
10
Hp cht silic hu c
107 Metyl etyl dimetoxy silan [Bis(1-methylethyl)-dimethoxysilane] 18230-61-0 C
8
H
20
O
2
Si 20.000
108
Bis(4-flophenyl) (metyl) (1H-1,2,4-triazol-1-ylmetyl) silan
[Bis(4-fluorophenyl)(methyl)(1H-1,2,4-triazol-1-ylmethyl)silane]
85509-19-9 C
16
H
15
F
2
N
3
Si 1.000
109 Isobutyl isopropyl dimetoxy silan (Isobutylisopropyldimethoxysilane) 111439-76-0 C
9
H
22
O
2
Si 20.000
110 Tetraetyl silicat (Tetraethyl silicate) 78-10-4 (C
2
H
5
O)
4
Si 20.000
111 Trietoxy isobutyl silan (Triethoxyisobutylsilane) 17980-47-1 C
10
H
24
O
3
Si 20.000
112
Tris(isopropenyloxy) phenyl silan
[Tris(isopropenyloxy)phenyl silane]
(#)

52301-18-5 100
Cc thnh phn hu c khc
113 Acrylamid (Acrylamide)
(#)
79-06-1 C
2
H
3
CONH
2
1,6 0,08
114 Acrylnitril (Acrylonitrile)
(#)
107-13-1 C
2
H
3
CN 12 0,6
115 4-Aminodiphenyl (4-Aminodiphenyl)
(#)
92-67-1 C
12
H
9
NH
2
10
116 Anilin (Aniline 62-53-3 C
6
H
5
NH
2
1.200 60
117 Axetonitril (Acetonitrile) 75-05-8 CH
3
CN 400 20
118 Axeton (Acetone) 67-64-1 C
3
H
6
O 8.000 400
119 Axetophenon (Acetophenone) 96-86-2 C
8
H
8
O 8.000 400
120 2-Axetylaminfloren (2-Acetylaminofluorene) 53-96-3 C
15
H
13
NO 200 10
QCVN 07: 2009/BTNMT
17
121 Benzal clorua (Benzal chloride)
(#)
98-87-3 C
7
H
6
Cl
2
100
122 Benzidin (Benzidine) v mui ca chng
(#)
92-87-5 C
12
H
8
(NH
2
)
2
0,2 0,01
123 n-Butyl alcol (n-Butyl alcohol) 71-36-3 C
4
H
7
OH 10.000
124 Cacbon disulfua (Carbon disulphide) 75-15-0 CS
2
8.000 400
125 p-Cloanilin (p-Chloroaniline)
(#)
106-47-8 C
6
H
4
ClNH
2
100
126 2-Clo-1,3-butadien (2-Chloro-1,3-butadiene)
(#)
126-99-8 C
4
H
5
Cl 100
127 p-Clo-m-cresol (p-Chloro-m-cresol) 59-50-7 C
7
H
7
ClO 20.000 1.000
128 Cyclohexanon (Cyclohexanone) 108-94-1 C
6
H
10
O 20.000
129 1,2-Dibrom-3-clopropan (1,2-Dibromo-3-chloropropane)
(#)
96-12-8 C
3
H
5
Br
2
Cl 10
130 3,3'-Diclobenzidin (3,3'-Dichlorobenzidine) v mui ca chng
(#)
91-94-1 C
12
H
10
Cl
2
N
2
16 0,8
131 4-Dimetylaminazobenzen (4-Dimethylaminoazobenzene)
(#)
60-11-7 C
14
H
15
N
3
10
132 1,4-Dinitrobenzen (1,4-Dinitrobenzene)
(#)
100-25-4 C
6
H
4
(NO
2
)
2
100
133 m-Dinitrobenzen (m-Dinitrobenzene)
(#)
99-65-0 C
6
H
4
(NO
2
)
2
8 0,4
134 4,6-Dinitro-o-cresol (4,6-Dinitro-o-cresol)
(#)
534-52-1 CH
3
C
6
H
2
OH(NO
2
)
2
100
135 1,2-Diclopropan (1,2-Dichloropropane) 78-87-5 C
3
H
6
Cl
2
20.000
136a 2,4-Dinitrotoluen (2,4-Dinitrotoluene)
(#)
121-14-2 CH
3
C
6
H
3
(NO
2
)
2
3 0,15
136b 2,6-Dinitrotoluen (2,6-Dinitrotoluene)
(#)
606-20-2 CH
3
C
6
H
3
(NO
2
)
2
3 0,15
136c 2,3-Dinitrotoluen (2,3-Dinitrotoluene)
(#)
602-01-7 CH
3
C
6
H
3
(NO
2
)
2
3 0,15
136 Tng Dinitrotoluen
(#)(4)
CH
3
C
6
H
3
(NO
2
)
2
3 0,15
137 Di-n-propylnitrosamin (Di-n-propylnitrosamine)
(#)
621-64-7 C
6
H
14
N
2
O 1 0,05
138 1,4-Dioxan (1,4-Dioxane) 123-91-1 C
4
H
8
O
2
600 30
QCVN 07: 2009/BTNMT
18
139 Diphenylamin (Diphenylamine) 122-39-4 (C
6
H
5
)
2
NH 1.800 90
140 1,2-Diphenylhydrazin (1,2-Diphenylhydrazine)
(#)
122-66-7 C
12
H
12
N
2
8 0,4
141 Etyl axetat (Ethyl acetate) 141-78-6 CH
3
COOC
2
H
5
10.000
142 Etylenimin (Ethyleneimine) hay Aziridene (Aziriden)
(#)
115-56-4 C
2
H
5
N 10
143 Etyl metacrylat (Ethyl methacrylate) 97-63-2 C
6
H
10
O
2
15.000
144 Iodmetan (Iodomethane) 74-88-4 CH
3
I 1.000
145 Isobutyl alcol (Isobutyl alcohol) 78-83-1 C
4
H
9
OH 10.000
146 Metacrylnitril (Methacrylonitrile)
(#)
126-98-7 C
4
H
5
N 8 0,4
147 Metanol (Methanol) 67-56-1 CH
3
OH 3.000
148 4,4-Metylen dicloanilin) [4,4-Methylene bis(2-chloroaniline)]
(#)
101-14-4 C
13
H
12
Cl
2
N
2
100
149 Metyl etyl keton (Methyl ethyl ketone) 78-93-3 C
4
H
8
O 4.000 200
150 Metyl isobutyl keton (Methyl isobutyl ketone) 108-10-1 C
6
H
12
O 4.000 200
151 -Naptylamin (-Naphthylamine)
(#)
134-32-7 C
10
H
9
N 10
152 -Naptylamin (-Naphthylamine)
(#)
91-59-8 C
10
H
9
N 10
153 o-Nitroanilin (o-Nitroaniline) 88-74-4 NO
2
C
6
H
4
NH
2
3.000
154 p-Nitroanilin (p-Nitroaniline) 100-01-6 NO
2
C
6
H
4
NH
2
3.000
155 Nitrobenzen (Nitrobenzene)
(#)
98-95-3 C
6
H
5
NO
2
40 2
156 4-Nitrobiphenyl (4-Nitrobiphenyl)
(#)
92-93-3 C
12
H
9
NO
2
10
157 5-Nitro-o-toluidin (5-Nitro-o-toluidine) 99-55-8 CH
3
NO
2
C
6
H
3
NH
2
1.000
158 N-Nitrosodimetylamin (N-Nitrosodimethylamine)
(#)
62-75-9 (CH
3
)
2
N
2
O 10
159 N-Nitroso-di-n-butylamin (N-Nitroso-di-n-butylamine)
(#)
924-16-3 C
8
H
18
N
2
O 1,2 0,06
QCVN 07: 2009/BTNMT
19
160 N-Nitrosometyletylamin (N-Nitrosomethylethylamine)
(#)
10595-95-6 C
3
H
8
N
2
O 0,4 0,02
161 N-Nitrosopyrolidin (N-Nitrosopyrrolidine)
(#)
930-55-2 C
4
H
8
N
2
O 4 0,2
162 Pentacloetan (Pentachloroethane) 76-01-7 C
2
HCl
5
1.000
163 Pentaclonitrobenzen (Pentachloronitrobenzene) 82-68-8 C
6
NO
2
Cl
5
200 10
164 Ptalic anhydrit (Phthalic anhydride) 85-44-9 C
8
H
4
O
3
10.000
165 -Propilacton (-Propiolactone)
(#)
57-57-8 C
3
H
4
O
2
10
166 Pyridin (Pyridine)
(#)
110-86-1 C
5
H
5
N 80 4
167 Safrol (Safrole)
(#)
94-59-7 C
10
H
10
O
2
100
168 1,2,3-Triclopropan (1,2,3-Trichloropropane)

96-18-4 C
3
H
5
Cl
3
400 20


QCVN 07: 2009/BTNMT
20
2.2.4. Ch thch:
(1)
Trong ngoc l tn ha cht theo ting Anh;
(2)
Trng hp cc ph liu kim loi ca antimon, bc, ch, km, nicken,
crom hoc ph liu hp kim c cha cc kim loi ny c lm sch, khng
ln tp cht, khng cha cc thnh phn nguy hi khc vt ngng CTNH,
dng thanh, khi, tm, on thanh, on ng, u mu, u tm, u ct,
phoi, si, mnh (khng phi dng bt), c tch ring cho mc ch ti ch,
ti s dng th cc kim loi ny khng tnh l thnh phn nguy hi v c trong
ph liu;
(3)
CAS l tn vit tt ca Chemical Abstracts Service Registry Numbers,
l s ng k tn cc ha cht;
(4)
Phi lun p dng gi tr tng i vi cc thnh phn ny;

(5)
Ch p dng i vi aming (bao gm cc loi chrysotile hay aming
trng, amosite hay aming nu, crocidolite hay aming xanh, tremolite,
anthophyllite v actinolite) trong cht thi dng bt, si, b, d vn; khng
p dng i vi vt liu aming-ximng thi;

(6)
Ch p dng gi tr tng trong trng hp khng p dng phn bit
theo tng nhm cht (TCDD, PeCDD, HxCDD);
(7)
Ch p dng gi tr tng trong trng hp khng p dng phn bit
theo tng nhm cht (TCDF, PeCDF, HxCDF);
(8)
Ch p dng gi tr tng trong trng hp khng p dng phn bit
theo s phn t C (cacbon);
(#)
Thnh phn nguy hi c bit (c tnh cht cc c hoc c kh nng
gy ung th hay gy t bin gen rt cao) vi ngng hm lng tuyt i
nh hn hoc bng 100 ppm.

3. QUY NH K THUT V LY MU, PHN TCH,
PHN NH V PHN LOI CTNH
3.1. Nguyn tc chung
3.1.1. Mi cht thi thuc loi ** hoc hn hp cht thi c cha t nht
mt cht thi thnh phn thuc loi ** trong Danh mc CTNH khng phi ly
mu, phn tch so snh vi ngng CTNH m phn nh ngay l CTNH
QCVN 07: 2009/BTNMT
21
hoc hn hp CTNH, tr trng hp phn tch cho mc ch khc, trong
c vic phn tch phn loi CTNH theo thnh phn nguy hi theo quy nh
ti im 2.1.3.
3.1.2. Mi cht thi thuc loi * hoc hn hp cht thi thuc loi * khi
cha chng minh c khng phi l CTNH th phi c qun l theo cc
quy nh i vi CTNH.
3.1.3. Nu mt dng cht thi pht sinh thng xuyn (c tnh cht lp
i lp li mt cch tng i n nh) t mt ngun thi nht nh (nh bn
thi t h thng x l nc thi) c tnh cht hoc thnh phn nguy hi lc
vt ngng, lc khng vt ngng (di ngng) CTNH ti cc thi im
ly mu khc nhau th phi phn nh chung dng cht thi l CTNH, tr
trng hp phn nh ring cho tng l cht thi ring l trong dng cht thi
.
3.1.4. Hn hp cht thi c t nht mt cht thi thnh phn l CTNH b
coi l CTNH (hay hn hp CTNH) v phi qun l theo cc quy nh i vi
CTNH.
3.2. Quy nh i vi n v ly mu, phn tch
3.2.1. n v ly mu, phn tch phi c cng nhn cht lng (i
vi cc phng php xc nh v cc thng s phn tch quy nh ti Quy
chun ny) hoc c c quan qun l nh nc v mi trng ch nh. Cc
kt qu phn tch ca n v cha c cng nhn m khng do c quan
qun l nh nc v mi trng ch nh ch c tnh cht tham kho, khng c
gi tr trc php lut.
3.2.2. n v ly mu, phn tch phi c trch nhim nh sau:
a) Phi chu trch nhim trc php lut v vic ly mu v kt qu
phn tch mu lm c s phn nh, phn loi CTNH;
b) Phi c cn b c nng lc tin hnh ly mu v lp bin bn ly
mu km theo (kt qu phn tch trn mu c ly bi ch ngun thi hoc
n v cha c cng nhn m khng do c quan qun l nh nc v mi
trng ch nh ch c tnh cht tham kho, khng c gi tr trc php lut);
c) Phi p dng ng nguyn tc ly mu v phng php xc nh quy
nh ti Quy chun ny.
QCVN 07: 2009/BTNMT
22
3.2.3. Trng hp c tranh chp do s khc bit gia kt qu phn tch
ca hai n v ly mu, phn tch th c quan qun l nh nc v mi trng
ch nh mt n v ly mu, phn tch th ba (c chnh thc cng nhn
cht lng) lm trng ti, ng thi yu cu hai n v ly mu, phn tch nu
trn tin hnh lp li kim tra i chiu.
3.3. Nguyn tc ly mu, phn tch, phn nh v phn loi CTNH
Ngoi quy nh c th v phng php ly mu nu trong cc phng
php xc nh quy nh ti Phn 4 ca Quy chun ny hoc cc phng php
ly mu khc c cng nhn trong nc hoc quc t, vic ly mu, phn
tch, phn nh v phn loi CTNH phi c tin hnh theo nguyn tc c
bn nh sau:
3.3.1. i vi cc cht thi ng nht th rn thuc loi *: ly t nht
03 mu i din ngu nhin cc v tr khc nhau trong khi cht thi (c tnh
n s phn b i din ca kch thc cc ht hoc phn t trong khi cht
thi) v s dng gi tr trung bnh ca kt qu phn tch so snh vi
ngng CTNH nhm phn nh c phi l CTNH hay khng.
3.3.2 i vi cht thi lng, bn thuc loi * hoc hn hp ca chng:
phi khy, trn u (nu c th) trc khi ly t nht 03 mu i din ngu
nhin cc v tr khc nhau v s dng gi tr trung bnh ca kt qu phn
tch so snh vi ngng CTNH nhm phn nh c phi l CTNH hay
khng.
3.3.3. i vi hn hp cht thi rn hoc hn hp gia cht thi rn v
cht thi lng, bn (ton b cc cht thi thnh phn u thuc loi *): s
dng ti a cc bin php c hc ph hp (cht, ct, bc, co, ly tm, trng
lc, thi kh... nhng khng c s dng nc hoc dung mi ra, tch)
tch ring cc cht thi thnh phn v ly mu i vi tng cht thi thnh
phn ny theo quy nh ti im 3.3.1 hoc 3.3.2; s dng gi tr trung bnh
ca kt qu phn tch i vi tng cht thi thnh phn so snh vi
ngng CTNH nhm phn nh c phi l CTNH hay khng. Trng hp
khng th tch ring cc cht thi thnh phn bng cc bin php c hc th
trn u khi cht thi (nu c th) v ly t nht 09 mu phn b u theo
cch chia u cc phn trong khi cht thi (mi phn ly 01 mu).
3.3.4. i vi cht thi rn thuc loi * c tp cht bm dnh: ly 03 mu
i din ngu nhin cc v tr khc nhau ca cht thi nn (cht thi ng
QCVN 07: 2009/BTNMT
23
nht th rn) m c tp cht bm dnh so snh vi ngng CTNH nhm
phn nh c phi l CTNH hay khng. Nu cht thi nn l hn hp cht thi
th phi tch ring cc cht thi thnh phn phn nh theo quy nh ti
im 3.3.3.
3.3.5. i vi vic phn nh chung mt dng cht thi pht sinh thng
xuyn t mt ngun thi nht nh c phi l CTNH hay khng th phi ly
mu vo t nht 03 ngy khc nhau, thi im ly mu ca mi ngy phi
khc nhau (u, gia v cui ca mt ca hoc m hot ng), mi ln t nht
03 mu ngu nhin cc v tr khc nhau.
3.3.6. i vi cc cht thi thuc loi ** hoc hn hp c t nht mt
cht thi thnh phn thuc loi ** th khng cn ly mu, phn tch m phn
nh lun l CTNH, nhng nu vn cn ly mu, phn tch cho cc mc ch
khc nh phn loi CTNH theo thnh phn nguy hi nh nu ti im 2.1.3 th
cng p dng nguyn tc quy nh t im 3.3.1 n 3.3.5.
3.3.7. i vi vic phn nh cht thi sau x l c cn l CTNH hay
khng th cng p dng cc nguyn tc quy nh t im 3.3.1 n 3.3.5.
3.4. Nguyn tc la chn cc tnh cht v thnh phn nguy hi
phn tch
Mt cht thi bt k ch cn c t nht mt tnh cht hoc mt thnh
phn nguy hi vt ngng CTNH th phn nh l CTNH. Do vy, nu ch
phn nh mt cht thi thuc loi * c phi CTNH hay khng, th trong qu
trnh la chn phn tch m pht hin ra mt tnh cht hoc mt thnh phn
nguy hi vt ngng CTNH th khng phi tin hnh phn tch cc tnh cht
hoc thnh phn nguy hi cn li, tr trng hp phn tch cho mc ch
khc. Vic la chn phn tch cc tnh cht hoc thnh phn nguy hi c
tin hnh nh sau:
3.4.1. i vi cc tnh cht nguy hi: Cn c vo c im ca ngun
thi v chng loi cht thi la chn c phn tch tnh d chy, tnh kim v
axit hay khng. Nu chc chn rng c im ngun thi v chng loi cht
thi khng th dn ti vic cht thi c cc cht d chy, kim hoc axit th
chuyn sang phn tch cc thnh phn nguy hi.
3.4.2. i vi cc thnh phn nguy hi v c: Khng nht thit phi
phn tch tt c cc thnh phn v c nu ti Bng 2. Cn cn c vo tnh
cht nguyn vt liu, nhin liu, quy trnh sn xut, c im ngun thi, qu
QCVN 07: 2009/BTNMT
24
trnh pht thi hoc hot ng c pht sinh cht thi xc nh cc thnh
phn nguy hi v c c th c trong cht thi phn tch. Nu nguyn vt
liu, nhin liu, quy trnh sn xut, c im ngun thi, qu trnh pht thi
hoc hot ng c pht sinh cht thi khng lin quan n cc cht c cha
thnh phn nguy hi v c no th khng phi phn tch thnh phn .
3.4.3. i vi cc thnh phn nguy hi hu c:
a) Sau khi tin hnh la chn theo quy nh ti im 3.4.1 v 3.4.2 m
vn cha phn nh c CTNH th mi phi tin hnh phn tch cc thnh
phn nguy hi hu c (tr trng hp bit chc chn s c mt ca mt
thnh phn hu c nht nh th c th b qua bc 3.4.1 v 3.4.2);
b) Khng nht thit phi phn tch tt c cc thnh phn hu c nu ti
Bng 3. Cn cn c vo tnh cht nguyn vt liu, nhin liu, quy trnh sn
xut, c im ngun pht thi, qu trnh pht thi hoc hot ng c pht
sinh ra cht thi xc nh cc thnh phn nguy hi hu c c th c trong
cht thi phn tch. Nu nguyn vt liu, nhin liu, quy trnh sn xut, c
im ngun thi, qu trnh pht thi hoc hot ng c pht sinh ra cht thi
khng lin quan n hoc khng c kh nng dn ti vic xut hin mt cch
khng ch nh (do phn ng ho hc ngu nhin) mt thnh phn nguy hi
hu c no th khng cn phn tch thnh phn .

4. PHNG PHP XC NH
4.1. Kt qu phn nh v phn loi CTNH ch c gi tr nu p dng
theo ng cc phng php xc nh sau y:
4.1.1. i vi tnh d bt chy: ASTM D3278-96: Phng php chun
xc nh im chp chy ca cht lng bng dng c cc kn (Standard test
method for flash point of liquids by small scale closed-cup apparatus).
4.1.2. i vi tnh kim v tnh axit: ASTM D4980-89: Phng php
chun xc nh pH trong cht thi (Standard test method for screening of pH in
waste).
4.1.3. i vi nng ngm chit, s dng mt trong hai phng php
chun b mu sau y trc khi tin hnh phn tch:
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25
a) ASTM D5233-92: Phng php chun xc nh mu cht thi n l
bng phng php ngm chit (Standard test method for single batch
extraction method for wastes).
b) EPA 1311: Phng php ngm chit c tnh TCLP (TCLP Method
1311 Toxicity characteristic leaching procedure).
4.1.4. i vi thnh phn xyanua: EPA SW-846 Phng php 9010
hoc 9012: Phn tch xyanua trong cht thi (Method 9010 or 9012:
Determination of Cyanide in wastes).
4.2. i vi vic phn tch dung dch sau ngm chit xc nh nng
ngm chit ca cc thnh phn nguy hi v vic phn tch cht thi xc
nh hm lng tuyt i ca cc thnh phn nguy hi c th p dng cc
phng php theo bt k quy chun k thut, tiu chun quc gia hoc tiu
chun quc t no c cng nhn.
4.3. Phng php ngm chit EPA 1311 v ASTM D5233-92 l cc
phng php chun b mu phn tch c p dng cho vic ngm chit cc
mu cht thi nhm xc nh kh nng r r cc thnh phn nguy hi trong
cht thi ra mi trng trong iu kin tng t iu kin t nhin (biu th
bng nng ngm chit c n v l mg/l), c chung nguyn l nh sau:
4.3.1. i vi cht thi c t hn 0,5% hm lng rn kh (cht thi
dng lng): sau khi lc qua mng lc si thu tinh 0,6 - 0,8 m, lng cht
lng thu c dng trc tip phn tch cc thnh phn nguy hi (khng cn
ngm chit lng cht rn b gi li).
4.3.2. i vi cht thi c t nht 0,5% hm lng rn kh (cht thi
dng bn hoc rn):
- Lng cht rn c tch khi lng cht lng bng vic lc qua
mng lc si thu tinh 0,6 - 0,8 m; lng cht lng tch ra c bo qun
phn tch sau.
- Lng cht rn (c th cn x l c hc nh bm, ct, nghin...
m bo ton b lng cht rn c lt qua sng c kch thc mt khng
vt qu 9,5 mm) c ngm chit bng dung dch ngm chit c tnh axit
(c pha ch t CH
3
COOH, nc v c th b sung NaOH t gi tr pH
4,93 0,05 hoc 2,88 0,05 tu theo loi thnh phn nguy hi cn phn tch)
c khi lng gp 20 ln khi lng cht rn trong khong thi gian 18 2h;
QCVN 07: 2009/BTNMT
26
- Nu tng thch, lng cht lng tch ra ban u c trn vi dung
dch sau ngm chit lng cht rn phn tch mt ln; nu khng tng
thch th c phn tch ring v kt hp gi tr trung bnh theo cng thc sau:
C
tb
=
(V
l
.C
l
+ V
nc
.C
nc
)
(V
l
+ V
nc
)
Trong :
+ C
tb
(mg/l) l nng ngm chit trung bnh ca mt thnh phn nguy
hi trong mu cht thi;
+ V
l
(l) l th tch lng cht lng tch ra ban u;
+ C
l
(mg/l) l nng thnh phn nguy hi trong lng cht lng tch ra
ban u;
+ V
nc
(l) l th tch dung dch sau ngm chit;
+ C
nc
(mg/l) l nng thnh phn nguy hi trong dung dch sau ngm
chit.

5. T CHC THC HIN
5.1. Quy chun ny p dng thng nht ngng CTNH trong vic phn
nh v phn loi CTNH theo Danh mc CTNH do B Ti nguyn v Mi
trng ban hnh; thay th p dng cc Tiu chun Vit Nam TCVN
6706:2000 v Cht thi nguy hi Phn loi v TCVN 7629:2007 v Ngng
cht thi nguy hi.
5.2. Mt s trng hp c bit thng gp trong thc t c quy
nh c th nh sau:
5.2.1. i vi bao b thi: trc khi tin hnh ly mu, phn tch
phn nh, phn loi CTNH, cc thnh phn cht c cha cn li trong bao
b phi c loi b ti a khi vt liu bao b bng cc bin php c hc ph
hp (bc, tch, co i vi thnh phn rn, bn hoc trng lc, ly tm i
vi thnh phn bn, lng, nhng khng c s dng nc hoc ho cht
ra, tch, ty), m bo ch cn li cc thnh phn bm dnh (vi dy trung
bnh di 01 mm hoc hm lng di 01%). Ly mu, phn tch ring bit
cho vt liu bao b (c cc thnh phn bm dnh) v thnh phn cht c
cha tch ring ra c phi l CTNH hay khng theo quy nh ti Phn 3
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ca Quy chun ny. Nu thnh phn cht c cha tch ring ra l
CTNH th phn nh lun ton b bao b l CTNH m khng cn phn tch vt
liu bao b. Nu thnh phn cht c cha ch cn li dng tp cht bm
dnh (vi dy trung bnh di 01 mm hoc hm lng di 01%) th khng
cn khu loi b bng cc bin php c hc m ly mu, phn tch lun.
5.2.2. i vi cc phng tin, thit b thi (v d phng tin giao
thng, thit b in, in t...): vic ly mu, phn tch phn nh, phn loi
CTNH phi c tin hnh cho tng cht thi thnh phn (b phn hoc vt
liu cu thnh nn phng tin, thit b, v d du my).
5.2.3. Mt cht thi ch c phn loi theo tn v m CTNH ca loi c
gc halogen hu c hoc c cha thnh phn halogen hu c (k c c clo
nh PCB) nu hm lng tuyt i ca ca t nht mt thnh phn halogen
hu c vt ngng CTNH.
5.2.4. Cc sn phm c thu hi, ti ch t cht thi lm nhin liu,
nguyn vt liu sn xut nh du m, dung mi, cn v cc ho cht: phi
m bo cc thnh phn kim loi nng (tr trng hp kim loi nng l thnh
phn chnh ca sn phm) v cc thnh phn halogen hu c di ngng
CTNH, ng k tiu chun c s v cht lng sn phm v t cc tiu
chun quc gia, quy chun k thut quc gia v cht lng sn phm (nu c)
theo quy nh hin hnh. Nu cn bt k mt thnh phn nguy hi l kim loi
nng hoc halogen hu c vt ngng CTNH th khng c coi l sn
phm m vn l CTNH.
5.2.5. Cht thi c x l bng bin php ho rn hoc n nh ho:
a) Tro x t hot ng thiu hu CTNH v cc cht thi v c khc: nu
khng c thnh phn kim loi nng no vt ngng nng ngm chit th
c th tn dng lm sn phm vt liu xy dng nu cng ho rn (b
tng ho hay cc bin php khc nh ng gch) khng thp hn mc 100;
hoc c coi l cht thi rn thng thng, c th chn lp trong bi chn
lp cht thi sinh hot hoc cht thi xy dng hp v sinh nu cng ho
rn thp hn mc 100;
b) Cht thi c thnh phn hu c sau khi ho rn hoc n nh ho
nu khng c thnh phn nguy hi no (tr aming th cho php hm lng
bt k) ng thi vt ngng hm lng tuyt i v ngng nng ngm
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chit th c coi l cht thi rn thng thng, c th chn lp trong bi chn
lp cht thi sinh hot hoc cht thi xy dng hp v sinh;
c) Cht thi sau khi c ho rn hoc n nh ho nu c t nht mt
thnh phn nguy hi v c hoc hu c ng thi vt c ngng hm
lng tuyt i v ngng nng ngm chit th vn l CTNH, phi c
chn lp trong bi chn lp cht thi nguy hi.
5.3. Phi s dng bn cp nht mi nht ca cc phng php xc
nh nu ti Mc 4.1. Trng hp cc phng php xc nh ny c cc quy
chun k thut hoc tiu chun quc gia tng ng th p dng cc quy
chun, tiu chun .
5.4. C quan qun l nh nc v mi trng c trch nhim hng
dn, kim tra, gim st vic thc hin Quy chun ny./.