40 de Phien Ban 2014

GSTT GROUP
2014
40 THI TH I HC
CHN LC
Mn HA HC
Tp 2

T I T R B I L O V E B O O K . V N
1 | G S T T G R O U P

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TUYN TP 40 THI TH I HC MN HA PHIN BN 2014
2 | L O V E B O O K . V N

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s 1

I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: Mt hn hp X c khi lng m gam gm Ba v Al. Cho m gam X tc dng vi nc d, thu c 8,96
lt kh H2. Cho m gam X tc dng vi dung dch Ba(OH)2 d thu c 22,4 lt kh H2 (cc phn ng u xy ra
hon ton, cc th tch kh o iu kin tiu chun). m c gi tr l
A. 16,8 gam. B. 27,2 gam. C. 24,6 gam. D. 29,9 gam.
Cu 2: C 3 dung dch hn hp l dung dch: X (NaHCO3 v Na2CO3); Y (NaHCO3 v Na2SO4); Z (Na2CO3 v Na2SO4).
Ch dng thm 2 dung dch no di y nhn bit c 3 dung dch trn?
A. HNO3 v Ba(NO3)2. B. HCl v NaCl. C. NaOH v NaCl. D. NH3 v NH4Cl.
Cu 3: Oxi ho nh 3,2 gam ancol CH3OH thu c hn hp sn phm gm anehit, axit, ancol d v nc
trong s mol anehit bng 3 ln s mol axit. Cho ton b sn phm phn ng vi lng d dung dch
AgNO3/NH3 thu c 15,12 gam Ag. Hiu sut phn ng oxi ho l
A. 70%. B. 65%. C. 40%. D. 56%.
Cu 4: Cho s phn ng sau :

Tn ca Y l
A. Vinylbenzoat. B. Metylacrylat. C. Benzylacrylat. D. Phenylacrylat.
Cu 5: Nung no ng t ng ca p chat trong binh kin: (1) Fe + S(r), (2) Fe2O3 + CO(k), (3) Au + O2(k), (4) Cu +
Zn(NO3)2(r), (5) Cu + KNO3(r), (6) Al + NaCl (r). Ca c tr ng h p xa y ra pha n ng oxi hoa kim loa i la
A. (1), (4), (5). B. (1), (4). C. (1), (3), (6). D. (1), (5).
Cu 6: Cho cc phn ng ho hc sau y:
(1) Al4C3 + 12H2O 4Al(OH)3 + 3CH4 (2) 2Na + 2H2O 2NaOH + H2
(3) CH3Cl + H2O
+OH

CH3OH + HCl (4) C2H2 + H2O
Hg
2+

CH3CHO
(5) Na2O2 + H2O NaOH + H2O2 (6) 2F2 + 2H2O 4HF + O2
S phn ng ho hc trong H2O ng vai tr cht oxi ho hoc cht kh l
A. 1. B. 3. C. 2. D. 4.
Cu 7: Dy gm cc cht u tc dng vi dung dch AgNO3/NH3 l
A. axit fomic, vinylaxetilen, propin. B. anehit axetic, but-1-in, etilen.
C. anehit axetic, axetilen, but-2-in. D. anehit fomic, axetilen, etilen.
Cu 8: Sc V lt CO2 ( ktc) vo 1 lt dung dch hn hp NaOH 0,02M v Ba(OH)2 0,02M n phn ng hon
ton thu c 1,97 gam kt ta v dung dch X. Cho dung dch NaOH vo dung dch X li thu c kt ta. Gi
tr ca V l
A. 1,12 lt. B. 0, 224 lt hoc 1,12 lt
C. 0,448 lt. D. 0,896 lt hoc 0,448 lt.
Cu 9: Hn hp kh A ( nhit thng) gm hirocacbon X mch h v oxi d c t l th tch 4:21 cho vo
mt bnh kn dung tch khng i thy p sut l p atm. Bt tia la in, t chy hon ton hn hp, sau phn
ng, loi b hi nc ri a v nhit ban u c hn hp B c p sut 0,52p atm. S cht X tha mn
d kin u bi l
A. 5. B. 1. C. 4. D. 6.
Cu 10: t chy hon ton 1,18 gam mt amin n chc Y bng mt lng khng kh va . Dn ton b
kh sau phn ng vo bnh ng dung dch Ca(OH)2 d thu c 6 gam kt ta v 9,632 lt kh ( ktc) duy
nht thot ra khi bnh. Cng thc phn t ca Y l
A. C2H7N. B. C4H11N. C. C3H9N. D. CH5N.
Cu 11: Dung dch X cha 0,375 mol K2CO3 v 0,3 mol KHCO3. Thm t t dung dch cha 0,525 mol HCl vo
dung dch X c dung dch Y v V lt CO2 (ktc). Thm dung dch nc vi trong d vo Y thy to thnh m
gam kt ta. Gi tr ca V v m l
A. 6,72 lt; 26,25 gam. B. 3,36 lt; 52,5 gam. C. 3,36 lt; 17,5 gam. D. 8,4 lt; 52,5 gam.
Cu 12: Cho 11,6 gam mui FeCO3 tc dng va vi dung dch HNO3, c hn hp kh CO2, NO v dung
dch X. Khi thm dung dch HCl (d) vo dung dch X c dung dch Y. Khi lng bt ng kim loi ti a c
th ha tan trong dung dch Y (bit NO l sn phm kh duy nht) l
A. 14,4 gam. B. 32 gam. C. 16 gam. D. 7,2 gam.
Cu 13: S proton, ntron, electron c trong mt ion Cr
3+
(cho
24
52
Cr) ln lt l
A. 24, 28, 21. B. 24, 30, 21. C. 24, 28, 24. D. 24, 28, 27.
Cu 14: Cho cc dung dch: Na2CO3, NaHCO3, AlCl3, CaCl2, Ca(HCO3)2, Mg(HCO3)2, K2SO3, K2SO4 ln lt tc dng
vi dung dch Ba(OH)2. S trng hp xy ra phn ng l
A. 8. B. 5. C. 7. D. 6.
Cu 15: Mun tng hp 60 kg thy tinh hu c (thy tinh plexiglat) th khi lng axit v ancol phi dng ln
lt l (bit hiu sut qu trnh este ha v qu trnh trng hp ln lt l 60% v 80%)
A. 107,5kg v 40kg. B. 85kg v 40kg. C. 32,5kg v 20kg. D. 85,5 kg v 41 kg.
Cu 16: Ha tan 2,29 gam hn hp Ba v Na vo nc thu c dung dch X v 672 ml kh (ktc). Nh t t
dung dch FeCl3 vo dung dch X cho n d, lc kt ta, ra sch, sy kh v nung n khi lng khng i
thu c m gam cht rn. Gi tr ca m l
A. 6,4. B. 4,8. C. 1,6. D. 3,2.
Cu 17: X v Y l 2 hp cht ch c chc ancol, trong khi lng mol ca X nh hn ca Y. Khi t chy hon
ton mi cht X, Y u to ra s mol CO2 t hn s mol H2O. t chy hon ton hn hp Z gm nhng lng
bng nhau v s mol ca X v Y thu c t l s mol CO2 v H2O tng ng l 2:3. S hp cht tha mn cc
tnh cht ca Y l
A. 6 cht. B. 2 cht. C. 4 cht. D. 5 cht.
Cu 18: Chia dung dch Z cha cc ion: Na
+
, NH4
+
, SO4
2-
, CO3
2-
thnh 2 phn bng nhau. Phn 1 cho tc dng vi
dung dch Ba(OH)2 d, un nng thu c 4,3 gam kt ta X v 470,4 ml kh Y 13,5
0
C v 1atm. Phn 2 cho
tc dng vi dung dch HCl d thu c 235,2 ml kh 13,5
0
C v 1atm. Tng khi lng mui trong Z l
Cu 19: Hn hp X gm Al, Fe2O3 c khi lng 21,67 gam. Tin hnh phn ng nhit nhm hn hp X trong
iu kin khng c khng kh (gi thit ch xy ra phn ng Al kh Fe2O3 thnh kim loi). Ha tan hn hp
cht rn sau phn ng bng dung dch NaOH d thu c 2,016 lt H2 (ktc) v 12,4 gam cht rn khng tan.
Hiu sut ca phn ng nhit nhm l
A. 45%. B. 50%. C. 71,43%. D. 75%.
Cu 20: Hp cht X mch h c cng thc phn t C4H9NO2. Cho X phn ng va vi dung dch NaOH sinh
ra cht kh Y v dung dch Z. Kh Y lm xanh giy qu tm m. Dung dch Z c kh nng lm mt mu nc brom
v khng c kh nng trng bc. S ng phn ca X tha mn d kin u bi l
A. 5. B. 2. C. 4. D. 3.
Cu 21: Dy gm cc cht u phn ng vi phenol l
A. nc brom, axit axetic, dung dch NaOH.
B. nc brom, anehit axetic, dung dch NaOH.
C. nc brom, kim loi natri, dung dch NaOH.
D. dung dch NaCl, dung dch NaOH, kim loi natri.
Cu 22: T 10 kg go np cha 80% tinh bt, khi ln men s thu c th tch dung dch ancol etylic 40
0
l
(bit rng hiu sut ca ton b qu trnh ln men t 80% v ancol etylic c khi lng ring 0,789 g/ml)
A. 15, 116 lt. B. 17,994 lt. C. 11,516 lt. D. 1,842 lt.
Cu 23: Trong cc cht sau y:(1) H2S; (2) SO2; (3) NaCl; (4) CaO; (5) NH3; (6) HBr; (7) H2SO4; (8) CO2; (9)
K2S. Cc cht cha lin kt cng ho tr l
A. (1), (2), (5), (6), (7), (8). B. (3), (5), (6), (7), (8), (9).
C. (1), (4), (5), (7), (8), (9). D. (1), (2), (3), (4), (8).
Cu 24: Cho s :
X
+CuO
Y
+O
2
D
+CH
3
OH
D
trng hp
thy tinh plexiglat.
Cng thc cu to ca X l
A. CH3CH(CH3)CH2OH. B. CH2=C(CH3)CH2CH2OH.
C. CH3CH(CH3)CH2CH2OH. D. CH2=C(CH3)CH2OH.
Cu 25: Cho 15,2 gam cht hu c X phn ng va vi 300 ml dung dch NaOH 1M thu c dung dch Y.
C cn dung dch Y ch thu c hi nc 23,6 gam hn hp mui khan Z. t chy hon ton Z thu c
Na2CO3, 14,56 lt CO2 (kc) v 6,3 gam H2O (bit X c cng thc phn t trng vi cng thc n gin nht).
Cng thc phn t ca X l
A. C8H10O3. B. C8H8O3. C. C8H8O. D. C9H8O2.
Cu 26: nhn bit cc cht etanol, propenol, etylenglycol, phenol c th dng cp cht
A. nc brom v dung dch NaOH. B. nc brom v Cu(OH)2.
C. dung dch KMnO4 v Cu(OH)2. D. dung dch NaOH v Cu(OH)2.
Cu 27: Ho tan hon ton x gam hn hp gm NaI v NaBr vo nc thu c dung dch X. Cho Br2 d vo X
c dung dch Y. C cn Y thu c y gam cht rn khan. Tip tc ho tan y gam cht rn khan trn vo nc
c dung dch Z. Cho Cl2 d vo Z c dung dch T. C cn T thu c z gam cht rn khan. Bit cc phn
ng xy ra hon ton v 2y = x + z. Phn trm khi lng ca NaBr trong hn hp ban u l
A. 7,3%. B. 3,7%. C. 6,7%. D. 4,5%.
Cu 28: Cho Bari kim loi ln lt vo cc dung dch sau: NaHCO3, CuSO4, (NH4)2CO3, NaNO3, MgCl2. S trng
hp to kt ta l
A. 3. B. 4. C. 1. D. 2.
Cu 29: Ha tan ht 6,08 gam hn hp gm Cu, Fe bng dung dch HNO3 thu c dung dch X v 1,792 lt NO
(ktc). Thm t t 2,88 gam bt Mg vo dung dch X n khi phn ng xy ra hon ton thu c 0,448 lt NO
(ktc), dung dch Y v m gam cht rn khng tan. Gi tr ca m l
Cu 30: Cho 6,9 gam mt ancol n chc phn ng vi CuO nung nng, thu c cht rn A v 9,3 gam hn
hp X gm anehit, nc v ancol d. Cho ton b lng hn hp X phn ng hon ton vi lng d dung
dch AgNO3 trong NH3, un nng, thu c m gam Ag. Gi tr ca m l
A. 32,4. B. 64,8. C. 24,3. D. 16,2.
Cu 31: Nung nng hn hp X gm 0,1 mol axetilen; 0,2 mol propen; 0,1 mol etilen v 0,6 mol hiro vi xc
tc Ni, sau mt thi gian thu c hn hp Y c t khi so vi H2 bng 12,5. Cho hn hp Y tc dng vi brom
d trong CCl4 thy c ti a a gam brom phn ng. Gi tr ca a l
A. 24. B. 16. C. 32. D. 48.
Cu 32: Cho cc th nghim sau:
(1) Sc t t n d kh CO2 vo dung dch NaAlO2 (hay Na[Al(OH)4]).
(2) Sc t t n d kh NH3 vo dung dch AlCl3.
(3) Nh t t n d dung dch HCl long vo dung dch NaAlO2 (hay Na[Al(OH)4]).
Nhng th nghim c hin tng ging nhau l
A. (1) v (3) . B. (1), (2) v (3). C. (2) v (3). D. (1) v (2).
Cu 33: Khi un mt ancol X vi H2SO4 c 170
0
C, thu c 3 anken ng phn c cng thc C7H14. Khi
hiro ho cc anken th u thu c 2,2-imetylpentan. Tn gi ca X l
A. 2,2-imetylpentan-3-ol. B. 2,2-imetylpentan-4-ol. C. 4,4-imetylpentan-2-
ol. D. 3,3-imetylpentan-2-ol.
Cu 34: Cp cht no di y khng tn ti trong cng mt dung dch?
A. CuSO4 v HNO3. B. Na2SO4 v KCl. C. KNO3 v CuCl2. D. NaHCO3 v HCl.
Cu 35: Dy gm cc cht v ion va c tnh oxi ha, va c tnh kh l
A. O3, Fe
2+
, FeCl2, CrO3. B. HCl, Na2S, NO2, Fe
3+
.
C. NO2, Fe
2+,
Cl2, FeCl3, SO3
2-
. D. FeO, H2S, Cu, HNO3.
Cu 36: Cho 9,6 gam hn hp hi gm metanal v propin tc dng hon ton vi lng d dung dch
AgNO3/NH3 thu c 73,89 gam kt ta. Cho kt ta ny vo dung dch HCl d, sau khi kt thc phn ng cn
li m gam cht khng tan. Gi tr ca m l
Cu 37: Ly 9,1 gam hp cht X c cng thc phn t l C3H9O2N tc dng vi dung dch NaOH d, un nng,
c 2,24 lt (o ktc) kh Y thot ra lm xanh giy qu tm m. t chy ht
1
2
lng kh Y ni trn, thu c
4,4 gam CO2. Cng thc cu to ca X v Y ln lt l
A. CH2=CHCOONH4; NH3. B. HCOOH3NC2H3; C2H3NH2.
C. CH3COOH3NCH3; CH3NH2. D. HCOOH3NC2H5; C2H5NH2.
Cu 38: o t cha y hoa n toa n 10,33 gam ho n h p X go m axit acrylic, axit aipic, axit propanoic va ancol etylic
(trong o so mol axit acrylic ba ng so mol axit propanoic) thu c ho n h p khi va hi Y. Da n Y va o 3,5 lit dung
dich Ca(OH)2 0,1M thu c 27 gam ket tu a va n c lo c Z. un no ng n c lo c Z li thu c ket tu a. Neu cho
10,33 gam ho n h p X tre n ta c du ng vi 100ml dung dich KOH 1,2M, sau pha n ng co ca n dung dich thi thu
c khi lng chat ra n la
Cu 39: Cho 2,13 gam hn hp gm Cu v Al dng bt tc dng hon ton vi oxi thu c hn hp X gm
hai oxit c khi lng 3,33 gam. Th tch dung dch HCl 0,6M va phn ng ht vi X l
A. 200 ml. B. 250 ml. C. 300 ml. D. 150 ml.
Cu 40: Thc hin phn ng nhit phn hon ton cc cht sau: KClO3 (xc tc MnO2), NH4NO3, NaHCO3, NH4NO2,
KMnO4, KNO3, BaCO3, AgNO3. S phn ng to ra O2 l
A. 4. B. 5. C. 3. D. 6.
II. PHN RING (10 cu)
Th sinh ch c lm mt trong hai phn (phn A hoc phn B)
1. Phn A: Dnh cho th sinh theo chng trnh chun (10 cu, t cu 41 n cu 50)
Cu 41: Khi lng glucoz c trong nc qu nho bng bao nhiu sau khi ln men thu c 100 lt ru vang
10
o
(bit hiu sut phn ng ln men t 95%, ancol etylic nguyn cht c khi lng ring 0,8 g/ml, gi thit trong
nc qu nho ch c mt loi ng l glucoz) l

A. 32,952 kg. B. 15,652 kg. C. 16,476 kg. D. 31,304 kg.
Cu 42: Cho 3,04 gam hn hp X gm FeO, Fe3O4, Fe2O3. kh hon ton hn hp X cn 0,1 gam hiro. Mt
khc, ho tan hn hp X trong H2SO4 c, nng th th tch kh SO2 (sn phm kh duy nht ktc) l
A. 336 ml. B. 448 ml. C. 112 ml. D. 224 ml.
Cu 43: Cho bit cc phn ng xy ra sau:
2FeBr2 + 3Br2 2FeBr3 2NaBr + Cl2 2NaCl + Br2
Pht biu ng l
A. Tnh kh ca Cl
mnh hn Br
. B. Tnh kh ca Br
mnh hn Fe
2+
.
C. Tnh oxi ho ca Br2 mnh hn Cl2. D. Tnh oxi ho ca Cl2 mnh hn ca Fe
3+
.
Cu 44: Ha tan ht 10,24 gam Cu bng 200 ml dung dch HNO3 3M c dung dch X. Thm 400 ml dung dch
NaOH 1M vo dung dch X. Lc b kt ta, c cn dung dch ri nung cht rn n khi lng khng i thu
c 26,44 gam cht rn. S mol HNO3 phn ng vi Cu l
A. 0,48 mol. B. 0,58 mol. C. 0,4 mol. D. 0,56 mol.
Cu 45: Hp cht c cng thc phn t C4H9Br c s ng phn cu to l
A. 6. B. 4. C. 3. D. 5.
Cu 46: chng n mn cho ng ng dn du bng thp chn di t, ngi ta dng phng php in
ho. Trong thc t, ngi ta dng kim loi no sau y lm in cc hi sinh?
A. Sn. B. Cu. C. Na. D. Zn.
Cu 47: Chia hn hp A gm ancol metylic v mt ancol ng ng lm 3 phn bng nhau.
- Phn 1: cho phn ng ht vi Na thu c 0,336 l H2 (kc).
- Phn 2: oxi ha bng CuO thnh hn hp anehit vi hiu sut 100%, sau cho ton b sn phm hu
c tc dng vi lng d AgNO3 /NH3 thu c 10,8 gam bc.
S mol ca ancol metylic v ancol ng ng trong mi phn ln lt l
A. 0,012 v 0,018. B. 0,01 v 0,02. C. 0,015 v 0,015. D. 0,02 v 0,01.
Cu 48: Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol hn
hp kh v dung dch X. Sc kh CO2 (d) vo dung dch X, lng kt ta thu c l 46,8 gam. Gi tr ca a
l
A. 0,45. B. 0,40. C. 0,60. D. 0,55.
Cu 49: Cho cc phn ng ho hc sau:
(1) (NH4)2SO4 + CaBr2 (2) CuSO4 + Ca(NO3)2
(3) K2SO4 + CaCl2 (4) H2SO4 + CaCO3
(5) (NH4)2SO4 + Ca(OH)2 (6) Fe2(SO4)3 + CaCl2
Cc phn ng c cng phng trnh ion thu gn l
A. (1), (2), (3), (6). B. (3), (4), (5), (6). C. (1), (3), (5), (6). D. (2), (3), (4), (6).
Cu 50: Mt peptit c cng thc cu to thu gn l:
CH3CH(NH2)CONHCH2CONH(CH3)CHCONH(C6H5)CHCONHCH2COOH
Khi un nng peptit trn trong mi trng kim sao cho cc lin kt peptit u b ph v th s sn phm hu
c thu c l
A. 3. B. 2. C. 4. D. 5.
2. Phn B: Dnh cho th sinh theo chng trnh nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Cho E
o
pin(Zn-Cu)
= +1,10V; E
o
(Zn
2+
/Zn)
= - 0,76V v E
o
(Ag
+
/Ag)
= +0,80V. Sut in ng chun ca
pin Cu - Ag l
A. +0,56. B. +0,46V. C. +0,34V. D. +1,14V.
Cu 52: Nguyn t nguyn t c s hiu nguyn t bng 24 c tng s electron c thn l
A. 5. B. 6. C. 3. D. 4.
Cu 53: Mt pin in ho c in cc Zn nhng trong dung dch ZnSO4 v in cc Cu nhng trong dung dch
CuSO4. Sau mt thi gian pin phng in th khi lng
A. in cc Zn gim cn khi lng in cc Cu tng.
B. in cc Zn tng cn khi lng in cc Cu gim.
C. c hai in cc Zn v Cu u gia m.
D. c hai in cc Zn v Cu u tng.
Cu 54: Cho dy chuyn ha sau: Phenol
+X
Phenyl axetat
+NaOH d,t
0

Y (hp cht thm). Hai cht X, Y trong
s ln lt l
A. axit axetic, natri phenolat. B. axit axetic, phenol.
C. anhirit axetic, natri phenolat. D. anhirit axetic, phenol.
Cu 55: Poli(metyl metacrylat) v nilon-6 c to thnh t cc monome tng ng l
A. CH2=C(CH3)COOCH3 v H2N[CH2]5COOH.
B. CH2=CHCOOCH3 v H2N[CH2]6COOH.
C. CH2=C(CH3)COOCH3 v H2N[CH2]6COOH.
D. CH3COOCH=CH2 v H2N[CH2]5COOH.
Cu 56: t chy m gam ng (II) sunfua trong kh oxi d thu c cht rn X c khi lng bng (m 4,8)
gam Nung X trong kh NH3 d ti khi lng khng i c cht rn Y. Ho tan Y trong dung dch HNO3 long
d, thu c V lt kh Z (ktc) khng mu, ha nu trong khng kh. Gi tr ca m (gam) v V (lt) l
A. 28,8 gam v 2,24 lt. B. 28,8 gam v 4,48 lt. C. 24,0 gam v 4,48 lt. D. 19,2 gam v 2,24 lt.
Cu 57: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong
khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh (
ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l
A. 78,4 lt. B. 56,0 lt. C. 70,0 lt. D. 84,0 lt.
Cu 58: Thu phn hon ton 150 gam hn hp cc ipeptit thu c 159 gam cc aminoaxit. Bit rng cc ipeptit
c to bi cc aminoaxit ch cha mt nguyn t N trong phn t. Nu ly 1/10 khi lng aminoaxit thu c tc
dng vi HCl d th lng mui thu c l
Cu 59: C mt dung dch X gm CH3COOH 1M v CH3COONa 0,10M (cho CH3COOH c K
a
= 10
4,76
). Gi tr
pH ca dung dch X l
A. 2,88. B. 3,76. C. 11,12. D. 10,24.
Cu 60: Cho dung dch cc cht sau: axit glutamic; glyxin, lysin, alanin, imetylamin, anilin,
phenylamoniclorua, kalibenzoat, etilenglicol. S dung dch lm qu tm chuyn mu hng, mu xanh, khng
i mu ln lt l
A. 2, 4, 3. B. 3, 2, 4. C. 3, 3, 3. D. 2, 3, 4.

10 | L O V E B O O K . V N
P N

1D 2A 3C 4D 5A 6B 7A 8A 9C 10C
11B 12B 13A 14C 15A 16C 17A 18C 19D 20A
21C 22C 23A 24D 25B 26B 27B 28C 29C 30B
31B 32D 33C 34D 35C 36D 37D 38B 39B 40A
41C 42D 43D 44D 45B 46C 47D 48C 49A 50A
51B 52A 53A 54C 55A 56B 57C 58D 59B 60D

GII CHI TIT V BNH LUN

Cu 1: p n D
Ta c: n
H
2
(TH1)
< n
H
2(TH2)
TH1 Al cha tan ht.
Gi x, y l s mol Ba v Al c trong m (g) hn hp.
+TH1: X + H
2
O.
Ba + 2H
2
O Ba(OH)
2
+ H
2
x x x

2Al + Ba(OH)
2
+ H
2
O Ba(AlO
2
)
2
+ 3H
2
x 3x

n
H
2
= 4x =
8,96
22,4
= 0,4 x = 0,1 (mol)
+TH2: X + Ba(OH)
2
d.
Ba + 2H
2
O Ba(OH)
2
+ H
2
x x

2Al + Ba(OH)
2
+ H
2
O Ba(AlO
2
)
2
+ 3H
2
y 1,5y

n
H
2
= x +1,5y =
22,4
22,4
= 1 (mol) y = 0,6 (mol)
Vy: m = m
Al
+m
Ba
= 0,6.27 +0,1.137 = 29,9(g).
Cu 2: p n A
-Cho cc dung dch tc dng vi dung dch Ba(OH)2 d. Ly kt ta thu c cho tc dng vi dung
dch HNO3 d:
+ Kt ta no tan + si bt kh Kt ta l BaCO3 dung dch X.
+ Kt ta no khng tan v khng c bt kh Kt ta BaSO4 dung dch Y.
+ Kt ta no tan mt phn v si bt kh Kt ta l BaCO3+ BaSO4 dung dch Z.
Cu 3: p n C
Pthh: 2CH3OH + O2 2HCHO + 2H2O CH3OH + O2 HCOOH + H2O
Gi n
HCOOH
= x mol n
HCHO
= 3x mol
Ta c: HCOOH
AgNO
3
/NH
3
2Ag ; HCHO
AgNO
3
/NH
3
4Ag
Suy ra: n
Ag
= 2n
HCOOH
+ 4n
HCHO
14x =
15,12
108
= 0,14 (mol) x = 0,01 (mol).
Vy: H% =
4a
0,1
= 40%
Cu 4: p n D
Ta c: CH
2
= CH COO C
6
H
5
(Y) C
6
H
5
ONa (A
1
) C
6
H
5
OH (B
1
) C
6
H
2
(NO
2
)
3
OH (C
1
).
CH
2
= CH COONa (A
2
) CH
2
= CH COOH (B
2
) CH
2
= CH COOCH
3
(C
2
).
Vy Y l Phenylacrylat.
Cu 5: p n A
Cc phn ng (4) v (5) th O2 to thnh do nhit phn mui nitrat s oxi ha cc kim loi.
Cu 6: p n B
Cc phng trnh trong H2O ng vai tr cht oxi ha hoc cht kh l:
(2), (4): H2O ng vai tr l cht oxi ha.
(6): H2O ng vai tr l cht kh.
Ch : Phng trnh (5) vi sn phm nh bi l trong iu kin nhit thp, cn vi iu kin nhit
cao ta c phng trnh: 2Na2O2 + 2H2O 4NaOH + O2.
Cu 7: p n A
Etilen khng tc dng vi dung dch AgNO3/NH3 nn loi B v D. Loi C v but-2-in khng c phn ng.
Ch : Ch cc lin kt 3 u mch mi c kh nng phn ng vi dung dch AgNO3/NH3.
Cu 8: p n C
Ta c: n
OH

= n
NaOH
+ 2n
Ba(OH)
2
= 0,06 mol.
Ta thy n
BaCO
3
= 0,01 < n
Ba(OH)
2
suy ra xy ra 2 trng hp.
+ Trng hp 1: OH
-
d.
n
CO
2
= n
BaCO
3

= 0,01 mol V = 0,1.22,4 = 0,224 lt.
+ Trng hp 2: OH
-
ht, CO2 ha tan mt phn kt ta.
12 | L O V E B O O K . V N
n
CO
2
= n
OH

n
BaCO
3
= 0,06 0,01 = 0,05 (mol) V = 0,05.22,4 = 1,12 (lt).
Cu 9: p n C
T gi thit ta gi n
A
= 4 (mol) suy ra n
O
2
= 21 (mol).
Phn ng:
C
x
H
y
+ (x +
y
4
) O
2
xCO
2
+
y
2
H
2
O
4 4(x +
y
4
) 4x

Sau phn ng: O
2
d: 21 4(x +
y
4
) , v 4x mol CO
2
suy ra n
sau
= 21 y (mol).
Do V v T khng i nn t l s mol bng t l vi p sut tng ng:
21 y
25
=
0,52p
p
y = 8
Vi y = 8 ta c cc cht kh sau:
+C3H8 (c 1 cht)
+C
4
H
8
(c 3 cht CH
2
= CH CH
2
CH
3
; CH
3
CH = CH CH
3
; CH
3
C(CH
3
) = CH
2
.
Cu 10: p n C
Gi Y l C
x
H
y
N vi s mol l a.
Phn ng: C
x
H
y
N+(x +
y
4
) O
2
xCO
2
+
y
2
H
2
O +
1
2
N
2

Mol a a (x +
y
4
) ax
ay
2

a
2

n
N
2
(khng kh)
= 4a (x +
y
4
) mol. C: {
(12x +y +14). a = 1,18
n
CO
2
= ax = 0,06
n
N
2
= 4a (x +
y
4
) +
a
2
{
ax = 0,06
ay = 0,18
a = 0,02
{
x = 3
y = 9

Vy Y l C3H9N.
Cu 11: p n B
Khi cho t t dung dch HCl vo dung dch X th:
K
2
CO
3
+ HCl KHCO
3
+ KCl (1)
Mol: 0,375 0,375 0,375
KHCO
3
+ HCl KCl +H
2
O +CO
2

Mol: 0,15 0,15 0,15
Sau phn ng (1), dung dch c: 0,375+ 0,3 = 0,675 mol KHCO3 v 0,525-0,375 = 0,15 mol HCl nn tip
tc xy ra phn ng (2).
Kt thc phn ng cn d 0,675 0,15 = 0,525 mol KHCO3
Ta c: V
CO
2
= 0,15.22,4 = 3,36(lt).
n
CaCO
3
= n
KHCO
3
= 0,525(mol) m
CaCO
3
= 0,525.100 = 52,5 (g).
Cu 12: p n B
Phn ng: 3FeCO
3
+ 10HNO
3
3Fe(NO
3
)
3
+3CO
2
+ NO +H
2
O
Mol: 0,1
1
3
0,1
0,1
3

Dung dch X cha 0,1 mol Fe
3+
v 0,3 mol NO
3

3Cu +8H
+
+ 2NO
3
3Cu
2+
+2NO +4H
2
O
Mol: 0,45 0,3
Cu +2Fe
3+
Cu
2+
+2Fe
2+

Mol: 0,050,1
n
Cu
= 0,45 +0,05 = 0,5 mol m
Cu
= 0,5.64 = 32(g)
Cu 13: p n A
Trong Cr
3+
c p =24 e = p - 3 = 21 v n = 52 24 = 28.
Cu 14: p n C
Cc cht tc dng c vi dung dch Ba(OH)2 l: Na2CO3; NaHCO3; AlCl3; Ca(HCO3)2; Mg(HCO3)2;
K2SO3 ; K2SO4.
Cu 15: p n A
CH
2
= C(CH
3
) COOH +CH
3
OH CH
2
= C(CH
3
) COOCH
3
+ H
2
O.
86(kg) 32(kg) 100(kg)
Vy: m
CH
3
OH
=
60.32
100.0,6.0,8
= 40(kg) v m
axit
=
60.86
100.0,6.0,8
= 107,5(kg).
Cu 16: p n C
Ta c n
OH
= 2n
H
2
= 2.0,03 = 0,06 (mol).
Nh t t FeCl3 vo dung dch X: Fe
3+
+ 3OH
Fe(OH)
3

Nung kt ta: 2Fe(OH)3 Fe2O3 + 3H2O
Theo phng trnh: n
Fe
2
O
3
=
1
6
n
OH

= 0,01 mol m
Fe
2
3
= 0,01.160 = 1,6(g)
Cu 17: p n A
Khi t chy X hay Y u thu c s mol ca CO2 nh hn s mol nc nn X v Y u l cc ancol no.
Theo bi ra ta c: C
=
2
3 2
= 2 =
1 +3
2
=
2 +2
2
.
+ 2 ancol l CH3OH v C3H7OH (2 cht) c 2 cp cht.
+2 ancol l CH3OH v C3H6(OH)2 (2 cht) c 2 cp cht.
+2 ancol l CH3OH v C3H5(OH)3 c 1 cp cht.
+ 2 ancol l C2H5OH v C2H4(OH)2 c 1 cp cht.
Vy c tt c 6 cp cht tha mn bi.
Ch : Trong bi ta thy khi t chy vi s mol bng nhau ca 2 ancol th s nguyn t C trung bnh
bng trung bnh cng ca s C ca 2 ancol . Ta c th m rng cho cc hp chy hu c khc.
Cu 18: p n C
-Xt trong mt na dung dch Z.
Ta c: n
NH
4
+ = n
NH
3
=
0,4704
22,4
273
. (273 +13,5)
= 0,02(mol)
n
BaCO
3
= n
CO
3
2 = n
CO
2
= 0,01 (mol) n
SO
4
2 = n
BaSO
4
=
4,3 0,01.197
233
= 0,01 (mol)
p dng nh lut bo ton in tch ta c: n
Na
+ = 2n
SO
4
2 + 2n
CO
3
2 n
NH
4
+ = 0,02 (mol).
Vy: m = 2.(2.0,02.23 + 0,02.18 + 0,01.96 + 0,01.60) = 4,76 (g).
Cu 19: p n D
Phn ng: 2Al + Fe2O3 Al2O3 + 2Fe
Mol: 2a a a 2a
Al, Al2O3 tan ht trong dung dch NaOH: 2Al + 2NaOH 2NaAlO2 + 3H2
Gi x, y l s mol ca Al v Fe2O3 c trong hn hp ban u v a l s mol Fe2O3 phn ng.
Suy ra: 27x + 160y = 12,67 (1)
Ta c: n
Al(d)
=
2
3
n
H
2
x 2a = 0,06 (2)
Cht rn cn li sau phn ng c 2a mol Fe v y a mol Fe2O3
56.2a + 160. (y a) = 12,4 160y 48a = 12,4(3)
T (1), (2) v (3) suy ra a = 0,075; x = 0,21 v y = 0,1.
Hiu sut tnh theo Fe
2
O
3
: H%=
0,075
0,1
. 100%= 75%.
Cu 20: p n A
Y lm xanh giy qu m nn Y c th l amin no hoc NH3. Z c kh nng lm mt mu dung dch nc
brom nn Z cha 1 lin kt i gc hidrocacbon ca mui.
Do X l CH2=CH-COONH3-CH3; CH
2
= CHCH
2
COONH
4
; CH3CH=CH-COONH4 (cis trans);
CH2=C(CH3)-COONH4.
Vy c 3 cht tha mn.
Cu 21: p n C
A. Sai v axit axetic khng tc dng vi phenol.
B. Sai v andehit khng tc dng vi phenol.
D. Sai v dung dch NaCl khng tc dng vi phenol.
14 | L O V E B O O K . V N
Cu 22: p n C
Ta c C
6
H
10
O
5
C
6
H
12
O
6
2C
2
H
5
OH
162(kg) 92(kg)
Suy ra: V
C
2
H
5
OH
=
92.10
162
.
0,8.0,8
0,789.0,4
= 11,516 (lt).
Cu 23: p n A
Cc cht cha lin kt cng ha tr (bao gm cng ha tr phn cc v cng ha tr khng phn cc) l:
H2S (1); SO2 (2); NH3 (5); HBr (6); H2SO4 (7); CO2 (8).
Cu 24: p n D
CH
2
= C(CH
3
)CH
2
OH (X)
+CuO
CH
2
= C(CH
3
) CHO
+O
2
CH
2
= C(CH
3
)COOH
+CH
3
OH
CH
2
= C(CH
3
)COOCH
3
.
Cu 25: p n B
p dng nh lut bo ton khi lng suy ra: n
H
2
O
=
15,2 +0,3.40 23,6
18
= 0,2 (mol)
Ta c: n
NaOH
: n
H
2
O
= 0,3: 0,2 = 3: 2 v v X tc dng vi dung dch NaOH ch to ra mui v nc nn
X c dng R COO C
6
H
3
(OH) R.
R COO C
6
H
3
(OH) R + 3NaOH RCOONa + R C
6
H
3
(ONa)
2
+ 2H
2
O
Theo phn ng: n
X
=
1
3
n
NaOH
= 0,1(mol).
M
X
=
15,2
0,1
= 152 suy ra: R + R + 136 = 152 R + R = 16 (H + CH
3
).
Vy X c cng thc phn t l C8H8O3.
Ch : Nh vo s nh gi bn trn ta c th a ra c dng ca X, khi s khng cn xt ti cc
d liu pha sau v bi lm s nhanh hn rt nhiu.
Cu 26: p n B
- Cho cc mu th tc dng vi nc Br2: propenol lm mt mu nc brom.
- Cho cc mu th cn li tc dng vi Cu(OH)2:
+ Mu th to ra dung dch mu xanh lam phenol.
+ Mu th to ra dung dch mu xanh thm c trng etilenglicol.
+ Mu th khng to ra hin tng g etanol.
Cu 27: p n B
Gi a, b ln lt l s mol ca NaI v NaBr c trong dung dch X.
Suy ra: 150a + 103b = x.
+ Dung dch X + Br2 d dung dch Y.
Dung dch Y cha (a + b) mol NaBr 103(a + b) = y.
+ Dung dch Y + Cl2 dung dch Z.
Dung dch Z cha (a+b) mol NaCl 58,5(a + b) = z.
Theo bi ra: 2y = x + z 2.103(a +b) = 150a + 103b + 58,5(a + b) b =
5
89
a.
%m
Mg
=
103b
103b +150a
=
103.
5
89
a
103.
5
89
a +150a
. 100%= 3,7%.
Cu 28: p n C
Vi a = b + 0,5c Cc cht tham gia phn ng va vi nhau. Vy sau phn ng dung dch ch
cha mui Zn(NO3)2, kim loi thu c l Ag v Cu.
Cu 29: p n C
Gi x, y ln lt l s mol Cu, Fe c trong hn hp.
Dung dch X tc dng vi Mg to NO Cu v Fe tan ht.
Theo bi ra ta c: {
64x +56y = 6,08
2x +3y = 0,08.3
{
x = 0,06
y = 0,04

Dung dch X cha HNO3 d, 0,06 mol Cu(NO3)2 v 0,04 mol Fe(NO3)3.
- Dung dch X + Mg: n
Mg
= 0,12(mol).
Cc phn ng xy ra:
3Mg + 8HNO
3
3Mg(NO
3
)
2
+ 2NO + 4H
2
O
0,03 0,03

Mg + 2Fe
3+
Mg
2+
+ 2Fe
2+
0,02 0,04

Mg + Cu
2+
Mg
2+
+ Cu
0,06 0,06 0,06

Mg + Fe
2+
Mg
2+
+ Fe
0,01 0,01 0,01

Sau phn ng: Mg ht v Fe
2+
cn d. Cht rn cn li gm 0,06 mol Cu v 0,01 mol Fe.
Vy m = m
Cu
+ m
Fe
= 0,06.64 +0,01.56 = 4,4 (g).
Cu 30: p n B
Ancol cn tm l tc dng vi CuO to ra anehit nn ancol c dng RCH2OH.
Phn ng: RCH
2
OH + CuO RCHO + Cu + H
2
O
n
CuO (phn ng)
= n
O (ly i)
=
9,3 6,9
16
= 0,15 (mol).
Suy ra: M
ancol
<
6,9
0,15
= 46 suy ra ancol cn tm l CH
3
OH.
Vy n
HCHO
= 0,15 (mol) n
Ag
= 4n
HCHO
= 0,6 mol m
Ag
= 0,6.108 = 64,8(g).
Cu 31: p n B
n
kh sau
=
m
hn hp X
M
Y
=
0,1.26 +0,2.42 +0,1.28 +0,6.2
12,5.2
= 0,6 (mol)
S mol kh gim i bng s mol H2 phn ng:
n
H
2(phn ng)
= 0,1 +0,2 +0,1 +0,6 0,6 = 0,4 (mol).
S lin kt cn li trong hn hp l: (0,1.2 + 0,2 + 0,1) 0,4 = 0,1 mol
n
Br
2
= n
= 0,1 mol m
Br
2
= 0,1.160 = 16 (g).
Cu 32: p n D
Nhng th nghim ging nhau l (1) v (2): xut hin kt ta keo trng. Th nghim (3): xut hin kt
ta keo trng v tan dn khi HCl d.
Cu 33: p n C
X l 4,4-imetylpentan-2-ol.
Cu 34: p n D
Ch : Nhng cht khng th cng tn ti trong cng mt dung dch khi chng c kh nng phn ng
vi nhau.
Cu 35: p n C
n
NaOH(phn ng)
= 0,5 0,2 = 0,3 (mol). Ta thy: n
Y
=
1
3
n
NaOH
nn Y l C
3
H
5
(OH)
3
.
Mui gm mui hu c v 0,2 mol NaCl.
Ta c: m
rn
= m
NaCl
+m
hu c
M
mui
=
34,9 0,2.58,5
0,3
= 77,33 X l (HCOO)C
3
H
5
(OOCCH
3
)
2
.
Cu 36: p n D
Gi n
HCHO
= x; n
C
3
H
4
= y mol.
HCHO
AgNO
3
/NH
3
4Ag v CH
3
C CH
AgNO
3
/NH
3
CH
3
C CAg.
Ta c h: {
30x +40y = 9,6
108.4x +147y = 73,89
{
x = 0,12
y = 0,15

Khi cho kt ta tc dng vi dung dch HCl d: CH
3
C CAg +HCl CH
3
C CH +AgCl
Kt ta thu c sau phn ng gm 0,12 mol Ag v 0,15 mol AgCl.
Vy m = m
Ag
+ m
AgCl
= 0,1.108 +0,15.143,5 = 73,365 (g).
Cu 37: p n D
Ta c: n
Y
= 0,1 mol. t chy mt na Y thu c 0,1 mol CO2.
16 | L O V E B O O K . V N
Vy C
Y
=
2.0,1
0,1
= 2 suy ra Y l CH
3
CH
2
NH
2
. Vy X l HCOONH
3
CH
2
CH
3
.
Cu 38: p n B
S mol axit acrylic bng s mol axit propanic 1 C3H4O2 + 1 C3H6O2 = 1 C6H10O4.
Vy ta coi hn hp ch gm x mol axit adipic v y mol ancol etylic.
m
X
= 146x +46y = 10,33.(1)
Do khi un nc lc Z cn thu c kt ta nn CaCO3 b ha tan mt phn, do ta c:
n
CO
2
= n
OH
n
CaCO
3
6x +2y = 2.0,35 0,27 = 0,33.(2)
T (1) v (2) suy ra x = 0,055; y = 0,05 (mol).
X + dung dch KOH:
HOOC (CH
2
)
4
COOH +2KOH KOOC (CH
2
)
4
COOK +2H
2
O
0,11 0,055

Vy sau phn ng, cht rn thu c gm:
0,12 0,11 = 0,01 mol KOH v 0,055 mol KOOC (CH
2
)
4
COOK
m = m
KOH
+ m
mui
= 0,01.56 +0,055.222 = 12,77(g)
Cu 39: p n B
Ta c: n
O(oxit)
=
3,33 2,13
16
= 0,075 mol; n
HCl
= 2n
O
= 0,15 (mol)
Suy ra: V
HCl
=
0,15
0,6
= 0,25 (lt)
Cu 40: p n A
Cc cht khi nung to ra O2 l: KClO3 (xc tc MnO2); KMnO4; KNO3; AgNO3. C 4 cht tt c.
Cu 41: p n C
Ta c:
C
6
H
12
O
6
2C
2
H
5
OH
180kg 92kg

Khi lng glucoz cn dng l: m
C
6
H
12
O
6
=
100.0,8.180.0,1
92.0,95
= 16,476 (kg).
Cu 42: p n D
Quy hn hp cho v hn hp gm: x mol FeO v y mol Fe
2
O
3
.
Theo bi ra ta c: {
72x +160y = 3,04
n
H
2
= x +3y = 0,05
{
x = 0,02
y = 0,01

X + dung dch H
2
SO
4
c nng: Ch c FeO phn ng to SO
2
.
p dng nh lut bo ton electron ta c:
n
SO
2
=
1
2
n
FeO
= 0,01 mol V
SO
2
= 0,01.22,4 = 0,224(lt).
Cu 43: p n D
A. Sai v Br
c tnh kh mnh hn Cl
(phng trnh th hai).

B. Sai v Fe
2+

c tnh kh mnh hn Br
(phng trnh th nht).

C. Sai v Cl
2
c tnh oix ha mnh hn Br
2
(phng trnh th hai).
Cu 44: p n D
n
Cu
=
10,24
64
= 0,16(mol)
Nu dung dch thu c ch cha NaNO3 cht rn thu c sau phn ng ch c mui NaNO2.
2NaNO
3
t
o
2NaNO
2
+O
2

n
NaNO
2
=
26,44
69
= 0,383 < n
NaOH
suy ra loi.
+Vy cht rn sau phn ng cha NaOH d.
Gi {
n
NaOH
= x
n
NaNO
2
= y
{
40x +69y = 26,44
x +y = 0,4
{
x = 0,04
y = 0,36

Vy s mol HNO3 phn ng vi Cu l: 0,6 0,04 = 0,56 (mol)
Cu 45: p n B
Cc cng thc cu to ng vi cng thc phn t C
4
H
9
Br:
CH
3
CH
2
CH
2
CH
2
Br; CH
3
CH
2
CHBrCH
3
; CH
3
CH(CH
3
)CH
2
Br; CH
3
C(Br)(CH
3
)CH
3
.
Cu 46: p n D
Cu 47: p n D
Gi x, y ln lt l s mol ca CH3OH v RCH2OH.
Phn 1: n
H
2
=
x +y
2
= 0,015 x +y = 0,03 (1)
Phn 2: CH
3
OH HCHO 4Ag
x 4x

RCH
2
OH RCHO 2Ag
y 2y

n
Ag
= 4x +2y = 0,1 (2)
T (1) v (2) suy ra x = 0,02 v y = 0,01.
Cu 48: p n C
Gi x, y ln lt l s mol ca Al v Al4C3.
Phn ng: Al + KOH +H
2
O KAlO
2
+ 1,5H
2

x x 1,5x

Al
4
C
3
+ 4KOH + 4H
2
O 4KAlO
2
+ 3CH
4
y 4y 3y

Sc CO
2
ti d vo dung dch: KAlO
2
+ CO
2
+ 2H
2
O KHCO
3
+ Al(OH)
3

Theo bi ra ta c: {
x +y = 0,3
x +4y =
46,8
78
{
= 0,2
= 0,1
. n
kh
= 1,5 + 3 = 0,6 ().
Cu 49: p n A
Cc phng trnh: (1); (2); (3); (6) c cng phng trnh ion: Ca
2+
+ SO
4
2
CaSO
4

Cu 50: p n A
Thy phn peptit trn th thu c 3 mui ca cc aminoaxit:
CH
3
CH(NH
2
)COOH; H
2
N CH
2
COOH; H
2
N(C
6
H
5
)CH COOH.
Cu 51: p n B
E
Cu Ag
= E
Cu
2+
Cu
0
+E
Ag
+
Ag
0
= E
Cu
2+
Cu
0
+E
Zn
2+
Zn
0
E
Zn
2+
Zn
0
+E
Ag
+
Ag
0
= E
ZnCu
0
E
Zn
2+
Zn
0
+E
Ag
+
Ag
0
= 1,1 +0,76 +0,8 = +0,46
Cu 52: p n A
(1) Sai v trong cng nghip ngi ta iu ch cht bo t m ng vt v du ca cc ht.
(5) Sai v amiloz l mt dng tinh bt nn khng dng sn xut t si dt vi.
(6) Sai v cc amino axit c s nhm NH2 bng s nhm COOH khng lm i mu qu tm.
(7) Sai v ch c tripeptit tr ln mi c phn ng mu biure vi Cu(OH)2.
Cu 53: p n A
Cu 54: p n C
C
6
H
5
OH
(CH
3
CO)
2
O(X)
Phenyl axetat
+NaOH (d),t
0
C
6
H
5
ONa (Y).
Cu 55: p n A
Cu 56: p n B
Ta c: CuS
+O
2
CuO
+NH
3
Cu
+HNO
3
NO
n
CuS
=
m(m4,8)
32 16
= 0,3 (mol) m
CuS
= 0,3.96 = 28,8(g).
p dng nh lut bo ton e ta c: n
NO
=
2
3
n
Cu
= 0,2 (mol) V
NO
= 0,2.22,4 = 4,48 (l)
Cu 57: p n C
Ta c: n
CO
2
=
7,84
22,4
= 0,35 (mol); n
H
2
O
=
9,9
18
= 0,55 (mol).
p dng nh lut bo ton nguyn t O ta c:
n
O
2
= n
CO
2
+
1
2
n
H
2
O
= 0,625 n
kk
= 5n
O
2
= 3,125 (mol) V
kk
= 3,125.22,4 = 70(lt)
Cu 58: p n D
Gi ipeptit l H2NRCO-NH-RCOOH.
H2NRCO-NH-RCOOH + H2O H2N-R-COOH + H2N-R-COOH.
18 | L O V E B O O K . V N
Ta c: n
H
2
O
=
159 150
18
= 0,5 (mol).
H
2
N R
COOH + HCl ClH

3
N R
COOH
n
HCl
= n
amino axit
=
1
10
= 0,1 (mol)
p dng nh lut bo ton ta c: m
mui
= m
amino axit
+ m
HCl
= 15,9 +0,1.36,5 = 19,55(g).
Cu 59: p n B
Phn ng: CH
3
COOH CH
3
COO
+ H
+

Ban u: 1 0,1
in ly: x x x
Cn bng: 1- x 0,1- x x
Ta c: K
a
=
(0,1 x). x
1 x
= 10
4,76

Gi s x << 0,1 khi ta c: 0,1x = 10
4,76
x = 10
3,76
pH = logx = 3,76.
Cu 60: p n D
Cc cht lm qu tm chuyn thnh mu:
+ Hng: axit glutamic, phenylamoniclorua. (2 cht)
+Xanh: lysine, imetylamin, kalibenzoat. (3 cht)
+Khng chuyn mu: glysin, alanin, anilin, etilenglicol. (4 cht).


s 2

Cu 1: Cho cc cht: NaHSO
3
; NaHCO
3
; KHS; NH
4
Cl; AlCl
3
; CH
3
COONH
4
, Al
2
O
3
, Zn, ZnO, NaHSO
4
. S cht
lng tnh l
A. 8. B. 6. C. 7. D. 5.
Cu 2: Thc hin cc th nghim sau:
(a) Nung NH4NO3 rn. (b) un nng NaCl tinh th vi dung dch H2SO4 (c).
(c) Cho CaOCl2 vo dung dch HCl c. (d) Sc kh CO2 vo dung dch Ca(OH)2 (d).
(e) Sc kh SO2 vo dung dch KMnO4. (g) Cho dung dch KHSO4 vo dung dch NaHCO3.
(h) Cho ZnS vo dung dch HCl (long). (i) Cho Na2CO3 vo dung dch Fe2(SO4)3.
S th nghim sinh ra cht kh l
A. 4. B. 5. C. 2. D. 6.
Cu 3: C 5 kim loi: Mg, Ba, Zn, Fe, Ag. Nu ch dng thm 1 cht th c th dng cht no trong s cc cht
cho di y nhn bit cc kim loi l
A. dung dch H2SO4 long. B. dung dch Ca(OH)2.
C. dung dch NaOH. D. dung dch FeSO4.
Cu 4: Hn hp A gm CH
4
, C
2
H
4
, C
3
H
4
. Nu cho 26,8 gam hn hp X tc dng vi dung dch AgNO3/NH3 d
th thu c 29,4 gam kt ta. Nu cho 8,4 lt hn hp X (ktc) tc dng vi dung dch brom th thy c 54
gam brom phn ng. % th tch CH
4
trong hn hp X l
A. 40%. B. 25%. C. 35%. D. 30%.
Cu 5: Ho tan ht m gam Al
2
(SO
4
)
3
vo nc c dung dch X. Cho 360 ml dung dch NaOH 1M vo X, thu
c 2a gam kt ta. Mc khc, nu cho 400 ml dung dch NaOH 1M vo X th thu c a gam kt ta. Cc phn
ng xy ra hon ton, gi tr ca m l:
A. 20,520. B. 19,665 C. 15,390. D. 18,810.
Cu 6: Cho propan qua xc tc ( nhit cao) thu c hn hp X gm C
3
H
8
, C
3
H
4
, C
3
H
6
v H
2
. T khi ca
X so vi H
2
bng d. Nu cho 6,16 lt X (ktc) vo dung dch brom (d) thy c 24 gam brom phn ng. Gi tr
ca d bng
A. 10. B. 15. C. 12. D. 8.
Cu 7: Hp cht hu c X tc dng c vi dung dch KOH v dung dch brom nhng khng tc dng vi
dung dch KHCO
3
. Tn gi ca X l
A. ancol benzylic. B. axit acrylic. C. anilin. D. vinyl axetat.
Cu 8: Cho cc phn ng:
(1). O
3
+ dung dch KI (6). F
2
+ H
2
O
t
0

(2). MnO
2
+ HCl c
t
0

(7). NH
3
(d) +Cl
2

(3). KClO
3
+ HCl c
t
0

(8). HF + SiO
2

(4) Dung dch HCl c + FeS
2
(9). C
2
H
5
NH
2
+ NaNO
2
+ HCl
(5). NH
3
(kh) + CuO
t
0

S trng hp to ra n cht l
A. 5. B. 8. C. 7. D. 6.
Cu 9: t chy hon ton 2,24 lt (ktc) hn hp kh gm: CH
4
, C
2
H
4
, C
2
H
6
, C
3
H
8
thu c 6,16 gam CO
2
v
4,14 gam H
2
O. S mol C
2
H
4
trong hn hp trn l
Cu 10: Ho tan Fe
3
O
4
trong lng d dung dch H
2
SO
4
long thu c dung dch X. Dung dch X tc dng
c vi bao nhiu cht trong s cc cht sau: Cu, NaOH, Br
2
, AgNO
3
, KMnO
4
, MgSO4, Mg(NO
3
)
2
, Al, H
2
S?
A. 5. B. 8. C. 6. D. 7.
Cu 11: Cho 9 gam axit axetic phn ng vi 13,8 gam ancol etylic (xc tc H
2
SO
4
c), un nng, thu c
8,25 gam etyl axetat. Hiu sut ca phn ng este ho l
20 | L O V E B O O K . V N
A. 50,00%. B. 62,50%. C. 40,00%. D. 31,25%.
Cu 12: Nung nng hn hp bt 0,1 mol Al; 0,2 mol Fe; 0,1 mol Zn; 0,3 mol S trong bnh kn. Sau mt thi gian
thu c hn hp cht rn X. Ha tan X trong dd HCl d thu c V lt kh Y (ktc). Gi tr ca V l
A. 10,08. B. 4,48. C. 6,72. D. 3,36.
Cu 13: Cc nguyn t thuc nhm IA, theo chiu in tch ht nhn tng dn th
A. bn knh nguyn t tng dn. B. nng lng ion ha tng dn.
C. tnh kh gim dn. D. m in tng dn.
Cu 14: T CH
4
ngi ta iu ch PE theo s sau:
CH
4
C
2
H
2
C
2
H
4
PE
Gi s hiu sut ca mi phn ng u bng 80% th th tch CH
4
(ktc) cn dng iu ch c 5,6 tn PE
l
A. 17500 m
3
. B. 3600,0 m
3
. C. 32626m
3
. D. 22400 m
3
.
Cu 15: Cho hn hp Fe
3
O
4
v Cu vo dung dch HCl d. Sau khi phn ng xy ra hon ton ngi ta thu c
dung dch X v cht rn Y. Nh vy trong dung dch X c cha:
A. HCl, FeCl
2
, FeCl
3
. B. HCl, FeCl
3
, CuCl
2
. C. HCl, CuCl
2
, FeCl
2
. D. HCl, CuCl
2
.
Cu 16: Cho cc cht: CH
3
CH
2
OH, C
2
H
6
, CH
3
OH, CH
3
CHO, C
6
H
12
O
6
, C
4
H
10
, C
2
H
5
Cl. S cht c th iu ch trc
tip ra axit axetic (bng 1 phn ng) l
A. 5. B. 2. C. 3. D. 4.
Cu 17: Cho hn hp X gm 2 amin n chc l ng ng k tip nhau tc dng va vi dung dch HCl
thu c 14,2 gam hn hp mui. Cho hn hp mui d vo dung dch AgNO
3
d thu c 28,7gam kt ta.
Hy cho bit cng thc phn t ca cc cht trong hn hp X
A. CH
5
N v C
3
H
9
N B. C
2
H
7
N v C
3
H
9
N C. CH
5
N v C
2
H
7
N D. C
3
H
9
N v C
4
H
11
N
Cu 18: Dy gm cc kim loi u tc dng c vi dung dch Fe(NO
3
)
3
l:
A. Cu, Ag, Au, Mg, Fe. B. Fe, Mg, Cu, Ag, Al. C. Fe, Zn, Cu, Al, Mg. D. Au, Cu, Al, Mg, Zn.
Cu 19: Chia m gam hn hp M gm hai ancol n chc k tip trong dy ng ng thnh 2 phn bng nhau.
Cho phn mt tc dng vi Na (d), c 3,36 lt kh hiro (ktc). Cho phn hai phn ng hon ton vi CuO
nhit cao, c hn hp
1
cha hai anehit (ancol ch to thnh anehit). Ton b lng
1
phn ng
ht vi AgNO
3
trong NH
3
, thu c 86,4 gam Ag. Gi tr ca m l
Cu 20: Cho cc pht biu di y
1. Cc halogen (F, Cl, Br, I) u c s oxi ho t -1 n +7
2. F
2
l cht ch c tnh oxi ho
3. F
2
y c Cl
2
ra khi dung dch mui NaCl
4. Tnh axit ca cc axit halogenhiric tng theo th t: HF, HCl, HBr, HI
Cc pht biu ng l
A. 1, 2, 3. B. 2, 3. C. 2, 4. D. 1, 2, 4.
Cu 21: Cho cc cht sau y: HNO
2
, Br
2
, SO
2
, N
2
, F
2
, H
2
O
2
, CrCl
3
, S. S cht c c tnh oxi ha v tnh kh l
A. 7. B. 4 C. 6. D. 5.
Cu 22: Cho bt Fe vo dung dch hn hp NaNO
3
v H
2
SO
4
n phn ng hon ton thu c dung dch A
(khng cha mui amoni), hn hp kh X gm NO, H
2
v c cht rn khng tan. Trong dung dch A cha cc
mui:
A. FeSO
4
, Na
2
SO
4
. B. FeSO
4
, Fe(NO
3
)
2
, Na
2
SO
4
.
C. FeSO
4
, Fe(NO
3
)
2
, Na
2
SO
4
, NaNO
3
. D. FeSO
4
, Fe
2
(SO
4
)
3
, NaNO
3
, Na
2
SO
4
.
TN1: Cho rt t t dung dch Na2CO3 vo dung dch AlCl3.
TN2: Cho rt t t dung dch cha 0,1mol HCl n ht vo dung dch cha 0,1 mol Na
2
CO
3
v 0,1 mol NaHCO
3

.
TN3: Cho dung dch NaHSO
4
vo dung dch Ca(HCO
3
)
2

S th nghim c gii phng kh CO
2
l
A. 0. B. 3. C. . 2. D. 1.
Cu 24: Ho tan hon ton m gam Fe trong dung dch HNO
3
thy c 0,3 mol kh NO
2
(sn phm kh duy nht)
thot ra, nh tip dung dch HCl va vo li thy c 0,02 mol kh NO (sn phm kh duy nht) bay ra. C
cn dung dch sau phn ng thu c cht rn c khi lng l
A. 26,92 g. B. 19,50 g. C. 24,27 g. D. 29,64 g.
Cu 25: Cho 100 ml dung dch Ba(OH)
2
0,8M vo 200 ml dung dch cha Na
2
SO
4
0,2M v FeSO
4
xM thu c
24,04 gam kt ta. Gi tr ca x l
A. 0,15M . B. 0,30M. C. 0,60M . D. 0,45M.
Cu 26: t chy hon ton m gam hn hp X gm hai este ng phn ca nhau cn dng 0,525 mol O2 v thu
c 0,45 mol CO2, 0,45 mol H2O. Nu cho m gam X tc dng ht vi 0,2 mol NaOH, ri c cn dung dch to
thnh cn li 12,9 gam cht rn khan. Phn trm khi lng ca este c s nguyn t cacbon trong gc axit
nh hn trong X l
A. 33,33. B. 66,67. C. 60,00. D. 50,00.
Cu 27: X v Y l 2 ng phn ca nhau. X, Y tc dng vi NaOH theo phng trnh sau
X + NaOH C
2
H
4
O
2
NNa + CH
4
O
Y + NaOH C
3
H
3
O
2
Na + Z + H
2
O.
Z l cht no di y
A. H
2
. B. CH
3
NH
2
. C. NH
3
. D. CH
3
OH.
Cu 28: t chy hon ton m gam cacbohirat cn 13,44 lt O2 (ktc) sau em hp th hon ton sn phm
chy trong 200 ml dung dch cha ng thi NaOH 1,75M v Ba(OH)
2
1M thu c kt ta c khi lng l
Cu 29: Phenol phn ng c vi bao nhiu cht trong s cc cht sau: NaOH, HCl, Br
2
,
(CH
3
CO)
2
O, CH
3
COOH, Na, NaHCO
3
, CH
3
CH
2
OH?
A. 4. B. 6. C. 5. D. 7.
Cu 30: C bao nhiu cht c th phn ng vi axit fomic trong s cc cht sau: KOH, NH
3
, CaO, Mg, Cu, Na
2
CO
3
,
Na
2
SO
4
, CH
3
OH, C
6
H
5
OH, dd Br
2
, AgNO
3
/NH
3
?
A. 8. B. 9. C. 7. D. 6.
Cu 31: Clo ho mt hirocacbon trong iu kin thch hp thu c 2 cht cng c cng thc phn t l
C
2
H
4
Cl
2
. Hirocacbon l
A. etilen. B. etilen hoc etan. C. axetilen. D. etan.
Cu 32: Trung ha 28 gam mt cht bo cn dng 20 ml dung dch NaOH 0,175M. Ch s axit ca cht bo l
A. 9. B. 8. C. 7. D. 6.
Cu 33: Cho 4 pht biu sau:
-Vi ti c th hy c brom c. - Kh clo nguyn cht c kh nng ty trng.
-CO2 rn bo qun thc phm an ton. - Kh CO2 gy ra hin tng ma axit.
S pht biu ng l
A. 3. B. 2. C. 4. D. 1.
Cu 34: C 8 cht: phenyl clorua, benzyl clorua, axetilen, propin, but-2-in, anehit axetic, glucoz, saccaroz,
propyl fomat. Trong cc cht , c bao nhiu cht tc dng c vi dung dch AgNO3 trong NH3 d to thnh
kt ta?
A. 8. B. 7. C. 6. D. 5.
Cu 35: Cho dung dch HCl ln lt tc dng vi: NaHS, K
2
CO
3
, CuS, FeS, Ag
2
S, Fe, Cu, Fe(NO
3
)
2
. S th nghim
xy ra phn ng ha hc l
A. 6. B. 5. C. 8. D. 7.
Cu 36: Cho m gam Mg vo 400 ml dung dch X cha FeCl
3
0,3M v CuSO
4
0,5M. Sau khi phn ng xy ra hon
ton thu c 2,56 gam cht rn. Gi tr ca m l
A. 2,88. B. 2,16. C. 2,40. D. 0,96
Cu 37: Cho 10 gam cht X (ch cha nhm chc este c phn t khi l 100 vC) tc dng vi 150 ml dung
dch NaOH 1M. Sau phn ng, c cn dung dch thu c 11,6gam cht rn khan v mt cht hu c Y. Cng
thc ca Y l
A. CH
3
OH. B. C
2
H
5
OH. C. CH
3
CHO. D. CH
3
COCH
3
.
Cu 38: Dung dch Y gm Al
3+
; Fe
2+
; 0,05 mol Na
+
; 0,1 mol SO
4
2
; 0,15 mol Cl
. Cho V lit dung dch NaOH 1M,

vo dung dchY thu c kt ta ln nht th gi tr V l
22 | L O V E B O O K . V N
A. 0,30. B. 0,25. C. 0,40. D. 0,35.
(1) t dy st trong kh clo.
(2) t nng hn hp bt Fe v S (trong iu kin khng c oxi).
(3) Cho FeO vo dung dch HNO
3
(long, d).
(4) Cho Fe vo dung dch Fe
2
(SO
4
)
3
.
(5) Cho Fe vo dung dch H
2
SO
4
(long, d).
C bao nhiu th nghim to ra mui st (II)?
A. 1. B. 3. C. 2. D. 4.
Cu 40: Hn hp X gm C
3
H
8
, C
2
H
4
(OH)
2
v mt s ancol no, n chc, mch h (trong C
3
H
8
v C
2
H
4
(OH)
2

c s mol bng nhau). t chy hon ton 5,444 gam X ri hp th ton b sn phm chy vo dung dch
Ba(OH)2 d thy khi lng bnh tng ln 16,58 gam v xut hin m gam kt ta. Gi tr ca m l
A. 42,158. B. 43,931. C. 47,477. D. 45,704.
II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B)
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: Cho cc polime: polietilen, poli(vinylclorua), caosu buna, Polistiren, amiloz, amilopectin, xenluloz,
nha novolac, t nilon-6. S polime c cu to mch khng nhnh l
A. 8. B. 6. C. 7. D. 9.
Cu 42: Hn hp A gm anehit X, xeton Y (Y c s nguyn t cacbon bng X) v anken Z. t chy hon ton
m gam hn hp A cn 17,696 lt O
2
(ktc) sinh ra 12,992 lt CO
2
(ktc) v 10,44 gam H
2
O. Tn gi ca X l
A. Etanal B. Etandial C. metanal D. Propanal
Cu 43: Cho Cu vo dung dch FeCl
3
; H
2
S vo dung dch CuSO
4
; HI vo dung dch FeCl
3
; dung dch AgNO
3
vo
dung dch Fe(NO
3
)
3
; dung dch NaHSO
4
vo dung dch Fe(NO
3
)
2
. S trng hp xy ra phn ng l
A. 5. B. 3. C. 2. D. 4.
Cu 44: Oxi ha 2m gam ancol no, n chc, bc 1 bng oxi khng kh trong iu kin thch hp th thu c
3m gam hn hp X gm anehit, axit v nc. Cng thc ca ancol trn l
A. CH
3
OH hoc C
2
H
5
OH. B. CH
3
OH. C. C
2
H
5
OH. D. C
2
H
5
OH hoc C
3
H
7
OH
Cu 45: Cho s phn ng sau: Este X + NaOH CH
3
COONa + cht hu c Y.
Y + O
2

xt
Y
1
; Y
1
+ NaOH CH
3
COONa + H
2
O. Hy cho bit bao nhiu cht X tha mn s trn?
A. 1. B. 4. C. 2. D. 3.
Cu 46: Khi nhit phn cc cht sau: KNO
3
, KMnO
4
, NH
4
NO
3
, H
2
O
2
, Fe(OH)
3
, NH
4
HCO
3
, CaCO
3
, KClO
3
. S phn
ng oxi ho kh l
A. 6. B. 5. C. 4. D. 7.
Cu 47: Cho x gam P
2
O
5
tc dng ht vi 338 ml dung dch NaOH 2M. C cn dung dch sau phn ng thu c
3x gam cht rn. Gi tr ca x l
A. 14,2. B. 12,78. C. 11,36. D. 17,04.
Cu 48: Cho cc th nghim sau
Sc SO
2
vo dung dch BaCl
2
d (1). Cho SO
3
vo dung dch Ba(OH)
2
d (2).
Cho dung dch KOH vo dung dch Ba(HCO
3
)
2
(3) Cho dung dch H
2
S vo dung dch ZnCl
2
(4)
Cho NH
3
d vo dung dch AlCl
3
(5)
S th nghim thu c kt ta l
A. 2. B. 5. C. 4. D. 3.
Cu 49: Hn hp M gm hai aminoaxit X v Y u cha mt nhm COOH v mt nhm NH
2
(t l mol 3 :2).
Cho 17,24 gam M tc dng ht vi 110 ml dung dch HCl 2M thu c dung dch Z. tc dng ht vi cc cht
trong Z cn 140 ml dung dch KOH 3M. Cng thc cu to ca X, Y ln lt l
A. H
2
NCH
2
COOH v H
2
NC
4
H
8
COOH. B. H
2
NCH
2
COOH v H
2
NC
3
H
6
COOH.
C. H
2
NC
2
H
4
COOH v H
2
NC
3
H
6
COOH. D. H
2
NCH
2
COOH v H
2
NC
2
H
4
COOH.
Cu 50: Hn hp X gm SO
2
v O
2
c t khi hi so vi H
2
l 24. Cho hn hp X (ktc) i qua bnh cha V
2
O
5

nung nng. Hn hp thu c sau phn ng c t khi so vi H
2
l 30. Hiu sut ca phn ng gia SO
2
vi O
2

l
A. 20%. B. 60%. C. 40%. D. 80%.
B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Chn pht biu sai
A. C th phn bit dung dch CrCl
3
v AlCl
3
bng dung dch NaOH.
B. Photpho bc chy khi tip xc vi CrO
3
.
C. Trong mi trng axit, Zn kh Cr
3+
thnh Cr.
D. Trong mi trng kim, Br
2
oxi ha Cr
3+
thnh CrO
4
2
.
Cu 52: Khi pin in ha Zn- Ag phng in c cu mui NH
4
Cl th
A. ion NH
4
+
di chuyn v in cc Zn v ion Cl
di chuyn v in cc Zn.
B. ion NH
4
+
di chuyn v in cc Ag.
C. ion NH
4
+
di chuyn v in cc Ag v ion Cl
D. ion NH
4
+
Cu 53: t chy hon ton m gam hn hp X gm ancol etylic, axetanehit, metyl fomat thu c 0,1 mol
CO
2
v 0,13 mol H
2
O. Cho m gam X trn vo 1 lng d dd AgNO
3
trong NH
3
thu c a gam kt ta. Gi tr
ca a l
A. 4,32 B. 1,08 C. 10,08 D. 2,16
Cu 54: Hirat ha 3,36 lt axetilen (ktc) thu c hn hp A gm hai cht hu c( hiu sut phn ng 60%
tnh theo C
2
H
2
). Cho ton b A trn vo bnh ng lng d nc brom th s mol brom phn ng l
A. 0,21. B. 0,15. C. 0,09. D. 0,06.
Cu 55: Cho dy cc cht: Si, CrO
3
, Zn, Pb, Cr, Al, Sn. S cht trong dy tan c trong dung dch NaOH c, un
nng l
A. 7. B. 6. C. 5. D. 4.
Cu 56: Cho cc dung dch c cng nng mol sau: NH
4
Cl (1), NaCl (2), NaF (3), HCl (4). Th t cc dung
dch c gi tr pH tng dn l
A. (1)<(4)<(2)<(3). B. (3)<(2)<(1)<(4). C. (4)<(1)<(2)<(3). D. (4)<(1)<(3)<(2).
Cu 57: hp cht hu c no, mch h, c cng thc phn t C4H8O, lm nht mu nc brom. S cu to tha
mn X l
A. 2. B. 1. C. 4. D. 3.
Cu 58: Cho s chuyn ha: Phenyl clorua
NaOH
,t
0
cao,p cao
X
HCl
Y
H
2
d,t
0
cao,p cao
Z
CuO d,t
0
T.
Bit X, Y, Z, T l cc cht hu c. Pht biu no sau y ng?
A. Y v T u lm nht mu nc brom.
B. Z l ancol no, n chc, mch h.
C. Dung dch ca X lm qu tm chuyn sang mu .
D. T phn ng c vi Br
2
(H
+
).
Cu 59: Xt phn ng thun nghch sau: SO
2
(k) + NO
2
(k) SO
3
(k) + NO(k).
Cho 0,11(mol)SO
2
, 0,1(mol)NO
2
, 0,07(mol)SO
3
vo bnh kn 1 lt. Khi phn ng t trng thi cn bng th cn
li 0,02(mol)NO
2
. Vy hng s cn bng K
C
l
A. 23,00. B. 20,00. C. 18,00. D. 0,05.
Cu 60: X l 1 pentapeptit mch h . Thy phn hon ton X ch thu c 1 aminoaxit no Y, mch h, c 1
nhm amino v 1 nhm cacboxyl (tng % khi lng ca O v N trong Y l 51,685%). Khi thy phn ht m
gam X trong mi trng axit thu c 30,2 gam tetrapeptit; 30,03 gam tripeptit; 25,6 gam ipeptit v 88,11
gam Y. Gi tr ca m l
A. 167,85. B. 156,66. C. 141,74. D. 186,90.
P N

1B 2D 3A 4D 5D 6A 7D 8B 9C 10B
11B 12A 13A 14A 15C 16D 17C 18C 19B 20C
21A 22A 23C 24A 25C 26B 27C 28D 29A 30A
31D 32C 33B 34D 35B 36C 37C 38A 39B 40D
41A 42D 43D 44D 45C 46B 47C 48D 49B 50D
51C 52C 53A 54A 55B 56C 57A 58D 59B 60B

24 | L O V E B O O K . V N

Cu 1: p n B
NaHSO
3
, NaHCO
3
, NaKHS, CH
3
COONH
4
, Al
2
O
3
, Zn
Cu 2: p n D
a) NH
4
NO
3
N
2
O +2H
2
O
b) NaCl
r
+H
2
SO
4
NaHSO
4
+ HCl
c) CaOCl
2
+ 2HCl Cl
2
+CaCl
2
+ H
2
O
g)2KHSO
4
+2NaHCO
3
K
2
SO
4
+Na
2
SO
4
+2CO
2
+2H
2
O
h)ZnS +2HCl ZnCl
2
+H
2
S
i)3Na
2
CO
3
+Fe
2
(SO
3
)
3
+3 H
2
O 2Fe(OH)
3
+3Na
2
SO
4
+3CO
2

Cu 3: p n A
Dng dung dch H
2
SO
4
th:
To ra kt ta v c kh bay ra l Ba
Ba +H
2
S BaSO
4
+H
2
()
Khng c kh bay ra l Ag
Mg, Zn, Fe u khng c hin tng kh bay ra thu c cc dung dch:
Mg +H
2
SO
4
MgSO
4
+H
2

Zn +H
2
SO
4
ZnSO
4
+H
2

Fe +H
2
SO
4
FeSO
4
+H
2

Sau phn ng () , Ba cn d:
Ba +2H
2
O Ba(OH)
2
+H
2

Dng dung dch Ba(OH)
2
th vo cc dung dch mui ca Mg, Fe, Zn
Kt ta xut hin v tan sau l Zn
ZnSO
4
+Ba(OH)
2
BaSO
4
+Zn(OH)
2

Zn(OH)
2
+Ba(OH)
2
BaZnO
2
+2H
2
O
Kt ta ha nu trong khng kh l Fe
FeSO
4
+Ba(OH)
2
Fe(OH)
2
+BaSO
4

2Fe(OH)
2
+
1
2
O
2
+H
2
O 2Fe (OH)
3

Cu 4: p n D
n
X(trong 8,4 g hn hp)
= 0,375(mol)
Trong 8,4 g hn hp c {
x mol CH
4
y mol C
2
H
4
z mol C
3
H
4
x +y +z = 0,375 (
1
)
n
Ba phn ng
= 0,3375 = y +2z (
2
)
Trong 26,8 g hn hp X c {
kx mol CH
4
ky mol C
2
H
4
kz mol C
3
H
4
k(16x +28y +40z) = 26,8 (1)
n
C
3
H
4
= n
C
3
H
3
Ag
=
294
147
= 0,2(2)
T (1) v (2) 0,2. (16x +28y +40z) = 26,8z(
3
)
Gii h {
(
1
)
(
2
)
(
3
)
{
x = 0,1125
y = 0,1875
z = 0,075
. Vy %V
CH
4
(X) =
0,1125
0,375
. 100%= 30%
Cu 5: p n D
n
NaOH(1)
= 0,36(mol); n
NaOH(2)
= 0,4(mol)
TH
1
: Th nghim u Al(OH)
3
cha b ha tan() n
Al(OH)
3
=
1
3
n
NaOH
= 0,12(mol)
n
Al(OH)
3
(TH
2
)
= 0,06 mol
TN
2
th Al(OH)
3
b ha tan
n
Al(OH)
3
= 8n
Al
2
(SO
4
)
3
n
NaOH
n
Al
2
(SO
4
)
3
= 0,0525(mol)(khng tha mn ())
TH
2
: Al(OH)
3
b tan mt phn 2 phn ng
Gi {
n
Al
2
(SO
4
)
3
= x
n
Al(OH)
3
(1) = 2y n
Al(OH)
3
(2) = y
c {
2y = 8x 0,36
y = 8x 0,4
{
y = 0,4
x = 0,55
m = 18,81
Cu 6: p n A
n
Br
2
= 0,15 (mol) = n
linkt
= n
H
2

(v c mi H
2
c tch ra sau phn ng hiro th c 1 lin kt )
n
hn hp
=
6,16
22,4
= 0,275 (mol) n
C
3
H
x
= 0,275 0,15 = 0,125 = n
C
3
H
8

d
=
m
n
=
m
C
3
H
8
n
x
=
0,125.44
0,275
= 20 d =
20
2
= 10
Cu 7: p n D
Cu 8: p n B
(1)O
3
+2KI +H
2
O 2KOH +O
2
+I
2
(5)2NH
3
+3CuO
t
o
N
2
+3Cu +3H
2
O
(2)MnO
2
+4HCl
t
o
MnCl
2
+Cl
2
+2H
2
O (6)2F
2
+2H
2
O 4HF +O
2

(3)KClO
3
+6HCl
KCl +3Cl
2
+3H
2
O (7)8NH
3
(d) +3Cl
2
N
2
+6NH
4
Cl
(4)2HCl +FeS
2
FeCl
2
+H
2
S +S (8)C
2
H
5
NO
2
+HCl +NaNO
2
t
o
C
2
H
4
O
3
+N
2
+H
2
O
Cu 9: p n C
n
CO
2
= 0,14 mol, n
H
2
O
= 0,23 mol
n
ankan
= n
H
2
O
n
CO
2
= 0,09 (mol). M n
hn hp
= 0,1 n
C
2
H
4
= 0,01(mol)
Cu 10: p n B
Fe
3
O
4
+4H
2
SO
4
(d) FeSO
4
+Fe
2
(SO
4
)
3
+4H
2
O
Dung dch X( FeSO
4
, Fe
2
(SO
4
)
3
, H
2
SO
4
) phn ng c vi: Cu, NaOH, Br
2
, AgNO
3,
, KMnO
4
, Mg(NO
3
)
2
, Al, H
2
S
Cu 11: p n B
n
CH
3
COOH
= 0,15 mol, C
2
H
5
OH = 0,3 mol
n
este l thuyt
= 0,15 (mol), m n
este thc t
= 0,09375 mol H =
0,09375
0,15
. 100%= 62,5%
Cu 12: p n A
Ton b qu trnh:
{
n
e cho
= 3.0,1 +0,2.2 +0,1.2
2n
e nhn
= 2n
H
2
S
+2n
H
2
n
H
2
S
+n
H
2
= 0,9 V = 10,08 (l)
Cu 13: p n A
Cu 14: p n A
n
mt xch
=
5,6.10
6
28
= 2.10
5
(mol)
n
CH
4
= 2n
mt xch
(bo ton C)
Do H = 0,8 mi phn ng n
CH
4
(thc t ) = 2.
n
mt xch
0,8
3
= 17,5.10
6
(l) = 17500 m
3

Cu 15: p n C
Fe
3
O
4
+8HCl FeCl
2
+2FeCl
3
+4H
2
O
2FeCl
3
+Cu 2FeCl
2
+CuCl
2

Sau phn ng thu c cht rn Y (Cu) FeCl
3
ht, dung dch X (FeCl
2
, CuCl
2
, HCl d)
Cu 16: p n D
CH
3
CH
2
OH+O
2
xt,t
o
CH
3
COOH + H
2
O CH
3
OH+CO
xt,t
0
CH
3
COOH
CH
3
CHO +O
2
t
o
CH
3
COOH 2C
4
H
10
+5O
2
t
o
,xt
4CH
3
COOH+2H
2
OS
Cu 17: p n C
n
AgCl
= 0,2mol = n
HCl
= n
X
m
hn hp X
= m
mui
m
HCl
= 6,9 (g)
X =
6,9
0,2
= 34,5 2 amin l CH
5
N, C
2
H
7
N
Cu 18: p n C
Cu 19: p n B
26 | L O V E B O O K . V N
n
H
2
= 0,15 (mol) n
ancol
= 0,3 mol
n
Ag
= 0,8 > 2n
ancol
2 ancol l {
CH
3
OH:
0,8 0.2.2
2
= 0,1(mol)
C
2
H
5
OH: 0,2 (mol)
m = 2(0,1.32 +0,2.46)
= 24,8(g)
Cu 20: p n C
Cu 21: p n A
HNO
2
, Br
2
, N
2
, H
2
O
2
, CrCl
3
, S
Cu 22: p n A
Sau phn ng cn li cht rn nn sinh ra mui Fe (II) v H
+
, NO
3
ht cn FeSO
4
, Na
2
SO
4

Cu 23: p n C
TN
1
: 3Na
2
CO
3
+2AlCl
3
+3H
2
O 6NaCl +2Al(OH)
3
+ 3CO
2

TN
2
: HCl +Na
2
CO
3
NaHCO
3
+NaCl
0,1 0,1
Phn ng va khng to ra CO2
TN
3
: 2NaHSO
4
+Ca(HCO
3
)
2
Na
2
SO
4
+CaSO
4
+2 CO
2
+2H
2
O
Cu 24: p n A
Phn ng 1: n
NO
2
= 0,3 mol n
NO
3
(mui ) = 0,3(mol)
Phn ng 2: n
NO
= 0,02 < n
NO
3
(mui ) n
NO
3
trong mui cn li: 0,3 0,02 = 0,28
Fe y ln ht ha tr III
3n
Fe
= n
NO
2
+3n
NO
n
Fe
= 0,12(mol)
Ta c: 3n
Fe
3+ = n
NO
3
+n
Cl
n
Cl
= 0,08(mol). Vy m
mui
= 0,12.56 +0,08.35,5 +0,28.62
Cu 25: p n C
{
n
Ba(OH)
2
= 0,08 mol
n
SO
4
2 = 0,04 +2x
n
Fe
2+ = 0,2 mol
mol
TH
1
: Ba
2+
kt ta ht thnh BaSO
4
(n
SO
4
2 n
Ba
2+)
24,04 = 0,08.233 +0,2x. 90 x = 0,3 (tha mn) chn ngay p n C
(TH
2
: Ba
2+
cha to kt ta, khng tha mn)
Cu 26: p n B
n
CO
2
= n
H
2
O
este no n chc mch h
Bo ton O ta c: 2. n
este
+2n
O
2
= 2n
CO
2
+n
H
2
O
n
este
= 0,15 C
=
0,45
0,15
= 3
{
CH
3
COOCH
3
: x mol
HCOOCH
3
: y mol
c{
x +y = 0,15 n
NaOH d
= 0,05
82x +68y = 12,9 0,05.40
{
x = 0,05
y = 0,1

%m
HCOOC
2
H
5
= 66,67%
Cu 27: p n C
X l H
2
NCH
2
COOCH
3
, Y l CH
2
CHCOONH
4

CH
2
CHCOONH
4
+NaOH CH
2
CHCOONa +NH
3
+H
2
O
Cu 28: p n D
Cacbonhirat C
n
(H
2
O)
m

n
O
2
= 0,6 mol = n
CO
2
; n
OH
= 0,75 mol, n
Ba
2+ = 0,2 mol
n
CO
3
2 = n
OH
n
CO
2
= 0,15 mol n
BaCO
3
= n
CO
3
2 = 0,15 m
BaCO
3
= 29,55 g
Cu 29: p n A
NaOH, Br
2
, (CH
3
CO)
2
O, Na
Cu 30: p n A
KOH, NH
3
, CaO, Mg, Na
2
CO
3
, CH
3
OH, dd Br
2
, AgNO
3
NH
3

Cu 31: p n D
Cu 32: p n C
n
NaOH
= 0,0035 (mol) ch s axit bng
0,0035.56
28
. 10
3
= 7
Cu 33: p n B
Cc pht biu ng gm: {
Vi ti c th hy c brom c
CO
2
rn bo qun thc phm an ton

Cu 34: p n D
Axetilen, propin, anehit axetic, glucoz, propyl fomat
Cu 35: p n B
NaHS, K
2
CO
3
, FeS, Fe, Fe(NO
3
)
2

Cu 36: p n C
n
FeCl
3
= 0,12 mol; n
CuSO
4
= 0,2 mol
2FeCl
3
+Mg 2FeCl
2
+MgCl
2

0,12 0,06 0,12
nu CuSO
4
phn ng ht th n
Cu
= 0,2.64 = 12,8 > 2,56
n
Cu phn ng
=
2,56
64
= 0,04 = n
Mg phn ng vi Cu
2+ m = (0,04 +0,06). 24 = 2,4g
Cu 37: p n C
n
Y
= 0,1 mol; bo ton khi lng: m
Y
= 10 +0,15.40 11,6 = 4,4 Y = 44(CH
3
CHO)
Cu 38: p n A
Ta c 3n
Al
3+

+2n
Fe
2+ +0,05 = 0,1.2 +0,15 3 n
Al
3+ +2n
Fe
2+ = 0,3 = n
OH

Cu 39: p n B
(2), (4), (5)
Cu 40: p n D
C
3
H
8
, C
2
H
4
(OH)
2
c s mol bng nhau
nn c cng thc chung l C
2,5
H
7
O (tng t 1 ancol no mch h)
Hn hp X c cng thc chung C
n
H
2n+2
O
Phng trnh: C
n
H
2n+2
O +
3n
2
O
2
t
nCO
2
+(n +1)H
2
O
n
CO
2
=
n
O
2
1,5
; m n
O
2
=
16,58 5,444
32
= 0,348 n
CO
2
= 0,232 = n
BaCO
3

m
BaCO
3
= 45,704(g)
Cu 41: p n A
Polietilen, poli(vinylclorua), caosu buna, polistiren, amiloz, xenluloz, novolac, nilon-6
Cu 42: p n D
Y c s C bng X m Y l xtn nn c s C t nht l 3 suy ra ch c D l hp l
Cu 43: p n D
Cu +2FeCl
3
2FeCl
2
+CuCl
2
HI +FeCl
3
FeCl
2
+
1
2
I
2
+HCl
H
2
S +CuSO
4
CuS +H
2
SO
4
3Fe
2+
+4H
+
+NO
3
3Fe
3+
+NO +2H
2
O
Cu 44: p n D
m
O
2
= m
X
m
ancol
= m n
O
2
=
m
32

Nu ancol chuyn ht v axit n
ancol
= n
O
2
=
m
32
M
ancol
= 64
Nu ancol chuyn ht v anehit n
ancol
= 2n
O
2
=
m
16
M
ancol
= 32
M hn hp gm axit v anehit nn 64 > M
ancol
> 32
cc ancol tha mn: C
2
H
5
OH, C
3
H
7
OH
Cu 45: p n C
CH
3
COOC
2
H
5
, CH
3
COOC
2
H
3

Cu 46: p n B
KNO
3
, KMnO
4
, NH
4
NO
3
, H
2
O
2
, KClO
3

Cu 47: p n C
T
x
142
mol P
2
O
5
x
71
mol Na
y
H
3y
PO
4
. M 3x =
x
71
(23y +3 y +95) y = 5,27 > 3
28 | L O V E B O O K . V N
3x (g)cht rn gm {
0,678
3x
71
(mol) NaOH d
x
71
(mol)Na
3
PO
4
3x =
x
71
. 164 +(0,678
3x
71
) . 40
x = 11,36
Cu 48: p n D
(2), (3), (5)
Cu 49: p n B
n
HCl
= 0,22, n
NaOH
= 0,42 n
M
= 0,42 0,22 = 0,2 mol n
X
= 0,12 mol, n
Y
= 0,08 mol
M
= 86,2 mt aminoaxit l H
2
NCH
2
COOH, c th l X hoc Y
Tnh theo khi lng tm c p n B
Cu 50: p n D
d
X H
2
= 24
n
SO
2
n
O
2
= 1 H s tnh theo SO
2

Gi s ban u {
1 mol SO
2
1 mol O
2
sau phn ng thu c
2.24
30
= 1,6 mol kh n
O
2
phn ng
= 0,4 mol
n
SO
2
phn ng
= 0,8 mol H = 80%
Cu 51: p n C
Ch chuyn v Cr
2+

Cu 52: p n C
Cu 53: p n A
n
X
=
n
CO
2
2
= 0,05 mol; n
ancol
= n
H
2
O
n
CO
2
= 0,03 mol n
anehit,este
= 0,02 mol
Axetanehit, metylfomat, phn ng vi AgNO
3
trong NH
3
u thu c 2Ag n
Ag
= 0,04 a
= 4,32
Cu 54: p n A
n
C
2
H
2
= 0,15 mol; hn hp gm 2 cht hu c (C
2
H
2
, C
2
H
4
)
n
C
2
H
4
= 0,6.0,15 = 0,09 mol, n
C
2
H
2
= 0,06(mol) n
Br
2
= 0,09 +0,06.2 = 0,24 (mol)
Cu 55: p n B
Si, CrO
3
, Zn, Al, Sn, Pb
Cu 56: p n C
Cu 57: p n A
Cu 58: p n D
X: C
6
H
5
ONa; Y: C
6
H
5
OH, Z: C
6
H
10
OH (xiclohecxanol); T: Dng xeton
T phn ng c vi Br
2
(H
+
)
Cu 59: p n B
n
NO
2
phn ng
= 0,08 mol ; Do V = 1l C
M
= n
Xt cn bng: SO
2
+ NO
2
SO
3
+ NO
Mol ban u 0,11 0,1 0,07
Mol phn ng 0,08 0,08 0,08 0,08
Mol cn bng 0,03 0,02 0,15 0,08
k
c
=
0,15.0,08
0,03.0,02
= 20
Cu 60: p n B
M
Y
= 89
n
tetrapeptit
=
30,2
89.4 3.18
= 0,1 mol; n
tripeptit
=
30,03
3.89 2.18
= 0,13 mol
n
ipeptit
=
25,6
2.89 18
= 0,16 mol; n
Y
=
88,11
89
= 0,99 mol
m =
0,1.4 +0,13.3 +0,16.2 +0,99
5
. (89.5 18.4) = 156,66g

s 3

A. PHN CHUNG CHO TT C TH SINH (40 cu: T cu 1 n cu 40)
Cu 1: T nilon-6,6 l sn phm trng ngng gia hexametylen iamin vi axit?
A. picric. B. phtalic. C. benzoic. D. aipic.
Cu 2: Cho cc cht NaCl, FeS
2
, Fe(NO
3
)
2
, NaBr, CaCO
3
, NaI. C bao nhiu cht m khi tc dng vi dung dch
H
2
SO
4
c, un nng th c phn ng oxi ha-kh xy ra?
A. 3. B. 6. C. 5. D. 4.
Cu 3: Cho 10,1 gam hn hp X gm hai ancol n chc X
1
, X
2
thuc cng dy ng ng (X
1
chim 80% v
s mol v M
X
1
< M
X
2
) tc dng ht vi 6,9 gam Na kt thc phn ng thu c 16,75 gam cht rn. Cng thc
ca X
1
, X
2
ln lt l
A. C2H5OH v C3H7OH. B.CH
3
OH v C
4
H
9
OH. C.CH
3
OH v C
2
H
5
OH. D.C
2
H
5
OH v C
4
H
9
OH.
Cu 4: Cho s phn ng: C
2
H
4
X Y
+NaOH,t
0
X.
Trong s cc cht CH
3
CHO, CH
3
COOH, CH
3
COOC
2
H
5
, C
2
H
5
OH, C
2
H
5
Cl, s cht tha mn vi iu kin ca X l
A. 2. B. 4. C. 1 D. 3
Cu 5: Ha tan 51,1 gam hn hp X gm NaCl v CuSO
4
vo nc c dung dch Y. in phn dung dch Y
vi in tr mng ngn xp n khi nc bt u b in phn 2 in cc th dng li, th th tch kh anot
sinh ra gp 1,5 ln th tch kh sinh ra catot (cc th tch kh o cng iu kin nhit , p sut). Phn trm
khi lng ca CuSO
4
trong hn hp X l
A. 94,25%. B. 73,22%. C. 68,69%. D. 31,31%.
Cu 6: Dung dch cha 0,6 mol H
2
SO
4
c, un nng ha tan ht m gam Fe, sau phn ng ch thu c dung
dch X v kh SO
2
(sn phm kh duy nht). Gi tr m l
A. 15,40. B. 22,75. C. 8,60. D. 8,96.
Cu 7: Hp cht hu c Y cha C, H, O trong oxi chim 55,17% theo khi lng v c s phn ng:
X Y X Z X. X, Y, Z ln lt l
A.C
2
H
4
(OH)
2
, (CHO)
2
, CH
2
Cl CH
2
Cl. B.C
2
H
4
Cl
2
, (CHO)
2
, (COOH)
2
.
C.(COOH)
2
, (CHO)
2
, CH
2
Cl CH
2
Cl. D.CH
3
OH, CH
2
O, CH
3
Cl.
Cu 8: Dung dch NaHSO4 tc dng c vi tt c cc cht c trong nhm no sau y?
A.NaNO
3
, AlCl
3
, BaCl
2
, NaOH, KOH. C.NaHCO
3
, BaCl
2
, Na
2
S, Na
2
CO
3
, KOH.
B.BaCl
2
, NaOH, FeCl
3
, Fe(NO
3
)
2
, KCl. D.Na
2
S, Cu(OH)
2
, Na
2
CO
3
, FeCl
2
, NaNO
3
.
Cu 9: Cho m gam bt Mg vo 500 ml dung dch FeCl
3
1M. Sau khi cc phn ng xy ra hon ton, khi lng
dung dch thay i 2,4 gam so vi dung dch ban u (nc bay hi khng ng k). Gi tr no ca m trong
cc gi tr sau l khng tha mn?
A. 2,4. B. 12,3. C. 8,7. D. 9,6.
Cu 10 Cho m gam mt kim loi tc dng va vi 12,5m gam dung dch H
2
SO
4
14% (long), sau khi phn
ng xy ra hon ton thu c dung dch X. Dung dch X c khi lng th no so vi dung dch H
2
SO
4
ban
u? (bit trong qu trnh phn ng nc bay hi khng ng k)
A. Tng 8,00%. B. Tng 2,86%. C. Tng 7,71%. D. Tng 8,97%.
Cu 11: Cho 30,8 gam hn hp Cu v Fe
3
O
4
tc dng vi dung dch cha a mol HNO
3
. Sau khi cc phn ng
xy ra hon ton thu c 2,24 lt kh X (sn phm kh duy nht, ktc), dung dch Y cha 64,6 gam mui
nitrat v cn li 6,4 gam kim loi. Cng thc phn t kh X v gi tr ca a ln lt l
A.NO
2
v 0,2. B. NO v 0,7. C. NO v 0,8. D.N
2
O v 1,0.
Cu 12: t chy hon ton x mol hn hp hai anehit no, c cng s nguyn t cacbon thu c 67,2x lt CO
2

(ktc) v 43,2x gam H
2
O. Mt khc cho x mol hn hp trn tc dng vi dung dch AgNO
3
d, trong NH
3
, sau
phn ng hon ton thu c khi lng Ag l
A. 345,6x gam. B. 324x gam. C. 216x gam. D. 378x gam.
Cu 13: X l mt amin bc 3 iu kin thng th kh. Ly 7,08 gam X tc dng ht vi dung dch HCl th
khi lng mui thu c l
Cu 14: C th iu ch mt loi thuc dit nm l dung dch CuSO
4
5% (d = 1,024 gam/ml) theo s sau:
CuS CuO CuSO
4
.
30 | L O V E B O O K . V N
thu c 3125 lt thuc dit nm trn cn bao nhiu tn nguyn liu cha 80% CuS v khi lng (cn li
l tp cht tr)? Bit hiu sut ca c qu trnh iu ch l 80%
A. 0,1200 tn. B. 0,1250 tn. C. 0,1875 tn D. 0,1500 tn.
Cu 15: Hn hp lng X gm benzen, phenol, axit benzoic, ancol benzylic. Ly 10,48 gam X tc dng vi Na
va , sau phn ng hon ton thu c 0,896 lt H
2
(ktc). Cng 10,48 gam hn hp X tc dng va vi
60 ml dung dch NaOH 1M. Khi em 5,24 gam X tc dng vi dung dch NaHCO
3
d th c 0,448 lt kh CO
2

(ktc). Phn trm s mol ca benzen trong hn hp l
A. 14,88%. B. 20%. C. 25%. D. 10%.
Cu 16: Anken khi hirat ha ch thu c mt ancol duy nht l
A. propen. B. but-1-en. C. pent-2-en. D. hex-3-en.
Cu 17: Cho 24,64 lt (ktc) hn hp kh X gm CO, CO
2
, N
2
c tng khi lng l 32,4 gam i qua 100 ml dung
dch cha NaOH 0,4M v Ba(OH)
2
0,4M sau cc phn ng hon ton thu c m gam kt ta. Gi tr ca m l?
A. 19,70. B. 15,76. C. 3,94. D. 7,88.
Cu 18: Kim loi M c ha tr n khng i tc dng vi HNO3 theo phn ng
M + HNO
3
M(NO
3
)
n
+ NO
2
+ NO + H
2
O ; bit V
NO
2
: V
NO
= 2: 1
T l s phn t HNO
3
khng b kh v b kh trong phng trnh ha hc trn l
A. 8 : 3. B. 5 : 3. C. 3 : 8. D. 3 : 5.
Cu 19: Ha tan ht 17,94 gam mt kim loi kim vo mt lng nc d thu c dung dch X. Cho dung
dch X tc dng vi 36,92 gam P
2
O
5
th thu c dung dch Y ch cha hai mui c nng mol bng nhau.
Kim loi kim l
A. Na. B. Rb. C. K. D. Li.
Cu 20: Hn hp kh v hi gm CH
3
OH, C
2
H
6
, C
3
H
8
, CH
3
O CH
3
c t khi hi so vi H
2
l 19,667. t
chy hon 11,5 gam hn hp trn thu c 12,32 lt CO
2
(ktc) v m gam H
2
O. Gi tr ca m l
A. 14,4. B. 15,79. C. 13,4. D. 15,163.
Cu 21: Cho cc cht: Fructoz, vinyl axetat, triolein (glixerol trioleat), glucoz, Ala-Gly-Ala. S cht tc dng
c vi Cu(OH)
2
l
A. 3. B. 5. C. 4. D. 2.
Cu 22: Cho cc dung dch khng mu ng ring bit trong cc l mt nhn: BaCl
2
, MgSO
4
, Na
2
SO
4
,
KNO
3
, K
2
S. Nu khng dng thm thuc th no khc th nhn bit c nhiu nht bao nhiu dung dch trong
cc dung dch trn?
A. 3. B. 2. C. 4. D. 5.
Cu 23: Hp cht hu c c dng sn xut t tng hp l
A. poli(metyl metacrylat). B. poli(vinyl xianua). C. polistiren. D. poliisopren.
Cu 24: Cho cc nguyn t X (Z = 11); Y(Z = 13); T(Z=17). Nhn xt no sau y l ng?
A. Cc hp cht to bi X vi T v Y vi T u l hp cht ion.
B. Theo chiu X, Y, T bn knh ca cc nguyn t tng ng tng dn.
C. Nguyn t cc nguyn t X, Y, T trng thi c bn u c 1 electron c thn.
D. Oxit v hiroxit ca X, Y, T u l cht lng tnh.
Cu 25: C cc cht lng: etylen glicol, axit axetic, propyl axetat, ancol etylic, anehit axetic v butyl amin. Dy
ha cht nhn bit cc cht trn l
A. Cu(OH)
2
v dung dch NaOH. B. dung dch AgNO
3
v dung dch HCl.
C.Cu(OH)
2
v dung dch NaCl. D.dung dch AgNO
3
/NH
3
v dung dch KMnO
4
.
Cu 26: Ch t cc ha cht: KMnO
4
, FeS, NaCl, dung dch H
2
SO
4
v khng s dng phng php in phn th
c th iu ch c ti a bao nhiu cht kh?
A. 3. B. 4. C. 5. D. 2.
Cu 27: X l hp cht hu c n chc cha C, H, O. Ly 14,4 gam X tc dng va vi 50 gam dung dch
NaOH 16%, sau phn ng hon ton c cn dung dch, thu c 22,4 gam cht rn khan. T X iu ch axit
acrylic cn t nht bao nhiu phn ng?
A. 1. B. 2. C. 3. D. 4.
Cu 28: Dy gm cc kim loi c cng kiu mng tinh th lp phng tm din l
A. Al, Ca, Cu. B. Al, Cr, Cu. C. Ca, Cr, Al. D. Ca, Ba, Mg.
Cu 29: Nung hn hp gm x mol Fe(NO
3
)2, y mol FeS
2
v z mol FeCO
3
trong bnh kn cha mt lng d
khng kh. Sau khi cc phn ng xy hon ton a bnh v nhit ban u thy p sut bnh khng i so
vi ban u. Mi lin h gia x, y, z l
A. 6x + 2z = y. B. 3x + z = y. C. 9x + 2z = 3y. D. 6x + 4z = 3y
Cu 30: Hn hp X gm CH
3
OH v C
2
H
5
OH c cng s mol. Ly 4,29 gam X tc dng vi 7,2 gam
CH
3
COOH (c H
2
SO
4
c xc tc) thu c m gam hn hp este (hiu sut phn ng este ha u bng 50%).
Gi tr m l
A. 4,455. B. 4,860. C. 9,720. D. 8,910.
Cu 31: Ha tan ht 23,2 gam hn hp rn X gm FeO, Fe
2
O
3
, Fe
3
O
4
trong dung dch HCl long, d ri c cn
dung dch sau phn ng thu c 45,2 gam mui khan. Nu kh hon ton lng X trn s thu c bao nhiu
gam st?
A. 11,6. B. 11,2. C. 16,8. D. 12,8.
Cu 32: Hiro ha hon ton hirocacbon X (cha mt lin kt mch h hoc mt vng no) thu c
hirocacbon Y cha 18,18% H v khi lng. S cng thc cu to tha mn vi iu kin ca X l
A. 1. B. 4. C. 3. D. 2.
Cu 33: ng vi cng thc phn t C
n
H
2n2
O
2
khng th c loi hp cht hu c:
A. Axit no, n chc mch vng.
B. Este n chc, mch h, c mt ni i trong mch cacbon.
C. Anehit no, hai chc, mch h.
D. Axit n chc c hai ni i trong mch cacbon.
Cu 34: Hn hp bt no sau y tan ht trong dung dch HCl d?
A. Fe
3
O
4
v Cu c t mol tng ng 1:2. B.Fe(NO
3
)
2
v Cu c s mol bng nhau.
C. CuS v Fe
2
O
3
c s mol bng nhau. D.CaCO
3
, MgSO
4
v BaSO
4
c s mol bng nhau.
Cu 35: Ancol etylic khng tc dng vi
A. NaOH. B.C
2
H
5
OH. C. HCl. D.CH
3
COOH.
Cu 36: Ly 10,32 gam hn hp gm petanal v anlyl fomat tc dng vi dung dch AgNO
3
d trong NH
3
, sau
khi cc phn ng hon ton thu c m gam Ag. Gi tr ca m l
A. 12,96. B. 25,92. C. 10,8. D. 21,6.
Cu 37: St khng b n mn in ha khi tip xc vi kim loi no sau y trong khng kh m?
A. Sn. B. Zn. C. Ni. D. Pb.
Cu 38: Axit cacboxylic c kh nng cng hp vi H
2
l
A. axit panmitic. B. axit oleic. C. axit stearic. D. axetic.
Cu 39: Thc hin phn ng nhit nhm (trong iu kin khng c oxi) hn hp gm Fe
3
O
4
, Al thu c 80,4
gam hn hp X. Chia X thnh hai phn: phn 2 c khi lng gp 3 ln khi lng phn 1. Phn 1 tc dng va
vi 100ml dung dch NaOH 1M. Phn 2 khi tc dng vi HNO
3
c nng, d th thu c V lt kh NO
2
(
ktc). Gi tr ca V l
A. 25,20. B. 20,16. C. 10,08. D. 45,36.
Cu 40: Hp cht hu c: OHC CH(OH) CH = CH CHO c tn gi l
A. 3-hiroxi prop-1-en-1,3-ial. B. 4-hiroxi pent-2-en-1,5-ial.
C. 2-hiroxi pent-3-en-1,5-ial. D. 1-hiroxi prop-2-en-1,3-ial.
B. PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II)
Phn I. Theo chng trnh Chun (10 cu: T cu 41 n cu 50)
Cu 41: t chy hon ton m gam hn hp X gm FeS
2
v mt oxit st cn dng 0,6 mol O
2
thu c 0,4 mol
Fe
2
O
3
v 0,4 mol SO
2
. Cho m gam hn hp X trn tc dng vi dung dch H
2
SO
4
c nng, d n khi cc phn
ng xy ra hon ton, sn phm kh duy nht l SO
2
th s mol H
2
SO
4
tham gia phn ng l bao nhiu?
Cu 42: Dy gm cc cht m khi cho tng cht tc dng vi dung dch HI u sinh ra sn phm c it l
A. Fe
2
O
3
, Fe
3
O
4
, Fe
2
(SO
4
)
3
, Cl
2
. C. AgNO
3
, Na
2
CO
3
, Fe
2
O
3
, Br
2
.
B. Fe
3
O
4
, FeO, AgNO
3
, FeS. D. Fe(OH)
3
, FeO, FeCl
3
, Fe
3
O
4
.
Cu 43: Hp cht m khng th dng 1 phn ng ha hc to ra butaien l
A. vinyl axetilen. B. but-2-en. C. ancol etylic. D. etilen
32 | L O V E B O O K . V N
Cu 44: Hp cht hu c X c cng thc phn t C
2
H
7
NO
2
. em 15,4 gam X tc dng ht vi dung dch NaOH
thu c m gam hn hp 2 cht hu c (u lm i mu qu tm m). Gi tr ca m l
A. 16,4. B. 19,8. C. 24,4. D. 13,2.
Cu 45: Bng phng php ha hc, c th phn bit 3 dung dch khng mu:HCl long, KNO
3
, Na
2
SO
4
ng
trong 3 l mt nhn ch vi thuc th l
A. Qu tm. B.BaCl
2
. C. Na
2
CO
3
D. Bt Fe.
Cu 46: Nung nng 0,5 mol hn hp X gm H
2
, N
2
trong bnh kn c xc tc thch hp, sau mt thi gian thu
c hn hp Y. Cho 12 gam hn hp Y i qua ng ng CuO d, un nng thy khi lng cht rn trong
ng gim nhiu nht l 3,2 gam. T khi hi ca X so vi H
2
l
A. 7,2. B. 11,4. C. 3,6. D. 3,9.
Cu 47: Nh t t dung dch NaOH vo dung dch X (dung mi H
2
O) thy xut hin kt ta, cho tip dung dch
HCl vo li thy kt ta tan ra. Vy cht tan trong dung dch X l
A. C
2
H
5
NH
3
Cl. B. CH
3
COONa. C. C
6
H
5
NH
3
Cl. D. C
6
H
5
ONa.
Cu 48: Cho 2,75 gam hn hp M gm 2 ancol X, Y qua CuO, t nng, sau phn ng hon ton thu c hn
hp Z gm 2 anehit n chc, ng ng k tip. Ly ton b lng Z thu c trn thc hin phn ng
trng bc th thu c ti a 27 gam Ag. Khng nh khng ng l
A. T X v Y u c th dng 1 phn ng ha hc to ra axit axetic.
B. X chim 50% s mol trong hn hp M.
C. Khi t chy hon ton hn hp M th s mol O
2
cn dng gp 1,5 ln s mol CO
2
to ra.
D. X v Y c th tc dng vi nhau.
Cu 49: t chy hon ton m gam hn hp X gm hai amino axit X
1
, X
2
(cha 1 chc axit, 1 chc amin v X
2

nhiu hn X
1
mt nguyn t cacbon), sinh ra 35,2 gam CO
2
v 16,65 gam H
2
O. Phn trm khi lng ca X
1

trong X l
A. 80%. B. 20%. C. 77,56%. D. 22,44%.
Cu 50: Cho cc cht Al, Zn, Cr, Sn, Pb, Si c bao nhiu cht tan c trong dung dch NaOH c un nng?
A. 5. B. 6. C. 3. D. 4.
Phn II. Theo chng trnh Nng cao (10 cu: T cu 51 n cu 60)
Cu 51: Hp cht hu c X mch h, phn t cha mt loi nhm chc c cng thc phn t C
6
H
y
O
z
. Trong
X oxi chim 44,44% theo khi lng. X tc dng vi NaOH to mui Y v cht hu c Z. Cho Y tc dng vi
dung dch HCl to ra cht hu c Y1 l ng phn ca Z. Cng thc ca Z l
A. CH
3
COOH. B.CH
3
CHO
C.HO CH
2
CHO. D.HO CH
2
CH
2
CHO.
Cu 52: Trong cc cht sau: SO
2
, C
2
H
4
, FeSO
4
, Cl
2
, FeCl
2
, HCl c bao nhiu cht c phn ng vi dung dch nc
brom?
A. 5. B. 3. C. 2. D. 4.
Cu 53: Hp cht kh tham gia th H ca vng benzen hn so vi benzen v s th u tin v tr ortho v
para so vi nhm c sn l
A.C
6
H
5
COOH. B.C
6
H
5
OH. C.C
6
H
5
Cl. D. C
6
H
5
CH
3
.
Cu 54: Cho hp cht hu c X c cng thc:
H
2
N CH(CH
3
) CO NH CH
2
CO NHCH
2
CH
2
CO NH CH(C
6
H
5
) CO NH
CH(CH
3
) COOH. Khng nh ng l
A. Trong X c 4 lin kt peptit.
B. Khi thy phn X thu c 4 loi -amino axit khc nhau.
C. X l mt pentapeptit.
D. Trong X c 2 lin kt peptit.
Cu 55: Nhn xt no sau y khng ng v nc?
A.H
2
O l cht lng tnh. B.H
2
O lc c tnh oxi ha, lc c tnh kh.
C.H
2
O l phn t dung mi lng cc D. Phn t H
2
O c cu trc chp tam gic.
Cu 56: Thm vi git dung dch KSCN (khng mu) vo dung dch X cha cc ion Fe
3+
, Na
+
, Fe
2+
, 3Al
3+
,
Cl
v SO
4
2
th c hin tng?
A. To dung dch mu xanh lam. B. To dung dch mu mu.
C. To kt ta mu nu . D. To kt ta mu trng xanh.
Cu 57: Cho 27,6 gam axit salixylic (axit o-hiroxibenzoic) tc dng ht vi anhirit axetic, th khi lng este
thu c l
A. 30,4 gam. B. 32 gam. C. 48 gam. D. 36 gam.
Cu 58: X l hp cht hu c tp chc thm c cng thc phn t C
7
H
6
O
2
. Khi cho 0,1 mol X tc dng vi
Cu(OH)
2
va , trong mi trng dung dch NaOH d th khi lng sn phm hu c thu c l
Cu 59: Ha tan hon ton 40 gam hn hp gm FeS
2
, CuS, FeS bng dung dch HNO
3
th thu c dung dch
X ch cha hai mui v 4 mol NO
2
, khng c kt ta to ra. Cho dung dch NH
3
d vo dung dch X, lc ly kt
ta em nung n khi lng khng i th thu c bao nhiu gam cht rn?
A. 32,0. B. 21,4. C. 24,0. D. 16,0.
Cu 60: Nung mt lng mui sunfua ca mt kim loi ha tr khng i trong bnh cha oxi d th thot ra
5,6 lt kh X (ktc) v cht rn Y. Cht rn Y c nung vi bt than d to ra 41,4 gam kim loi. Nu cho ton
b kh X i chm qua bt Cu d nung nng th th tch kh gim i 20%. Cng thc ca mui sunfua l
A. PbS. B.Cu
2
S. C. ZnS. D. FeS.

P N
1.D 2.D 3.B 4.C 5.D 6.A 7.A 8.C 9.D 10.C
11.C 12.A 13.C 14.D 15.B 16.D 17.C 18.B 19.A 20.D
21.A 22.D 23.B 24.C 25.A 26.C 27.B 28.A 29.B 30.A
31.C 32.D 33.D 34.B 35.A 36.B 37.B 38.B 39.A 40.C
41.C 42.A 43.D 44.B 45.D 46.C 47.C 48.B 49.C 50.A
51.C 52.A 53.C 54.D 55.C 56.B 57.D 58.B 59.D 60.A

34 | L O V E B O O K . V N
s 4

I. Phn chung cho tt c cc th sinh (40 cu, t cu 1 n cu 40)
Cu 1: Hn hp A gm X, Y (MX< MY) l 2 este n chc c chung gc axit. un nng m gam A vi 400 ml dung
dch KOH 1M d thu c dung dch B v (m 12,6) gam hn hp hi gm 2 anehit no, n chc ng ng k
tip c t khi hi so vi H2 l 26,2. C cn dung dch B thu c (m + 6,68) gam cht rn khan. % khi lng ca
X trong A l:
A. 54,66% B. 45,55% C. 36,44% D. 30,37%
Cu 2: Cho 240 ml dung dch KOH 1,5M vo V lt dung dch AlCl3 aM thu c 7,8 gam kt ta. Nu cho 100 ml
dung dch KOH 1,5M vo V lt dung dch AlCl3 aM th s gam kt ta thu c l:
A. 5,85 gam B. 3,9 gam C. 2,6 gam D. 7,8 gam
Cu 3: Cho cc cht: CH3COOH (1); CH3-CH2-CH2OH (2); C2H5OH (3); C2H5COOH (4); CH3COCH3 (5). Th t cc
cht theo chiu tng dn nhit si l:
A. 5, 3, 2, 1, 4 B. 4, 1, 2, 3, 5 C. 5, 3, 2, 4, 1 D. 1, 4, 2, 3, 5
Cu 4: Cho 8,04 gam hn hp hi gm CH3CHO v C2H2 tc dng hon ton vi dung dch AgNO3/NH3 thu
c 55,2 gam kt ta. Cho kt ta ny vo dung dch HCl d, sau khi kt thc phn ng cn li m gam cht
khng tan. Gi tr ca m l:
Cu 5: Cho 3,84 gam Mg tc dng vi dung dch HNO3 d thu c 1,344 lt NO (ktc) v dung dch X. Khi
lng mui khan thu c khi lm bay hi dung dch X l:
Cu 6: X phng ha 265,2 kg cht bo c ch s axit bng 7 cn 56,84 kg dung dch NaOH 15%. Khi lng
glixerol thu c l (gi s phn ng xy ra hon ton v ch s axit l s mg KOH dng trung ha ht lng
axit t do c trong 1 gam cht bo):
A. 5,98 kg B. 4,62 kg C. 5,52 kg D. 4,6 kg
Cu 7: Tnh cht no sau y khng bin i tun hon theo chiu tng ca in tch ht nhn ca cc nguyn
t trong bng tun hon:
A. Nguyn t khi B. m in C. Nng lng ion ha D. Bn knh nguyn t
Cu 8: Trong qu trnh sn xut Ag t qung Ag2S bng phng php thy luyn ngi ta dng cc ha cht:
A. Dung dch H2SO4, Zn B. Dung dch HCl long, Mg
C. Dung dch NaCN, Zn D. Dung dch HCl c, Mg
Cu 9: Cht no sau y c cu trc mng khng gian:
A. Amilopectin B. Nha rezit C. Cao su buna-S D. Nha rezol
Cu 10: Hp cht X c cha vng benzen v c cng thc phn t l C7H6Cl2. Thy phn X trong NaOH c,
nhit cao, p sut cao thu c cht Y c cng thc C7H7O2Na. Hy cho bit X c bao nhiu cng thc cu
to:
A. 3 B. 6 C. 5 D. 4
Cu 11: Ion M
2+
c cu hnh e: [Ar]3d
8
. V tr ca M trong bng tun hon l:
A. Chu k 4, nhm VIIIB B. Chu k 3, nhm VIIIA
C. Chu k 3, nhm VIIIB D. Chu k 4, nhm VIIIA
Cu 12: Phn ng no sau y chng t glucoz c cu trc dng vng
A. tc dng vi H2/Ni, t
0
B. tc dng vi AgNO3/NH3
C. tc dng vi CH3OH/HCl khan D. tc dng vi Cu(OH)2/OH
-
nhit thng
Cu 13: Ha tan 17 gam hn hp X gm K v Na vo nc c dung dch Y v 6,72 lt H2 (ktc). trung ha
mt na dung dch Y cn dng dung dch hn hp H2SO4 v HCl (t l mol 1:2). Tng khi lng mui c to
ra l:
Cu 14: C 4 gi bt trng: Glucoz, tinh bt, xenluloz, saccaroz. C th chn nhm thuc th no di y
phn bit c c 4 cht trn:
A. H2O, dd AgNO3/NH3, dd HCl B. H2O, dd AgNO3/NH3, dd I2
C. H2O, dd AgNO3/NH3, dd NaOH D. H2O, O2 ( t chy), dd AgNO3/NH3
Cu 15: Hn hp X gm Al, Fe2O3 c khi lng 21,67 gam. Tin hnh phn ng nhit nhm hn hp X trong
iu kin khng c khng kh. Ha tan hon ton hn hp cht rn sau phn ng bng dung dch NaOH d thu
c 2,016 lt H2 (ktc) v 12,4 gam cht rn khng tan. Hiu sut ca phn ng nhit nhm l:
A. 80% B. 75% C. 60% D. 71,43%
Cu 16: Trong mt bnh kn dung tch 2 lt, ngi ta cho vo 9,8 gam CO v 12,6 gam hi nc. C phn ng
xy ra: CO + H2O CO2 + H2 850
0
C, hng s cn bng ca phn ng l K = 1. Nng H2 khi t n trng
thi cn bng l:
A. 0,22M B. 0,12M C. 0,14M D. 0,75M
Cu 17: t chy hon ton 0,1 mol ancol no A cn 15,68 lt O2 (ktc) bit t khi hi ca A so vi H2 bng 52.
Ly 4,16 gam A cho tc dng vi CuO nung nng d sau phn ng thy khi lng cht rn gim 0,64 gam v
thu c cht hu c B khng c kh nng trng bc. Vy A l:
A. 2-metylbutan-1,4-iol B. Pentan-2,3-iol C. 2-metylbutan-2,3-iol D. 3-metylbutan-1,3-iol
Cu 18: Mt mui X c cng thc phn t l C3H10O3N2. Ly 19,52 gam X cho phn ng vi 200 ml dung dch
KOH 1M. C cn dung dch sau phn ng thu c cht rn v phn hi. Trong phn hi c cht hu c Y n
chc bc I v phn rn ch l hn hp cc cht v c c khi lng m gam. Gi tr ca m l:
Cu 19: Ha tan ht 6,08 gam hn hp gm Cu, Fe bng dung dch HNO3 thu c dung dch X v 1,792 lt NO
(ktc). Thm t t 2,88 gam bt Mg vo dung dch X n khi phn ng xy ra hon ton thu c 0,448 lt NO
(ktc), dung dch Y v m gam cht rn khng tan. Gi tr ca m l :
Cu 20: Ha tan ht 10,24 gam Cu bng 200 ml dung dch HNO3 3M c dung dch A. Thm 400 ml dung dch
NaOH 1M vo dung dch A. Lc b kt ta, c cn dung dch ri nung cht rn n khi lng khng i thu
c 26,44 gam cht rn. S mol HNO3 phn ng vi Cu l:
A. 0,48 mol B. 0,58 mol C. 0,56 mol D. 0,4 mol
Cu 21: Cho dung dch Ba(HCO3)2 ln lt tc dng vi cc dung dch sau: NaOH, NaHSO4, HCl, KHCO3, K2CO3,
H2SO4. S trng hp xy ra phn ng v s trng hp c kt ta l:
A. 4 v 4 B. 6 v 5 C. 5 v 2 D. 5 v 4
Cu 22: Cho m gam Ba tc dng vi H2O d sau phn ng thu c 500 ml dung dch c pH = 13. Gi tr ca
m l:
Cu 23: t chy hon ton m gam FeS2 bng mt lng O2 va thu c kh X. Hp th ht X vo 1 lt dung
dch cha Ba(OH)2 0,2M v KOH 0,2M thu c dung dch Y v 32,55 gam kt ta. Cho dung dch NaOH vo
dung dch Y li thy xut hin thm kt ta. Gi tr ca m l:
A. 24 gam B. 27 gam C. 30 gam D. 36 gam
Cu 24: C 4 dung dch, mi dung dch cha 1 trong 4 cht: CH4O, CH5N, CH2O, CH2O2. Dng cht no nhn bit
chng:
A. Giy qu, dd AgNO3 /NH3 B. Giy qu, dd FeCl3
C. Giy qu, dd AgNO3 /NH3, Na D. Giy qu, dd AgNO3 /NH3, Br2
Cu 25: Cho cc cht: H2N-CH2-COOH; HOOC-CH2-CH2-CH(NH2)-COOH; H2NCH2COOC2H5; CH3COONH4;
C2H5NH3NO3. S cht lng tnh l:
A. 4 B. 3 C. 5 D. 2
Cu 26: H2O2 th hin tnh kh khi tc dng vi cht no sau y:
A. Ag2O B. PbS C. KI D. KNO2
Cu 27: Cho 8,4 gam Fe tc dng va vi dung dch cha 0,4 mol H2SO4 c, nng (gi thit SO2 l sn phm
kh duy nht). Sau khi phn ng xy ra hon ton c cn dung dch c m gam mui khan. Gi tr ca m l:
A. 35,2 gam B. 22,8 gam C. 27,6 gam D. 30 gam
Cu 28: Cho 0,5 mol H2 v 0,15 mol vinyl axetilen vo bnh kn c mt xc tc Ni ri nung nng. Sau phn ng thu c
hn hp kh X c t khi so vi CO2 bng 0,5. Cho hn hp X tc dng vi dung dch Br2 d thy c m gam Br2 tham
gia phn ng. Gi tr ca m l:
Cu 29: Cho s : But 1 in
+HCl
X
1
+HCl
X
2
+NaOH
X
3
th X3 l:
36 | L O V E B O O K . V N
A. CH3CO-C2H5 B. C2H5CH2CHO C. C2H5CO-COH D. C2H5CH(OH)CH2OH
Cu 30: Cho cc hirocacbon sau y phn ng vi clo theo t l 1:1 v s mol, trng hp no to thnh nhiu sn
phm ng phn nht:
A. neopentan B. Pentan C. etylxiclopentan D. Isopentan
Cu 31: Cho hi nc i qua than nung nng sau khi loi b hi nc d thu c 17,92 lt (ktc) hn hp
kh X gm CO2, CO v H2. Hp th X vo dung dch Ba(OH)2 d thu c 39,4 gam kt ta v c V lt kh Y thot
ra. Cho Y tc dng vi CuO d nung nng sau phn ng thy khi lng cht rn gim m gam. Gi tr ca m l:
Cu 32: Kh mt este E no n chc mch h bng LiAlH4 thu c mt ancol duy nht G. t chy m gam G
cn 2,4m gam O2. t m gam E thu c tng khi lng CO2 v H2O l 52,08 gam. Nu cho ton b lng CO2,
H2O ny vo 500 ml dung dch Ba(OH)2 1M. Khi lng kt ta sinh ra l:
Cu 33: Dung dch X c cha KCl, FeCl3, HCl. in phn dung dch X mt thi gian thu c dung dch Y. Y khng
lm i mu qu tm chng t qu trnh in phn dng li khi:
A. va ht FeCl3 B. va ht FeCl2 C. va ht HCl D. in phn ht KCl
Cu 34: Ch dng mt thuc th no sau y phn bit cc dung dch ng trong cc l mt nhn: anbumin,
glucoz, saccaroz, axit axetic.
A. dung dch NH3 B. Cu(OH)2 C. CuSO4 D. HNO3 c
Cu 35: Nhn nh no sau y khng ng:
A. Hn hp Fe3O4 v Cu c th tan ht trong dung dch HCl
B. Hn hp Al2O3 v K2O c th tan ht trong nc
C. Hn hp CuS v FeS c th tan ht trong dung dch HCl
D. Hn hp Al v BaO c th tan ht trong nc
Cu 36: X l mt -amino axit c cha vng thm v mt nhm NH2 trong phn t. Bit 50 ml dung dch X phn ng
va vi 80 ml dung dch HCl 0,5M, dung dch thu c phn ng va vi 50 ml dung dch NaOH 1,6M. Mt khc
nu trung ha 250 ml dung dch X bng lng va KOH ri em c cn thu c 40,6 gam mui. Cng thc cu to
ca X l:
A. C6H5-CH(CH3)-CH(NH2)COOH B. C6H5-CH(NH2)-CH2COOH
C. C6H5-CH(NH2)-COOH D. C6H5-CH2CH(NH2)COOH
Cu 37: Trong cng nghip ngi ta iu ch nc giaven bng cch:
A. Cho kh Cl2 i t t qua dung dch NaOH, Na2CO3 C. Sc kh Cl2 vo dung dch KOH
B. in phn dung dch NaCl khng mng ngn D. Cho kh Cl2 vo dung dch Na2CO3
Cu 38: T no sau y c ch to t polime trng hp:
A. T e nang B. T capron C. T lapsan D. T nilon-6,6
Cu 39: Lc 13,14 gam Cu vi 250 ml dung dch AgNO3 0,6M mt thi gian thu c 22,56 gam cht rn A v
dung dch B. Nhng thanh kim loi M nng 15,45 gam vo dung dch B khuy u n khi phn ng hon ton
thu c dung dch ch cha mt mui duy nht v 17,355 gam cht rn Z. Kim loi M l:
A. Zn B. Mg C. Pb D. Fe
Na2SO3 + H2SO4 Kh X FeS + HCl Kh Y
NaNO2 bo ha + NH4Clbo ha
t
0

Kh Z KMnO4

0

Kh T
Cc kh tc dng c vi nc clo l:
A. X, Y, Z, T B. X, Y, Z C. Y, Z D. X, Y
II. Phn ring (10 cu) Th sinh c chn lm 1 trong 2 phn (phn I hoc phn II)
Phn I: Theo chng trnh Chun (t cu 41 n cu 50)
Cu 41: Nung m gam K2Cr2O7 vi S d thu c hn hp cht rn X. Ha tan hon ton X vo nc, lc b
phn khng tan ri thm BaCl2 d vo dung dch thu c 18,64 gam kt ta. Gi tr ca m l:
Cu 42: Phn ng no sau y thu c kt ta sau phn ng:
A. Cho kh H2S vo dung dch FeCl2.
C. Cho t t n d dung dch HCl v dung dch Na[Cr(OH)4]
B. Cho dung dch NaOH c, d vo dung dch Pb(NO3)2.
D. Sc kh H2S vo dung dch Pb(NO3)2.
Cu 43: Cho cn bng: H2 (K) + I2 (K) 2HI (K) H > 0.
Yu t no sau y khng lm chuyn dch cn bng:
A. p sut B. Nng I2 C. Nhit D. Nng H2
Cu 44: Cho 4,44 gam axit cacboxylic, n chc X tc dng hon ton vi 500 ml gm: KOH 0,12M, NaOH
0,12M. C cn dung dch thu c 9,12 gam hn hp cht rn khan. Cng thc phn t ca X l:
A. CH3CHO. B. HCOOH C. C3H7COOH D. C2H5COOH
Cu 45: Mu xanh ca dung dch keo X mt i khi un nng v tr li nh ban u khi ngui. Vy X l:
A. dd (CH3COO)2Cu B. dd I2 trong tinh bt C. dd ng (II) glixerat D. dd I2 trong xenluloz
Cu 46: Cho m gam ancol n chc X qua ng ng CuO d nung nng. Sau khi phn ng xy ra hon ton ngoi cht
rn thu c hn hp hi gm 2 cht c t khi so vi H2 l 19. Ancol X l:
A. C3H5OH B. CH3OH C. C2H5OH D. C3H7OH
Cu 47: kh mi tanh ca c (gy ra do mt s amin) ta c th ra c vi:
A. Nc B. Nc vi trong C. Cn D. Gim
Cu 48: X l mt tetrapeptit cu to t mt amino axit (A) no, mch h c 1 nhm COOH; 1 nhm NH
2
. Trong A
%N = 15,73% (v khi lng). Thy phn m gam X trong mi trng axit thu c 41,58 gam tripeptit; 25,6 gam
ipeptit v 92,56 gam A. Gi tr ca m l:
A. 149 gam B. 161 gam C. 143,45 gam D. 159 gam
: Trong pin in ha Cu Ag ti in cc ng xy ra qu trnh:
A. Oxi ha H2O B. Kh Cu
2+
C. Kh H2O D. Oxi ha Cu
Cu 50: Cho s phn ng:
C4H10O
H
2
O
X
Br
2
(dd)
Y
+NaOH;t
0

Z
CuO;t
0

2 hiroxi 2 metyl propan. X l:
A. Isobutilen B. But-2-en C. But-1- en D. xiclobutan
Phn II: Theo chng trnh nng cao (t cu 51 n cu 60)
Cu 51: Khi bn m ure cho cy ngi ta khng bn cng vi
A. NH4NO3 B. phn kali C. phn ln D. vi
Cu 52: Cn a mol K2Cr2O7 v b mol HCl iu ch c 6,72 lt Cl2 (ktc). Gi tr ca a v b l::
A. 0,05 v 0,7 B. 0,2 v 2,8 C. 0,1 v 1,4 D. 0,1 v 0,35
Cu 53: Cho th in cc ca cc cp oxi ha kh: E
Zn
2+
/Zn
0
= 0,76V, E
Fe
2+
/Fe
0
= 0,44V, E
Pb
2+
/Pb
0
=
0,13V, E
Ag
+
/Ag
0
= 0,8V. Pin in ha no sau y c sut in ng tiu chun ln nht ?
A. Zn Fe B. Zn - Pb C. Pb - Ag D. Fe - Ag
Cu 54: Cho kh CO i qua ng s ng 0,09 mol hn hp A gm Fe2O3 v FeO nung nng sau mt thi gian
thu c 10,32 gam cht rn B. Dn kh i ra khi ng s vo dung dch Ba(OH)2 d thu c 17,73 gam kt
ta. Cho B tc dng ht vi dung dch HNO3 d thu c V lt NO (ktc, sn phm kh duy nht). Gi tr ca V
l:
A. 1,344 lt B. 1,68 lt C. 1,14 lt D. 1,568 lt
Cu 55: Ln men 162 gam tinh bt vi hiu sut cc qu trnh ln men ln lt l 80% v 90%. Tnh th tch
dung dch ru 40
o
thu c? Bit khi lng ring ca C2H5OH nguyn cht l 0,8 g/ml
A. 115ml B. 230ml C. 207ml D. 82,8ml
Cu 56: Vinyl axetat c iu ch bng phn ng gia:
A. Etilen vi axit axetic B. Ancol vinylic vi axit axetic
C. Axetilen vi axit axetic D. etanol vi anhirit axetic
Cu 57: t chy hon ton m gam hn hp X gm hai anehit no, n chc, mch h thu c 0,4 mol CO2.
Mt khc hiro ha hon ton m gam X cn 0,2 mol H2 (Ni, t
o
), sau phn ng thu c hai ancol no n chc.
t chy hon ton hn hp hai ancol ny th s mol H2O thu c l:
Cu 58: Cho cc cht: Propan, Propin, 2,2-iclopropan, Propan-2-ol, Propan-1-ol, Propen, anlyl clorua, 2-
clopropen. S cht c th iu ch c axeton ch bng mt phn ng l:
A. 3 B. 6 C. 5 D. 4
38 | L O V E B O O K . V N
(1) Cl2 + Br2 + H2O
(2) Cl2 + KOH
t
0

(3) H2O2
MnO
2

(4) Cl2 + Ca(OH)2 khan
(5) Br2 + SO2 + H2O
S phn ng l phn ng t oxi ha kh l:
A. 4 B. 3 C. 2 D. 5
Cu 60: Cho 0,1 mol alanin phn ng vi 100 ml dung dch HCl 1,5M thu c dung dch A. Cho A tc dng
va vi dung dch NaOH thu c dung dch B, lm bay hi dung dch B thu c bao nhiu gam cht rn
khan?

P N

1.C 2.B 3.A 4.C 5.B 6.A 7.A 8.C 9.B 10.A
11.A 12.C 13.A 14.B 15.B 16.B 17.B 18.A 19.D 20.C
21.D 22.C 23.B 24.A 25.B 26.A 27.C 28.D 29.A 30.C
31.A 32.B 33.B 34.B 35.C 36.D 37.B 38.B 39.A 40.D
41.A 42.D 43.A 44.D 45.B 46.D 47.D 48.C 49.D 50.A
51.D 52.C 53.D 54.D 55.C 56.C 57.A 58.B 59.B 60.A

s 5

Cu 1: Hirocacbon X c cng thc phn t C6H10. X tc dng vi dung dch AgNO3/NH3 to ra kt ta vng.
Khi hiro ha hon ton X thu c neo-hexan. X l:
A. 2,2-imetylbut-3-in B. 2,2-imetylbut-2-in C. 3,3-imetylbut-1-in D. 3,3-imetylpent-1-in
Cu 2: X l hp cht thm c cng thc phn t C7H8O khi cho X tc dng vi nc Br2 to ra sn phm Y c
cha 69,565% Br v khi lng. X l:
A. o-crezol B. m-crezol C. Ancol benzylic D. p-crezol
Cu 3: Thy phn 95,76g mantoz trong mi trng axit vi hiu sut phn ng t 75% thu c hn hp
X. Trung ha hn hp X bng NaOH thu c hn hp Y. Cho Y tc dng vi dung dch AgNO3/NH3 d un
nng thu c m gam Ag kt ta. Gi tr ca m l:
: Cho m gam hn hp X gm axit glutamic v alanin tc dng vi dung dch HCl d. Sau phn ng lm bay hi
cn thn dung dch thu c (m + 11,68)gam mui khan. Nu cho m gam hn hp X tc dng vi dung dch KOH
va , sau phn ng lm bay hi cn thn dung dch thu c (m + 19) gam mui khan. Gi tr ca m l:
Cu 5: Tng s ht c bn trong nguyn t ca nguyn t M, X ln lt l 58 v 52. Hp cht MXn c tng s
ht proton trong mt phn t l 36. Lin kt trong phn t MXn thuc loi lin kt:
A. Cho nhn B. Cng ha tr phn cc C. Ion D. Cng ha tr khng
phn cc
Cu 6: Cht no sau y khng c kh nng lm mt mu dung dch thuc tm:
A. HCl B. SO3 C. H2S D. SO2
Cu 7: t chy hon ton 5,4g mt amin X n chc trong lng va khng kh. Dn sn phm kh qua bnh
ng nc vi trong d thu c 24g kt ta v c 41,664 lt (ktc) mt cht kh duy nht thot ra. X tc dng
vi HNO2 to ra kh N2. X l:
A. imetylamin B. anilin C. etylamin D. metylamin
Cu 8: in phn 200 ml dung dch hn hp gm HCl 0,2M v CuSO4 1M bng in cc tr. Khi catot c 6,4 gam
Cu th th tch kh thot ra anot l:
A. 0,672 lt B. 1,344 lt C. 1,12 lt D. 0,896 lt
Cu 9: Hn hp X gm Al, FexOy. Tin hnh phn ng nhit nhm hon ton m gam hn hp X trong iu kin
khng c khng kh thu c hn hp Y. Chia Y thnh 2 phn.
Phn 1 cho tc dng vi dung dch NaOH d thu c 1,008 lt H2 (ktc) v cn li 5,04g cht rn khng tan.
Phn 2 c khi lng 29,79gam, cho tc dng vi dung dch HNO3 long d thu c 8,064 lt NO (ktc, l sn
phm kh duy nht). Gi tr ca m v cng thc ca oxit st l:
A. 39,72 gam v FeO B. 39,72 gam v Fe3O4 C. 38,91 gam v FeO D. 36,48 gam v Fe3O4
Cu 10: Cho 6,8g mt hp cht hu c n chc tc dng va vi dung dch cha 0,3 mol AgNO3/NH3 thu
c 21,6g Ag. X l:
A. 2-metylbut-3-inal B. But-1-inal C. but-2-inal D. But - 3- inal
Cu 11: Trn cc dung dch HCl 0,75M; HNO3 0,15M; H2SO4 0,3M vi cc th tch bng nhau th c dung
dch X. Trn 300 ml dung dch X vi 200 ml dung dch Ba(OH)2 0,25M thu c m gam kt ta v dung dch Y
c pH = x. Gi tr ca x v m ln lt l:
A. 1 v 2,23 gam B. 1 v 6,99 gam C. 2 v 2,23 gam D. 2 v 1,165 gam
Cu 12: C 6 ng nghim ng 6 dung dch long FeCl3, NH4Cl, Cu(NO3)2, FeSO4, AlCl3, (NH4)2CO3. Ch dng
mt ha cht no sau y nhn bit c c 6 dung dch trn:
A. Qu tm B. Dung dch AgNO3 C. Dung dch BaCl2 D. dung dch NaOH
Cu 13: Ha tan ht m gam Al trong dung dch hn hp NaOH, NaNO3 thu c 6,048 lt (ktc) hn hp kh
gm NH3 v H2 c t l mol tng ng l 4:5. Gi tr ca m l:
40 | L O V E B O O K . V N
Cu 14: Dung dch X c cha H
+
, Fe
3+
, SO
4
2
dung dch Y cha Ba
2+
, OH
-
, S
2-
. Trn X vi Y c th xy ra bao nhiu
phn ng ha hc?
A. 7 B. 5 C. 8 D. 6
Cu 15: Tin hnh cc th nghim sau y, trng hp no sau y s to ra kt ta khi kt thc th nghim?
A. Cho dung dch Ba(OH)2 d vo dung dch Na[Al(OH)4].
B. Cho Al vo dung dch NaOH d
C. Cho dung dch AlCl3 d vo dung dch Na[Al(OH)4].
D. Cho CaC2 tc dng vi nc d c dung dch A v kh B. t chy hon ton B ri hp thu ton b sn
phm chy vo dung dch A.
Cu 16: Hp cht hu c X c cng thc phn t C4H8O2 mch thng tha mn cc tnh cht sau:
- X lm mt mu dung dch Br2.
- 4,4 gam X tc dng vi Na d thu c 0,56 lt H2 (ktc).
- Oxi ha X bi CuO, t
0
to ra sn phm Y l hp cht a chc. Cng thc cu to ca X l:
A. CH3-CH2-CO-CHO B. CH2=CH-CH(OH)-CH2OH
C. HO-(CH2)3-CH=O D. HO-CH2-CH(CH3)-CHO
Cu 17: Axit no trong s cc axit sau c tnh axit mnh nht:
A. CH2F-CH2-COOH B. CH3-CF2-COOH C. CH3CHF-COOH D. CH3-CCl2-COOH
Cu 18: phn bit O3 v O2 khng th dng ha cht no sau y:
A. Cacbon B. Ag C. PbS D. Dung dch KI
Cu 19: un nng hn hp gm etanol v butan-2-ol vi H2SO4 c th thu c ti a bao nhiu sn phm
hu c?
A. 5 B. 7 C. 8 D. 6
Cu 20: Dy cht no sau y gm cc cht ch c tnh oxi ha?
A. Cl2, H2O2, HNO3, H2SO4. B. SO2, SO3, Br2, H2SO4.
C. Fe(NO3)3, CuO, HCl, HNO3 D. O3, Fe2O3, H2SO4, O2
Cu 21: ha tan mt mu Zn trong dung dch HCl 25
0
C cn 243 pht. Cng mu Zn tan ht trong dung dch
HCl nh trn 65
0
C cn 3 pht. ha tan ht mu Zn trong dung dch HCl c nng nh trn 45
0
C cn thi
gian bao lu:
A. 9 pht B. 81 pht C. 27 pht D. 18 pht
Cu 22: Hn hp X gm 2 este n chc. Cho 0,5 mol X tc dng vi dung dch AgNO3/NH3 d thu c 43,2g
Ag. Cho 14,08g X tc dng vi dung dch KOH va thu c hn hp 2 mui ca 2 axit ng ng lin tip
v 8,256g hn hp 2 ancol no n chc ng ng lin tip, mch h. Cng thc ca 2 ancol l:
A. C4H9OH v C5H11OH B. CH3OH v C2H5OH C. C2H5OH v C3H7OH D. C3H7OH v C4H9OH
Cu 23: Hp cht hu c X c cng thc phn t l C4H6O4. Thy phn X trong mi trng NaOH un nng
to ra mt mui Y v mt ancol Z. t chy Y th sn phm to ra khng c nc. X l:
A. HCOOCH2CH2OOCH. B. HOOCCH2COOCH3. C. HOOC-COOC2H5. D. CH3OOC-COOCH3.
Cu 24: Cho s : C2H4
Br
2

X
+KOH/C
2
H
5
OH;t
0

Y
+AgNO
3
/NH
3

Z
+HBr
Y. Y l
A. C2H6. B. C2H2. C. C2H5OH. D. C2H4.
Cu 25: Kh Cl2 tc dng c vi: (1) kh H2S; (2) dung dch FeCl2; (3) nc Brom; (4) dung dch FeCl3; (5)
dung dch KOH.
A. 1, 2, 4, 5 B. 1, 2, 3, 4, 5 C. 1, 2, 5 D. 1, 2, 3, 5
Cu 26: Cho cc dung dch: FeCl3 (1); NaHSO4 (2); NaHCO3 (3); K2S (4); NH4Cl (5); AlCl3 (6); CH3COONa (7).
Cc dung dch c pH < 7 l:
A. 1, 2, 5, 6 B. 1, 2, 6 C. 1, 2 D. 1, 2, 3, 5, 6
: Hn hp A gm C
3
H
4
v H
2
. Cho A i qua ng ng bt Ni nung nng thu c hn hp B ch gm 3 hirocacbon
c t khi so vi H
2
l 21,5. T khi ca A so vi H
2
l:
A. 10,4 B. 9,2 C. 7,2 D. 8,6
Cu 28: Trn dung dch cha Ba
2+
; Na
+
: 0,04 mol; OH
-
: 0,2 mol; vi dung dch cha K
+
; HCO
3
: 0,06 mol; CO
3
2
:
0,05 mol thu c m gam kt ta. Gi tr ca m l:
Cu 29: Ha tan 54,44 gam hn hp X gm PCl3 v PBr3 vo nc c dung dch Y. trung ha hon ton
dung dch Y cn 500 ml dung dch KOH 2,6M. % khi lng ca PCl3 trong X l:
A. 26,96% B. 12,125 C. 8,08% D. 30,31%
Cu 30: X l tetrapeptit c cng thc Gly Ala Val Gly. Y l tripeptit c cng thc Gly Val Ala. un m gam hn
hp A gm X, Y c t l mol tng ng l 4:3 vi dung dch KOH va sau khi phn ng xy ra hon ton c cn
dung dch thu c 257,36g cht rn khan. Gi tr ca m l:
Cu 31: Nhit phn 50,56 gam KMnO4 sau mt thi gian thu c 46,72 gam cht rn. Cho ton b lng kh
sinh ra phn ng ht vi hn hp X gm Mg, Fe thu c hn hp Y nng 13,04 gam. Ha tan hon ton hn
hp Y trong dung dch H2SO4 c, nng d thu c 1,344 lt SO2 (ktc). % khi lng Mg trong X l:
A. 52,17% B. 39,13% C. 28,15% D. 46,15%
Cu 32: Hn hp X gm 1 ankan v 1 anken. Cho X tc dng vi 4,704 lt H
2
(ktc) cho n phn ng hon ton thu c
hn hp Y gm 2 kh trong c H2 d v 1 hirocacbon. t chy hon ton Y ri cho sn phm vo nc vi trong d
thy khi lng bnh ng nc vi trong tng 16,2 gam v c 18 gam kt ta to thnh. Cng thc ca 2 hirocacbon
l:
A. C2H6 v C2H4 B. C2H8 v C3H6 C. C4H10 v C4H8 D. C5H10 v C5H12
Cu 33: Trng hp no sau y khng tha mn quy tc bt t:
A. NH3, HCl B. CO2, SO2 C. PCl5, SF6 D. N2, CO
Cu 34: Mt ancol no, a chc X c s nhm OH bng s nguyn t cacbon. Trong X, H chim xp x 10% v
khi lng. un nng X vi cht xc tc nhit thch hp loi nc th thu c mt cht hu c Y c
MY = MX 18. Kt lun no sau y hp l nht:
A. T khi hi ca Y so vi X l 0,8 B. X l glixerol
C. Y l anehit acrylic D. Y l etanal
Cu 35: Mt hn hp kim loi gm: Zn, Ag, Fe, Cu. Ha cht c th ha tan hon ton hn hp kim loi trn l:
A. Dung dch NaOH c B. Dung dch HCl c, d
C. Dung dch HNO3 long, d D. Dung dch H2SO4 c, ngui, d
Cu 36: Cho cc phn ng ha hc:
(1) C2H5OH + H2SO4 c C2H5OSO3H + H2O (4) C2H5Br + NaOH
t
0

C2H5OH + NaBr
(2) C2H5OH
H
2
SO
4
,170
C2H4 + H2O (5) C2H4 + H2O
H
+

C2H5OH
(3) C2H5OH + CH3COOH CH3COOC2H5 + H2O
Cc phn ng th l:
A. 1, 4 B. 1, 4, 5 C. 1, 3, 4 D. 4
Cu 37: Cho 200 ml dung dch KOH 0,9M; Ba(OH)2 0,2M vo 100 ml dung dch H2SO4 0,3M v Al2(SO4)3 0,3M.
Sau khi cc phn ng xy ra hon ton, khi lng kt ta thu c l:
A. 9,32 gam B. 10,88 gam C. 14 gam D. 12,44 gam
Cu 38: Phn ng no sau y mch polime c gi nguyn?
A. PVA + NaOH
t
0

B. Xenluloz + H2O
H
+
, t
0

C. PS
t
0

D. Nha Rezol
t
0

Cu 39: t chy hon ton 18 gam mt este X n chc thu c 20,16 lt CO2 (ktc) v 12,96 gam nc.
Mt khc nu cho 21g X tc dng vi 200ml dung dch KOH 1,2M sau c cn dung dch thu c 34,44 gam
cht rn khan. Cng thc phn ca axit to ra X l :
A. C5H6O3. B. C5H8O3. C. C5H10O3 D. C5H10O2.
Cu 40: Ha tan hon ton hn hp gm 0,18 mol FeS2 v a mol Cu2S bng dung dch HNO3 va thu c
dung dch X ch cha mui sunfat v V lt NO (ktc) l sn phm kh duy nht. Gi tr ca V l:
A. 44,8 lt B. 22,4 lt C. 26,88 lt D. 33,6 lt
42 | L O V E B O O K . V N
: Khi in phn dung dch no sau y ti catot xy ra qu trnh kh nc?
A. Dung dch ZnCl2. B. Dung dch CuCl2 C. dung dch AgNO3. D. Dung dch MgCl2.
Cu 42: phn bit SO2, CO2 v SO3 c th dng:
A. Dung dch BaCl2 v dung dch Br2 B. Dung dch Ba(OH)2, dung dch thuc tm
C. Dung dch Br2, nc vi trong. D. Dung dch BaCl2 v nc vi trong
Cu 43: Pb tan d dng trong dung dch no sau y?
A. Dung dch H2SO4 m c B. Dung dch HNO3 c C. Dung dch HCl long
D. Dung dch H2SO4 long
Cu 44: Dung dch X cha cc ion : Ba
2+
, Na
+
, HCO
3
, Cl
trong s mol Cl
l 0,24. Cho dung dch X tc

dng vi dung dch NaOH d thu c 9,85g kt ta. Cho dung dch X tc dng vi dung dch Ba(OH)2 d
thu c 15,76g kt ta. Nu un si dung dch X n cn th thu c m gam cht rn khan. Gi tr ca m l :
A. 15,81 B. 18,29. C. 31,62 D. 36,58
: Cht c dng ty trng nc ng trong qu trnh sn ng saccaroz t cy ma l:
A. nc gia-ven B. SO2. C. Cl2. D. CaOCl2.
: t chy hon ton 0,12 mol mt amin no, mch h X bng oxi va thu c 0,6 mol hn hp kh v hi. Cho
9,2 gam X tc dng vi dung dch HCl d th s mol HCl phn ng l:
A. 0,4 B. 0,3 C. 0,1 D. 0,2
Cu 47:Hn hp M gm 2 axit cacboxylic u no, mch h A, B (B hn A mt nhm chc). Ha hi hon ton m
gam M thu c th tch hi bng th tch ca 7 gam nit o cng iu kin nhit , p sut. Nu cho m gam M tc
dng vi Na d thu c 4,48 lt H2 (ktc). Khi t chy hon ton m gam M thu c 28,6g CO2. Cng thc phn
t ca A v B l:
A. C2H4O2 v C3H4O4. B. CH2O2 v C3H4O4 . C. C2H4O2 v C4H6O4 D. CH2O2 v C4H6O2.
Cu 48: Hn hp X gm Cu, Fe, Mg. Nu cho 10,88 gam X tc dng vi clo d th sau phn ng thu c 28,275g
hn hp mui khan. Mt khc 0,44 mol X tc dng vi dung dch HCl d th thu c 5,376 lt H
2
(ktc). %
m
Cu
trong X l:
A. 67,92% B. 58,82% C. 37,23% D. 43,52%
Cu 49: Oxi ha 16,8g anehit fomic bng oxi c mt Mn
2+
thu c hn hp X. Cho hn hp X tc dng vi
dung dch AgNO3/NH3 d thu c 151,2g Ag. Hiu sut ca phn ng oxi ha anehit fomic l:
A. 37,5% B. 80% C. 60% D. 75%
: Dy no sau y gm cc polime nhn to?
A. T visco, t axetat, xenluloz trinitrat B. Xenluloz, tinh bt, t tm
C. T lapsan, PVA, thy tinh hu c. D. T nilo 6,6; bng, tinh bt, t capron
Phn II: Theo chng trnh nng cao (t cu 51 n cu 60)
Cu 51: Cho 6,85 gam Ba kim loi vo 150ml dung dch CrSO4 0,3M trong khng kh n phn ng hon ton
thu c m gam kt ta. Gi tr ca m l:
A. 14,09 gam B. 10,485gam C. 3,87 gam D. 14,355 gam
Cu 52: Cho cc cht CH3 -CHCl2; ClCH=CHCl; CH2=CH-CH2Cl, CH2Br-CHBr-CH3; CH3-CHCl-CHCl-CH3; CH2Br-
CH2-CH2Br. S cht khi tc dng vi dung dch NaOH long un nng to ra sn phm c kh nng phn ng
vi Cu(OH)2 l:
A. 5 B. 4 C. 2 D. 3
Cu 53: Cho sut in ng chun ca 1 s pin in ha sau: E
0
X-Cu = 0,78V; E
0
Y-Cu = 2,0V; E
0
Cu-Z = 0,46V. Th t
cc kim loi theo chiu gim dn tnh kh l:
A. X,Y, Z, Cu B. X, Y, Cu, Z C. Y, X, Cu, Z D. Z, Cu, X, Y
Cu 54: Kh no sau y l nguyn nhn gy hiu ng nh knh?
A. NO B. CO2. C. SO2. D. CO
: Cho s : Propilen
H
2
O,H
+

A
CuO,t
0

B
HCN
D. D l:
A. CH3CH2CH2OH B. CH3C(OH)(CH3)CN C. CH3CH(OH)CH3. D. CH3CH2CH(OH)CN
Cu 56: Dung dch X cha 0,01 mol ClH3N-CH2-COOH, 0,02 mol CH3-CH(NH2)COOH; 0,05 mol HCOOC6H5. Cho
dung dch X tc dng vi 160 ml dung dch KOH 1M un nng phn ng xy ra hon ton. C cn dung dch
sau phn ng thu c m gam cht rn khan. Gi tr ca m l:
Cu 57: Cho t t n d dung dch NH3 ln lt vo cc dung dch sau: CuCl2, AlCl3, Fe(NO3)3, NiSO4, AgNO3,
MgSO4. Sau khi cc phn ng xy ra hon ton, s kt ta thu c l:
A. 2 B. 4 C. 5 D. 3
Cu 58: Dy no sau y gm cc polime c cu trc mch phn nhnh?
A. T nilon-6,6; t lapsan, t olon B. Nha rezol, cao su lu ha
C. Cao su Buna-S, xenluloz, PS D. Amilopectin, glicogen
Cu 59: Dung dch X gm NH3 0,1M; NH4Cl 0,1M. pH ca dung dch X c gi tr l: (cho Kb ca NH3 l 1,75.10
-5
)
A. 9,24 B. 4,76 C. 8,8 D. 9,42
Cu 60: Trung ha ht 10,36 gam axit hu c n chc bng dung dch Ba(OH)2 va thu c 19,81 gam
mui khan. Xc nh cng thc ca axit?
A. CH3COOH B. C2H3COOH C. C3H5COOH D. C2H5COOH

P N

1.C 2.B 3.C 4.B 5.C 6.B 7.C 8.B 9.B 10.D
11.B 12.D 13.A 14.B 15.C 16.C 17.B 18.A 19.B 20.D
21.C 22.C 23.D 24.B 25.D 26.A 27.D 28.A 29.D 30.B
31.B 32.A 33.C 34.D 35.C 36.C 37.D 38.A 39.B 40.C
41.D 42.A 43.A 44.C 45.B 46.A 47.A 48.B 49.D 50.A
51.A 52.D 53.C 54.B 55.B 56.A 57.D 58.D 59.A 60.D

44 | L O V E B O O K . V N
s 6

I. Phn chung cho tt c cc th sinh (40 cu, t cu 1 n cu 40)
Cu 1: X l 1 ancol c cng thc phn t C3H8On, X c kh nng ha tan Cu(OH)2 nhit thng. S cht c
th c ca X l:
A. 3 B. 4 C. 2 D. 1
Cu 2: t chy hon ton 1 anhit X c nCO2 - nH2O = nX. Cho 11,52 gam X phn ng vi lng d AgNO3
trong NH3 c 69,12 gam Ag. Cng thc ca X l:
A. CH2(CHO)2 . B. CH2=CH-CHO. C. CH3CHO. D. HCHO.
Cu 3: T m kg khoai c cha 25% tinh bt, bng phng php ln men ngi ta iu ch c 100 lt ru
60
0
.Gi tr ca m l: (bit khi lng ring ca C2H5OH l 0,8g/ml hiu sut chung ca c qu trnh l 90%)
A. 375,65kg B. 338,09kg C. 676,2kg. D. 93,91kg
Cu 4: Cht hu c X c cng thc phn t l C5H8O2. Cho X tc dng vi dung dch Br2 thu c cht hu c
Y c cng thc l C5H8O2Br2. un nng Y trong NaOH d thu c glixerol, NaBr v mui cacboxylat ca axit
Z. Vy cng thc cu to ca X l :
A. HCOOCH(CH3)-CH=CH2 B. CH3-COOCH=CH-CH3
C. CH2=CH-COOCH2CH3 D. CH3COOCH2-CH=CH2
: Ha tanhonton 31,25 gam hn hp X gm Mg, Al v Zn trong dung dch HNO
3
, sau phn ng hon ton thu c
dung dch Y v hn hp gm 0,1 mol N
2
O v 0,1 mol NO. C cn dung dch sau phn ng thu c 157,05 gam hn hp
mui. Vy s mol HNO
3
b kh trong phn ng trn l:
Cu 6: Cho dy cc cht: phenylaxetat, anlylaxetat, metylaxetat, etylfomat, tripanmitin, vinyl clorua. S cht
trong dy khi thy phn trong dung dch NaOH long(d), un nng sinh ra ancol l:
A. 4 B. 3 C. 5 D. 6
Cu 7: Mt - aminoaxit c cng thc phn t l C2H5NO2, khi t chy 0,1 mol oligopeptit X to nn t -
aminoaxit th thu c 12,6 gam nc.Vy X l:
A. tetrapeptit B. ipeptit C. tripeptit D. pentapeptit
Cu 8: Kh CO2 tc dng c vi: (1) nc Gia-ven; (2) dung dch K2CO3; (3) nc Brom; (4) dung dch
NaHSO3; (5) dung dch KOH, (6) dung dch NaHCO3, (7) Mg nung nng.
A. 1, 2, 5, 6 B. 2, 4, 5, 7 C. 1, 2, 5, 7 D. 2, 3, 4, 5
Cu 9: t chy hon ton 29,16 gam hn hp X gm RCOOH, C2H3COOH, v (COOH)2 thu c m gam H2O v
21,952 lt CO2 (ktc). Mt khc, 29,16 gam hn hp X phn ng hon ton vi NaHCO3 d thu c 11,2 lt
(ktc) kh CO2.Gi tr ca m l
A. 10,8 gam B. 9 gam C. 8,1gam D. 12,6 gam
Cu 10: Gi s gang cng nh thp ch l hp kim ca St vi Cacbon v St ph liu ch gm St, Cacbon v
Fe
2
O
3
. Coi phn ng xy ra trong l luyn thp Martanh l: Fe
2
O
3
+3C
t
0

2Fe +3CO . Khi lng St ph
liu (cha 40% Fe
2
O
3
, 1%C) cn dng khi luyn vi 6 tn gang 5%C trong l luyn thp Martanh, nhm
thu c loi thp 1%C, l:
A. 1,82 tn B. 2,73 tn C. 1,98 tn D. 2,93 tn
Cu 11: t chy hon ton m gam cht bo X (cha triglixerit ca axit stearic,axit panmitic v cc axit bo t
do ). Sau phn ng thu c 13,44 lt CO2 (ktc) v 10,44 gam nc. X phng ho m gam X (H=90%) th
thu c khi lng glixerol l:
Cu 12: Cho t t 300ml dung dch NaHCO3 0,1M, K2CO3 0,2M vo 100ml dung dch HCl 0,2M; NaHSO4 0,6M
thu c V lt CO2 thot ra ktc v dung dch X. Thm vo dung dch X 100ml dung dch KOH 0,6M; BaCl2
1,5M thu c m gam kt ta. Gi tr ca V v m l:
A. 0,448 lt v 11,82g B. 0,448 lt v 25,8g C. 1,0752 lt v 23,436g D. 1,0752 lt v
22,254g
Cu 13: Sc 13,44 lt CO2 (ktc) vo 200 ml dung dch X gm Ba(OH)2 1,5M v NaOH 1M . Sau phn ng thu
c m1 gam kt ta v dung dch X. Cho dung dch X tc dng vi 200ml dung dch BaCl2 1,2M; KOH 1,5M thu
c m2 gam kt ta. Gi tr ca m2 l:
Cu 14: Ho tan hon ton hn hp X (gm x mol Fe, y mol Cu, z mol Fe2O3 v t mol Fe3O4) trong dung dch
HCl khng thy kh c kh bay ra khi khi bnh, dung dch thu c ch cha 2 mui. Mi quan h gia s mol
cc cht c trong hn hp X l.
A. x+ y = 2z +2t B. x +y = z +t C. x+y =2z +3t D. x+y =2z +2t
Cu 15: Ha tan hon ton m gam hn hp gm Na, Na2O, NaOH v Na2CO3 trong dung dch axt H2SO4 40%
(va ) thu c 8,96 lt hn hp kh c t khi i vi H2 bng 16,75 v dung dch Y c nng 51,449%.
C cn Y thu c 170,4 gam mui. Gi tr ca m l:
Cu 16: Hn hp X gm hai oaminoaxit mch h no c 1 nhm COOH v 1 nhm NH2 ng ng k tip c
phn trm khi lng oxi l 37,427%. Cho m gam X tc dng vi 800ml dung dch KOH 1M (d) sau khi phn
ng kt thc c cn dung dch thu c 90,7gam cht rn khan. m c gi tr l :
Cu 17: Cho s phn ng
C6H5CH3
+Cl
2
(a.s)
A
+NaOH d,t
0

B
CuO,t
0

C
O
2
,xt
D
CH
3
OH,t
0
,xt
E . Tn gi ca E l:
A. phenyl axetat B. metyl benzoat C. axit benzoic D. phenyl metyl ete
Cu 18: Ha tan 32,52 gam photpho halogenua vo nc c dung dch X. trung ha hon ton dung dch
X cn 300 ml dung dch KOH 2M. Cng thc ca photpho halogenua l:
A. PCl5 B. PBr5 C. PBr3 D. PCl3.
Cu 19: Hp cht hu c mch h X c cng thc phn t C5H10O. Cht X khng phn ng vi Na, tho mn
s chuyn ho sau: X
+H
2
,Ni,t
0

Y
+CH
3
COOH,xt,H
2
SO
4
,t
0

Este

c mi chui chn. Tn ca X l
A. 2-metylbutanal. B. pentanal. C. 3-metylbutanal. D. 2,2-imetylpropanal
Cu 20: Cho dy cc cht: CrO3, Cr2O3, SiO2, Cr(OH)3, CrO, Zn(OH)2, NaHCO3, Al
2
O
3
. S cht trong dy tc
dng c vi dung dch NaOH (c, nng) l
A. 4. B. 7. C. 6. D. 5.
Cu 21: Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H
2
l17. t chy hon ton
0,1 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2(d) th khi lng dung
dch thay i:
A. gim 10,4 gam. B. tng 7,8 gam. C. gim 7,8 gam. D. tng 14,6 gam.
: Cho C
7
H
16
tc dng vi Clo c chiu sng theo t l mol 1: 1 thu c hn hp gm 3 dn xut monoclo.
S cng thc cu to ca C
7
H
16
c th c l
A. 4 B. 5 C. 2 D. 3
Cu 23: Ho tan Fe3O4 trong lng d dung dch H2SO4 long thu c dung dch X. Dung dch X tc dng
c vi bao nhiu cht trong s cc cht sau: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al, H2S?
A. 5 B. 8 C. 6 D. 7
: Xt phn ng thun nghch sau: SO
2
(k) + NO
2
(k) SO
3
(k) + NO(k).
Cho 0,11(mol)SO
2
, 0,1(mol)NO
2
, 0,07(mol)SO
3
vo bnh kn 1 lt. Khi t cn bng ha hc th cn li 0,02(mol)NO
2
.
Vy hng s cn bng K
C
l
A. 20 B. 18 C. 23 D. 0,05
Cu 25: Cht no sau y tn ti dng mng tinh th phn t?
A. P trng, than ch B. kim cng, pht pho
C. kim cng, P trng D. I2, nc
Cu 26: C cc nhn nh sau:
46 | L O V E B O O K . V N
1)Cu hnh electron ca ion X
2+
l 1s
2
2s
2
2p
6
3s
2
3p
6
3d
6
. Trong bng tun hon cc nguyn t ho hc, nguyn
t X thuc chu k 4, nhm VIIIB.
2)Cc ion v nguyn t: Ne , Na
+
, F
c im chung l c cng s electron.

3) Bn knh ca cc vi ht sau c sp xp theo th t gim dn: Mg
2+
, Na
+
, F
-
, Na, K.
4)Dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l K, Mg, Si,
5)Tnh baz ca dy cc hiroxit: NaOH, Al(OH)3 , Mg(OH)2 gim dn.
Cho: N (Z = 7), F (Z=9), Ne (Z=10), Na (Z=11), Mg (Z=12), Al (Z=13), K (Z = 19), Si (Z = 14). S nhn nh ng:
A. 5. B. 4. C. 3. D. 2.
Cu 27: un nng fomandehit vi phenol (d) c axit lm xc tc thu c polime c cu trc:
A. Mch phn nhnh B. Mch khng phn nhnh
C. Khng xc nh c D. Mng li khng gian
Cu 28: Cho Cacbon (C) ln lt tc dng vi H2, Al, H2O, CuO, HNO3 c, H2SO4 c, KClO3, CO2 iu kin
thch hp. S phn ng m trong C ng vai tr l cht kh?
A. 5 B. 6 C. 7 D. 4
Cu 29: Cho cc dung dch sau cng nng mol/l : NH2CH2COOH (1), CH3COOH (2), CH3CH2NH2 (3), NH3 (4).
Th t pH tng dn ng l :
A. (2), (1), (4), (3) B. (1), (2), (3), (4) C. (1), (2), (4), (3) D. (2), (1), (3), (4)
Cu 30: Mt mui X c cng thc C3H10O3N2. Ly 17,08g X cho phn ng ht vi 200ml dung dch KOH 2M. C
cn dung dch sau phn ng thu c phn hi v cht rn. Trong phn hi c mt cht hu c Y (bc 1), trong
phn rn ch l hn hp cc cht v c. Khi lng ca phn rn l:
A. 16,16g B. 28,7g C. 16,6g D. 11,8g
Cu 31: Cho cc cht: BaCl2; NaHSO3; NaHCO3; KHS; NH4Cl; AlCl3; CH3COONH4, Al2O3, Zn, ZnO. S cht lng
tnh l:
A. 8 B. 7 C. 6 D. 5
Cu 32: Nhn nh no sau y khng ng?
A. Phn t mantoz do 2 gc oglucoz lin kt vi nhau qua nguyn t oxi, gc th nht C1, gc th hai
C4(C1OC4)
B. Phn t saccaroz do 2 gc oglucoz v fructoz lin kt vi nhau qua nguyn t oxi, gc oglucoz
C1, gc fructoz C4(C1OC4)
C. Tinh bt c 2 loi lin kt o[1,4]glicozit v o[1,6]glicozit
D. Xenluloz c cc lin kt [1,4]glicozit
Cu 33: in phn vi in cc tr dung dch cha 0,3 mol AgNO3 vi cng dng in 2,68 A, trong thi
gian t (gi) thu c dung dch X (hiu sut qu trnh in phn l 100%). Cho 22,4 gam bt Fe vo X thy
thot ra kh NO (sn phm kh duy nht) v sau cc phn ng hon ton thu c 34,28 gam cht rn. Gi tr
ca t l
A. 0,60. B. 1,00. C. 0,25. D. 1,20.
Cu 34: Sc 1,56g C2H2 vo dung dch cha HgSO4, H2SO4 trong nc 80
o
C thu c hn hp gm 2 cht kh
(bit hiu sut phn ng t 80%). Tip tc cho hn hp kh thu c qua dung dch AgNO3/NH3 d thu c
m gam kt ta. Gi tr ca m l:
A. 13,248g B. 2,88g C. 12,96g D. 28,8g
(a) Zn + HCl (long) (b) Fe3O4 + H2SO4 (long)
(c) KClO3 + HCl (c) (d) Cu + H2SO4 (c)
(e) Al + H2SO4 (long) (g) FeSO4+ KMnO4 + H2SO4
S phn ng m H
+
ca axit ng vai tr cht oxi ho l
A. 5. B. 3. C. 6. D. 2.
: Cho t t 450 ml dd HCl 1M vo 500 ml dung dch X gm Na
2
CO
3
v NaHCO
3
th thu c 5,6 lt kh
(ktc) v dung dch Y. Cho dung dch Y tc dng vi dung dch Ba(OH)
2
d th thu c 19,7 gam kt ta. Nng
mol ca Na
2
CO
3
v NaHCO
3
trong dung dch X ln lt l:
A. 0,2M v 0,15M B. 0,2M v 0,3M C. 0,3M v 0,4M D. 0,4M v 0,3M
Cu 37: Cho cc polime sau: PE (1), PVC (2), cao su buna (3), poli isopren (4), amiloz (5), amilopectin (6),
xenluloz (7), cao su lu ho (8), nha rezit (9). Cc polime c cu trc khng phn nhnh l
A. 1,2,3,4,6,7. B. 1,3,4,5,8. C. 1,2,4,6,8. D. 1,2,3,4,5,7.
Cu 38: Thc hin cc th nghimsau:
(a) Nung NH
4
NO
3

rn. (b)un nng NaCl tinh th vi dung dch H
2
SO
4
(c).
(c) Cho CaOCl2 vo dung dch HCl c. (d) Sc kh CO
2

vo dung dch Ca(OH)
2
(d).
(e) Sc kh SO
2

vo dung dch KMnO
4
. (g) Cho dung dch KHSO
4

vo dung dch NaHCO
3
.
h) Cho ZnS vo dung dch HCl (long). (i) Cho Na
2
CO
3
vo dung dch Fe
2
(SO
4
)
3
.
A. 4. B. 5. C. 2. D. 6.
Cu 39: Cho cc kim loi: Cr, W , Fe , Cu , Cs . Sp xp theo chiu tng dn cng t tri sang phi l
A. Cu < Cs < Fe < Cr < W B. Cu < Cs < Fe < W < Cr C. Cs < Cu < Fe < Cr < W D. Cs < Cu < Fe < W < Cr
Cu 40: Khi nhit phn hon ton m gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht
to ra lng O2 nhiu nht l
A. KNO3 B. AgNO3 C. KMnO4 D. KClO3
Cu 41: Oxi ho khng hon ton 0,16 mol hn hp gm ancol etylic v mt ancol n chc X bng CuO nung
nng(H=100%), thu c hn hp cht hu c Y. Cho hn hp Y phn ng vi AgNO3 trong dung dch NH3 d
thu c 51,84 gam bc. Tn gi ca X l
A. propan-2-ol B. 2-metylpropan-2-ol C. propan-1-ol D. Metanol
Cu 42: Dy gm cc cht c th iu ch trc tip c axit axetic l:
A. C2H2, CH3CHO, HCOOCH3 B. C2H5OH, HCHO, CH3COOCH3
C. C2H5OH, CH3CHO, CH3COOCH3 D. C2H5OH, CH3CHO, HCOOCH3
Cu 43: Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, K2O, MgO nung nhit cao. Sau phn ng
hn hp rn cn li l:
A. Cu, Fe, K2O, MgO. B. Cu, Fe, K2O, Mg. C. Cu, FeO, KOH, MgO. D. Cu, Fe, KOH, MgO.
(1) Ca(OH)2 + Cl2

(4) H2S + SO2

(2) NO2 + NaOH

(5) KClO3 + S
t
0

(3) PbS + O3 (6) Fe3O4 + HCl
S phn ng oxi ho kh l
A. 2. B. 4 C. 5. D. 3
Cu 45: Ho tan hon ton m gam Fe trong dung dch HNO3 thy c 0,3 mol kh NO2 sn phm kh duy nht
thot ra, nh tip dung dch HCl va vo li thy c 0,02 mol kh NO duy nht bay ra. C cn dung dch sau
phn ng thu c cht rn c khi lng l:
A. 24,27 g B. 26,92 g C. 19,5 g D. 29,64 g
Cu 46: Trong cc cht : propen (I); 2-metylbut-2-en(II); 3,4-imetylhex-3-en(III); 3-cloprop-1-en(IV); 1,2-
icloeten (V), cht no c ng phn hnh hc :
A. I, V B. III, V C. II, IV D. I, II, III, IV
Cu 47: C cc dung dch sau (dung mi nc) : CH3NH2 (1); anilin (2); amoniac (3); HOOC-CH(NH2)-COOH
(4); H2N-CH(COOH)-NH2(5), lysin (6), axit glutamic (7). Cc cht lm qu tm chuyn thnh mu xanh l:
A. (1), (2), (3) B. (1), (3), (5), (6) C. (1), (2), (3), (5) D. (1), (2), (3), (4), (5)
48 | L O V E B O O K . V N
Cu 48: X l mt -Aminoaxit no, cha 1 nhm -COOH v 1 nhm -NH2. T m gam X iu ch c m1 gam
ipeptit. T 2m gam X iu ch c m2 gam tripeptit. t chy m1 gam ipeptit thu c 0,3 mol nc. t
chy m2 gam tripeptit thu c 0,55 mol H2O. Gi tr ca m l:
Cu 49: Tch ring Ag ra khi hn hp Ag, Cu, Ni, Fe dng bt. Dung dch cn dng l (vn gi nguyn khi
lng ca Ag ban u)
A. Dung dch FeCl3 B. Dung dch HNO3 c ngui
C. Dung dch H2SO4 long D. Dung dch HCl
Cu 50: Cc kh thi cng nghip v ca cc ng c t, xe my... l nguyn nhn ch yu gy ra ma axit.
Thnh phn ha hc ch yu trong cc kh thi trc tip gy ra ma axit l:
A. NO2, CO2, CO. B. SO2, CO, NO2. C. SO2, CO, NO. D. NO, NO2, SO2.
Phn II: Theo chng trnh nng cao
Cu 51: Thu phn hon ton 150 gam hn hp cc ipeptit thu c 159 gam cc aminoaxit. Bit rng cc ipeptit
c to bi cc aminoaxit ch cha mt nguyn t N trong phn t. Nu ly 1/10 khi lng aminoaxit thu c tc
dng vi HCl d th lng mui thu c l:
Cu 52: Hn hp X gm: HCHO, CH3COOH, HCOOCH3 v CH3CH(OH)COOH. t chy hon ton hn hp X cn
V lt O2 (ktc) sau phn ng thu c CO2 v H2O. Hp th ht sn phm chy vo nc vi trong d thu c
50 gam kt ta. Vy gi tr ca V tng ng l:
A. 7,84 lt B. 8,40 lt C. 11,2 lt D. 16,8 lt
Cu 53: Tnh pH ca dd A gm HF 0,1M v NaF 0,1M.Bit hng s axit ca HF l K
a
= 6,8.10
4
.
A. 2,18 B. 1,18 C. 3,17 D. 1,37
Cu 54: A l mt hp cht mu lc thc t khng tan trong dung dch long axit v kim. Khi nu chy vi
K2CO3 c mt khng kh th chuyn thnh cht B c mu vng (d tan trong nc). Cho cht B tc dng vi
H2SO4 long to thnh cht C c mu da cam. Cht C tc dng vi HCl c thy to thnh cht kh mu vng
lc. A, B, C ln lt l
A. Cr2O3, K2CrO4, K2Cr2O7. B. CrO3, K2CrO4, K2Cr2O7.
C. CrO, K2Cr2O7, K2CrO4. D. Cr2O3, K2Cr2O7, K2CrO4.
Cu 55: C dung dch X gm (KNO3 v H2SO4). Cho ln lt tng cht sau: Fe2O3, FeCl2, Cu, FeCl3, Fe3O4, CuO,
FeO tc dng vi dung dch X. S phn ng oxi ha kh xy ra l
A. 5 B. 4 C. 3 D. 2
Cu 56: Khng th dng cht no sau y phn bit CO2 v SO2?
A. Dung dch KMnO4 B. Kh H2S C. dung dch Br2. D. Ba(OH)2.
Cu 57: Cho 7,52g hn hp hi gm C2H2 v CH3CHO tc dng vi dung dch AgNO3/NH3 d thu c 50,4g
kt ta. Ha tan kt ta vo dung dch HCl d cn li m gam khng tan. Gi tr ca m l:
A. 34,44 gam B. 38,82gam C. 56,04gam D. 13,44gam
Cu 58: T 180 lt ancol etylic 40
0
(khi lng ring ca ancol etylic nguyn cht l d = 0,8g/ml) iu ch
c bao nhiu kg cao su buna (hiu sut qu trnh l 75%)
A. 25,357 kg B. 18,783 kg C. 28,174 kg D. 18,087 kg
Cu 59: Pht biu no sau y l ng:
A. Trong n mn in ho trn cc m xy ra qu trnh oxi ho.
B. Trong in phn dung dch NaCl trn catot xy ra qu trnh oxi ho nc.
C. Than cc l nguyn liu cho qu trnh sn xut thp.
D. Criolit c tc dng h nhit nng chy ca Al.
Cu 60: Pht biu no sau y l ng?
A. Trng hp stiren thu c poli(phenol-fomanehit).
B. T nilon-6,6 c iu ch bng phn ng trng hp hexametylen iamin vi axit aipic.
C. Trng hp buta-1,3-ien vi stiren c xc tc Na c cao su buna-S.
D. T visco l t tng hp.
P N
1.C 2.A 3.A 4.D 5.D 6.A 7.A 8.C 9.D 10.D
11.D 12.D 13.C 14.A 15.C 16.C 17.B 18.C 19.C 20.B
21.A 22.A 23.B 24.A 25.D 26.C 27.B 28.B 29.A 30.B
31.C 32.B 33.D 34.A 35.D 36.D 37.D 38.D 39.D 40.D
41.D 42.C 43.A 44.C 45.B 46.B 47.B 48.A 49.A 50.D
51.A 52.C 53.C 54.A 55.B 56.D 57.C 58.A 59.A 60.C

50 | L O V E B O O K . V N
s 7

I. Phn chung cho tt c cc th sinh: 40 cu
Cu 1: Hp chtA c cng thc phn t C4H6Cl2O2. Cho 0,1 mol A tc dng va vi dung dch c cha 0,3
mol NaOH, thu c dung dch hn hp trong c hai cht hu c gm ancol etylic v cht hu c X, c cn
dung dch sau phn ng thu c m gam cht rn khan. Khi lng m l:
A. Axeton khng lm mt mu dung dch KMnO4 iu kin thng.
B. Cc xeton khi cho phn ng vi H2 u sinh ra ancol bc 2.
C. Tr axetilen, cc ankin khi cng nc u cho sn phm chnh l xeton.
D. Cc hp cht c cha nhm C = O u phn ng vi dung dch Br2.
Cu 3: Cho 70g hn hp phenol v cumen tc dung vi dung dch NaOH 16% va , sau phn ng thy tch
ra hai lp cht lng phn cch, chit thy lp pha trn c th tch l 80 ml v c khi lng ring 0,86g/cm
3
.
% theo khi lng ca cumen trong hn hp l:
A. 26,86% B. 98,29% C. 73,14% D. 56,8%
Cu 4: Cho 27,3 gam hn hp A gm hai este no, n chc tc dng va vi dung dch KOH, thu c 30,8
gam hn hp hai mui ca 2 axit k tip v 16,1 gam mt ancol. Khi lng ca este c khi lng phn t
nh c trong hn hp A l
A. 21 gam. B. 22 gam. C. 17,6 gam. D. 18,5 gam.
Cu 5: Ch dng qu tm c th nhn bit c ti a bao nhiu dung dch trong cc dung dch sau: NaCl,
NaHCO3, Na2CO3, NaHSO4, NaNO3, NaOH.
A. 3 B. 2 C. 4 D. 6
Cu 6: Cho 13,62 gam trinitrotoluen (TNT) vo mt bnh ng bng thp c dung tch khng i 500ml (khng
c khng kh) ri gy n. Sau phn ng nhit bnh l 1800
0
C, p sut trong bnh l P atm, bit rng sn phm
kh trong bnh sau n l hn hp CO, N2, H2. P c gi tr l:
A. 224,38 B. 203,98 C. 152,98 D. 81,6
Cu 7: trung ho dung dch cha 0,9045 gam 1 axit hu c A cn 54,5 ml dung dch NaOH 0,2 M. Trong
dung dch ancol B 94% (theo khi lng) t s mol ancol : nc l 86:14. Cng thc ca A v B l:
A. C4H8(COOH)2, C2H5OH B. C6H4(COOH)2, CH3OH
C. C4H8(COOH)2, CH3OH D. C6H4(COOH)2, C2H5OH.
Cu 8: Cc cht kh sau: SO2, NO2, Cl2, N2O, H2S, CO2. Cc cht kh khi tc dng vi dung dch NaOH ( nhit
thng) lun to ra 2 mui l:
A. NO2, SO2 , CO2 B. CO2, Cl2, N2O C. SO2, CO2, H2S D. Cl2, NO2
Cu 9: Hp cht hu c X c cng thc phn t C6H10O2, cho 9,12 gam X tc dng vi dung dch NaOH va
thu c dung dch Y, cho dung dch Y tc dng vi dung dch AgNO3 d trong NH3 un nng thu c 34,56
gam Ag. S ng phn cu to ca X l:
A. 4. B. 5 C. 2. D. 3.
Cu 10: Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3, Fe3O4 phn ng ht vi dung dch HNO3 long d thu
c 1,344 lt kh NO sn phm kh duy nht ( ktc) v dung dch X. Dung dch X c th ho tan c ti a
11,2 gam Fe. S mol ca HNO3 c trong dung dch ban u l:
Cu 11: Cho cc cht v dung dch sau: toluen, stiren, etilen, xiclopropan, isopren, vinyl axetat, etyl acrylat,
ivinyl oxalat, foocmon, axeton, dung dch glucoz, dung dch Fructoz, dung dch mantoz, dung dch
saccaroz. S cht v dung dch c th lm mt mu dung dch Br2 l:
A. 11. B. 10 C. 8 D. 9
Cu 12: Ha tan 14g hn hp Cu, Fe3O4 vo dung dch HCl, sau phn ng cn d 2,16g hn hp cht rn v
dung dch X. Cho X tc dng vi AgNO3 d thu c bao nhiu gam kt ta:
A. 45,92 B. 12,96 C. 58,88 D. 47,4
Cu 13: Ho tan ht m gam Al2(SO4)3 vo nc c dung dch X. Cho 360 ml dung dch NaOH 1M vo X, thu
c 2a gam kt ta. Mc khc, nu cho 400 ml dung dch NaOH 1M vo X, cng thu c a gam kt ta. Cc
phn ng xy ra hon ton, gi tr ca m l:
A. 18,81 B. 15,39 C. 20,52 D. 19,665
(1). O3 + dung dch KI (6). F2 + H2O
t
0

(5). NH3(kh) + CuO
t
0

(2). MnO2 + HCl c
t
0

(7). H2S + dung dch Cl2 (10). Cu2S + Cu2O
(3). KClO3 + HCl c
t
0

(8). HF + SiO2 (4). NH4HCO3
t
0

(9). NH4Cl + NaNO2
t
0

S trng hp to ra n cht l:
A. 5. B. 6. C. 7. D. 8.
Cu 15: Ha tan 15,84 gam hn hp gm mt oxit kim loi kim v mt oxit kim loi kim th bng dung dch
HCl d c dung dch X. C cn dung dch X, ly mui khan em in phn nng chy hon ton th thu c
6,048 lt kh (o ktc) anot v a (gam) hn hp kim loi catot. Gi tr ca a l:
A. 7,2. B. 11,52. C. 3,33. D. 13,68.
Cu 16: X l ipeptit Ala-Glu, Y l tripeptit Ala-Ala-Gly. un nng m (gam) hn hp cha X v Y c t l s mol
ca X v Y tng ng l 1:2 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn cn
thn dung dch T thu c 56,4 gam cht rn khan. Gi tr ca m l:
A. 45,6 B. 40,27. C. 39,12. D. 38,68.
Cu 17: C cc nhn xt sau:
1- Cht bo thuc loi cht este.
2- T nilon, t capron, t enang u iu ch bng phn ng trng ngng.
3- Vinyl axetat khng iu ch c trc tip t axit v ancol tng ng.
4- Nitro benzen phn ng vi HNO3 c (xc tc H2SO4 c) to thnh m-initrobenzen.
5- phenyl amoni clorua phn ng vi nc brom d to thnh (2,4,6-tribromphenyl) amoni clorua.
Nhng cu ng l:
A. 1, 3, 4. B. 2, 3, 4. C. Tt c. D. 1, 2, 4, 5.
Cu 18: Mt loi phn Supephotphat kp c cha 72,68% mui canxi ihirophotphat cn li gm cc cht
khng cha pht pho. dinh dng ca loi phn ln ny l:
A. 60,68% B. 37,94% C. 30,34% D. 44,1%
Cu 19: Pht biu no di y khng ng?
A. Cht bo nh hn nc v khng tan trong nc
B. M ng vt ch yu cu thnh t gc axit bo, no, tn ti trng thi rn
C. Hiro ho du thc vt lng s to thnh cc m ng vt rn
D. Nhc im ca cht git ra tng hp l gy nhim cho mi trng
Cu 20: Cho cc cht sau: FeBr3, FeCl2, Fe3O4,AlBr3, MgI2, KBr, NaCl, CaF2,CaC2. Axit H2SO4 c nng c th oxi
ha bao nhiu cht?
A. 3 B. 6 C. 5 D. 7
Cu 21:Cho ankan X tc dng vi clo (nh sng) thu c 26,5 gam hn hp cc dn xut clo (mono v iclo).
Kh HCl bay ra c hp th hon ton bng nc sau trung ha bng dd NaOH thy tn ht 500 ml dd
NaOH 1M. Xc nh cng thc ca X?
A. C2H6 B. C4H10 C. C3H8 D. CH4
52 | L O V E B O O K . V N
Cu 22: Cho cc cht: xiclobutan, metylxiclopropan, 1,2-imetylxiclopropan, -butilen, but-1-in, trans but-2-
en, butaien, vinyl axetilen, isobutilen, anlen. C bao nhiu cht trong s cc cht trn khi tc dng vi hiro
c th to ra butan.
A. 8 B. 9 C. 7 D. 6
Cu 23: Khi iu ch Na trong cng nghip ngi ta dng hn hp gm 2 phn NaCl v 3 phn CaCl2 v khi
lng vi mc ch:
A. To ra nhiu cht in ly hn
B. Tng nng ion Cl
-
C. Gim nhit nng chy

D. To ra hn hp c khi lng ring nh ni ln trn Na nng chy
CH
2
= CH
2
+H
2
O
H
+
,t
0

Cl
2
+KOH CH
3
CHO +H
2

C
2
H
5
OH +HBr (bk) Mg(NO
3
)
2
t
Fe
3
O
4
+H
2
SO
4
(long)
CH
3
CH = CH
2
+Br
2
(dd) Na
2
O
2
+H
2
O
Trong cc phn ng trn c bao nhiu phn ng l oxh-kh, bao nhiu phn ng ni phn t:
A. 7 4 B. 6 4 C. 5 4 D. 6 2
Cu 25: Sb cha 2 ng v chnh
121
Sb v
123
Sb, khi lng nguyn t trung bnh ca Sb l 121,75. % khi lng ca
ng v
121
Sb trong Sb2O3 (MO=16) l:
A. 52,2 B. 62,5 C. 26,1 D. 51,89
Cu 26: Cho H (Z=1), N (Z=7), O (Z=8). Trong phn t HNO3, tng s cp electron lp ngoi cng khng tham
gia lin kt ca 5 nguyn t l:
A. 8. B. 9. C. 7. D. 6.
Cu 27: Mt loi cao su buna-N c phn trm khi lng ca nit l 19,72%. T l mt xch butaien v vinyl
xianua l:
A. 1 : 2 B. 2 : 1 C. 1 : 3 D. 3 : 1
Cu 28: Cho cc cn bng sau:
(1) 2NH3(k) N2(k) + 3H2(k) AH > 0 (2) 2SO2(k) + O2(k) 2SO3(k) AH < 0
(3) CaCO3(r) CaO(r) + CO2(k) AH > 0 (4) H2(k) + I2(k) 2HI(k) AH < 0
Trong cc cn bng trn cn bng no s chuyn dch theo chiu thun khi tng nhit v gim p sut:
A. 1, 3. B. 2, 4. C. 1, 2, 3 ,4. D. 1, 4.
Cu 29: Cho cc dung dung dch sau: (1): natri cacbonat; (2): st (III) clorrua; (3): axit sunfuaric long; (4):
axit axetic; (5): natri phenolat; (6): phenyl amoni clorua; (7): imetyl amoni clorua. Dung dch metylamin tc
dng c vi dung dch:
A. 3, 4, 6, 7 B. 2, 3, 4, 6 C. 2, 3, 4, 5 D. 1, 2, 4, 5
Cu 30: Cho 1 ipeptit Y c cng thc phn t C6H12N2O3. S ng phn peptit ca Y (ch cha gc -amino
axit) mch h l:
A. 5. B. 4. C. 7. D. 6.
: Cho dung dch mui X vo cc dung dch Na
2
CO
3
; dung dch Na2S u thy c kt ta v c kh bay ln. Vy X l :
A. AlCl3 B. FeCl3 C. FeCl2 D. CuCl2.
Cu 32: C cc pht biu sau y:
(1) Amiloz c cu trc mch phn nhnh. (2) Mantoz b kh ha bi dd AgNO3 trong NH3.
(3) Xenluloz c cu trc mch phn nhnh. (4) Saccaroz lm mt mu nc brom.
(5) Fructoz c phn ng trng bc. (6) Glucoz tc dng c vi dung dch thuc tm.
(7) Trong dung dch, glucoz tn ti ch yu dng mch vng v mt phn nh dng mch h.
S pht biu ng l:
A. 6. B. 4. C. 5. D. 3.
Cu 33: Gi thit trong tinh th cc nguyn t st l nhng hnh cu chim 74% th tch tinh th, phn cn li
l cc khe rng gia cc qu cu, cho nguyn t khi ca Fe l 55,85 20
0
C khi lng ring ca Fe l
7,87g/cm
3
. Bn knh nguyn t gn ng ca Fe l:
A. 1,28 A
0
. B. 1,41A
0
. C. 1,67 A
0
. D. 1,97 A
0
.
Cu 34: Cho 7,8 gam hn hp X gm 2 ancol n chc, bc I qua CuO d, nung nng (phn ng hon ton) sau
phn ng thy khi lng cht rn gim 3,2 gam. Cho hn hp sn phm tc dng vi AgNO3 d trong NH3,
un nng thu c m gam Ag. Gi tr ca m l:
A. 64,8 B. 43,2 C. 21,6 D. 86,4
Cu 35: Hn hp X gm NaBr v NaI. Cho hn hp X tan trong nc thu c dung dch Y.Nu cho brom d
vo dung dch Y, sau phn ng hon ton, c cn thy khi lng mui khan thu c gim 7,05 gam. Nu sc
kh clo d vo dung dch Y, phn ng hon ton, c cn dung dch thy khi lng mui khan gim 22,625
gam. Thnh phn % khi lng ca mt cht trong hn hp X l:
A. 35,9% B. 47,8% C. 33,99% D. 64,3%
Cu 36: Cho hi nc i qua than nung nng sau khi loi b hi nc d thu c 17,92 lt (ktc) hn hp
kh X gm CO
2
, CO v H
2
. Hp th X vo dung dch Ba(OH)
2
d thu c 35,46 gam kt ta v c V lt kh Y
thot ra. Cho Y tc dng vi CuO d nung nng sau phn ng thy khi lng cht rn gim m gam. Gi tr ca
m l:
Cu 37: t chy hon ton mt hn hp X (glucoz, fructoz, metanal v etanoic) cn 3,36 lt O2 (iu kin
chun). Dn sn phm chy qua bnh ng dung dch Ca(OH)2 d, sau phn ng hon ton thu c m gam
kt ta. Gi tr ca m l
A. 10,0 B. 12,0 C. 15,0 D. 20,5
Cu 38: C cc pht biu sau:
(1) Lu hunh, photpho, C2H5OH u bc chy khi tip xc vi CrO3.
(2) Ion Fe
3+
c cu hnh electron vit gn l [Ar]3d
5
.
(3) Bt nhm t bc chy khi tip xc vi kh clo.
(4) Phn chua c cng thc l Na2SO4.Al2(SO4)3.24H2O.
Cc pht biu ng l:
A. (1), (2), (4) B. (1), (2). C. (1), (2), (3). D. (3), (4).
Cu 39: in phn c mng ngn vi in cc tr 250 ml dung dch hn hp CuSO4 aM v NaCl 1,5M, vi
cng dng in 5A trong 96,5 pht. Dung dch to thnh c khi lng b gim so vi ban u l 17,15g.
Gi tr ca a l
A. 0,5 M. B. 0,4 M. C. 0,474M. D. 0,6M.
Cu 40: Nung hn hp gm 11,2 gam Fe; 6,4 gam Cu v 19,5 gam Zn vi mt lng d lu hunh n khi phn
ng hon ton. Sn phm ca phn ng tc dng vi dung dch HCl d thu c kh B. Th tch dung dch
Pb(NO3)2 20% (d = 1,1 g/ml) ti thiu cn dng hp th ht kh B l
A. 752,27 ml B. 902,73 ml C. 1053,18 ml D. 910,25 ml
Phn I: Theo chng trnh Chun
Cu 41: Cho cc cht sau: axetilen, axit oxalic, axit acrylic, fomanehit, phenyl fomat, vinyl axetilen, glucz,
anehit axetic, metyl axetat, saccaroz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l
A. 6 B. 8 C. 7 D. 5
Cu 42: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 50 ml dung dch
NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 19,04 lt kh CO2 ( ktc) v 14,76 gam H2O.
% s mol ca axit linoleic trong m gam hn hp X l:
A. 31,25% B. 30% C. 62,5% D. 60%
Cu 43: Dy cc kim loi c cu trc mng tinh th lp phng tm khi l:
A. Na, K, Ba B. Ca, Sr, Ba C. Mg, Ca, Ba D. Na, K, Mg
54 | L O V E B O O K . V N
Cu 44: Xt phn ng: CO(kh) + H2O (kh) CO2(kh) + H2(kh). Trong iu kin ng nhit, khi tng p
sut ca h th tc phn ng nghch nh th no?
A. Gim. B. Tng. C. C th tng hoc gim D. Khng i.
Cu 45: Hin tng ln lt xy ra khi cho t t n d dung dch NaOH vo dung dch CrCl3, thm tip H2O2
d, ri cho dung dch BaCl2 vo l:
A. To kt ta xanh lc ri tan, thnh dung dch da cam, sau c kt ta mu vng.
B. To kt ta xanh lc ri tan, thnh dung dch mu vng, sau c kt ta da cam.
C. To kt ta xanh lc ri tan, thnh dung dch mu vng, sau c kt ta mu vng.
D. To kt ta trng ri tan, thnh dung dch mu xanh, sau c kt ta mu vng.
Cu 46: Hn hp X gm hai anken c t khi so vi H2 bng 16,625. Ly hn hp Y cha 26,6 gam X v 2 gam
H2. Cho Y vo bnh kn c dung tch V lt ( ktc) c cha Ni xc tc. Nung bnh mt thi gian sau a v 0

o
C thy p sut trong bnh bng 7/9 at. Bit hiu sut phn ng hiro ho ca cc anken bng nhau v th tch
ca bnh khng i. Hiu sut phn ng hiro ho l
A. 40%. B. 50%. C. 75%. D. 77,77%.
Cu 47: X c cng thc C4H14O3N2. Khi cho X tc dng vi dung dch NaOH th thu c hn hp Y gm 2 kh
iu kin thng v u c kh nng lm xanh qu tm m. S cng thc cu to ph hp ca X l:
A. 5 B. 3 C. 4 D. 2
Cu 48: Co hai thi nghie m sau:
Thi nghie m 1: Cho 6g ancol no h n ch c X ta c du ng v i m gam Na, sau pha n ng thu c 0,075 gam H2.
Thi nghie m 2: Cho 6g ancol no h n ch c X ta c du ng v i 2m gam Na, sau pha n ng thu kho ng t i 0,1gam H2.
X co co ng th c la :
A. CH3OH. B. C2H5OH. C. C3H7OH. D. C4H9OH.
Cu 49: Ha tan m gam hh X gm CuCl2 v FeCl3 trong nc c dung dch Y. Chia Y thnh 2 phn bng nhau.
Phn 1 : cho kh H2S d vo c 1,28g kt ta. Phn 2 : cho Na2S d vo c 3,04g kt ta. Gi tr ca m l :
A. 14,6 g B. 8,4 g C. 10,2 g D. 9,2 g
Cu 50: xc nh hm lng ca FeCO3 trong qung xierit, ngi ta lm nh sau: Cn 0,600 gam mu
qung, ch ho n theo mt quy trnh hp l, thu c dd FeSO4 trong mi trng H2SO4 long. Chun dung
dch thu c bng dung dch chun KMnO4 0,025M th dng va ht 25,2 ml dung dch chun.Thnh phn
phn trm theo khi lng ca FeCO3 trong qung l:
A. 12,18% B. 60,9% C. 24,26% D. 36,54%
Phn II: Theo chng trnh nng cao
Cu 51: Hn hp M gm mt peptit X v mt peptit Y (chng cu to t 1 loi aminoaxit, tng s nhm CO
NH trong 2 phn t l 5) vi t l s mol nX : nY = 1: 2. Khi thy phn hon ton m gam M thu c 12 gam
glixin v 5,34 gam alanin. m c gi tr l :
A. 14,46g B. 110,28g C. 16,548 D. 15,86g
Cu 52: Cho s phn ng sau: Anehit no, mch h X1
+H
2
/Ni,t
0

X
2
H
2
O
X
3
t
0
,p,xt
Cao su buna.
Anehit no mch h X
4
+H
2
/Ni,t
0

X
5
H
2
O,H
2

X
3
t
0
,p,xt
Cao su buna.

Hy cho bit: khi cho X1 v X4 vi khi lng bng nhau tc dng hon ton vi dung dch AgNO3 trong NH3
un nng, cht no to ra lng Ag nhiu hn ?
A. bng nhau. B. X1. C. X4. D. khng xc nh c.
Cu 53: Cho dung dch CH3COONa 0,1M (Kb Ca CH3COO
-
l 5,71.10
-10
). Nng mol/l ca H
+
trong dung dch
bng:
A. 1,2.10
-9
mol/l B. 1.32.10
-9
mol/l C. 1,15.10
-9
mol/l D. 2,25.10
-10
mol/l
Cu 54: Cho dung dch AgNO3 vo dd X c kt ta to thnh, lc ly kt ta cho vo dung dch NH3 thy kt ta
tan.Vy X
A. ch c th l NaCl. B. ch c th l Na3PO4. C. l NaCl hay NaBr. D. l NaCl, NaBr hay NaI.
Cu 55: X l mt hp cht mu lc thc t khng tan trong dung dch long axit v kim. Khi nu chy vi
K2CO3 c mt khng kh th chuyn thnh cht Y c mu vng (d tan trong nc). Cho cht Y tc dng vi
H2SO4 long to thnh cht Z c mu da cam. Cht Z tc dng vi HCl c thy to thnh cht kh mu vng lc.
X, Y, Z ln lt l
A. Cr2O3, K2CrO4, K2Cr2O7. B. CrO, K2CrO4, K2Cr2O7.
C. CrO, K2Cr2O7, K2CrO4. D. CrO3, K2Cr2O7, K2CrO4.
Cu 56: Ha tan 1,0 gam qung crom trong axit, oxi ha Cr
3+
thnh Cr
2
O
7
2
. Sau khi phn hy ht lng d
cht oxi ha, pha long dd thnh 100 ml. Ly 20 ml dd ny cho vo 25 ml dd FeSO4 trong H2SO4. Chun
lng d FeSO4 ht 7,50 ml dd chun K2Cr2O7 0,0150M. Bit rng 25 ml FeSO4 tng ng vi 35 ml dd
chun K2Cr2O7. Thnh phn % ca crom trong qung l:
A. 10,725% B. 13,65%. C. 21,45%. D. 26%.
Cu 57: Hn hp X c C2H5OH, C2H5COOH, CH3CHO (trong C2H5OH chim 50% theo s mol). t chy m
gam hn hp X thu c 2,88 gam H2O v 2,912 lt CO2 (ktc). Mt khc 9 gam hn hp X thc hin phn ng
trng bc thy c p gam Ag kt ta. Gi tr ca p l
A. 12,96. B. 4,32. C. 8,64. D. 5,4.
Cu 58: Cho s : Propilen
+H
2
O,H
+

A
+CuO,t
0

B
+HCN
D. D l:
A. CH3CH2CH2OH B. CH3CH2CH(OH)CN C. CH3C(OH)(CH3)CN D. CH3CH(OH)CH3.
Cu 59: Ha tan hon ton hn hp gm mt kim loi ha tr 1 v oxit kim loi ha tr 2 vo nc d. Sau khi
phn ng xong c 500 ml dd X ch cha mt cht tan duy nht v 4,48 lt kh H2. Tnh nng mol ca dung
dch X:
A. 0,2M B. 0,4 M C. 0,3M D. 0,25 M
Cu 60: T khi ca mt hn hp kh (gm 2 hidrocacbon mch h) so vi hiro l 17. iu kin tiu chun, trong
bng ti, 400 ml hn hp tc dng va vi 71,4 cm
3
dung dch brom 0,2 M. Sau phn ng th tch kh cn li l 240
cm
3
. Cng thc phn t ca 2 hidrocacbon l:
A. C2H2 v C3H8 B. CH4 v C4H6 C. C2H6 v C3H6 D. C2H6 v C3H4

P N

1.D 2.D 3.B 4.D 5.C 6.B 7.D 8.D 9.D 10.C
11.B 12.C 13.A 14.C 15.B 16.C 17.A 18.D 19.C 20.D
21.A 22.C 23.C 24.D 25.D 26.C 27.C 28.A 29.B 30.A
31.A 32.D 33.A 34.A 35.B 36.C 37.C 38.C 39.B 40.A
41.D 42.B 43.A 44.D 45.C 46.B 47.B 48.C 49.D 50.B
51.A 52.B 53.B 54.A 55.A 56.C 57.A 58.C 59.B 60.D

56 | L O V E B O O K . V N
s 8

I.PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
a). HBr + C2H5OH

b). C2H4 + Br2 c). C2H4 + HBr
d). C2H6 + Br2
askt(1:1)
h). C2H2 + 2HBr g). C2H4Br2 + Zn
t
0

S phn ng to ra etyl bromua l
A. 4 B. 2 C. 3 D. 1
Cu 2: Cho m gam hn hp axit axetic, axit benzoic, axit adipic, axit oxalic tc dng va vi dung dch NaOH
thu c a gam mui. Nu cng cho m gam hn hp X ni trn tc dng vi Ca(OH)2 va th thu c b
gam mui. Biu thc lin h m, a, b l:
A. 9m = 20 a 11b B. 3m = 22b 19a C. 8m = 19 a- 11b D. m = 11b 10a
Cu 3: Cho m gam ancol no,mch h X tc dng hon ton vi CuO (d) nung nng, thu c hn hp hi Y
(c t khi hi so vi H2 l 47/3) c cht hu c Z v thy khi lng cht rn gim 2,4 gam. Mt khc t a
mol Z, thu c b mol CO2 v c mol nc; vi b = a + c. Gi tr ca m l
A. 4,65 B. 9,3 C. 4,5 D. 4,35
Cu 4: Cho 15,84 gam este no n chc mch h phn ng va ht vi 30ml dung dch MOH 20% (d = 1,2g/ml,
M l kim loi kim). Sau phn ng hon ton c cn dung dch thu c cht rn X. t chy hon ton X thu
c 9,54 gam M2CO3 v hn hp gm CO2, H2O. Kim loi M v este ban u c cu to l:
A. Na v HCOOC2H5 B. K v CH3COOCH3 C. K v HCOOCH3 D. Na v CH3COOC2H5
Cu 5: Nhng mt l st nh v d vo dung dch cha mt trong nhng cht sau: FeCl3, AlCl3, CuSO4, Pb(NO3)2,
NaCl, HCl, HNO3 long, H2SO4 c nng, NH4NO3. S trng hp phn ng to mui Fe(II) l:
A. 6 B. 5 C. 3 D. 4
Cu 6: Hp cht hu c X ch cha C, H, O. X c khi lng mol phn t l 90g/mol. Cho X tc dng vi NaHCO3
th c kh bay ra. Cho X tc dng ht vi Na to ra s mol H2 bng s mol X. S lng hp cht tha mn nhng
tnh cht trn ca A l:
A. 2 cht B. 3 cht C. 4 cht D. 1 cht
Cu 7: Hn hp X gm axit axetic, axit fomic v axit salixylic (axit o-hiroxibenzoic). Cho a gam X tc dng va
vi 400ml dung dch NaOH 1M. Nu t chy hon ton a gam X cn 16,24 lt O2(ktc) thu c 35,2 gam
CO2 v m gam H2O. Gi tr ca m l
A. 9 gam B. 14,4 gam C. 10,8 gam D. 18 gam
Cu 8: Hn hp X gm N2 v H2 c M= 7,2. Nung X vi bt Fe phn ng tng hp NH3 xy ra vi hiu sut
20% c hn hp Y. Cho Y tc dng vi CuO d, nung nng thu c 32,64 g Cu. Hn hp X c th tch l bao
nhiu ktc?
A. 16,8 lt B. 8,4 lt C. 11,2 lt D. 14,28 lt
Cu 9: Cho cc cht sau y: 1) CH3COOH, 2) C2H5OH, 3) C2H2, 4) CH3COONa, 5) HCOOCH=CH2, 6) CH3COONH4,
7) C2H4. Dy gm cc cht no sau y u c to ra t CH3CHO bng mt phn ng ha hc l:
A. 1, 2, 3, 6, 7 B. 2, 3, 5, 7. C. 1, 2, 6. D. 1, 2, 4, 6.
Cu 10: Cho t t V lt dung dch Na2CO3 1M vo V1 lt dung dch HCl 1M thu c 2,24 lt CO2 (ktc). Cho t
t V1 lt HCl 1M vo V lt dung dch Na2CO3 1M thu c 1,12 lt CO2 (ktc). Vy V v V1 tng ng l:
A. V = 0,15 lt ; V1 = 0,2 lt B. V = 0,25 lt ; V1 = 0,2 lt C. V = 0,2lt ; V1 = 0,25 lt `
D. V = 0,2 lt ; V1 = 0,15 lt
Cu 11: T anehit no n chc A c th chuyn trc tip thnh ancol Y v axit Z tng ng iu ch este
E t Y v Z. Hy xc nh t s d = ME / MA.
A. 2/3 B. 2 /1 C. 3/2 D. 1/2
Cu 12: Nung hn hp gm 11,2g Fe; 6,4g Cu v 26g Zn vi mt lng d lu hunh n hon ton. Sn phm
ca phn ng tc dng vi dung dich HCl d thu c kh X. Tnh th tch dung dch CuSO4 10% (d = 1,1g/ml)
ti thiu cn dng hp th ht kh X?
A. 872,73ml B. 750,25ml C. 525,25ml D. 1018,18ml
Cu 13: Cho 0,87 gam hn hp gm Fe, Cu v Al vo bnh ng 300 ml dung dch H2SO4 0,1M. Sau khi cc phn
ng xy ra hon ton thu c 0,32 gam cht rn v c 448 ml kh (ktc) thot ra. Thm tip vo bnh 0,425
gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc), sn phm kh duy nht) to thnh v khi
lng mui trong dd l
A. 0,224 lt v 3,750 gam. B. 0,112 lt v 3,750 gam.
C. 0,112 lt v 3,865 gam. D. 0,224 lt v 3,865 gam.
Cu 14: Cho 12,25 gam KClO3 vo dung dch HCl c d, kh Cl2 thot ra cho tc dng ht vi kim loi M thu
c 38,10 gam hn hp cht rn X. Cho X vo dung dch AgNO3 d, thu c 118,5 gam kt ta. Cc phn
ng u xy ra hon ton. Vy kim loi M l:
A. Zn B. Mg C. Fe D. Cu
Cu 15: Mt hn hp X gm Na, Al v Fe (vi t l mol Na v Al tng ng l 5:4) tc dng vi H2O d th thu
c V lt kh, dung dch Y v cht rn Z. Cho Z tc dng vi dung dch H2SO4 long d th thu c 0,25V lt
kh (cc kh o cng iu kin). Thnh phn % theo khi lng ca Fe trong hn hp X l
A. 14,4% B. 33,43% C. 34,8%. D. 20,07%
Cu 16: A l mt hexapeptit c to t mt loi aminoaxit X. Phn t X cha 1 nhm NH2 v 1 nhm COOH,
tng khi lng nito v oxi trong X chim 61,33%. Khi thy phn m gam A thu c hn hp sn phm gm 90,9
gam pentapeptit; 147,6 gam tetrapeptit; 37,8 gam tripeptit; 39,6 gam ipeptit; 45 gam X. Gi tr ca m l:
A. 342 gam B. 409,5 gam C. 360,9 gam D. 427,5 gam
Cu 17: Bn cht hu c X, Y, Z, T c cng cng thc phn t C3H4O2 cc tnh cht : c 4 cht tc dng c
vi H2, trong Y, Z tc dng theo t l mol 1 : 2 , X, T theo t l mol: 1 : 1. X, Y, Z c phn ng trng gng. Y
c th iu ch propan-1,3- diol bng phn ng xi ho . Cng thc cu to ca X, Y , Z, T:
A. H-COOC2H3 , CH2(CHO)2 , C2H3COOH. CH3COCHO . C. C2H3COOH , H-COOC2H5 , CH2(CHO)2 , CH3COCHO.
B. CH2(CHO)2 , CH3COCHO, C2H3COOH , H-COOC2H3. D. H-COOC2H3 , CH2(CHO)2 , CH3COCHO, C2H3COOH.
Cu 18: Cho 14,948 gam hn hp KMnO4 v MnO2 (trong MnO2 chim 6,98% v khi lng) tc dng vi
150 ml HCl 36,8% (d = 1,19 g/ml). Lng kh clo thu c ( ktc) l:
A. 2,016 lt B. 4,928 lt C. 0,012 lt D. 5,1968 lt
Cu 19: Cho cc pht biu sau:
a) Cht bo l trieste ca glixerol vi cc axit monocacboxylic c s chn nguyn t cacbon, mch cacbon di
khng phn nhnh.
b) Lipit gm cht bo, sp, steroit, photpholipit.
c) Cht bo l cc cht lng
d) Cht bo cha ch yu cc gc khng no ca axit bo thng l cht lng nhit phng v c gi l du
e) Phn ng thy phn cht bo trong mi trng kim l phn ng thun nghch
g) Cht bo l thnh phn chnh ca du, m ng thc vt
Nhng pht biu ng l
A. c, d, e B. a, b, d, e C. a, b, d, g D. a, b, c
Cu 20: Cho 13,36 gam hn hp X gm Cu, Fe3O4 vo dung dch H2SO4 c nng d c V1 lt SO2 v dung
dch Y. Cho Y phn ng vi NaOH d c kt ta T, nung kt ta ny n khi lng khng i c 15,2
gam cht rn Q. Nu cng cho lng X nh trn vo 400 ml dung dch P cha HNO3 v H2SO4 thy c V2 lt NO
duy nht thot ra v cn 0,64 gam kim loi cha tan ht. Cc phn ng xy ra hon ton v cc kh o ktc.
Gi tr V1 v V2 l
A. 2,576 v 0,224 B. 2,912 v 0,224 C. 2,576 v 0,896 D. 2,576 v 0,672
Cu 21: Khi nung butan vi xc tc thch hp thu c hn hp A gm CH4, C3H6, C2H4, C2H6, C4H8, H2 v C4H10
d. t chy hon ton hn hp A thu c 8,96 lt CO2 (o ktc) v 9,0 gam H2O. Mt khc, hn hp A lm
mt mu va ht 12 gam Br2 trong dung dch nc brom. Hiu sut phn ng nung butan l:
A. 75%. B. 65%. C. 50%. D. 45%.
Cu 22: Mt axit bo (X) c cng thc cng thc cu to sau: CH3[CH2]4-CH=CH-CH2-CH=CH-[CH2]7-COOH. Hy
cho bit X c bao nhiu ng phn hnh hc?
A. 4 B. 2 C. 3 D. 5
58 | L O V E B O O K . V N
Cu 23: Ha tan Ba, Na c t l mol 1:1 vo nc d thu c dung dch X v 0,672 lt H2 (ktc). Thm m gam
NaOH vo dung dch X c dung dch Y. Thm 100ml dung dch Al2(SO4)3 0,2M vo dung dch Y thu c kt
ta Z. Gi tr m khi lng kt ta Z b nht v khi lng kt ta ln lt l
A. m 4,5 g v 4,66 g B. m 4,0 g v 3,495 g C. m 3,2 g v 4,66 g D. m 4 4,66
Cu 24: Cho cn bng sau: 2A(k) 3B(k) + D(r). Khi tng nhit ca phn ng, t khi hi ca hn hp kh so
vi H2 tng ln. Khng nh no sau y ng?
A. Phn ng thun l to nhit; khi tng nhit , cn bng chuyn dch theo chiu phn ng thun.
B. Phn ng thun l thu nhit; khi tng nhit , cn bng chuyn dch theo chiu phn ng thun.
C. Phn ng thun l thu nhit; khi tng nhit , cn bng chuyn dch theo chiu phn ng nghch.
D. Phn ng thun l to nhit; khi tng nhit , cn bng chuyn dch theo chiu phn ng nghch.
Cu 25: X, Y l hai nguyn t lin tip nhau trong mt chu k, tng s n v in tch ht nhn ca hai nguyn
t tng ng l 25 ( ZX< ZY). So snh tnh kim loi v bn knh nguyn t ca X v Y ta c:
A. Tnh kim loi ca X < Y, RX> RY B. Tnh kim loi ca X > Y, RX< RY
C. Tnh kim loi ca X > Y, RX> RY D. Tnh kim loi ca X < Y, RX< RY
Cu 26: S nguyn t m nguyn t c tng s 4 electron trn phn lp s l:
A. 7. B. 1. C. 2. D. 6.
Cu 27: Trng ngng 1,232 tn hexametyleniamin vi 1,460 tn axit aipic thu c bao nhiu kg t nilon-
6,6 (bit hiu sut phn ng l 90%)?
A. 2232 kg B. 2034 kg C. 2692 kg D. 2196 kg
Cu 28: Cho hn hp Na, Al, Fe, FeCO3, Fe3O4 tc dng vi dung dch NaOH d, lc ly kt ta ri chia lm 2
phn. Phn 1 em tc dng vi dung dch HNO3 long d. Phn 2 em tc dng va ht vi dung dch HCl. S
phn ng oxi ha kh c th xy ra l:
A. 8. B. 6. C. 7. D. 5.
Cu 29: Hp cht hu c X c cng thc phn t C4H9O2N. Cho 0,15 mol X phn ng vi dung dch NaOH va
, un nng thy thot ra kh khng mu, nng hn khng kh, lm xanh giy qu m. Dung dch sau phn ng
lm nht mu nc brom. C cn cn thn dung dch sau phn ng thu c s gam mui l:
A. 16,2 g B. 14,1 g C. 14,4 g D. 12,3 g
Cu 30: Nhng a thy tinh th nht vo dung dch HCl c, a thy tinh th 2 vo l ng cht X l mt trong
cc cht sau: trimetylamin, metylamin, alanin, etylamin, amoniac, anilin. Ly hai a ra gn nhau, thy hin
tng khi trng. C bao nhiu cht X tha mn hin tng trn?
A. 1 B. 2 C. 3 D. 4
Cu 31: Khi cho hn hp MgSO4, FeCO3, Ba3(PO4)2, FeS, Ag2S vo dung dch HCl d th phn khng tan cha:
A. FeS, AgCl, Ba3(PO4)2 B. FeS, AgCl, BaSO4
C. Ba3(PO4)2, Ag2S D. Ag2S, BaSO4
Cu 32: Cho cc nhn nh sau:
a) Saccaroz v glucoz u c phn ng trng bc
b) C th dng ch Cu(OH)2 nhn bit cc l mt nhn cha Glixerol, Glucoz, Fructoz, Etanal
c) Trong s iu ch: Xenluloz
+H
2
O,H
+

X
enzim
Y
ZnO,MgO/500
0
C
Z. Vy Z l divinyl
d) dng mch h, glucoz c 5 nhm -OH cnh nhau
e) Trong phn t amilopectin, cc gc -glucoz lin kt vi nhau bi cc lin kt -1,4- v -1,6-glicozit
g) Xenluloz c cu trc mch phn nhnh.
h) Nh dung dch H2SO4 c vo vi si bng, vi b en v thng ngay do phn ng H2SO4 oxi ha tinh bt
Cc nhn nh ng l
A. c, d, e B. a, b, c, h C. d, e, h D. b, d, g
Cu 33: in phn dung dch cha Fe(NO3)3, Cu(NO3)2 vi I = 10A, in cc tr n khi dung dch va ht mu
xanh th dng li, khi anot thu c 0,196 lt kh (ktc) v khi lng dung dch gim 0,92g. Thi gian
in phn, s mol tng mui trc in phn theo th t trn l:
A. 6,5 pht; 0,01 mol ; 0,02 mol B. 5,6 pht; 0,01 mol ; 0,01 mol
C. 6,5 pht; 0,01 mol ; 0,015 mol D. 5,6 pht; 0,015 mol ; 0,01 mol
Cu 34: Thy phn hon ton 21,12 gam este X c to bi axit cacboxylic Y v ancol Z bng dung dch NaOH
thu c 23,04 gam mui v m gam hi ancol Z. T Z bng mt phn ng c th to ra c:
A. CH3COOH, C2H4, CH3CHO B. CO2, C2H4, CH3CHO
C. HCHO, HCOOH, CH3COOH D. CH3Cl, C2H4, CH2 = CH- CH = CH2
Cu 35: Cho cc axit sau: HCl, HF, HBr, HI, HNO3, H3PO4, H2S. C bao nhiu axit c iu ch bng cch cho
tinh th mui tc dng vi H2SO4 c, un nng?
A. 3 B. 2 C. 5 D. 4
Cu 36: Cho cc mnh sau
Cc halogen (F, Cl, Br, I) c s oxi ha t +1, +3, +5, +7
Flo ch c tnh oxi ha
F2 y c Cl2 ra khi mui NaCl nng chy
Tnh axit ca cc dung dich halogen hiric tng theo th t HF, HCl, HBr, HI.
Cc mui AgF, AgCl, AgBr, AgI u khng tan trong nc.
Tnh kh ca hiro halogenua: HF, HCl, HBr, HI gim dn
Cc mnh ng l
A. (2), (4), (5), (6) B. (1), (3), (4), (5) C. (2), (3), (4) D. (2), (3), (4), (6)
Cu 37: Oxi ho 25,6 gam CH3OH (c xc tc) thu c hn hp sn phm X. Chia X thnh hai phn bng nhau
Phn 1 tc dng vi AgNO3 d trong NH3 un nng thu c m gam Ag. Phn 2 tc dng va vi 100ml
dung dch KOH 1M. Hiu sut qu trnh oxi ho CH3OH l 50%. Gi tr ca m l
A. 108. B. 64,8. C. 129,6. D. 54.
Cu 38: Cho cc hn hp sau c t l mol bng nhau: (1) BaO v Al2O3; (2) K2O v Al2O3; (3) FeCl3 v Cu; (4) Na
v Zn; (5) Na2O v Zn; (6) Na v ZnO. C bao nhiu hn hp tan ht trong nc?
A. 5 B. 3 C. 4 D. 2
Cu 39: C 4 dung dch ring bit: CuSO4, ZnCl2, FeCl3, AgNO3. Nhng vo mi dung dch mt thanh Ni, s
trng hp xut hin n mn in ho l:
A. 1 B. 2 C. 4 D. 3
Cu 40: Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v
80% th tch N2) n khi phn ng xy ra hon ton, thu c cht rn v hn hp kh Y c thnh phn th
tch: N2 = 84,77%; SO2 = 10,6% cn li l O2. Thnh phn % theo khi lng ca FeS trong X l
A. 68,75% B. 59,46% C. 26,83% D. 42,3%
II. PHN RING (10 cu)
Th sinh c chn lm 1 trong 2 phn (phn A hoc phn B)
Cu 41: Hn hp X gm hiro, propen, propanal, ancol anlylic. t 1 mol hn hp X thu c 40,32 lt CO2
(ktc). un X vi bt Ni mt thi gian thu c hn hp Y c
/
= 1,25. Nu ly 0,1 mol hn hp Y th tc
dng va vi V lt dung dch Br2 0,2M. Gi tr ca V l:
A. 0,25 lt B. 0,1 lt C. 0,2 lt D. 0,3 lt
Cu 42: tch c CH3COOH t hn hp (CH3COOH v C2H5OH) ta dng ho cht no sau y?
A. Na v dung dch HCl B. H2SO4 c
C. Ca(OH)2 v dung dch H2SO4 D. CuO (t
o
) v AgNO3/NH3 d
Cu 43: Ha tan 4,5 gam tinh th MSO
4
.5H
2
O vo nc c dung dch X. in phn dung dch X vi in cc
tr v cng dng in 1,93A. Nu thigian in phn l t (s) th thu c kim loi M catotv156,8 ml
kh ti anot. Nu thigian in phn l 2t (s) th thu c 537,6 ml kh . Bit th tch cc kh o ktc. Kim loi
M v thi gian t lnlt l:
A. Cu v 1400 s B. Cu v 2800 s C. Ni v 2800 s D. Ni v 1400 s
Cu 44: Dy gm cc cht no sau y u c tnh lng tnh ?
A. AlCl3, H2O, NaHCO3, Zn(OH)2, ZnO, H2NCH2COOH, CrO3
B. H2O, Zn(OH)2, HOOC-COONa, H2NCH2COOH, NaHCO3
C. ZnCl2, AlCl3, NaAlO2, NaHCO3, H2NCH2COOH, Al2O3
60 | L O V E B O O K . V N
D. Al, NaHCO3, NaAlO2, ZnO, Be(OH)2
Cu 45: Dung dch X gm KOH 1M, Ba(OH)2 0,75M. Cho t t dung dch X vo 100 ml dung dch Zn(NO3)2 1M
thu c 7,425 g kt ta. Th tch ca dung dch X dng l
A. 50ml hoc 100ml B. 60ml hoc 120 ml C. 600ml hoc 1200ml D. 60 ml hoc 100ml
Cu 46: Cho 9,2 g hp cht hu c X C6H4O phn ng va vi dung dch cha 68 gam AgNO3 trong NH3 thu
c21,6 g Ag kt ta . Cng thc ca X l:
A. CHC-CH(CHO)-CCH B. CHC-CO-CH2-CCH C. CHC-CH=C=CH-CHO D. CHC-CC-CH2-CHO
Cu 47: Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu ipeptit
khc nhau?
A. 3 B. 1 C. 2 D. 4
Cu 48: Dy nhng nguyn liu no sau y c sn trong t nhin
A. olomit, boxit, manhetit, criolit, xenluloz, t tm, cao su t nhin.
B. Xt, vi, boxit, nc Javen, manhetit, cao su buna, xenlulozo triaxetat, bng, t tm.
C. vi, manhetit, bng, t tm, cao su t nhin, nha epoxi.
D. olomit, boxit, manhetit, thy tinh phale, bng, t tm, cao su t nhin.
Cu 49: Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gmH2SO4 0,5M
v NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy
nht). Cho V ml dung dch NaOH 1,5M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu
ca V l
A. 160. B. 240. C. 266,67. D. 80.
Cu 50: S dng dung dch NaOH c th phn bit trc tip dy dung dch no sau y?
A. Na2CO3, HCl, MgCl2, FeCl2 B. HCl, NH4Cl, NaHCO3, MgCl2
C. NH4Cl, MgCl2, AlCl3, HCl D. NH4Cl, ZnCl2, AlCl3, FeCl2
Cu 51: Cho amin X tc dng vi CH3I thu c amin Y bc III c cng thc phn t l C5H13N. Hy cho bit X c
bao nhiu cng thc cu to?
A. 5 B. 3 C. 2 D. 4
Cu 52: Oxi ho 4,48 lt C2H4 ( ktc) bng oxi (xc tc PdCl2, CuCl2), thu c cht X n chc. Ton b lng
cht X trn cho tc dng vi HCN d th c 7,1 gam CH3 CH(CN)OH (xianohirin ). Hiu sut qu trnh to
xianohirin t C2H4 l
A. 60% B. 80% C. 70% D. 50%
Cu 53: Cho X l dung dch HNO2 1M c in li l . Ln lt thm vo 100 ml dung dch X 100 ml cc dung
dch sau: HCl 1M, CH3COOH 1M, Na2CO3 1M, NaCl 1M. S trng hp lm tng in li l:
A. 3 B. 2 C. 4 D. 1
Cu 54: Nung m gam Cu trong oxi thu c hn hp cht rn X c khi lng 24,8g gm Cu2O, CuO, Cu. Ha
tan hon ton X trong dung dch H2SO4 c nng thu c 4,48 lit kh SO2 (ktc). Hy tm gi tr ca m.
A. 22,4 g B. 2,24 g C. 6,4 g D. 32 g
Cu 55: Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau tc dng ht vi lng d
dung dch HCl long, nng thu c dung dch Y v kh H2. C cn dung dch Y thu c 8,98 gam mui khan.
Nu cho m gam hn hp X tc dng hon ton vi O2 (d) to hn hp 3 oxit th th tch kh O2 (ktc) phn
ng l
A. 1,008 lt. B. 0,672 lt. C. 2,016 lt. D. 1,344 lt.
Cu 56: C 5 kh ng ring bit trong 5 l l Cl2, O2, HCl, O3, SO2. Hy chn trnh t tin hnh no trong cc
trnh t sau phn bit cc kh:
A. Qu tm m, dung dch KI/h tinh bt, Cu un nng.
B. Dung dch AgNO3, dung dch KI/h tinh bt, dng u que m cn tn .
C. Nhn bit mu ca kh, dung dch AgNO3, dung dch KI, dng u que m cn tn .
D. Dung dch H2S, dung dch AgNO3, dung dch KI.
Cu 57: Ancol X, andehit Y, axit cacboxylic Z c cng s nguyn t H trong phn t thuc cc dy ng ng
no, n chc mch h. t hon ton hn hp 3 cht ny (c s mol bng nhau) thu c t l mol CO2 : H2O
= 11: 12. Cng thc phn t ca X, Y, Z l:
A. C2H6O, C3H6O, C3H6O2 B. CH4O, C2H4O, C2H4O2 C. C4H10O, C5H10O, C5H10O2 D. C3H8O, C4H8O, C4H8O2
Cu 58: Phn ng no sau y lm thay i mch cacbon?
A. C
6
H
5
CH
3
+Br
2
as
B. C
6
H
5
C
2
H
3
+KMnO
4
+H
2
O
C. C
6
H
6
+Cl
2
askt
D. C
6
H
5
C
2
H
5
+KMnO
4
+H
2
SO
4

Cu 59: e gang trong kho ng khi am ta i ie n c c cacbon xa y ra qua trinh:
A. 2H
+
+ 2e H2 B. Fe Fe
3+
+ 3e
C. Fe Fe
2+
+ 2e D. O2 + H2O + 4e4OH
-

Cu 60: Thy phn 1kg poli(vinylaxetat) trong NaOH. Sau phn ng thu c 800 gam polime. % s mt xch
polime b thy phn l ?
A. 40,95% B. 63,95% C. 61,05% D. 80%

P N
1.C 2.B 3.A 4.D 5.A 6.B 7.C 8.D 9.B 10.A
11.B 12.A 13.C 14.C 15.C 16.A 17.D 18.D 19.C 20.C
21.A 22.A 23.D 24.D 25.C 26.A 27.B 28.C 29.B 30.D
31.D 32.A 33.D 34.C 35.C 36.C 37.B 38.B 39.B 40.B
41A 42.C 43.A 44.B 45.D 46.A 47.C 48.A 49.B 50.C
51.B 52.D 53.B 54.A 55.A 56.C 57.D 58.D 59.D 60.A

62 | L O V E B O O K . V N
s 9

PHN I: Phn chung cho tt c cc th sinh (t cu 1 n cu 40)
Cu 1: Cho s chuyn ho :
C6H5-CH2-CCH
+HCl
X
+HCl
Y
+2NaOH
Z
Trong X, Y, Z u l sn phm chnh. Cng thc ca Z l
A. C6H5CH2CH2 CH2OH. B. C6H5CH(OH)CH2CH2OH. C. C6H5CH2COCH3. D. C6H5 CH2CH(OH)CH3.
Cu 2: t chy hon ton 1 anhit X c n
H
2
O
= n
X
. Trong X hidro chim 2,439% v khi lng. Cho 3,28
gam X phn ng vi lng d AgNO3 trong NH3 c 17,28 gam Ag. Cng thc ca X l:
A. CH2(CHO)2 . B. O=CH-CC-CH=O. C. O=CH-CH=O. D. HCHO.
Cu 3:Cho 20,72 gam hn hp X gm hiroquinon, catechol v phenol tc dng vi kali (d) thu c 3,584
lt (ktc) kh H2. Thnh phn phn trm v khi lng ca phenol trong hn hp X l
A. 38,547%. B. 41,096%. C. 14,438%. D. 36,293%.
Cu 4: Cho cc este: C6H5OCOCH3 (1); CH3COOCH=CH2 (2); CH2=CH-COOCH3 (3); CH3-CH=CH-OCOCH3 (4);
(CH3COO)2CH-CH3 (5). Nhng este no khi thy phn khng to ra ancol?
A. 1 , 2 , 4 , 5 B. 1 , 2 , 4 C. 1 , 2 , 3 D. 1 , 2 , 3 , 4 , 5
Cu 5: Cho t t dung dch cha 0,3 mol HCl vo dung dch cha m gam hn hp X gm K2CO3, NaHCO3 th thy
c 0,12 mol kh CO2 thot ra. Cho dung dch Ca(OH)2 d vo m/2 gam hn hp X nh trn thy c 17 gam kt
ta. Gi tr ca m l
A. 19,14 B. 38,28. C. 35,08. D. 17,54.
Cu 6: Mt este E mch h c cng thc phn t C5H8O2. un nng E vi dung dch NaOH thu c hai sn
phm hu c X, Y, bit rng Y lm mt mu dung dch nc Br2. Co ca c tr ng h psau v X, Y:
1. X l mui, Y l anehit. 2. X l mui, Y l ancol khng no.
3. X l mui, Y l xeton. 4. X l ancol, Y l mui ca axit khng no.
So tr ng h ptho a ma n la :
A. 1 B. 3 C. 2 D. 4
Cu 7: Thy phn 109,44g mantoz trong mi trng axit vi hiu sut phn ng t 60% thu c hn hp
X. Trung ha hn hp X bng NaOH thu c hn hp Y. Cho Y tc dng vi dung dch AgNO3/NH3 d un
nng thu c m gam Ag kt ta. Gi tr ca m l:
Cu 8: Khi lng oleum cha 71% SO3 v khi lng cn ly ha tan vo 100 gam dung dch H2SO4 60%
th thu c oleum cha 30% SO3 v khi lng l:
A. 506,78gam B. 312,56 gam C. 539,68gam D. 496,68gam
Cu 9: t chy hon ton 0,05 mol hn hp X gm hai anehit no, mch h sinh ra 1,792 lt CO2 (ktc). Mt
khc, ton b lng X trn phn ng va vi 0,08 mol H2 (xc tc Ni, t
0
). Cng thc ca hai anehit trong X
l
A. HCHO v O=HC-CH2-CH=O. B. CH3CHO v O=HC-CH=O.
C. HCHO v O=HC-CH=O. D. HCHO v CH3CHO.
Cu 10: Cho 100ml dung dch cha NaOH 1M, KOH 1M v Ba(OH)21,2M vo 100ml dung dch AlCl3 xM th thu
c 9,36 gam kt ta. Vy nu cho 200 ml dung dch NaOH 1,2M vo 100 ml dung dch AlCl3 xM th khi
lng kt ta thu c v gi tr ca x l (bit cc phn ng xy ra hon ton)
A. 11,70 gam v 1,6. B. 9,36 gam v 2,4. C. 6,24 gam v 1,4. D. 7,80 gam v 1,0.
Cu 11: Cho m gam cht bo to bi axit stearic v axit oleic tc dng ht vi dung dch NaOH va thu c
dung dch X cha 109,68 gam hn hp 2 mui. Bit 1/2 dung dch X lm mt mu va 0,12 mol Br2 trong
CCl4. Gi tr ca m l:
A. 132,90. B. 106,32. C. 128,70. D. 106,80.
Cu 12: Cho hn hp gm m gam bt Cu v 27,84gam Fe3O4vo dung dch H2SO4long d thy tan hon ton
thu c dung dch X. oxi ha ht Fe
2+
trong dung dch X cn dng 90 ml dung dch KMnO
4
0,5M. Gi tr ca
m l:
A. 3,36gam. B. 5,12gam. C. 2,56gam. D. 3,20gam.
Cu 13: C cc nhn xt v kim loi kim:
(1)Cu hnh electron lp ngoi cng ca kim loi kim l ns
1
vi n nguyn v 1 < n 7.
(2)Kim loi kim kh H2O d dng nhit thng gii phng H2.
(3)Kim loi kim c cu trc mng tinh th lp phng tm khi nn chng c nhit nng chy, nhit si thp.
(4)Khi cho kim loi kim vo dung dch HCl th kim loi kim phn ng vi dung mi H2O trc, vi axit sau.
(5) Cc kim loi kim khng y c kim loi yu hn ra khi dung dch mui
S nhn xt ng l:
A. 4 B. 3 C. 5 D. 2
Cu 14: Cho s chuyn ha sau:
Ca
3
(PO
4
)
2
+SiO
2
+C,1200
0
C
X
+Ca,t
0

Y
+HCl
Z
+O
2
du
T
X, Y, X, T ln lt l
A. P , Ca3P2, PH3, P2O3. B. P trng, Ca3P2, PH3, P2O5.
C. CaC2, C2H2, C2H3Cl, CO2. D. P, Ca3P2, PH3, P2O5.
Cu 15: Hp th ht V lt kh CO
2
vo dung dch cha 0,42mol Ca(OH)
2
thu c a gam kt ta. Tch ly kt ta,
sau thm tip 0,6V lt kh CO
2
na, thu thm 0,2a gam kt ta.Th tch cc kh o ktc. Gi tr ca V l:
A. 7,84lt. B. 5,60lt. C. 6,72lt. D. 8,40lt.
Cu 16: Thy phn hon ton a gam ipeptit Glu-Gly trong dung dch KOH d, un nng thu c 40,32 gam
hn hp mui. Gi tr ca a l:
Cu 17: Axit no trong s cc axit sau c tnh axit mnh nht:
A. CH3-CCl2-COOH B. CH3-CBr2-COOH C. CH3 -CH2- CCl2-COOH D. CCl2-CH2-COOH
Cu 18:Cho s sau: KCl
pdd,70
(X)
HCl
(Y) .Cc cht X, Y ln lt l:
A. KClO, Cl2. B. K, H2. C. KClO3, Cl2. D. KOH, KCl
Cu 19: Khi thy phn este C7H6O2 trong mi trng axit thu c 2 sn phm hu c X v Y, trong X cho
phn ng trng gng, cn Y khng c phn ng trng gng nhng tc dng vi dung dch Br2 cho kt ta
trng. Cng thc cu to ca este l:
A. CHC-COOCC-C2H5 B. CH3COOCH=CH-CCH
C. HCOOC6H5 D. HCOOCH=CH-CC-CH-CH2
Cu 20: Ha tan hon ton hn hp gm cc kim loi Mg, Al, Zn, Fe, Ni, Cu, Ag vo dung dch HNO3 long (d),
thu c dung dch X. Cho X tc dng vi dung dch NaOH (d), thu c kt ta Y. em Y tc dng vi dung
dch NH3 (d), n phn ng hon ton thu c kt ta Z. S hiroxit c trong Y v Z ln lt l
A. 7 ; 4. B. 3 ; 2. C. 5 ; 2. D. 4 ; 2.
Cu 21: Cho cc cht sau: ivinyl, toluen, etilen, xiclopropan, stiren, vinylaxetilen, propilen, benzen. S cht
lm mt mu dung dch KMnO4 nhit thng l:
A. 4. B. 5. C. 7. D. 6.
Cu 22: Hp cht X c cng thc phn t C3H6, X tc dng vi dung dch HBr thu c mt sn phm hu c
duy nht. Vy X l:
A. ispropen. B. xiclopropan. C. propen. D. propan.
Cu 23: Ha tan hon ton 19,2 gam hn hp X gm Fe, FeO, Fe3O
4
v Fe2O
3
trong 50ml dung dch H2SO4 18M
(c, d,un nng), thu c dung dch Y v V lt kh SO2(ktc v l sn phm kh duy nht). Cho 450 ml dung
dch NaOH 2M vo dung dch Y thuc21,4 gam kt ta. Gi tr caV l:
A. 3,36lt. B. 4,48lt. C. 6,72lt. D. 5,60lt.
Cu 24: Cho phng trnh phn ng: Mg + HNO3 Mg(NO3)2 + NO + N2O + H2O. Nu t khi ca hn hp NO v
N2O i vi H2 l 17,8. T l s phn t b kh v b oxi ha l
A. 14 : 25 B. 11 : 28 C. 25 : 7 D. 28 : 15
Cu 25: Dy no sau y gm cc cht m cu to phn t khng th tha mn quy tc bt t?
A. H2S, HCl B. SO2, SO3. C. CO2, H2O D. NO2, PCl5.
64 | L O V E B O O K . V N
Cu 26:C bao nhiu nguyn t ha hc m nguyn t ca n c electron cui cng in vo phn lp 4s ?
A. 12. B. 9. C. 3. D. 2.
Cu 27:S phn ng n gin nht iu ch nha novolac (dng sn xut bt p, sn) nh sau:
+ nCH
2
=O
n
n
n
CH
2
OH
OH OH
CH
2
OH
H
+
, 75
0
C
- nH
2
O

nha novolac
thu c 21,2 kg nha novolac th cn dng x kg phenol v y kg dung dch fomalin 40% (hiu sut qu
trnh iu ch l 80%). Gi tr ca x v y ln lt l :
A. 11,75 v 3,75. B. 11,75 v 9,375. C. 23,5 v 18,75. D. 23,5 v 7,5.
Cu 28: e hoa tan mo t mau ke m trong dung dich HCl 20
0
C ca n 27 phu t. Cu ng mau ke m o tan het trong dung
dich axit no i tre n 40
0
C trong 3 phu t. e hoa tan het ma u ke m o trong axit no i tre n 45
0
C thi ca n bao nhie u th i
gian?
A. 103,92 gia y B. 60,00 gia y C. 44,36 gia y D. 34,64 gia y
Cu 29: X c cng thc phn t C4H11O2N. Khi cho X tc dng vi dung dch NaOH thu c etyl amin. Vy cng thc phn
t ca X l:
A. CH3COONH3C2H5 B. CH3COONH2C2H5 C. C2H5COOCH2NHCH3. D. HCOONH3C3H7
Cu 30: Nhng nhn xt no trong cc nhn xt sau l ng?
(1) Metylamin, imetylamin, trimetylamin v etylamin l nhng cht kh mi khai kh chu, c.
(2) Cc amin ng ng ca metylamin c tan trong nc gim dn theo chiu tng ca khi lng phn t.
(3) Anilin c tnh baz v lm xanh qu tm m.
(4) Lc baz ca cc amin lun ln hn lc baz ca amoniac.
A. (1), (2). B. (2), (3), (4). C. (1), (2), (3). D. (1), (2), (4).
(1)Trong dung dch,tng nng cation dng bng nng cc ion m.
(2)Dy cc cht: CaCO
3
,HBr v NaOH u l cc cht in ly mnh.
(3)Trong 3 dung dch cng pH l HCOOH, HCl v H
2
SO
4
, dung dch c nng ln nht l HCOOH.
(4)Phn ng axit-baz xy ra theo chiu to ra cht c tnh axit v baz yu hn.
(5)Phn ng trao i ion trong dung dch khng km theo s thay i s oxi ha.
S pht biu ng l:
A. 2 B. 3 C. 4 D. 5
Cu 32: Thm dung dch brom ln lt vo 4 mu th cha cc dung dch: fructoz, saccaroz, mantoz, h
tinh bt. Mu th c kh nng lm mt mu dung dch brom l:
A. dung dch fructoz. B. dung dch mantoz.
C. dung dch saccaroz. D. dung dch h tinh bt.
Cu 33: Cho m gam Mgvo dung dch cha 0,1mol AgNO3v 0,25mol Cu(NO3)2, sau mt thi gian thu c
19,44 gam kt ta v dung dch X cha 2 mui. Tch ly kt ta, thm tip 8,4gam bt st vo dung dch X, sau
khi cc phn ng hon ton thu c 9,36 gam kt ta. Gi tr ca m l:
Cu 34: X l hp cht thm c cng thc phn t C7H8O2 tc dng vi dung dch Br2 to ra c dn xut
tribrom. X tc dng c vi dung dch NaOH theo t l mol 1: 1. S ng phn ca X l:
A. 2 B. 6 C. 5 D. 4
Cu 35: Cho bt nhm d vo axit X long, un nng thu c kh Y khng mu, nng hn khng kh v dung
dch Z. Cho dung dch NaOH n d vo dung dch Z, un nng. Sau phn ng hon ton, thy thot ra kh T
(khng mu, i mu qu tm m sang xanh). Axit X v kh Y l:
A. HNO
3
v N
2
. B. H
2
SO
4
v H
2
S. C. HNO
3
v N2O. D. HCl v H2.
Cu 36: Cho a gam P2O5vo dung dch cha a gam KOH, thu c dung dch X. Cht tan c trong dung dch X
l:
A. KH2PO
4
v H
3
PO
4
B. K
2
HPO
4
v K
3
PO
4
C. KH2PO4v K2HPO
4
D. K
3
PO
4
v KOH
Cu 37: Phn ng no sau y mch polime b thay i?
A. Cao su Isopren + HCl B. PVC + Cl2
as

C. PVA + NaOH
t
0

D. Nha Rezol
t
0

Cu 38:Cho cc phn ng:
(1) FeCO3 + H2SO4c
t
0

kh X + kh Y + (4) FeS + H2SO4long kh G +
(2) NaHCO3 + KHSO4 kh X + (5) NH4NO2
t
0

kh H +
(3) Cu + HNO3(c)
t
0

kh Z + (6) AgNO3
t
0

kh Z + kh I +
Trong cc cht kh sinh ra cc phn ng trn, s cht kh tc dng vi dung dch NaOH l:
A. 4. B. 6. C. 3. D. 5.
Cu 39: Dy cc dung dch no sau y, khi in phn (in cc tr, mng ngn) c s tng pH ca dung dch
?
A. NaOH, KNO
3
,KCl. B. NaOH, CaCl
2
,HCl. C. CuSO
4
,KCl, NaNO
3
. D. KCl, KOH, KNO
3
.
Cu 40:Trong cc th nghim sau, th nghim no khng to ra NaHCO3?
A. Sc CO2 vo dung dch natriphenolat. C. Sc CO2 vo dung dch bo ha cha NaCl v NH3.
B. Sc CO2 vo dung dch Na2CO3. D. Cho dung dch NaOH vo Ba(HCO3)2.
PHN II: Phn cho th sinh theo chng trnh c bn t cu 41 n cu 50
Cu 41: Cho cc dung dch sau: NH4NO3 (1), KCl (2), K2CO3 (3), CH3COONa (4), NaHSO4 (5), Na2S (6). Cc dung
dch c kh nng lm i mu phenolphtalein l:
A. (4), (5) B. (3), (5) C. (2), (3) D. (3), (4), (6)
Cu 42: X c cng thc phn t l C4H8Cl2. Thy phn X trong dung dch NaOH un nng thu c cht hu
c Y c kh nng tc dng vi Cu(OH)2. Hy cho bit X c bao nhiu cng thc cu to tha mn tnh cht
trn?
A. 3 B. 5 C. 2 D. 4
Cu 43: Cho m gam bt Zn vo 500ml dung dch Fe2(SO
4
)
3
0,24M. Sau khi cc phn ng xy ra hon ton, khi
lng dung dch tng thm 9,6 gam so vi khi lng dung dch ban u. Gi tr ca m l
A. 32,50. B. 48,75. C. 29,25. D. 20,80.
Cu 44: Dy gm cc cht c th iu ch trc tip c axeton l:
A. C2H5OH, CH3CHO, CH3COOH C. C6H5CH(CH3)2, CH3CH2CH2OH, HCOOCH3
B. C2H5OH, CH3CH=CHBr, C6H5CH(CH3)2 D. CH3CHOHCH3, (CH3COO)2Ca, CH2=CBr-CH3
Cu 45: Pht biu no sau y l sai?
A. Thic c th dng ph ln b mt ca st chng g.
B. Ch (Pb) c ng dng ch to thit b ngn cn tia phng x.
C. Km c ng dng bo v v tu bin bng thp.
D. Nhm l kimloi dn in tt hn vng.
Cu 46: C th dng dung dch NH3 phn bit 2 dung dch mui no sau y?
A. CuSO4 v ZnSO4. B. NH4NO3 v KCl. C. MgCl2 v AlCl3. D. NaCl v KNO3.
Cu 47: hiro ho hon ton 0,035mol hn hp X gm hai anehit c khi lng 2,2 gam cn 1,568 lt
H
2
(ktc). Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch AgNO
3
trong NH
3

th thu
c 10,8 gam Ag. Cng thc cu to ca hai anehit trong X l
A. H-CHO v OHC-CH
2
-CHO. B. CH
2
=C(CH
3
)-CHOv OHC-CHO.
C. OHC-CH
2
-CHOv OHC-CHO. D. CH
2
=CH-CHOv OHC-CH
2
-CHO.
Cu 48: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y
(cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn
gi ca X l
A. but-2-en. B. xiclopropan. C. but-1-en. D. propilen.
Cu 49: Au (vng) c th tan trong dung dch no sau y?
66 | L O V E B O O K . V N
A. HNO3 bc khi B. KCN c mt khng kh. C. H2SO4 m c
D. HCl bc khi.
Cu 50: Ancol v amin no sau ycngbc?
A. (C
6
H
5
)
2
NHv C
6
H
5
CH
2
OH. B. C
6
H
5
NHCH3v C
6
H
5
CH(OH)CH
3
.
C. (CH
3
)3COHv (CH
3
)3C NH
2
. D. (CH
3
)2CHOHv (CH
3
)2CHNH
2
.
PHN III: Phn cho th sinh theo chng trnh nng cao t cu 51 n cu 60
Cu 51: Trong qu trnh hot ng ca pin in ho Zn Cu th
A. nng ca ion Zn
2+
trong dung dch tng. C. khi lng ca in cc Cu gim.
B. nng ca ion Cu
2+
trong dung dch tng. D. khi lng ca in cc Zn tng.
Cu 52: Ch dng qu tm c th nhn bit c bao nhiu dung dch trong s cc dung dch sau ng trong
cc l mt nhn: Na2CO3, NaCl, NaOH, HCl, BaCl2, KNO3?
A. 3. B. 6. C. 1 D. 4
Cu 53: Nung m gam K2Cr2O7 vi S d thu c hn hp cht rn X. Ha tan hon ton X vo nc, lc b
phn khng tan ri thm BaCl2 d vo dung dch thu c 27,96 gam kt ta. Gi tr ca m l:
Cu 54: Cho cc cht sau: KMnO4, O2/Mn
2+
, H2/Ni, t
o
, dung dch Br2/CCl4, Cu(OH)2/NaOH, t
o
, HCN, HCl,
AgNO3/NH3. S cht c kh nng phn ng c vi CH3CHO l:
A. 8 B. 7 C. 5 D. 6
Cu 55: Cho kh CO i qua ng s ng 37,12 gam Fe3O4 nung nng thu c hn hp rn X. Kh i ra khi
ng s c hp th ht vo dung dch Ba(OH)2 d thu c 43,34 gam kt ta. Ha tan ht lng hn hp X
trong dung dch H2SO4 c nng, d thy bay ra V lt SO2 (ktc). Gi tr ca V l:
A. 4,48 B. 3,584 C. 3,36 D. 6,72
Cu 56: ipeptit X, hexapeptit Y u mch h v cng c to ra t 1 amino axit no, mch h trong phn t
c 1 nhm -NH2 v 1 nhm -COOH. Cho 13,2 gam X tc dng ht vi dung dch HCl d, lm kh cn thn dung
dch sau phn ng thu c 22,3 gam cht rn. Vy khi t chy hon ton 0,1 mol Y th cn t nht bao nhiu
mol O2 nu sn phm chy thu c gm CO2, H2O, N2 ?
A. PVA bn trong mi trng kim khi un nng
B. T olon c sn xut t polome trng ngng.
C. T nilon -6 c iu ch bng phn ng ng trng ngng hexametylen iamin vi axit aipic.
D. ng trng hp buta-1,3-ien vi acrylonitrin c cao su buna-N.
Cu 58: Cho 14,8 gam hn hp X gm 2 ancol n chc A v B (MA< MB) tc dng Na d thu c 3,36 lt hiro
(ktc). Oxi ha cng lng hn hp X c hn hp anehit Y. Cho ton b lng Y phn ng ht vi lng
d dung dch AgNO3 trong NH3 thu c 86,4 gam Ag. B c s ng phn ancol l
A. 3 B. 1 C. 4 D. 2
Cu 59: Hn hp M gm mt anehit v mt ankin (c cng s nguyn t cacbon). t chy hon ton x mol
hn hp M, thu c 3x mol CO
2
v 1,6x mol H
2
O. Cho 0,1 mol hn hp M tc dng vi dung dch AgNO3/NH3
d thu c y mol Ag. Gi tr ca y l:
A. 0,06. B. 0,04. C. 0,08. D. 0,02.
Cu 60: Phn ng no sau y khng thuc phn ng t oxi ho, t kh ?
A. 3S + 6NaOH
t
0

Na2SO3 + 2 Na2S + 3H2O B. 2NO2 + 2NaOH NaNO3 + NaNO2 + H2O
C. 2KClO3
t
0
,xt
2KCl + 3O2 D. Cl2 + 2KOH KCl + KClO + H2O

P N

1.C 2.B 3.D 4.A 5.B 6.B 7.B 8.A 9.C 10.C
11.B 12.A 13.A 14.D 15.C 16.A 17.A 18.C 19.C 20.D
21.D 22.B 23.C 24.A 25.D 26.D 27.C 28.A 29.A 30.A
31.C 32.B 33.C 34.A 35.C 36.C 37.D 38.A 39.B 40.D
41.D 42.B 43.D 44.D 45.D 46.A 47.D 48.C 49.B 50.B
51.A 52.D 53.A 54.D 55.D 56.B 57.D 58.B 59.C 60.C

68 | L O V E B O O K . V N
s 10

Cu 1: Nung nng 5,4 gam Al vi 3,2 gam S trong mi trng khng c khng kh; phn ng hon ton thu
c hn hp rn X; cho hn hp X tc dng vi dung dch H
2
SO
4
long d thu c hn hp kh Y. em t
hon ton hn hp Y cn va V lt O
2
( ktc). V lt O
2
( ktc) cn dng l
A. 11,2 lt B. 5,6 lt C. 13,44 lt D. 2,8 lt
Cu 2: Ha tan hon ton Fe
3
O
4
vo dung dch H
2
SO
4
long d c dung dch A. Dung dch A tc dng vi
dy cht no sau y?
A. . KMnO
4
, HNO
3
, Cu, HCl, BaCl
2
, K
2
Cr
2
O
7
, NaNO
3
. B. K
2
Cr
2
O
7
, Br
2
, H
2
S, KI, NaNO
3
, NH
4
Cl, Cu
C. K
2
Cr
2
O
7
, Fe, Cl
2
, KI, KNO3, (NH
4
)
2
SO
4
, Cu. D. KMnO
4
, HNO
3
, Cu, KI, BaCl
2
, K
2
Cr
2
O
7
, KNO
3
.
Cu 3: ha tan ht hn hp X gm Cr2O3, CuO ; Fe3O4 cn va 550 ml HCl 2M, sau phn ng thu c
dung dch Y. Mt na dung dch Y ha tan ht ti a 2,9 gam Ni. C cn na dung dch Y cn li thu c bao
nhiu gam mui khan ?
Cu 4: Cho s chuyn ha sau ( cc iu kin phn ng c )
(1)X(C
4
H
6
O
2
Cl
2
) + NaOH B +D +E +H
2
O (2) D +O
2
F (3)E +H
2
O NaOH +G +H
(4) G +H I (5)G +F K +I (6) K +NaOH B +E
X c cng thc cu to no sau y?
A. CH
3
COOCCl
2
CH
3
B. CH
3
COOCHClCH
2
Cl
C. CH
3
COOCH
2
CHCl
2
D. CH
2
ClCOOCHClCH
3

Cu 5: Hn hp X gm 0,1 mol anehit metacrylic v 0,3 mol kh hiro. Nung nng hn hp X mt thi gian,
c mt cht xc tc Ni, thu c hn hp hi Y gm hn hp cc ancol, cc anehit v hiro. T khi hi ca Y
so vi He bng 95/12. Mt khc dn ton b hn hp Y qua dung dch nc Br2 th lm mt mu va a mol
Br2. Gi tr ca a l
Cu 6: C cc cht sau : keo dn ure-fomanehit; t lapsan; t nilon-6,6; protein; si bng; amoniaxetat; nha
novolac; t nitron. Trong cc cht trn, c bao nhiu cht m trong phn t ca chng c cha nhm NH-
CO-?
A. 4 B. 6 C. 3 D. 5
Cu 7: Hiro ha hon ton hirocacbon mch h X ( k c ng phn hnh hc) thu c butan. S cht X
tha mn l
A. 9 B. 10 C. 7 D. 6
Cu 8: t hon ton 11,68 gam hn hp X gm CH
3
COOH; C
x
H
y
COOH; CH
2
(COOH)
2
thu c a gam H
2
O
v 18,04 gam CO
2
.Nu cho hn hp X tc dng hon ton vi NaHCO
3
d th thu c 4,256 lt CO
2
ktc). Gi
tr ca a l
Cu 9: Nung nng n phn ng hon ton m1 gam C
4
H
10
thu c hn hp X gm C2H4, C2H6, C3H6, CH4. Hp
th t t X vo bnh cha dung dch . KMnO
4
d, thy khi lng bnh tng m2 gam. t chy ht hn hp kh
Y i ra khi dung dch . KMnO
4
thu c 5,6 lt CO
2
(ktc) v 8,1 gam H
2
O. Gi tr ca m1, m2 ln lt l
A. 14,5 v 7,7. B. 11,2 v 7,8. C. 11,6 v 3,9. D. 11,6 v 7,7.
Cu 10: t chy hon ton 3,48 gam mt hirocacbon X (cht kh iu kin thng) ri em ton b sn
phm chy hp th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn ng thu c 29,55 gam kt ta v
khi lng dung dch gim bt 13,59 gam. Cng thc phn t ca X l
A. CH4 B. C2H4 C. C3H4 D. C
4
H
10

Cu 11: Hn hp X gm propan-1-ol, propan-2-ol; ancol anlylic; etyl metyl ete; metyl vinyl ete, glixerol. t m
gam hn hp X cn V lt oxi ( ktc), thu c 5,2416 lt CO
2
(ktc). Mt khc, m gam hn hp X lm mt mu
ti a 4,48 gam brom hay ha tan ti a 0,686 gam Cu(OH)2. Gi tr ca V l
A. 7,2352 lt B. 7,1680 lt C. 7,4144 lt D. 7,3696 lt
Cu 12: un nng m gam hn hp Cu v Fe c t l khi lng tng ng 3 : 7 vi mt lng dung dch HNO
3
.
Khi cc phn ng kt thc, thu c 0,8m gam cht rn, dung dch X v 3,36 lt hn hp kh (ktc) gm NO v
N2O (khng c sn phm kh khc ca N
5+
). Bit lng HNO
3
phn ng l 56,7 gam. Gi tr ca m l
Cu 13: Hai nguyn t A v B ng k tip nhau trong cng mt chu k ca bng tun hon, c tng s n v
in tch ht nhn l 23, s n v in tch ht nhn ca B ln hn A . Kt lun no sau y v A v B l khng
ng?
A. Tnh kim loi ca A mnh hn
B. A, B thuc chu k 3 trong bng tun hon
C. Cu hnh electron ca A khng c electron c thn no
D. Cu hnh electron ca B khng c electron c thn
Cu 14: Hirocacbon mch h X trong phn t ch cha lin kt ; tng s lin kt l 25 v c 2 nguyn t
ccbon bc bn trong phn t. Khi Cho X tc dng vi Cl2( theo t l 1:1), s dn xut monoclo ti a sinh ra l:
A. 1 B. 3 C. 4 D. 2
Cu 15: Dung dch X cha 0,01 mol H2N-CH2COOCH3; 0,02 mol ClH3N-CH2COONa v 0,03 mol
HCOOC6H4OH. tc dng ht vi dung dch X cn ti a V ml dung dch NaOH 0,5M un nng thu c dung
dch Y. Gi tr ca V l
A. 280. B. 160. C. 240. D. 120.
Cu 16: Hn hp A gm CuSO4, FeSO4 v Fe2(SO4)3 c % khi lng ca S l 22%. Ly 50 gam hn hp A ha
tan vo nc v cho tc dng vi mt lng va dung dch NaOH thu c kt ta B. Lc v nung B trong
khng kh n khi lng khng i c cht rn D. Dn lung kh CO d i qua D nung nng n phn ng
hon ton ta c m gam cht rn E. Gi tr ca m l
A. 20. B. 19. C. 17. D. 18.
Cu 17: t chy hon ton m gam hn hp X gm hai este ng phn cn dng 4,704 lt kh O2, thu c
4,032 lt kh CO
2
v 3,24 gam H
2
O. Nu cho m gam X tc dng ht vi 110 ml dung dch KOH 1M, c cn dung
dch sau phn ng th thu c 7,98 gam cht rn khan, trong c a mol mui Y v b mol mui Z ( M-Y>MZ).
Cc th tch kh u iu kin chun. T l a:b l
A. 2:3 B. 2:1 C. 1:5 D. 3: 2
Cu 18: Cho s chuyn ha sau: C
3
H
9
O
2
N
+NaOH
X
+HNO
3

+CuO,t
0

Z
+AgNO
3
/NH
3
T
+HCl
CO
2

C
3
H
9
O
2
N l cht no sau y?
A. HCOONH2(CH3)2 B. CH3COONH
3
CH3 C. HCOONH
3
C2H5 D. C2H5COONH4
(1)Dn kh F2 vo dung dch NaOH long; lnh (2) Cho Ca3P2 vo nc
(3) Cho NH
3
tip xc vi CrO3 (4) Cho Ag2O vo H
2
O
2

(5) Cho H
2
SO
4
long vo dung dch Na2S2O3 (6)Cho SiO2 vo Na2CO3 nng chy
S th nghim to ra cht kh l
A. 4 B. 6 C. 3 D. 5
Cu 20: Np mt hn hp kh c 20% th tch hirocacbon A v 80% th tch O2 (d) vo kh nhin k. Sau khi
cho n ri cho hi nc ngng t nhit ban u th p sut trong kh nhin k gim cn 0,6 ln. Cng thc
phn t ca A l
A. CH4 B. C
3
H
8
C. C2H6 D. C
4
H
10

Cu 21: Cho cc phn t : H2, CO
2
, Cl2, N2, I2, CO; C2H4, C2H2. Bao nhiu phn t c lin kt ba trong phn t ?
A. 3 B. 1 C. 2 D. 4
Cu 22: Khi pin in ha Zn- Ag phng in c cu mui NH4Cl th
A. ion NH
4+
B. ion NH
4+
di chuyn v in cc Zn
C. ion NH
4+
D. ion NH
4+
Cu 23: Pht biu no sau y ng?
A. Tt c cc phn ng ca nit vi kim loi u cn un nng.
B. Silicagen c dng lm cht ht m v hp ph nhiu cht.
C. CrO3 tc dng vi nc to ra axit cromic.
D. Trong cng nghip, photpho c sn xut t qung canxit.
Cu 24: Cho s phn ng sau: Phtpho
+X
Y
+H
2
O
Z
t
0

T
t
0

J
70 | L O V E B O O K . V N
Cht Y v J ln lt l
A. P2O5; HPO3 B. Zn3P2; H3PO3 C. P2O3; H4P2O7 D. PCl5; H3PO4
(a) Tt c cc cacbohirat u c phn ng thy phn
(b) Khi thu phn hon ton hn hp gm tinh bt; xenluloz v saccaroz trong mi trng axit, ch thu
c mt loi monosaccarit duy nht.
(c) C th phn bit glucoz v fructoz bng phn ng vi dung dch brm hay dung dch AgNO
3
trong NH
3

(d) Trong dung dch, glucoz ; fructoz; saccaroz v mantoz u ha tan Cu(OH)2 nhit thng cho
dung dch mu xanh lam.
(e) Trong dung dch, fructoz tn ti ch yu dng mch vng (vng ).
(g) Trong dung dch, glucoz tn ti ch yu dng mch h.
S pht biu ng l
A. 1. B. 3. C. 4. D. 2.
Cu 26: Cho cc cht sau y - Hirocacbon C
6
H
10
(X) c x ng phn tc dng vi dung dch AgNO
3
/NH
3
to
kt ta mu vng nht -Ancol thm C
8
H
10
O (Y) c y ng phn oxi ha tham gia phn ng trng gng
C
6
H
10
O
4
(Z) l este 2 chc c mch cacbon khng phn nhnh c z ng phn tc dng vi NaOH cho mt
mui mt ancol - Amin C
4
H
11
N (T) c t ng phn tc dng vi HCl to mui c dng RNH
3
Cl ( R l gc
hirocacbon) Mi quan h ng gia x, y, z, t l
A. x = y; z = t. B. x = z; y = t. C. x > y = z > t. D. x = y = z = t.
Cu 27: in phn dung dch hn hp cha 0,04 mol AgNO
3
v 0,05 mol Cu(NO3)2, in cc tr, dng in
5A, trong 32 pht 10 giy. Khi lng kim loi bm vo catot l:
Cu 28: Sc kh CO
2
vo cc dung dch ring bit cha cc cht: Na[Al(OH)4]; NaOH d, Na2CO3, NaClO, CaCO3,
CaOCl2, Ca(HCO3)2; CaCl2. S trng hp c xy ra phn ng ha hc l
A. 8. B. 5. C. 6. D. 7.
Cu 29: C cc tp hp cc ion sau y : (1). NH
4+
; Na
+
; HSO
3
; OH
(2). Fe
2+
; NH
4+
; NO
3
; SO
4
2

(3) Na+; Fe
2+
; H+ ; NO
3
(4)Cu
2+
; K
+
; OH
; NO
3
( 5) H
+
; K
C bao nhiu tp hp c th tn ti ng thi trong cng mt dung dch?
A. 2 B. 1 C. 4 D. 3
Cu 30: Kt lun no sau y ng?
A. in phn dung dch CuSO
4
vi anot ng, nng Cu
2+
trong dung dch khng i
B. t l st trong kh Cl
2
xy ra n mn in ha
C. Thanh km nhng trong dung dch CuSO
4
khng xy ra n mn in ha
D. Kim loi c tnh kh, n b kh thnh ion dng
Cu 31: Cho cc phng trnh phn ng sau y:
(1) SO
2
+ dung dch KMnO
4
(4) C
2
H
4
+ dung dch KMnO
4

(2) HCl + dung dch KMnO
4
(5) C
2
H
2
+ dung dch KMnO
4

(3) KMnO
4

t
0

(6) C
6
H
5
CH
3
+ dung dch KMnO
4
t
0

S phng trnh khng to sn phm MnO
2
l
A. 4 B. 3 C. 1 D. 2
Cu 32: Cho m gam hn hp X gm Na, Ca, K tc dng vi H
2
O thu c dung dch Y v kh H2. Cho ton b
lng H2 thu c tc dng vi CuO, t
0
d . Sau phn ng cho lng H
2
O thu c hp th vo 63 gam dung
dch H
2
SO
4
90% th thy C% ca dung dch H
2
SO
4
cn 70%. Cho ton b dung dch Y vo dung dch cha 0,6
mol AlCl
3
thu c m gam kt ta. Cc phn ng xy ra hon ton. Gi tr ca m l
A. 46,8 B. 15,6 C. 27,3 D. 31,2
Cu 33: Hn hp X gm ancol etylic, imetylete; butan-1,2-iol; butan-2,3-iol; butan-1,3-iol.t m gamhn
hp X, thu c 26,88 lt CO
2
(ktc). Cho m gam hn hp X tc dng vi natri d thu c 5,824 lt H2 (ktc).
Khi lng imetylete c trong m gam hn hp X l
A. 4,14 g B. 3,45g C. 3,68g D. 3,22g
Cu 34: Cho cc cp cht sau: (1)Ba(HSO
3
)
2
+ NaOH (2)Fe(NO
3
)
2
+ HCl (3)NaCl + H
2
SO
4
(4)KCl
+ NaNO3 (5) Fe(NO
3
)
2
+ AgNO
3
(6)NH4Cl + NaNO2 (7)AgNO
3
+ H2S (8) KI +FeCl
3
(9)Br
2
+
I
2
+ H
2
O (10)F
2
+ N
2
(11) Mg + SiO
2
(12)C + H
2
O
S cp cht xy ra phn ng trong dung dch; cht rn v dung dch; cc cht kh hay cc cht rn vi iu kin
thch hp l:
A. 8 B. 7 C. 10 D. 9
Cu 35: Cho 1,2 lt hn hp gm hiro v clo vo bnh thu tinh y kn v chiu sng bng nh sng khuch
tn. Sau mt thi gian ngng chiu sng th thu c mt hn hp kh cha 30% hiroclorua v th tch v
hm lng ca clo gim xung cn 20% so vi lng clo ban u. Thnh phn phn trm v th tch ca
hiro trong hn hp ban u bng
A. 66,25% B. 30,75% C. 88,25% D. 81,25%
Cu 36: C cc kt qu so snh sau:
(1) Tnh axit : H2SiO3 > H2CO3. (2)
Tnh oxi ha: Fe
3+
> Cu
2+
.
(3) Tnh kh: HCl > HF. (4) Tnh phi kim: Si
14
> N
7
> O
8
.
(5) Bn knh nguyn t: K
19
> Mg
12
> Al
13
. (6) Tnh dn in Cu > Ag.
(7) Tnh do: Au > Fe. (8) Nhit nng chy Na > Hg.
(9) Tnh cng: Cr > Ag.
S kt qu so snh ng l
A. 5. B. 7. C. 6. D. 4.
Cu 37: Cho x mol hn hp kim loi Al, Fe ( c t l mol 1:1) tan ht trong dung dch cha y mol HNO
3
(t l
x:y= 3:17). Sau khi kim loi tan ht , thu c sn phm kh Y duy nht v dung dch Z ch cha mui nitrat.
Cho AgNO
3
n d vo Z, thu c m gam rn. Gi tr ca m l:
A. 54y/17 B. 27y/17 C. 108y/17 D. 432y/17
Cu 38: Hin tng no sau y ng?
A. Pht pho trng pht quang mu lc nht trong bng ti nhit thng.
B. Cho Cu vo HNO
3
long xut hin kh mu nu; dung dch c mu xanh
C. Dn kh NH
3
qua cht rn CuO mu nung nng thy xut hin cht rn mu en v c hi nc
D. Cho dung dch NH
3
n d vo dung dch CuSO
4
thy xut hin kt ta mu xanh.
Cu 39: Hn hp X gm HCHO ; CH
3
COOH; HCOOCH
3
v CH
3
CH(OH)COOH. t chy hon hn X cn V lt O
2

(ktc) sau phn ng thu c CO
2
v H
2
O. Hp th ht sn phm chy vo nc vi trong d thu c 15
gam kt ta. Vy gi tr ca V l
A. 3,92 lt B. 3,36 lt C. 4,2 lt D. 2,8 lt
Cu 40: Mt bnh kn cha hn hp X gm 0,07 mol axetilen; 0,09 mol vinylaxetilen; 0,18 mol H2 v mt t bt
Ni. Nung hn hp X thu c hn hp Y gm 7 hirocacbon c t khi hi so vi H2 l 21,4375. Cho ton b
hn hp Y i qua bnh ng dung dch AgNO
3
/NH
3
d, thu c m gam kt ta vng nht v 2,24 lt hn hp
kh Z ( ktc) gm 5 hirocacbon thot ra khi bnh. Hn hp Z mt mu va ht 80 ml dung dch Br2 1M. Cc
phn ng xy ra hon ton. Gi tr ca m l
A. 12,78. B. 13,59. C. 11,97. D. 11,16.
Cu 41: ha tan mt ming km trong dung dch HCl 20
0
C cn 27 pht. Nu thc hin th nghim 40
0
C
th thi gian phn ng l 3 pht.Nu thc hin th nghim 55
0
C th thi gian phn ng l:
A. 44,36 giy B. 34,64 giy C. 64,43 giy D. 43,64 giy
Cu 42: C bao nhiu tn ph hp vi cng thc cu to (1). H2N-CH2-COOH : Axit aminoaxetic. (2). H2N-
[CH2]5-COOH : Axit w - aminocaporic. (3). H2N-[CH2]6-COOH: Axit e - aminoenantoic. (4). HOOC-[CH2]2-
CH(NH2)-COOH: Axit a - aminoglutaric. (5). H2N-[CH2]4-CH (NH2)-COOH : Axit a,e - aminocaporic.
A. 3 B. 5 C. 4 D. 2
Cu 43: Xt cn bng trong bnh kn c dung tch khng i X
(kh)
2Y
(kh)

Ban u cho 1 mol kh X vo bnh; khi t cn bng th thy:
- 400C trong bnh kn c 0,75mol X
- 450C trong bnh kn c 0,65 mol X
C cc pht biu sau :
72 | L O V E B O O K . V N
(1) Phn ng thun l phn ng thu nhit
(2) Khi tng p sut, cn bng chuyn dch theo chiu nghch
(3) Thm tip Y vo hn hp cn bng th cn bng chuyn dch theo chiu nghch
(4) Thm xc tc thch hp va hn hp cn bng th cn bng vn khng chuyn dch
S pht biu ng l:
A. 3 B. 2 C. 1 D. 4
Cu 44: Loi thuc no sau y thuc loi gy nghin cho con ngi ?
A.Vitamin C ; glucoz B.Senduxen, moocphin
C.Penixilin ; amoxilin D.Thuc cm pamin, paradol
Cu 45: Cho cc pht biu sau v anilin.
(1) Anilin l cht lng; rt c, tan nhiu trong nc.
(2)Anilin c tnh baz nhng dung dch ca n khng lm i mu qu tm.
(3) Nguyn t H ca vng benzen trong anilin d b thay th hn nguyn t H trong benzen v u tin th vo
v tr meta.
(4)Anilin dng sn xut phm nhum, polime, dc phm.
(5) Nh nc brom vo dung dch anilin thy xut hin kt ta trng.
(6)Anilin l amin bc II
S pht biu ng l
A. 2 B. 5 C. 3 D. 4
Cu 46: Ho tan 4,8 gam Cu vo 250 ml dd NaNO3 0,5 M, sau thm vo 250ml dd HCl 1 M. Kt thc phn ng
thu c dung dch X v kh NO duy nht. Phi thm bao nhiu ml dung dch NaOH 1 M vo X kt ta ht
ion Cu
2+
.
A. 250 ml. B. 300 ml C. 200 ml D. 400 ml
Cu 47: C cc cht benzyl clorua, clobenzen, anlyl clorua, vinyl clorua; etylclorua. S cht c th tham gia phn
ng thy phn trong dung dch NaOH long (t0) l
A. 3 B. 4 C. 1 D. 2
Cu 48: Tripeptit M v tetrapeptit Q c to t mt amino axit X mch h (phn t ch cha 1 nhm
NH2).Phn trm khi lng nito trong X bng 18,667%. Thy phn khng hon ton m gam hn hp M,Q ( c
t l s mol 1:1) trong mi trng axit thu c 0,945 gam M; 4,62 gam ipeptit v 3,75 gam X. Gi tr ca m
l
Cu 49: t chy hon ton m gam cht bo X (cha triglixerit ca axit stearic,axit panmitic v cc axit bo t
do ). Sau phn ng thu c 6,72 lt CO
2
(ktc) v 5,22 gam nc. X phng ho m gam X (hiu sut = 90%)
th thu c khi lng glixerol l
Cu 50: Cho dung dch X cha x mol FeCl
2
v x mol NaCl vo dung dch cha 4x mol AgNO
3
thu c 53,85
gam kt ta v dung dch Y. Khi lng cht tan c trong dung dch Y l
A. 37,77 B. 32,7 C. 38,019 D. 54,413

P N

1.B 2.D 3.B 4.D 5.D 6.C 7.B 8.B 9.D 10.D
11.A 12.C 13.C 14.A 15.C 16.C 17.C 18.B 19.B 20.A
21.A 22.B 23.B 24.A 25.D 26.D 27.A 28.C 29.B 30.A
31.D 32.D 33.C 34.C 35.D 36.C 37.A 38.A 39.B 40.C
41.B 42.D 43.D 44.B 45.C 46.C 47.A 48.C 49.A 50.B
51.B 52.D 53.A 54.B 55.C 56.A 57.B 58.B 59.A 60.D

LI GII CHI TIT V BNH LUN
Cu 1: p n B
{
0,2 mol Al
0,1 mol S
t
o
X
+H
2
SO
4
l
[
Y{
H
2
H
2
S
+O
2
{
H
2
O
SO
2
{
Al
3+
SO
4
2

Gi s mol O
2
phn ng l x.
Bo ton electron ta c: 3n
Al
3+ +4n
S
= 2n
O
3.0,2 +4.0,1 = 2.2x x = 0,25(mol).
Vy V
O
2

= 5,6(l)
Cu 2: p n D
Dung dch A cha cc ion SO
4
2
; Fe
3+
; Fe
2+
nn c th c cc phn ng ca c 3 ion trn.
Cu 3: p n B
Gi s mol ca Cr
2
O
3
; CuO v Fe
3
O
4
ln lt l a , b, c (mol)
Dd Y c 2a mol CrCl
3
; b mol CuCl
2
; c mol FeCl
2
; 2c mol FeCl
3
6a +2b +8c = n
Cl
= 1,1 (1)
Khi cho Ni vo na dung dch th c cc phn ng:
Fe
3+
+e Fe
2+
Cu
2+
+2e Cu Ni Ni
2+
+2e
2n
Ni
= 2n
Cu
2+ +n
Fe
3+ 2c +2b = 0,2
Thay vo (1) a +c = 0,15
Khi lng oxit ban u l:
m
oxit
= 152a +80b +232c = 152(0,15 c) +80b +232c = 22,8 +80(b +c) = 30,8(g)
Vy m
mui
trong
1
2
dung dch Y l:
m =
1
2
(m
oxit
m
O
+m
Cl
) =
1
2
(30,8 0,55.16 +1,1.35,5) = 30,525(g)
Cu 4: p n D
Ta c: E: NaCl; D: CH
3
CHO; B: CH
2
(OH)COONa; F: CH
3
COOH; G: Cl
2
; H: H
2
; I: HCl; K: CH
2
(Cl)COOH
Ch phn ng (3) l phn ng in phn dung dch. Cc phn ng cn li khng phc tp tuy nhin
lm bi ny ta phi th cc p n v cc trng hp ca cc cht cha xc nh mi tm p n
ng.
Cu 5: p n D
X gm 0,1 mol CH
2
C(CH
3
)CHO v 0,3 mol H
2
.
m
X
= m
Y
= 7,6(g) n
Y
=
m
Y
M
Y
= 0,24(mol)
n = 0,4 0,24 = 0,16(mol) = n
H
2
phn ng

Li c: n
H
2
phn ng
+n
Br
2
phn ng
= 2n
anehit
= 0,2(mol). Vy a = 0,04(mol)
Cu 6: p n C
Cc cht m trong phn t ca chng c cha nhm NH CO l: t lapsan; t nilon-6,6; protein.
Cu 7: p n B
X c th c 1 lin kt i; 1 lin kt ba; 2 lin kt i; 2 lin kt ba hoc 1 lin kt i v 1 lin kt ba.
Cu 8: p n B
n
COOH
= 0,19(mol); n
CO
2
(trong phn ng t)
= 0,41(mol)
Bo ton nguyn t ta c: n
O trong X
= 0,38(mol); n
C trong X
= 0,41(mol)
Bo ton khi lng c: m
X
= m
O
+m
H
+m
C
m
H
= 0,68(g) n
H
= 0,68(mol).
Vy n
H
2
O
= 0,34(mol) a = 6,12(g)
Cu 9: p n D
n
CO
2
= 0,25(mol); n
H
2
O
= 0,45(mol) m
Y
= m
C
+m
H
= 3,9(g)
Ta c khi lng bnh tng ln chnh l khi lng ca C
2
H
4
v C
3
H
6
cn Y gm CH
4
v C
2
H
6
.
Ta c n
Y
= n
C
4
H
10
= n
H
2
O
n
CO
2
= 0,2(mol) m
1
= 11,6(g)
Bo ton khi lng ta c: m
1
= m
2
+m
Y
m
2
= 7,7(g)
Cu 10: p n D
74 | L O V E B O O K . V N
n
BaCO
3

= 0,15(mol). Gi n
CO
2

= x(mol); n
H
2
O
= y(mol)
Khi lng dung dch gim l: m = m
BaCO
3
m
H
2
O
m
CO
2
44x +18y = 15,96
(V bi khng cho dung dch Ba(OH)2 d nn ta cha bit tt c lng CO2 sinh ra t phn ng t
chy c to kt ta hay khng)
C: m
X
= m
H
+m
C
12x +2y = 3,48. Vy {
x = 0,24
y = 0,3
{
n
C
= 0,24
n
H
= 6
C
4
H
10

Cu 11: p n A
n
CO
2
= 0,234(mol); n
Br
2
= 0,028(mol); n
Cu(OH)
2
= 0,007(mol)
Ta thy cc cht trong X u c 3 nguyn t C nn n
X
= 0,078(mol)
n
lin kt i trong X
= n
Br
2
= 0,028(mol); n
glixerol
= 2n
Cu(OH)
2
= 0,014(mol)
Trong X, tr glixerol th cc cht cn li u c 1 nguyn t O
n
O trong X
= 0,078 0,014 +0,014.3 = 0,106(mol)
Li c: n
H
2
O
n
CO
2
= n
X
n
lin kt i trong X
n
H
2
O
= 0,284(mol)
Bo ton nguyn t O ta c: 2n
O
2
phn ng
+n
O trong X
= 2n
CO
2
+n
H
2
O
n
O
2
phn ng
= 0,323(mol).
Vy V = 7,2352(l)
Cu 12: p n C
n
kh
= 0,15(mol); n
HNo
3
= 0,9(mol). t n
NO
= x(mol); n
N
2
O
= y(mol) x +y = 0,15
Sau phn ng cn 0,8m gam cht rn nn mi c 0,2m gam l Fe phn ng. V kim loi cn d nn
sn phm cui cng sau phn ng l mui Fe(II)
Bo ton electron ta c: 2n
Fe phn ng
= 3x +8y
B ton nguyn t N ta li c: n
HNO
3
= 2n
Fe(NO
3
)
2
+n
NO
+2n
N
2
O
4x +10y = 0,9
{
x = 0,1
y = 0,05
n
Fe phn ng
= 0,35(mol) m
Fe phn ng
= 0,2m = 19,6(g). Vy m = 98(g)
Cu 13: p n C
Gi s n v in tch ht nhn ca A v B l a,b (b > a) a +b = 23
b a = 1 {
a = 11
b = 12
(cng thuc chu k 3 tha mn)
b a = 2 {
a = 10
b = 13
(khng cng thuc 1 chu k khng tha mn)
Tng t vi cc trng hp khc. Nh vy ta ch thu c 1 kt qu tha mn l A l Na v B l Ca.
Vy kt lun khng ng l cu hnh electron ca A khng c electron c thn no.
Cu 14: p n A
X ch cha lin kt n nn X l ankan. t X l C
n
H
2n+2

Tng s lin kt = s ha tr ca H+s lin kt (C C) = (2n +2) +(n 1) = 3n +1 = 2
n = 8
X c 2 nguyn t C bc 4 nn CTCT ca X l (CH
3
)
3
C C(CH
3
)
3
. Khi cho X tc dng vi Cl
2
(1: 1) th
ch thu c 1 dn xut monoclo duy nht.
Cu 15: p n C
n
NaOH
= n
H
2
NCOOCH
3
+n
ClH
3
NCOONa
+3n
HCOOC
6
H
4
OH
= 0,12(mol) V = 240(ml)
Cu 16: p n C
A{
CuSO
4
FeSO
4
Fe
2
(SO
4
)
3
ha vo nc;+NaOH
B{
Cu(OH)
2
Fe(OH)
2
Fe(OH)
3
lc,nung trong khng kh
D{
CuO
Fe
2
O
3
+CO d
E{
Cu
Fe
m
E
= m
ion kim loi trong A

%m
S
= 22% %m
SO
4
= 66% %m
ion kim loi trong A
= 34%. Vy m = 17(g)
Cu 17: p n C
n
O
2
= 0,21(mol); n
H
2
O
= 0,18(mol); n
CO
2
= 0,18(mol); n
KOH
= 0,11(mol)
n
CO
2
= n
H
2
O
2 este u no, n chc, mch h trong mi este c 2 nguyn t O.
Bo ton nguyn t O ta c: 2n
este
+2n
O
2
= 2n
CO
2
+n
H
2
O
n
este
= 0,06(mol) = n
KOH phn ng

n
KOH d
= 0,05(mol)
Cht rn thu c gm mui khan v KOH d m
mui
= 5,18(g) M
mui
= 86,33
M este c 3 C nn 2 mui ch c th l HCOOK(b mol) v CH
3
COOK ( a mol)
{
a +b = 0,06
84b +98a = 5,18
{
a = 0,01
b = 0,05
a: b = 1: 5
Cu 18: p n B
T phi l (NH
4
)
2
CO
3
Z l HCHO Y: CH
3
OH X: CH
3
NH
2
. Vy cht cn tm l CH
3
COONH
3
CH
3
.
Cu 19: p n B
(1): OF
2
; (2)PH
3
; (3): N
2
; (4): O
2
; (5): SO
2
; (6): CO
2

Cu 20: p n A
Da vo p n ta thy cc cht u l ankan nn t CTPT ca A l C
n
H
2n+2

Gi s n
A ban u
= 1; n
O
2
= 4
n
CO
2
= n; n
H
2
O
= n +1; n
O
2
phn ng
= n +
n +1
2
; n
O
2
cn li
= 4 n
n +1
2

Sau khi ngng t nc ta c:
P
sau
P
trc
=
n
CO
2
+n
O
2
cn li
1 +5
=
4
n +1
2
5
= 0,6 n = 1.
Vy A l CH
4

Cu 21: p n A
Cc phn t c lin kt ba trong phn t l: N
2
; C
2
H
2
; CO
Cu 22: p n B
Cu 23: p n B
A sai v phn ng ca N2 v Li xy ra nhit thng.
C sai v CrO3 tc dng vi nc to thnh hn hp axit cromic v axit icrommic. Nhng trong mi
trng axit nn dng ch yu l axit icrommic.
D sai v photpho c sn xut t qung photphoric.
Cu 24: p n A
Cu 25: p n D
Cc pht biu ng l: d, e
Cu 26: p n D
Ta c cc c im:
X c lin kt 3 u mch x = 4 Y l ancol thm bc 1 y = 4
Z l este i xng, khng phn nhnh z = 4 T l amin bc 1 t = 4
Vy x = y = z =t.
Cu 27: p n A
n
e trao i
=
It
F
= 0,1(mol). Khi in phn hn hp bi cho th qu trnh in phn catot s theo th t:
Ag
+
+1e Ag
Cu
2+
+2e Cu
Vy khi lng kim loi bm vo catot l: m = 0,04.108 +
0,1 0,04
2
. 64 = 6,24(g)
Cu 28: p n C
Cc trng hp c xy ra phn ng ha hc l khi sc kh CO
2
vo:
Na[Al(OH)
4
]; NaOH d; Na
2
CO
3
; NaClO; CaCO
3
; CaOCl
2

Cu 29: p n B
Tp hp c th tn ti ng thi trong cng mt dung dch l: (2)
(1) khng c v c phn ng NH
4
+
+OH
NH
3
+H
2
O
(3) khng c v c phn ng Fe
2+
+H
+
+NO
3
Fe
3+
+NO +H
2
O
(4) khng c v c phn ng Cu
2+
+2OH
Cu(OH)
2

(5) khng c v khng cn bng in tch.
Cu 30: p n A
Cu 31: p n D
Cc phng trnh khng to sn phm l MnO
2
l: (1); (2)
Cu 32: p n D
76 | L O V E B O O K . V N
m
H
2
SO
4
= 56,7(g) m
dung dch H
2
SO
4
70%
= 81(g) m
H
2
O thm vo
= 18(g)
n
H
2
= 1(mol) n
OH
= 2n
H
2
= 2(mol)
Ta d dng tm c n
Al(OH)
3
= 0,6 (2 0,6.3) = 0,4(mol) m = 31,2(g)
Cu 33: p n C
n
CO
2
= 1,2(mol); n
H
2
= 0,26(mol) n
OH
= 2n
H
2
= 0,52(mol) (1)
Ta thy cc cht trong hn hp X u c s nguyn t C gp i s nguyn t O
n
O trong X
= 0,6(mol) (2)
(1);(2) n
imetylete
= 0,08(mol) m
imetylete
= 3,68(g)
Cu 34: p n C
Cc cp cht xy ra phn ng l: (1); (2); (3); (5); (6); (7); (8); (9);(11);(12)
Cu 35: p n D
H
2
+Cl
2
2HCl
Ta thy sau phn ng th tch ca hn hp vn khng thay i v bng 1,2 (l)
V
HCl
= 0,36(mol) V
Cl
2
phn ng
= 0,18 (mol) = 80% V
Cl
2
ban u

V
Cl
2
ban u
= 0,225(mol) %V
H
2
ban u
= 81,25%
Cu 36: p n C
Cc kt qu so snh ng l: (2); (3); (5); (7); (8); (9)
Cu 37: p n A
Cho x = 3; y = 17 n
Fe
= n
Al
= 1,5(mol)
Khi cho AgNO3 vo dung dch Z th to thnh cht rn do c phn ng Ag
+
+Fe
2+
Ag +Fe
3+

Gi n
Ag
= a. Bo ton e t u n cui cng ta c: 3n
Fe
+3n
Al
= n
Ag
+n
electron m N trao i

n
electron m N trao i
= 9 a(mol)
Dung dch cui cng c Fe(NO
3
)
3
; Al(NO
3
)
3
trong c a mol NO
3
do mui AgNO
3
cung cp
Bo ton nguyn t N ta c: n
HNO
3
= y = 17 = n
N trong kh
+n
N trong mui
= x(9 a) +(9 a)
Trong x l t l gia s nguyn t N trong phn t kh v s e m mt phn t kh trao i.
C 0 < a < 1,5
8
9
< x <
19
15
D thy ch c x = 1 tha mn a = 0,5 m = 54 =
54y
17

Cu 38: p n A
B: kh mu nu ha nu trong khng kh (NO)
C: CuO mu en, Cu mu
D: xut hin kt ta mu xanh sau kt ta tan to thnh dung dch phc mu xanh m.
Cu 39: p n B
Cc cht trong hn hp X c CTPT chung l: C
n
H
2n
O
n

n
CO
2
= n
H
2
O
= n
CaCO
3
= 0,15(mol) n
O
2
phn ng
= 0,15(mol). Vy V = 3,36(l)
Cu 40: p n C
m
X
= 6,86(g) = m
Y
n
Y
= 0,16(mol) n = n
H
2
phn ng
= 0,18(mol)
H
2
phn ng ht nn trong Y cn C
2
H
2
( a mol) v C
4
H
4

n
Z
= 0,1(mol) a +b = 0,06 (mol)(1)
Li c: n
Br
2
= 0,08(mol)
n
lin kt i trong X
= 2.0,07 +3.0,09 = 0,41 = n
H
2
phn ng
+n
Br
2
+2a +3b 2a +3b = 0,15 (2)
T , (2) {
a = 0,03
b = 0,03

Vy kt ta gm 0,03 mol C
2
Ag
2
v 0,03 mol C
4
H
3
Ag m = 11,97(g)
Cu 41: p n B
Ta thy khi nhit tng 2O
o
C th vn tc tng 9 ln hay thi gian gim 3
2
ln.
Ta c khi nhit tng x
o
C th thi gian gim 3
x
10
ln.
Vy ta tnh c thi gian phn ng 55
O
C l: 34,64 giy
Cu 42: p n D
Cc trng hp tn ph hp vi cng thc l: (1); (4)
Cu 43: p n D
Ta thy khi tng nhit th cn bng dch chuyn theo chiu nghch nn phn ng thun l phn
ng thu nhit.
Cc pht biu ng l: (1); (2); (3); (4)
Cu 44: p n B
Cu 45: p n C
Cc pht biu ng l: (2); (4); (5)
Cu 46: p n C
n
Cu
= 0,075(mol); n
H
+ = 0,25(mol); n
NO
3
= 0,125(mol)
Ta c phn ng: 3Cu +8H
+
+2 NO
3
3Cu
2+
+2NO +4H
2
O
Cu phn ng ht. n
H
+
d
= 0,05 (mol). Vy n
NaOH
= 0,075.2 +0,05 = 0,2(mol) V = 200 (ml)
Cu 47: p n A
Cc cht c th tham gia phn ng thy phn trong dung dch NaOH long (t
o
) l : benzyl clorua, anlyl
clorua, etyl clorua.
Cu 48: p n C
M
X
= 75 X: H
2
NCH
2
COOH M: C
6
H
11
O
4
N
3
; Q: C
8
H
14
O
5
N
4

Sau khi thy phn ta thu c: n
M
= 0,005(mol); n
ipeptit
= 0,035(mol); n
X
= 0,05(mol)
Tng s mol gc X l: 3.0,005 +2.0,035 +0,05 = 0,135 (mol) n
M
= n
Q
=
27
1400

Vy m = 8,389 (g)
Cu 49: p n A
n
CO
2
= 0,3(mol); n
H
2
O
= 0,29(mol)
V mt phn t cht bo bi cho c 3 lin kt i 2n
cht bo
= n
CO
2
n
H
2
O
= 0,01(mol)
Vy n
glyxerol
= 0,0005(mol) m = 0,414(g)
Cu 50: p n B
Kt ta thu c gm x mol Ag v 3x mol AgCl 108x +143,5.3x = 53,85 x = 0,1(mol)
Trong dung dch Y cn x mol NaNO
3
v x mol Fe(NO
3
)
3
. Vy m = 32,7 (g)
Cu 51: p n B
t n
X
= a; n
Y
= 3a
Cht rn Z gm 2a mol mui Ala; 4a mol mui Gly; 7a mol mui Val
2a. 111 +4a. 96 +139.7a = 25,328 a = 0,016
Vy m = 18, 16 (g)
Cu 52: p n D
Cu 53: p n A
n
H
2
O
= 0,17(mol); n
CO
2
= 0,14(mol) n
C
2
H
5
OH
= 0,03(mol)
t n
C
2
H
5
COOH
= x; n
CH
3
CHO
= y {
x +y = 0,03
3x +2y +0,03.2 = 0,14
{
x = 0,02
y = 0,01

Trong 13,2 g hn hp X ta c: n
C
2
H
5
OH
= 0,12(mol); n
C
2
H
5
COOH
= 0,08(mol); n
CH
3
CHO
= 0,04(mol)
Vy n
Ag
= 0,08(mol) m = 8,64(g)
Cu 54: p n B
Cc cht v ion va c tnh oxi ha, va c tnh kh l: Cl
2
; SO
2
; NO
2
; C; Fe
2+

Cu 55: p n C
Oleum c cng thc tng qut l H
2
SO
4
. nSO
3
oleum cha 71% SO
3
v khi lng lH
2
SO
4
. 3SO
3

Nu ta coi y l dung dch H
2
SO
4
th C%=
4.98
98 +3.80
= 115,98%
Tng t nu oleum cha 30% SO3 v khi lng l dung dch H
2
SO
4
th C%= 106,75%
Ta s dng s ng cho vi C% th s tnh c m
Oleum
cha 71% SO
3
v khi lng cn ly
l: 506,78 (g)
Cu 56: p n A
Ch c phn ng (4) l khng xy ra.
Cu 57: p n B
Xt trong 13,44(l) hn hp kh. Ta c: n
X
= 0,6(mol); n
C
2
H
2
= n
= 0,15(mol)
78 | L O V E B O O K . V N
Xt trong 8,6 (g) hn hp X. t n
C
2
H
2
= a(mol); n
C
2
H
4
= b; n
CH
4
= c
{
a +b +c = 4a
26a +28b +16c = 8,6
2a +b = n
Br
2
= 0,3
{
a = 0,1
b = 0,1
c = 0,2
%V
CH
4
= 50%
Cu 58: p n B
m
CO
2
= 20 6,8 = 13,2(g) n
CO
2
= 0,3(mol) n
glu
= 0,25(mol) m = 45(g)
Cu 59: p n A
m
X
= m
Y
= 5,8(g) n
Y
= 0,2(mol) n
H
2
phn ng
= 0,2 (mol)
Vy n
Br
2
= 0,1(mol) m = 16(g)
Cu 60: p n D
Gi CTPT ca aminoaxit l: C
n
H
2n+1
O
2
N X: C
2n
H
4n
O
3
N
2
; Y: C
3n
H
6n1
O
4
N
3

Ta d dng tnh c n = 3. Vy m = 60 (g)


s 11

Cu 1. Hp cht X to bi kim loi M ha tr khng i v S. Ly 13g X chia lm 2 phn. Phn 1 tc dng vi
O
2
c kh Y. Phn 2 tc dng vi HCl d c kh Z. Trn 2 kh Y v Z c 7,68 gam cht rn mu vng,
cn 1 kh mi trng ung thot ra tc dng va vi dd CuCl
2
thu c 1,92 gam kt ta en. Tm X?
A. ZnS B. Al
2
S
3
C. CuS D. MgS
Cu 2. Cho phn ng: FeS
2
+H
2
SO
4
Fe
2
(SO
4
)
3
+SO
2
+H
2
O
T l gia s phn t H
2
SO
4
b kh v khng b kh l
A. 11/3 B. 3/11 C. 1/5 D. 5/1
Cu 3. Cho 6,975 g photpho vo bnh kn cha V lt O
2
v Cl
2
c M
= 49,875 thu c 21,9375 gam hn hp X

gm 4 cht rn. Ha tan X vo nc d c dung dch Y. Trung ha va dung dch Y cn x mol NaOH. Gi
tr ca x l
A. 0,0657 B. 0,575 C. 0,85 D. 0,725
Cu 4. Ha tan hon ton m gam Al
2
(SO
4
)
3
vo nc c 100ml dung dch X c nng C(M). Thm vo
dung dch X dung dch NaOH 1 M, cho ti khi tng nng cht tan trong dung dch thu c l C/2 th thy
ht 2,1 lt. Xc nh m
A. 51,3 B. 34,2 C. 85,5 D. 68,4
Cu 5. Ha tan hon ton m gam Fe bng dung dch HNO
3
thu c dung dch X v 1,12 lt NO (ktc). Thm
dung dch cha 0,1 mol HCl vo dung ch X th thy kh NO tip tc thot ra v thu c dung dch Y. phn
ng ht vi cc cht trong dung dch Y cn 115ml dung dch NaOH 2M. Gi tr ca m l:
A.3,36 B.3,92 C. 2,8 D.3,08
Cu 6. t chy hon ton hn hp gm FeS
2
v Ag
2
S vi s mol bng nhau thu c 3,696 lt SO
2
(ktc) v
cht rn B. Cho B tc dng vi dd H
2
SO
4
long d, sau phn ng hon ton thy cn li m gam cht rn khng
tan. Gi tr ca m l:
A. 13,64 B.17,16 C. 11,88 D. 8,91
Cu 7. Cho dung dch AgNO
3
tc dng vi dd cht X thy to kt ta T mu vng. Cho kt ta T tc dng vi dd
HNO
3
d thy kt ta tan. Cht X l:
A. KCl B. K
3
PO
4
C. KI D. KBr
Cu 8. Cho cc phn ng sau:
(1) Ha tan qung pirit st vo dd axit H
2
SO
4
c nng thu c kh X
(2) Nhit phn qung dolomit thu c kh Y
(3) Nhit phn dd amoni nitrit bo ha thu c kh Z
(4) Ha tan st sunfua vo dd H
2
SO
4
long thu c kh T
Kh gy ra hin tng ma axit v hiu ng nh knh trong cc kh trn theo th t l:
A. X v Y B. X v Z C. Y v Z D. Y v T
Cu 9. Khng nh no sau y l sai ?
A. Este l sn phm thu c khi thay th H trong nhm COOH ca axit hu c bng gc ankyl ca ru
B. Este c mi thm v khng tan trong nc
C. Este ca glyxerol vi axit bo gi chung l cht bo
D. Este no, 2 chc, h c CTPT C
n
H
2n2
O
4
(n 4).
Cu 10. X phng ha 15,3 gam mt este no, n chc cn dng va 300ml dung dch NaOH nng 0,5
mol/l. Sau phn ng thu c 12,3 gam mui. S ng phn cu to ca este l:
A. 3 B. 2 C. 4 D. 5
Cu 11. Dng CuO nung nng oxi ha hon ton 9,2 gam hn hp hi X bng 2 ancol thuc cng dy ng ng,
thu c hn hp Y khng lm i mu qu tm m. Cho ton b Y sc vo dung dch AgNO
3
/NH
3
va , lc
b kt ta thu c dung dch Z. Cho 100ml dung dch Ba(OH)
2
1M phn ng vi Z un nng thy va v
trong dung dch khng cn ion Ba
2+
. Tm cng thc cu to ca 2 ancol . Bit lng CO
2
thu c khi t chy
ton b hn hp hi Y trn l 8,96 lt (ktc).
A. C
2
H
5
OH v CH
3
CH
2
CH
2
OH B. CH
3
OH v CH
3
CH(OH)CH
3

C. CH
3
OH v CH
3
CH
2
OH D. C
2
H
5
OH v CH
3
OH
80 | L O V E B O O K . V N
Cu 12. X l hn hp hi ca H
2
hai andehit no, n chc, h c cng s nguyn t C. Cho X qua bt Ni nung
nng n khi phn ng hon ton thu c hn hp hi Y c th tch l 11,2 l(ktc). Thu ly ton b cc ancol
trong Y em tc dng vi Na thu c V lt H
2
. Gi tr ln nht ca V l bao nhiu bit d
X
Y
= 5/7.
A. 2,24l B. 4,48l C. 5,6l D. 1,12l
Cu 13. Cho V lt kh CO
2
(ktc) hp th ht trong dd cha 0,2 mol Ba(OH)
2
v 0,1 mol NaOH. Sau phn ng
thu c kt ta v dung dch c cha 21,35 gam mui. Gi tr ca V tng ng l:
A. 8,96 B. 7,84 C. 6,72 D.8,4
Cu 14. Ha tan m gam hn hp NaHCO
3
v Na
2
CO
3
vo nc c dung dch X. Cho t t 100ml dd hn hp
HCl 0,4M v H
2
SO
4
0,3M vo dung dch X, khuy u thu c 0,896 lt CO
2
(ktc) v dd Y. Cho dd Y tc dng
vi mt lng d dd Ba(OH)
2
thu c 18,81 gam kt ta. Cc phn ng xy ra hon ton. Gi tr ca m l:
A. 9,72 B. 11,4 C. 9,28 D. A hoc C u ng.
Cu 15. C cc nhn nh sau:
1) Andehit va c tnh kh, va c tnh oxi ha
2) Khi b kh bi AgNO
3
/NH
3
, andehit chuyn thnh mui amoni ca axit hu c
3) Xeton kh b oxi ha cn andehit th rt d b oxi ha
4) Khi cho axit fomic tc dng vi AgNO
3
/NH
3
ta khng thu c kt ta
5) Andehit lm mt mu cam ca brom lng
6) Oxi ha andehit c th thu c axit cacboxylic
7) Axit salixilic c cng thc phn t l C
7
H
6
O
3

S nhn nh ng l :
A. 4 B. 5 C. 2 D. 3
Cu 16. phn bit cc dung dch glucozo, glixerol, andehit axetic, ancol etylic v lng trng trng ta dng
A. NaOH B. AgNO
3
/NH
3
C. Cu(OH)
2
D. HNO
3

Cu 17. S pht biu ng l?
1) Amino axit l hp cht hu c tp chc
2) Trng hp cc aminoaxit ta thu c chui polypeptit
3) Cng thc tng qut ca amin no, mch h, n chc l C
n
H
2n+3
N(n 1)
4) Tnh baz ca anilin C
6
H
5
NH
2
yu hn .
5) Thy phn c th thu c ti a 3 loi ipeptit
6) C th phn bit anilin, benzen, C
2
H
5
OH ch bng mt thuc th
A. 4 B. 5 C. 2 D. 3
Cu 18. Hp cht hu c A c cng thc phn t l c vi dung dch NaOH, dung dch HCl v lm mt mu
dd Brom. Cng thc cu to ca A l:
A. CH
3
CH(NH
2
)COOH B. CH
2
= CHCOONH
4
C. HCOOCH
2
CH
2
NH
2
D. H
2
NCH
2
CH
2
COOH
Cu 19. Hn hp A gm mt tripeptit v mt i peptit c cu to t mt loi duy nht
+) Cho m gam A thy phn hon ton trong dung dch H
2
SO
4
long va thu c (m+24,1)gam mui.
+) Cho m gam A thy phn hon ton trong dung dch NaOH long va thu c (m+13,3)gam mui.
Gi tr ca m l bao nhiu. Bit khi t chy hon ton , sau cho sn phm chy qua bnh cha P
2
O
5
khan
th thy khi lng bnh tng ln 6,75 gam.
Cu 20. Cho hn hp A gm FeO, CuO, Fe
2
O
3
, Fe
3
O
4
.A tc dng va vi 540ml dung dch HCl 1M. Cho hn
hp A qua kh NH
3
va , t nng thu c V(l) kh sau phn ng (khng tnh hi nc). Tnh V
A. 1,792 (l) B. 2,24(l) C. 2,016 (l) D. 2,464 (l)
Cu 21. Thy phn m gam hn hp X gm mantozo v saccarozo trong mi trng axit. Gi s hiu sut thy
phn mi cht l 80%. Hn hp thu c sau khi trung ha ht axit d em phn ng vi AgNO
3
/NH
3
d thu
c 90,72 gam kt ta. Mt khc m/2 gam X phn ng va vi 750ml dung dch Brom 0,1M. Tm m?
A. 68,4 g B. 83,3625 g C. 85,5 g D. 75,24 g
Cu 22. Cho nhng polime sau y: cao su buna, nha bakelit, cao su lu ha, xenlulozo, nilon 6, PVC, amilozo.
S polime c cu trc mng khng gian l:
A. 1 B. 2 C. 3 D. 4
Cu 23. Cho cc phn ng sau y:
1) NH
4
NO
3
t
0
3) K
2
Cr
2
O
7
t
0
5) Cl
2
+NH
3
t
0
7) H
2
O
2
+KI
2) CaOCl
2
+HCl 4) (NH
4
)
2
Cr
2
O
7
t
0
6) Cl
2
+H
2
S
dd
8) NH
4
Cl +NaNO
2

S phn ng to ra n cht l:
A. 4 B. 5 C. 7 D. 3
Cu 24. Cho cc axit sau: HClO, HClO
2
, HClO
3
, HClO
4
. Pht biu ng l
A. Theo chiu t tri sang, tnh axit gim dn B. Theo chiu t phi sang, tnh oxi ha tng dn
C. Cc axit c nhit si ngang nhau D. Tt c u sai.
Cu 25. Cho hn hp A gm 0,05 mol axetilen, 0,08 mol vinyl axetilen v 0,1 mol kh hidro qua bt Ni un nng,
sau phn ng thu c hn hp B gm 7 hidrocacbon. Cho B qua dung dch AgNO
3
/NH
3
d thu c m gam
kt ta vng. Hn hp kh C thot ra gm 5 hidrocacbon c th tch l 1,568 lt (ktc) , C tc dng va vi
800 ml dd brom 0,1M. Gi tr m bng?
A. 8,14 B. 11,16 C. 11,97 D. 4,07
Cu 26. Este X c M = 180 c to thnh t 2 axit cacboxylic l ng ng lin tip ca nhau. Bit X c phn
ng trng bc v X tc dng vi NaOH theo t l 1:4. Cho 0,1 mol X tc dng vi 500ml dung dch KOH 1 M.
Tnh khi lng cht rn to thnh sau phn ng:
A. 36,8 (g) B. 48(g) C. 34,8 (g) D. 42,4(g)
Cu 27. Cho s phn ng : (X)C
5
H
10
A
+NaOH
B C D
+NaHCO
3
(1;2)
E
Xc nh s CTCT ca X tha mn
A. 1 B. 2 C. 3 D. 4
Cu 28. Cho cht hu c X c CTPT: C
4
H
6
Cl
2
. un X trong nc si ri sau cho vo dung dch AgNO
3
d thu
c 62,875 (g) kt ta. Khi cho kh d, xc tc Ni, qua X th thy tng ln 0,25 (g). Xc nh s CTCT tha mn
ca X
A. 3 B. 4 C. 5 D. 6
. Cho s chuyn ha sau: C
4
H
8
+Br
2
X
+NaOH,t
0
Y
Bit Y khng ha tan c Cu(OH)
2
. Tn gi ca cht c CTPT C
4
H
8
ban u:
A. but - 1- en B. but 2 en C. xyclobutan D. metyl xiclopropan
Cu 30. C bao nhiu cht c th tham gia phn ng trng hp? stiren, etilen oxit, acrilonitrin, butadiene, metyl
metacrylat, benzen, caprolactam, toluen, axit etanoic, 1,1,2,2 tetra floeten.
A. 4 B. 8 C. 6 D. 7
Cu 31. t chy 0,45g cht hu c A ri cho ton b sn phm qua bnh nc vi trong th c 112 ml kh nito
(ktc) thot ra khi bnh, khi lng dung dch gim 0,49g v c 2 g kt ta trng. CTPT ca A l:
A. C
2
H
7
N B. CH
3
NH
3
NO
3
C. CH
5
N D. CH
3
COONH
4

Cu 32. Cho cc cht sau: s cht phn ng vi dd brom to kt ta l bao nhiu? hidroquinon, 1,2-ihidroxyl
benzen, anilin, toluen, benzen, ancol benzylic, axit benzoic, axit salixilic.
A. 4 B. 5 C. 6 D. 7
Cu 33. Pht biu ng l?
82 | L O V E B O O K . V N
1. Phenol c tnh axit mnh hn etanol v nhn benzen ht electron ca nhm -OH bng hiu ng lin hp, trong
khi nhm y e vo nhm OH.
2. Phenol c tnh axit mnh hn etanol minh ho bng phn ng phenol tc dng vi NaOH cn etanol th khng.
3. Tnh axit ca phenol yu hn do phenol khng phn ng vi.
4. Phenol t tan trong nc lnh v khng gy bng khi ri vo da.
5. Phenol tc dng vi axit hu c to este tng ng.
6. Ngun phenol ch yu l sn phm ly t chng ct than .
S p n ng l:
A. 2 B. 3 C. 4 D. 5
Cu 34. Cho cc cht sau: Na
2
CO
3
, K
3
PO
4
, (NH
4
)CO
3
, H
2
S, Ca(OH)
2
, MgSO
4
, Na
2
SO
4
.
C bao nhiu cht c th s dng lm mm nc cng:
A. 2 B. 3 C. 4 D. 5
Cu 35. Cho 3 mui nitrat X, Y, Z c s mol bng nhau. Nhit phn hon ton X, Z u to cht rn mu en. em
cht rn cho vo dung dch HCl d th thy cn mt lng cht khng tan. Nhit phn hon ton Y thu c
1,7 (g) mt cht rn mu trng. Nu em t cht rn th thy ngn la c mu tm. Khi in phn dung dch
mui ca X th thu c kim loi khng tan trong HCl. Tnh tng th tch kh to thnh khi nhit phn c 3 mui
X, Y, Z
A. 1,568 (l) B. 2,016(l) C. 1,344(l) D. 2,688(l)
Cu 36. Cho a mol FeCl
2
tc dng vi AgNO
3
thu c gam cht rn. Cng cho a mol FeCl
2
a mol tc dng vi 2a
mol Al thu c m
2
gam cht rn. Cc phn ng xy ra hon ton. T l m
1
: m
2
l:
A. 4,1 B. 4,2 C. 4,3 D. 4,4
Cu 37. Nung 0,12 mol Fe(NO
3
)
2
trong chn khng, thu c cht rn X v hn hp kh Y. Thm Y 1,12 lt O
2
(ktc)
ri sc ton b hn hp kh vo nc d, c dung dch Z. Ha tan X vo Z thy c a gam cht rn khng tan. Gi
tr ca a l:
A. 1,6 B. 3,2 C. 4,8 D. 0,8
Cu 38. Cho 8,06 gam oxit ca kim loi kim tc dng vi H
2
SO
4
d, c cn dung dch thu c 18,46 gam mui.
Kim loi kim l:
A. Li B. K C. Na D. Cs
Cu 39. Nguyn t nguyn t M c 5e phn lp d (trng thi c bn). S nguyn t tha mn l
A. 1 B. 2 C. 3 D. 4
Cu 40. Phn ng no sau y ng ?
A. KHS +BaCl
2
KCl +HCl +BaS
B. H
2
O +2F
2
2HF +OF
2

C. 3Na
2
S +2AlCl
3
+3H
2
O 6NaCl +2Al(OH)
3
+3H
2
S
D. SiO
2
+HF H
2
SiO
3
+F
2

Cu 41. Cho cc cht sau: HCOOH, glucozo, BaSO
4
, NaCl, HNO
3
, HF, ancol etylic, H
2
O, NH
3
, HClO, FeS, Mg(OH)
2

Trong cc cht trn c my cht l cht in li yu?
A. 5 B. 6 C. 7 D. 8
Cu 42. Cho cht hu c sau:
H
2
N CH
2
CO NH C
2
H
4
CO NH CH(CH
2
NH
2
) CO NHCH(CH
2
)
2
(COOH) CO NH
CH
2
CH(COOH) CH
3

Cht hu c trn c my lin kt peptit
A. 0 B. 1 C. 2 D. 4
Cu 43. trung ha lng axit t do c trong 14g mt mu cht bo cn 15ml dung dch KOH 0,1M. Ch s axit
ca mu cht bo trn l:
A. 5,5 B. 7,2 C. 4,8 D. 6,0
Cu 44. Cho hn hp X gm 2 andehit n chc c t l s mol l 2:3. Chia X thnh 2 phn bng nhau:
+) Phn 1 tc dng vi dung dch AgNO
3
/NH
3
d thu c 37,8(g) kt ta
+) Phn 2 tc dng va vi 12 (g) Br
2
trong dung mi CCl
4
. Nu cho hn hp X ban u tc dng vi dung dch
nc Br
2
d th thy c m(g) Br
2
phn ng v to thnh V(l) kh. Tnh m, V
A. 40(g); 2,24(l). B. 80(g ); 2,24 (l) C.64(g); 4,48(l). D. 40(g); 4,48(l)
Cu 45. Cho cc pht biu sau:
(1) Cr l kim loi cng nht.
(2) Os l kim loi nng nht.
(3) Hg l kim loi c nhit nng chy thp nht.
(4) Cht no dn in tt th cng dn nhit tt.
(5) Cht no c nh kim l kim loi.
(6) Ty tng mi trng khc nhau, kim loi c th l cht oxi ha hoc cht kh.
S pht biu ng l:
A. 5 B. 3 C. 4 D. 6
Cu 46. Trong cc dung dch sau:
AgNO
3
, AAlCl
3
, Fe
2
(SO
4
)
3
, CH
3
COONH
4
, NaH
2
PO
4
, CH
3
COOK, KHS, NaOH, H
2
O, Na
2
HPO
3
, Na
2
HPO
4
.
S cht lng tnh l:
A. 4 B. 5 C. 6 D. 7
Cu 47. Pht biu no sau y ng ?
A. Mui axit khng th to ra t axit n chc
B. Mi axit v c u l cht in li mnh
C. C th cho 2 mui phn ng vi nhau thu c axit
D. Mui ca axit yu v baz mnh th in li km
Cu 48. Hn hp A gm 10,2 g NaNO
3
v 0,48 mol HCl. Hn hp A ha tan ti a bao nhiu gam hn hp B gm
Fe v Cu c t l mol l 2:1
A. 10,56 B. 17,6 C. 36,4 D. 7,92
Cu 49. Pht biu no sau y ng ?
A. Nc c cu trc tinh th nguyn t B. Iot(rn) c cu trc tinh th phn t
C. Kim cng tn ti di dng phn t (cu trc t din) D. Photpho trng c cu
trc polime
Cu 50. Cho cc phn ng
(1) (NH
4
)
2
SO
4
+Ba(OH)
2
2NH
3
+BaSO
4
+2H
2
O
(2) NH
4
Cl +NaOH NaCl +NH
3
+H
2
O
(3) NH
4
HSO
4
+2KOH NH
3
+K
2
SO
4
+H
2
O
(4) CH
3
COONH
4
+NaOH CH
3
COONa +NH
3
+H
2
O
(5) NH
4
HCO
3
t
0
NH
3
+H
2
O +CO
2

S phn ng c phng trnh ion rt gn NH
4
+
+OH
NH
3
+H
2
O l
A. 1 B. 2 C. 3 D. 4

P N

1. B 2.A 3. C 4.A 5.B 6.C 7.B 8.A 9.A 10.B
11.B 12.A 13.B 14.D 15.A 16.C 17.A 18.B 19.C 20.C
21.B 22.B 23.B 24.B 25.B 26.C 27.C 28.D 29.D 30.D
31.A 32.B 33.B 34.C 35.B 36.C 37.B 38.C 39.B 40.C
41.A 42.A 43.D 44.B 45.C 46.C 47.C 48.A 49.B 50.B

84 | L O V E B O O K . V N
s 12
( thi th GSTT GROUP ln 1 Nm hc 2013 2014)
Cu 1: Cho cc nhn xt sau:
1. Tinh bt v xenluloz l ng phn cu to ca nhau.
2. Amiloz c cu to mch phn nhnh.
3. Saccaroz khng c tnh kh.
4. Sn phm thy phn xenluloz c th tham gia phn ng trng gng.
5. Dung dch glucoz phn ng vi Cu(OH)
2
trong mi trng kim nhit cao to ra phc ng glucoz.
S nhn xt ng l:
A. 2 B. 3 C. 4 D. 5
Cu 2: Cho s phn ng:
Toluen
+Cl
2
; nh sng
A B
+CuO
C
7
H
6
O
+O
2
,xt
C
Toluen
+KMnO
4
D C
S phn ng oxi ha kh l:
A. 2 B. 3 C. 4 D. 5
Cu 3: X mch h c cng thc C
3
H
n
. Mt bnh kn dung tch khng thay i ng hn hp gm X v O
2
d 150
v 2 atm. Bt tia la in t chy ht X, sau a bnh v 150, p sut bnh vn l 2 atm. Trn 9,6 gam X
vi 1,2 gam H
2
ri cho qua bnh ng Ni nung nng, phn ng t 100% th thu c hn hp Y. M
Y
c gi tr l:
A. 40,5. B. 30. C. 42. D. 35,5.
Cu 4: C cc nhn nh sau y:
(1) Cc ion v nguyn t Cl
, Ar, K
+
, S
2
c sp xp theo chiu tng dn bn knh l S
2
, Cl
, Ar, K
+
.
(2) C 8 nguyn t c cu hnh electron lp ngoi cng l 4s
2
trng thi c bn.
(3) Nit c hai ng v khc nhau. Oxi c ba ng v khc nhau. S phn t N
2
O khc nhau c to ra t cc
ng v trn l 12.
(4) Cc nguyn t F, O, S, Cl u l nhng nguyn t p.
(5) Nguyn t phi kim X to c hp cht vi hiro c cng thc HX. Vy oxit ng vi ha tr cao nht ca
nguyn t ny l X
2
O
7
.
S nhn nh ng l:
A. 4. B. 2. C. 5. D. 3.
Cu 5: Cho cc hp cht hu c thuc: ankaien; anken; ankin; ancol khng no (c 1 lin kt i) mch h, hai
chc; anehit no, mch h, hai chc; axit khng no (c 1 lin kt i), mch h, n chc; amino axit (c mt
nhm chc amino v hai nhm chc cacboxyl), no, mch h. Tng s cc loi hp cht hu c trn tha mn cng
thc C
n
H
2n2
O
x
N
y
(x, y l s nguyn) l:
A. 2. B. 3. C. 4. D. 5.
Cu 6: Ha tan ht hn hp hai kim loi M, N trong dung dch HCl d, thm tip vo lng d NH
3
. Lc tch kt
ta, nhit phn kt ta ri in phn nng chy cht rn th thu c kim loi M. Thm H
2
SO
4
va vo dung
dch nc lc, ri in phn dung dch thu c th sinh ra kim loi N. M v N l cp kim loi:
A. Al v Fe. B. Ag v Zn. C. Al v Zn. D. Zn v Cu.
Cu 7: Ion M
2+
c tng s ht proton, electron v ntron l 80, s ht mang in nhiu hn s ht khng mang
in l 20. V tr ca M trong bng tun hon cc nguyn t ha hc l:
A. Chu k 4, nhm VIIIB. B. Chu k 4, nhm VIIIA.
C. Chu k 3, nhm VIIIB. D. Chu k 4, nhm IIA.
Cu 8: C cc dung dch ring bit, mt nhn: NaOH, NaCl, MgCl
2
, CuCl
2
, AlCl
3
, FeCl
3
. Khng dng thm thuc th
c th nhn bit c my dung dch trong s cc dung dch trn?
A. 2. B. 3. C. 4. D. 6.
Cu 9: Cho m gam hn hp X gm Al, Zn tc dng vi 500ml dung dch Cu(NO
3
)
2
1M n khi phn ng hon ton
thu c dung dch Z v cht rn T. Cho Z tc dng vi dung dch NaOH d thu c 19,6 gam kt ta. Gi tr ln
nht ca m l:
A. 19,5. B. 39. C. 5,4. D. 16,2.
Cu 10: Ha tan hon ton 30,4 gam cht rn X gm Cu, CuS, Cu
2
S v S bng dung dch HNO
3
d thy thot ra
20,16 lt NO duy nht (ktc) v dung dch Y. Thm dung dch Ba(OH)
2
d vo dung dch Y thu c m gam kt
ta. Gi tr ca m l:
A. Hng s cn bng K
C
ca mi phn ng u tng khi tng nhit .
B. Hng s cn bng K
C
cng ln, hiu sut phn ng cng nh.
C. Khi mt phn ng thun nghch trng thi cn bng c chuyn sang mt trng thi cn bng mi nhit
khng i, hng s cn bng K
C
bin i.
D. Khi thay i h s t lng cc cht trong phng trnh ha hc ca mt phn ng gi tr ca hng s cn
bng K
C
thay i.
Cu 12: Cho hn hp X gm hai cht hu c no, n chc tc dng va vi 100ml dung dch KOH 0,4M, thu
c mt mui v 336 ml mt hi ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th
ht sn phm chy vo bnh ng dung dch Ca(OH)
2
d th khi lng bnh tng 6,82 gam. Cng thc ca hai
hp cht hu c trong X l:
A. HCOOH v HCOOC
2
H
5
. B. HCOOH v HCOOC
3
H
7
.
C. C
2
H
5
COOH v C
2
H
5
COOCH
3
. D. CH
3
COOH v CH
3
COOC
2
H
5
.
Cu 13: Thy phn este E thu c axit cacboxylic A v hn hp B gm hai ancol n chc l ng ng k tip
ca nhau. X phng ha hon ton 3,65 gam E cn va ng 500ml dung dch NaOH 0,1M thu c m gam mui
v x gam hn hp B. Gi tr ca m l:
A. 3,4. B. 4,8. C. 4,1. D. 3,7.
Cu 14: Oxit Y ca mt nguyn t X ng vi ha tr II c thnh phn % theo khi lng ca X l 42,86%. Trong cc
mnh sau:
(1) Y tan nhiu trong nc.
(2) Lin kt gia X v O trong Y l lin kt ba.
(3) Y c th iu ch trc tip t phn ng gia X v hi nc nng.
(4) T axit fomic c th iu ch c Y.
(5) T Y, bng mt phn ng trc tip c th iu ch c axit etanoic.
(6) Y l kh khng mu, khng mi, khng v, c tc dng iu ha khng kh.
(7) Trong cc hp cht, X c th c nhiu ha tr khc nhau.
(8) Y l oxit baz.
S mnh ng khi ni v X v Y l:
A. 4. B. 5. C. 6. D. 7.
Cu 15: em nung hn hp rn gm hai mui FeCO
3
v FeS
2
c t l mol 1:1 trong bnh c th tch khng i, th
tch cc cht rn khng ng k, ng khng kh d (80% th tch khng kh l N
2
, cn li l O
2
) cc mui trn
b oxi ha ht to oxit st c ha tr cao nht. ngui bnh, a nhit bnh v lc ban u nh trc khi nung,
p sut trong bnh s nh th no?
A. Khng i. B. S gim xung. C. S tng ln. D. Khng xc nh.
Cu 16: Trong mt bnh kn dung tch khng i cha hn hp A gm etan v mt ankin (u th kh) c t l s
mol l 1:1. Thm oxi vo bnh th c hn hp kh B c t khi so vi H
2
l 18. t chy hon ton hn hp B sau
a v 0 thy hn hp kh trong bnh c t khi so vi H
2
l 21,4665. Cng thc ca ankin l:
A. C
2
H
2
. B. C
3
H
4
. C. C
4
H
6
. D. C
5
H
8
.
Cu 17: Xt phn ng sau: (CH
3
)
2
CH OH +HX (CH
3
)
2
CHX +H
2
O.
Th t gim dn kh nng phn ng ca HX l:
86 | L O V E B O O K . V N
A. HF > HCl > HBr > HI. B. HI > HBr > HCl > HF.
C. HI > HCl > HBr > HF. D. HCl > HBr > HI > HF.
Cu 18: Tripeptit M v tetrapeptit Q c to t mt amino axit X mch h (phn t ch cha mt nhm NH
2
).
Phn trm khi lng nit trong X bng 18,667%. Thy phn khng hon ton m gam hn hp M, Q (c t l mol
1:1) trong mi trng axit thu c 0,945 gam M; 4,62 gam ipeptit v 3,75 gam X. Gi tr ca m l:
1. Cu hnh electron ca ion X
2+
l 1s
2
2s
2
2p
6
3s
2
3p
6
3d
6
. Trong bng tun hon nguyn t ha hc, nguyn t
X thuc chu k 4 nhm VIIIB.
2. Dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri trang phi l K, Mg, Si.
3. Cc ion v nguyn t Ne, Na
+
, F
c im chung l c cng s electron.

4. Mc nng lng ion ha u tin l nng lng tch ton b electron ra khi nguyn t.
5. Dung dch H
2
S lu trong khng kh s c vn c mu en.
S pht biu ng l:
A. 2. B. 3. C. 5. D. 4.
Cu 20: Cho nhng pht biu sau:
1. in li bng s phn t tan trong dung dch ca cht tan.
2. in li t l thun vi s phn t cht tan trong dung dch.
3. in li tng khi nng mol/l cng nh.
4. Qu trnh phn li cc cht ra ion l s in li.
5. tan mt nhit nht nh ca mt cht l s gam cht tan m 1 lt nc c th ho tan c.
S pht biu ng l:
A. 1. B. 2. C. 3. D. 4.
Cu 21: tch ring NH
3
ra khi hn hp kh N
2
, H
2
v NH
3
, trong cng nghip, ngi ta thc hin phng php
no sau y?
A. Nn v lm lnh hn hp, NH
3
ha lng.
B. Cho hn hp i qua CuO nung nng.
C. Cho hn hp i qua dung dch H
2
SO
4
c.
D. Cho hn hp i qua dung dch nc vi trong.
Cu 22: t chy hon ton hn hp gm FeS2 v Ag2S vi nhng s mol bng nhau thu c 3,36 lt SO2 (ktc)
v cht rn B. Cho B vo cc ng lng d dung dch axit HCl. S gam cht rn khng tan trong axit HCl l:
Cu 23: Cho 37,95 gam hn hp hai mui MgCO3 v RCO3 vo 100ml dung dch H2SO4 long thy c 1,12 lt kh
CO2 (ktc) thot ra, dung dch A v cht rn B. C cn dung dch A thu c 4g mui khan. Nung cht rn B n
khi lng khng i thu c B1 v 4,48 lt CO2 (ktc). Khi lng cht rn B1 v nguyn t R l:
A. 26,95 v Ba. B. 27,85 v Ba. C. 27,85 v Ca. D. 26,95 v Ca.
Cu 24: Pht biu no sau y khng ng?
A. Kim loi cng mnh th m in cng ln.
B. Kim loi ch th hin tnh kh trong cc phn ng ha hc.
C. Nguyn t kim loi c t electron lp ngoi cng.
D. Cc phn nhm ph ca bng tun hon ha hc ch gm cc kim loi.
Cu 25: t chy hon ton 7,65 gam anlylclorua thu c hn hp kh v hi nc (c cha HCl). Dn ton b
sn phm qua 500ml dung dch NaOH 2M thu c dung dch B. C cn dung dch B thu c m gam cht rn
khan. Gi tr ca m l:
A. 38,45 B. 50,45 C. 49,65 D. 37,65
(1) FeCO
3
+H
2
SO
4 (c)
t
o
kh X +kh Y +
(2) NaHCO
3
+KHSO
4
kh X +
(3) Cu +HNO
3 (c)
t
o
kh Z +
(4) FeS +H
2
SO
4 long
kh G +
(5) NH
4
NO
2
t
o
kh H +
(6) AgNO
3
t
o
kh Z +kh I +
Trong cc cht kh sinh ra t cc phn ng trn, s cht kh tc dng c vi dung dch NaOH l:
A. 4 B. 5 C. 6 D. 3
Cu 27: C bao nhiu pht biu ng?
1. Trong tinh th kim loi, nguyn t v ion kim loi nm nhng nt mng tinh th.
2. Trong tinh th lc phng c khong 26% l khng gian trng.
3. Lin kt kim loi l lin kt c hnh thnh gia cc nguyn t trong mng tinh th.
4. dn in tng dn theo th t: Al, Fe, Au, Cu, Ag.
5. Tnh dn in ca kim loi quyt nh bi cc electron t do c trong khi kim loi .
A. 1. B. 3. C. 5. D. 4.
Cu 28: Ha tan ht hn hp gm 1 kim loi kim v mt kim loi kim th trong nc thu c dung dch A v
1,12 lt H2 (ktc). Cho dung dch cha 0,03 mol AlCl3 vo dung dch A thu c khi lng kt ta l:
A. 0,78 (g) B. 0,81 (g) C. 2,34 (g) D. 1,56 (g)
Cu 29: X l dung dch AlCl3, Y l dung dch NaOH 2M. Cho 150ml dung dch Y vo cc cha 100ml dung dch X,
khuy u cho n khi phn ng hon ton thy trong cc c 7,8 gam kt ta. Nu thm tip vo cc 100ml dung
dch Y kt thc phn ng thu c 10,92 gam kt ta. Nng mol ca dung dch X l:
A. 3,2 M B. 2,0 M C. 1,0 M D. 1,6 M
Cu 30: Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dung
dch HCl 1M vo 100ml dung dch X, sinh ra V lt kh (ktc). un nng c cn dung dch sau phn ng th thu
c m gam mui khan. Gi tr ca m l:
A. 25,6 B. 30,1 C. 23,9 D. 18,2
Cu 31: Cho hn hp X gm 0,02 mol C
2
H
2
v 0,03 mol H
2
vo mt bnh kn c mt xc tc Ni ri un nng thu
c hn hp kh Y. Cho Y li t t vo bnh nc brom d thy c 448ml kh Z (ktc) bay ra. Bit t khi hi ca
Z so vi H
2
bng 4,5. Khi lng bnh brom tng sau phn ng l:
Cu 32: Thy phn hon ton hn hp cht bo triglixerit X bng NaOH thu c hn hp mui gm natri stearat;
natri oleat; natri pamitat v glyxerol. Trong X c ti a bao nhiu cht bo c th lm mt mu dung dch brom?
A. 11 B. 12 C. 14 D. 15
Cu 33: Nung m gam hn hp gm bt Al v FexOy trong iu kin khng c khng kh cho n khi phn ng hon
ton thu c hn hp X. Trn u X, chia X thnh 2 phn. Phn 1 (c khi lng 14,49 gam) ha tan ht trong
HNO3 d thu c 0,165 mol kh NO (sn phm kh duy nht ). Phn 2 tc dng ht vi dung dch NaOH, un
nng thy gii phng 0,015 mol H2 v cn li 2,52 gam cht rn. Cng thc st oxit v gi tr m l:
A. Fe2O3; 19,32 gam B. Fe3O4; 28,98 gam C. Fe2O3; 28,98 gam D. Fe3O4; 19,32 gam
Cu 34: Cho cc mnh di y:
(1) Cc halogen (F,Cl, Br, I) c s oxi ha t -1 n +7
(2) Flo l cht ch c tnh oxi ha
(3) F2 y c Cl2 ra khi dung dch mui NaCl
(4) Tnh axit ca cc hp cht vi hidro ca cc halogen tng theo th t: HF,HCl.HBr, HI.
(5) Cc cht: HI, NH3, C2H5OH, CH3COOH c lin kt hidro vi nc trong dung dch.
(6) Phng php iu ch I2 trong cng nghip: 2HI + H2SO4 c I2 + 2H2O + SO2
S mnh ng l:
A. 1 B. 2 C. 3 D. 4
88 | L O V E B O O K . V N
Cu 35: Cho X l hp cht hu c c hai chc ging nhau, mch h. Cho X tc dng vi CuO, nung nng thu c
sn phm Y c phn ng trng bc. Bit t 1 mol Y thu c 4 mol CO
2
. S cng thc cu to tha mn ca X l:
A. 6 B. 7 C. 8 D. 9
Cu 36: Trong cng nghip, t nitron c sn xut theo s :
CH
3
CH
2
CH
3
CH
2
= CH CH
3
CH
2
= CH CN t nitron
Tnh khi lng t to thnh khi sn xut t 1000m
3
kh thin nhin (ktc) c cha 10% propan v hiu sut ca
mi giai on l 80%.
A. 121,14 (kg) B. 189,29 (kg) C. 12,11 (kg) D.18,93 (kg)
Cu 37: So snh no di y l sai?
A. Nhit nng chy: H
2
NCH
2
COOH < CH
3
COOH
B. Tnh baz: C
6
H
5
NH
2
> (C
6
H
5
)
2
NH
C. Nhit si: CH
3
CH
2
COOH > CH
3
COOCH
3

D. pH: valin > glyxin.
Cu 38: Cho bit cht no di y khi b oxi ha bi dung dch KMnO
4
H
2
SO
4
un nng cho sn phm ch l hn
hp cc axit CH
3
COOH v HOOC(CH
2
)
3
COOH?
A. CH
3
C (CH
2
)
3
C CH B. CH
3
(CH
2
)
5
C CH
C. CH
3
C(CH
2
)
3
C CCH
3
D. HC C(CH
2
)
3
C CH
Cu 39: Mt hp cht ion Y c to nn t ion M
2+
v X
2
. Tng s ht trong phn t Y l 60. S ht mang in
nhiu hn s ht khng mang in l 20 ht. S ht mang in ca X
2
t hn s ht mang in ca ion M
2+
l 4.
Trong ion M
2+
c tng s ht mang in l:
A. 20. B. 22. C. 18. D. 24.
Cu 40: Cho mt phn ng thun nghch nh sau:
A (k) +B (k) C (r) +2D (k) H < 0
Nhng cch no sau y c th lm cn bng chuyn dch theo chiu thun?
A. Gim nhit , tng p sut, ly bt C ra ngoi.
B. Tng nhit , gim p sut, ly bt D ra ngoi.
C. Gim nhit , ly bt D ra ngoi.
D. Dng cht xc tc, gim p sut.
Cu 41: Cho phng trnh phn ng
Fe(NO3)2 + KHSO4 Fe(NO3)3 + Fe2(SO4)3 + K2SO4 + NO + H2O
Tng h s cn bng ca cc cht tham gia phn ng trong phng trnh trn l:
A. 43. B. 21. C. 27. D. 9.
Cu 42: Cho cc cht: glixerol, glucoz, axit acrylic, fructoz, anehit fomic, axit axetic, vinyl fomat, etyl fomat,
anehit acrylic, axeton, saccaroz, mantoz, ancol anlylic. C bao nhiu cht va tc dng c vi Cu(OH)
2
, va
phn ng c vi dung dch nc Br
2
trong iu kin thch hp?
A. 6 B. 7 C. 8 D. 9
Cu 43: iu ch ancol etylic t m gam tinh bt. Chia lng ancol iu ch c thnh 2 phn bng nhau. Phn 1
cho i qua dung dch H
2
SO
4
c 140
o
C, sau khi phn ng hon ton thy to thnh (m 1,8) gam sn phm hu
c. Phn 2 tc dng vi Na d thu c V lt kh (ktc). Gi tr ca V l?
A. 2,24 lt B. 3,36 lt C. 4,48 lt D. 5,6 lt
Cu 44: Cho hn hp cc este l ng phn mch h ca nhau c cng s mol v c cng thc phn t l C
4
H
6
O
2
.
X phn ng va vi 600ml dung dch NaOH 1M thu c hn hp sn phm Y. Cho ton b Y vo dung dch
Ag(NO
3
)trong NH
3
d thu c m gam kt ta. Gi tr ca m?
A. 151,2 B. 86,4 C. 129,6 D. 108
Cu 45: Chn nhn xt sai:
A. Cc hp cht Al(OH)3, HCOONH4, Sn(OH)2, Pb(OH)2 u l cht lng tnh.
B. Cc hp cht NaHSO4, Na2HPO3, NaH2PO4, NaHSO3 u l mui axit.
C. Cc dung dch: ancol etylic, glixerol, saccarozo u khng dn c in.
D. Dung dch mui: NaHCO3, CH3COOK, NaClO, K3PO4 u c pH>7.
Cu 46: nhng vng m c khong vt pirit FeS
2
, nc b nhim, pH ca nc rt thp, tc l nc rt axit v
c nhiu kt ta nu lng ng. Hy chn cch gii thch hp l nht v hin tng trn:
A. {
4FeS
2
+11O
2
t
o
2Fe
2
O
3
+8SO
2
SO
2
+H
2
O H
2
SO
3

B. {
4FeS
2
+11O
2
t
o
2Fe
2
O
3
+8SO
2
2SO
2
+O
2
xt
2SO
3
SO
3
+H
2
O H
2
SO
4

C. {
4FeS
2
+11O
2
t
o
2Fe
2
O
3
+8SO
2
Fe
2
O
3
+3H
2
O 2Fe(OH)
3

D. {
2FeS
2
+7O
2
+4H
2
O 2Fe
2+
+4SO
4
2
+4H
+
4Fe
2+
+O
2
+6H
2
O 4FeO(OH) +8H
+

Cu 47: Trn 18 gam axit axetic vi 32,2 gam ancol etylic trong mi trng c H
2
SO
4
c, un nng thu c 17,6
gam este. Mt khc khi trn 27 gam axit axetic vi V ml dung dch ancol etylic 1M th thu c 26,4 gam este. Tnh
V?
A. 300 B. 350 C. 1050 D. 500
Cu 48: Cho 15,5 gam hn hp hai cht lin tip nhau trong dy ng ng ca phenol tc dng va vi 0,5 lt
dung dch NaOH 0,3M. Cng thc phn t ca hai cht v phn trm khi lng ca chng trong hn hp l:
A. C
7
H
7
OH (69,68%) v C
8
H
9
OH (30,32%) B. C
6
H
5
OH (69,68%) v C
7
H
7
OH (30,32%)
C. C
6
H
5
OH (30,32%) v C
7
H
7
OH (69,68%) D. Kt qu khc.
Cu 49: C 2 amin: X (ng ng ca anilin) v Y (ng ng ca metylamin). t chy hon ton 3,21g amin X
sinh ra kh CO2 v hi nc v 336 cm
3

kh nit (ktc). Khi t chy hon ton amin Y cho n
CO
2
: n
H
2
O
= 2: 3. Bit
X v Y khi tc dng vi HNO
2
nhit thng u khng to kh. Cng thc phn t ca hai amin l?
A. C
6
H
4
NHCH
3
; CH
3
CH
2
NHCH
3
B. C
2
H
5
C
6
H
4
NH
2
; CH
3
CH
2
CH
2
NH
2

C. CH
3
C
6
H
4
NH
2
; CH
3
CH
2
CH
2
NH
2
D. C
2
H
5
C
6
H
4
NH
2
; CH
3
CH
2
NHCH
3

Cu 50: Cho s : C
6
H
6
X mBr C
6
H
4
NO
2

Phn t khi ca X l:
A. 78 B. 157 C. 92 D. 123

P N
1.A 2.C 3.B 4.B 5.C 6.C 7.A 8.D 9.A 10.C
11.D 12.D 13.D 14.A 15.A 16.C 17.B 18.C 19.B 20.B
21.D 22.B 23.A 24.A 25.C 26.A 27.B 28.D 29.D 30.C
31.A 32.B 33.D 34.C 35.D 36.A 37.A 38.C 39.B 40.C
41.B 42.B 43.A 44.A 45.B 46.D 47.C 48.C 49.A 50.D

90 | L O V E B O O K . V N

Cu 1: p n A.
1. Phn t khi ca xenlulozo ln hn rt nhiu ln so vi tinh bt.
2. Amilozo c cu trc mch thng cn aminopectin mi c cu trc mch nhnh.
3. Saccarozo c th hin tnh kh khi tham gia phn ng chy.
Nhn xt: y chng ta xt tnh kh ni chung ch khng xt ring tnh kh mang tnh c trng ca
nhm chc cc hp cht.
Cu 2: p n C.
Toluen
+Cl
2
; nh sng (1)
A B
+CuO(2)
C
7
H
6
O
+O
2
,xt(3)
C
Toluen
+KMnO
4
(4)
D
(5)
C
Cc cht A, B, C, D ln lt l benzyl clorua, ancol benzylic, axit benzoic, kali benzoat.
Cc phn ng oxi ha kh l: (1), (3), (4), (5).
Cu 3: p n B.
C
3
H
n
+(3 +
n
4
) O
2
t
3CO
2
+
n
2
H
2
O
V p sut khng i nn ta c:
1 +3 +
n
4
= 3 +
n
2
n = 4.
n
C
3
H
4
=
9,6
40
= 0,24 (mol); n
H
2
=
1,2
2
= 0,6 (mol). n
H
2
> 2n
C
3
H
4
H
2
d.
Tng s mol sau: 0,24 +0,6 0,24.2 = 0,36.
M
Y
=
m
Y
n
Y
=
m
X
n
Y
=
0,24.40 +0,6.2
0,36
= 30.
Cu 4: p n B.
(1)Th t ng phi l: K
+
, Ar, Cl
, S
2
. Do cc nguyn t v ion ny c cng s electron nn nguyn t,
ion no cng c nhiu proton th bn lc ht cng mnh, do bn knh cng nh.
(2)Th t in e l: 4s
2
3d
x
(0 x 10, x 4, x 9). D dng thy c nhiu hn 8 nguyn t tha
(5) Loi ngay trng hp ca Flo v Flo ch c s oxi ha -1 trong mi loi hp cht.
Cu 5: p n C.
Cc cht l: ankaien; ankin; anehit no, mch h, hai chc; axit khng no (c 1 lin kt i), mch
h, n chc.
Cu 6: p n C.
Da vo d kin bi, M, N tan trong HCl suy ra loi hai p n B, D, v sau ta ch thu c M chng t
kt ta N(OH)n b tan, to phc khi amoniac d, vy ch c C tha mn.
Cu 7: p n A.
Da vo bi ta c h: {
2P +N 2 = 80
2P 2 N = 20
{
P = 26
N = 30
Cu hnh e: 3d
6
4s
2
Chu k 4 nhm VIIB.
Cu 8: p n D.
Ln lt ly tng cht cho phn ng vi cc cht cn li ri lp bng th ta c kt qu nh sau:
NaOH NaCl MgCl2 CuCl2 AlCl3 FeCl3
NaOH
C kt trng
khng tan
C kt ta
xanh
Kt ta keo trng,
sau tan khi kim d
Kt ta mu nu

NaCl

MgCl2
C kt trng
khng tan

CuCl2
C kt ta xanh
AlCl3
Kt keo trng,
sau tan khi kim
d

FeCl3
Kt ta mu nu

T bng ta thy c th hn bit c c 6 dung dch.
Cu 9: p n A.
Dung dch Z sau phn ng c th cha c 3 loi ion: Al
3+
, Zn
2+
, Cu
2+
.
Sau khi Z tc dng vi NaOH d th kt ta Al(OH)3

v Zn(OH)2 tan, ch cn li 19,6 gam Cu(OH)2.
n
Cu(OH)
2
=
19,6
63 +34
= 0,2 < n
Cu2
+ = 0,5 n
Cu2
+ phn ng = 0,5 0,2 = 0,3 (mol)
+) Nu nh hn hp ch c Al m =
0,3.2
3
. 27 = 5,4(gam).
+) Nu nh hn hp ch c Zn m =
0,3
2
. 65 = 19,5 (gam).
Vy m ln nht bng 19,5 gam.
Nhn xt: V y hi gi tr cc tr nn ta c th gi s nh trong hn hp ch cha mt trong hai
loi kim loi. Gii hai trng hp ra v chn ly gi tr tha mn.
Cu 10: p n C.
S dng phng php quy i ta cho ton b hn hp v Cu v S.
Gi s mol ca Cu v S ln lt l a v b.
p dng nh lut bo ton e ta c:
2a +6b =
20,16
22,4
. 3 = 2,7.
Da vo khi lng ta c: 64a +32b = 30,4.
{
a = 0,3
b = 0,35
. Kt ta gm BaSO
4
, Cu(OH)
2
.
n
BaSO
4
= n
S
= 0,35; n
Cu(OH)
2
= n
Cu
= 0,3
m
kt ta
= 0,35.233 +0,3.98 = 110,95 (gam).
Nhn xt: y chng ta thy hn hp ban u gm rt nhiu cht khc nhau, nu t n cho tng cht
th rt nhiu n, hn na s d kin li nh hn s n c th lp h phng trnh. Trong ha hc
thng xuyn ta gp nhng trng hp nh vy. Phng php chung l gp n n gin ha bi
ton, c th ng quy i nh bi ton ny, tng gim khi lng hoc trung bnh.
Cu 11: p n D.
A. Ty thuc phn ng ta nhit hay thu nhit mi c th xc nh c.
B. Hng s cn bng K
C
cng ln, hiu sut phn ng cng ln.
C. Khi mt phn ng thun nghch trng thi cn bng c chuyn sang mt trng thi cn bng mi
nhit khng i, hng s cn bng K
C
khng i.
Cu 12: p n D.
n
KOH
= 0,1.0,4 = 0,04 (mol).
n
ancol
=
0,336
22,4
= 0,015 (mol) < 0,04.
Nhn xung p n ta suy ra:
n
este
= 0,015; n
axit
= 0,025 (do tt c cc phng n u l axit, este no, h, n chc)
Theo p n, nu ta t chy X th thu c n
CO
2
= n
H
2
O

Khi lng bnh tng chnh bng khi lng ca kh cacbonic v nc nn ta c:
n
CO
2
= n
H
2
O
=
6,82
44 +18
= 0,11 (mol).
Gi s phn t C trong axit v este ln lt l m v n ta c: 0,015. n +0,025. m = 0,11.
92 | L O V E B O O K . V N
Xt thy ch c m = 2, n = 4 tha mn. Vy chn D.
Cu 13: p n D.
Este E l este 2 chc, ME = 146.
V 2 ancol ng ng lin tip nn E ch c th l CH3OOCCH2C2H5.
m = 0,025.148 = 3,7(gam).
Cu 14: p n A.
Da vo thnh phn % khi lng ca X ta d dng tm c X l C, Y l CO (cacbon monoxit). Cc sai
sau khi sa li l:
(1) CO tan t trong nc.
(2) Lin kt gia X v O gm mt lin kt cho nhn v mt lin kt cng ha tr.
(6) Y l kh rt c.
(8) Y khng phi l oxit baz.
Cu 15: p n A.
2FeCO
3
+
1
2
O
2
t
Fe
2
O
3
+ 2CO
2

2FeS
2
+
11
2
O
2
t
Fe
2
O
3
+ 4SO
2

Ta c:
1
2
+
11
2
= 2 +4 kh hai bn cn bng nhau. Do p sut khng i.
Cu 16: p n C.
V ankan v ankin c s mol bng nhau nn khi t chy hn hp ta s thu c CO2 v H2O vi s mol
bng nhau.
B c t khi vi hidro bng 18 M
B
= 36 Ankin cn li phi l propin hoc butin.
n y lm nhanh nht ta thc hin phng php thay p s. Nu gii bnh thng c th tn rt
nhiu thi gian v d nhm ln do nhiu ln xut hin t khi. V t l ankin v ankan bng nhau nn ta c
th th lun nh vi mt hidrocacbon vi hai trng hp C2,5H5 v C3H6.
Cu 17: p n B.
Cu 18: p n C.
M
X
=
14
0,18667
= 75 X l Glyxin.
n
M
=
0,945
189
= 0,005; n
ipeptit
=
4,62
132
= 0,035; n
X
=
3,75
75
= 0,05.
s mt xch X = 3. n
M
+2. n
ipeptit
+ n
X
= 0,135.
n
M
= n
Q
=
0,135
3 +4
= 0,0193 m = 0,0193.189 +0,0193.246 = 8,389.
Cu 19: p n B.
4. Mc nng lng ion ha u tin l nng lng tch mt electron ra khi nguyn t, mc nng lng
ion ha th 2 l nng lng tch electron th 2 ra khi nguyn t, v vv.
5. Dung dch H2S lu trong khng kh s c vn c mu vng do phn ng: H2S + SO2 = S + H2O
Cu 20: p n B.
1. in li bng s phn t phn li trong tng s phn t ca cht tan trong dung dch.
2. in li khng t l thun vi s phn t cht tan.
3. tan mt nhit nht nh ca mt cht l s gam cht tan m 100ml nc c th ho tan c.
Cu 21: p n A.
Do nhit ha lng ca cc cht khc nhau nn ta c th tch tng cht ra khi hn hp.
Cu 22: p n C.
FeS
2
1
2
Fe
2
O
3
+ 2SO
2
; Ag
2
S Ag + SO
2

n
SO
2
=
3,36
22,4
= 0,15 n
Ag
=
0,15
3
. 2 = 0,1 (mol).
Cu 23: p n A.
Nung B c kh CO
2
chng t mui cacbonat d, axit ht.
n
H
2
SO
4
= n
CO
2
(1)
=
1,12
22,4
= 0,05 (mol).
n
CO
2
(2)
=
4,48
22,4
= 0,2 (mol).
n
CO
2
= n
mui cacbonat
= 0,2 +0,05 = 0,25 (mol).
M

Mui
=
37,95
0,25
= 151,8 Mui cn li phi l BaCO
3
(kt hp vi p n th ch c Ba tha mn).
p dng nh lut bo ton khi lng ta c:
m
hn hp
+m
axit
= m
mui tan
+m
B
+m
CO
2
(1)
+m
H
2
O
; n
CO
2
(1)
= n
axit
= n
H
2
O

m
B
= 37,95 +0,05(98 44 18) 4 = 35,6 (gam).
m
B
= m
B1
+m
CO
2
(2)
m
B1
= 35,6 0,2.44 = 26,59 (gam).
Cu 24: p n A.
A. m in c trng cho kh nng ht e ca nguyn t. m in cng nh th tnh kim loi cng
mnh.
Cu 25: p n C.
CH
2
= CH CH
2
Cl HCl +3CO
2
+2H
2
O
0,1 0,1 0,3
Khi cho hn hp kh vo dung dch NaOH th c th to ra mui NaCl, NaHCO3, Na2CO3
y ta thy n
NaOH
> n
HCl
+ 2n
CO
2
trong dung dch ch cha cc mui NaCl, Na
2
CO
3
.
m
cht rn
= m
NaOH d
+ m
NaCl
+ m
Na
2
CO
3

= (1 0,1 0,6)40 +0,1.58,5 +0,3.106 = 49,65 (gam).
Nhn xt: y bi cho vo trng hp n gin, ta c th nhn ra r rng mi quan h gia s mol
kim, axit v baz. mt s trng hp khc ta phi kim tra c th hn nhng mui no c trong dung
dch da vo cc s mol. Th t u tin l HCl s phn ng trc ri n CO2.
Cu 26: p n A.
Cc kh X, Y, Z, G, H, I ln lt l: CO2, SO2, NO2, H2S, N2, O2.
Trong cc kh ch c CO2, SO2, NO2, H2S tc dng c vi dung dch NaOH.
Cu 27: p n B.
(3) Lin kt kim loi l lin kt hnh thnh gia cc ion kim loi v nguyn t trong mng tinh th, c s
tham gia ca cc electron t do.
(4) dn in tng dn theo th t: Fe, Al, Au, Cu, Ag.
Cu 28: p n D.
n
OH
= 2n
H
2
=
2.11,2
22,4
= 0,1(mol).
n
= 4n
Al
3+ n
OH
= 4.0,03 0,1 = 0,02 (mol).
m = 0,02.78 = 1,56 (gam).
Cu 29: p n D.
ln u tin ta thy n
OH
= 3n
OH
c th va ht hoc thiu.
ln th hai, thy rng d ta thm mt lng OH
tng ln nhng kt ta tng nh hn t l y.

iu chng t OH
d v ha tan mt phn kt ta.

p dng ngay cng thc tnh nhanh:
4n
Al
3+ = n
OH
+ n
= 0,25.2 +
10,92
78
= 0,64.
94 | L O V E B O O K . V N
C
M
=
0,64
4.0,1
= 1,6 M.
Cu 30: p n C.
Khi nh t t HCl vo hn hp trn, th t phn ng xy ra nh sau:
H
+
+ CO
3
2
HCO
3

H
+
+ HCO
3
CO
2
+ H
2
O
Phn ng th (2) ch xy ra khi H
+
cn d, do ta tnh c:
n
CO
2
= 0,2 0,15 = 0,05 (mol). n
HCO
3
cn li = 0,15 +0,1 0,05 = 0,2 (mol).
Sau khi nung, mui RHCO3 b nhit phn thnh R2CO3 nn khi lng cht rn:
m = m
RCl
+ m
R
2
CO
3
= m
R
+ m
Cl
+ m
CO
3
2
= (0,15.2.23 +0,1.39) +0,2.35,5 +
0,15.2+0,10,2
2
. 60 = 23,9 (gam).
Nhn xt: y ta tnh c s mol ca CO
3
2
da vo nh lut cn bng in tch m v dng:
n
Na
+ +n
K
+ = n
Cl
+ 2n
CO
3
2
Cu 31: p n A.
Ta c: m
Z
= 0,02.9 = 0,18(gam)
p dng bo ton khi lng ta c:
m
bnh tng
= m
X
m
Z
= 0,02.26 +0,03.2 0,18 = 0,4 (gam).
Cu 32: p n B.
Ta thy c 3 loi axit bo khc nhau thu c khu thy phn hn hp cht bo. Ch c axit oleic mi tc
dng c vi nc brom vy trong thnh phn cht bo tha mn yu cu bi ton nht thit phi c t
nht mt gc axit oleic.
T 3 loi axit bo trn ta c th to c 12 loi cht bo tha mn yu cu bi.
Cu 33: p n D.
Xt phn 2:
Ta thy c kh thot ra khi cho hn hp vo dung dch kim, do Al d v ton b oxit st phn ng
ht v chuyn v st.
m
Fe
= 2,52 gam n
Fe
=
2,52
56
= 0,045 (mol).
n
Al
d =
2
3
n
H
2
=
2
3
. 0,015 = 0,01 (mol).
Nu cho phn 2 phn ng hon ton vi HNO
3
th s mol kh NO thu c l:
n
NO
=
(0,01.3 +0,045.3)
3
= 0,055(mol) =
0,165
3
(0,165 l s mol kh thot ra phn 1)
Khi lng phn 2 bng:
14,49
3
= 4,83(g).
m
Al
2
O
3
= 4,83 0,045.56 0,01.27 = 2,04 (g).
n
O
=
2,04
102
. 3 = 0,06.
n
Fe
n
O
=
0,045
0,06
=
3
4
oxit st l Fe
3
O
4
.
m = 14,49 +4,83 = 19,32(g).
Cu 34: p n C.
Nhng ng gm 2, 4 v 5
1 sai ch F ch c s oxi ha 1 trong hp cht
3 sai ch F
2
bc chy trong nc to axit HF nn khng y Cl
2
ra khi dung dch mui
6 sai ch khng th iu ch I
2
bng axit sunfuric
v I
2
l cht oxi ha mnh v SO
2
l cht kh s xy ra phn ng ngc li
Cu 35: p n D.
t 1 mol Y thu c4 m ol CO2 nn suy ra trong phn t X c 4 nguyn t C. Cho X qua CuO nung nng
thu c sn phm c kh nng trng bc nn chc chnX c cha chc ancol v t nht mt trong 2
chc ny phi nm v tr Cacbon bc 1. Ta vit c9 CTCT nh sau:
C C C(OH) C OH; C = C C(OH) C OH; C C C(OH) C OH
C C(OH) C C (OH); OH C C C C OH; OH C C = C C OH
OH C C C C OH; C C(C)(OH) C OH; C = C(C OH) C OH
Cu 36: p n A.
m
t
=
0,1.1000. 10
3
22,4
. 53. 0,8
3
= 121,14. 10
3
(g).
Cu 37: p n A.
Cu 38: p n C.
Khi ankin mch di phn ng vi KMnO4 /H2SO4 un nng th chng c th b b gy mch C ti cc v tr
lin kt yu to thnh cc sn phm oxi ha kh.
Cu 39: p n B.
Theo bi ra ta c h:
{
2(Z
M
+Z
X
) +(N
M
+N
X
) = 60
2(Z
M
+Z
X
) (N
M
+N
X
) = 20
{
Z
M
+Z
X
= 40
Z
M
+Z
X
= 20

S ht mang in ca X
2
t hn ca M
2+
l 4 nn ta c: 2Z
M
2 = 2Z
X
+2 +4 {
Z
X
= 8
Z
M
= 12

Vy s ht mang in ca M
2+
l 2.12 2 = 22.
Nhn xt: y s ht mang in bao gm proton v electron. Ht khng mang in chnh l notron.
Nu l ion m th n c thm electron, nu l ion dng th n b mt i electron.
Cu 40: p n C.
Cu 41: p n B.
Sau khi cn bng bng phng php thng bng e ta c phng trnh:
9Fe(NO3)2 + 12KHSO4 Fe(NO3)3 + 2Fe2(SO4)3 + 6K2SO4 +3NO + 6H2O
Cu 42: p n B.
Cc cht l: glucoz, axit acrylicanehit fomic, vinyl fomat, etyl fomat, anehit acrylic, mantoz.
Cu 43: p n A.
Phn 1 to thnh ete.
Phng trnh thng qut:
R OH +R
OH R O R
+
1
2
H
2
O
n
H
2
O
=
1,8
18
= 0,1 (mol) n
ancol
= 0,1.2 = 0,2 (mol).
R OH +Na R ONa +
1
2
H
2

n
H
2
=
0,2
2
. 22,4 = 2,24 (l).
Cu 44: p n A.
Cc este c cng cng thc phn t C4H6O2 l:
Cis-HCOOCH=CHCH3; trans-HCOOC(CH3)=CH2; HCOOCH2CH=CH2; CH3COOCH=CH2; CH2=CHCOOCH3.
Hn hp este phn ng va vi 500ml dung dch NaOH 1M nn ta c:
n
mi este
=
0,6
6
= 0,1 (mol).
Khi cho phn ng trng bc, vi mi mt phn t este trn, ln lt chng s cho ra s phn t bc
tng ng l: 4; 4; 2; 2; 2; 0.
m
Ag
= 0,1(4 +4 +2 +2 +2 +2). 108 = 151,2(g).
96 | L O V E B O O K . V N
Nhn xt: y rt d thiu trng hp ng phn hnh hc cis-trans. Cc em hc sinh nh k cu
t ca bi trnh nhm ln.
Cu 45: p n B.
Axit H3PO3 ch l axit hai nc nn mui Na2HPO3 khng phi l mui axit m l mui trung ha.
Cu 46: p n D.
Cu 47: pp n C.
* n
CH
3
COOH
= 0,3; n
C
2
H
5
OH
= 0,7; n
CH
3
COOC
2
H
5
= 0,2
CH
3
COOH +C
2
H
5
OH CH
3
COOC
2
H
5
+H
2
O
K
C
=
[CH
3
COOC
2
H
5
]. [H
2
O]
[CH
3
COOH]. [C
2
H
5
OH]
=
0,2.0,2
0,1.0,5
= 0,8
* n
CH
3
COOH
= 0,45; n
CH
3
COOC
2
H
5
= 0,3; n
C
2
H
5
OH
= a
K
C
=
0,3
2
0,15. (a 0,3)
= 0,8 a = 1,05 V = 1,05 (lt)
Cu 48: p n C.
S dng phng php trung bnh. Ta c:
n
NaOH
= 0,5.0,3 = 0,15 (mol) = n
hn hp
M
=
15,5
0,15
= 103,33 (g/mol).
Suy ra hai cht l C6H5OH v C7H7OH.
Cu 49: p n A.
+) Tm X:
m
N
=
0,336
22,4
. 28 = 0,42(g).
Cng thc tng qut ng ng ca anilin: C
n
H
2n5
N
14
14n +9
=
0,42
3,21
n = 7.
+) Tm Y:
Cng thc tng qut ca ng ng metyl amin: C
m
H
2m+3
N
Theo bi: n
CO
2
: n
H
2
O
= 2: 3
m
m+
3
2
=
2
3
m = 3
V c X v Y u khng to kh vi HNO2 nn chng khng phi amin bc 1. Vy ch c A l tha mn.
Cu 50: p n D.
V sn phm cui l m-Br-C6H4-NO2, nhm th v tr meta nn X phi l cht c nhm th loi 2. Do vy,
X ch c th l C6H5-NO2, phn t khi bng 123.
Nhn xt: Nu vng benzen cha nhm th loi 1(-CH3, -Cl, -Br,) th khi th u tin th vo v tr ortho
v para. Cn nu l nhm th loi 2 (-NO2, -COOH,) th u tin th vo v tr meta.

s 13

Cu 1: Cho 300 ml dung dch Ba(OH)2 0,1M vo 250 ml dung dch Al2(SO4)3 x(M) thu c 8,55 gam kt ta. Thm
tip 400 ml dung dch Ba(OH)2 0,1M vo hn hp phn ng th lng kt ta thu c l 18,8475 gam. Gi tr ca x l
A. 0,06. B. 0,09. C. 0,12. D. 0,1.
Cu 2: Cho Fe tc dng ht vi dung dch H2SO4 c nng thu c kh SO2 (sn phm kh duy nht) v 8,28 gam mui.
Bit s mol Fe bng 37,5% s mol H2SO4 phn ng. Khi lng Fe tham gia phn ng l
Cu 3: Cho 0,1 mol cht X (C2H8O3N2) tc dng vi dung dch cha 0,2 mol NaOH un nng thu c cht kh lm
xanh giy qu tm tm t v dung dch Y. C cn dung dch Y c m gam cht rn khan. Gi tr ca m l
A. 5,7. B. 12,5. C. 15,5. D. 21,8.
Cu 4: Cho 2,16 gam hn hp gm Al v Mg tan ht trong dung dch axit HNO3 long, un nng nh to ra dung dch
X v 448 ml (o 354,9
0
K v 988 mmHg) hn hp kh Y kh gm 2 kh khng mu, khng i mu trong khng
kh. T khi ca Y so vi oxi bng 0,716 ln t khi ca kh cacbonic so vi nit. Lm khan X mt cch cn thn
thu c m gam cht rn Z, nung Z n khi lng khng i thu c 3,84 gam cht rn T. Gi tr ca m l
A. 15,18. B. 17,92. C. 16,68. D. 15,48.
Cu 5: Oxi ha 4,6 gam ancol etylic bng O2 iu kin thch hp thu c 6,6 gam hn hp X gm anehit, axit,
ancol d v nc. Hn hp X tc dng vi natri d sinh ra 1,68 lt H2 (ktc). Hiu sut ca phn ng chuyn ha
ancol thnh anehit l
A. 75%. B. 50%. C. 33%. D. 25%.
Cu 6: Ho n h p X go m a mol Fe, b mol FeCO3 va c mol FeS2. Cho X va o binh dung tich kho ng o i ch a kho ng khi
(d), nung en khi ca c pha n ng xa y ra hoa n toa n, sau o a ve nhie t o ban a u thay a p suat trong binh ba ng
a p suat tr c khi nung. Quan he cu a a, b, c la
A. a = b+c. B. 4a+4c=3b. C. b=c+a. D. a+c=2b.
Cu 7: ho tan ht mt mu Al trong dung dch axit HCl 25
0
C cn 36 pht. Cng mu Al tan ht trong dung
dch axit ni trn 45
0
C trong 4 pht. Hi ho tan ht mu Al trong dung dch axit ni trn 60
0
C th cn
thi gian bao nhiu giy?
A. 45,465 giy. B. 56,342 giy. C. 46,188 giy. D. 38,541 giy.
Cu 8: Cho cc pht biu sau. S pht biu ng l
(1) Trong hp cht vi oxi, nit c cng ha tr cao nht bng V.
(2) Trong cc hp cht, flo lun c s oxi ha bng -1.
(3) Lu hunh trong hp cht vi kim loi lun c s oxi ha l -2.
(4) Trong hp cht, s oxi ha ca nguyn t lun khc khng.
(5) Trong hp cht, mt nguyn t c th c nhiu mc s oxi ha khc nhau.
(6) Trong mt chu k, theo chiu tng in tch ht nhn, bn knh nguyn t ca cc nguyn t tng dn.
A. 3. B. 5. C. 2. D. 4.
Cu 9: Hp cht hu c C4H7O2Cl (X), khi thy phn trong mi trng kim c cc sn phm, trong c hai cht c
kh nng phn ng trng gng. Cng thc cu to ng ca (X) l
A. HCOO-CH2-CHCl-CH3. B. CH3COO-CH2-CH2Cl. C. HCOOCHCl-CH2-CH3. D. ClCH2COO-CH2-CH3.
Cu 10: Cho cc phn ng sau:
(1) dung dch Na2CO3 + dung dch H2SO4. (2) dung dch Na2CO3 + dung dch FeCl3.
(3) dung dch Na2CO3 + dung dch CaCl2. (4) dung dch NaHCO3 + dung dch Ba(OH)2.
(5) dung dch (NH4)2SO4 + dung dch Ba(OH)2. (6) dung dch Na2S + dung dch AlCl3.
S phn ng to ng thi c kt ta v kh bay ra l
A. 3. B. 6. C. 4. D. 5.
Cu 11: Cht hu c X cha vng benzen c cng thc phn t l CxHyO. Bit %O = 14,81% (theo khi lng). S
cng thc cu to ph hp ca X l
A. 8. B. 6. C. 7. D. 5.
98 | L O V E B O O K . V N
Cu 12: Thc hin tng hp tetrapeptit t 3,0 mol glyxin; 4,0 mol alanin v 6,0 mol valin. Bit phn ng xy ra
hon ton. Khi lng tetrapeptit thu c l
Cu 13: un nng m gam cht hu c (X) cha C, H, O vi 100 ml dung dch NaOH 2M n khi phn ng xy ra
hon ton. trung ha lng NaOH d cn 40 ml dung dch HCl 1M. Lm bay hi cn thn dung dch sau khi
trung ha, thu c 7,36 gam hn hp 2 ancol n chc (Y), (Z) v 15,14 gam hn hp 2 mui khan, trong c
mt mui ca axit cacboxylic (T). Kt lun no sau y ng?
A. Axit (T) c cha 2 lin kt i trong phn t.
B. S nguyn t cacbon trong axit (T) bng mt na s nguyn t cacbon trong cht hu c X.
C. Ancol (Y) v (Z) l 2 cht ng ng lin tip vi nhau.
D. Cht hu c X c cha 14 nguyn t hiro.
Cu 14: Thy phn 4,3 gam poli (vinyl axetat) trong mi trng kim thu c 2,62 gam polime. Hiu sut ca phn
ng thy phn l
A. 60%. B. 80%. C. 75%. D. 85%.
Cu 15: t chy hon ton 24,8 gam hn hp X gm (axetilen, etan v propilen) thu c 1,6 mol nc. Mt
khc 0,5 mol X tc dng va vi dung dch cha 0,645 mol Br2. Phn trm th tch ca etan trong hn hp X l
A. 5,0%. B. 3,33%. C. 4,0 %. D. 2,5%.
Cu 16: Cho m gam hn hp tinh th gm NaBr, NaI tc dng va vi H2SO4 c iu kin thch hp, thu
c hn hp kh X iu kin thng. iu kin thch hp hn hp X tc dng va vi nhau to thnh 9,6
gam cht rn mu vng v mt cht lng khng lm i mu qu tm. Gi tr ca m l
A. 260,6. B. 240. C. 404,8. D. 50,6.
Cu 17: Cho m gam butan qua xc tc ( nhit thch hp), thu c hn hp gm 5 hirocacbon. Cho hn hp
kh ny sc qua bnh ng dung dch nc brom d th lng brom tham gia phn ng l 25,6 gam v sau th
nghim bnh brom tng 5,32 gam. Hn hp kh cn li sau khi qua dung dch nc brom c t khi so vi metan
l 1,9625. Gi tr ca m l
A. 17,4. B. 8,7. C. 5,8. D. 11,6.
Cu 18: Hap thu het 4,48 lit CO2 (ktc) va o dung dich ch a x mol KOH va y mol K2CO3 thu c 200 ml dung dich X.
Lay 100 ml dung dch X cho t t va o 300 ml dung dich HCl 0,5M thu c 2,688 lit khi (ktc). Mt khc, 100 ml
dung dch X tc dng vi dung dch Ba(OH)2 d thu c 39,4 gam kt ta. Gia tri cu a x la
A. 0,15. B. 0,2. C. 0,1. D. 0,06.
Cu 19: Dung dch CH3COOH (dung dch A) c pH = 2,57. Nu trn 100 ml dung dch A vi 100 ml dung dch NaOH
(dung dch B) c pH = 13,3 c 200 ml dung dch C. Bit Ka(CH3COOH) = 1,85.10
-5
. pH ca dung dch C l
A. 3,44. B. 4,35. C. 5,47. D. 4,74.
(1) Trong 3 dung dch c cng pH l HCOOH, HCl v H2SO4 th dung dch c nng mol ln nht l HCOOH.
(2) Phn ng trao i ion khng km theo s thay i s oxi ha ca nguyn t.
(3) C th phn bit trc tip 3 dung dch: KOH, HCl, H2SO4 (long) bng mt thuc th l BaCO3.
(4) Axit, baz, mui l cc cht in li.
(5) Dung dch CH3COONa v dung dch C6H5ONa (natri phenolat) u l dung dch c pH >7.
(6) Theo thuyt in li, SO3 v C6H6 (benzen) l nhng cht in li yu.
S pht biu ng l
A. 5. B. 3. C. 2. D. 4.
Cu 21: o t cha y hoa n toa n 4,02 gam ho n hp gm axit acrylic, vinyl axetat va metyl metacrylat ro i cho toa n bo
sa n pham cha y va o binh 1 ng dung dich H2SO4 a c, binh 2 ng dung dich Ba(OH)2 d thay kho i l ng binh 1
tng m gam, binh 2 xuat hin 35,46 gam ket tu a. Gia tri cu a m la
A. 2,70. B. 2,34. C. 3,24. D. 3,65.
Cu 22: Cho ca c pha t bieu sau:
(1) CaOCl2 l mui kp.
(2) Lin kt kim loi l lin kt c hnh thnh gia cc nguyn t v ion kim loi trong mng tinh th do s
tham gia ca cc electron t do.
(3) Supephotphat kp c thnh phn ch yu l Ca(H2PO4)2.
(4) Trong ca c HX (X: halogen) thi HF co tinh axit yu nht.
(5) Bo n nhie u pha n a m amoni se la m cho at chua.
(6) Kim loi c nhit nng chy thp nht l thy ngn (Hg).
(7) CO2 l phn t phn cc.
So pha t bieu u ng la
A. 7. B. 4. C. 6. D. 5.
Cu 23: Cho phn ng: CH3COCH3 + KMnO4 + KHSO4 CH3COOH + MnSO4 + K2SO4 + CO2 + H2O. Tng h s ca
cc cht (l nhng s nguyn, ti gin) trong phng trnh phn ng l
A. 68. B. 97. C. 88. D. 101.
Cu 24: C 4 cht: isopropyl benzen (1), ancol benzylic (2), benzanehit (3) v axit benzoic (4). Th t tng dn
nhit si ca cc cht trn l
A. (2) < (3) < (1) < (4). B. (2) < (3) < (4) < (1). C. (1) < (2) < (3) < (4). D. (1) < (3) < (2) < (4).
Cu 25: Bit tan ca NaCl trong 100 gam nc 90
0
C l 50 gam v 0
0
C l 35 gam. Khi lm lnh 600 gam
dung dch NaCl bo ha 90
0
C v 0
0
C lm thot ra bao nhiu gam tinh th NaCl?
A. 45 gam. B. 55 gam. C. 50 gam. D. 60 gam.
Cu 26: Cho hn hp (HCHO v H2 d) i qua ng ng bt Ni un nng thu c hn hp X. Dn ton b sn
phm thu c vo bnh nc lnh thy khi lng bnh tng 5,9 gam. Ly ton b dung dch trong bnh cho tc
dng vi dung dch AgNO3/NH3 d thu c 10,8 gam Ag. Khi lng ancol c trong X l gi tr no di y?
Cu 27: Cho cc nguyn t sau: 13Al; 5B; 9F; 21Sc. Hy cho bit c im chung ca cc nguyn t .
A. Electron cui cng thuc phn lp p. B. C 1 electron c thn trng thi c bn.
C. u c 3 lp electron. D. u l cc nguyn t thuc chu k nh.
Cu 28: Ho tan hon ton 0,775 gam n cht (X) trong dung dch HNO3 c thu c 5,75 gam hn hp gm
hai kh (c thnh phn % theo khi lng ca oxi nh nhau) v dung dch (Y). Bit t khi hi ca hn hp kh so
vi hiro l 115/3. trng thi c bn nguyn t X c s electron c thn l
A. 3. B. 4. C. 2. D. 1.
Cu 29: Cho cc cht: Glixerol, etylen glicol, gly-ala-gly, glucoz, axit axetic, saccaroz, anehit fomic, anilin. S
cht tc dng c vi Cu(OH)2 ( iu kin thch hp) l
A. 7. B. 8. C. 6 . D. 5.
Cu 30: Nguyn t X c cu trc mng lp phng tm din (hnh bn). Phn trm th
tch khng gian trng trong mng li tinh th ca X l

A. 32 %. B. 26 %. C. 74 %. D. 68 %.
Cu 31: Tch nc hon ton t 25,8 gam hn hp A gm 2 ancol X v Y (MX<MY), sau phn ng thu c hn hp
B gm 2 anken k tip nhau trong dy ng ng. t chy hon ton B cn va 1,8 mol O2. Mt khc nu tch
nc khng hon ton 25,8 gam A ( 140
0
C, xt H2SO4 c), sau phn ng thu c 11,76 gam hn hp cc ete.
Bit hiu sut ete ha ca Y l 50%. Hiu sut ete ha ca X l
A. 35%. B. 65%. C. 60%. D. 55%.
Cu 32: Mt khong cht c cha 20,93% nhm; 21,7% silic (theo khi lng), cn li l oxi v hiro. Phn trm
khi lng ca hiro trong khong cht l
A. 2,68%. B. 5,58%. C. 1,55%. D. 2,79%.
Cu 33: Cho cc cht sau: Tristearin, hexan, benzen, glucoz, xenluloz, metylamin, phenylamoni clorua, triolein,
axetilen, saccaroz. S cc cht khng tan trong nc l
A. 6. B. 9. C. 8. D. 7.
Cu 34: Khi thy phn 500 gam protein A thu c 170 gam alanin. Nu phn t khi ca A l 50.000, th s mt
xch alanin trong phn t A l bao nhiu?
100 | L O V E B O O K . V N
A. 191. B. 189. C. 196. D. 195.
Cu 35: C cc dung dch ring bit sau: H2N-CH2-CH2-CH(NH2)-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-
COONa, ClH3N-CH2-COOH, C6H5-NH3Cl (phenylamoni clorua). S lng cc dung dch c pH < 7 l
A. 2. B. 5. C. 4. D. 3.
Cu 36: Hirocacbon thm C9H8 (X) lm mt mu nc brom, cng hp c vi brom theo t l mol 1:2, khi oxi
ha to thnh axit benzoic, khi tc dng vi dung dch AgNO3 trong NH3 to kt ta c trng. Pht biu no sau
y khng ng?
A. X c 3 cng thc cu to ph hp. B. X c tn gi l benzyl axetilen.
C. X c bt bo ha bng 6. D. X c lin kt ba u mch.
Cu 37: Mt hn hp Y gm 2 este A, B mch h (MA< MB). Nu un nng 15,7 gam hn hp Y vi dung dch NaOH
d th thu c mt mui ca axit hu c n chc v 7,6 gam hn hp 2 ancol no n chc k tip nhau trong
dy ng ng. Nu t chy 15,7 gam hn hp Y cn dng va ht 21,84 lt O2 v thu c 17,92 lt CO2. Cc th
tch kh o ktc. Phn trm khi lng ca A trong hn hp Y l
A. 63,69%. B. 40,57%. C. 36,28%. D. 48,19%.
Cu 38: Qu trnh iu ch t no di y l qu trnh trng hp?
A. T lapsan t etylen glicol v axit terephtalic.
B. T capron t axit -amino caproic.
C. T nilon-6,6 t hexametyleniamin v axit aipic.
D. T nitron (t olon) t acrilonitrin.
Cu 39: Trong cht bo lun c mt lng axit bo t do. Khi thy phn hon ton 2,145 kg cht bo cn dng 0,3 kg
NaOH, thu c 0,092 kg glixerol v m (kg) hn hp mui natri. Gi tr ca m l
A. 3,765. B. 2,610. C. 2,272. D. 2,353.
Cu 40: Hai hp cht thm X v Y c cng cng thc phn t l CnH2n-8O2. Bit hi cht Y c khi lng ring
5,447 gam/lt (ktc). X c kh nng phn ng vi Na gii phng H2 v c phn ng trng bc. Y phn ng c
vi Na2CO3 gii phng CO2. Tng s cng thc cu to ph hp ca X v Y l
A. 4. B. 5. C. 7. D. 6.
Cu 41: Cho cc pht biu sau. S pht biu ng l
(1) Cc tiu phn Ar, K
+
, Cl
-
u c cng s n v in tch ht nhn.
(2) Trong nguyn t s proton lun bng s ntron.
(3) ng v l hin tng cc nguyn t c cng s khi.
(4) Bn knh ca cation nh hn bn knh ca nguyn t tng ng.
(5) Nc thuc loi tinh th nguyn t.
(6) Kim cng c cu trc tinh th phn t.
A. 4. B. 2. C. 3. D. 1.
Cu 42: Cho cc cht sau: Glixerol, ancol etylic, p-crezol, phenylamoni clorua, valin, lysin, anilin, ala-gly, phenol,
amoni hirocacbonat. S cht tc dng c vi dung dch NaOH l
A. 10. B. 9. C. 7. D. 8.
Cu 43: Cho 1,0 mol axit axetic tc dng vi 1,0 mol ancol isopropylic th cn bng t c khi c 0,6 mol isopropyl
axetat c to thnh. Lc ngi ta cho thm 2,0 mol axit axetic vo hn hp phn ng, cn bng b ph v v
chuyn n trng thi cn bng mi. S mol ca isopropyl axetat trng thi cn bng mi l
Cu 44: Khi un nng 25,8 gam hn hp ru (ancol) etylic v axit axetic c H2SO4 c lm xc tc thu c 14,08 gam
este. Nu t chy hon ton lng hn hp ban u thu c 23,4 ml nc. Hiu sut ca phn ng este ha
l
A. 70%. B. 80%. C. 75%. D. 85%.
Cu 45: Trong phng th nghim c cc dd v cht lng ng trong cc bnh mt nhn ring bit gm NH4HCO3,
Ba(HCO3)2, C6H5ONa (natri phenolat), C6H6 (benzen), C6H5NH2(anilin) v KAlO2 hoc K[Al(OH)4]. Hy chn mt
thuc th nhn bit trc tip c cc dung dch v cht lng trn?
101 | G S T T G R O U P
A. Dung dch NaOH. B. Dung dch H2SO4. C. Dung dch BaCl2. D. Qu tm.
Cu 46: Cho 2,5 kg glucoz cha 20% tp cht ln men thnh ru (ancol) etylic. Tnh th tch dung dch ru
40
0
thu c? Bit ru nguyn cht c khi lng ring 0,8 g/ml v trong qu trnh ch bin, ru b hao ht
mt 10%.
A. 2300,0 ml. B. 2875,0 ml. C. 3194,4 ml. D. 2785,0 ml.
Cu 47: Cho 30,1 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3 long, un nng v khuy u.
Sau khi cc phn ng xy ra hon ton thu c 1,68 lt NO (sn phm kh duy nht, ktc), dung dch Y v cn
d 0,7 gam kim loi. C cn dung dch Y, khi lng mui khan thu c l
Cu 48: Cho cc cht: H2S, S, SO2, FeS, Na2SO3, FeCO3, Fe3O4, FeO, Fe(OH)2. C bao nhiu cht trong s cc cht trn
tc dng c vi H2SO4 c nng?
A. 6. B. 8. C. 5. D. 7.
Cu 49: Ho tan hon ton 8,3 gam hn hp X (Fe v 1 kim loi M c ho tr khng i) trong dung dch HNO3
long d th thu c 8,96 lt hn hp kh Y ktc gm NO, NO2 c d
Y H
2
= 21 v ch xy ra 2 qu trnh kh. Nu
ho tan hon ton 8,3 (g) hn hp X trn trong dung dch HCl th thu c 5,6 lt H2 (ktc). Kim loi M l:
A. Ni. B. Mg. C. Al. D. Zn.
Cu 50: Cho cc pht biu sau y:
(1) Amilopectin c cu trc dng mch khng phn nhnh.
(2) Xenluloz c cu trc dng mch phn nhnh.
(3) Saccaroz b kh bi AgNO3/dd NH3.
(4) Xenluloz c cng thc l [C6H7O2(OH)3]n.
(5) Saccaroz l mt isaccarit c cu to t mt gc glucoz v mt gc fructoz lin kt vi nhau qua nguyn
t oxi.
(6) Tinh bt l cht rn, dng v nh hnh, mu trng, khng tan trong nc lnh.
S pht biu ng l
A. 4. B. 3. C. 5. D. 6.

P N

1B 2D 3B 4D 5D 6C 7C 8C 9C 10A
11D 12D 13B 14B 15A 16A 17D 18C 19D 20A
21B 22D 23C 24D 25D 26B 27B 28A 29A 30D
31C 32C 33A 34A 35D 36A 37A 38D 39C 40A
41D 42C 43C 44B 45B 46B 47C 48B 49C 50B

102 | L O V E B O O K . V N
s 14

A. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l
A. (CH3)3N, CH3CH2OH, CH3CH2CH2NH2, HCOOH
B. C4H10, C3H7Cl, C3H7NH2, C3H7OH, CH3CH2COOH
C. C4H10, C3H7NH2, C3H7F, C3H7OH, CH3CH2COOH
D. Benzen, toluen, phenol, CH3COOH
Cu 2: A l hn hp cc mui Cu(NO
3
)
2
, Fe(NO
3
)
2
, Fe(NO
3
)
3
, Mg(NO
3
)
2
trong O chim 55,68% v khi lng.
Cho dung dch KOH d vo dung dch cha 50 gam mui, lc kt ta thu c em nung trong chn khng n
khi lng khng i thu c m gam oxit. Gi tr ca m l
A. 18,68 B. 23,32 C. 31,44 D. 12,88
Cu 3: Hp cht hu c X c cng thc phn t C4H8O2 mch thng tha mn cc tnh cht sau:
- X lm mt mu dung dch Br2.
- 4,4 gam X tc dng vi Na d thu c 0,56 lt H2 (ktc).
- Oxi ha X bi CuO, t
0
to ra sn phm Y l hp cht a chc. Cng thc cu to ca X l:
A. CH2=CH-CH(OH)-CH2OH B. CH3-CH2-CO-CHO C. HO-(CH2)3-CH=O D. HO-CH2-CH(CH3)-CHO
Cu 4: Chia m gam hn hp 2 anehit n chc mch h thnh hai phn bng nhau
+ Phn 1 tc dng vi lng d AgNO3 trong NH3 thu c 86,4 gam Ag kt ta.
+ Phn 2 tc dng va vi 1 gam hiro c xc tc Ni nung nng thu c hn hp ancol Y. Ngng t Y ri cho
ton b vo bnh cha Na thy khi lng bnh tng (0,5m + 0,7) gam.
Cng thc hai anehit l
A. HCHO v CH3CHO B. CH2=CHCHO v HCHO
C. HCHO v C2H5CHO D. CH2=CHCHO v CH3CHO
Cu 5: X l dung dch AlCl3 ; Y l dung dch NaOH 2M. Thm 150ml dung dch Y vo cc cha 100 ml dung dch X
khuy u n khi phn ng hon ton thy trong cc c 7,8g kt ta. Thm tip vo cc 100ml dung dch Y khuy
u ti khi kt thc phn ng thy trong cc c 10,92 g kt ta. Nng mol ca dung dch X l
A. 1,0 M B. 1,6 M C. 3,2 M D. 2,0 M
Cu 6: X l este to bi o-amino axit Y (cha 1 nhm -COOH v 1 nhm -NH2) vi ancol n chc Z. Thy phn
hon ton 0,1 mol X trong 200 ml dung dch NaOH 1M, c cn dung dch thu c 13,7 gam cht rn v 4,6 gam
ancol Z. Cng thc ca X l:
A. H2N-CH2-COOCH2-CH=CH2 B. CH3-CH(NH2)-COOCH3
C. H2N-CH2-COOC2H5 D. CH3-CH(NH2)-COOC2H5
Cu 7: Mt hn hp gm Na, Al, Fe (vi t l mol Na v Al tng ng l 5:4) tc dng vi nc d thu c V lt
kh, dung dch Y v cht rn Z. Cho Z tc dng vi dung dch H
2
SO
4
long d th thu c 0,25V lt kh (cc kh o
cng iu kin). Thnh phn % theo khi lng ca Na trong hn hp X l
A. 33,63 B. 20,07 C. 34,8 D. 14,4
+
, Fe
3+
, SO4
2-
; dung dch Y cha Ba
2+
, OH
-
, S
2-
phn ng ha hc?
A. 8 B. 6 C. 7 D. 5
Cu 9: Cho cc cht sau: Cu, FeS2, Na2SO3, S, NaCl, Cu2O, KBr, Fe3O4
tc dng vi dung dch H2SO4
c, nng.
S trng hp xy ra phn ng oxi ha - kh l:
A. 7 B. 6 C. 4 D. 5
Cu 10: Cho 2,54g este (X) mch h bay hi trong 1 bnh kn dung tch 0,6 lt (lc u l chn khng). Khi este bay
hi ht th p sut 136,5
0
C l 425,6 mmHg. Thu phn 25,4 gam (X) cn 0,3 mol NaOH thu c 28,2 g mt mui
duy nht. Bit rng (X) pht xut t ancol a chc. X l
A. etylenglicoliaxetat B. glixerin triaxetat C. glixerin tripropionat D. glixerin triacrylat
103 | G S T T G R O U P
Cu 11: Ho tan hon ton 21,1gam hn hp gm FeCl2 v NaF (c t l mol l 1:2) vo mt lng nc (d), thu
c dung dch X. Cho dung dch AgNO3 (d) vo X, sau khi phn ng xy ra hon ton sinh ra m gam cht rn.
Gi tr ca m l:
A. 39,5g B. 28,7g C. 57,9g D. 68,7g
Cu 12: Hirat ho hon ton 1,56 gam mt ankin (A) thu c mt anehit (B). Trn (B) vi mt anehit n
chc (C). Thm nc c mt 0,1 lt dung dch (D) cha (B) v (C) vi nng mol tng cng l 0,8M. Thm
t t vo dung dch (D) vo dung dch cha AgNO3/NH3 d thu c 21,6g Ag kt ta. Cng thc cu to v s
mol ca (B) v (C) trong dung dch (D) l
A. (B): CH3-CHO 0,1 mol, (C): H-CHO 0,15 mol
B. (B): CH3-CHO 0,06 mol, (C): C2H5CHO 0,02 mol
C. (B): CH3-CHO 0,06 mol,(C): H-CHO 0,02 mol
D. (B): CH3-CHO 0,08 mol,(C): H-CHO 0,05 mol
Cu 13: Cho dung dch Ba(HCO3)2 ln lt tc dng vi cc dung dch sau: NaOH, NaHSO4, HCl, KHCO3, K2CO3,
H2SO4. S trng hp xy ra phn ng v s trng hp c kt ta l
A. 5 v 4 B. 4 v 4 C. 5 v 2 D. 6 v 5
Cu 14: Mt hn hp X gm 1 ankan A

v 1 ankin B c cng s nguyn t cacbon. Trn X vi H2

(va ) c
hn hp Y. Khi cho Y qua Pt, xc tc th thu c kh Z c t khi i vi CO2 bng 1 (phn ng cng H2 hon ton).
Bit rng Vx = 6,72 lt v VH2 = 4.48 lt. Cc th tch kh c o ktc. Cng thc phn t v s mol ca A, B trong
hn hp X l
A. C2H6,C2H2, 0,1 mol C2H6, 0,2 mol C2H2 B. C3H8,C3H4, 0,1 mol C3H8, 0,2 mol C3H4
C. C2H6,C2H2, 0,2 mol C2H6, 0,2 mol C2H2 D. C3H8,C3H4, 0,2 mol C3H8, 0,1 mol C3H4
Hirocacbon A
Br
2
,as
B
NaOH
C
CuO
D
O
2
,Mn
2+

HOOCCH2COOH. Vy A l
A. C3H8. B. C. CH2=CHCH3. D. CH2=CHCOOH.
Cu 16: in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu c m gam Al catot v
67,2 lt ( ktc) hn hp kh X c t khi so vi oxi bng 1. Ly 1,12 lt ( ktc) hn hp kh X sc vo dung dch
nc vi trong (d) thu c 1 gam kt ta. Gi tr ca m l
A. 108,0 B. 54,0 C. 75,6 D. 67,5
Cu 17: Cho cc cht sau: axetilen, etilen, but-1-in, axit fomic, fomanehit, phenyl fomat, glucoz, anehit axetic,
metyl axetat, mantoz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l:
A. 7 B. 9 C. 6 D. 8
Cu 18: Hn hp gm hai axit X, Y c s nhm chc hn km nhau mt n v v c cng s nguyn t cacbon.
Chia hn hp axit thnh hai phn bng nhau. Cho phn mt tc dng ht vi K, sinh ra 2,24 lt kh H2 ( ktc). t
chy hon ton phn hai, sinh ra 6,72 lt kh CO2 ( ktc). Cng thc cu to thu gn v phn trm v khi lng
ca mt axit c trong hn hp l
A. HOOC-COOH v 42,86% B. HOOC-COOH v 66,67%
C. CH2(COOH)2 v 66,67% D. CH2(COOH)2 v 42,86%
Cu 19: Cho a gam bt Al vo dung dch cha 0,1 mol AgNO3 ; 0,15 mol Cu(NO3)2 v 0,2 mol Fe(NO3)3 thu c
dung dch X v kt ta Y. Hy la chn gi tr ca a kt ta Y thu c cha 3 kim loi.
A. 3,6 gam < a s 9 gam B. 5,4 gam < a s 9 gam
C. 2,7 gam < a < 5,4 gam. D. a > 3,6 gam
Cu 20: Cho cc cht v dung dch: SO2, H2S, Br2, HNO3, CuSO4. C bao nhiu phn ng to ra c H2SO4 t hai
cht cho trn vi nhau?
A. 4 B. 3 C. 5. D. 6
Cu 21: Cho lung kh CO d i qua hn hp BaO, Al2O3 v FeO t nng thu c cht rn X1. Ho tan cht rn
X1 vo nc thu c dung dch Y1 v cht rn E1. Sc kh CO2 d vo dung dch Y1 thu c kt ta F1. Ho tan E1
104 | L O V E B O O K . V N
vo dung dch NaOH d thy b tan mt phn v cn cht rn G1. Cho G1 vo dung dch AgNO3 d (Coi CO2 khng
phn ng vi nc). Tng s phn ng xy ra l
A. 7. B. 8. C. 9. D. 6.
Cu 22: Cho khi lng ring ca cn nguyn cht l D = 0,8 g/ml. Hi t 1 tn v bo (cha 80% xenluloz) c
th iu ch c bao nhiu lt cn thc phm 40 (bit hiu sut ca ton b qu trnh iu ch l 64,8%)?
A. 294 lt. B. 368 lt. C. 920 lt. D. 147,2 lt.
Cu 23: Nguyn t ca nguyn t X c tng s ht electron trong cc phn lp p l 7. S ht mang in ca mt
nguyn t Y nhiu hn s ht mang in ca mt nguyn t X l 6 ht. Hp cht ca X, Y c dng:
A. X2Y. B. X3Y2. C. XY2. D. X2Y3.
Cu 24: Hn hp bt X gm BaCO3, Fe(OH)2, Al(OH)3, CuO, MgCO3. Nung X trong khng kh n khi lng khng
i c hn hp rn A1. Cho A1 vo nc d khuy u c dung dch B cha 2 cht tan v phn khng tan C1.
Cho kh CO d qua bnh cha C1 nung nng c hn hp rn E (Cho cc phn ng xy ra hon ton). E cha ti
a
A. 2 n cht v 1 hp cht. B. 2 n cht v 2 hp cht.
C. 3 n cht. D. 1 n cht v 2 hp cht.
Cu 25: Cho phn ng sau: 2SO2(k) + O2(k) 2SO3(k) ; AH < 0
cn bng trn chuyn dch theo chiu thun th: (1): tng nhit , (2): tng p sut, (3): h nhit , (4): dng
xc tc l V2O5, (5): gim nng SO3. Bin php ng l:
A. 2, 3, 4, 5. B. 1, 2, 3, 4, 5. C. 2, 3, 5. D. 1, 2, 5.
Cu 26: X l tetrapeptit c cng thc Gly Ala Val Gly. Y l tripeptit c cng thc Gly Val Ala. un m gam hn
hp A gm X, Y c t l mol tng ng l 4:3 vi dung dch KOH va sau khi phn ng xy ra hon ton c cn dung
dch thu c 257,36g cht rn khan. Gi tr ca m l:
Cu 27: un nng 10,71 gam hn hp X gm propyl clorua v phenyl clorua vi dung dch NaOH long, va
v un nng, sau thm tip dung dch AgNO3 n d vo hn hp sau phn ng thu c 8,61 gam kt ta, cc
phn ng xy ra hon ton. Khi lng phenyl clorua c trong hn hp X l:
A. 6,0 gam. B. 2,71 gam. C. 4,71 gam D. 4,0 gam.
Cu 28: Cho m gam hn hp X gm axit glutamic v alanin tc dng vi dung dch HCl d. Sau phn ng lm bay
hi cn thn dung dch thu c (m + 11,68) gam mui khan. Nu cho m gam hn hp X tc dng vi dung dch
KOH va , sau phn ng lm bay hi cn thn dung dch thu c (m + 19) gam mui khan. Gi tr ca m l:
Cu 29: Hn hp X gm 2 este n chc. Cho 0,5 mol X tc dng vi dung dch AgNO3/NH3 d thu c 43,2g Ag.
Cho 14,08g X tc dng vi dung dch KOH va thu c hn hp 2 mui ca 2 axit ng ng lin tip v
8,256g hn hp 2 ancol no n chc ng ng lin tip, mch h. Cng thc ca 2 ancol l:
A. C4H9OH v C5H11OH B. CH3OH v C2H5OH C. C2H5OH v C3H7OH D. C3H7OH v C4H9OH
Cu 30: Mt hp cht hu c A gm C, H, O c 50% oxi v khi lng. Ngi ta cho A qua ng ng 10,4 gam
CuO nung nng thu c 2 cht hu c v 8,48 gam cht rn. Mt khc cho hn hp 2 cht hu c trn tc dng
vi dung dch AgNO3(d) trong NH3 to ra hn hp 2 mui v 38,88 gam Ag. Khi lng ca A cn dng l
Cu 31: Cc cht u b thy phn trong dung dch NaOH long, nng l
A. nilon-6, tinh bt, saccaroz, t visco, anlyl clorua, poliacrilonitrin, phenyl bromua
B. vinyl clorua, glyxylalanin, poli(etylen-terephtalat), poli(vinyl axetat), nilon-6,6.
C. nilon-6, protein, nilon-7, anlyl clorua, vinyl axetat.
D. mantoz, protein, poli(etylen-terephtalat), poli(vinyl axetat), tinh bt.
Cu 32: Xt phn ng ho hc: A(kh) + 2B(kh) C(kh) + D(kh). Tc ca phn ng c tnh theo biu thc: v
= k[A].[B]
2
, trong k l hng s tc phn ng; [A] v [B] nng mol/lt ca cc cht A, B tng ng. Khi nng
ca cht B tng 3 ln, nng ca cht A gim 6 ln th tc phn ng so vi trc l
A. gim 1,5ln B. tng 1,5 ln C. tng 3 ln D. gim 3 ln
105 | G S T T G R O U P
Cu 33: Ha tan 54,44 gam hn hp X gm PCl3 v PBr3 vo nc c dung dch Y. trung ha hon ton dung
dch Y cn 500 ml dung dch KOH 2,6M. % khi lng ca PCl3 trong X l:
A. 12,125 B. 26,96% C. 8,08% D. 30,31%
Cu 34: Nhit phn 50,56 gam KMnO4 sau mt thi gian thu c 46,72 gam cht rn. Cho ton b lng kh sinh
ra phn ng ht vi hn hp X gm Mg, Fe thu c hn hp Y nng 13,04 gam. Ha tan hon ton hn hp Y
trong dung dch H2SO4 c, nng d thu c 1,344 lt SO2 (ktc). % khi lng Mg trong X l:
A. 52,17% B. 46,15% C. 28,15% D. 39,13%
Cu 35: Amin X c cha vng benzen v c CTPT l C8H11N. X c phn ng th H trong vng benzen vi Br
2
(dd). Khi cho X tc dng vi HCl thu c mui Y c cng thc dng RNH3Cl. S cng thc cu to ca X l
A. 6 B. 8 C. 9 D. 7
Cu 36: Cho s phn ng sau:
O
3
+ dung dch KI Ba(NO
3
)
2

t
0

NaNO
2bo ha
+ NH
4
Cl bo ha
t
0

KMnO
4

t
0

F
2
+ H
2
O SO
2
+ dung dch Cl
2

MnO
2
+ HCl

t
0

Cl
2
+ dung dch NaOH
Ag + O
3
H
2
S + Cl
2

S phn ng to ra n cht l
A. 8 B. 6 C. 5 D. 7
Cu 37: C 4 hp cht hu c c cng thc phn t ln lt l: CH2O, CH2O2, C2H2O3 v C3H4O3.S cht va tc
dng vi Na, va tc dng vi dung dch NaOH, va c phn ng trng gng l
A. 3 B. 2 C. 1 D. 4
Cu 38: Tng s ht c bn trong nguyn t ca nguyn t M, X ln lt l 58 v 52. Hp cht MXn c tng s ht
proton trong mt phn t l 36. Lin kt trong phn t MXn thuc loi lin kt
A. cho nhn B. cng ha tr khng phn cc
C. cng ha tr phn cc D. ion
Cu 39: Cho s phn ng: C
2
H
5
OH
xt,t
[
X
+R
X
1
Y
+Q
Y
1
] C
2
H
5
OH
Hy chn cc cht X, R, X1, Y, Q, Y1 thch hp trong s cc cht di y: Na, H2O, HBr, C2H4, NaOH, C2H2, Br2, C2H5Br.
A. C2H4, Br2, C2H5Br, H2O, NaOH, HBr; B. C2H4, HBr, C2H2, Br2, Na, NaOH;
C. C2H4, Br2, C2H5Br, NaOH, HBr, H2O. D. C2H4, HBr, C2H5Br, H2O, Na, NaOH;
Cu 40: Nhng 1 thanh kim loi ho tr II vo dung dch CuSO4, sau 1 thi gian ly thanh kim loi ra thy thanh
kim loi gim 0,05% khi lng. Mt khc cng nhng thanh kim loi trn vo dung dch Pb(NO3)2, sau phn ng
ly ra cn li thy khi lng tng 7,1%. Bit s mol 2 mui tham gia phn ng nh nhau. Kim loi M l
A. Fe. B. Cd. C. Zn. D. Mg.
B. PHN RING (10 cu). Th sinh ch c lm 1 trong 2 phn: Phn I hoc phn II
I. THEO CHNG TRNH NNG CAO (10 cu, t cu 41 n cu 50)
Cu 41: Cho s chuyn ho gia cc hp cht ca crom:
Cr(OH)3
KOH
X
Cl
2
+KOH
Y
H
2
SO
4
Z
FeSO
4
+H
2
SO
4
T
Cc cht X, Y, Z, T theo th t l:
A. KCrO2; K2Cr2O7; K2CrO4; CrSO4. B. KCrO2; K2CrO4; K2Cr2O7; Cr2(SO4)3.
C. K2CrO4; KCrO2; K2Cr2O7; Cr2(SO4)3. D. KCrO2; K2Cr2O7; K2CrO4; Cr2(SO4)3.
(1)H
2
(k) +I
2
2HI(k) (2)
1
2
H
2
(k) +
1
2
I
2
(k) HI(k)
(3)HI(k)
1
2
H
2
(k) +
1
2
I
2
(k) (4) 2HI(k) H
2
(k) +I
2
(k)
(5)H
2
(k) +I
2
(r) 2HI(k)
106 | L O V E B O O K . V N
nhit xc nh, nu KC
ca cn bng (1) bng 64 th KC
bng 0,125 l ca cn bng
A. (5). B. (2). C. (3). D. (4).
Cu 43: Cho s chuyn ho: Butan-2-ol
H
2
SO
4
,t
0

X(anken)
HBr
Y
Mg,ete khan
Z. Trong X, Y, Z l sn phm
chnh. Cng thc ca Z l
A. (CH3)3C-MgBr. B. (CH3)2CH-CH2-MgBr.
C. CH3-CH2-CH2 -CH2-MgBr. D. CH3-CH(MgBr)-CH2-CH3.
Cu 44: Axit axetic tc dng vi ancol isopropylic theo phn ng thun nghch:
CH3COOH + C3H7OH CH3COOC3H7 + H2O
Nu ban u ngi ta cho 1 mol axit axetic tc dng vi 1 mol ancol isopropylic th cn bng s t c khi c
0,6 mol isopropyl axetat c to thnh. Lc ngi ta cho thm 1 mol axit axetic vo hn hp phn ng, cn
bng s b ph v v chuyn dch n trng thi cn bng mi. trng thi cn bng mi, s mol ancol isopropylic
l
Cu 45: Cho 16 gam hn hp X gm Fe, Cu, Zn tc dng vi oxi thu c 19,2 gam cht rn Y. Ha tan hon ton
Y trong dung dch H2SO4
c, nng d thy thot ra V lt kh SO2
(ktc). SO2
l sn phm kh duy nht ca H2SO4.
C cn dung dch thu c 49,6 gam hn hp mui khan. Gi tr ca V l:
A. 4,48 lt. B. 3,36 lt. C. 2,80 lt. D. 3,92 lt.
Cu 46: C 3 dung dch mui cha cc anion sau: dd (1): CO
3
2
; dd (2): HCO
3
; dd (3): CO
3
2
, HCO
3
. phn bit
ba dung dch trn c th dng cch no sau y?
A. Cho dd Ba(OH)2 d, lc, cho axit H2SO4 vo nc lc.
B. Cho dd BaCl2 d, lc, cho axit H2SO4 vo nc lc.
C. Cho dd KOH d, lc, cho axit H2SO4 vo nc lc.
D. Cho dd NaCl d, lc, cho axit HCl vo nc lc.
Cu 47: Hn hp X gm hidro, propen, propanal, ancol alylic. t 1 mol hn hp X thu c 40,32 lt CO
2
(ktc).
un nng X vi bt Ni mt thi gian thu c hn hp Y c t khi so vi X bng 1,25. Nu ly 0,1 mol hn hp Y
th tc dng va vi V lt dung dch nc Br
2
0,2M. Gi tr ca V l
A. 0,3 B. 0,25 C. 0,1 D. 0,2
Cu 48: Cho cc cht sau y: 1) CH3COOH, 2) C2H5OH, 3) C2H2, 4) CH3COONa, 5) HCOOCH=CH2, 6) CH3COONH4,
7) C2H4. S cht c to ra t CH3CHO bng mt phng trnh phn ng l:
A. 4. B. 5 C. 3. D. 2.
Cu 49: Cht hu c X c cng thc phn t l C4H9O2N. Cho 5,15 gam X tc dng dung dch NaOH (ly d 25%
so vi lng phn ng) un nng. Sau phn ng hon ton, c cn dung dch thu c 6,05 gam cht rn khan.
Cng thc ca X l:
A. C2H3COONH3-CH3. B. H2N-C3H6COOH.
C. H2N-C2H4COO-CH3. D. H2N-CH2COO-C2H5.
Cu 50: Sau mt thi gian in phn 200ml dung dch CuSO
4
vi in cc graphit, khi lng dung dch gim 8,0
gam. loi b ht ion Cu
2+
cn li trong dung dch sau in phn cn phi dng va ht 8,4 gam bt st (phn
ng vi hiu sut 100%). Nng mol/l ban u ca dung dch CuSO
4
l
A. 1,0M B. 1,25M C. 0,5M D. 0,75M
II. THEO CHNG TRNH CHUN (10 cu, t cu 51 n cu 60)
Cu 51: Cho bt Fe vo dung dch NaNO3 v H2SO4. n phn ng hon thu c dung dch A, hn hp kh X gm
NO v H2 c v cht rn khng tan. Bit dung dch A khng cha mui amoni. Trong dung dch A cha cc mui:
A. FeSO4, Na2SO4. B. FeSO4, Fe2(SO4)3, NaNO3, Na2SO4.
C. FeSO4, Fe(NO3)2, Na2SO4. D. FeSO4, Fe(NO3)2, Na2SO4, NaNO3.
Cu 52: Cho cc cht CH3 -CHCl2; ClCH=CHCl; CH2=CH-CH2Cl, CH2Br-CHBr-CH3; CH3-CHCl-CHCl-CH3; CH2Br-CH2-
CH2Br. S cht khi tc dng vi dung dch NaOH long un nng to ra sn phm c kh nng phn ng vi
Cu(OH)2 l:
A. 2 B. 4 C. 5 D. 3
107 | G S T T G R O U P
Cu 53: Trn cc dung dch HCl 0,75M; HNO3 0,15M; H2SO4 0,3M vi cc th tch bng nhau th c dung dch X.
Trn 300 ml dung dch X vi 200 ml dung dch Ba(OH)2 0,25M thu c m gam kt ta v dung dch Y c pH = x.
Gi tr ca x v m ln lt l:
A. 1 v 2,23 gam B. 2 v 2,23 gam C. 2 v 1,165 gam D. 1 v 6,99 gam
Cu 54: Hn hp X gm 0,15 mol Mg v 0,1 mol Fe cho vo 500ml dung dch Y gm AgNO3 v Cu(NO3)2; sau khi
phn ng xong nhn c 20 gam cht rn Z v dung dch E; cho dung dch NaOH d vo dung dch E, lc kt ta
nung ngoi khng kh nhn c 8,4 gam hn hp 2 oxit. Nng mol/l ca AgNO3 v Cu(NO3)2 ln lt l
Cu 55: Cho s : C
2
H
4

+Br
2

X
+KOH/C
2
H
5
OH,t
0
Y
+AgNO
3
/NH
3
Z
+HBr
Y. Y l
A. C2H4. B. C2H6. C. C2H2. D. C2H5OH.
Cu 56: Hn hp X gm ankin Y v H2
c t l mol l 1 : 2. Dn 13,44 lt hn hp X (ktc) qua Ni, nung nng thu
c hn hp Z c t khi so vi H2
l 11. Dn hn hp Z qua dung dch Br2
d, sau phn ng hon ton thy
c 32 gam Br2
phn ng. Cng thc ca ankin Y l:
A. C4H6. B. C5H8. C. C2H2. D. C3H4.
Cu 57: Hn hp X gm CnH2n1CHO, CnH2n1COOH, CnH2n1CH2OH (u mch h, n e N*). Cho 2,8 gam X phn ng
va 8,8 gam brom trong nc. Mt khc, cho ton b lng X trn phn ng vi lng d dung dch AgNO3
trong NH3, kt thc phn ng thu c 2,16 gam Ag. Phn trm khi lng ca CnH2n1CHO trong X l
A. 26,63%. B. 20,00%. C. 22,22%. D. 16,42%.
Cu 58: Cho 0,01 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,10M. Mt khc 0,02 mol X tc dng
va vi 10 gam dung dch NaOH 8% thu c 2,80 gam mui khan. Cng thc ca X l
A. H2NC3H5(COOH)2 B. (H2N)2C2H3COOH C. H2NC3H6COOH D. (H2N)2C3H5COOH
Cu 59: Cho hn hp gm 0,15 mol CuFeS2 v 0,09 mol Cu2FeS2 phn ng hon ton vi dung dch HNO3 d thu
c dung dch X v hn hp kh Y gm NO v NO2. Thm BaCl2 d vo dung dch X thu c m gam kt ta. Mt
khc, nu thm Ba(OH)2 d vo dung dch X, ly kt ta nung trong khng kh n khi lng khng i thu c
a gam cht rn. Gi tr ca m v a ln lt l
A. 112,84 v 157,44 B. 111,84 v 157,44 C. 111,84 v 167,44 D. 112,84 v 167,44
Cu 60: Cho phng trnh ha hc: Mg + HNO3 Mg(NO3)2 + NO + N2O + N2 + H2O (bit t l th tch ca NO: N2O
: N2 = 27 : 2: 11). Sau khi cn bng ha hc trn vi cc h s l nguyn t ti gin th h s ca H2O l
A. 520 B. 207 C. 53 D. 260

P N

1B 2A 3C 4B 5B 6C 7A 8D 9B 10D
11A 12C 13A 14D 15B 16C 17A 18A 19B 20A
21A 22C 23D 24A 25C 26B 27A 28B 29C 30A
31C 32B 33D 34D 35C 36A 37A 38D 39D 40C
41B 42C 43D 44A 45B 46B 47B 48A 49C 50B
51A 52D 53D 54C 55C 56D 57B 58D 59B 60D

108 | L O V E B O O K . V N
s 15

Cu 1: Ho tan hon ton a gam Al2O3 trong 400 ml dung dch HNO3 2M thu c dung dch X. Thm 600 ml dung dch
NaOH 1M vo dung dch X th thu c 7,8 gam kt ta. Vy gi tr ca a tng ng l
Cu 2: Hn hp X gm axit fomic, axit acrylic, axit oxalic v axit axetic . Cho m gam X phn ng ht vi dung dch NaHCO3
thu c 0,672 lt CO2 (ktc). t chy hon ton m gam X cn 1,008 lt O2 (ktc), thu c 2,42 gam CO2 v a gam H2O.
Gi tr ca a l
A. 1,80. B. 0,72 C. 1,44. D. 1,62.
Cu 3: Cho ho n h p X gm KMnO4 va MnO2 va o dung dich HCl c, d un nng (phn ng hon ton), thy thot ra kh
Cl2. Xc nh % khi lng ca MnO2 trong hn hp X, bit rng HCl b kh chim 60% lng HCl phn ng.
A. 26,9% B. 21,59% C. 52,4% D. 45,2%
Cu 4: Cho m gam bt st vo 200 ml dung dch HNO3 4M, un nng, sau phn ng hon ton thy thot ra kh NO (sn
phm kh duy nht ca HNO3) v dung dch ch cha 52,6 gam mui. Vy gi tr ca m tng ng l
Cu 5: Cho m gam dung dch H2SO4 nng C% tc dng ht vi mt lng hn hp hai kim loi Kali v Magie (dng
d), thy khi lng kh hiro bay ra l 0,05m gam. Gi tr ca C l:
A. 19,73%. B. 15,80%. C. 17,93%. D. 18,25%.
: Tnh th tch dung dch NaOH 1M ln nht cn cho vo dung dch cha 0,1 mol H
2
SO
4
v 0,2 mol ZnSO
4
sau phn
ng hon ton thu c 9,9 gam kt ta?
A. 0,6 lt B. 0,8 lt C. 0,4 lt D. 1,0 lt
Cu 7: Dung dch X gm cc cht tan: AgNO3, Al(NO3)3, Cu(NO3)2, Zn(NO3)2. Chia dung dch X lm hai phn ri thc hin
hai th nghim sau: Cho dung dch NaOH d vo phn 1 v cho dung dch NH3 d vo phn 2.
Tng s cht kt ta thu c c hai th nghim l:
A. 2. B. 3. C. 4. D. 5.
Cu 8: Cho cc nguyn t sau : X(Z = 8), Y(Z = 13), M (Z = 15) v T (Z = 19). S sp xp no ng vi chiu tng dn m
in ca cc nguyn t ?
A. T, M, Y, X B. X, Y, M, T C. T, Y, M, X D. Y, T, X, M
Cu 9: t chy hon ton 20 ml hi hp cht hu c X (ch gm C, H, O) cn va 110 ml kh O2, thu c 160 ml hn
hp Y gm kh v hi. Dn Y qua dung dch H2SO4 c (d), cn li 80 ml kh Z. Bit cc th tch kh v hi o cng iu
kin. S ng phn X tc dng c Na gii phng kh l
A. 3 B. 5 C. 4 D. 6
Cu 10: Cho cc cht sau: FeS, Fe3O4, NaCl, NaI, Na2CO3 v Cu2O tc dng vi dung dch H2SO4 c . S phn ng m trong
, H2SO4 ng vai tr cht oxi ha?
A. 6 B. 4 C. 3 D. 5
Cu 11: Cho phng trnh ha hc: Fe3O4 + HNO3
Fe(NO3)3 + NaOb + H2O.

Sau khi cn bng phng trnh ha hc trn vi h s ca cc cht l nhng s nguyn, ti gin th h s ca H2O l
A. 45a 18b. B. 13a 9b. C. 46a 18b. D. 23a 9b.
Cu 12: X phng ha hon ton 13,2 gam hn hp hai este HCOOC3H7 v CH3COOC2H5 bng dung dch NaOH, thu c
hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 140
o
C, sau khi phn ng xy ra hon ton thu c m gam
nc . Gi tr ca m l
A. 1,35 B. 2,7 C. 5,4 D. 4,05.
Cu 13: un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp gm cc ete . Ly 3,6 gam mt
trong cc ete em t chy hon ton, thu c 4,48 lt kh CO2 ( ktc) v 3,6 gam H2O. Hai ancol l
A. CH3OH v C3H7OH. B. C2H5OH v CH2=CH-CH2-OH.
C. CH3OH v CH2=CH-CH2-OH. D. C2H5OH v CH3OH.
109 | G S T T G R O U P
Cu 14: Ho tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu c dung dch X v 1,344 lt ( ktc) hn
hp kh Y gm hai kh l N2O v N2. T khi ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X thu c m gam cht
rn khan. Gi tr ca m l
A. 97,98. B. 106,38. C. 38,34. D. 34,08.
Cu 15: Gi s trong bnh kn, ti 80
0
C tn ti cn bng sau:
2NO + O2 2NO2 (1) Hp =?
Khi h nhit bnh xung 40
0
C, thy mu ca hn hp m hn. Vy kt lun no sau y ng?
A. Hp < 0, phn ng to nhit. B. Hp > 0, phn ng to nhit.
C. Hp < 0, phn ng thu nhit. D. Hp > 0, phn ng thu nhit.
Cu 16: e m (g) phoi ba o sa t (A) ngoa i kho ng khi mo t th i gian bien tha nh ho n h p B co kho i l ng 30 gam go m FeO,
Fe3O4, Fe2O3, Fe . Cho B pha n ng hoa n toa n v i dung dich HNO3 thay gia i pho ng ra 5,6 lit khi NO duy nhat (ktc). Gia tr
cu a m la :
A. 27,5 g B. 22,5 g C. 26,2 g D. 25,2 g
Cu 17: Hn hp kh X gm H2 v mt anken c t khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn
ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. S ng
phn anken tha mn l
A. 2 B. 3 C. 4. D. 5
Cu 18: t chy hon ton hn hp gm FeS2 v Ag2S vi s mol bng nhau thu c 3,696 lt SO2 (ktc) v cht rn B .
Cho B tc dng vi H2SO4 long d, sau phn ng hon ton thy cn li m gam cht rn khng tan. Gi tr ca m l:
A. 11,88 gam B. 13,64 gam C. 17,16 gam D. 8,91gam
Cu 19: Cht hu c X c cng thc phn t C3H5Cl. S ng phn ca X l:
A. 4 B. 3 C. 6 D. 5
Cu 20: Ho tan 28,4g photpho (V) oxit trong 500 gam dung dch axit photphoric c nng 9,8%. Nng phn trm
ca dung dch axit photphoric thu c l
A. 16,7%. B. 17,6%. C. 13,0%. D. 14,7%.
Cu 21: Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 350 ml dung dch
HCl 1M vo 100 ml dung dch X, sinh ra V lt kh ( ktc). Gi tr ca V l
A. 1,12. B. 3,36. C. 2,24. D. 4,48.
Cu 22: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC . tng hp 150 kg PVC theo s trn th cn V m
3
kh
thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca tng giai on l 80%)
A. 262,50. B. 131,25. C. 134,40. D. 168,00.
Cu 23: Hn hp kh X gm xiclopropan, etan, propen, buta-1,3-ien c t khi so vi H2 l 18. t chy hon ton 0,05
mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng dung dch gim m gam.
Gi tr ca m l
A. 4,3 B. 9,8 C. 2,7 D. 8,2
(1) Cu(NO3)2
t
0

(2) H2NCH2COOH + HNO2 (3) NH3 + CuO
t
0

(4) NH4NO2
t
0

(5) C6H5NH2 + HNO2
HCl(05
0
)
(6) (NH4)2CO3
t
0

S phn ng thu c N2 l :
A. 4, 5, 6. B. 2, 3, 4. C. 1, 2, 3. D. 3, 4, 5.
Cu 25: Cho 21 gam hn hp X gm kim loi kim R v Al vo H2O d c 11,2 lt kh (ktc) v 4,5 gam cht rn khng
tan. Tm R?
A. Li B. Na C. K D. Rb
Cu 26: 20
0
C Fe c D = 7,87 g/cm
3
, nguyn t khi trung bnh l 55,85, gi thit cc khe rng chim 26% th tch tinh
th. Bn knh nguyn t gn ng ca Fe l
A. 1,38 A
0
. B. 1,26 A
0
. C. 1,28 A.
0
D. 1,18 A
0
.
110 | L O V E B O O K . V N
Cu 27: Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M (un
nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to ca X l
A. CH3 -COO-CH=CH-CH3. B. CH3-CH2-COO-CH=CH2.
C. CH2=CH-CH2-COO-CH3. D. CH2=CH-COO-CH2-CH3.
Cu 28: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln
hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn
Y thu c m gam cht rn. Gi tr m l
A. 29,75. B. 24,25. C. 27,75. D. 26,25.
Cu 29: Cho dy cc cht: C3H6, CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6
(benzen). S cht trong dy lm mt mu dung dch brom l
A. 8. B. 7. C. 5. D. 6.
Cu 30: t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng) ri em ton b sn phm chy
hp th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn ng thu c 39,4 gam kt ta v khi lng phn dung dch
gim bt 19,912 gam. Cng thc phn t ca X l
A. CH4. B. C2H4. C. C3H4. D. C4H10.
(a) Cht bo c gi chung l triglixerit hay triaxylglixerol.
(b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c.
(c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch.
(d) Tristearin, triolein c cng thc ln lt l: (C17H35COO)3C3H5, (C17H33COO)3C3H5.
S pht biu ng l
A. 4. B. 1. C. 3. D. 2.
Cu 32: Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH (4), NH3 (5) (C6H5- l gc phenyl). Dy cc
cht sp xp theo th t lc baz gim dn l:
A. (4), (1), (5), (2), (3). B. (4), (2), (5), (1), (3). C. (4), (2), (3), (1), (5). D. (3), (1), (5), (2), (4).
Cu 33: Este X khng no, mch h, c t khi hi so vi oxi bng 2,6875 v khi tham gia phn ng x phng ho to ra
mt anehit v mt mui ca axit hu c. C bao nhiu cht ph hp vi X ?
A. 3. B. 4. C. 2. D. 5.
Cu 34: A l hn hp kh gm N2 v H2 c t khi so vi oxi bng 0,225. Dn A vo bnh c Ni un nng, phn ng tng
hp amoniac xy ra th thu c hn hp kh B c t khi so vi oxi bng 0,25. Hiu sut ca qu trnh tng hp NH3 l
A. 20%. B. 15%. C. 25% D. 30%.
Cu 35: Cc cht: mantoz, glucoz, fructoz v saccaroz c tnh cht chung l:
A. phn ng vi Cu(OH)2 to dung dch xanh lam
B. phn ng vi Cu(OH)2, t
o
c kt ta gch
C. phn ng vi AgNO3/NH3 cho Ag kt ta
D. thy phn trong mi trng axit cho monosaccarit nh hn
Cu 36: Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sau khi cc phn ng xy
ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v
V ln lt l
A. 10,8 v 4,48. B. 17,8 v 4,48. C. 17,8 v 2,24. D. 10,8 v 2,24.
Cu 37: Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v
un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z
i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l
Cu 38: Thu phn hn hp gm 0,03 mol saccaroz v 0,02 mol mantoz mt thi gian thu c dung dch X (hiu sut
phn ng thy phn mi cht u l 80%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO3 trong NH3 th
lng Ag thu c l
A. 0,056mol. B. 0,095 mol. C. 0,16 mol. D. 0,168 mol.
111 | G S T T G R O U P
Cu 39: Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat,
anlyl clorua . S cht trong dy tc dng c vi dung dch NaOH long, un nng l
A. 4. B. 3. C. 5. D. 6.
Cu 40: Dy cc cht no sau y m phn t phn cc ?
A. CO2, HF, NH3 B. HCl, H2O, SO2 C. NH3, CO2, SO2 D. Cl2, SO2, CH4
II. PHN RING [10 cu]Th sinh ch c lm mt trong hai phn (phn A hoc B)
Cu 41: Cho cc dung dch sau: saccaroz, fructoz, etilenglicol, anehit axetic, axeton, anbumin, mantoz, metanol, axit
fomic . S lng dung dch c th phn ng vi Cu(OH)2 iu kin thng l
A. 5 B. 4 C. 6 D. 7
Cu 42: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH
0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cngthc phn t ca X l
A. C3H7COOH B. HCOOH. C. C2H5COOH. D. CH3COOH.
Cu 43: Cho 0,01 mol mt este ca axit hu c phn ng va vi 100ml dung dch NaOH 0,2M, sn phm to thnh
ch gm 1 ancol v 1 mui c s mol bng nhau. Mt khc khi x phng ho hon ton 1,29 gam este bng lng va
60 ml dung dch KOH 0,25M. Sau khi kt thc phn ng, em c cn dung dch thu c 1,665 gam mui khan. Este
c cng thc phn t l
A.
C
3
H
6
COOCH
2
COOCH
2
B.
C
2
H
4
COOCH
2
COOCH
2
C. C
3
H
7
COOC
2
H
5
D.
C
4
H
8
COOCH
2
COOCH
2

Cu 44: Ha tan hon ton 30,4 g cht rn X gm Cu, CuS, Cu2S v S bng HNO3 d, thot ra 20,16 lt kh NO duy nht
(ktc) v dung dch Y. Thm Ba(OH)2 d vo Y thu c m (g) kt ta . Gi tr ca m l
A. 119,5g B. 112g C. 115,9g D. 110,95g
Cu 45: Hy cho bit trong cc ha cht sau: NaClO, KMnO4, CaOCl2, Na2CO3, Na2ZnO2 v AgNO3. Hy cho bit dung dch
HCl tc dng c vi bao nhiu dung dch?
A. 6 B. 3 C. 5 D. 4
Cu 46: Khi lng dung dch KOH 8% cn ly cho tc dng vi 47g K2O thu c dung dch KOH 21% l:
A. 250 g B. 320g C. 354,85g D. 400g
Cu 47: Thy phn khng hon ton pentapeptit X ngi ta thu c tripeptit l Ala-Glu-Gly v cc ipeptit l Val-Ala,
Glu-Gly v Gly-Ala . Vy cng thc cu to ca X l
A. Ala-Val-Glu-Gly-Ala B. Gly-Ala-Val-Ala-Glu C. Val-Ala-Glu-Gly-Ala D. Ala-Glu-Gly-Ala-Val
Cu 48: Hn hp rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan hon ton trong dung dch
A. NaOH (d). B. AgNO3 (d). C. NH3(d). D. HCl (d).
(1) dung dch AlCl3 + dung dch Na[Al(OH)4]; (2) dung dch NaOH d + dung dch AlCl3;
(3) kh CO2 (d) + dung dch Na[Al(OH)4]; (4) Na[Al(OH)4] (d) + dung dch HCl;
(5) kh CO2 (d) + dung dch Ba(OH)2.
Nhng th nghim thu c kt ta sau phn ng l:
A. (2), (3), (5) B. (1), (2), (5) C. (1), (3), (4) D. (1), (2), (4)
Cu 50: Thu phn 51,3 gam mantoz trong mi trng axit vi hiu sut phn ng t 80% thu c hn hp X. Trung
ho X bng NaOH thu c dung dch Y. Cho Y tc dng ht vi lng d dung dch AgNO3 trong NH3 un nng, sinh ra
m gam Ag. Gi tr ca m l
A. 58,32. B. 51,84. C. 32,40. D. 58,82.
Cu 51: Cho cc dung dch cha cc cht tan : glucoz, fructoz, saccaroz, mantoz, axit fomic, glixerol, vinyl axetat,
anehit fomic . S dung dch va ho tan Cu(OH)2 va lm mt mu nc brom l
A. 4. B. 3. C. 5. D. 6.
112 | L O V E B O O K . V N
Cu 52: Cho 8,04 gam hn hp kh v hi gm anehit axetic v axetilen tc dng hon ton vi dung dch AgNO3 trong
NH3 thu c 55,2 gam kt ta . Lc ly kt ta sau cho vo dung dch HCl d, sau khi kt thc phn ng thy c m
gam cht khng tan. Gi tr ca m l:
A. 61,78 B. 21,6 C. 41,69 D. 55,2
Cu 53: Thuc th no trong cc trng hp sau c th dng phn bit c 5 kim loi: Mg, Zn, Fe, Ba, Ag.
A. Dung dch HCl B. Dung dch NaOH
C. H2O D. Dung dch H2SO4 long
Cu 54: Cho cc cht sau: Fe, Mg, Cu, AgNO3, CuCl2, Fe(NO3)2. S cp cht tc dng vi nhau l?
A. 7. B. 9 C. 6 D. 8.
Cu 55: Ho tan hon ton 74 gam hn hp X gm FeO, Fe
3
O
4
, Fe
2
O
3
bng dung dch H
2
SO
4
long d sinh ra 178 gam
mui sunfat. Nu cng cho 74 gam hn hp X trn phn ng vi lng d kh CO nhit cao v dn sn phm kh qua
dung dch nc vi trong d th khi lng kt ta thu c l (cc phn ng xy ra hon ton)
A. 240 g B. 130 g C. 150 g D. 180 g
Cu 56: Ho a tan 12 gam Mg trong V ml dung dich HNO3 2M thu c 2,24 lit khi N2O (ktc) va dung dich X. Co ca n dung
dich X thu c m (g) muo i khan. Gia tri cu a V va m la n l t la :
A. 625; 74 B. 500; 76 C. 500; 74 D. 625; 76
Cu 57: Cho 0,1 mol axit cacboxylic n chc X tc dng vi 0,15 mol ancol n chc Y thu c 4,5 gam este vi hiu
sut 75%. Vy tn gi ca este l:
A. metyl axetat B. etyl axetat C. etyl propionat D. metyl fomiat
Cu 58: Nh t t n ht dung dch cha 0,1 mol Na2CO3 v 0,3 mol NaHCO3 vo 150 ml dung dch H2SO4 1M thu c
kh CO2 v dung dch X. Cho dung dch Ba(OH)2 d vo dung dch X th thu c kt ta c khi lng l
Cu 59: Trn ln dung dch cc cp cht sau:
(1) Na[Al(OH)4] + CO2 (d) (2) Ca(OH)2 (d) + Mg(HCO3)2, (3) CuSO4 + NH3 (d),
(4) Na2CO3 (d) + FeCl3 (5) KOH (d) + Ca(H2PO4)2 (6) Na2CO3 + AgNO3 (d)
C bao nhiu trng hp to thnh kt ta?
A. 3 B. 4 C. 2 D. 5
Cu 60: t chy hon ton mt amin, no, n chc, mch h. Sn phm chy sau khi ngng t hi nc c t khi so vi
H2 l 19,333. Cng thc phn t ca amin l
A. CH3NH2 B. C2H5NH2 C. C3H7NH2 D. C4H9NH2

P N

1A 2B 3B 4C 5B 6B 7B 8C 9B 10B
11D 12A 13C 14B 15A 16D 17C 18A 19D 20A
21D 22A 23A 24B 25C 26C 27B 28D 29D 30C
31A 32B 33A 34C 35A 36C 37A 38D 39C 40B
41C 42D 43D 44D 45A 46C 47C 48D 49C 50A
51B 52B 53D 54D 55B 56D 57D 58B 59D 60A

113 | G S T T G R O U P
s 16

A. un ancol etylic 140C (xc tc H
2
SO
4

c) thu c imetyl ete.
B. Khi un C
2
H
5
Br vi dung dch KOH ch thu c etilen.
C. Dy cc cht: C
2
H
5
Cl, C
2
H
5
Br, C
2
H
5
I c nhit si tng dn t tri sang phi.
D. Dung dch phenol lm phenolphtalein khng mu chuyn thnh mu hng.
Cu 2: Cho cn bng sau: A2(k) + 3B2(k) 2D(k). Khi tng nhit , t khi ca hn hp kh gim. Pht biu no
sau y ng?
A. Phn ng thun l thu nhit. Khi tng nhit , cn bng (1) chuyn dch v phn ng thun
B. Phn ng thun l ta nhit. Khi tng nhit , cn bng (1) chuyn dch v phn ng nghch
C. Phn ng thun l thu nhit. Khi tng nhit , cn bng (1) chuyn dch v phn ng nghch
D. Phn ng thun l ta nhit. Khi tng nhit , cn bng (1) chuyn dch v phn ng thun
(a) C
3
H
4
O
2

+ NaOH X + Y
(c) Z + dung dch AgNO
3
/NH
3
(d) E + Ag + NH
4
NO
3

(b) X + H
2
SO
4
(long) Z + T (d) Y + dung dch AgNO
3
/NH
3
(d) F + Ag + NH
4
NO
3

Cht E v cht F theo th t l

A. (NH
4
)
2
CO
3
v CH
3
COOH. B. (NH
4
)
2
CO
3
v CH
3
COONH
4
.
C. HCOONH
4

v CH
3
CHO. D. HCOONH
4

v CH
3
COONH
4

Cu 4: Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng
c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N
ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va
dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l
A. H
2
NC
2
H
4
COOH. B. CH
2
=CHCOONH
4
. C. H
2
NCOO-CH
2
CH
3
. D. H
2
NCH
2
COO-CH
3
.
A. Nc kh thuc loi tinh th phn t.
B. Thch anh c cu trc tinh th phn t.
C. th rn, NaCl tn ti di dng tinh th phn t.
D. Photpho trng c cu trc tinh th nguyn t.
Cu 6: Cho cc phn ng sau: (1) AgNO3
+ Fe(NO3)2
Fe(NO3)3
+ Ag
(2) Mn + 2HCl MnCl2
+ H2 (3) 3Ag + 4HNO3 3AgNO3 + NO + 2H2O
Th t tng dn tnh oxi ha ca cc ion l
A. NO
3
(H
+
), Ag
+
; Fe
3+
; Mn
2+
B. Mn
2+
; Fe
3+
; Ag
+
; NO
3
(H
+
)

C. Mn
2+
; Fe
3+
; NO
3
(H
+
), Ag
+
.
D. NO
3
(H
+
), Mn
2+
; Fe
3+
; Ag
+
.

Cu 7: Cho dy cc hp cht thm: p HO CH
2
C
6
H
4
OH, mHO C
6
H
4
CH
2
OH, p HO C
6
H
4
COOC
2
H
5
, p HO C
6
H
4
COOH, p HCOO C
6
H
4
OH, p CH
3
O C
6
H
4
OH. C bao nhiu cht trong dy
tha mn ng thi 2 iu kin sau? (a) Ch tc dng vi NaOH theo t l mol 1 : 1.
(b) Tc dng c vi Na (d) to ra s mol H
2
bng s mol cht phn ng.
A. 1. B. 2. C. 3. D. 4.
Cu 8: Cho 10,92 gam Fe vo 600 ml dung dch HNO3
1M, n khi phn ng xy ra hon ton, thu c kh NO
(sn phm kh duy nht) v dung dch X. Dung dch X c th ho tan ti a m gam Cu. Gi tr ca m l
A. 1,92 B. 1,29. C. 1,28 D. 6,4
Cu 9: Cho cc dung dch: HCl(X1); KNO3(X2); HCl +KNO3(X3); Fe2(SO4)3(X4). Dung dch no c th ho tan c
bt Cu?
A. X1, X2, X3, X4 B. X3, X2 C. X1, X4, X2 D. X3, X4
114 | L O V E B O O K . V N
Cu 10: Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau tc dng ht vi lng d dung
dch HCl long, nng thu c dung dch Y v kh H2. C cn dung dch Y thu c 29,185 gam mui khan. Nu
cho m gam hn hp X tc dng hon ton vi O2
(d) to hn hp 3 oxit th th tch kh O2
(ktc) phn ng
l
A. 1,3104 lt. B. 1,008 lt C. 3,276 lt D. 1,344 lt.
Cu 11: Khi nhit phn hon ton tng mui X, Y u to ra s mol kh nh hn s mol mui tng ng. t
mt lng nh tinh th Y trn n kh khng mu, thy ngn la c mu tm. Hai mui X, Y ln lt l
A. Cu(NO3)2, KNO3. B. CaCO3, KNO3. C. KMnO4, KNO3. D. KNO3, NaNO3.
Cu 12: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH
0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau
hp th ht sn phm chy vo bnh ng dung dch Ca(OH)
2
(d) th khi lng dung dch trong bnh gim 2,66
gam. Cng thc ca hai hp cht hu c trong X l
A. HCOOH v HCOOC
2
H
5
. B. C
2
H
5
COOH v C
2
H
5
COOCH
3
.
C. HCOOH v HCOOC
3
H
7
. D. CH
3
COOH v CH
3
COOC
2
H
5

Cu 13: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 5,696 gam Ala, 6,4
gam Ala-Ala v 5,544 gam Ala-Ala-Ala. Gi tr ca m l
A. 13,288. B. 18,12. C. 22,348. D. 16,308.
Cu 14: Cho cc pht biu sau: Trong pin Zn - Cu
(1) Zn l anot (-) xy ra qu trnh kh: Zn Zn
2+
+ 2e
(2) Cu l catot (+) xy ra qu trnh kh: Cu
2+
+ 2e Cu
(3) Dng in mch ngoi c chiu t in cc Cu sang in cc Zn
(4) Cc ion dng trong cu mui di chuyn v pha in cc Cu
Cc pht biu ng l
A. 2, 3, 4 B. 1, 3, 4 C. 2, 4 D. 1, 2, 3
Cu 15: Pht biu khng ng l:
A. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li thu c
phenol.
B. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu c anilin.
C. Dung dch natri phenolat phn ng vi kh CO
2
, ly kt ta va to ra cho tc dng vi dung dch NaOH li
thu c natri phenolat
D. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO
2
li thu
c axit axetic.
Cu 16: Cho cc cht sau: glucoz, glixerol, fructoz, mantoz, C2H5OH, HCOOH, C2H2, HCOOCH3, phenol, C6H5CHO,
axit oxalic, axit picric. S cht c phn ng trng bc l:
A. 8 B. 6 C. 7 D. 5
Cu 17: Ho tan hon ton 12,15 gam Al bng dung dch HNO
3
long (d), thu c dung dch X v 1,344 lt (
ktc) hn hp kh Y gm hai kh l N2O v N2. T khi ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X,
thu c m gam cht rn khan. Gi tr ca m l
A. 103,95 B. 106,65 C. 45,63 D. 95,85
(1) t thanh thp cacbon trong bnh kh clo
(2) Nhng thanh km nguyn cht vo dung dch FeSO4
(3) Hp kim ng thau(Cu Zn) trong khng kh m
(4) a st ty b xy xc su n lp bn trong ngoi khng kh.
Th nghim no xy ra n mn in ha hc?
A. 1, 3, 4 B. 4 C. 3, 4 D. 2, 3, 4
115 | G S T T G R O U P
Cu 19: Cho dung dch cha 19,38 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t c trong t nhin,
hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX
< ZY) vo dung dch AgNO3

(d), thu c 39,78 gam kt
ta. Phn trm khi lng ca NaX trong hn hp ban u l
A. 36,32%. B. 42,23%. C. 16,32%. D. 16,23%.
Cu 20: Cho cc hp cht hu c:
(1) ankan; (2) ancol no, n chc, mch h;
(3) xicloankan; (4) ete no, n chc, mch h;
(5) anken; (6) ancol khng no (c mt lin kt i C=C), mch h;
(7) ankin; (8) anehit no, n chc, mch h;
(9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc.
Dy gm cc cht khi t chy hon ton u cho s mol CO
2
bng s mol H
2
O l:
A. (3), (5), (6), (8), (9). B. (3), (4), (6), (7), (10).
C. (2), (3), (5), (7), (9). D. (1), (3), (5), (6), (8).
Cu 21: Cho phng trnh phn ng: Fe3O4 + KMnO4 + KHSO4 Fe2(SO4)3 + MnSO4 + K2SO4 + H2O
H s cn bng (l nhng s nguyn dng ti gin nht) ca H2O trong cn bng trn l
A. 49. B. 47. C. 48. D. 50.
Cu22: Cho cc nguyn t v ion
sau:
17
Cl;
18
Ar;
26
Fe
2+
;
24
Cr
3+
;
16
S
2
;
12
Mg;
25
Mn
2+
;
4
Be
2+
;
21
Sc
3+
;
31
Ga
3+
. S vi ht c cu hnh electron
trng thi c bn ging kh him l
A. 6 B. 4 C. 3 D. 5
Cu 23: X, Y, Z l cc hp cht mch h, bn c cng cng thc phn t C
3
H
6
O. X tc dng c vi Na v khng
c phn ng trng bc. Y khng tc dng c vi Na nhng c phn ng trng bc. Z khng tc dng c vi
Na v khng c phn ng trng bc. Cc cht X, Y, Z ln lt l:
A. CH
3
-CO-CH
3
, CH
3
-CH
2
-CHO, CH
2
=CH-CH
2
-OH. B. CH
2
=CH-CH
2
-OH, CH
3
-CO-CH
3
, CH
3
-CH
2
-CHO.
C. CH
2
=CH-CH
2
-OH, CH
3
-CH
2
-CHO, CH
3
-CO-CH
3
. D. CH
3
-CH
2
-CHO, CH
3
-CO-CH
3
, CH
2
=CH-CH
2
-OH.
Cu 24: Cho cc phn t v ion sau: HSO
4
; C3H6; N2O; N2O5; H2O2; NO

3
; Cl2; H3PO4; C2H5OH; CO2. S phn t v

ion cha lin kt cng ha tr khng phn cc l
A. 6 B. 4 C. 5 D. 3
Cu 25: Cho 0,04 mol mt hn hp X gm CH
2
=CH-CH2OH, CH
3
COOH v CH
2
=CH-CHO phn ng va vi
dung dch NaHCO3 d thu c 0,224 lit kh ktc. Mt khc, 0,04 mol X phn ng cn 1,12 lt H2, xc tc
Ni, un nng. Khi lng ca CH
2
=CH-CH2OH trong X l
Cu 26: T Na2CO3, cn ti thiu bao nhiu phn ng iu ch kim loi natri?
A. 2 B. 3 C. 4 D. 1
Cu 27: t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri hp
th ton b sn phm chy vo dung dch Ca(OH)
2
(d). Sau phn ng thu c 18 gam kt ta v dung dch X.
Khi lng X so vi khi lng dung dch Ca(OH)
2
ban u thay i nh th no?
A. Tng 2,70 gam. B. Gim 7,74 gam. C. Tng 7,92 gam. D. Gim 7,38 gam.
Cu 28: Cho hn hp gm 1,68 gam Fe v 1,344 gam Cu vo 400 ml dung dch cha hn hp gm H
2
SO
4
0,5M
v NaNO
3
0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy
nht). Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu ca
V l
A. 386 B. 365 C. 360 D. 356
Cu 29: Cho 3,87 gam hn hp 2 kim loi Al v Mg vo 250 ml dung dch X gm HCl 1M v H2SO4 0,5 M thu c
dung dch B v 4,368 lt kh H2(ktc). Cho dung dch B tc dng vi V lt dung dch hn hp A gm NaOH 0,2M v
Ba(OH)2 0,1 M. Th tch dung dch A cn thit tc dng vi dung dch B cho kt ta ln nht l
A. 2,75 lt. B. 1,475 lt. C. 1,25 lt. D. 1,2 lt.
116 | L O V E B O O K . V N
A. Trong dung dch, H
2
N-CH
2
-COOH cn tn ti dng ion lng cc H
3
N
+
CH
2
COO
-
.
B. Hp cht H
2
N-CH
2
-COOH
3
N-CH
3
l este ca glyxin (hay glixin).
C. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt.
D. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl.
(1) Cho dung dch FeCl2 tc dng vi dung dch AgNO3
(2) nc Javen trong khng kh mt thi gian.
(3) Bnh nc vi trong ngoi khng kh.
(4) Sc kh sunfur vo dung dch thuc tm.
(5) Ngm dy ng trong bnh ng dung dch HCl trong khng kh h ming bnh.
S th nghim xy ra phn ng oxi ha kh l
A. 4 B. 3 C. 2 D. 5
Cu 32: Hai cht X v Y c cng cng thc phn t C
2
H
4
O
2
. Cht X phn ng c vi kim loi Na v tham gia
phn ng trng bc. Cht Y phn ng c vi kim loi Na v ho tan c CaCO
3
. Cng thc ca X, Y ln
lt l:
A. CH
3
COOH, HOCH
2
CHO. B. HCOOCH
3
, HOCH
2
CHO.
C. HCOOCH
3
, CH
3
COOH. D. HOCH
2
CHO, CH
3
COOH.
A. Poli(etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng.
B. Trng hp stiren thu c poli(phenol-fomanehit).
C. T visco l t tng hp.
D. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N.
Cu 34: Thm t t 100g dd H2SO4 98% vo nc v iu chnh c 1 lt dung dch X. Phi thm vo 1 lt
dung dch X bao nhiu lt dung dch NaOH 1,5M thu c dung dch c pH = 13?
A. 1,24 lt B. 1,50 lt C. 1,14 lt D. 3,00M.
Cu 35: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn
thu c hn hp kh Y. Cho Y qua dung dch H
2
SO
4
c, thu c hn hp kh Z c t khi i vi hiro bng 19.
S ng phn mch h ca X l
A. 1 B. 4 C. 2 D. 3
Cu 36: Cho cc cht: axetilen, vinylaxetilen, metylxiclopropan, cumen, stiren, xiclohexan, xiclopropan v
xiclopentan. Trong cc cht trn, s cht phn ng c vi dung dch brom l
A. 3. B. 6. C. 5. D. 4.
Cu 37: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: K2O v Al2O3 ; Cu v Fe2(SO4)3;
CaCl2
v Na2CO3; Ca v KHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l
A. 1 B. 3 C. 2 D. 4
Cu 38: t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O
2
, thu c 23,52
lt kh CO
2
v 18,9 gam H
2
O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M, c cn dung
dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z (M
Y
< M
Z
). Cc
th tch kh u o iu kin tiu chun. T l a : b l
A. 3 : 5. B. 2 : 3. C. 3 : 2. D. 4 : 3.
Cu 39: Cho 37,95g hn hp hai mui MgCO3 v RCO3 vo 100ml dd H2SO4 long thy c 1,12 lt CO2(ktc) thot
ra, dung dch A v cht rn B. C cn dung dch A thu c 4g mui khan. Nung cht rn B n khi lng khng
i th thu c rn B1 v 4,48 lt CO2 (ktc). Bit trong hn hp u c t l n
RCO
3
: n
MgCO
3
= 3: 2. Khi lng cht
rn B1 v nguyn t R l
A. 27,85g v Ba. B. 26,95g v Ca. C. 27,85g v Ca. D. 26,95g v Ba.
117 | G S T T G R O U P
Cu 40: t chy hon ton 3 lt hn hp X gm 2 anken k tip nhau trong dy ng ng cn va 10,5 lt
O
2
(cc th tch kh o trong cng iu kin nhit , p sut). Hirat ha hon ton X trong iu kin thch
hp thu c hn hp ancol Y, trong khi lng ancol bc hai bng 21/55 ln tng khi lng cc ancol bc
mt. Phn trm khi lng ca ancol bc mt (c s nguyn t cacbon ln hn) trong Y l
A. 46,43%. B. 7,89%. C. 11,84%. D. 31,58%.
II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B)
Cu 41: Cho mt s cht: BaSO4, NaOH, HF, NaHCO3, SO3, H2SO4, C2H5OH, CH3COOH, CaCO3, CH3COONa, C2H5ONa.
C bao nhiu cht cho dung dch cht in li mnh (khi tan trong nc)?
A. 6. B. 4. C. 5. D. 7.
Cu 42: t chy hon ton m gam hn hp X gm axeton, propananehit v axit acrylic, sau phn ng thu c
2,688 lt kh CO2 ( ktc) v 1,98 gam H2O. Gi tr m l
A. 2,46. B. 2,64. C. 1,72. D. 1,27.
Cu 43: Cho 0,2 mol hn hp X gm 2 anehit n chc l ng ng k tip tc dng ht vi dung dch AgNO3
trong NH3 thu c 49,68 gam Ag. T l mol ca 2 anehit trong hn hp X l
A. 1:1. B. 3:17. C. 7:13. D. 1:3.
Cu 44: C cc cp oxi ha/kh (dng oxi ha v dng kh u c s mol bng 1). Cp no cho sau phn ng vi
nhau (vi hiu sut t 100%) m c khi lng cht rn gim l t nht?
A. Al
3+
/Al v Mg
2+
/Mg. B. Zn
2+
/Zn v Fe
2+
/Fe. C. Ni
2+
/Ni v Fe
2+
/Fe. D. Pb
2+
/Pb v Ag
+
/Ag.
Cu 45: Cho s phn ng: K2Cr2O7 + HI + H2SO4 K2SO4 + X + Y + H2O. Bit Y l hp cht ca crom. Cng thc
ha hc ca X v Y ln lt l
A. I2 v Cr(OH)3. B. I2 v Cr(OH)2. C. KI v Cr2(SO4)3. D. I2 v Cr2(SO4)3.
Cu 46: Ngm 3,2 gam bt ng vo dung dch cha ng thi 0,02 mol H2SO4 v 0,04 mol HNO3 th th tch kh
NO ( ktc) thu c ti a l
A. 448 ml. B. 896 ml. C. 747 ml. D. 224 ml.
Cu 47: Thuc th duy nht phn bit 5 dung dch khng mu ng ring bit trong cc l mt nhn AlCl3,
Fe2(SO4)3, Mg(NO3)2, KCl, NH4NO3 l dung dch
A. HCl. B. NaOH. C. BaCl2. D. NH3.
Cu 48: Tin hnh trng hp caprolactam thu c sn phm trng vi sn phm ca phn ng trng ngng cht
no di y?
A. Axit -aminocaproic. B. Axit - aminocaproic.
C. Axit -aminglutaric. D. Axit -aminovaleric.
Cu 49: Thc hin phn ng ln men a gam tinh bt, ton b lng CO2 sinh ra c hp th hon ton vo nc
vi trong (d) thu c a gam kt ta. Hiu sut ca c qu trnh ln men l
A. 75%. B. 85%. C. 90%. D. 81%.
Cu 50: Khi thy phn hon ton mt tripeptit X thu c hn hp Y gm 2 amino axit no, c phn t khi khc
nhau 14, mi aminoaxit cha 1 nhm amino v 1 nhm cacboxyl. S cng thc cu to c th c ca X l
A. 6. B. 5. C. 4. D. 3.
Cu 51: Cho phn ng: N2O4 (k) 2NO2(k). Hng s cn bng Kc ca phn ng ny ch ph thuc vo yu t no
sau y ?
A. Nhit . B. Nng N2O4.
C. Nng NO2. D. T l nng N2O4 v NO2.
Cu 52: Hp cht hu c Y l mt xeton no, n chc c cng thc tng qut CnH2nO. Tng s lin kt trong mt
phn t Y l
A. 3n 1. B. 3n + 1. C. 3n. D. 2n + 3.
118 | L O V E B O O K . V N
Cu 53: Hn hp X cha mui natri ca 2 axit cacboxylic n chc l ng ng k tip. t chy hon ton hn
hp X sn phm thu c gm H2O, Na2CO3 v CO2 trong s mol CO2 ng bng s mol X phn ng. Cng thc
cu to thu gn ca 2 mui trong X l
A. CH3COONa v C2H5COONa. B. C2H5COONa v C3H7COONa
C. C2H3COONa v C3H5COONa. D. CH3COONa v HCOONa.
Cu 54: Trong pin in ho Zn - Pb, in cc m xy ra s
A. oxi ho Pb. B. oxi ho Zn. C. kh Zn
2+
. D. kh Pb
2+
.
Cu 55: Cho 100 ml dung dch H3PO4 vo 100 ml dung dch NaOH 2,5M thu c dung dch cha 20,2 gam hn
hp mui. Nng mol/l ca dung dch H3PO4 l:
A. 1,2M B. 1,4M C. 1,0M D. 1,5M
Cu 56: Dung dch X cha cc ion Fe
3+
, NO
3
, NH
4
+
, Cl

. Chia dung dch X thnh 3 phn bng nhau. Phn 1 tc
dng vi dung dch NaOH d un nng c 6,72 lit kh (ktc) v 21,4 gam kt ta. Phn 2 c cn thu c 56,5
gam mui khan. Cho vo phn 3 dung dch H2SO4 d c th ha tan ti a m gam Cu to ra kh NO. Gi tr ca m l
A. 35,2 B. 28,8 C. 25,6 D. 32,5.
Cu 57. xc nh nng Ag
+
trong mt mu dung dch ngi ta tin hnh nh sau: Cho bt st d vo 100,0
ml dung dch , tch b kt ta sau thm H2SO4 long d vo v tin hnh chun Fe
2+
bng dung dch
KMnO4 0,02M thy ht 12 ml. Vy nng Ag
+
trong mu trn l:
A. 0,012M B. 0,024M C. 0,060M D. 0,048M
A. Mantoz thuc loi isaccarit c kh nng ha tan Cu(OH)2.
B. Saccaroz thuc loi isaccarit c tnh kh.
C. Mantoz thuc loi isaccarit c phn ng thy phn.
D. Fructoz l monosaccarit c phn ng trng gng.
Cu 59: un nng 2-clo-2-metylbutan vi KOH trong C2H5OH. Sn phm chnh thu c l
A. 2-metylbut-2-en. B. 3- metylbut-2-en. C. 2-metylbut-1 en. D. 3- metylbut-1-en.
Cu 60: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c p gam mui Y. Cng cho 1 mol amino axit X
phn ng vi dung dch KOH (d), thu c q gam mui Z. Bit q p = 39,5. Cng thc phn t ca X l
A. C5H9O4N. B. C4H10O2N2. C. C5H11O2N. D. C4H8O4N2.

P N

1C 2B 3B 4D 5A 6B 7B 8A 9D 10C
11C 12A 13D 14A 15D 16B 17A 18D 19C 20A
21C 22B 23C 24C 25B 26A 27D 28D 29C 30B
31A 32D 33A 34B 35B 36C 37C 38D 39D 40C
41D 42A 43B 44A 45D 46A 47B 48B 49D 50A
51A 52C 53D 54B 55D 56A 57B 58B 59A 60A

119 | G S T T G R O U P
s 17

I. PHN CHUNG CHO TT C CC TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: Hn hp X gm (Fe, Fe2O3, Fe3O4, FeO) vi s mol mi cht l 0,1 mol, ha tan ht vo dung dch Y gm HCl
v H2SO4 (long, d) thu c dung dch Z. Nh t t dung dch Cu(NO3)2 1M vo dung dch Z cho ti khi ngng
thot kh NO (sn phm kh duy nht). Th tch dung dch Cu(NO3)2 cn dng v th tch kh thot ra ktc l
A. 0,5 lt; 22,4 lt. B. 50 ml; 2,24 lt. C. 50 ml; 1,12 lt. D. 25 ml; 1,12 lt.
Cu 2: phn bit CH3NH2; (CH3)2NH; (CH3)3N ta dng thuc th no sau y:
A. Qu tm. B. Dung dch HCl.
C. Dung dch phenolphlatein. D. Dung dch HNO2.
Cu 3: Thy phn m gam pentapeptit A c cng thc Gly-Gly-Gly-Gly-Gly thu c hn hp B gm 3 gam Gly;
0,792 gam Gly-Gly; 1,701 gam Gly-Gly-Gly; 0,738 gam Gly-Gly-Gly-Gly; v 0,303 gam Gly-Gly-Gly-Gly-Gly. Gi tr
ca m l
Cu 4: Magie trong thin nhin gm 2 loi ng v l X, Y. ng v X c nguyn t khi l 24. ng v Y hn X mt
ntron. Bit s nguyn t ca hai ng v c t l X/Y = 3/2. Nguyn t khi trung bnh ca Mg l
A. 24,8 B. 25,0 C. 24,4 D. 24,0
Cu 5: Cht hu c X c cha vng benzen v c cng thc phn t l C8H10O. X tc dng vi Na nhng khng tc
dng vi NaOH. Hy cho bit X c th c bao nhiu cng thc cu to ?
A. 5 B. 4 C. 6 D. 3
Cu 6: Cho 200ml dung dch NaOH vo 400ml dung dch Al(NO3)3 0,2M thu c 4,68 g kt ta. Nng mol ca
dung dch NaOH ban u l
A. 0,9M hoc 1,3M B. 0,9M hoc 1,2M C. 0,8M hoc 1,4M D. 0,6M hoc 1,1M
Cu 7: C 4 mu kim loi Na, Al, Ca, Fe. Ch dng nc lm thuc th th s kim loi c th phn bit c ti a
l
A. 1 B. 3 C. 2 D. 4
Cu 8: Hn hp X gm Na, Ba v Al .
Nu cho m gam hn hp X vo nc d ch thu c dung dch X v 12,32 lt H2 (ktc).
Nu cho m gam hn hp X tc dng vi dung dch HCl d thu c dung dch Y v H2. C cn dung dch Y thu
c 66,1 gam mui khan. Gi tr ca m l
Cu 9: Cho cht hu c X c cng thc phn t C3H12O3N2 tc dng vi dung dch NaOH (d) sau c cn dung
dch thu c cht hu c n chc Y v phn cht rn ch cha cc cht v c. Nu cho X tc dng vi dung dch
HCl d sau c cn dung dch th c phn cht rn v gii phng kh Z. Phn t khi ca Y v Z ln lt l
A. 31; 46 B. 31; 44 C. 45; 46 D. 45; 44
Cu 10: Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dd
HCl 1M vo 100 ml dd X, sinh ra V lt kh (ktc). un nng c cn dung dch sau phn ng thu c m (g) mui
khan. Gi tr ca m l
A. 25,6gam B. 18,2gam C. 30,1 gam D. 23,9 gam
Cu 11: t chy hon ton m gam hirocacbon th kh, mch h thu c 7,04g CO2. Sc m gam hirocacbon
ny vo nc brom d n khi phn ng hon ton, thy c 25,6 gam brom phn ng. Gi tr ca m l
A. 2 gam. B. 2 gam hoc 4 gam. C. 2 gam hoc 2,08 gam. D. 4 gam.
Cu 12: Cho cc dung dch sau: Phenol; natri phenolat; ancol benzylic v axit picric. Ha cht no sau y s dng
phn bit cc dung dch ?
A. Dung dch NaHCO3 v dung dch Br2. B. Qu tm v dung dch Br2.
C. Na v dung dch Br2. D. Dung dch NaOH v dung dch Br2.
120 | L O V E B O O K . V N
Cu 13: Tin hnh in phn (c mng ngn xp) 500 ml dung dch cha hn hp HCl 0,02M v NaCl 0,2M. Sau
khi anot bay ra 0,448 lt kh ( ktc) th ngng in phn. Th tch dung dch HNO3 0,1M ti thiu cn dng
trung ho dung dch thu c sau in phn l (coi th tch dung dch thay i khng ng k)
A. 300 ml B. 150 ml C. 200 ml D. 250 ml
4 NH3 + 5O2 4NO + 6 H2O (1) NH3 + H2SO4 NH4HSO4 (2)
2NH3 + 3 CuO 3Cu + N2| + 3 H2O (3) 8NH3 + 3Cl2 N2 + 6 NH4Cl (4)
NH3 + H2S NH4HS (5) 2NH3 + 3O2 2N2| + 6H2O (6)
NH3 + HCl NH4Cl (7)
S phn ng trong NH3 ng vai tr l cht kh l
A. 5 B. 3 C. 2 D. 4
Cu 15: Tnh cht no sau y khng phi l tnh cht ca protein
A. Protein c phn ng thy phn.
B. Protein c phn ng mu biure.
C. Sau khi protein ng t ta un nng c dung dch keo.
D. Protein c kh nng ng t.
Cu 16: Nhit phn hon ton R(NO3)2 (vi R l kim loi) thu c 8 gam mt oxit kim loi v 5,04 lt hn hp kh
X gm NO2 v O2 (o ktc). Khi lng ca hn hp kh X l 10 gam. Xc nh cng thc ca mui R(NO3)2 ?
A. Mg(NO3)2. B. Cu(NO3)2 . C. Fe(NO3)2. D. Zn(NO3)2 .
Cu 17: Khng nn dng li du, m c dng rn v
A. c mi kh chu.
B. du, m tc dng vi H2 trong khng kh to thnh dng rn.
C. mt phn du, m b thy phn to thnh x phng c hi cho sc khe.
D. mt phn du, m b oxi ha thnh anehit khng m bo v sinh an ton thc phm.
Cu 18: Cho 0,64 gam S tan hon ton trong 150 gam dung dch HNO3 63%, un nng thu c kh NO2 (sn phm
kh duy nht) v dung dch X. Hy cho bit dung dch X c th ho tan ti a bao nhiu gam Cu (Bit sn phm
kh duy nht l NO)
Cu 19: Hn hp A gm 4 hirocacbon l ng ng lin tip, cht nng nht c khi lng phn t gp 2,5 ln
cht nh nht. Trong hn hp, theo chiu tng dn ca khi lng phn t th s mol ca chng lp thnh 1 cp
s cng c cng sai bng 1/ 91. Hi % khi lng ca cht nh nht bng bao nhiu bit khi lng ca hn hp
em dng l 53 gam ?
A. 13,21%. B. 37,37% C. 20,68% D. 28,74%
Cu 20: Thc hin crackinh V lit kh butan thu c 1,75V lit hn hp kh gm 5 hirocacbon. Hiu sut phn
ng crackinh butan l (Bit cc kh o cng iu kin nhit v p sut)
A. 80% B. 25% C. 75% D. 50%
Cu 21: t chy hon ton 12,88 gam hn hp gm mt axit no n chc v 1 ancol no n chc c 0,54 mol
CO2 v 0,64 mol H2O. Thc hin phn ng este ha hon ton lng hn hp trn th thu c m (g) este. Gi tr
ca m l
A. 8,82 g B. 10,20 g C. 12,30 g D. 11,08 g
Cu 22: un 1,66 gam hn hp hai ancol vi H2SO4 m c thu c hai anken ng ng k tip ca nhau. Hiu
sut phn ng gi thit l 100%. Nu t hn hp anken cn dng 2,688 lt O2 (ktc). Tm cng thc cu to
hai ancol bit ete to thnh t hai ancol l ete c mch nhnh.
A. C2H5OH, (CH3)2CHOH B. C2H5OH, CH3CH2OH
C. (CH3)2CHOH, (CH3)3COH D. (CH3)2CHOH, CH3(CH2)3OH
Cu 23: X, Y, Z l cc hp cht v c ca mt kim loi, khi t nng nhit cao u cho ngn la mu vng. X
tc dng vi Y thnh Z. Nung nng Y nhit cao thu c Z, hi nc v kh E. Bit E l hp cht ca cacbon,
E tc dng vi X cho Y hoc Z. X, Y, Z, E ln lt l cc cht no di y?
121 | G S T T G R O U P
A. NaOH,Na2CO3,NaHCO3,CO2 B. NaOH, Na2CO3, CO2,NaHCO3
C. KOH, KHCO3, CO2, K2CO3 D. NaOH,NaHCO3,Na2CO3,CO2
Cu 24: PVC c iu ch t kh thin nhin theo s : CH4 C2H2 CH2=CHCl PVC.
Nu hiu sut ton b qu trnh iu ch l 20% th th tch kh thin nhin (ktc) cn ly iu ch ra 1 tn PVC
l (xem kh thin nhin chim 100% metan)
A. 6426 m
3
B. 8635 m
3
C. 12846 m
3
D. 3584 m
3

Cu 25: Cho mt ming Zn vo dung dch cha NaOH v NaNO3 ta thu c hn hp hai kh
A. NO2; NO B. NH3; H2 C. NH3; NO2 D. NO2; N2O
Cu 26: Nung 3,08 gam bt st trong khng kh thu c 3,72 gam hn hp A gm Fe2O3, Fe3O4, FeO v Fe d.
Ha tan hn hp A vo dung dch H2SO4 long, d thy gii phng V lt kh (ktc). Gi tr ca V l
A. 0,336 B. 0,224 C. 0,448 D. 0,896
Cu 27: Khi thy phn hon ton mt este n chc bng dung dch NaOH thu c dung dch X. Nu c cn cn
thn dung dch X thu c 18,4 gam mui. Cho dung dch X vo dung dch AgNO3 trong NH3 d thu c 21,6 gam
kt ta. Cng thc phn t ca este l
A. HCOOC6H5 B. HCOOC6H4CH3 C. CH3COOC6H5 D. HCOOCH=CH2
Cu 28: Hn hp X gm C2H5OH, C2H5COOH, CH3CHO trong ancol chim 50% theo s mol. t chy m gam hn
hp X c 3,06 gam H2O v 3,136 lt CO2 (ktc). Mt khc 13,2 gam hn hp X thc hin phn ng trng bc thy
c p gam Ag kt ta. Gi tr ca p l
A. 8,64 g B. 10,08 g C. 6,48 g D. 9,72 g
Cu 29: S electron trong cc ion sau: NO
3
, NH
4
+
, HCO
3
, SO
4
2
theo th t l
A. 32; 12; 32; 0; 50 B. 32; 10; 32; 0; 50 C. 32; 10; 32; 0; 46 D. 31;11; 31; 0; 48
Cu 30: Chn cu tr li ng nht:
A. n mn kim loi l qu trnh oxi ha kh trong kim loi b n mn do tc dng ca dung dch cht in
li to nn dng electron chuyn di t cc m n cc dng.
B. S ph hu kim loi hay hp kim do tc dng ca cc cht trong mi trng xung quanh gi l s n mn
kim loi.
C. S ph hy kim loi hoc hp kim di tc dng ha hc ca mi trng xung quanh gi l n mn kim
loi.
D. n mn kim loi l qu trnh oxi ha kh trong cc electron ca kim loi c chuyn trc tip n
cc cht trong mi trng.
Cu 31: Cho hai mui X, Y tho mn iu kin sau:
X + Y khng xy ra phn ng. X + Cu khng xy ra phn ng.
Y + Cu khng xy ra phn ng. X + Y + Cu xy ra phn ng.
X v Y l mui no di y?
A. Mg(NO3)2 v KNO3. B. Fe(NO3)3 v H2SO4 long.
C. NaNO3 v NaHSO4. D. NaNO3 v NaHCO3.
Cu 32: Nhit si ca cc cht sau: Ancol etylic(1), etyl clorua (2), ietyl ete (3) v axit axetic (4) c sp xp
theo th t gim dn l
A. (1 ) > (2) > (3) > (4) B. (1) > (2) > (3) > (4) C. (4) > (3) > (2) > (1 ) D. (4) > (1) > (3) > (2)
Cu 33: Tnh oxi ha ca (1) HClO; (2) HClO2; (3) HClO3; (4) HClO4 c sp sp theo th t tng dn l
A. 2<3<4<1 B. 4<3<2<1 C. 1<2<3<4 D. 4<1<2<3
Cu 34: Hp cht hu c X mch khng phn nhnh c cng thc phn t C6H10O4 (ch cha mt loi nhm chc).
Cho 0,1 mol X tc dng va vi dung dch NaOH un nng thu c cht hu c Y v 18,0 gam hn hp mui.
Cng thc cu to thu gn ca X l
A. HCOO - CH2 - CH2 - OOC - C2H5 B. CH3OOC - COO - C3H7.
C. CH3OOC - CH2 - COO - C2H5 D. CH3COO - CH2 - COO - C2H5
Cu 35: Mt hp cht hu c X cha 2 nguyn t. t chy hon ton m gam X thu c 9m/7 gam H2O. T khi
ca X so vi khng kh nm trong khong 2,3 n 2,5. Cng thc phn t ca X l
122 | L O V E B O O K . V N
A. C4H8 B. C5H10 C. C6H12 D. C6H6
Cu 36: Dung dch X cha NaOH 0,2M v Ca(OH)2 0,1M. Sc 7,84 lt kh CO2 (ktc) vo 1 lt dung dch X th lng
kt ta thu c l
Cu 37: Dung dch Cu(NO3)2 c ln tp cht AgNO3. Cht no sau y c th loi b c tp cht:
A. Bt Cu d, lc. B. Bt Ag d, lc. C. Bt Al d, lc. D. Bt Fe d, lc.
Cu 38: Khi cho hn hp Fe3O4 v Cu vo dung dch H2SO4 long d thu c cht rn X v dung dch Y. Dy gm
cc cht u tc dng c vi dung dch Y l
A. BaCl2, HCl, Cl2 B. NaOH, Na2SO4,Cl2 C. KI, NH3, NH4Cl D. Br2, NaNO3, KMnO4
Cu 39: E l este 2 ln este ca axit glutamic v 2 ancol ng ng no n chc mch h k tip nhau c phn
trm khi lng ca cacbon l 55,30%. Cho 54,25 gam E tc dng vi 800 ml dung dch NaOH 1M un nng, c
cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l
Cu 40: C 6 l nh s t 1 n 6, mi l cha mt cht trong s cc cht sau: Hex-1- en, etylfomat, anehit
axetic, etanol, axit axetic, phenol.
Bit: - cc l 2, 5, 6 phn ng vi Na gii phng kh .
- cc l 4, 6 lm mt mu nc Br2 rt nhanh.
- cc l 1, 5, 6 phn ng c vi dung dch NaOH.
- cc l 1, 3 phn ng vi AgNO3/NH3 to kt ta Ag.
Cc l t 1 n 6 cha ln lt cc cht l:
A. anehit axetic, ancol etylic, etylfomat, hex - 1- en, phenol, axit axetic.
B. axit axetic, etylfomat, hex - 1 -en, anehit axetic, ancol etylic, phenol.
C. etylfomat, ancol etylic, anehit axetic, hex - 1 - en, axit axetic, phenol.
D. etylfomat, ancol etylic, anehit axetic, phenol, axit axetic, hex- 1 - en.-------------------------------
II. PHN RING: TH SINH CH C LM MT TRONG HAI PHN (phn A hoc B)
A. Theo chng trnh chun (10 cu, t cu 41 n cu 50)
Cu 41: Hp cht X c cng thc C2H7NO2 c phn ng trng gng, khi phn ng vi dung dch NaOH long to
ra dung dch Y v kh Z, khi cho Z tc dng vi dung dch hn hp gm NaNO2 v HCl to ra kh P. Cho 11,55 gam
X tc dng vi dung dch NaOH va , c cn dung dch thu c s gam cht rn khan l
A. 14,32 g B. 8,75 g C. 9,52 g D. 10,2 g
Cu 42: Cho cc peptit Ala-Gly; Gly-Gly-Gly; Gly-Gly; Glu-Lys-Val-Gly; Val-Val; Ala-Ala-Ala; Lys- Lys- Lys-Lys; Gly-
Glu-Glu-Gly; Val-Gly-Val-Ala-Lys-Glu. S peptit tc dng vi Cu(OH)2 to hp cht mu tm l
A. 8 B. 6 C. 7 D. 5
Cu 43: Cho cc hiroxit Zn(OH)2; Cu(OH)2; Al(OH)3; Fe(OH)3; Cr(OH)3. S hiroxit tan c trong dung dch NH3
l:
A. 2 B. 3 C. 1 D. 4
Cu 44: Cho ca c ca n ba ng sau
(1) 2HI (k) H2 (k) + I2 (k); (2) CaCO3 (r) CaO (r) + CO2 (k) ;
(3) FeO (r) + CO (k) Fe (r) + CO2 (k); (4) 2SO2 (k) + O2 (k) 2SO3 (k)
(5) N2+ 3H2 2NH3
Khi gia m a p suat cu a he , so ca n ba ng bi chuyen di ch theo chie u nghi ch la
A. 3 B. 1 C. 2 D. 4
Cu 45: Cho 33,6 gam Fe vo dung dch H2SO4 c, nng sau khi phn ng xy ra hon ton thu c 2,24 lt kh
duy nht SO2 (ktc) v 14,4 gam cht rn. S mol axit H2SO4 tham gia phn ng l
Cu 46: C hai axit hu c no mch h M n chc, N a chc. Ta tin hnh th nghim nh sau:
- Th nghim 1: Hn hp X1 cha a mol M v b mol N. trung ha X1 cn 500 ml dung dch
123 | G S T T G R O U P
NaOH 1M, nu t chy hon ton X1 th thu c 11,2 lt CO2.
- Th nghim 2: Hn hp X2 cha b mol M v a mol N. trung ha X2 cn 400 ml dung dch
NaOH 1M. Bit a + b = 0,3mol. Cng thc cu to thu gn ca hai axit l
A. CH3COOH v (COOH)2 B. HCOOH v HOOC-CH2-COOH
C. HCOOH v (COOH)2 D. CH3COOH v HCOOH
Cu 47: Cho m gam hn hp X gm glixin v alanin tc dng vi dung dch NaOH va thu c (m+11) gam
mui. Nu t chy hon ton m gam hn hp X th cn 35,28 lt O2 (ktc). Gi tr ca m l
Cu 48: Cho cc cp oxi ho kh sau: Fe
2+
/Fe; Cu
2+
/Cu; Fe
3+
/Fe
2+
. T tri sang phi tnh oxi ho tng dn theo th
t Fe
2+
, Cu
2+
, Fe
3+
v tnh kh gim dn theo th t Fe, Cu, Fe
2+
. iu khng nh no sau y l ng:
A. Fe khng tan c trong dung dch CuCl2.
B. Fe c kh nng tan c trong cc dung dch FeCl3 v CuCl2.
C. Cu c kh nng tan c trong dung dch CuCl2.
D. Cu c kh nng tan c trong dung dch FeCl2.
Cu 49: Cho cc cht: etylenglicol, ancol etylic, glixerol, glucoz, imetyl ete, axit fomic. S cht tc dng c vi
Cu(OH)2 l
A. 4 B. 2 C. 3 D. 5
Cu 50: Sau khi chng ct cy s bng hi nc, ngi ta thu c mt hn hp gm lp tinh du ni trn lp
nc. Bng phng php no tch ring c lp tinh du khi lp nc.
A. Phng php chng ct. B. Phng php chit.
C. Phng php kt tinh phn on. D. Phng php lc.
B. Theo chng trnh nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Vi hai cng thc phn t: C4H9Cl v C7H7Cl (thm) c s ng phn tng ng l
A. 5 v 4 B. 4 v 4 C. 3 v 4 D. 4 v 3
Cu 52: Cho cc th in cc chun: E
Al
3+
/Al
0
= 1,66V; E
Cu
2+
/Cu
0
= +0,34V. Bit sut in ng chun ca pin:
E
0
Zn-Cu
=1,1 V, E
0
Mg-Al
= 0,71 V. Vy sut in ng chun ca pin Mg-Zn (E
0
Mg-Zn
) l
A. 1,81 V B. 0,9 V C. 1,61 V D. 2 V
Cu 53: Cho 25,65 gam mui gm H2NCH2COONa v H2NCH2CH2COONa tc dng va vi 250 ml dung dch
H2SO4 1M. Sau phn ng c cn dung dch th khi lng mui do H2NCH2COONa to thnh l
Cu 54: Cho cc dung dch: C6H5NH2 (anilin), CH3NH2, NaOH, C2H5OH, Na2CO3 v H2NCH2COOH, HCl. Trong cc
dung dch trn, s dung dch c th lm i mu phenolphtalein l
A. 2 B. 4 C. 5 D. 3
Cu 55: Nhng ion no sau y c th tn ti trong cng mt dung dch?
A.
+ + - 2-
4
Ag , H , Cl , SO B.
- + 2+ 2-
4 3
HSO , Na , Ca , CO C. OH
-
, Na
+
, Ba
2+
, Cl
-
D. Na
+
, Mg
2+
, OH
-
,
3
NO
Cu 56: Hp cht ca nhm c mt khp ni, nh c trong t st, mica, boxit, criolit..Trong t st c cha
A. Al2O3.2SiO2.2H2O B. 3NaF.AlF3 C. K2O.Al2O3.6SiO2 D. Al2O3.2H2O
Cu 57: Trong cc pht biu sau :
(1) Theo chiu tng dn in tch ht nhn, cc kim loi kim th (t Be n Ba) c nhit nng chy gim
dn.
(2) Kim loi Cs c dng ch to t bo quang in.
(3) Kim loi Mg c kiu mng tinh th lp phng tm din.
(4) Cc kim loi Na, Ba, Be u tc dng vi nc nhit thng.
(5) Kim loi Mg tc dng vi hi nc nhit cao.
Cc pht biu ng l
A. (2), (4). B. (2), (3), (4). C. (1), (2), (3), (4), (5). D. (2), (5).
124 | L O V E B O O K . V N
Cu 58: Cht hu c Y thnh phn cha C, H, O c kh nng tc dng vi Na gii phng H2, tham gia phn ng
trng bc v ha tan Cu(OH)2 thnh dung dch mu xanh. Khi t chy 0,1 mol Y thu c khng qa 0,2 mol sn
phm. Cng thc phn t Y l
A. C2H4O2 B. CH2O3 C. CH2O D. CH2O2
Cu 59: Ha tan hon ton 24,9 gam hn hp X gm Zn v Sn bng dung dch HCl (d) thu c 6,72 lt kh H2
(ktc). Th tch O2 ( ktc) cn phn ng hon ton vi hn hp X trn l
A. 4,48 lt B. 3,92 lt C. 3,36 lt D. 2,08 lt
Cu 60: C phn ng xy ra trong dung dch: C2H5Br + KOH C2H5OH + KBr
Nng ban u ca KOH l 0,07M. Sau 30 pht ly ra 10ml dung dch hn hp phn ng th thy n c
trung ha va bi 12,84ml dung dch HCl 0,05M. Tnh tc trung bnh ca phn ng trong khong thi gian
trn.
A. 2.10
-6
M.s
-1
B. 3,22.10
-6
M.s
-1
C. 3.10
-5
M.s
-1
D. 2,32.10
-6
M.s
-1

P N
1B 2D 3C 4C 5A 6A 7D 8C 9B 10D
11C 12B 13A 14D 15C 16C 17D 18C 19A 20C
21B 22A 23D 24D 25B 26A 27A 28A 29B 30B
31C 32D 33B 34D 35B 36A 37A 38D 39B 40C
41D 42B 43A 44C 45C 46C 47D 48B 49A 50B
51B 52C 53D 54D 55C 56A 57D 58D 59A 60B


Cu 1: p n B
Ta thy trong Z gm 2 mui Fe
3+
, Fe
2+
vi s mol l n
Fe
2+ = 0,3(mol); n
Fe
3+ = 0,4(mol)
Khi nh dung dch Cu(NO
3
)
2
vo dung dch Z th: 3Fe
2+
+4H
+
+NO
3
3Fe
3+
+NO +H
2
O
n
NO
= n
NO
3
=
1
3
n
Fe
2+ = 0,1(mol). Vy V
NO
= 2,24(l); V
Cu(NO
3
)
2
= 50(ml)
Cu 2: p n D
Cu 3: p n C
n
Gly
= 0,04(mol); n
GlyGly
= 0,006(mol); n
GlyGlyGly
= 0,009(mol);
n
GlyGlyGlyGly
= 0,003(mol)
n
GlyGlyGlyGlyGly
= 0,001(mol). Bo ton gc axit Gly ta c: n
Gly
= 0,096(mol)
Vy s mol peptit ban u l: n
GlyGlyGlyGlyGly
=
n
Gly
5
= 0,0192(mol) m = 5,8176(g)
Cu 4: p n C
Nguyn t khi trung bnh ca Mg l: M
=
3.24 +2.25
3 +2
= 24,4
Cu 5: p n A
X tc dng vi Na nhng khng tc dng vi NaOH do X l ng phn ancol thm ch khng phi
phenol, tc l nhm OH khng gn trc tip vo vng. Ta c cc ng phn tha mn l
C
6
H
5
C
2
H
4
OH; C
6
H
5
CH(OH) CH
3
; CH
3
C
6
H
4
CH
2
OH(, , )

Cu 6: p n A
n
Al
3+ = 0,08(mol); n
Al(OH)
3
= 0,06(mol). Ta s thy 2 trng hp:
+) TH1: Trong dung dch d Al
3+
. Khi n
NaOH
= 3n
Al(OH)
3
= 0,18(mol) C = 0,9(M)
125 | G S T T G R O U P
+) TH2: Al
3+
ht. Trongdung dch cha mui AlO
2

Khi ta c: n
NaOH
= 4n
Al
3+ n
Al(OH)
3
= 0,26(mol) C = 1,3(M)
Cu 7: p n D
Ta c hin tng theo bng sau:
Na Al Ca Fe
H2O
Tan, to thnh dung
dch trong sut
Khng
tan
Tan, dung dch thu c
dng huyn ph
Khng tan
Ly dung dch NaOH nhn c trn Tan Khng tan
Vy ta nhn c c 4 kim loi.
Cu 8: p n C
Cho X vo nc d ch thu c dung dch X nn Al tan ht.
Khi ta c: n
H
2
=
1
2
n
Na
+n
Ba
+
3
2
n
Al
= 0,55(mol).
Khi cho X vo HCl d th sn phm mui thu c l: NaCl, BaCl
2
, AlCl
3

Ta c: n
Cl
= n
Na
+2n
Ba
+3n
Al
= 2n
H
2
= 1,1(mol)
Khi lng mui khan l: 66,1 = m
X
+m
Cl
m
X
= 27,05(g)
Cu 9: p n B
X c cng thc phn t C
3
H
12
O
3
N
2
.
X tc dng vi HCl gii phng kh Z do X phi l mui ca mt axit yu v d bay hi. Ta thy X s l
mui cacbonat. Do X l: (CH
3
NH
3
)CO. Vy Y l CH
3
NH
2
v Z l CO
2
.
Cu 10: p n D
n
HCl
= 0,2(mol); n
Na
2
CO
3
= 0,15(mol); n
KHCO
3
= 0,1(mol).
Khi cho t t HCl vo dung dch X th HCl s phn ng vi theo th t:
H
+
+CO
3
2
HCO
3

H
+
+HCO
3
CO
2
+H
2
O
Khi ta c H
+
ht.
Khi un nng c cn dung dch ta li c phng trnh: 2HCO
3

0

CO
3
2
+H
2
O +CO
2

Do sn phm mui cui cng chc chn s gm: 0,3mol Na
+
; 0,1 mol K
+
; 0,2 mol Cl
v CO
3
2

Bo ton in tch ta c: n
CO
3
2 = 0,1 mol. Vy khi lng hn hp mui khan bng 23,9 gam.
Cu 11: p n C
n
CO
2
= 0,16(mol); n
Br
2
= 0,16(mol)
Hirocacbon th kh nn c ti a l 4 nguyn t cacbon v c ti a l 4 lin kt .
+) Nu hirocacbon c 1 lin kt th n
hidrocacbon
= n
Br
2
= 0,16(mol)

Suy ra: hirocacbon c 1 C (loi)
hidrocacbon
=
1
2
n
Br
2
= 0,08(mol)
Hidrocacbon c 2C (C
2
H
2
) m = 2,089(g).
hidrocacbon
=
1
3
n
Br
2
=
0,16
3
(mol)
Hidrocacbon c 3C (khng c cht no tha mn)
hidrocacbon
=
1
4
n
Br
2
= 0,04(mol)
Hidrocacbon c 4C C
4
H
4
m = 2(g)
Cu 12: p n B
Ta c hin tng nh bng sau:
Phenol Natriphenolat Ancol benzylic Axit picric
Qu tm Tm Xanh Tm
Dung dch Br2 Kt ta vng Khng c hin tng g.
Cu 13: p n A
126 | L O V E B O O K . V N
n
H
+ = 0,01(mol); n
Cl
= 0,11(mol)
Qu trnh in phn anot: 2Cl
Cl
2
+2e
Qu trnh in phn canot: 2H
+
+2e H
2
; 2H
2
O +2e H
2
+2OH

Ta thy khi anot thot ra 0,448 lt kh, tc l 0,02 mol Cl
2
th s mol e nhn anot l:
0,02.2 = 0,04(mol).
V s mol electron trao i anot v catot l bng nhau nn ta c s mol electron nhng catot cng
bng 0,04
n
OH
= 0,04 n
H
+ = 0,03(mol)
Vy th tch HNO
3
cn dng l: V =
n
C
= 300 (ml)
Cu 14: p n D
Cc phn ng NH
3
ng vai tr cht kh l: (1), (3), (4), (6)
Cu 15: p n C
Cu 16: p n C
t n
NO
2
= x; n
O
2
= y. Ta c h {
x +y = 0,225
46x +32y = 10
{
x = 0,2
y = 0,025

Bo ton nguyn t N ta c n
R(NO
3
)
2
=
n
NO
2
2
= 0,1(mol)
Bo ton khi lng ta li c: n
R(NO
3
)
2
= 10 +8 = 18(g) M
R(NO
3
)
2
= 180 Fe(NO
3
)
2

Cu 17: p n D
Cu 18: p n C
n
S
= 0,02; n
HNO
3
= 1,5(mol). Ta c phng trnh S +6HNO
3
H
2
SO
4
+6NO
2
+2H
2
O
Do S phn ng ht. Trong dung dch sau phn ng cn: 0,02 mol H
2
SO
4
; 1,38 mol HNO
3

n
H
+ = 1,42(mol); n
NO
3
= 1,38(mol)
Khi cho Cu vo ta li c phng trnh: 3Cu +8H
+
+3NO
3
3Cu
2+
+3NO +4H
2
O
Vy n
Cu phn ng
= 0,5325(mol) m
Cu
= 34,08(g).
Cu 19: p n A
Gi khi lng phn t ca cht nh nht l M th khi lng phn t ca cht nng nht l M+42
M+42 = 2,5M M = 28.
Gi s mol ca cht nh nht l x th s mol ca cc cht sau ln lt l: x +
1
91
; x +
2
91
; x +
3
91

28x +42(x +
1
91
) +56(x +
2
91
) +70(x +
3
91
) = 53 x = 0,25(mol)
Vy phn trm khi lng ca cht c khi lng phn t nh nht l:
0,25.28
53
= 13,2%
Cu 20: p n C
Ta c phn ng crackinh: C
4
H
10
ankan +anken
Do ta thy th tch tng ln chnh l th tch butan b crackinh. Vy H =
0,75V
V
= 75%
Cu 21: p n B
Khi t chy axit no n chc th thu c s mol H
2
O v CO
2
bng nhau.
Khi t chy ancol no n chc ta c n
H
2
O
n
CO
2
= n
ancol
n
ancol
= 0,1(mol)
Ta c khi lng ca ancol v axit ban u l: 12,88 = m
C
+m
H
+m
O

V mi nguyn t ancol c 1 nguyn t O, mi nguyn t axit c 2 nguyn t O nn khi lng O trong axit
l
m
O(axit)
= 12,88 12. n
CO
2
2n
H
2
O
16n
ancol
3,52(g) n
axit
=
3,52
32
= 0,11(mol)
Gi s C ca axit v ancol l a, b. Ta c: 0,11a +0,1b = 0,54 1,1a +b = 5,4
Do a, b nguyn nn ta d dng suy ra: a = 4; b = 1 C
3
H
7
COOH, CH
3
OH.
127 | G S T T G R O U P
Khi thc hin phn ng este ha th ancol ht, axit d. Vy khi lng este thu c l:
m
este
= n
ancol
. M
CH
3
COOCH
3
= 10,2(g)
Cu 22: p n A
Gi cng thc trung bnh ca 2 anken l C
n
H
2n
th ancol l C
n
H
2n+2
O.
C
n
H
2n
+
3n
2
O
2
t
nCO
2
+nH
2
O
n
anken
= n
ancol
=
2
3n
n
O
2
=
0,08
n
(mol) m
ancol
=
0,08
n
(14n +18) = 1,667 n =
8
3
.
Do 2 ancol l C
2
H
5
OH; C
3
H
7
OH.
Ete to thnh t 2 ancol c mch nhnh nn 2 ancol c cng thc cu to l: C
2
H
5
OH v (CH
3
)
2
CH(OH).
Cu 23: p n D
X, Y, Z l hp cht v c ca mt kim loi, khi t chy th ngn la mu vng nn kim loi l Na.
Z li khng th l CO2 nn da vo p n ta suy ra c X l NaOH, E l CO2
Nung Y nhit cao thu c Z nn Y l NaHCO
3
; Z l Na
2
CO
3

Cu 24: p n D
PVC c cng thc (CH
2
CHCl)
n
2CH
4
PVC.
Do th tch CH
4
(hay kh thin nhin) cn dng l:
V = n
CH
4
. 22,4 =
2. n
PVC
. 22,4
H
=
2.10
6
62,5.20%
. 22,4 = 3584000(l) = 3584(m
3
)
Cu 25: p n B
Zn +2NaOH Na
2
ZnO
2
+H
2
4Zn +7OH
+NO
3
4ZnO
2
2
+NH
3
+2H
2
O.
Cu 26: p n A
m
O(oxit)
= m
oxit
m
Fe
= 0,64(g) n
O
= 0,04(mol)
Khi cho hn hp A vo axit th oxit phn ng vi axit trc, to thnh mui Fe
2
(SO
4
)
3
v FeSO
4
. Sau ta
c trnh t phn ng:
Fe +Fe
2
(SO
4
)
3
3FeSO
4

Fe +H
2
SO
4
FeSO
4
+H
2

Tc l sn phm mui cui cng l mui FeSO4. Bo ton electron ta c:
2n
Fe
= 2n
O
+2n
H
2
n
H
2
= 0,015(mol) V
H
2
= 0,336(l).
Cu 27: p n A
Da vo p n ta thy c loi p n C v khng c sn phm no to kt ta khi phn ng vi AgNO3. Vi
cc p n cn li c 2 trng hp xy ra.
+) Nu l p n D trong dung dch X c mui HCOONa v anehit CH3CHO
n
HCOONa
= n
CH
3
CHO
0,27(mol) n
Ag
= 2. n
HCOONa
+2n
CH
3
CHO
= 1,08(mol)(khng tha mn)
+) Nu l p n hoc ta c: n
HCOONa
=
1
2
n
Ag
= 0,1(mol) = n
RC
6
H
4
ONa

m
RC
6
H
4
ONa
= 18,4 m
HCOONa
= 11,6 M
RC
6
H
4
ONa
= 116 R = 1 . Vy este l HCOONa
Cu 28: p n A
n
H
2
O
= 0,17(mol); n
CO
2
= 0,14(mol) n
ancol
= n
H
2
O
n
CO
2
= 0,03(mol).
t n
C
2
H
5
COOH
= x; n
CH
3
CHO
= y. Ta c h {
x +y = n
ancol
= 0,03
3x +2y = n
CO
2
2n
C
2
H
5
OH
= 0,08
{
x = 0,02
y = 0,01

Vy C
2
H
5
OH, C
2
H
5
COOH, CH
3
CHO c s mol theo t l 3 2 1.
Do trong 13,2 (g)X ta tnh c: n
CH
3
CHO
=
13,2
3.46 +2.74 +44
= 0,04(mol)
n
Ag
= 0,08(mol) p = 8,64(g).
Cu 29: p n B
Cu 30: p n B
128 | L O V E B O O K . V N
Qu trnh oxi ha kh trong kim loi b n mn do tc dng ca dung dch cht in li to nn dng
electron chuyn di t cc m n cc dng gi l n mn in ha. S ph hy kim loi hoc hp kim
di tc dng ha hc ca mi trng xung quanh gi l n mn ha hc.
Cu 31: p n C
A sai v Cu +Mg(NO
3
)
2
+KNO
3
khng xy ra phn ng.
B sai v Cu +2Fe(NO
3
)
3
Cu(NO
3
)
2
+2Fe(NO
3
)
2

sai v NaHCO
3
kh in li ra H+ nn coi nh Cu +NaNO
3
+NaHCO
3
khng xy ra phn ng.
Cu 32: p n D
Axit c lin kt hiro mnh nn c nhit si cao nht. Ancol cng c lin kt hiro nn nhit si cao
hn ete v dn xut halogen.
Cu 33: p n B
Tnh oxi ha ph thuc nhiu vo bn ca phn t. Phn t cng bn th tnh oxi ha cng yu.
Cu 34: p n D
V thu c hn hp mui nn loi p n B v C.
S mol mi mui bng s mol este v bng 0,1 mol.
Th p n A v D ta tm c p n.
Lu 2 mui p n D l CH
3
COONa; OHCH
2
COONa
.

Cu 35: p n B
2,3 < d
X
kk
< 2,5 66,7 < M

X
< 72,5. Vy ch c p n tha mn.
Cu 36: p n A
n
CO
2
= 0,35(mol); n
OH
= 0,4(mol):
CO
2
+OH
HCO
3

Khi cho CO
2
vo X ta c: HCO
3
+OH
CO
3
2
+H
2
O
n
CO
3
2 = 0,05(mol) n
CaCO
3
= 0,05(mol) m
= 5(g).
Cu 37: p n A
Nu s dng p n B th s khng xy ra phn ng.
Nu s dng p n C hoc D th dung dch li ln thm mui nhm hoc st.
Cu 38: p n D
Do thu c cht rn X nn X l Cu d. Vy dung dch Y gm CuSO4; FeSO4; H2SO4 d.
A, B, C sai v ln lt c: HCl, Na2SO4, KI, NH4Cl khng tc dng vi Y.
Cu 39: p n B
Gi cng thc chung ca 2 ancol l C
n
H
2n+2
O th M
este
= M
axit glutamic
+2(14n +2 +16) 2.18 = 147 +
28n
%C =
12(2n +5)
147 +28n
= 55,3% n = 2,5 M
este
= 217 n
E
= 0,25 mol
n
NaOH
= 0,8(mol) cht rn gm 0,25 mol mui natri glutamat v 0,3 mol NaOH d.
Vy m = 59,75(g).
Cu 40: p n C
1 va phn ng vi NaOH, va c phn ng trng bc nn 1 l etyl fomat loi A, B
6 phn ng vi Na to kh nn 6 khng th l hex-1-en loi D
Nu khng da vo p n ta vn c th suy lun t t tm c cc cht.
Cu 41: p n D
Khi cho Z tc dng vi dung dch hn hp gm NaNO2 v HCl to ra kh P nn Z l amin bc 1. X li c
phn ng trng gng nn X phi l mui ca axit fomic. Vy X l HCOOH
3
NCH
3
.
HCOOH
3
NCH
3
+NaOH HCOONa +CH
3
NH
2
.
n
HCOONa
= n
HCOOH
2
NCH
2
= 0,15(mol) m = 10,2(g).
Cu 42: p n B
129 | G S T T G R O U P
Peptit tc dng vi Cu(OH)2 to hp cht mu tm l peptit to t t nht l 3 gc amino axit.
Cu 43: p n A
Cc hiroxit tan trong dung dch NH
3
l: Zn(OH)
2
; Cu(OH)
2

Cu 44: p n C
Cc cn bng b chuyn dch theo chiu nghch l cc cn bng c tng s mol kh sau nh hn tng s mol
kh trc. l cc cn bng: (4); (5)
Cu 45: p n C
Gi s cht rn tt c l lu hunh, Fe ht.
Ta c n
Fe
= 0,6(mol); n
S
= 0,45(mol); n
SO
2
= 0,1(mol)
(S mol e nhng v nhn s khng bng nhau, khng the mn)
Do cn Fe d nn ch to mui FeSO
4

Gi s mol Fe d l x, s mol S l y 56x +32y = 14,4
Bo ton electron ta li c: 2n
FeSO
4
= 6n
S
+2n
SO
2
2(0,6 x) = 6y +0,2 x = 0,2; y = 0,1
Bo ton nguyn t S ta c: n
H
2
SO
4
= n
S
+n
FeSO
4
+n
SO
2
= 0,6(mol)
Cu 46: p n C
Da vo p n ta thy B ch c th c 2 chc {
a +b = 0,3
b +2a = 0,4
{
a = 0,1
b = 0,2

t chy X
1
thu c 0,5 mol CO
2
nn A c 1 nguyn t C v B c 2 nguyn t C.
Cu 47: p n D
Ta thy c 1 mol NaOH phn ng th khi lng tng ln l 22 (g) n
X
= n
NaOH
=
11
22
= 0,5.
Gi cng thc chung ca X l C
n
H
2n+1
O
2
N.
C
n
H
2n+1
O
2
N +(n +
2n +1
4
1) O
2
t
nCO
2
+
2n +1
2
H
2
O +
1
2
N
2

n +
2n +1
4
1 =
n
O
2
0,5
= 3,15 n = 2,6 m = 41,7 (gam)
Cu 48: p n B
Cu 49: p n A
Cc cht tc dng vi Cu(OH)2 l: etylenglicol, glixerol, glucoz, axit fomic.
Cu 50: p n B
Cu 51: p n B
Cu 52: p n C
E
0
Mg
2+
Mg
= E
0
Al
3+
Al
E
0
MgAl
= 2,37; E
0
Zn
2+
Zn
= E
0
Cu
2+
Cu
E
0
ZnCu
= 0,76
Sut in ng chun ca pin Mg Zn(E
0
ZnZn
)l: E
0
ZnCu
= E
0
Mg
2+
Mg
+E
0
Zn
2+
Zn
= 1,61(V).
Cu 53 : p n D
Ta c mui thu c l:
(HCOOCH
2
NH
3
)
2
SO
4
; (HCOOCH
2
CH
2
NH
3
)
2
SO
4

{
n
H
2
NCH
2
COONa
= x
n
H
2
NCH
2
COONa
= y
{
x +y = n
H
2
SO
4
= 0,25
97x +111y = 25,65
{
x = 0,15
y = 0,1

Vy mui do H
2
NCH
2
COONa to ra gm 0,075 mol (HCOOCH
2
NH
3
)
2
SO
4
; 0,075 mol Na
2
SO
4
c khi lng
l : 29,25 (g)
Cu 54 : p n D
Cc dung dch c th lm i mu phenolphtalein l: CH
3
NH
2
, NaOH, Na
2
CO
3

Cu 55: p n C
Cc ion tn ti cng trong mt dung dch khi n khng phn ng vi nhau to kt ta hay cht kh.
Cu 56: p n A
Cu 57: p n D
130 | L O V E B O O K . V N
(1) sai v theo chiu tng dn in tch ht nhn, cc kim loi kim th (t Be n Ba) c nhit nng
chy khng tun theo quy lut.
(3) sai v kim loi Mg c kiu mng tinh th lc phng.
(4) sai v Be khng tc dng vi nc nhit thng.
Cu 58: p n D
Y va c tnh cht ca axit, va c tnh cht ca anehit nn Y l HCOOH.
Cu 59: p n A
t: n
Sn
= x; n
Zn
= y {
x +y = n
H
2
= 0,3
119x +65y = 24,9
{
x = 0,1
y = 0,2

X phn ng hon ton vi oxi s to sn phm l ZnO v SnO
2
. Vy n
O
2
= 0,2(mol).
Cu 60: p n B
n
KOH
= n
HCl
= 6,4.10
4
(mol) C
M(KOH)
= 0,0642(M). Vy V =
0,07 0,0642
30.60
= 3,22.10
6
(M. s
1
)

131 | G S T T G R O U P
s 18

Cu 1: Cho hn hp X gm Fe
3
O
4
v Fe
2
O
3
vo dung dch H
2
SO
4
long d thu c dung dch X trong s mol
Fe
2
(SO
4
)
3
gp 2 ln s mol FeSO
4
. Mt khc, ha tan hon ton 39,2 gam hn hp X trong H
2
SO
4
c, nng thu
c bao nhiu lt SO
2
(ktc)?
A. 1,68 lt B. 3,36 lt C. 1,12 lt D. 2,24 lt
(1) Nguyn t ca nguyn t X c 11 electron p, s hiu nguyn t ca nguyn t X l 17
(2) Kim loi c cu hnh e lp ngoi cng l 4s
1
ch c th l 19K
(3) Bn knh ca ion 19K
+
ln hn ca ion 20Ca
2+

(4) Cu hnh e ca ion X
3+
l 1s
2
2s
2
2p
6
3s
2
3p
6
3d
3
th v tr ca X trong bng tun hon l 24, chu k 4, nhm
IB.
S khng nh sai l:
A. 2 B. 3 C. 1 D. 0
Cu 3: Trn dung dch X (NaOH 0,1M, Ba(OH)
2
0,2M) vi dung dch (HCl 0,2M, H
2
SO
4
0,1M) theo t l no v th
tch dung dch thu c c p = 13?
A. V
X
V
Y
= 6 4 B. V
X
V
Y
= 5 4 C. V
X
V
Y
= 4 5 D. V
X
V
Y
= 5 3
Cu 4: Hirocacbon X cng HCl theo t l mol 1:1 to sn phm c hm lng clo l 55,04%. X c cng thc phn
t l:
A. C
4
H
8
. B. C
2
H
4
. C. C
2
H
6
D. C
3
H
6
.
Cu 5: Hp th hon ton 8,96 lt CO2 (ktc) vo 200 ml dung dch hn hp KOH 2M v Ca(OH)2 0,5M thu c
dung dch X. Dung dch X cha cht tan l
A. K2CO3 B. KHCO3 v K2CO3 C. Ca(HCO3)2 D. KHCO3 v Ca(HCO3)2
Cu 6: X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m gam hn hp X v c t l s mol n
X
n
Y
= 1 3 tc dng va vi 780 ml dung dch NaOH 1M. m c gi tr l:
Cu 7: Cho Al tc dng vi dung dch NaOH. Cht oxi ha trong phn ng l:
A. Al B. OH
C. H2O D. Na
+

Cu 8: Cho cc khng nh sau?
(1) Ion kim loi c tnh oxi ho cng mnh th kim loi c tnh kh cng yu.
(2) Cc kim loi tan trong nc th oxit v hiroxit ca kim loi cng tan trong nc
(3) Ion ca cc kim loi ng trc trong dy in ho c th oxi ho c kim loi ng sau trong dy in
ho
(4) Trong mt chu k cc nguyn t kim loi c bn knh nguyn t ln hn phi kim.
S khng nh ng l:
A. 4 B. 3 C. 1 D. 2
Cu 9: Ho tan ht hn hp gm 1 kim loi kim v mt kim loi kim th trong H2O thu c dung dch A v 1,12
(l) H2 (ktc). Cho dung dch cha 0,03 mol AlCl3 vo dung dch A thu c khi lng kt ta l?
A. 0,78 (g) B. 0,81 (g) C. 2,34 (g) D. 1,56 (g)
Cu 10: Hy cho bit phenyl amoni clorua u tc dng c vi dy cc cht no sau y?
A. NaCl, Na
2
CO
3
, NH
3
B. NaOH, C
6
H
5
OH, NH
3

C. NaOH, AgNO
3
, Br
2
(dung dch) D. AgNO
3
, NaOH; CH
3
NH
2

Cu 11: Hy cho bit tnh cht no khng c trng i vi glucoz?
A. phn ng vi AgNO3/ dung dch NH3 thu c Ag.
B. phn ng vi Cu(OH)2 nhit thng to dung dch xanh lam
C. phn ng thy phn trong mi trng axit.
D. phn ng ln men to ancol etylic.
132 | L O V E B O O K . V N
Cu 12: Cht X c cng thc l C4H8O. X lm mt mu dung dch nc brm v tc dng vi Na gii phng H2. S
ng phn mch h tha mn ca X l
A. 2. B. 4. C. 5. D. 3.
Cu 13: Cho cc dung dch long c nng mol/l bng nhau: Al2(SO4)3 (I), Al(NO3)3 (II), NaCl (III), K2SO4 ( V).
Dung dch dn in tt nht l
A. I. B. III. C. II. D. IV.
Cu 14: Hn hp A gm C
2
H
2
v H
2
c d
A H
2
= 5,8. Dn A (ktc) qua bt Ni nung nng cho n khi cc phn ng

xy ra hon ton ta c hn hp B. Tnh d
B H
2
l
A. 13,5. B. 11,5. C. 29. D. 14,5.
Cu 15: Cho cc cht: Al, Al
2
O
3
, Al
2
(SO
4
)
3
, Zn(OH)
2
, NaHS, K
2
SO
3
, (NH
4
)
2
CO
3
, H
2
N CH
2
COOH. S cht lng
tnh l:
A. 5. B. 7. C. 6. D. 4.
Cu 16: Ho tan hon ton mg FeS
2
vo axit HNO
3
ch c kh NO
2
bay ra, thu c dung dch B. Ly mt t dung
dch B cho tc dng vi lng d bt Cu v H
2
SO
4
long, khng c kh bay ra, nhng dung dch c mu xanh m
hn. Ly 1/10 dung dch B em pha long c 2 lit dung dch C c pH = 2 (b qua nh hng ca mui ti pH
dung dch). Gi tr ca m.
A. 24 B. 6 C. 18 D. 12
Cu 17: Cho 150 ml dung dch Ba(OH)
2
0,8M vo 250 ml dung dch Al
2
(SO
4
)
3
xM thu c 34,2 gam kt ta.
Thm tip 200 ml dung dch Ba(OH)
2
vo hn hp th thu c lng kt ta l 75,39 gam. Gi tr ca x l?
A. 0,18 B. 0,4 C. 0,36 D. 0,2
Cu 18: in phn 100 ml dung dch gm Cu(NO
3
)
2
0,1M v NaCl 0,2 M ti khi c hai in cc u c kh thot ra
th dng li. Dung dch sau in phn c pH l:
A. 8 B. 5 C. 6 D. 7
Cu 19: Cho cc dung dch sau y
Dung dch (I): H
+
, Fe
2+
, Cl
, SO
4
2
, NO
3
Dung dch (II): Na

+
, K
+
, Fe
3+
, SO
4
2
, Cl
, OH
;
Dung dch (III): Ca
2+
, Mg
2+
, Al
3+
, SO
3
2
, Br
, NO
3
; Dung dch (IV): Na

+
, K
+
, Al
3+
, SO
4
2
, S
2

Dung dch (V): Fe
2+
, Fe
3+
, Na
+
, Cl
, SO
4
2
, I
; Dung dch (VI): Fe

3+
, NH
4
+
, CO
3
2
, Cl

S dung dch khng tn ti l:
A. 6 B. 3 C. 4 D. 5
Cu 20: Cho 11,2 gam Fe vo 400ml dung dch AgNO
3
1,2M. Tnh khi lng kt ta thu c sau phn ng xy
ra hon ton.
Cu 21: Khi t chy hon ton 2,2 gam cht hu c X n chc thu c sn phm chy ch gm 2,24 lt CO
2
(
ktc) v 1,8 gam nc. Nu cho 2,2 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon
ton, thu c 2,4 gam mui ca axit hu c v cht hu c Z. Tn ca X l
A. Isopropyl axetat. B. Etyl axetat. C. Metyl propionat. D. Etyl propionat.
Cu 22: C bao nhiu amin c cha vng benzen v c cng thc phn t l C
7
H
9
N lm mt mu nc brom?
A. 3 B. 5 C. 4 D. 2
Cu 23: X cng thc phn t dng C
2
H
2
O
n
(n 0). Bit X tc dng c vi dung dch AgNO
3
/NH
3
. Gi tr n c
th l
A. 0, 2, 3, 4 B. 0, 2, 3 C. 0, 1, 2, 3 D. 1, 3, 4
Cu 24: Cho phng trnh ho hc:
FeSO
4
+ KMnO
4
+ KHSO
4
Fe
2
(SO
4
)
3
+ MnSO
4
+ K
2
SO
4
+ H
2
O.
Tng h s (s nguyn ti gin) ca cc cht c trong phng trnh phn ng l:
A. 52 B. 40 C. 54 D. 48
Cu 25: t chy a mol mt este no; h thu c x mol CO
2
v y mol H
2
O. Bit x y = a; Cng thc chung ca este:
A. C
n
H
2n2
O
2
B. C
n
H
2n
O
2
C. C
n
H
2n4
O
6
D. C
n
H
2n2
O
4

133 | G S T T G R O U P
Cu 26: C 4 dung dch ring bit: a) HCl, b) CuCl
2
, c) FeCl
3
, d) HCl c ln CuCl
2
, e) HCl c ln ZnCl
2
. Nhng vo
mi dung dch mt thanh Fe nguyn cht. S trng hp xut hin n mn in ho l
A. 4. B. 2. C. 1 D. 3.
Cu 27: Chia hn hp Mg, Al lm 2 phn bng nhau. Phn 1 tan ht trong dung dch HCl to ra 8,96 lt H
2
(ktc).
Phn 2, nung trong oxi thu c 14,2 gam hn hp oxit. Khi lng hn hp 2 kim loi ban u l:
A. 12 gam B. 7,8 gam C. 11 gam D. 15,6 gam
Cu 28: X l cht lng khng mu, khng lm i mu cht ch th phenolphtalein. X tc dng c vi dung dch
Na
2
CO
3
, dung dch NaOH v dung dch AgNO
3
/NH
3
. X c cng thc cu to l:
A. HCHO. B. HCOOH. C. CH
3
COOH. D. HCOOCH
3
.
Cu 29: Nhit phn dy mui no sau y u thu c NH
3

A. NH
4
Cl, NH
4
HCO
3
, NH
4
NO
3
B. NH
4
Cl, NH
4
HCO
3
, (NH
4
)
2
CO
3

C. NH
4
Cl, (NH
4
)
2
CO
3
, NH
4
NO
3
D. NH
4
Cl, NH
4
HCO
3
, NH
4
NO
2

Cu 30: Cho H (Z = 1), N (Z = 7), O (Z = 8). S cp electron lin kt v khng lin kt trong phn t HNO
3
l
A. 6 v 8 B. 5 v 7 C. 6 v 7 D. 5 v 8
Cu 31: T ancol etylic v cc cht v c cn thit, ta c th iu ch trc tip ra cc cht no sau y? (1). Axit
axetic (2). Axetanehit (3). Buta-1,3-ien (4). Etyl axetat
A. (1), (2) v (3) B. (1), (2) v (4) C. (1), (3) v (4) D. (1), (2), (3) v (4)
Cu 32: Ho tan hon ton 1,5 g hn hp hai kim loi R v X vo dung dch hn hp gm HNO
3
v H
2
SO
4
. Sau
phn ng, thu c dung dch B khng cha mui nitrat v 672 ml hn hp kh C (ktc). Bit kh C nng 1,47 g,
gm hai kh trong c NO
2
. Tng s gam cc mui c trong dung dch B l
A.4,21 B. 3,53 C. 3,18 D. 4,49
Cu 33: C cc pht biu sau y:
(1) Amiloz c cu trc mch phn nhnh.
(2) Glucoz b kh ha bi dung dch AgNO
3
trong NH
3
.
(3) Xenluloz v tinh bt l ng phn ca nhau.
(4) Fructoz khng lm mt mu nc brom.
(5) Trong dung dch, glucoz tn ti ch yu dng mch vng v mt phn nh dng mch h.
S pht biu ng l:
A. 2. B. 4. C. 5. D. 3.
Cu 34: Oxi ha m gam ancol etylic mt thi gian thu c hn hp X. Chia X thnh 3 phn bng nhau:
- Phn 1 tc dng va vi dung dch NaHCO
3
thot ra 2,24 lt kh.
- Phn 2 tc dng vi Na d thot ra 4,48 lt kh
- Phn 3 tc dng vi dung dch AgNO
3
/NH
3
d to thnh 10,8 gam Ag.
Cc phn ng ca hn hp X xy ra hon ton. h tch kh o ktc. Gi tr ca m l
A. 41,4 B. 62,1 C. 48,4 D. 13,8
Cu 35: Cho cc cht sau: Fe
3
O
4
, AlBr
3
, FeCl
2
, MgI
2
, NaCl, CaCO
3
. Axit H
2
SO
4
c nng c th oxi ha bao nhiu
cht?
A. 5 B. 2 C. 4 D. 3
Cu 36: X l hp cht c cng thc phn t l C
2
H
7
O
3
N. X phn ng vi NaOH v HCl u c kh khng mu thot
ra. Hi nu cho 13,95g X tc dng vi 100 g dung dch NaOH 16% th sau phn ng c cn dung dch thu c bao
nhiu gam cht rn khan?
A. 29,2 B. 19,9 C. 15,9 D. 18,6
Cu 37: Thy phn hon ton 17,1 gam saccaroz. Ly sn phm thu c un nng vi mt lng d
Cu(OH)
2
trong mi trng kim ti khi phn ng hon ton to thnh m gam kt ta Cu
2
O. Gi tr ca m l
A. 3,6 B. 7,2 C. 5,4 D. 14,4
Cu 38: Thy phn triglixerat X trong NaOH ngi ta thu c hn hp hai mui natrioleat v natristearat theo
t l mol 1:2. Khi t chy a mol X thu c b mol CO
2
v c mol H
2
O. Lin h gia a, b, c
A. b c = 2a B. b = c + a C. b c = 4a D. b c = 3a
134 | L O V E B O O K . V N
Cu 39: Cho 39g benzen vo 1 l ng Cl
2
d ri a ra nh sng. Sau khi phn ng xy ra hon ton thu c
bao nhiu g cht sn phm.
A. 56,25g. B. 108 g. C. 145,5 g. D. 142,5 g.
Cu 40: t chy hon ton mt hirocacbon X thu c 33,6 lit kh CO
2
( 27,3
o
C p sut 0,22atm) v 7,2 gam
H
2
O. S mol X tham gia phn ng l :
Cu 41: Cho cc kh: CO, O
3
, NO
2
, NO, CO
2
, SO
2
. Kh gy ra hin tng ma axit l
A. O
3
, NO
2
, SO
2
. B. NO
2
, NO, SO
2
. C. NO
2
, CO
2
, SO
2
. D. NO
2
, CO, CO
2
.
Cu 42: Hn hp X gm 0,01 mol HCOONa v a mol mui natri ca hai axit no n chc mch h l ng ng
lin tip. t chy hon ton hn hp X v cho sn phm chy (CO
2
, hi nc) ln lt qua bnh 1 ng H
2
SO
4

c bnh 2 ng KOH d thy khi lng bnh 2 tng nhiu hn bnh mt l 3,51 gam. Phn cht rn cn li sau
khi t cn nng 2,65 gam. Cng thc phn t ca hai mui natri l
A. C
2
H
5
COONa v C
3
H
7
COONa. B. C
3
H
7
COONa v C
4
H
9
COONa.
C. CH
3
COONa v C
2
H
5
COONa. D. CH
3
COONa v C
3
H
7
COONa.
Cu 43: Cho cc polime sau y: PVA (poli vinyl axetat); t nilon 6,6; cao su isopren; Poli (vinyl clorua); t
capron; poli stiren. S polime b thu phn trong mi trng kim l:
A. 4 B. 5 . C. 3 D. 2
Cu 44: Ha tan 3,23 gam hn hp 2 mui CuCl
2
v Cu(NO
3
)
2
vo nc c dung dch A. Nhng thanh kim loi
Mg vo dung dch A v khuy u cho n khi mu xanh ca dung dch bin mt. Ly thanh Mg ra cn li thy khi
lng tng thm 0,8 gam so vi ban u. C c dung dch n khan th thu c m gam mui khan. Gi tr ca m
l:
A. 2,43 g B. 4,13 g. C. 1,15 g. D. 1,43 g.
Cu 45: Cho 21,8 gam este X thun chc tc dng vi 1 lt dung dch NaOH 0,5M thu c 24,6 gam mui v 0,1
mol ancol. Lng NaOH d c trung ha bi 0,5 lt dung dch HCl 0,4 M. Cng thc cu to thu gn ca A l
cng thc no?
A. CH
3
COOC
2
H
5
B. (CH
3
COO)
2
C
2
H
4
C. (CH
3
COO)
3
C
3
H
5
D. C
3
H
5
(COOCH
3
)
3

Cu 46: t chy m gam ancol n chc X mch h, c nhnh c m gam nc, MX< 114. X l:
A. ancol bc 3 B. ancol bc 1 C. ancol bc 2 D. ancol no
Cu 47: Cho 50 ml dung dch ancol etylic 46
0
phn ng ht vi kim loi Na d, thu c V lt kh H
2
(ktc). Bit
khi lng ring ca ancol etylic nguyn cht bng 0,8 g/ml. Gi tr ca V l:
A. 10,64 B. 4,48 C. 16,8 D. 21,28
Cu 48: Nung nng hn hp gm 0,5mol N
2
v 1,5mol H
2
trong bnh kn (c xc tc) ri a v nhit t
0
C thy
p sut trong bnh lc ny l P
1
. Sau cho mt lng d H
2
SO
4
c vo bnh (nhit lc ny trong bnh l t
0
C)
n khi p sut n nh th thy p sut trong bnh lc ny l P
2
(P
1
= 1,75P
2
). Hiu sut tng hp NH
3
l:
A. 65%. B. 75%. C. 42,86%. D. 60%.
Cu 49: Cn bng sau tn ti trong dung dch: CH
3
COOH H
+
+ CH
3
COO
. in li ca axit s tng khi no?

A. Khi tng nng dung dch B. Khi nh vi git dung dch Cl
C. Nh vi git CH
3
COONa D. Khi nh vi git NaO
Cu 50: T ancol etylic, metylic v axit oxalic (xt H
2
SO
4
c) c th iu ch c bao nhiu ieste?
A. 6 B. 4 C. 3 D. 5

P N

1C 2C 3B 4B 5B 6A 7C 8D 9D 10D
11C 12B 13A 14D 15A 16A 17B 18D 19D 20D
21C 22C 23B 24A 25D 26B 27D 28B 29B 30D
31D 32C 33A 34A 35C 36B 37D 38D 39C 40B
41B 42A 43A 44A 45C 46B 47D 48D 49D 50C
135 | G S T T G R O U P

s 19

Cu 1: Mt mui X c cc tnh cht sau:
-X tc dng vi dung dch HCl to ra kh Y, kh Y lm c nc vi trong, khng lm mt mu dung dch brom.
- X tc dng vi dung dch Ba(OH)2 c th to ra hai mui.
X l cht no di y?
A. K2CO3. B. KHCO3. C. K2S. D. K2SO3.
Cu 2: Trong phng trnh phn ng: aK2SO3 + bKMnO4 + cKHSO4 dK2SO4 + eMnSO4 + gH2O
(cc h s a, b, c... l nhng s nguyn, ti gin). Tng h s cc cht tham gia phn ng (a + b + c) l:
A. 10. B. 15. C. 13. D. 18.
Cu 3: Cho m gam hn hp X gm Cu, Al vo dung dch HCl d th c 2 gam cht rn khng tan. Nu trn thm 4
gam Mg vo 0,5m gam X th c hn hp Y. Hm lng % theo khi lng ca Al trong Y nh hn trong X l
33,33%. Khi ngm Y trong dung dch NaOH m c, sau mt thi gian thu c nhiu hn 2 lt H2 (ktc). Hm
lng %Cu trong X c gi tr l:
A. 30% B. 16,67% C. 18,64% D. 50%
Cu 4: Cho 0,2 mol cht X (CH6O3N2) tc dng vi dung dch 200 ml NaOH 2M cha un nng thu c cht kh
lm xanh qu tm m v dung dch Y. C cn dung dch Y c m gam cht rn. Gi tr ca m l:
A. 11,4 gam B. 25 gam C. 30 gam D. 43,6 gam
Cu 5: Cho m gam Fe vo dung dch AgNO3 c hh X gm hai kim loi. Chia X thnh hai phn: Phn t (m1 gam),
cho tc dng vi dung dch HCl d c 0,1 mol kh H2. Phn nhiu (m2 gam), cho tc dng ht vi dung dch
HNO3 long d, c 0,4 mol kh NO. Bit m
2
m
1
= 32,8. Gi tr m bng:
A. 23,3 gam hoc 47,1 gam B. 33,6 gam hoc 47,1 gam
C. 33,6 gam hoc 63,3 gam D. 11,74 gam hoc 6,33 gam
Cu 6: X mch h c cng thc C3Hy. Mt bnh c dung tch i cha hn hp kh gm X v O2 d 150
0
C, p sut
2 atm. Bt tia la in t chy X sau a bnh v 150
0
C, p sut bnh vn l 2 atm. Ngi ta trn 9,6 gam X
vi 0,6 gam H2 ri cho qua bnh Ni nung nng (H=100%) th thu c hn hp Y. Khi lng mol trung bnh ca
Y l:
A. 52,5 B. 46,5 C. 48,5 D. 42,5
Cu 7: Nhit phn hon ton mt hn hp X gm x mol Fe(NO3)2 v y mol Cu(NO3)2 thu c hn hp kh B c t
khi so vi H2 bng 22. T s x/y bng:
A. 2. B. 1/2. C. 1/3. D. 3/2.
A. Hn hp Fe2O3 v Cu c th tan ht dung dch HCl.
B. Hn hp FeS v CuS c th tan ht dung dch HCl long.
C. Hn hp Na2O v Al2O3 c th tan ht trong nc .
D. Hn hp KNO3 v Ag c th tan ht dung dch HCl.
Cu 9: Cho 22,4 lit hn hp A gm hai kh CO, CO2 i qua than nng (khng c mt khng kh) thu c kh B
c th tch hn th tch A l 5,6 lit (th tch kh o c ktc). Dn B i qua dung dch Ca(OH)2 va th thu
c dung dch ch cha 20,25 g Ca(HCO3)2. Thnh phn phn trm (v th tch) ca mi kh trong hn hp ln
lt l
A. 25% v 75% B. 37,5% v 62,5% C. 40% va 60% D. 50% v 50%
Cu 10: Hn hp X c C2H5OH, C2H5COOH, CH3CHO trong C2H5OH chim 50% theo s mol. t chy m gam hn
hp X thu c 3,06 gam H2O v 3,136 lt CO2 (ktc). Mt khc 13,2 gam hn hp X thc hin phn ng trng bc
thy c p gam Ag kt ta. Gi tr ca p l:
A. 8,64 B. 9,72 C. 2,16 D. 10,8
136 | L O V E B O O K . V N
Cu 11: Khi un nng 25,8 gam hn hp ancol etylic v axit axetic c H2SO4 c lm xc tc thu c 14,08 gam
este. Nu t chy hon ton lng hn hp thu c 23,4 ml H2O (lng). Tnh thnh phn trm mi cht trong
hn hp u v hiu sut ca phn ng este ho.
A. 60,0% C2H5OH; 40,0% CH3COOH v hiu sut 75%
B. 45,0% C2H5OH; 55,0% CH3COOH v hiu sut 60%
C. 55,3% C2H5OH; 44,7% CH3COOH v hiu sut 80%
D. 53,5% C2H5OH; 46,5% CH3COOH v hiu sut 80%
Cu 12: Mt khong vt c cng thc tng qut l aKCl.bMgCl2.xH2O. Nung nng 27,75 gam khong vt trn n
khi lng cht rn gim 10,8 gam. Ho tan phn cht rn cn li vo nc c dung dch B, ri cho B vo dung
dch AgNO3 d th thu c 43,05 gam kt ta trng. Cng thc ca khong trn l:
A. KCl.2MgCl2.6H2O. B. 2KCl.1MgCl2.6H2O. C. KCl.MgCl2.6H2O. D. KCl.3MgCl2.6H2O.
Cu 13: Cho cc cp dung dch:
a) NaHCO3; HCl b) Na[Al(OH)4]; HCl
c) NaOH; Al2(SO4)3 d) Ca(OH)2; H3PO4.
Nu khng dng ho cht khc, c th xc nh c hai cht trong bao nhiu cp?
A. 1 cp B. 3 cp C. 2 cp D. 4 cp
Cu 14: t chy hon ton a gam metan ri cho sn phm chy hp th ht vo dung dch cha 0,2 mol Ca(OH)2
n khi thu c 10,0 gam kt ta. Gi tr ca a l bao nhiu gam?
A. 1,6 gam hoc 4,8 gam B. 1,6 gam C. 3,2 gam D. 4,8 gam
Cu 15: in phn dung dch hn hp 0,1 mol Cu(NO3)2 v 0,06 mol HCl vi dng in mt chiu c cng
1,34A trong 2 gi, cc in cc tr. Khi lng kim loi thot ra catot v th tch kh ktc thot ra anot b
qua s ho tan ca clo trong nc v coi hiu sut in phn l 100% nhn nhng gi tr no sau y:
A. 0,32 gam v 0,896 lit. B. 3,2 gam v 0,896 lit. C. 6,4 gam v 8,96 lit. D. 6,4 gam v 0,896
lit.
Cu 16: Pha cc dung dch sau:
(1) Ly 0,155 gam Na2O pha thnh 500 ml dung dch X.
(2) Ly 4,59 gam BaO pha thnh 2 lt dung dch Y.
(3) Trn 250 ml dung dch HCl 0,08M vi 250 ml dung dch Ba(OH)2 0,05M thnh 500 ml dung dch Z.
(4) Trn 250 ml dung dch HCl 0,08M vi 250 ml dung dch NaOH 0,16M thnh 500 ml dung dch P.
S dung dch c pH bng nhau l: (Cc cht phn li hon ton)
A. 0 B. 2 C. 3 D. 4
Cu 17: Trn 10,8 gam bt Al vi 32 gam bt Fe2O3 ri tin hnh phn ng nhit nhm trong iu kin khng c
khng kh (gi s ch xy ra phn ng kh Fe2O3 thnh Fe). Ho tan hn hp rn sau phn ng bng dung dch
H2SO4 long thu c 10,08 lt kh H2 ( ktc). Hiu sut ca phn ng nhit nhm l
A. 85%. B. 90%. C. 80%. D. 75%.
Cu 18: Dn kh CO vo ng s cha m gam bt Fe2O3 nung nng thu c 61,2 gam hn hp A gm 4 cht. Kh
bay ra khi ng s c dn vo dung dch Ba(OH)2 d c 132,975 gam kt ta. Ho tan ht A bng dung dch
HNO3 d thu c V lt (ktc) kh NO l sn phm kh duy nht. Gi tr V l:
A. 11,2 lt B. 5,6 lt C. 10,08 lt D. 6,72 lt
Cu 19: Cho cn bng: NH3 + H2O NH4
+
+ OH
-
cn bng trn chuyn dch sang phi ngi ta lm cch no sau y?
A. Cho thm vi git dung dch phenolphtalein. B. Cho thm vi git dung dch NaOH.
C. Cho thm vi git dung dch NH4Cl. D. Cho thm vi git dung dch HCl.
Cu 20: Hn hp A gm 3 kim loi X, Y, Z u c ho tr II v ng trc H trong dy in ho. T l khi lng
nguyn t ca 3 kim loi l 3:5:7. T l s mol trong hn hp A l: 4:2:1. Khi cho 1,16 gam hn hp A tc dng ht
v dung dch HCl d thy c 0,784 lt H2 (ktc) thot ra. Tng khi lng nguyn t ca X, Y, Z l:
A. 240 B. 135 C. 140 D. 120
Cu 21: c im khc nhau gia glucoz v fructoz l:
137 | G S T T G R O U P
A. V tr nhm cacbonyl. B. T l nguyn t cc nguyn t.
C. Thnh phn nguyn t. D. S nhm chc OH.
Cu 22: C mt hn hp X gm C2H2, C3H6, C2H6. t chy hon ton 24,8 gam hn hp trn thu c 28,8 gam
H2O. Mt khc 0,5 mol hn hp trn tc dng va vi 500 gam dung dch Br2 20%. Phn trm khi lng ca
C2H2 trong hn hp X l:
A. 33,33% B. 25,25% C. 50% D. 41,94%
Cu 23: Mt loi cht bo c ch s iot l 3,81. Tnh thnh phn % cc cht trong mu cht bo trn gi s mu
cht bo gm triolein v tripanmitin. % triolein v tripanmitin ln lt l
A. 40%; 60% B. 4,46%; 95,54% C. 50%; 50% D. 4,42%; 95,58%
Cu 24: Trong bnh kn dung tch khng i cha y khng kh (cha 20% th tch O2 cn li l N2) 25
o
C v 2
atm. Bt tia la in phn ng xy ra: N2 + O2 2NO.
p sut p v khi lng mol phn t trung bnh ca hn hp sau phn ng 25
o
C l M
s c gi tr:
A. p = 2 atm, M
> 29 g/mol. B. p = 2 atm, M
< 29 g/mol.
C. p = 2 atm, M
= 29 g/mol. D. p = 1 atm, M
= 29 g/mol.
Cu 25: Hn hp X gm 2 hirocacbon A, B thuc loi ankan, anken, ankin. t chy hon ton 6,72 lt (ktc) X
v cho sn phm chy hp th hon ton vo nc vi trong d thy khi lng bnh tng thm 46,5g v c 75g
kt ta. Nu t l khi llng A, B trong X l 22:13 th phn trm s mol ca A trong X l:
A. 50% B. 41,10% C. 49,5% D. 10,5%
Cu 26: Cho 0,25a/17 mol P2O5 vo 125 gam dung dch NaOH 16% c dung dch B cha hai mui NaH2PO4 v
Na2HPO4. Gi tr a trong khong:
A. 17 < a< 34 B. 4,25 <a < 8,5 C. 8,5 < a< 17 D. 8,5 < a < 34
Cu 27: Tin hnh cc th nghim sau:
(1) Chiu sng vo hn hp kh (CH4 v Cl2) (2) Nhit phn Al(OH)3.
(3) un NaBr vi H2SO4 c nng. (4) Ho tan nhm bng dung dch NaOH.
(5) Cho canxicacbua tc dng vi dung dch HCl.
S th nghim xy ra phn ng oxi ho - kh l:
A. 1 B. 4 C. 3 D. 2
Cu 28: un m gam ancol X vi H2SO4 c 170
O
C thu c 2,688 lt kh ca mt olefin ( ktc). t chy hon
ton m gam X ri cho ton b sn phm hp th ht vo dung dch NaOH d th khi lng ca bnh tng 17,04
gam. m c gi tr l
A. 5,52 gam B. 7,2 gam. C. 6,96 gam. D. 8,88 gam.
Cu 29: Cho hn hp X gm hai cht nguyn cht FeS2 v FeCO3 vi t l s mol 1:1 vo bnh kn cha khng kh
vi lng gp i lng cn thit phn ng vi hn hp X, p sut trong bnh ban u l P1 (atm). Nung bnh
nhit cao phn ng xy ra hon ton, a bnh v nhit ban u, p sut trong bnh l P2 (atm). p sut
kh trong bnh trc v sau khi nung l
A. P1 = P2 B. P1 =
7
6
P2 C. P1 =
5
8
P2 D. P1 = 2P2
Cu 30: A l mt kim loi chuyn tip, c kh nng nhim t, tham gia c s chuyn ho sau:
(A) + O2 (B)
(B) + H2SO4 dung dch (C) + (D) + (E)
(C) + NaOH dung dch (F)+ + (G)
(D) + NaOH dung dch (H)+ + (G)
(F) + O2 + H2O (H)
S phn ng oxi ho-kh trong s l
A. 3 B. 5 C. 4 D. 2
Cu 31: A, B l 2 axit no, n chc, mch h. Hn hp X gm 0,1 mol A + 0,1 mol B. t chy hon ton X c 0,6
mol CO2. Mt khc ly 10g mt trong 2 axit cho tc dng vi Na d th lng H2 sinh ra < 0,05 mol. 2 axit A, B l:
A. HCOOH v CH3COOH B. CH3COOH v C2H5COOH
138 | L O V E B O O K . V N
C. CH3COOH v C4H9COOH D. HCOOH v C4H9COOH
Cu 32: t chy hon ton 33,4 gam hn hp B1 gm bt cc kim loi Al, Fe v Cu ngoi khng kh, thu c 41,4
gam hn hp B2 gm 3 oxit. Cho ton b hn hp B2 tc dng hon ton vi dung dch H2SO4 20% c khi lng
ring d = 1,14 g/ml. Th tch ti thiu ca dung dch H2SO4 20% ho tan ht hn hp B2 l:
A. 175 ml. B. 200 ml. C. 300 ml. D. 215 ml.
Cu 33: Hp cht hu c X cha mt loi nhm chc c cng thc phn t l C8H14O4. Khi thy phn hon ton
3,48 gam X trong dung dch NaOH c 1 mui v hn hp 2 ancol A, B. Phn t ancol B c s C nhiu gp i A.
Khi un nng vi H2SO4 c 170
0
C: A cho 1 olefin cn B cho 3 olefin ng phn. Nu oxi ho ton b lng ancol
thu c bng CuO t nng, ton b lng anehit cho trng bc hon ton th khi lng bc thu c l:
Cu 34: Da nhn to (PVC) c iu ch t kh thin nhin theo s :
CH4 C2H2 CH2=CHCl [CH2CHCl]n.
Nu hiu sut ca ton b qu trnh iu ch l 20%, mun iu ch c 1 tn PVC th th tch kh thin nhin
(cha 80% metan) iu kin tiu chun cn dng l
A. 4450 m
3
. B. 4375 m
3
. C. 4480 m
3
. D. 6875 m
3
.
Cu 35: Cho a gam hn hp X (Al, Mg, Fe) tc dng vi dung dch HNO3 d thu c hn hp kh gm 0,02 mol
NO; 0,01 mol N2O; 0,01 mol NO2 v dung dch Y. C cn dung dch Y thu c 11,12 gam mui khan. Gi tr a l:
A. 9,3. B. 11,2. C. 3,56. D. 1,82.
Cu 36: C 1 amin bc 1 n chc em chia thnh 2 phn u nhau:
- Phn 1: Ha tan hon ton trong nc ri thm dung dch FeCl3 d. Kt ta sinh ra em nung n khi lng
khng i c 1,6g cht rn.
- Phn 2: Tc dng vi HCl d sinh ra 4,05g mui. Cng thc phn t amin l:
A. CH3NH2 B. C2H5NH2 C. C3H7NH2 D. C4H9NH2
Cu 37: Nm dung dch A1, A2, A3, A4, A5 cho tc dng vi Cu(OH)2/NaOH trong iu kin thch hp th thy: A1
to mu tm, A2 to mu xanh lam, A3 to kt ta khi un nng, A4 to dung dch mu xanh lam v khi un nng
th to kt ta gch, A5 khng c hin tng g. A1, A2, A3, A4, A5 ln lt l:
A. Protein, saccaroz, anehit fomic, fructoz, lipit.
B. Lipit, saccaroz, anehit fomic, fructoz, protein.
C. Protein, saccaroz, lipit, fructoz, anehit fomic.
D. Protein, lipit, saccaroz, glucz, anehit fomic.
Cu 38: Mt loi go cha 75% tinh bt. Ly 78,28 kg go ny em ln men iu ch ancol etylic 40
0
, hiu sut
phn ng ca c qu trnh l 60%. Khi lng ring ca ancol etylic l 0,8 g/ml. Th tch ancol 40
0
thu c l:
A. 60 lt B. 52,4 lt C. 62,5 lt D. 45 lt
Cu 39: Hn hp E gm hai este n chc X, Y. t 21,4gam E thu c 24,64 lt CO2 (ktc) v 16,2 gam H2O. Mt
khc, un 21,4 gam E vi NaOH d thu c 17,8 gam hn hp mui ca hai axit n chc k tip nhau trong dy
ng ng v mt ancol n chc duy nht. Cng thc cu to thu gn ca X v Y l:
A. C2H3COOC2H5 v C3H5COOC2H5. B. CH3COOC2H5 v C2H5COOC2H5.
C. CH3COOC3H5 v C2H5COOC3H5. D. HCOOC3H7 v CH3COOC3H7.
Cu 40: Oxi ha hon ton hn hp X gm HCHO v CH3CHO bng O2 (xt) thu c hn hp axit tng ng Y. T
khi hi ca Y so vi X bng 145/97. Tnh % s mol ca HCHO?
A. 16,7% B. 22,7% C. 83,3% D. 50,2%
Cu 41: Mt cc ng 200 ml dung dch AlCl3 2M. Rt vo cc ny 200 ml dung dch NaOH nng a mol/l, ta thu
c mt kt ta, em sy kh v nung n khi lng khng i th c 5,1g cht rn. Hi a c gi tr no sau
y?
A. 1,5M B. 1,5M hay 7,5M C. 1,5M hay 3M D. 1M hay 1,5M
Cu 42: Trung ho 5,48 g hn hp gm axit axetic, phenol v axit benzoic cn dng 600ml dung dch NaOH 0,1M.
C cn dung dch sau phn ng, thu c hn hp rn khan c khi lng l
A. 4,9g B. 6,84g C. 8,64g D. 6,8g
139 | G S T T G R O U P
Cu 43: Cho 12,8 gam dung dch glixerol trong nc c nng 71,875% tc dng ht vi mt lng d Na thu
c V lt kh H2 ( ktc). Gi tr ca V l
A. 3,36 lt. B. 11,2 lt. C. 4,48 lt. D. 5,6 lt.
Cu 44: T cht X bng mt phn ng c th iu ch ra C2H5OH v t C2H5OH bng mt phn ng c th iu
ch ra cht X. Trong cc cht sau: C2H2, C2H4, C2H5COOCH3, CH3CHO, CH3COOC2H5, C2H5ONa, C2H5Cl. S cht ph
hp vi X l:
A. 6 B. 5 C. 3 D. 4
Cu 45: Trong dy bin ha:
C2H6 C2H5Cl C2H5OH CH3CHO CH3COOH CH3COOC2H5 C2H5OH
S phn ng oxi ha-kh trong dy bin ha trn l bao nhiu?
A. 3 B. 4 C. 5 D. 2
Cu 46: Cho cc cu sau:
1- Cht bo thuc loi cht este.
2- T nilon, t capron, t enang u iu ch bng phn ng trng ngng.
3- Vinyl axetat khng iu ch c trc tip t axit v ancol tng ng.
4- Nitro benzen phn ng vi HNO3 c (xc tc H2SO4 c) to thnh m-initrobenzen.
5- Anilin phn ng vi nc brom to thnh p-bromanilin.
S lng cu nhn xt ng l:
A. 3. B. 2. C. 4. D. 5.
Cu 47: Nhn nh no sau y khng ng v glucoz v fructoz?
A. Glucoz v fructoz u tc dng vi Cu(OH)2 to ra dung dch phc ng mu xanh lam.
B. Glucoz v fructoz u tc dng vi hiro to ra poliancol.
C. Khc vi glucoz, fructoz khng c phn ng trng bc v dng mch h n khng c nhm CHO.
D. Glucoz c phn ng trng bc v n c tnh cht ca nhm CHO.
Cu 48: Trong cng nghip, phn ln supephotphat kp c sn xut theo s sau:
Ca3(PO4)2

H3PO4

Ca(H2PO4)2
Khi lng dung dch H2SO4 70% dng iu ch c 468 kg Ca(H2PO4)2 theo s bin ho trn l
bao nhiu? Bit hiu sut ca c qu trnh l 80%.
A. 392 kg. B. 600 kg. C. 700 kg. D. 520 kg.
Cu 49: Cho m gam Al4C3 phn ng ht vi lng dung dch c 0,03 mol HCl, c dung dch X. Mt khc cho m

gam Al4C3 k trn phn ng va ht vi dung dch c 0,04 mol KOH c dung dch Y. Trn ln ton b X v Y
trn vi nhau c hn hp Z c cha bao nhiu mol mui nhm?
Cu 50: Cho 13,6g hp cht hu c X cha C, H, O tc dng va vi 300 ml dung dch AgNO3 2M trong NH3 thu
c 43,2g Ag, bit dX/H2=34. Nu cho lng cht hu c trn tc dng vi H2 (Ni/t
0
C) th cn t nht bao nhiu lt
H2 (ktc) chuyn hon ton X thnh cht hu c no?
A. 13,44 lt B. 8,96 lt C. 4,48 lt D. 6,72 lt

P N

1B 2C 3B 4B 5B 6D 7A 8B 9D 10A
11D 12C 13D 14D 15B 16B 17D 18C 19D 20D
21A 22D 23D 24C 25A 26A 27D 28A 29A 30D
31D 32D 33B 34C 35D 36A 37A 38C 39C 40C
42B 42D 43D 44B 45A 46C 47C 48C 49A 50A

140 | L O V E B O O K . V N
s 20

Cu 1: Hn hp X gm (anehit no n chc, mch h v H2) t khi hi so vi He bng 3,5. Dn X qua bt Ni, t
o

ti phn ng hon ton thu c hn hp sn phm Y c t khi so vi H2 bng 9,8. Cng thc ca anehit l:
A. CH3CHO B. HCHO C. C2H5CHO D. C3H7CHO
Cu 2: Este A c iu ch t aminoaxit B v CH3OH, d
A H
2
= 44,5. t chy hon ton 8,9 gam A thu c

13,2gam CO2; 6,3gam H2O v 1,12 lt N2 (ktc). Cng thc cu to ca A l
A. H2NC3H6COOCH3 B. H2NC2H4COOCH3 C. H2NCH2COOCH3 D. H2NC2H2COOCH3
Cu 3: Hn hp X gm axit fomic, axit acrylic, axit oxalic v axit axetic. Cho m gam X phn ng ht vi dung dch
NaHCO3

thu c 1,344 lt CO2 (ktc). t chy hon ton m gam X cn 2,016 lt O2

(ktc), thu c 4,84 gam CO2
v a gam H2O. Gi tr ca a l:
A. 1,44. B. 1,62. C. 3,60. D. 1,80.
Cu 4: t chy hon ton 26,8 gam cht hu c A ch thu c sn phm gm 8,8 gam CO2 v 21,2 gam Na2CO3.
% khi lng C, Na, O trong A ln lt l:
A. 8,96%; 34,33%; 56,71% B. 17,91%;22,39%; 59,70%
C. 8,96%; 47,76%; 43,28% D. 17,91%; 34,33%; 47,76%
Cu 5: t chy hon ton 2,8g cht hu c X mch h bng mt lng va 6,72 lt oxi (ktc) ch thu c CO2
v H2O c th tch bng nhau trong cng iu kin. X thuc dy ng ng no:
A. Dy ng ng ca axit axetic B. Dy ng ng ca ru etylic.
C. Dy ng ng ca mtan D. Dy ng ng ca. etilen.
Cu 6: Cho s phn ng sau:
But1en
+HCl
+NaOH,t
0

H
2
SO
4
c,180
0

+Br
2

+NaOH,t
0

Bit X, Y, Z, T, K u l sn phm chnh ca tng giai on. Cng thc cu to thu gn ca K l
A. CH3CH2CH(OH)CH3. B. CH2(OH)CH2CH2CH2OH.
C. CH3CH(OH)CH(OH)CH3. D. CH3CH2CH(OH)CH2OH.
Cu 7: Cho cc hp cht c cng thc phn t l C2H2On. Vi n nhn cc gi tr no th cc hp cht l hp cht
no a chc?
A. 1 v 3 B. 2 v 3 C. 1 v 2 D. 2 v 4
Cu 8: Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 long, thu c 940,8 ml kh NxOy (sn phm
kh duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l:
A. NO v Mg B. NO2 v Al C. N2O v Al D. N2O v Fe
Cu 9: Thc hin hai th nghim sau:
Th nghim 1: Cho m gam hn hp Ba v Al vo nc d, thu c 0,896 lt kh ( ktc)
Th nghim 2: Cng cho m gam hn hp trn cho vo dung dch NaOH d thu c 2,24 lt kh ( ktc) Cc phn
ng xy ra hon ton. Gi tr ca m l:
Cu 10: C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn ng cng H2

(xc
tc Ni, t
o
)?
A. 4. B. 5 C. 3 D. 6.
Cu 11: Este X c cng thc phn t C7H12O4, khi cho 16 gam X tc dng va vi 200 gam dung dch NaOH 4%
th thu c mt ancol A v 17,8 gam hn hp hai mui. Cng thc cu to ca X l
A. CH3COO(CH2)3OOCCH3 B. HCOO(CH2)3OOCC2H5.
C. HCOO(CH2)3OOCCH3. D. CH3COO(CH2)2OOCC2H5.
Cu 12: Tng s lin kt n trong phn t anken C
n
H
2n
l
A. 4n B. 3n - 2 C. 3n D. 3n + 1
Cu 13: Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H2SO4 0,5M v
NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy nht).
Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l:
A. 360 ml B. 240 ml C. 400 ml D. 120 ml
141 | G S T T G R O U P
Cu 14: t chy hn hp no, mch h X (axit v anehit c cng s C) thu c n
H
2
O
= n
X
. Nu cho X phn ng
vi AgNO3/NH3 thu c nAg = 2nX. Phn trm O trong axit l:
A. 69,56 B. 71,11 C. 53,33 D. 55,17
Cu 15: Ha tan hon ton 100 gam hn hp X gm Fe, Cu , Ag trong dung dch HNO3 (d). Kt thc phn ng thu
c 13,44 lt hn hp kh Y gm NO2, NO, N2O theo t l s mol tng ng l 3 : 2 : 1 v dung dch Z (khng cha
mui NH4NO3). C cn dung dch Z thu c m gam mui khan. Gi tr ca m v s mol HNO3 phn ng ln lt
l:
A. 205,4 gam v 2,5 mol B. 199,2 gam v 2,4 mol
C. 205,4 gam v 2,4 mol D. 199,2 gam v 2,5 mol
Cu 16: t chy hon ton 3,61g cht hu c X thu c hn hp kh gm CO2, H2O v HCl. Dn hn hp ny qua
bnh cha dung dch AgNO3/HNO3 nhit thp thy c 2,87g kt ta v bnh cha tng 2,17g. Cho bit ch c
H2O v HCl b hp th. Dn kh thot ra vo 100ml dung dch Ba(OH)2 1M thu c 15,76g kt ta Y, lc b Y, ly
dung dch em si li c kt ta na. Bit khi lng mol ca X < 200; Cng thc phn t X:
A. C6H9O4Cl B. C6H7O4Cl C. C6H10O4Cl D. C5H9O4Cl
Cu 17: C 5 l mt nhn ng 5 cht lng sau: dung dch HCOOH, dung dch CH3COOH, ancol etylic, glixerol, dung dch
CH3CHO. Ch dng thm 2 thuc th no di y nhn bit c 5 l trn dung dch trn?
A. Cu(OH)2, Na2SO4 B. AgNO3 trong dung dch NH3, Cu(OH)2
C. AgNO3 trong dung dch NH3, qu tm. D. Qi tm, Cu(OH)2.
Cu 18: Pht biu ng l
A. Lc baz tng dn theo dy : C2H5ONa, NaOH, C6H5ONa, CH3COONa.
B. Fructoz b kh bi AgNO3 trong dung dch NH3 (d).
C. Cho HNO2 vo dung dch alanin hoc dung dch etyl amin th u c si bt kh thot ra.
D. Benzen v cc ng ng ca n u lm mt mu dung dch thuc tm khi un nng.
Cu 19: Cho 13,35 gam hn hp X gm CH2NH2CH2COOH v CH3CHNH2COOH tc dng vi V ml dung dch NaOH
1M thu c dung dch Y. Bit dung dch Y tc dng va vi 250 ml dung dch HCl 1M. Gi tr ca V l
A. 100 ml B. 150 ml C. 200 ml D. 250 ml
Cu 20: Cho s chuyn ho: C6H5-CCH
+HCl
X
+HCl
Y
+2NaOH
Z
Trong X, Y, Z u l sn phm chnh. Cng thc ca Z l
A. C6H5CH(OH)CH3. B. C6H5CH2CH2OH. C. C6H5COCH3. D. C6H5CH(OH)CH2OH.
Cu 21: T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic (hiu sut 80%). Oxi
ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X. trung ho hn hp X cn 720
ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l
A. 90%. B. 10%. C. 20%. D. 80%.
Cu 22: Thc hin phn ng este ho gia axit axetic v hn hp gm 8,4 gam 3 ancol l ng ng ca ancol etylic. Sau
phn ng thu c 16,8 gam 3 este. Ly sn phm ca phn ng este ho trn thc hin phn ng x phng ho vi dung
dch NaOH 4 M th thu c m gam mui: (Gi s hiu sut phn ng este ho l 100%). Gi tr ca m l
A. 10,00gam B. 16,4gam C. 20,0gam. D. 8,0 gam
Cu 23: Cho 12,8 gam dung dch ancol A c nng 57,8125% tc dng vi lng d Na thu c 4,48 lt H2 (ktc). S
nguyn t H c trong cng thc phn t ancol A l:
A. 4 B. 10 C. 6 D. 8
Cu 24: Cho cc cht: axit propionic (X), axit axetic (Y), ancol (ru) etylic (Z) v imetyl ete (T). Dy gm cc
cht c sp xp theo chiu tng dn nhit si l
A. T, Z, Y, X. B. Z, T, Y, X. C. Y, T, X, Z. D. T, X, Y, Z.
Cu 25: Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra
hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn Z v
3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l:
Cu 26: Chia 0,4 mol anehit A mch h thnh 2 phn bng nhau:
- Phn 1 tc dng hon ton vi hiro phi dng ht 8,96 lt H2 ktc.
142 | L O V E B O O K . V N
- Phn 2 tc dng vi AgNO3 d trong NH3, un nng thu c 43,2 gam Ag.
MA

< 74. S cht A tho mn bi l (khng k ng phn hnh hc):
A. 4 B. 5 C. 2 D. 3
Cu 27: A l hp cht hu c n chc C, H, O. Cho 1 lng cht A tc dng hon ton vi 500 ml dung dch KOH
2,4M ri c cn c 105 gam rn khan B v m gam ru. Oxi ha m gam ru C bng oxi c xc tc c hn
hp X, chia X thnh 3 phn bng nhau:
I/ Tc dng vi AgNO3/NH3 d thu c 21,6 gam Ag.
II/ Tc dng vi NaHCO3 d thu c 2,24 lt kh (ktc).
III/ Tc dng vi Na (va ), thu c 4,48 lt kh (ktc) v 25,8 gam rn khan.
Xc nh cng thc phn t ca A. Bit C un vi axit sunfuric c nng, 170
o
C to olefin:
A. C4H8O2 B. C5H10O2 C. C6H12O2 D. C3H6O2
Cu 28: Cho mt axit n chc tc dng va vi Na thu c mui, t mui trong O2 va thu c 0,1
mol Na2CO3 v 0,3 mol CO2 v m gam nc. Gi tr m l:
A. 3,6 B. 5,4 C. 7,2 D. 9
Cu 29: Nung m gam bt Cu trong oxi thu c 37,6 gam hn hp rn X gm Cu, CuO v Cu2O. Ha tan hon ton
X trong dung dch H2SO4 c, nng, d thy thot ra 3,36 lt kh (ktc). Gi tr ca m l:
A. 25,6 gam B. 32 gam C. 19,2 gam D. 22,4 gam
Cu 30: Mt cht hu c X c cng thc phn t l C4H11NO2. Cho X tc dng hon ton vi 100ml dung dch NaOH 2M,
sau phn ng thu c dung dch X v 2,24 lt kh Y (ktc). Nu trn lng kh Y ny vi 3,36 lt H2 (ktc) th c hn
hp kh c t khi so vi H2 l 9,6. Hi khi c cn dung dch X th thu c bao nhiu gam cht rn khan?
Cu 31: em nhhit phn hon ton a mol Fe(NO3)2 thu c hn hp kh X c t khi so vi H2 bng T1. Nhit
phn hon ton a mol Fe(NO3)3 thu c hn hp kh Y c t khi so vi H2 bng T2. Biu thc no di y l
ng:
A. T
1
= 0,972T
2
. B. T
1
= T
2
. C. T
2
= 0,972T
1
. D. T
2
= 1,08T
1
.
Cu 32: Trong cc loi t sau: T visco, t xenluloz axetat, t olon, t enang, nilon-6,6. S t c iu ch bng phn ng
trng ngng l
A. 1. B. 4. C. 3. D. 2.
Cu 33: Mt hn hp rn gm Ca v CaC2 tc dng vi nc (d) thu c hn hp kh c t khi i vi H2 l 5.
trung ho dung dch sau phn ng, cn dng 600 ml dung dch HCl 0,5M. Tnh khi lng ca hn hp rn
dng ban u:
A. 4 gam B. 7,2 gam C. 8,4 gam D. 9,6 gam
Cu 34: nh hng ca nhm -OH n nhn thm C6H5- trong phn t phenol lm cho phenol
A. c tnh c. B. kh tan trong nc.
C. tc dng c vi dung dch kim D. d tham gia phn ng th trong nhn thm.
Cu 35: Cao su buna-N c to ra do phn ng ng trng hp gia buta-1,3-ien vi acrylonitrin (CH2=CH
CN). t chy hon ton cao su buna-N vi khng kh va , sau a hn hp sau phn ng v 136,5
o
thu
c hn hp kh Y ch 14,41% CO2 v th tch. T l mc xch gia buta-1,3-ien v acrylonitrin:
A. 1:2 B. 2:1 C. 2:3 D. 3:2
Cu 36: Cho 200 dung dch K2HPO4 1M tc dng vi dung dch cha 300ml dung dch H3PO4 0,5M. Tnh khi lng
mui thu c sau phn ng.
A. 23,1 gam. B. 51,4 gam. C. 28 gam. D. 41,6 gam.
Cu 37: C cc bnh mt nhn cha cc kh sau: CO2, SO2, C2H4, C2H2, SO3. Hy cho bit c th s dng dy cc
thuc th no nhn bit cc kh :
A. dung dch NaOH, dung dch H2SO4, dung dch Ca(OH)2 v AgNO3/NH3
B. dung dch HCl, dung dch Na2SO4, nc brom v AgNO3 /NH3
C. dung dch Ba(OH)2, dung dch Na2SO4, nc brom v AgNO3 /NH3
D. dung dch Ba(OH)2, dung dch H2SO4, nc brom v AgNO3 /NH3
143 | G S T T G R O U P
Cu 38: Hn hp M gm ancol no, n chc, mch h X v ancol khng no, a chc, mch h Y (Y cha 1 lin kt
trong phn t v X, Y c cng s mol). t chy hon ton mt lng M cn dng V lt O2 (ktc) sinh ra 2,24 lt
CO2 (ktc) v 2,16 gam H2O. Cng thc ca Y v g tr ca V ln lt l
A. C4H6(OH)2 v 2,912 B. C3H4(OH)2 v 3,584.
C. C4H6(OH)2 v 3,584. D. C5H8(OH)2 v 2,912.
Cu 39: Thu phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32
gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l:
A. 111,74. B. 81,54. C. 66,44. D. 90,6
Cu 40: Nhm th c sn trn nhn benzen nh hng phn ng th vo v tr ortho v para l:
A. OH , NH2, gc ankyl, halogen B. CnH2n+1-, NO2
C. OH, NH2, CHO D. CnH2n+1-, COOH
Cu 41: Mt hn hp gm axetilen, propilen, metan.
- t chy hon ton 11 gam hn hp th thu c 12,6 gam H2O
- Mt khc 5,6 lt hn hp (ktc) phn ng va vi dung dch cha 50 gam brom.
% th tch ca hn hp u ln lt l
A. 40%, 30%, 30% B. 30%, 35%, 35% C. 25%, 37,5%, 37,5% D. 50%, 25%, 25%
Cu 42: Khi thu phn 0,1 mol este A c to bi mt ancol a chc vi mt axit cacboxylic n chc cn dng va
12 gam NaOH. Mt khc thu phn 6,35 gam A cn dng 3 gam NaOH v thu c 7,05 gam mui. Cng thc ca A l:
A. (CH3COO)3C3H5 B. (HCOO)3C3H5 C. (C2H3COO)3C3H5 D. (CH3COO)2C2H4
Cu 43: Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na, NaOH,
Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca X1, X2 ln lt l:
A. CH3-COOH, CH3-COO-CH3. B. (CH3)2CH-OH, H-COO-CH3.
C. H-COO-CH3, CH3-COOH. D. CH3-COOH, H-COO-CH3
Cu 44: Chia hn hp axetilen, buta-1,3-ien, isopren lm hai phn bng nhau. Phn 1 em t chy thu c
1,76 gam CO2 v 0,54 gam H2O. Phn 2 em tc dng vi dung dch Br2 d th khi lng Br2 tham gia phn ng
l:
A. 6,4 gam B. 3,2 gam C. 4 gam D. 1,6 gam
Cu 45: Hiro ho hon ton 0,3mol hn hp X cha hai anehit n chc, h (trong mi phn t cha khng
qu 2 lin kt ) cn va 0,4 mol H2 v thu c hai ancol no Y. t chy hon ton Y v sc sn phm chy
vo 163,6 gam dung dch NaOH 40%, sau phn ng nng ca NaOH cn li l 12,72%. Tn gi ca hai anehit
l:
A. Anehit axetic v anehit metacrylic B. Anehit axetic v anehit acrylic
C. Anehit fomic v anehit acrylic D. Anehit fomic v anehit metacrylic
Cu 46: Cho cc cht: etyl axetat, anilin, ancol etylic, axit acrylic, phenol, phenylamoniclorua, ancol benzylic, p-
crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l
A. 5. B. 6 C. 4 D. 3
a. C2H6 + Br2 d. 2C2H5OH C2H5OC2H5+ H2O
b. C2H2 + Br2 e. C2H5COOH + Na
c. C2H5OH + HBr f. CH3CHO + H2
Cc phn ng thuc loi phn ng th l:
A. a, d, e B. a, f, e C. a, e, c, f D. a, c, d, e
Cu 48: Cng thc n gin nht ca 1 anehit no, a chc, mch h l C2H3O. Cng thc phn t ca n l
A. C4H6O2. B. C4H6O. C. C12H18O6. D. C8H12O4.
Cu 49: Cho 13,6 gam hn hp X gm 2 axit n chc l ng ng k tip ca nhau, phn ng vi 200 ml dung
dch NaOH 1M. Sau phn ng c cn dung dch thu c 15,28 gam cht rn. Hy tm cng thc cu to ca 2 axit
trn.
A. HCOOH v CH2 = CH COOH B. CH2 = CH COOH v CH2 = C(CH3) COOH
C. CH3COOH v C2H5COOH D. HCOOH v CH3COOH
144 | L O V E B O O K . V N
Cu 50: Hn hp CH4, C3H8, C2H6 t khi so vi H2 l 15. t chy hon ton 0,1 mol hn hp trn cho ton b sn
phm kh thu c vo dung dch Ca(OH)2 d. Xc nh khi lng kt ta thu c:
A. 30g B. 40g C. 20g D. 10g

P N

1A 2C 3A 4D 5D 6C 7D 8C 9B 10B
11D 12B 13A 14B 15C 16A 17D 18C 19A 20C
21A 22B 23B 24A 25C 26A 27B 28B 29B 30C
31C 32C 33B 34D 35C 36A 37D 38A 39B 40A
41D 42C 43D 44B 45C 46A 47D 48A 49D 50C
51 52 53 54 55 56 57 58 59 60B

145 | G S T T G R O U P
s 21

Cu 1: Mt cht bt mu lc thm X thc t khng tan trong dung dch long ca axit v kim. Khi nu chy vi
dd NaOH c v c mt kh clo n chuyn thnh cht Y d tan trong nc, cht Y tc dng vi dd axit sunfuric
long chuyn thnh cht Z . Cht Z b S kh thnh cht X v cht Z oxi ha c axit clohidric thnh kh clo. Tn
ca cc cht X, Y, Z v s phn ng oxi ha - kh ln lt l:
A. crom(III) hiroxit; natriicromat; natricromat; 2 B. crom(III) oxit; natricromat; natriicromat; 3
C. crom(III) oxit; natriicromat ; natricromat; 2 D. crom(III) oxit; natricromat; natriicromat; 2
Cu 2: Cho 2,58 gam hn hp gm Al v Mg phn ng va vi 20 ml dung dch hn hp 2 axt HNO3 4M v
H2SO4 7M (m c). Thu c 0,02 mol mi kh SO2, NO, N2O. Tnh s khi lng mui thu c sau phn ng
Cu 3: Mt hn hp X gm ankan A v anken B c chia thnh 2 phn:
- Phn 1: c th tch l 11,2 lt, em trn vi 6,72 lt H2, un nng (c xc tc Ni) n khi phn ng hon ton
ri a v nhit v p sut ban u th thy hn hp kh sau phn ng c th tch gim 25% so vi ban u.
- Phn 2: nng 80 gam, em t chy hon ton thu c 242 gam CO2.
Cng thc phn t ca A v B ln lt l:
A. C4H10 v C3H6 B. C3H8 v C2H4 C. C2H6 v C3H6 D. CH4 v C4H8
Cu 4: Hp th hon ton V lt CO2 (ktc) vo 400ml dung dch NaOH a M th thu c dng dch X. Cho t t va khuay
e u 300ml dung dch HCl 1M vo X thu c dd Y v 4,48 lt kh (ktc). Cho Y tc dng vi Ca(OH)2 d xut hin 30 gam
kt ta. Xa c inh a?
A. 0,75M. B. 2M. C. 1,5M. D. 1M.
Cu 5: E l este mch khng nhnh ch cha C, H, O, khng cha nhm chc no khc. un nng mt lng E vi
150 ml dung dch NaOH 1M n kt thc phn ng. trung ho dung dch thu c cn 60ml dung dch HCl
0,5M. C cn dung dch sau khi trung ho c 11,475 gam hn hp hai mui khan v 5,52 gam hn hp 2 ancol
n chc. CTCT ca este l
A. CH3CH2CH2-OOC-CH2CH2COOCH3 B. HCOOCH3 v CH3COOC2H5
C. C2H5-COO-C2H5 D. CH3-CH2-OOC-CH2COOCH3
Cu 6: phn bit 4 cc ng ring bit 4 loi nc sau b mt nhn: nc ct, nc cng tm thi, nc cng
vnh cu, nc cng ton phn:
A. un nng, dng dd NaOH B. dng dd Na2CO3 , un nng
C. un nng, dng dd Na2CO3 D. Dng dd Ca(OH)2 , un nng
Cu 7: Cho hi nc i qua than nng c hn hp kh A gm CO2,CO, H2. Ton b lng kh A va kh ht 72 gam
CuO thnh Cu v thu c m gam H2O. Lng nc ny hp th vo 8,8 gam dd H2SO4 98% th dd axit H2SO4 gim xung
cn 44%. Phn trm th tch CO2 trong hn hp kh A l
A. 28,57. B. 16,14. C. 14,29. D. 13,24.
Cu 8: Ho tan mt loi qung st vo dd HNO3 long, d thu c hn hp X gm 2 cht kh khng mu trong
c mt kh l oxit ca nit. Tn gi ca qung b ho tan l:
A. Hematit nu. B. Manhetit. C. Xiderit. D. Pirit.
Cu 9: Mt trong cc tc dng ca mui it l c tc dng phng bnh bu c. Thnh phn ca mui it l:
A. NaCl c trn thm mt lng nh KI B. NaCl c trn thm mt lng nh AgI
C. NaCl c trn thm mt lng nh I2 D. NaCl c trn thm mt lng nh HI
Cu 10: C 5 hn hp kh c nh s:
1. CO2, SO2, N2, HCl. 2. Cl2, CO, H2S, O2. 3. HCl, CO, N2, Cl2.
4. H2, HBr, CO2, SO2. 5. O2, CO, N2, H2, NO. 6. F2 , O2 ; N2 ; HF
C bao nhiu hn hp kh khng tn ti c iu kin thng :
A. 2 B. 5 C. 4 D. 3
Cu 11: Ta tin hnh cc th nghim:
146 | L O V E B O O K . V N
MnO2 tc dng vi dung dch HCl (1). t qung sunfua (2); Nhit phn mui Zn(NO3)2 (3). Nung hn hp:
CH3COONa + NaOH/CaO (4). Nhit phn KNO3(5).
Cc bao nhiiu th nghim to ra sn phm kh gy nhim mi trng l:
A. 5 B. 3 C. 4 D. 2
Cu 12: C 3 dung dch sau ng trong 3 l mt nhn: dung dch natriphenolat, natri cacbonat, natrialuminat,
natri fomat. phn bit 3 dung dch ny bng mt thuc th ta dng:
A. Dung dch HCl B. Qu tm C. Dung dch CaCl2 D. Dung dch NaOH
Cu 13: Nhit phn 17,54 gam hn hp X gm KClO3 v KMnO4, thu c O2 v m gam cht rn gm K2MnO4,
MnO2 v KCl . Ton b lng O2 tc dng ht vi cacbon nng , thu c 3,584 lt hn hp kh Y (ktc) c t
khi so vi O2 l 1. Thnh phn % theo khi lng ca KClO3 trong X l:
A. 62,76% B. 74,92% C. 72,06% D. 27,94%
Cu 14: Cho 80 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 83,02
gam hn hp mui khan. Khi lng NaOH tham gia phn ng l:
Cu 15: Chn cu sai trong s cc cu sau y
A. Ngm thanh thp trong du ha ri ngoi khng kh m thanh thp s b n mn chm hn
B. Trn b mt ca cc h nc vi hay cc thng nc vi ngoi khng kh thng c mt lp vng mng.
Lp vng ny ch yu l canxi cacbonat.
C. Nhit nng chy ca hp kim thng cao hn nhit nng chy ca cc kim loi ban u
D. Phng php in phn c th iu ch c hu ht cc kim loi t Li, Na, Fe, Cu, Ag.
Cu 16: Dy cc cht no sau y tt c cc cht u d b nhit phn
A. NaHCO3, MgCO3, BaSO4, (NH4)2CO3. B. NaHCO3, NH4HCO3, H2SiO3, NH4Cl.
C. K2CO3, Ca(HCO3)2, MgCO3, (NH4 )2CO3, D. NaHCO3, Na2CO3, CaCO3, NH4NO3.
Cu 17: Cho tng dung dch: NH4Cl, HNO3, Na2CO3, Ba(HCO3)2, MgSO4, Al(OH)3 ln lt tc dng vi dung dch Ba(OH)2.
S phn ng thuc loi axit baz l:
A. 4 B. 2 C. 5 D. 3
Cu 18: Cho cc t sau: t axetat, t capron, t nitron, t visco, t nilon-6,6; t enang hay t nilon-7, t lapsan
hay poli (etylen terephtalat). C bao nhiu t thuc loi t poliamit?
A. 2 B. 4 C. 3 D. 1
Cu 19: T khi hn hp X gm: C2H6; C2H2; C2H4 so vi H2 l 14,25. t chy hon ton 11,4 gam X, cho sn phm
vo bnh ng dung dch Ca(OH)2 d thy khi lng bnh tng m gam v c a gam kt ta. Gi tr ca m v a ln
lt l
A. 62,4 v 80. B. 68,50 v 40. C. 73,12 v 70. D. 51,4 v 80.
Cu 20: Cho hn hp cha Na, Ba ly d vo 180g dung dch H2SO4 49% th th tch kh H2 thot ra iu kin
tiu chun l:
A. 20,16 lit B. 77,28 lit C. 134,4 lit D. 67,2 lit
Cu 21: Cho 5,6g bt Fe vo 300ml dung dch HCl 1M sau phn ng thu c dung dch A. Cho A tc dng vi
800ml dung dch AgNO3 1M n phn ng hon ton to m gam kt ta. Gi tr ca m l:
A. 43,05g B. 10,8g C. 21,6g D. 53,85g
Cu 22: Cho cc cht: etilenglicol, anlyl bromua, metylbenzoat, valin, brombenzen, axit propenoic, axeton, tripanmitin,
lng trng trng, .Trong cc cht ny, s cht tc dng vi dd NaOH l:
A. 5 B. 6 C. 4 D. 7
Cu 23: Cho m gam Fe vo dung dch AgNO3 c hn hp X gm 2 kim loi. Chia X lm 2 phn.
- Phn 1: c khi lng m1 gam, cho tc dng vi dung dch HCl d, c 0,1 mol kh H2.
- Phn 2: c khi lng m2 gam, cho tc dng ht vi dung dch HNO3 long d, c 0,4 mol kh NO. Bit m2
m1 = 32,8. Gi tr ca m bng:
A. 1,74 gam hoc 6,33 gam B. 33,6 gam hoc 47,1 gam
C. 3,36 gam hoc 4,71 gam D. 17,4 gam hoc 63,3 gam
147 | G S T T G R O U P
Cu 24: Ho tan hon ton m gam hn hp X gm FeS
2 v Cu
2
S vo axit HNO
3 (va ), thu c dung dch X
(ch cha hai mui sunfat) v 8,96 lt (ktc) kh duy nht NO. Nu cng cho lng X trn tan vo trong dd H2SO4
c nng thu c V lit (ktc) kh SO2 . Gi tr ca V l
A. 8,96. B. 13,44. C. 6,72. D. 5,6.
Cu 25: Cho dy cc cht: isopentan , lysin, glucoz, isobutilen, propanal, isopren, axit metacrylic, phenyl amin,
m-crezol, cumen, stiren, xiclo propan. S cht trong dy phn ng c vi nc brom l:
A. 9 B. 6 C. 8 D. 7
Cu 26: Trong cc dy cht sau, dy gm tt c cc cht u khng tham gia phn ng trng bc l:
A. Vinyl axetilen, etilen, benzen, axit fomic
B. Metyl axetat, but-2-in, mantoz, fructoz
C. Vinyl fomat, but-1-in, vinyl axetilen, anehit propionic
D. Axetilen, propin, saccaroz, axit oxalic
Cu 27: Cho cc pht biu sau v cacbohirat:
(a) fructoz v saccaroz u l cht rn c v ngt, d tan trong nc.
(b) Tinh bt v xenluloz u l polisaccarit, khi un vi dd H2SO4 long th sn phm thu c u c phn
ng trng gng
(c) Trong dung dch, glucoz v saccaroz u ha tan Cu(OH)2, to phc mu xanh lam m.
(d) Khi thy phn hon ton hn hp gm xeluloz v saccaroz trong mi trng axit, ch thu c mt loi
monosaccarit duy nht.
(e) Khi un nng fructoz vi Cu(OH)2/ NaOH u thu c Cu2O
(g) Glucoz v glucoz u tc dng vi H2 (xc tc Ni, un nng) to sobitol.
S pht biu ng l:
A. 3 B. 5 C. 4 D. 6
Cu 28: Cho cn bng ha hc: a A(k) + b B(k) cC(k) + d D(k). (A, B, C, D l k hiu cc cht, a, b, c, d l h s nguyn
dng ca phng trnh phn ng). 105
0
C, s mol cht D l x mol; 180
o
C, s mol cht D l y mol. Bit x > y, (a
+ b) > (c + d). Kt lun no sau y ng:
A. Phn ng thun ta nhit v tng hiu sut cn gim p sut
B. Phn ng thun ta nhit v tng hiu sut cn tng p sut
C. Phn ng thun thu nhit v tng hiu sut cn tng p sut
D. Phn ng thun thu nhit v tng hiu sut cn gim p sut.
Cu 29: 17,7 gam hn hp X gm 2 anehit n chc phn ng hon ton vi dung dch AgNO3 trong NH3 (dng
d) c 1,95 mol Ag v dung dch Y. Ton b Y tc dng vi dung dch HCl d c 0,45 mol CO2. Cc cht trong
hn hp X gm:
A. C2H3CHO v HCHO B. C2H5CHO v CH3CHO
C. CH3CHO v HCHO D. C2H5CHO v HCHO
Cu 30: Cho s sau:
X Z
CH3COOH
Y T
Vi mi mi tn l mt phn ng th X, Y, Z, T l:
A. etanol, natri axetat, anehit axetic, glucoz B. etylaxetat ,natri etylat, etanol,
C. anehit axetic, vinylaxetat, etylclorua, butan D. metanol, butan, etanol ,natri axetat
Cu 31: in phn 1lit dd hn hp gm HCl 0,01M; CuSO4 0,01M v NaCl 0,02M vi in cc tr, mng ngn xp.
Khi anot thu c 0,336lit kh (ktc) th dng in phn. Dung dch sau in phn c pH bng:
A. pH =8 B. pH =6 C. pH =7 D. pH =5
Cu 32: Trong cc phn ng sau:
1, dung dch BaS + dd H2SO4 2, dung dch Na2CO3 +dd FeCl3
3, dung dch Na2CO3 + dd CaCl2 4, dung dch Mg(HCO3)2 + dd HCl
148 | L O V E B O O K . V N
5, dung dch(NH4)2SO4 + dd KOH 6, dung dch NH4HCO3 + dd Ba(OH)2
Cc phn ng sn phm to ra c ng thi c kt ta v kh bay ra l:
A. 1, 2, 6 B. 1, 4, 6 C. 3, 4, 5 D. 1, 5, 6
(a) Khi t chy hon ton mt cht hu c X bt k cha C, H, O, nu thu c s mol CO2 nh hn s mol
H2O th X l ankan hoc ancol no, mch h
(b) Trong thnh phn hp cht hu c nht thit phi c H
(c) Lin kt ha hc ch yu trong hp cht hu c l lin kt cng ha tr.
(d) Nhng hp cht hu c c thnh phn nguyn t ging nhau, thnh phn phn t hn km nhau 1 hay
nhiu nhm CH2 - l ng ng ca nhau
(e) Phn ng hu c thng xy ra chm v khng theo mt hng nht nh
(g) Hp cht C7H8BrCl c vng benzen trong phn t
S pht biu ng l
A. 4 B. 3 C. 2 D. 5
A. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ha hc, ch cn dng thuc
th l dd KMnO4.
B. Dung dch phenol v dung dch anilin khng lm i mu qu tm nhng dung dch mui ca chng th lm
i mu qu tm
C. Phn ng gia glixerol vi axit HNO3 c ( iu kin thch hp), to thnh thuc sng khng khi
D. Trong phn ng este ha gia cc axit hu c, n chc RCOOH vi ancol no, n chc R
OH, sn phm
H2O to nn t -H trong nhm -COOH ca axit v nhm -OH ca ancol.
: Cho s sau: (CH
3
)
2
CH CH
2
CH
2
Cl
KOH,etanol (t
0
)
A
HCl
B
KOH/etanol (t
0
)
A
HCl
D
NaOH,H
2
O (t
0
)
E
E c cng thc cu to l
A. (CH
3
)
2
CHCH
2
CH
2
OH. B. (CH
3
)
2
CHCH(OH)CH
3
.
C. (CH
3
)
2
C = CHCH
3
. D. (CH
3
)
2
C(OH) CH
2
CH
3
.
Cu 36: Cho cc nguyn t 19K, 11Na, 20Ca, 9F, 8O, 17Cl. C bao nhiu phn t hp cht ion to thnh t 2 nguyn
t trong cc nguyn t trn c cu hnh electron ca cation khc cu hnh electron ca anion ?
A. 4 B. 6 C. 3 D. 5
Cu 37: Cht X c cng thc phn t C8H14O4 tho mn s sau:
X + 2NaOH X1 + X2 + H2O X1 + H2SO4 X3 + Na2SO4
nX3 + nX4 nilon 6,6 + nH2O 2X2 + X3 X5 + 2H2O;
Cng thc cu to ca X l:
A. HCOO(CH2)6OOCH B. CH3OOC(CH2)4COOCH3
C. CH3OOC(CH2)5COOH D. CH3CH2OOC(CH2)4COOH
Cu 38: Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c n chc Y
v cc cht v c. Khi lng phn t (theo vC) ca Y l
A. 46 B. 68 C. 45 D. 85
Cu 39: Cho cc cht sau: ancol etylic(1),imetyl ete (2), axit axetic (3), metyl axetat(5), etyl clorua(6). Sp xp theo
chiu gim nhit si l:
A. 3 > 1 > 5 > 2 > 6 B. 3 > 1 > 5 > 6 > 2 C. 3 > 1 > 6 > 5 > 2 D. 3 > 1 > 6 > 2 > 5
Cu 40: Hn hp kh A gm SO2 v khng kh c t l th tch l 1 : 5. Nung hn hp A vi xc tc V2O5 trong mt
bnh kn c dung tch khng i thu c hn hp kh B. T khi ca A so vi B l 0,93. Khng kh c 20% th tch
l O2 v 80% th tch l N2. Tnh hiu sut ca phn ng oxi-ha SO2:
A. 75% B. 86% C. 84% D. 80%
Cu 41: So snh linh ng ca nguyn t H trong nhm chc ca cc cht hu c sau:
C6H5OH, HOCH2-CH2OH ; C6H13OH , C6H5COOH
A. HOCH2-CH2OH < C6H13OH < C6H5OH < C6H5COOH B. HOCH2-CH2OH < C6H13OH < C6H5COOH < C6H5OH
149 | G S T T G R O U P
C. C6H13OH < HOCH2-CH2OH < C6H5OH < C6H5COOH D. C6H5OH < HOCH2-CH2OH < C6H13OH < C6H5COOH
Cu 42: Hai cc ng dung dch HCl t trn hai a cn A, B. Cn trng thi cn bng. Cho 5gam CaCO3 vo cc
A v 4,784gam M2CO3 (M : Kim loi kim) vo cc B. Sau khi hai mui tan hon ton, cn tr li v tr thng
bng. Kim loi M l?
A. K B. Cs C. Li D. Na
Cu 43: un nng hn hp A gm: 0,1 mol axeton; 0,08 mol anehit acrylic (propenal); 0,06 mol isopren v
0,32mol hiro c Ni lm xc tc thu c hn hp kh v hi B. T khi ca B so vi khng kh l 375/203. Hiu
sut hiro tham gia phn ng cng l:
A. 87,5% B. 93,75% C. 80% D. 75,6%
Cu 44: Kh no tha mn tt c cc tnh cht: to kt ta vi dung dch AgNO3, lm mt mu dung dch KMnO4, khng tn ti
trong mt hn hp vi SO2, tc dng c vi nc Clo.
A. C2H2 B. H2S C. NH3 D. HCl
Cu 45: Y l hexapeptit c to thnh t glyxin. Cho 0,15 mol Y tc dng hon ton vi dd NaOH (ly d 20% so
vi lng cn thit), sau phn ng c cn dung dch th thu c bao nhiu gam cht rn?
Cu 46: Mt hn hp gm hai axit cacboxylic no, n chc k tip nhau trong dy ng ng. Ly m gam hn hp ri
thm vo 75ml dung dch NaOH 0,2M, sau phi dng ht 25ml dung dch HCl 0,2M trung ha kim d thu c
dung dch X. C cn dung dch X n khi lng khng i thu c 1,0425gam mui khan. Phn trm khi lng ca
axit c khi lng phn t b hn trong hn hp trn l:
A. 50% B. 43,39% C. 40% D. 46,61
Cu 47: t chy hon ton mt lng hn hp X gm mt s ancol thuc cng dy ng ng cn dng 10,08 lit
kh O2 (ktc) thu c 6,72 lt kh CO2 (ktc) v 9,90 gam H2O. Nu un nng 10,44g hn hp X nh trn vi H2SO4
c nhit thch hp chuyn ht thnh ete th tng khi lng ete thu c l:
Cu 48: Hai cht hu c X, Y c thnh phn phn t gm C, H, O (MX <MY <74). C X v Y u c kh nng tham gia
phn ng trng bc v u phn ng c vi dung dch KOH sinh ra mui. T khi hi ca Y so vi X c gi tr l:
A. 1,403 B. 1,333 C. 1,304 D. 1,3
Cu 49: Hn hp X gm CaO, Mg, Ca, MgO. Ha tan 5,36 gam hn hp X bng dd HCl va thu c 1,624 lt H2
(ktc) v dung dch Y trong c 6,175 gam MgCl2 v m gam CaCl2. Gi tr ca m l
Cu 50: Este X c cng thc phn t dng C
n
H
2n2
O
2
. t chy 0,42 mol X ri cho sn phm chy hp th hon
ton vo dung dch nc vi trong c cha 68,376 gam Ca(OH)2 th thy dung dch nc vi trong vn c. Thu
phn X bng dung dch NaOH thu c 2 cht hu c khng tham gia phn ng trng gng. Pht biu no sau
y v X l ng:
A. X l ng ng ca etyl acrylat
B. Thnh phn % khi lng O trong X l 36,36%
C. Khng th iu ch c t ancol v axit hu c tng ng
D. Tn ca este X l vinyl axetat

P N

1B 2B 3D 4C 5A 6C 7C 8C 9A 10D
11C 12A 13D 14B 15C 16C 17A 18C 19D 20B
21D 22A 23B 24B 25A 26D 27B 28B 29A 30D
31C 32A 33C 34B 35D 36D 37D 38C 39B 40C
41C 42D 43A 44B 45D 46B 47A 48C 49B 50A


150 | L O V E B O O K . V N
Cu 1: p n B
X: Cr
2
O
3
; Y: Na
2
CrO
4
; Z: Na
2
Cr
2
O
7
.
Cr
2
O
3
NaOH,Cl
2
Na
2
CrO
4
+H
+
Na
2
Cr
2
O
7
+S
Na
2
SO
4
+ Cr
2
O
3

Na
2
Cr
2
O
7
+HCl
Cl
2

C 3 phn ng oxi ha kh.
Cu 2: p n B
Mg, Al + dung dch axit mui + hn hp kh + H2O.
Ta c n
H
2
O
=
1
2
n
H
+ =
1
2
(0,02.4 +0,02.2.7) = 0,18 (mol)
+)p dng nh lut bo ton khi lng: mmui = mkim loi + maxit moxit - mnc
m
mui
= 2,58 + 0,08.63 + 0,14.98 0,02. (64 + 30 + 44) 0,18.18 = 15,34(g)
Cu 3: p n D
ankan A: C
n
H
2n+2
; anken B: C
m
H
2m
.
+) Phn 1: C
m
H
2m
+ H
2
C
m
H
2m+2

Th tch hn hp gim bng th tch H
2
phn ng: 25%. (11,2 + 6,72) = 4,48 (l) < V
H
2
(ban u).
Suy ra H
2
d, nn B ht v V
B
= 4,48(l) V
A
= 6,72(l) V
A
= 1,5V
B
.
+)Phn 2: gi x, y l s mol ca A,B.
Ta c:
{
(14n +2)x +14my = 80

x =
3
2
y
n
CO
2
= nx +my = 5,5
{
x = 1,5
y = 1
1,5n +m = 5,5

+)1,5n + m = 5,5 n = 1; m = 4. Suy ra l CH
4
v C
4
H
8
.
Cu 4: p n C
n
HCl
= 0,3 > n
CO
2
= 0,2, m dung dch Y to kt ta vi dung dch Ca(OH)
2
nn HCl ht.
n
HCl
= n
CO
3
2 +n
CO
2
0,3 = n
CO
3
2 +0,2 n
CO
3
2 = 0,1(mol)
S mol CO
2
ban u: n
CaCO
3
+n
CO
2
= 0,5(mol)
+Bo ton nguyn t C: n
CO
2
(ban u) = 2n
Na
2
CO
3
+n
NaHCO
3
0,5 = 0,1 +n
NaHCO
3

n
NaHCO
3
= 0,4 mol
+Ta c: n
NaOH
= 2n
Na
2
CO
3
+n
NaHCO
3
= 0,6(mol) [NaOH] =
0,6
0,4
= 1,5 M
Cu 5: p n A
Este E + dung dch NaOH 2 ancol n chc nn da vo cc p n tr li th E c dng R(COOR
)2.
Phng trnh ha hc: R(COOR
)
2
+ 2NaOH R(COONa)
2
+ 2R
OH.
HCl + NaOH NaCl + H
2
O.
n
NaOH
(d) = n
HCl
= 0,03(mol) n
mui
= 0,15 0,03 = 0,12(mol)
Ta c: M
mui
= m
NaCl
+m
R(COOR
)
2
(R +134). 0,12 +0,03.58,5 = 11,475 (g)
R = 28(CH
2
CH
2
).
M
ancol
=
5,52
0,12
R
+17 = 46 R
= 29 2 ancol l CH
3
OH v C
3
H
7
OH.
Vy E l: C
3
H
7
OOCCH
2
CH
2
COOCH
3
.
Cu 6: p n C
Cu 7: p n C
C + H
2
O CO + H
2
C + 2H
2
O CO
2
+ 2H
2

x x x y y 2y
n
CO
+n
H
2
= n
CuO
2x +2y = 0,9 x +y = 0,45.
p dng phng php ng cho ta tm c: n
H
2
O
= x +2y = 0,6
151 | G S T T G R O U P
Suy ra x = 0,3 mol; y = 0,15 mol. Vy %V
CO
2
= %n
CO
2
=
y
2x +3y
. 100% = 14,29%
Cu 8: p n C
Khi tc dng vi dung dch HNO3 long th:
A, Hemantit nu Fe
2
O
3
. nH
2
O: khng to kh.
B, manhetit Fe
3
O
4
: to ra kh NO duy nht.
C, Xiderit FeCO3: to ra hn hp kh CO2 v NO.
D, Pirit FeS2: to kh NO duy nht
Cu 9: p n A
Cu 10: p n D
V CO + Cl
2
COCl
2
. 2NO + O
2
2NO
2
.
Do loi cc phng n 2, 3, 5.
Cu 11: p n C
Sn phm kh ca cc th nghim:
1, Cl2 2, H2S 3, NO2 + O2 4, CH4. 5, O2.
Cc kh gy nhim mi trng l: Cl
2
, H
2
S, CH
4
, (NO
2
+ O
2
).
Cu 12: p n A
Ta s dng thuc th: dung dch HCl.
+) C6H5ONa: c kt ta trng C6H5OH.
+) Na2CO3: c bt kh CO2.
+) NaAlO2: c kt ta trng, tan trong kim d.
+) HCOONa: khng c hin tng g.
Cu 13: p n D
Gi x, y l s mol KClO
3
v KMnO
4
.
Hn hp Y (CO +CO
2
), s dng phng php ng cho ta c: n
CO
2
= 0,04 v n
CO
= 0,12
Bo ton nguyn t O: n
O
2
= n
CO
2
+
1
2
n
CO
= 0,1(mol)
Theo bi ra ta c: {
m
hh
= 122,5x +158y = 17,54
n
O
2
=
3
2
x +
1
2
y = 0,1
{
x = 0,04
y = 0,08

Vy %m
KClO
3
=
0,04.122,5
17,54
. 100%= 27,94%.
Cu 14: p n B
R
COOH + NaOH R
COONa + H
2
O (1)
(R
COO)
3
C
3
H
5
+ 3NaOH 3R
COONa + C
3
H
5
(OH)
3
(2)
x 3x 3x x

n
NaOH(1)
=
80.7
1000.56
= 0,01 n
H
2
O
= 0,01(mol).
p dng nh lut bo ton khi lng: m
cht bo
+m
NaOH
= m
mui
+m
H
2
O
+m
C
3
H
5
(OH)
3

Suy ra: 80 + 40(0,01 + 3x) = 83,02 + 18.0,01 + 92x x = 0,1(mol)
n
NaOH
= 0,01 +3x = 0,31(mol) m
NaOH
= 0,31.40 = 12,4 (g).
Cu 15: p n C
A, ng v du ha to lp mng bao ph ln b mt thanh st ngn khng cho st tip xc vi khng kh
m, nn s trnh c hin tng n mn.
B, ng v phn dung dch trong h vi l Ca(OH)2 tc dng vi CO2 trong khng kh to ra lp vng CaCO3
hnh thnh trn b mt.
Cu 16: p n C
Cc mui BaSO
4
, cacbonat ca kim loi kim khng b nhit phn.
H
2
SiO
3
H
2
O + SiO
2

152 | L O V E B O O K . V N
Cu 17: p n A
Khi phn ng vi dung dch Ba(OH)2 th cc cht ng vai tr l axit l:
NH
4
Cl, HNO
3
, Ba(HCO
3
)
2
, Al(OH)
3
= HAlO
2
. H
2
O (axit aluminic).
Cu 18: p n C
T poliamit: t capron (NH (CH
2
)
5
CO )
n
,
t nilon 6,6 (NH(CH
2
)
6
NHCO (CH
2
)
4
CO )
n
, t nilon 7 (NH (CH
2
)
6
CO )
n

Cu 19: p n D
Ta ch tt c hirocacbon u c 2 nguyn t C.
Gi X: C
2
H
x
MX = 24 + x = 14,25.2 x = 4,5.
C
2
H
4,5
2CO
2
+ 2,25H
2
O
Mol: 0,4 0,8 0,9
+) m = m
CO
2
+m
H
2
O
= 0,8.44 + 0,9.18 = 51,4(g)
+) a = m
CaCO
3
= 0,8.100 = 80(g).
Cu 20: p n B
n
H
2
SO
4
= 0,9; n
H
2
O
= 5,1 n
H
2
= n
H
2
SO
4
+
1
2
n
H
2
O
= 3,45 V
H
2
= 3,45.22,4 = 77,28 (l)
Cu 21: p n D
Fe + 2HCl FeCl
2
+ H
2
.
C: n
FeCl
2
= 0,1; n
HCl
= 0,1
Dung dch A + dung dch AgNO
3
: Ag
+
+ Cl
AgCl Ag
+
+ Fe
2+
Fe
3+
+ Ag
Theo phng trnh ha hc: m = m
AgCl
+m
Ag
= 0,3.143,5 +0,1.108 = 53,85(g).
Cu 22: p n A
Cc cht tc dng vi dung dch NaOH l: valin, axit propenoic, tripanmitin, lng trng trng, metyl
benzoat.
Brom benzen tc dng vi NaOH c, p sut cao.
Cu 23: p n B
X tc dng vi dung dch HCl to kh nn X gm x mol Ag v Fe d.
+) Phn 1: n
Fe d
= n
H
2
= 0,1 mol; n
Ag
= y(mol)
t m
2
= n. m
1
. Suy ra: n
Fe(2)
= 0,1n v n
Ag(2)
= ny(mol).
+) Phn 2: p dng nh lut bo ton electron:
0,3n + ny = 1,2 n =
1,2
0,3 +y
n 1 =
0,9 y
0,3 +y
(1)
m2 - m1 = 32,8 5,6(n-1) +108y(n-1) = 32,8(2)
Th (1)vo (2)suy ra:
5,6(0,9 y)
0,3 +y
+
108y(0,9 y)
0,3 +y
= 32,8
Suy ra: 108y
2
58,8y + 4,8 = 0 y = 0,1; y =
4
9
(mol).
Vi y = 0,1 n = 3 n
Fe(X)
= 0,4; n
Ag(X)
= 0,4(mol).
n
Fe ban u
= n
Fe d
+
1
2
n
Ag
= 0,6 (mol) m = 56.0,6 = 33,6 (gam)
Da vo cc p n tr li ta suy ra p n B.
Ta c th tnh tng t khi y =
4
9
(mol) cng ra m = 47,1(g).
Cu 24: p n B
FeS
2
Fe
+3
+ 2 S
+6
+ 15e Cu
2
S 2Cu
+2
+ S
+6
+ 10e.
S
+6
+ 2e S
+4
N
+5
+ 3e N
+2
.
Theo bi ra th s mol e m N
+5
nhn bng s mol S
+6
nhn.
153 | G S T T G R O U P
Suy ra n
SO
2
= 0,6(mol) V
SO
2
= 0,6.22,4 = 13,44(l).
: Vi cch vit: FeS
2
Fe
+3
+ 2 S
+6
+ 15e Cu
2
S 2Cu
+2
+ S
+6
+ 10e.
L khng ng bn cht ca phn ng. ng ra l phi:
FeS
2
Fe
+3
+ 2 S
+4
+ 11e Cu
2
S 2Cu
+2
+ S
+4
+ 8e.
Tuy nhin, vi dng bi ny th n khng nh hng ti kt qu v c th l gii rng, lng S X chuyn
thnh S
+6
sau S
+6
chuyn thnh S
+4
kh SO2 do s e trao i khng b nh hng.
Cu 25: p n A
Ch c isopentan v cumen khng phn ng vi nc brom.
Cu 26: p n D
Cu 27: p n B
d, Sai v xenluloz thy phn cho glucoz, saccaroz thy phn cho glucoz v fructoz.
e, ng v trong mi trng kim fructoz glucoz nn fructoz c phn ng vi Cu(OH)2, t
o
cho Cu2O.
Cu 28: p n B
aA(k) + bB(k) cC(k) + dung dch(k).
n
D,105
0 = x > y = n
D,108
0 phn ng thun ta nhit.
Tng a + b > c +d nn phn ng thun tng khi tng p sut.
Cu 29: p n A
Y + dung dch HCl d CO
2
Y cha (NH
4
)
2
CO
3
X cha HCHO.
n
HCHO
= n
(NH
4
)
2
CO
3
= 0,45(mol)
Hn hp X gm RCHO v HCHO.
RCHO
AgNO
3
/NH
3
2Ag HCHO
AgNO
3
/NH
3
4Ag
0,075 0,15 0,45 1,8
C m
X
= 0,075(R + 29) + 0,45.30 = 17,7 R = 27(CH
2
= CH).
Vy X gm CH2=CHCHO v HCHO.
Cu 30: p n D
Glucoz, C2H5ONa v C2H5Cl khng trc tip to ra CH3COOH ch bng 1 phn ng.
, ng. CH
3
OH + CO
xt,t
0
CH
3
COOH.
2C
4
H
10
+ 5O
2
xt,t
0
4CH
3
COOH + 2H
2
O
Cu 31: p n C
Ta c: CuCl
2
dpdd
Cu + Cl
2
2HCl
dpdd
H
2
+ Cl
2
.
0,01 0,01 0,01 0,05
Sau phn ng dung dch ch cha Na
2
SO
4
vi s mol 0,01 pH = 7.
Cu 32: p n A
1, BaS + H
2
SO
4
BaSO
4
+ H
2
S.
2, 2FeCl
3
+ 3Na
2
CO
3
+ 3H
2
O 2Fe(OH)
3
+ 3CO
2
+ 6NaCl.
6, NH
4
HCO
3
+ Ba(OH)
2
BaCO
3
+ NH
3
+ 2H
2
O.
Cu 33: p n C
b, Sai v CCl4 l 1 hp cht hu c.
d, Sai v chng phi c thm l cu to ging nhau v tnh cht ha hc tng t nhau mi c gi l
ng ng.
e, Sai
g, Sai v bt bo ha k =
7.2 +2 8 1 1
2
= 3
ch c 3 lin kt ( +vng). Trong khi , hp cht cha vng benzen c cha t nht 4 lin kt
(+vng).
154 | L O V E B O O K . V N
Cu 34: p n B
A, Sai v vi KMnO
4
: stiren phn ng nhit thng, toluen phn ng khi un nng v benzen khng
phn ng.
C, Sai.
, Sai v trong phn ng este ha th H
2
O to thnh t OH ca axit v H ca ancol.
Cu 35: p n D
(CH
3
)
2
CHCH
2
CH
2
Cl
KOH,C
2
H
5
OH,t
0
(CH
3
)
2
CHCH = CH
2
(A)
HCl
(CH
3
)
2
CHCHClCH
3
(B)
KOH,C
2
H
5
OH,t
0

(CH
3
)
2
C = CHCH
3
( C)
HCl
(CH
3
)
2
CClCH
2
CH
3
(D)
NaOH,H
2
O,t
0
(E)
Cu 36: p n D
Cc hp cht m cu hnh e ca cation khc cu hnh e ca anion l: K
2
O, CaO, KF, CaF
2
, NaCl c 5 cht.
Cu 37: p n D
nX
3
+nX
4
nilon 6,6 X
3
l axit aipic.
Suy ra X
1
l (CH
2
CH
2
COONa)
2
. V X + 2NaOH X
1
+ X
2
+ H
2
O, phn ng sinh ra mt phn t H
2
O
nn X cha 1 nhm COOH nn X l C
2
H
5
OOCCH
2
CH
2
CH
2
CH
2
COOH.
Cu 38: p n C
X + NaOH Y (hu c) + cc cht v c.
Suy ra X l mui ca HNO
3
vi amin X l C
2
H
5
NH
3
NO
3
Y l C
2
H
5
NH
2
M
Y
= 45.
Cu 39: p n B
Nhit si ca mt hp cht hu c ph thuc vo khi lng phn t v bn lin kt H. Khi lng
phn t cng ln, lin kt H cng bn th nhit si cng cao.
Ta c sp xp: CH
3
COOH(3) > C
2
H
5
OH(1) > CH
3
COOCH
3
(5) > C
2
H
5
Cl(6) > CH
3
OCH
3
(2).
Cu 40: p n C
Gi a l s mol SO
2
n
kk
= 5a mol (a mol O
2
v 4a mol SO
2
).

155 | G S T T G R O U P
2SO
2
+ O
2
2SO
3

Ban u: a a
Phn ng: 2x x 2x
Cn bng: a-2x a-x 2x.
n
S
= 6a x; d
A/B
= 0,93
n
S
n
t
= 0,93
6a x
6a
= 0,93
x
a
= 0,42
Hiu sut: H%=
2x
a
= 84%.
Cu 41: p n C
+) linh ng ca nguyn t H trong nhm OH yu hn trong nhm COOH.
+) Gc hirocacbon gn vi nhm (-OH hay COOH) y e cng mnh th H trong nhm cng km linh
ng v ngc li.
Cu 42: p n D
CaCO
3
+ 2HCl CaCl
2
+ H
2
O + CO
2
. (1) M
2
CO
3
+ 2HCl 2MCl + H
2
O + CO
2
. (2)
Khi cn thng bng tr li suy ra: m
CaCO
3
m
CO
2(1)
= m
M
2
CO
3
m
CO
2(2)
.
5 0,05.44 = 4,784 m
CO
2
(2)
m
CO
2
(2)
= 1,984(g) n
CO
2
(2)
=
1,984
44
(mol)
Suy ra: 2M+60 =
4,784.44
1,984
M = 23(Na).
Cu 43: p n A
m
B
= m
A
+m
H
2
= 15(g) n
B
=
15.203
375.29
= 0,28(mol).
n
H
2
= n
A
+n
H
2
ban u
n
B
= 0,28 (mol) H% =
0,28
0,32
. 100% = 87,5%
Cu 44: p n B
Cc cht c th cng tn ti chung khi chng khng phn ng vi nhau. C2H2, NH3, HCl khng tc dng
c vi kh SO2 nn chng c th tn ti chung vi SO2.
Cu 45: p n D
Y + 6NaOH 6H
2
NCH
2
COONa + H
2
O
Mol: 0,15 0,9 0,9
S mol NaOH d: 0,2.0,9 = 0,18(mol).
m
rn
= m
H
2
NCH
2
COONa
+m
NaOH
(d) = 0,9.97 + 0,18.40 = 84,5 (g).
Cu 46: p n B
Gi 2 axit no n chc l C
n
H
2n+1
COOH.
C
n
H
2n+1
COOH + NaOH C
n
H
2n+1
COONa + H
2
O NaOH + HCl NaCl + H
2
O.
0,01 0,01 0,05 0,05 0,05
m
mui
= 0,01(14n + 68) + 0,005.58,5 = 1,0425 n =
1
2
=
0 +1
2
Suy ra 2 axit HCOOH v CH
3
COOH c s mol bng nhau

Vy %m
HCOOH
=
46
46 +60
. 100%= 43,39%.
Cu 47: p n A
n
CO
2
< n
H
2
O
n
ancol
= n
H
2
O
n
CO
2
= 0,55 0,3 = 0,25(mol)
m
ancol
= m
H
2
O
+m
CO
2
m
O
2
= 8,7(g).
8,7(g) X c s mol l 0,25 mol
10,44(g)X c s mol l
10,44.0,25
8,4
= 0,3(mol).
Trong phn ng ete ha: n
H
2
O
=
1
2
n
ancol
= 0,15(mol).
o
xt,t
156 | L O V E B O O K . V N
m
ete
= m
ancol
m
H
2
O
= 10,44 0,15.08 = 7,74(g).
Cu 48: p n C
X, Y + KOH mui X,Y c cha nhm COO-.
X, Y phn ng vi dung dch AgNO
3
/NH
3
Ag X l HCOOH, Y l HCOOCH
3

V (M
X
< M
Y
< 74).
Suy ra: d
Y/X
=
60
46
= 1,304.
Cu 49: p n B
Xt X + O CaO + MgO.
Bo ton e ta c: n
O
= n
H
2
= 0,0725(mol).
Gi x, y l s mol CaO v MgO trong hn hp sau phn ng. 56x +40y = m
X
+m
O
= 6,52.
S mol MgCl
2
: y = 0,065 (mol) x = 0,070 (mol).
Vy m
CaCl
2
= 0,070.111 = 7,770(g).
Cu 50: p n A
Phng trnh ha hc: C
n
H
2n2
O
2
nCO
2
+(n 1)H
2
O
0,42 0,42n

Sn phm chy + dung dch Ca(OH)
2
kt ta. Suy ra:
n
OH
n
CO
2
> 1 n < 4,4.
X + dung dch NaOH 2 cht hu c khng c phn ng trng gng
X l CH
2
= CHCOOCH
3
.
B. Sai v %m
0
=
32
86
. 100% = 37,2%
C. Sai v CH
2
= CHCOOH + CH
3
OH CH
2
= CHCOOCH
3
+ H
2
O.
D, Sai v X l metylacrylat.
o
2 4
H SO ,d,t
157 | G S T T G R O U P
s 22

Cu 1: Hn hp c 0,36 (gam) Mg v 2,8 (gam) Fe cho vo 250 ml dung dch CuCl
2
, khuy u phn ng xy ra
hon ton thu c dung dch B
1
v 3,84(g) cht rn B
2
, Cho B
1
tc dng vi dung dch NaOH d, lc kt ta nung
n khi lng khng i c 1,4 (gam) 2 oxit. Tnh C
M

ca CuCl
2

A. 0,15M B. 0,05M C. 0,1M D. 0,5M
Cu 2: Phng php no sau y iu ch c Al t Al
2
O
3
A. in phn dung dch B. in phn nng chy
C. Nhit luyn D. Thu luyn
Cu 3: Cho s sau: alanin
+HCl
X
1
+CH
3
OH/HCl khan
X
2
+NaOH d
X
3
. Hy cho bit trong s trn c bao nhiu
cht c kh nng lm i mu qu tm?
A. 0 B. 3 C. 2 D. 1
Cu 4: t chy hon ton 0,1 mol hirocacbon A cho 0,5 mol CO
2
. Mt khc 0,1 mol A phn mg va vi 0,2
mol Br
2
trong dung dch. Cng thc phn t ca A?
A. C
5
H
8
B. C
5
H
10
C. C
3
H
4
D. C
4
H
6

Cu 5: t chy hon ton mt lng hirocacbon trong bnh kn bng mt lng va oxi 120
0
C. Sau phn
ng nhit p sut bnh khng thay i. Hirocacbon trn c c im.
A. Ch c s H = 4 B. Ch c th l anken C. Ch c th l ankan D. Ch c s C = 3.
Cu 6: Cho cc phn ng oxi ho - kh sau?
2H
2
O
2
2H
2
O +O
2
(1) HgO Hg + O2 (2)
Cl2 + KOH KCl + KClO + H2O (3) KClO3 KCl + O2 (4)
NO2 + H2O HNO3 + NO (5) FeS + H2SO4 Fe2(SO4)3 + SO2 + H2O (6)
Trong cc phn ng trn c bao nhiu phn ng t oxi ho - kh?
A. 3 B. 1 C. 2 D. 4
Cu 7: Ch c dung dch nc Brm v cc dng c th nghim c th phn bit c my cht trong s cc dung
dch sau: Benzen, C
2
H
6
; C
2
H
4
; C
2
H
2
, phenol, ng trong cc ng nghim ring bit.
A. 4 B. 2 C. 3 D. 5
Cu 8: Cho s sau: C4H10 X1 X2 X3 X4 CH3COOH
Bit rng X1, X2, X3, X4 c cng s nguyn t cacbon v t chy thu c CO2 v H2O. Vy X1 ; X2 ; X3 ; X4 l :
A. CH3-CH3 ; CH2=CH2 ; CH3-CH2OH ; CH3CH=O B. CH3-CH3 ; CH2=CH2 ; CH2=CH-OH ; CH3-CH2OH
C. CH3-CH3 ; CH2=CH2 ; CH3-CH2Cl ; CH3CH2OH D. CH2=CH2 ; CH3-CH3 ; CH3-CH=O ; CH3CH2OH
Cu 9: Trong ba kim loi kim th Mg, Ca, Ba ch c Mg khng phn ng vi H2O iu kin thng l do nguyn
nhn no?
A. Mg km hot ng hn Ca v Ba B. MgO khng tan trong H2O
C. Tnh baz ca Mg(OH)2 km hn Ca(OH)2 v Ba(OH)2 D. Mg(OH)2 khng tan trong H2O cn Ca(OH)2 tan
c
Cu 10: Cho a mol CO
2
hp th ht vo dung dch cha b mol NaOH thu c dung dch A. Cho BaCl
2
d vo dung
dch A thu c m (g) kt ta. Nu cho Ba(OH)
2
d vo dung dch A thu c m
1
(g) kt ta (m m
1
). T s T =
b/a c gi tr ng l?
A. T 2 B. 0<T<1 C. T>0 D. 1<T<2
Cu 11: Nung mt lng mui Cu(NO
3
)
2
sau mt thi gian dng li ,thy khi lng gim i 5,4gam. Kh thot ra
hp th hon ton vo 100ml H2O thu c dung dch X (th tch coi nh khng i). Nng mol/l ca dd X l:
A. 0,5mol/l B. 1mol/l C. 2 mol/l D. 0,1mol/l
Cu 12: Mt ru no, n chc c % H = 13,04% v khi lng. Cng thc phn t ca ru l?
A. CH3OH B. C4H9OH C. C2H5OH D. C3H7OH
Cu 13: C bao nhiu ru bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c
phn trm khi lng cacbon bng 68,18%?
A. 2 B. 3 C. 4 D. 5
158 | L O V E B O O K . V N
Cu 14: Hp cht hoc cp hp cht no sau y khng th tham gia phn ng trng ngng?
A. axit amino caproic B. hexa metyleniamin v axit aipic.
C. phenol v anehit fomic D. butaien-1,3 v stiren.
Cu 15: Khi hnh thnh lin kt trong phn t Cl
2
theo phng trnh Cl + Cl Cl
2
th h
A. Thu nng lng B. Qua 2 giai on: To nng lng ri thu nng lng
C. To nng lng D. Khng thay i nng lng
Cu 16: Polime X c phn t khi 420 000 vC v h s trng hp n = 10 000. X l
A. PVC B. (- CF2 CF2 - )
n
C. P.P D. PE
Cu 17: iu no l sai trong cc iu sau?
A. ru a chc c nhm OH cnh nhau ho tan Cu(OH)2 to dung dch xanh lam
B. CH3COOH ho tan Cu(OH)2 to thnh dung dch xanh nht
C. Anehit tc dng vi Cu(OH)2 to kt ta gch
D. Phenol ho tan Cu(OH)2 to dung dch xanh nht
Cu 18: in phn 100 ml dung dch A cha ng thi HCl 0,1M v NaCl 0,2M, vi mng ngn xp, in cc tr
ti khi anot thot ra 0,224 lt kh (ktc) th ngng in phn. Dung dch sau in phn c pH l bao nhiu? (coi
th tch dung dch khng thay i)
A. 7 B. 12 C. 13 D. 6
Cu 19: Cho cc cht: etyl axetat, anilin, ru etylic, axit acrylic, phenol, phenylamoni clorua, ru benzylic, p-
crezol v ietyl sunfat. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l:
A. 6 B. 5 C. 4 D. 7
Cu 20: Cn phi trn hai dung dch H
2
SO
4
0,02M v dung dch KOH 0,035M theo t l th tch nh th no thu
c dung dch c pH = 2
A. 1:2 B. 2:1 C. 2:3 D. 3:2
Cu 21: Cho m (gam) NaOH rn ho tan trong H
2
O thu c 100ml dung dch NaOH c pH = 13. m =?
A. 0,6(g) B. 0,4(g) C. 0,2(g) D. 0,8(g)
Cu 22: Khi in phn cc dung dch sau, dung dch no cho pH tng?
A. Dung dch AgNO
3
B. Dung dch BaCl
2
C. Dung dch Na
2
SO
4
D. Dung dch CuCl
2

A. Kim loi cng mnh th m in cng ln.
B. Kim loi ch th hin tnh kh trong cc phn ng ho hc
C. Nguyn t kim loi c t electron lp ngoi cng.
D. Cc phn nhm ph ca bng HTTH ch gm cc kim loi
Cu 24: Ln men glucoz thu c ru etylic v kh CO2. Hp th ht kh CO2 trong 500 ml dung dch NaOH 1M
thu c dung dch c cha 16,8 gam NaHCO3. Xc nh th tch ru nguyn cht thu c (d = 0,8 gam/ml)
A. 20,125 ml B. 16,1 ml C. 25,76 ml D. 8,05 ml
Cu 25: t chy hon ton mt hn hp gm ankan v anken thu c 4,14(g) H
2
O v 6,16(g) CO
2
. Tnh khi
lng ankan trong hn hp u?
A. 2,7(g) B. 1,44(g) C. 3,69(g) D. Khng xc nh c
Cu 26: tn gi no sau y l tn gi khc ca thu tinh hu c.
A. polimetylacrilat B. polimetacrilic C. axit picric D. polimetylmetacrilat
Cu 27: Lin kt cng ho tr l lin kt c hnh thnh gia hai nguyn t bng
A. Mt hay nhiu cp electron chung B. Nhiu cp electron chung
C. S cho - nhn prton D. Mt cp electron dng chung
Cu 28: Cho 14 (gam) hn hp 2 anken k tip, i qua dung dch Br
2
thy phn ng va vi 320 (gam) dung
dch Br
2
20%. Cng thc phn t ca anken?
A. C
5
H
10
, C
6
H
12
B. C
3
H
6
, C
4
H
8
C. C
4
H
8
, C
5
H
10
D. C
2
H
4
, C
3
H
6

Cu 29: iu no l ng trong cc iu sau:
159 | G S T T G R O U P
A. Baz kim tc dng vi mui tan khng bao gi to kh bay ra.
B. Ch c cc oxit th kh nh CO
2
, SO
2
, NO
2
mi tc dng vi cc baz kim.
C. Baz tc dng vi axit lun l phn ng trung ho.
D. cc hiroxit khng tan b nhit phn
Cu 30: Dy cc cht c xp theo chiu tng dn s phn cc lin kt?
A. NaCl; Cl
2
; HCl B. HCl; N
2
; NaCl C. Cl
2
; HCl; NaCl D. Cl
2
; NaCl; HCl
Cu 31: Khi un nng n ru n chc c H
2
SO
4
c 140
0
C th thu c s ete ti a l?
A. 2n B. n
2
C. n(n+1)/2 D. 3n
Cu 32: nh ngha no sau y l ng khi ni v Hircacbon no?
A. L hp cht hu c ch cha lin kt n trong phn t
B. l hircacbon ch cha lin kt n trong phn t
C. L hircacbon c cha t nht mt lin kt n trong phn t
D. L hircacbon c cha cc lin kt n trong phn t
Cu 33: Cho cc cht sau: phenol, etanol, axit axetic, etyl amin, phenyl amoni clorua, natri phenolat, natrihiroxit.
S cp cht tc dng c vi nhau l
A. 9 B. 8 C. 7 D. 6
Cu 34: t chy hon ton hn hp 3 ankin thu c 3,36(l) CO2 (ktc) v 1,8(g) nc. Xc nh khi lng ca
0,1(mol) hn hp ban u?
A. 4(g) B. 3,2(g) C. 5,2(g) D. 2,6(g)
Cu 35: Cho 1 ming Fe vo cc ng dung dch H2SO4 long. Bt kh H2 s bay ra nhanh hn khi ta thm vo cc
trn dung dch no trong cc dung dch sau?
A. Na2SO4 B. MgSO4 C. Al2(SO4)3 D. HgSO4
Cu 36: Khi in phn cc dung dch cha hn hp a mol NaCl v b mol CuSO
4
(m.n.x) kt thc qu trnh in
phn ta thy dung dch c pH tng so vi ban u. Mi quan h gia a v b ?
A. 2b > a > b B. a = 2b C. a > 2b D. a b
Cu 37: Crackinh 560 lt C
4
H
10
thu c hn hp kh X c th tch 1010 lt (cc kh o cng iu kin). Xc nh
th tch C
4
H
10
cha b crckinh?
A. kt qu khc B. 90 lt C. 110 lt D. 80 lt
Cu 38: Cho cc phn ng sau?
1. HCl + MnO2 MnCl2 + Cl2 + H2O 2. HCl + Cu + O2 CuCl2 + H2O
3. HCl + Fe FeCl2 + H2

4. HCl + KMnO4 KCl + MnCl2 + Cl2 + H2O
C bao nhiu phn ng trong HCl ng vai tr l cht b kh?
A. 3 B. 2 C. 1 D. 4
Cu 39: Dy cc cht c xp theo chiu tng tnh axit?
A. HF, HCl, HBr, HI B. HF, HBr, HCl, HI C. HI, HCl, HBr, HF D. HI, HBr, HCl, HF
Cu 40: X l 1 mui ca Fe. X ho tan trong HCl c kh A bay ln .t chy X trong O2 c kh B bay ln. Bit A
v B u lm mt mu dung dch nc Brom. X l:
A. FeS B. FeCO3 C. FeSO4 D. Fe3C
Cu 41: un nng mt ru A vi H2SO4 c nhit thch hp thu c 1 olefin duy nht. Cng thc tng qut
ca X l?
A. CnH2n+1OH B. ROH C. CnH2n+1CH2OH D. CnH2n+2O
Cu 42: Cho s phn ng: A B TNT, Cu tr li no sau y l ng v A, B?
A. A l hexan, B l toluen B. A l toluen, B l heptan
C. Tt c iu sai D. A l benzen, B l toluen
Cu 43: Cho hn hp gm 0,14 mol Mg v 0,01 mol MgO tan hon ton trong dung dch HNO3 ch thu c 0,02
mol N2 v dung dch. Xc nh khi lng mui khan thu c nu c cn dung dch?
A. Khng xc nh c. B. 23(g) C. 22,2(g) D. 23,2(g)
160 | L O V E B O O K . V N
Cu 44: Cho 1 gam bt Fe tip xc vi oxi mt thi gian thy khi lng bt vt qu 1,41gam. Nu ch to
thnh mt oxit st duy nht th l oxit no?
A. FeO B. Fe3O4 C. Fe2O3 D. Khng xc nh c
Cu 45: Thy phn hon ton mt tripeptit thu c hn hp gm alanin v glyxin theo t l mol l 2: 1. Hy cho
bit c bao nhiu tri peptit tha mn?
A. 1 B. 3 C. 2 D. 4
Cu 46: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn
hp Z gm hai ru X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2
lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn
ca X v Y l (th tch dung dch thay i khng ng k).
A. C3H7OH v C4H9OH B. C4H9OH v C5H11OH C. CH3OH v C2H5OH D. C2H5OH v C3H7OH
Cu 47: Lp N c bao nhiu phn lp?
A. 3 B. n C. 2n D. 4
Cu 48: Cho cc cht (X): n Butan; (Y): n Hexan; (Z): isohexan, (T) : neohexan. Cc cht c xp theo chiu
gim dn nhit si?
A. Y, Z, X, T B. Y, Z, T, X C. T, Z, Y, X D. Y, X, Z, T
Cu 49: Ho tan mt ming Al vo dung dch cha 0,05 mol NaOH ,thy c 0,672 (ktc) H2 bay ln v cn li dung
dch A .Cho vo dung dch A dung dch cha 0,065mol HCl th lng kt ta sinh ra l:
A. 1,56g B. 2,34g C. 1,17g D. 0,78g
Cu 50: Lin kt trong phn t no c hnh thnh nh s xen ph p - p
A. Cl
2
B. H
2
C. NH
3
D. HCl

P N

1C 2B 3B 4A 5A 6A 7C 8A 9D 10D
11B 12C 13B 14D 15C 16C 17D 18C 19A 20D
21B 22B 23A 24A 25B 26D 27A 28D 29D 30C
31C 32B 33B 34A 35D 36C 37C 38C 39A 40A
41C 42D 43B 44C 45B 46D 47D 48B 49C 50A

161 | G S T T G R O U P
s 23

A. Trong mi trng kim, ipeptit mch h tc dng c vi Cu(OH)2 cho dung dich ma u ti m xanh
B. Trong mt phn t tripeptit mch h c 3 lin kt peptit.
C. Cc hp cht peptit bn trong mi trng baz va mo i trng axit.
D. axit glutamic HOOC-CH2-CH2-CH(NH2)-COOH co tinh l ng tinh
Cu 2: Trong t nhin, canxi sunfat tn ti di dng mui ngm nc (CaSO4.2H2O) c gi l
A. thch cao sng. B. vi. C. thch cao nung. D. thch cao khan.
Cu 3: Este E c iu ch t axit n chc, mch h X v ancol n chc, mch h Y. t chy hon ton 4,8
gam E, thu c 5,376 lt CO2 v 3,456 gam H2O. Mt khc, khi cho 15 gam E tc dng vi 195 ml dung dch NaOH
1M, c cn dung dch sau phn ng thu c 14,1 gam cht rn khan. Cng thc cu to ca Y l
A. CH2=CHCH2OH B. CH3CH2CH2OH C. CH3CH2OH D. CHC-CH2OH
Cu 4: Ho n h p X go m ca c chat h u c ma ch h , n ch c co cu ng co ng th c pha n t la C3H4O2. un no ng nhe
14,4 gam X v i dung di ch KOH d en hoa n toa n thu c dung di ch Y (gia s kho ng co sa n pham na o thoa t ra
kho i dung di ch sau pha n ng). Trung ho a baz co n d trong dung dich Y ba ng HNO3, thu c dung dich Z. Cho
Z ta c du ng v i dung di ch AgNO3 d trong NH3 thu c 43,2 gam ket tu a. Ho i cho 14,4 gam X ta c du ng Na d thu
c to i a bao nhie u lit H2 ktc?
Cu 5: Cho 8,96 lit CO2 (ktc) su c va o dung dich ch a 100 ml dung dich ch a hn hp Ca(OH)2 2M va NaOH 1,5M
thu c a gam ket tu a va dung dich X. un no ng ki dung dich X thu c the m b gam ket tu a. Gia tri b la :
Cu 6: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn
t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,15 mol Y, thu c tng khi lng CO2 v
H2O bng 82,35 gam. t chy hon ton 0,1 mol X, sn phm thu c cho li t t qua nc vi trong d, to
ra m gam kt ta. Gi tr ca m l
A. 40 B. 80 C. 60 D. 30
Cu 7: Tng s cc ht electron trong anion XY
3
2
l 42. Trong X chim 40% v khi lng. Trong cc ht nhn
ca X v Y u c s ht proton bng s ht ntron. V tr ca X, Y trong bng tun hon l?
A. X th 16, chu k 3, nhm VIA; Y th 9; chu k 2, nhm VIIA
B. X th 16, chu k 3, nhm VIA; Y th 8; chu k 2, nhm VIA
C. X th 14, chu k 3, nhm IVA; Y th 8; chu k 2, nhm VIB
D. X th 14, chu k 4, nhm VIIIB; Y th 9; chu k 2, nhm VIIA
Cu 8: Hn hp X gm propin, propan v propilen c t khi so vi hiro l 21,2. t chy hon ton 15,9 gam X,
sau hp th ton b sn phm vo bnh ng 1 lt dung dch Ba(OH)2 0,8M; thy khi lng bnh tng m gam
v c a gam kt ta. Gi tr ca m v a ln lt l
A. 42,4 gam v 157,6 gam B. 71,1 gam v 93,575 gam C. 42,4 gam v 63,04 gam D. 71,1 gam v 73,875 gam
Cu 9: t chy hon ton 2,01 gam hn hp gm axit acrylic, vinyl axetat, metyl metacrylat. Ton b sn phm
chy cho qua dung dch Ca(OH)2 d, sau phn ng thu c 9 gam kt ta v dung dch X. Vy khi lng dung
dch X thay i so vi dung dch Ca(OH)2 ban u l:
A. gim 3,87 gam B. tng 5,13 gam C. tng 3,96 gam D. gim 9 gam
Cu 10: C hai hp cht hu c mch h X, Y l ng phn ca nhau, trong X l hp cht n chc, Y l hp
cht a chc. Cng thc n gin ca chng l C2H4O. Bit X, Y tc dng vi Cu(OH)2 nhit thng. Vy X, Y
l:
A. X l axit n chc v Y l ancol n chc B. X l axit n chc, Y l ancol 3 chc.
C. X l axit n chc; Y l anehit 2 chc. D. X l axit n chc, Y l ancol 2 chc.
162 | L O V E B O O K . V N
Cu 11: Cho cc nguyn t sau: X (Z = 9); Y (Z = 12); M (Z = 15); T (Z = 19). Hy cho bit s sp xp no
ng vi chiu tng dn bn knh nguyn t ca cc nguyn t ?
A. Y < T < X < M B. M < Y < X < T C. X < M < Y < T D. X < Y < M < T
Cu 12: Cho cc dung dch: CH3COONa, (H2N)2CH-CH2-COOH, CH3NH2, C6H5OH, C6H5ONa, CH3COOH, C6H5NH2.
Trong s cc dung dch trn, c bao nhiu dung dch lm i mu qu tm?
A. 4 B. 3 C. 5 D. 6
Cu 13: Khi cho mt lng va dung dch long ca KMnO4 v H2SO4 vo mt lng H2O2, thu c 2,24 lt O2
(ktc). Khi lng ca H2O2 c trong dung dch ly v khi lng ca KMnO4 phn ng ln lt l
A. 6,32 g v 2,04 g . B. 2,04 g v 3,16 g . C. 3,4g v 3,16 g. D. 3,4g v 6,32g.
Cu 14: Cho 3,78 gam hn hp X gm CH2=CHCOOH, CH3COOH v CH2=CHCH2OH phn ng va vi dung dch
cha 8 gam brom. Mt khc, trung ho 0,03 mol X cn dng va 20 ml dung dch NaOH 0,75M. Khi lng
ca CH2=CHCOOH c trong 3,78 gam hn hp X l
Cu 15: Cho 1 lit n c c ng ta m th i ch a (Ca
2+
, Mg
2+
va HCO
3
). Bit ti le mol cu a 2 ion Ca

2+
va Mg
2+
tng ng
la 2:1. To ng kho i l ng cu a hai muoi hidrocacbonat trong 1 lit n c tre n la 14,1 gam. Tinh khoi l ng Ca(OH)2
ca n the m va o 1 lit n c c ng tre n, e n c thu c mat hoa n toa n tinh c ng?
Cu 16: Cho phn ng sau: aCuFeS2 + bH2SO4 cFe2(SO4)3 + d SO2 + eCuSO4 + fH2O
Trong a, b, c, d, e l cc s nguyn dng, ti gin. Gi tr ca b, d trong phn ng trn sau khi cn bng
tng ng l:
A. 18 v 17 B. 18 v 13 C. 22 v 13 D. 22 v 17
Cu 17: Cho ca c chat:
(1) dung dich KOH (un no ng); (2) H2/ xu c ta c Ni, t
o
;
(3) dung dch H2SO4 loa ng (un no ng); (4) dung dich Br2;
(5) Cu(OH)2 nhie t o pho ng (6) Na
Ho i Triolein nguye n chat co pha n ng v i bao nhie u chat trong so ca c chat tre n ?
A. 4 B. 5 C. 3 D. 2
Cu 18: Cho ca c pha t bieu sau:
(1) C th dng nc brom phn bit glucoz v fructoz.
(2) Dung dch glucoz v dung dch saccaroz u co pha n ng tra ng ba c.
(3) Dung dich saccaroz hoa tan Cu(OH)2 nhie t o th ng cho dung di ch ma u xanh lam.
(4) Thu phn hon ton tinh bt thu c fructoz.
So pha t bieu u ng la :
A. 3 B. 2 C. 4 D. 1
Cu 19: Nung hn hp X gm FeO, CuO, MgO v Al nhit cao, sau khi ca c phn ng xa y ra hoa n toa n cho phn
rn vo dd NaOH d thy c kh H2 bay ra va cht rn khng tan Y. Cho Y vo dd H2SO4 long, d. Cho bit c bao
nhiu phn ng xy ra?
A. 5 B. 6 C. 7 D. 8
Cu 20: C bao nhiu ng phn l hp cht thm c cng cng thc phn t: C8H10O tc dng c vi Na v tc
dng c vi NaOH?
A. 6 B. 8 C. 9 D. 7
Cu 21: Cho cc dung dch sau: H2SO4 (1); KHSO4 (2); KCl (3); CH3COOH (4); CH3NH2 (5) c cng nng 0,1M.
Dy cc dung dch xp theo chiu tng dn gi tr pH l:
A. (1), (2), (3), (4), (5). B. (1), (4), (3), (2), (5) C. (5), (3), (4), (2), (1) D. (1), (2), (4), (3), (5).
Cu 22: Cho dung dch X cha 0,2 mol Al
3+
, 0,4 mol Mg
2+
, 0,4 mol NO
3
, x mol Cl
, y mol Cu
2+

- Nu cho dung dch X tc dng vi dung dch AgNO3 d th thu c 172,2 gam kt ta.
- Nu cho 1,7 lit dung dch NaOH 1 M vo dung dch X th khi lng kt ta thu c l
163 | G S T T G R O U P
Cu 23: Cho ho n h p Na, Al va o n c d thu c 4,48 lit H2 (ktc) va dung dich X chi ch a 1 chat tan. Su c CO2
d va o dung dich X thi thu c bao nhie u gam ket tu a?
Cu 24: Cho cc cht rn sau: CuO, Fe3O4, BaCO3 v Al2O3. Ch dng mt thuc th no sau y c th nhn bit
c tt c cc ha cht ?
A. dd FeCl2 B. dd NaOH C. dd NH3 D. dd HCl.
Cu 25: Hidrat ho a 7,8 gam axetilen co xu c ta c HgSO4 80
0
C, hie u suat pha n ng na y la H %. Cho toa n bo ho n h p
thu c sau pha n ng va o dung dich AgNO3 d trong NH3 thi thu c 66,96 gam ket tu a. Gia tri H la :
A. 10,3% B. 70% C. 93% D. 7%
Cu 26: Pht biu lin quan trng thi cn bng ha hc (CBHH) no di y l khng ng?
A. Gi tr hng s cn bng ho hc ca mt phn ng khng thay i mi nhit .
B. trng thi CBHH, cc phn ng thun v nghch vn xy ra vi tc bng nhau.
C. S thay i yu t nhit , nng hoc p sut c th ph v trng thi CBHH v to ra s chuyn di
cn bng.
D. trng thi CBHH, nng cc cht tham gia phn ng v cc cht sn phm u khng i.
Cu 27: Hn hp kh X gm 0,45 mol H2 v 0,15 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu c
hn hp kh Y c t khi so vi H2 l 14,5. Nu cho ton b Y sc t t vo dung dch brom (d) th c m gam brom
tham gia phn ng. Gi tr ca m l
A. 32. B. 48. C. 24. D. 16.
Cu 28: Hn hp X gm CH3CH2COOH, HCOOH, C6H5COOH v HOOC-CH2-COOH. Khi cho m gam X tc dng vi
NaHCO3 (d) th thu c 20,16 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn 26,88 lt kh O2
(ktc), thu c 52,8 gam CO2 v y mol H2O. Gi tr ca y l
A. 1,9 B. 2,1 C. 1,8. D. 1,6
Cu 29: Cho 3,78g Fe tc dng vi oxi thu c 4,26g hn hp A gm 4 cht rn. Ho tan ht A trong 500ml dd
HNO3 x M thu c 0,84 lit NO (kc) v dd khng c NH4NO3. Tnh gi tr x?
A. 0,12M B. 0,42M C. 0,21M D. 0,3M
Cu 30: Cho cc phn ng ha hc sau:
(I). C6H5CH(CH3)2
(1)+O
2
;(2)+H
2
O;H
2
SO
4

(II). CH3CH2OH + CuO
t
0

(III). CH2=CH2 + O2
xt,t
0

(IV). CH3-C C-CH3 + H2O
HgSO
4
,t
0

(V). CH3-CH(OH)-CH3 + O2
xt,t
0

(VI). CH CH + H2O
HgSO
4
,t
0

(VII). CH3CHCl2 + NaOH
t
0

(VIII). CH3COOCH=CH2 + KOH
t
0

C bao nhiu phn ng trn c th to ra anehit?
A. 7 B. 4 C. 5 D. 3
Cu 31: Dy cc cht no sau y ch c lin kt cng ha tr trong phn t?
A. CaCl2, H2O, N2 B. K2O, SO2, H2S C. NH4Cl, CO2, H2S D. H2SO4, NH3, H2
Cu 32: Cho cc ha cht sau: (1) dung dch Fe2(SO4)3 ; (2) dung dch HCl v KNO3 ; (3) dung dch KNO3 v KOH;
(5) dung dch HCl; (6) dung dch H2SO4 c, nng; (7) Propan-1,2- iol; (8) dung dch HNO3 loa ng. Ho i co bao nhie u
dung dich ho a tan c Cu?
A. 5 B. 4 C. 2 D. 3
Cu 33: Mt hn hp A (gm 0,1 mol Cu; 0,1 mol Ag; v 0,1 mol Fe2O3) em ha tan vo dung dch HCl d, sau
phn ng thu c dung dch X v cht rn Y. Khi lng mui khan thu c khi c cn trong dung dch X v
khi lng cht rn Y ln lt l:
A. 32,5 gam v 17,2 gam B. 38, 9 gam v 10,8 gam
C. 38,9 gam v 14,35 gam D. 32,5 gam v 10,8 gam
Cu 34: Cho cc t sau: t axetat; t capron; t nitron; t visco; t nilon-6,6; t enang. Cc t thuc loi t to ng
h p la
164 | L O V E B O O K . V N
A. t capron; t nitron; t nilon-6,6; t enang. B. t capron; t visco; t nilon-6,6; t enang.
C. t axetat; t capron; t nitron; t visco. D. t axetat; t capron; t nitron; t nilon-6,6.
Cu 35: Cho s phn ng sau: X + H2SO4 (c, nng) Fe2(SO4)3 + SO2 + H2O. Trong s cc cht: Fe, FeCO3,
FeO, Fe2O3, Fe3O4, Fe(OH)3, Fe(OH)2, FeS, FeS2, Fe2(SO4)3 th s cht X tha mn s phn ng trn l:
A. 7 B. 8 C. 5 D. 6
Cu 36: Hn hp X gm mt anehit v mt ankin c cng s nguyn t cacbon. t chy hon ton a (mol) hn
hp X thu c 3a (mol) CO2 v 1,8a (mol) H2O. Cho 0,1 mol hn hp X tc dng c vi ti a 0,14 mol AgNO3
trong NH3 (iu kin thch hp). S mol ca anehit trong 0,1 mol hn hp X l
A. 0,02. B. 0,08. C. 0,04. D. 0,03.
(a) Nung AgNO3 rn. (b) un nng NaCl tinh th vi H2SO4 (c).
(c) Sc kh SO2 vo dung dch NaHCO3. (d) Cho dung dch KHSO4 vo dd NaHCO3.
(e) Cho CuS vo dung dch HCl (long).
A. 4. B. 2. C. 5. D. 3.
Cu 38: Cho tng cht: C6H5NH2 (anilin), CH3-COOH va CH3-COOCH3 ln lt tc dng vi dung dch NaOH (t
0
) v
vi dung dch HCl (t
0
). S phn ng xy ra l
A. 6. B. 3. C. 5. D. 4.
Cu 39: Cho 6,9 gam mt ancol, n chc phn ng vi CuO nung nng, thu c cht rn A v 9,3 gam hn hp
X gm anehit, nc v ancol d. Cho ton b lng hn hp X phn ng hon ton vi lng d dung dch AgNO3
trong NH3, un nng, thu c m gam Ag. Gi tr ca m l
A. 32,4 B. 64,8 C. 16,2 D. 24,3
Cu 40: Sau mt thi gian t in phn 200 ml dung dch CuSO4 (D = 1,25 g/ml) vi in cc tr, cng dng
in 5A, nhn thy khi lng dung dch gim 8 gam. lm kt ta ht ion Cu
2+
cn li trong dung dch sau in
phn cn dng 100 ml dung dch H2S 0,5M. Nng phn trm ca dung dch CuSO4 ban u v gi tr ca t ln
lt l
A. 12% v 4012 giy B. 9,6% v 3860 giy C. 12% v 3860 giy D. 9,6% v 4396 giy
II. PHN RING [10 cu]
Th sinh ch c lm mt trong hai phn (phn A hoc B)
Cu 41: Cho ho n h p go m 2,7 gam Al va 8,4 gam Fe va o 200 ml dung di ch ch a Cu(NO3)2 1M va AgNO3 2M, sau
khi ca c pha n ng xa y ra hoa n toa n thu c m gam ket tu a. Gia tri m la :
Cu 42: Cho bit c ti a bao nhiu cng thc cu to ancol no, mch h, bn v c 3 nguyn t cacbon trong
phn t?
A. 6 B. 4 C. 5 D. 2
Cu 43: Trong cc cht: Fe3O4, HCl, FeSO4, Fe2(SO4)3, SO2. S cht c c tnh oxi ho v tnh kh l
A. 4. B. 5. C. 2. D. 3.
Cu 44: Cho dy cc kim loi kim: 1 1Na, 19K, 37Rb, 55Cs. Kim loi trong dy c nhit nng chy thp nht l
A. Cs. B. Rb. C. Na. D. K.
Cu 45: Cho Ankaien X thc hin phn ng cng vi Brom (t l mol 1:1) iu kin thch hp thu c sn
phm c tn gi l 1,4-ibrom-2-metylbut-2-en. Tn gi ca ankaien X l
A. 3-metylpenta-1,3-ien. B. 3-metylbuta-1,3-ien.
C. 2-metylpenta-1,3-ien. D. 2-metylbuta-1,3-ien.
Cu 46: Chia 7,8g hn hp gm C2H5OH v mt ancol cng dy ng ng thnh 2 phn bng nhau:
- Phn 1 cho tc dng vi Na d thu c 1,12 lt H2 (ktc).
- Phn 2 cho tc dng vi 30 g CH3COOH, xc tc H2SO4 (c). Bit hiu sut cc phn ng este u l 80%.
Tng khi lng este thu c l:
165 | G S T T G R O U P
Cu 47: Ln men 360 gam glucoz trong iu kin thch hp (gi s ch c phn ng to thnh ancol etylic). Cho
ton b lng kh CO2 sinh ra hp th ht vo dung dch NaOH, thu c 106 gam Na2CO3 v 168 gam NaHCO3.
Hiu sut ca phn ng ln men glucz l
A. 50% B. 62,5% C. 80% D. 75%
Cu 48: Cho 0,15 mol o- aminoaxit mch cacbon khng phn nhnh A phn ng va ht vi 150ml dung dch HCl
1M to 27,525gam mui. Mt khc, cho 44,1 gam A tc dng vi mt lng NaOH d to ra 57,3 gam mui khan.
Cng thc cu to ca A l
A. HOOC-CH2-CH(NH2)-COOH B. HOOC-CH2-CH2-CH(NH2)-COOH
C. HOOC-CH2-CH2-CH2-CH(NH2)-COOH D. H2N- CH2-CH2-CH(NH2)-COOH
Cu 49: Tin hnh 5 th nghim sau:
- TN1: Nhng thanh st vo dung dch FeCl3.
- TN2: Nhng thanh km vo dung dch CuSO4.
- TN3: Cho thanh st tip xc vi thanh ng ri nhng vo dung dch HCl.
- TN4: Nhng thanh nhm vo dung dch NaOH.
- TN5: mt vt lm bng thp trong khng kh m.
S trng hp xy ra n mn in ha l:
A. 3 B. 2 C. 5 D. 4
Cu 50: Trong cu hnh electron ca nguyn t nguyn t X, tng s electron cc phn lp p l 7. S proton
trong nguyn t Y t hn ca nguyn t X l 5. Vy tng s ht mang in c trong hp cht to bi nguyn t X
v Y l:
A. 50 B. 21 C. 100 D. 42
Cu 51: un nng Butan - 2 - ol vi H2SO4 c 170
0
C, thu c cht hu c X. Cho X tc dng vi dung dch HBr
c thu c cht hu c Y. un nng Y vi Mg trong ete khan thu c sn phm Z. (Trong X, Y, Z l cc sn
phm chnh). Cng thc ca Z l
A. CH3CH2CH2CH2OH B. CH3CH(MgBr)CH2CH3
C. CH3CH2CH2CH2MgBr D. CH3CH2CH(OH)CH3
Cu 52: Cho 39,5 gam ho n h p X go m phenyl axetat va phenylamoni clorua ta c du ng v a u v i 400 ml dung dich
NaOH 1M. Tinh khoi l ng muo i khan thu c khi co ca n dung dich sau pha n ng?
Cu 53: Cho: E
0
(Cu
2+
/Cu)=0,34V; E
0
(Zn
2+
/Zn)=-0,76V. Kt lun no sau y khng ng?
A. Cu
2+
b Zn oxiho to thnh Cu.
B. Cu
2+
c tnh oxi ha mnh hn Zn
2+
.
C. Phn ng xy ra trong pin l: Zn+Cu
2+
Zn
2+
+Cu.
D. Cu c tnh kh yu hn Zn.
Cu 54: Cho 43,9 gam hn hp A gm Ni, Sn, Mg, Zn tc dng vi oxi d thu c 56,7 gam hn hp cc oxit. Mt
khc cho 43,9 gam hh A tc dng dung dch H2SO4 long d c 13,44 lit kh H2 (ktc). Phn trm khi lng
ca Sn trong hn hp l:
A. 48,79% B. 27,11% C. 40,66% D. 54,21%
Cu 55: Mt hn hp X gm sacaroz v mantoz. Thu phn hon ton hn hp X thu c glucoz v fructoz
theo t l mol 4 : 1. Hi 17,1 gam hn hp X khi tc dng vi AgNO3 d trong NH3 th thu c ti a bao nhiu
gam kt ta bc?
Cu 56: Hai cht ng phn A, B (A c ly t ngun thin nhin) c cha 40,45%C, 7,86%H; 15,73% N v cn
li l O. T khi hi ca cht lng so vi khng kh l 3,069. Khi phn ng vi NaOH, A cho mui C3H6O2NNa, cn
B cho mui C2H4O2NNa. Nhn nh no di y l sai?
A. A c tnh lng tnh nhng B ch c tnh baz
166 | L O V E B O O K . V N
B. A l alanin, B l metyl amino axetat.
C. t
0
thng A l cht lng, B l cht rn.
D. A v B u tc dng vi HNO2 to kh N2.
Cu 57: Hin tng xy ra khi cho dung dch KOH long vo dung dch K2Cr2O7 l:
A. Khng c hin tng chuyn mu
B. Xut hin kt ta trng
C. Dung dch t mu vng chuyn sang mu da cam
D. Dung dch t mu da cam chuyn sang mu vng
Cu 58: X l hn hp gm cc kim loi: Al, Zn, Cu, Fe, Mg. Ha tan hon ton X trong dung dch HNO3 long d thu
c dung dch A. Sc kh NH3 n d vo dung dch A thu c kt ta B. Nung B ngoi khng kh n khi lng
khng i c cht rn C. Cho C vo ng s nung nng ri cho kh CO d i qua n phn ng hon ton c
cht rn D. Cht rn D gm:
A. Al2O3, MgO, Zn, Fe B. Al2O3, MgO, Zn, Fe,Cu
C. Al2O3, MgO, Fe D. MgO, Al, Zn, Fe, Cu
Cu 59: Khi in phn dung dch CuSO4 vi anot bng Cu. Hin tng v qu trnh xy ra bn anot l:
A. Khi lng anot gim, xy ra s kh Cu
B. Khi lng anot khng thay i, xy ra s kh nc
C. Khi lng anot gim, xy ra s oxi ha Cu
D. Khi lng anot khng thay i, xy ra s oxi ha nc
Cu 60: Cho s sau:
CH
3
COCH
3

+HCN
X
H
3
O
+
,t
0

Y
H
2
SO
4
,t
0

Z(C
4
H
6
O
2
)
CH
3
OH/H
2
SO
4
,t
0

T.
Cng thc cu to ca cht hu c T l
A. CH2 = CHCOOCH3. B. CH3CH2COOCH3.
C. CH3CH(OH)COOCH3. D. CH2 = C(CH3)COOCH3.

P N

1D 2A 3A 4B 5A 6C 7B 8B 9A 10D
11C 12C 13D 14B 15C 16A 17A 18B 19B 20C
21D 22C 23C 24D 25B 26A 27C 28C 29B 30C
31D 32B 33B 34A 35D 36A 37A 38D 39B 40B
41B 42C 43A 44A 45D 46D 47D 48B 49A 50C
51B 52A 53A 54D 55C 56C 57D 58C 59C 60D
167 | G S T T G R O U P
s 24

I. PHN CHUNG CHO TT C CC TH SINH (40 cu t cu 1 n cu 40)
Cu 1: Ion R
3+
c cu hnh electron ca phn lp ngoi cng l 3d
5
. Cu hnh electron ca nguyn t R l:
A.1s
2
2s
2
2p
6
3s
2
3p
2
3d
5
4s
2
4p
1
B. 1s
2
2s
2
2p
6
3s
2
3p
2
3d
9

C.1s
2
2s
2
2p
6
3s
2
3p
2
3d
5
4s
1
D. 1s
2
2s
2
2p
6
3s
2
3p
2
4s
1
3d
5
4s
2
4p
1

Cu 2: Dy gm cc cht c xp theo chiu gim dn lc baz theo chiu t tri sang phi l:
A.(C
6
H
5
)
2
NH, C
6
H
5
NH
2
, NH
3
, C
2
H
5
NH
2
, (C
2
H
5
)
2
NH, NaOH
B. C
6
H
5
NH
2
, (C
6
H
5
)
2
NH
2
, NaOH, (C
2
H
5
)
2
NH, C
2
H
5
NH
2
, NH
3
.
C. NaOH, (C
2
H
5
)
2
NH, C
2
H
5
NH
2
, NH
3
, C
6
H
5
NH
2
, (C
6
H
5
)
2
NH.
D. NaOH, (C
2
H
5
)
2
NH, C
2
H
5
NH
2
, C
6
H
5
NH
2
, (C
6
H
5
)
2
NH, NH
3
.
Cu 3: A l mt amino axit. Trn 25ml dung dch A 1 M vi 250 ml dung dch HCl 0,1M. Dung dch thu c tc
dng va vi 500ml dung dch NaOH 0,1M. Mc khc nu trung ha 100ml dung dch A 1M bng dung dch
KOH (va ) th thu c 17,5 gam mui. Cng thc ca amino axit A l
A. (H
2
N)
2
C
3
H
4
COOH B. H
2
NC
6
H
4
COOH C. H
2
NC
6
H
3
(COOH)
2
D. H
2
NC
3
H
6
COOH.
(1) FeO +2HNO
3
Fe(NO
3
)
2
+H
2
O
(2) 2Fe +3I
2
2FeI
3

(3) AgNO
3
+Fe(NO
3
)
2
Fe(NO
3
)
3
+Ag
(4) 2FeCl
3
+3Na
2
CO
3
Fe
2
(CO
3
)
3
+6NaCl
(5) Zn +2FeCl
3
ZnCl
2
+2FeCl
2

(6) 3Fe
d
+8HNO
3
l 3Fe(NO
3
)
3
+2NO +4H
2
O
(7) NaHCO
3
+Ca(OH)
2
(d) CaCO
3
+NaOH +H
2
O
Nhng phn ng ng l:
A.(2), (3), (4) , (6), (7) B. (1), (2) , (4), (5), (6) C. (2), (4), (5), (7). D. (3), (5), (6), (7)
Cu 5: ung nng h hp gm axit axetic v glixerol (c vi git H
2
SO
4
c lm xc tc) mt thi gian sn phm
cha chc este c th thu c l
A.4 B. 2 C. 3 D. 5
Cu 6: Dy gm cc polime l sn phm ca phn ng trng ngng:
A.T lapsan, nha novolac, t nilon- 6,6
B.T lapsan, poli(metyl metacrylat), t xenluloz axetat.
C.Polistiren, t lapsan, nha novolac, t nilon- 6,6
D.T lapsan, t nitron, cao su buna, nha novolac
Cu 7: Ba cht hu c X,Y,Z c cng thc phn t ln lt l C
2
H
6
O
2
, C
2
H
2
O
2
, v C
2
H
2
O
4
. Trong phn t mi cht
trn ch cha mt loi nhm chc. Cc cht phn ng c vi Cu(OH)
2
(trong iu kin thch hp) l:
A. Y v Z B. Y v Z, X C. X v Z D. Y v X
Cu 8: Thc hin cc th nghim sau trong cc ng nghim c nh s
(1) Sc kh ccbonic vo dung dch natri aluminat cho ti d
(2) Nh tng dung dch axit clohidric vo dung dch natri aluminat cho ti d
(3) Nh tng dung dch amoni nitrat vo dung dch natri aluminat cho ti d
(4) Nh tng dung dch natri hidroxit vo dung dch nhm clorua cho ti d
(5) Nh tng dung dch natri aluminat vo dung dch nhm clorua cho ti d
Sau khi phn ng xa ra hon ton, s ng nghim c kt ta l:
A.3 B.5 C.4 D.2
(1) Cho rt t t dung dch Na
2
CO
3
vo dung dch AlCl
3
.
(2) Cho rt t t dung dch cha 0,1mol HCl vo dung dch cha 0,1 mol NaCO
3
v NaHCO
3
.
(3)Cho dung dch NaHSO
4
vo dung dch Ca(HCO
3
)
2
.
168 | L O V E B O O K . V N
Th nghim c gii phng kh CO
2
l:
A. (1), (2) v (3) B. Ch c (2) C. (2) v (3) D. (1) v (3)
Cu 10: Thy phn cht A (C
3
H
5
O
2
Cl) trong mi trng kim thu c cc sn phm, trong c kh nng trng
bc. Cng thc cu to ng ca A l
A. HCOOCHCl CH
3
B. Cl C
2
H
4
COOH C. HCOOCH
2
CH
2
Cl D. CH
2
Cl COOCH
3

Cu 11: X, Y, Z, T c cng thc tng qut C
2
H
2
O
n
(n 0). Bit:
X, Y, Z phn ng c vi dung dch AgNO
3
/NH
3

Z, T phn ng vi NaOH
Z phn ng c vi H
2
O khi c HgSO
4
lm xc tc.
X, Y, Z, T ln lt l:
A. OHC COOH, HOOC COOH, CH CH, (CHO)
2

B. CH CH, (CHO)
2
, OHC COOH, HOOC COOH.
C. (CHO)
2
, OHC COOH, HOOC COOH, CH CH.
D. HOOC COOH, CH CH, (CHO)
2
, OHC COOH.
Cu 12: Hn hp A gm 0,1 mol propenal v 0,3 mol kh hiro. Cho hn hp A qua ng s nung nng cha Ni lm
xc tc, sau mt thi gian thu c hn hp B. T khi hi ca hn hp B so vi l 1,55. S mol H
2
trong hn hp
B bng
A. 0,05. B. 0,10. C. 0,15. D. 0,20.
Cu 13: C 6 dung dch trong 6 ng nghim ring bit khng dn nhn: Lng glixerol, glucozo, axit formic, natri
hiroxit, axit axetic. phn bit 6 cht trn ch cn dng thm:
A. dung dch CuSO
4
. B. dung dch AgNO
3
NH
3
C. phenolphtalein. D. qu tm.
Cu 14: C cc nhn nh sau:
(1) Cht bo l trieste ca glixerol vi cc axit monoccboxylic c mch ccbon di khng phn nhnh
(2) Lipit gm cht bo, sp, steroit, photpholipit,..
(3) Cht bo cha cc gc axit khng no thng l cc cht rn nhit thng
(4) Phn ng thy phn cht bo trong mi trng kim l phn ng thun nghch
(5) Cht bo l thnh phn chnh ca du m ng, thc vt.
(6) Khi un cht bo lng vi hiro c xc tc Ni trong ni hp th chng chuyn thnh cht bo rn
Cc nhn nh ng l
A. (1), (2), (4), (5). B. (3), (4), (5). C. (1), (2), (5), (6). D. (1), (2), (3)
Cu 15: Nung hn hp X gm m gam Al v 15,2 gam Cr
2
O
3
trong iu kin khng c khng kh, phn ng hon
ton thu c 23,3 gam cht rn Y. Dng dung dch HCl d (khng c mt oxi) ha tan hon ton cht rn Y to
ra V lt kh ktc. Gi tr ca V l:
A. 4,48 lt B. 3,36 lt C. 7,84 lt D. 10,08 lt
Cu 16: Cho dy cc cht: NH
4
Cl, (NH
4
)
2
SO
4
, NaCl, MgCl
2
, FeCl
2
, AlCl
3
, NaHCO
3
. S cht trong dy tc dng vi
lng d dung dch Ba(OH)
2
to thnh kt ta l:
A. 1. B. 4. C. 5. D. 3.
Cu 17: Ln men m gam tinh bt thnh ancol etylic (hiu sut 75%); lng CO
2
sinh ra c hp th hon ton
vo dd Ca(OH)
2
thu c 700 gam kt ta v dung dch X. un nng dung dch X thu thm 200 gam kt ta. Gi
tr ca m l:
Cu 18: Dy gm cc cht va tc dng c vi dung dch NaOH va tc dng c vi dung dch HCl l:
A. (NH
4
)
2
CO
3
, NH
4
NO
3
, Al
2
O
3
B. NaHCO
3
, (NH
4
)
2
CO
3
, NH
4
NO
3

C. NaHCO
3
, KHSO
4
, (NH
4
)
2
CO
3
D. NaHCO
3
, (NH
4
)
2
CO
3
, Zn(OH)
2

Cu 19: Trong s cc cht c cng thc phn t C
2
H
6
, C
3
H
8
, C
4
H
10
, C
5
H
12
, C
6
H
14
, C
7
H
16
, C
8
H
18
, s cht kh tc
dng vi Clo c chiu sng ch thu c duy nht 1 dn xut monoclo l:
A. 2. B. 3. C. 4. D. 5.
169 | G S T T G R O U P
Cu 20: Cho 9,3 gam mt ankylamin tc dng vi dung dch FeCl
3
d thu c 10,7 gam kt ta. Ankylamin
l:
A. C
4
H
9
NH
2
. B. CH
3
NH
2
. C. C
3
H
7
NH
2
. D. C
2
H
5
NH
2
.
Cu 21: Cho m gam Ba vo 600ml dung dch cha KOH 0,1M v NaOH 0,1M thu c dung dch X. Cho t t dung
dch X vo 200ml dung dch Al
2
(SO
4
)
3
0,1M c kt ta Y. thu c kt ta Y ln nht th gi tr m ti thiu
v khi lng kt ta Y ln lt l:
A. 8,22 gam v 13,98 gam. B. 0,00 gam v 3,12 gam.
C. 8,22 gam v 19,38 gam. D. 2,74 gam v 4,66 gam.
Cu 22: Pht biu ng l:
A. Hp cht NH
4
Cl ch cha ton lin kt cng ha tr.
B. Na
2
HPO
4
, Na
2
HPO
3
l cc mui axit.
C. Kim cng c cu trc mng tinh th nguyn t.
D. Tinh th NaCl l tinh th phn t.
Cu 23: Ha tan hon ton hn hp X gm CuO, a mol Cu v b mol Cu(NO
3
)
2
vo dung dch HCl thu c dung
dch ch cha 1 mui duy nht. Quan h gia a v b l:
A. 3a=2b. B. 2a=b. C. a=3b. D. 2a=3b.
Cu 24: Cho tng cht Mg, FeO, Fe(OH)
2
, Ca(OH)
2
, Fe
3
O
4
, Al
2
O
3
, FeCl
2
, FeSO
4
, Fe
2
(SO
4
)
3
, Mg(HCO
3
)
2
,
Cu
2
S, FeS
2
ln lt phn ng vi dung dch HNO
3
c nng. S phn ng thuc loi phn ng oxi ha kh l:
A. 10 B. 9 C. 8 D. 11
Cu 25: Trong s cc ng phn cha vng benzen ca C
7
H
8
O c: a ng phn tc dng c vi NaOH, b ng
phn tc dng c vi Na, c ng phn khng tc dng c vi c NaOH. Gi tr ca a, b v c ln lt l:
A. 4, 3, 2 B. 3, 4, 1 C. 4, 4, 1 D. 2, 3, 1
Cu 26: Trn 50 gam dung dch KOH 11,2% vi 150 gam dung dch Ba(OH)
2
22,8% c dung dch A. Dn 7,84
lt kh CO
2
(ktc) vo dung dch A, sau khi phn ng hon ton thu c dung dch B. Khi lng ca dung dch B
so vi khi lng ca dung dch A
A. gim 24 gam B. gim 29,55 gam C. gim 14,15 gam D. tng 15,4 gam.
Cu 27: Hn hp X gm ancol metylic v 1 ancol n chc mch khng phn nhnh R. Cho 8,5 gam X tc dng vi
Na d thu c 2,24 lt kh hiro (ktc). Oxi ha 8,5 gam X bng CuO nung nng thu c hn hp Y. Cho ton b
hn hp Y tc dng vi lng d AgNO
3
un nng thu c 64,8 gam cht kt ta. Cc phn ng u t hiu
sut 100%. Tn thay th ca R l
A. propan-1-ol B. propan-2-ol C. butan-1-ol D. butan-2-ol
Cu 28: Hn hp A gm etilen v mt hiroccbon X. t chy hon ton 3,36 lt hn hp A (ktc) thu c 8,4
lt CO
2
(ktc)v 8,1 gam H
2
O. X c cng thc phn t l:
A. C
3
H
6
B. C
2
H
6
C. C
4
H
8
D. C
3
H
8

Cu 29: Hn hp A gm Al v Zn. Ha tan hon ton 22,2 gam hn hp A vo dung dch HCl d thu c 10,08 lt
kh (ktc). Mt khc, nu em ha tan 22,2 gam hn hp A trn vo dung dch HNO
3
long d thy thot 2,24 lt
kh X(ktc) v tng khi lng mui trong dung dch thu c l 79 gam. Kh X l
A. N
2
O B. NO C. N
2
D. NO
2

Cu 30: Cho cc pht biu sau
(1) Nguyn t cc nguyn t halogen u c 7 electron lp ngoi cng.
(2) Cc nguyn t halogen ch c s oxi ha -1 trong mi hp cht.
(3) Cc nguyn t halogen c m in gim dn theo th t: F>Cl>Br>I
(4) Cc hiro halogenua u l nhng cht kh, dung dch ca chng trong nc u c tnh axit mnh
(5) Tnh kh ca cc hiro halogenua tng dn theo th t HF<HCl<HBr<HI
(6) Cc mui bc halogenua u khng tan trong nc
(7) Trong t nhin cc halogen tn ti ch yu dng n cht.
Cc pht biu sai l:
A. (1), (2), (4), (5). B. (2), (4), (6), (7). C. (2), (3), (5), (6). D. (1), (3), (4), (6).
170 | L O V E B O O K . V N
Cu 31: Thy phn cht X (C
7
H
10
O
4
) trong mi trng axit thu c hai cht hu c Y,Z v mt axit- cacboxylic
a chc. Bit: Y b oxi ha bi CuO khi nung nng; Z to kt ta gch khi phn ng vi Cu(OH)
2
(NaOH, t
0
).
Cng thc cu to ca X l:
A. CH
3
COOCH
2
CH = CHOOCCH
3
. B. C
2
H
5
OOCCH
2
COOCH = CH
2
.
C. CH
3
OOCCH = CHCOOC
2
H
5
. D. CH
3
OOCCH
2
COOCH
2
CH = CH
2
.
Cu 32: Cho hn hp cha x mol Zn mol CuSO
4
, sau khi kt thc phn ng ngi ta thu c cht rn gm hai
kim loi. Mi lin h gia x, y v z l:
A. x z < x +y. B. x z. C. x < y < z. D. x +y = z
Cu 33: Ha tan hon ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu c dung dch X v 2,688 lt kh H2
(ktc). Dung dch Y gm HCl H2SO4 c t l mol tng ng l 4:1. Trung ha dung dch X bi dung dch Y, tng khi
lng ca cc mui c to ra l:
A. 13,70 gam B. 12,78 gam C. 14,62 gam D.18,46 gam.
Cu 34: Cho cc cht: etyl axetat, anilin, ancol etylic, axit acrylic, phenylamoni clorua, ancol banzylic, amoni axetat,
phenol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l:
A. 3 B. 6 C. 4 D. 5
Cu 35: Cho hn hp bt gm 0,48gam Mg v 1,68 gam Fe vo dung dch CuCl2 ri khuy u n phn ng hon
ton thu c 3,12 gam cht rn khng tan X. S mol CuCl2 tham gia phn ng l:
A. 0,06 mol B. 0,04mol C. 0,05mol D. 0,03mol
Cu 36: Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO v Fe3O4
nung nng. Sau khi cc phn ng sy ra hon ton, Khi lng hn hp rn gim 0,32 gam. Gi tr ca V l:
A. 0,560 B. 0,112 C. 0,448 D. 0,224
Cu 37: Trn tng cp dung dch: NaCl v AgNO3, FeCl3 v Na2CO3, Fe(NO3)2 v AgNO3, NaHSO3 v HCl. S cp
dung dch c th sy ra phn ng oxi ha kh l:
A. 1 B. 2 C. 3 D. 4
Cu 38: in phn 200ml dung dch cha NaCl 0,5M, Fe(NO3)3 0,3M v Cu(NO3)2 0,3M bng in cc tr c mng
ngn xp n khi khi lng dung dch gim 5,63gam th dng li. Dung dch sau khi in phn c cha
A. NaNO3, Fe(NO3)2, Cu(NO3)2 v HNO3 B. NaNO3 v NaCl
C. NaNO3 v NaOH D. NaNO3,Cu(NO3)2 v HNO3
Cu 39: C 4 cc mt nhn ng ring bit cc cht lng sau: nc mm; nc cng tm thi; nc cng vnh
cu; nc cng ton phn. phn bit c cc cht lng trn (vi cc iu kin cn thit c ), c th dng
thm:
A. NaCl hoc Ca(OH)2 B. NaHCO3 C. Na2CO3 hoc NaHCO3 D. Ca(OH)2 hoc Na2CO3
Cu 40: Mt dung dch c cc tnh cht:
+ Ha tan c Cu(OH)2 cho dung dch mu xanh lam
+ Kh c AgNO3/NH3 Cu(OH)2/OH
-
khi un nng.
+ B thy phn trong mi trng axit.
Dung dch l:
A. Mantoz B. Saccaroz C. Fructoz D. Glucoz
II. PHN RING (Th sinh ch c lm mt trong hai phn A hoc B)
A. Theo chng trnh Chun (10 cu t cu 41 n cu 50)
Cu 41: Cho Este n chc X c t khi so vi hiro bng 44 tc dng va 120 gam NaOH 4% thu c 5,52gam
ancol Y v m gam mui. Gi tr ca m l:
A. 9,84gam B. 11,26gam C. 9,56gam D. 11,87gam
Cu 42: x l s b nc thi c cha cc In kim loi nng, ngi ta thng s dng
A. Nc clo B. Gim n C.Nc vi trong D.Ru etylic
Cu 43: Sc kh H2S cho ti d vo 100ml dung dch hn hp Fe2(SO4)3 0,1M v CuSO4 0,2M; phn ng song thu
c a gam kt ta . Gi tr ca a l:
A. 3,68gam B. 4gam C. 2,24gam D. 1,92gam
171 | G S T T G R O U P
Cu 44: Ha tan hon ton m gam hn hp X gm Na2O v Al2O3 vo nc thu c 200ml dung dch A ch cha
mt cht tan duy nht c nng 0,5M. Sc kh CO2 d vo dung dch A c gam a kt ta. Gi tr ca m v a ln
lt l:
A. 16,4g v 7,8g B. 8,2g v 7,8g C. 16,4g v 15,6g D. 8,2g v 6,8g
Cu 45: Axit acrylic c th tc dng vi tt c cc cht trong dy:
A. Ba, H2, Br2, dung dch NH3, dung dch NaHSO4, CH3OH(H2SO4 c).
B. Na, Cu, Br2, dung dch NH3, dung dch NaHSO3, CH3OH(H2SO4 c).
C. Ca, H2, Cl2, dung dch NH3, dung dch NaCl, CH3OH(H2SO4 c).
D. Mg, H2, Br2, dung dch NH3, dung dch Na2CO3, CH3OH(H2SO4 c).
Cu 46: Khi lm bay hi 5,8 gam hn hp cht hu c X thu c 4,48 lt kh hi X ( 109,2
0
C v 0,7 atm). Mt
khc cho 5,8 gam X tc dng vi AgNO3/NH3 to ra 43,2 gam Ag. Cng thc cu to ca X l:
A. OHC-CHO B. C2H5CHO C. HCHO D. CH3CHO
Cu 47: Cho 3,2 gam bt Cu tc dng vi 100ml dung dch hn hp HNO3 0,8M v H2SO4 0,2M. Sau khi cc phn
ng sy ra hon ton sinh ra V lt kh NO (sn phm kh duy nht) ktc. V c gi tr l:
A. 0,672 lt B. 0,448 lt C. 0,336 lt D. 0,560 lt
Cu 48: Cho s chuyn ha sau: A
1
(C
3
H
6
O
2
)
dd NaOH
A
2
dd H
2
SO
4
A
3
dd AgNO
3
NH
3
A
4
.
Cng thc cu to ca A1 l:
A. CH3COCH2OH B. CH3CH2COOH C. HOCH2CH2CHO D. HCOOCH2CH3
Cu 49: Cht hu c X (C6H10O4) ch cha mt loi nhm chc. un nng X vi dung dch NaOH d thu c mt
mui ca axit cacboxylic Y v mt ancol Z. Bit Y c mch cacbon khng phn nhnh v khng c phn ng trng
bc. S cng thc cu to ca X l:
A. 5 B. 3 C. 4 D. 2
Cu 50: Cho qu tm vo mi dung dch sau: H2N-CH2-COOH (1), ClNH3-CH2-COOH (2), H2N-CH2-COONa (3), C6H-
5OH (4), C6H5NH2 (5), CH
3
NH
2
(6), H2N-CH2-CH2-CH(NH2)-COOH (7), HOOC-CH2-CH2-CH(NH2)-COOH (8). Cc
dung dch lm qu tm i mu l:
A. (2), (3), (6), (7), (8) B. (2), (3), (4), (5) C. (1), (4), (6), (7), (8) D. (1), (2), (4), (5), (6)
B. Theo chng trnh Nng cao (10 cu t cu 51 n cu 60)
Cu 51:Trong qu trnh sn xut gang, xy ra phn ng:
Fe2O3 (r) + 3CO (k) 2Fe (r) + 3CO2 (k); H > 0
tng hiu sut chuyn ha Fe2O3 thnh Fe, c th dng bin php:
A. Tng nhit phn ng. B. Nghin nh qung Fe2O3 C. Nn kh CO2 vo
l. D. Tng p sut chung ca h.
Cu 52: Cho 3,36 lt kh Cl2 ktc tc dng ht vi dung dch cha 15 gam NaI. Khi lng I2 thu c l:
A. 12,7gam B. 2,54gam C. 25,4gam D. 7,62 gam
Cu 53: Dy gm cc cht, In ch c tnh baz:
A. HI, S
2
, PO
4
3
, NaOH B. HCO
3
, NH
3
, NaOH, H
2
O C. CH
3
COO
, S
2
, NH
3
, PO
4
3
D.
HSO
4
, NH
4
+
, HCO
3
, HI
Cu 54: Cho 84,6 gam hn hp hai mui CaCl2 v BaCl2 tc dng ht vi 1 lt dung dch ch Na2CO3 0,25M v
(NH4)2CO3 0,75M sinh ra 79,1 gam kt ta. Thm 600ml Ba(OH)2 1M vo dung dch sau phn ng thu c m gam
kt ta v V lt kh ktc. Gi tr ca m v V l:
A. 98,5gam v 2,688 lt B. 98,5 gam v 26,88 lt C.9,85 gam v 26,88 lt D. 9,85 gam v 2,688 lt
Cu 55: kh hon ton 200ml dung dch KMnO4 0,2M to thnh cht rn mu nu en cn V lt kh C2H4 (
ktc). Gi tr ti thiu ca V l:
A. 2,688 B. 2,240 C. 4,480 D. 1,344
(1) FeCl3 + SnCl2 (2) FeCl3 + Fe (3) ZnCl2 + KI
(4) FeCl3 + KI (5) Fe(NO3)2 + AgNO3 (6) FeCl2 + I2
172 | L O V E B O O K . V N
Bit E
Zn
2+
Zn
0
= 0,76V, E
Fe
2+
Fe
0
= 0,44V, E
Sn
4+
Sn
2+
0
= +0,15V, E
I
2
2I
0
= +0,53V, E
Fe
3+
Fe
2+
0
= +0,77V,
E
Ag
+
Ag
0
= 0,80V. Cc phn ng ha hc c th xy ra l:
A. Tt c cc phn ng trn. B. (1), (2), (4), (5).
C. (1), (3), (4), (5), (6) D. (1), (2), (3), (4), (6)
Cu 57: Cho s phn ng sau: Cr
HCl
X
Cl
2
Y
NaOH d
Z
Br
2
NaOH
T
Cc cht X, Y, Z, T ln lt l:
A. CrCl2, CrCl3, Cr(OH)3, Na2Cr2O7 B.CrCl2, CrCl3, Na[Cr(OH)4], Na2Cr2O7
C. CrCl2, CrCl3, Na[Cr(OH)4], Na2CrO4 D. CrCl2, CrCl3, Cr(OH)3, Na2CrO4
Cu 58: t chy hon ton hn hp X gm amin no n chc, mch h k tip nhau trong dy ng ng, thu
c 13,44 lt CO2 (ktc) v 15,12 gam H2O. Cng thc phn t ca hai amin l:
A. C3H9N v C4H11N B. C2H7N v C3H9N C. CH5N v C2H7N D. C4H11N v C5H13N
Cu 59: Cho cht hu c X mch h c cng thc phn t C4H8O. X khng phn ng vi Na. Khi cng hp H2 (xc
tc Ni, t
0
) to ancol Y. Thc hin phn ng tch nc t Y trong iu kin thch hp thu c anken Z c ng
phn cis-trans. Tn thay th ca X l:
A. Butan-2-on B. 2-metylpropanal C. Butanal D. But-3-en-2-ol
Cu 60: xc nh hm lng Fe3O4 trong 1 mu qung manhetit, ngi ta tin hnh nh sau: ha tan 10 gam
mu qung vo dung dch H2SO4 d c 500 ml dung dch A. Chun 25 ml dung dch A bng dung dch KMnO4
0,01M th thy 12,4 ml dung dch chun. Hm lng Fe3O4 trong mu qung l:
A. 28,76% B. 86,30% C. 57,536% D. 18,85%

P N

1C 2C 3B 4D 5D 6A 7B 8A 9D 10A
11B 12C 13A 14C 15C 16B 17D 18D 19B 20A
21A 22C 23C 24C 25B 26C 27D 28D 29A 30B
31B 32A 33D 34D 35B 36C 37A 38A 39D 40A
41A 42C 43C 44B 45D 46A 47A 48D 49B 50A
51A 52D 53C 54B 55D 56B 57C 58A 59A 60A

173 | G S T T G R O U P
s 25

PHN CHUNG CHO TH SINH C 2 BAN (T cu 1 n cu 40)
Cu 1: Cho cc cht sau: HOOC COONa, K
2
S, H
2
O, KHCO
3
, Al(OH)
3
, Al, KHSO
4
, Zn, (NH
4
)
2
SO
3
. S cht c tnh
lng tnh l
A. 5. B. 6. C. 4. D. 7
Th nghim 1: Trn 0,015 mol ancol no X vi 0,02 mol ancol no Y ri cho hn hp tc dng ht vi Na c 1,008
lt H
2
.
Th nghim 2: Trn 0,02 mol ancol X vi 0,015 mol ancol Y ri cho hn hp tc dng ht vi Na c 0,952 lt H
2
.
Th nghim 3: t chy hon ton mt lng hn hp ancol nh trong th nghim 1 thu c 6,21 gam hn hp
gm CO
2
v H
2
O.
Bit th tch cc khi o ktc v cc ancol u mch h. Cng thc 2 ancol X v Y ln lt l
A. C
3
H
6
(OH)
2
v C
3
H
5
(OH)
3
. C
2
H
4
(OH)
2
v C
3
H
5
(OH)
3

. CH
3
OH v C
2
H
5
OH . C
2
H
5
OH v C
3
H
7
OH
Cu 3: Cho cc cp cht sau:
(1). Kh Cl
2
v kh O
2
. (6). Dung dch KMnO
4
v kh SO
2
.
(2). Kh H
2
S v kh SO
2
(7). Hg v S.
(3). Kh H
2
S v dung dch Pb(NO3)
2
. (8). Kh CO
2
v dung dch NaClO.
(4). Kh Cl
2
v dung dch NaOH. (9). CuS v dung dch HCl.
(5). Kh NH
3
v dung dch AlCl
3
. (10). Dung dch AgNO
3
v dung dch Fe(NO
3
)
2
.
S cp cht xy ra phn ng ha hc nhit thng l
A. 7 B. 8 C. 9 D. 10
Cu 4: Cho cc cht sau: toluen, etilen, xiclopropan, stiren, vinylaxetilen, etanal, imetyl xeton, propilen. S cht
lm mt mu dung dch KMnO
4
nhit thng l
A. 4. B. 6. C. 7. D. 5.
Cu 5: Mt hn hp X gm ankan A v anken B c chia thnh 2 phn. Phn 1 c th tch 11,2 lit em trn vi
6,72 lit H
2
v mt t bt Ni trong mt kh k ri un nng n khi phn ng xy ra hon ton thy hn hp kh sau
cng c th tch gim 25% so vi ban u. Phn 2 nng 80 gam, em t chy hon ton th to c 242 gam
CO
2
. Xc nh A v B.
A. C
2
H
6
v C
4
H
8
. C
2
H
6
v C
3
H
6
. CH
4
v C
3
H
6
. CH
4
v C
4
H
8

Cu 6: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 5,696 gam Ala, 6,4
gam Ala-Ala v 5,544 gam Ala-Ala-Ala. Gi tr ca m l:
A. 13,288. B. 18,12. C. 22,348. D. 16,308.
Cu 7: Cho cc nguyn t v ion sau: 17Cl, 18Ar, 26Fe
2+
, 24Cr
3+
, 16S
2
, 12Mg, 25Mn
2+
, 4Be
2+
, 21Sc
3+
, 31Ga
3+
S vi ht
c cu hnh electron trng thi c bn ging kh him l
A. 6 B. 4 C. 3 D. 5
Cu 8: Tin hnh cc th ngim sau: (1) Cho dung dch NaOH vo dung dch Ca(HCO
3
)
2
; (2) Cho dung dch HCl ti
d vo dung dch Na[Al(OH)
4
]; (3) Sc kh H
2
S vo dung dch FeCl
2
; (4) Sc NH
3
ti d vo dung dch AlCl
3
; (5)
Sc kh CO
2
ti d vo dung dch Na[Al(OH)
4
]; (6) Sc kh etilen vo dung dch KMnO
4
. Sau khi cc phn ng kt
thc c bao nhiu th nghim thu c kt ta?
A. 4 B. 6 C. 5 D. 3
Cu 9: t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri hp th
ton b sn phm chy vo dung dch Ca(OH)
2
(d). Sau phn ng thu c 18 gam kt ta v dung dch X. Khi
lng X so vi khi lng dung dch Ca(OH)
2
ban u thay i nh th no?
A. Tng 7,92 gam. B. Gim 7,38 gam. C. Gim 7,74 gam. D. Tng 2,70 gam.
Cu 10: Cho 13,74 gam axit picric vo bnh kn ri nung nng nhit cao. Sau khi phn ng xy ra hon ton
thu c x mol hn hp kh gm CO, CO
2
, N
2
v H
2
. Gi tr ca x l:
174 | L O V E B O O K . V N
Cu 11: Cho cc pht biu sau: Trong pin Zn - Cu
(1) Zn l anot (-) xy ra qu trnh kh: Zn Zn
2+
+ 2e
(2) Cu l catot(+) xy ra qu trnh kh: Cu
2+
+ 2e Cu
(3) Dng in mch ngoi c chiu t in cc Cu sang in cc Zn
(4) Cc ion dng trong cu mui di chuyn v pha in cc Cu
Cc pht biu ng l
A. 1, 3, 4 B. 2, 3, 4 C. 2, 4 D. 1, 2, 3
Cu 12: Cho 5,2 gam ankanal X phn ng hon ton vi dung dch AgNO
3
/NH
3
, lng Ag sinh ra cho tc dng
hon ton vi dung dch HNO
3
c thu oc 3,64 lt kh NO
2
(sn phm kh duy nht 270C, 740mmHg). Cng
thc phn t ca ankanal l
A. C
3
H
7
CHO B. CH
3
CHO C. C
2
H
5
CHO D. HCHO
Cu 13: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ho m gam X cn 40 ml dung dch
NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lit CO
2
(ktc) v 11,7 gam H
2
O. S mol
ca axit linoleic trong m gam hn hp X l:
A. 0,015mol B. 0,010mol C. 0,020mol D. 0,050mol.
Cu 14: Ho tan ht mt lng ZnCl
2
vo nc c 300ml dung dch X. Cho 100ml dung dch NaOH 2M vo X
c 2a gam kt ta. Mt khc, nu cho 140ml dung dch NaOH 2M vo X th c a gam kt tA. Nng mol
ca dung dch X l:
A. 0,4M B. 0,6M C. 0,3M D. 0,2M
Cu 15: Ho tan hon ton m gam hn hp gm Fe v MgCO
3
bng dung dch HCl d thu c hn hp kh A gm
H
2
v CO
2
. Nu cng ho tan m gam hn hp trn trong dung dch H
2
SO
4
c nng th thu c hn hp B gm
SO
2
v CO
2
. m
B
: m
A
= 3,6875. Thnh phn % theo khi lng ca MgCO
3
l:
A. 53% B. 47% C. 38%. D. 63%
(a) C
3
H
4
O
2
+ NaOH X + Y
(b) X + H
2
SO
4
(long) Z + T
(c) Z + dung dch AgNO
3
/NH
3
(d) E + Ag + NH
4
NO
3

(d) Y + dung dch AgNO
3
/NH
3
(d) F + Ag + NH
4
NO
3

Cht E v cht F theo th t l
A. HCOONH
4
v CH
3
COONH
4
. (NH
4
)
2
CO
3
v CH
3
COOH
C. (NH
4
)
2
CO
3
v CH
3
COONH
4
. HCOONH
4
v CH
3
CHO
Cu 17: Cho cc hp cht hu c:
(1) ankan; (2) ancol no, n chc, mch h;
(3) xicloankan; (4) ete no, n chc, mch h;
(5) anken; (6) ancol khng no (c mt lin kt i C=C), mch h;
(7) ankin; (8) anehit no, n chc, mch h;
(9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc.
Dy gm cc cht khi t chy hon ton u cho s mol CO
2
bng s mol H
2
O l:
A. (1), (3), (5), (6), (8). B. (3), (4), (6), (7), (10). C. (2), (3), (5), (7), (9). D. (3), (5), (6), (8), (9).
Cu 18: Ho tan hon ton hn hp X gm Fe v Mg bng mt lng va dung dch HCl 20% thu c dung
dch Y. Nng ca FeCl
2
trong dung dch Y l 15,76%. Nng % ca MgCl
2
trong dung dch Y l:
A. 15,76% B. 24,24%. C. 28,21% D. 11,79%
Cu 19: Cho cc cht sau: phenol, kh sunfur, toluen, ancol benzylic, isopren, axit metacrylic, vinyl axetat, phenyl
amin, axit benzoic. S cht phn ng c vi dung dch nc brom nhit thng l
A. 5. B. 6. C. 4. D. 3.
Cu 20: Hp th hon ton 4,48 lt CO
2
(ktc) vo 200ml dung dch cha Na
2
CO
3
0,5M v NaOH 0,75M thu c
dung dch X. Cho dung dch BaCl
2
d vo dung dch X thu c kt ta c khi lng l
175 | G S T T G R O U P
A. 9,85gam B. 29,55 gam C. 19,7gam D. 39,4 gam
Cu 21: Nhit phn hon ton R(NO
3
)
2
(vi R l kim loi) thu c 8 gam mt oxit kim loi v 5,04 lt hn hp
kh X gm NO
2
v O
2
(o ktc). Khi lng ca hn hp kh X l 10 gam. Xc nh cng thc ca mui R(NO
3
)
2

?
A. Mg(NO
3
)
2
. Zn(NO
3
)
2
. Fe(NO
3
)
2
. Cu(NO
3
)
2

Cu 22: C 500 ml dung dch X cha Na
+
, NH
4
+
, CO
3
2
v SO
4
2
. Ly 100 ml dung dch X tc dng vi lng d dung
dch HCl thu c 2,24 lt kh. Ly 100 ml dung dch X cho tc dng vi lng d dung dch BaCl
2
thu c 43
gam kt ta. Ly 200 ml dung dch X tc dng vi lng d dung dch NaOH thu c 8,96 lt kh NH
3
. Cc phn
ng hon ton, cc th tch kh u o ktc. Tnh tng khi lng mui c trong 300 ml dung dch X ?
A. 86,2 gam. B. 119 gam. C. 71,4 gam. D. 23,8 gam.
Cu 23: Ho tan hon ton hn hp 3 kim loi Na, Zn, Fe trong dung dch H
2
SO
4
long thu c V lit H
2
(ktc).
Ho tan hon ton hn hp gm kim loi M ho tr II v Fe trong dung dch H
2
SO
4
long cng thu c V lit H2
(ktc). Bit rng Fe c khi lng nh nhau trong 2 hn hp v khi lng ca M bng na tng khi lng ca
Na v Zn trong hn hp ban u. M l:
A. Mg B. Cr C. Ca D. Ba
Cu 24: t chy hon ton x gam hai axit hu c hai chc mch h, u c mt lin kt C=C trong phn t, thu
c V lit CO
2
ktc v y mol H
2
O. Biu thc lin h gia x, y, V l
A. V= 28/55 x (x-30y) B. V= 28/55 x (x-62y) C. V= 28/55 x (x+30y) D. V= 28/55 x (x+62y).
Cu 25: Trong mt bnh kn dung tch 11,2 lit cha sn 24 g hn hp gm O
2
v O
3
. Bm vo bnh V lit hirocacbon
A p sut trong bnh l 2 atm 0
o
C. Bt tia la in t chy hn hp sau phn ng cn li 0,15 mol hirocacbon
A (bit khi cho 0,875gam qua dung dch Br2 d thu c sn phm c khi lng l 2,875 gam). Cng thc ca A
l :
A. C
4
H
8
. C
5
H
8
. C
4
H
6
. D. C
5
H
10

Cu 26: Trong mt bnh kn dung tch 11,2 lit cha sn 24g oxi. Bm V lit mt hirocacbon A vo bnh c hn
hp X 0
o
C p sut trong bnh lc ny l 2atm. t chy X sau phn ng ch thu c CO
2
v H
2
O. Cng thc phn
t ca A l:
A. C
3
H
4
B. C
3
H
6
. C
2
H
4
. C
2
H
6

Cu 27: Cho dy cc hp cht thm: p HO CH
2
C
6
H
4
OH, mHO C
6
H
4
CH
2
OH, p HO C
6
H
4
COOC
2
H
5
, p HO C
6
H
4
COOH, p HCOO C
6
H
4
OH, p CH
3
O C
6
H
4
OH. C bao nhiu cht trong dy
tha mn ng thi 2 iu kin sau?
(a) Ch tc dng vi NaOH theo t l mol 1 : 1.
(b) Tc dng c vi Na (d) to ra s mol H
2
bng s mol cht phn ng.
A. 3. B. 4. C. 2. D. 1.
Cu 28: Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH d thu c
dung dch Y cha (m+ 30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c
dung dch Z cha (m+ 36,5) gam mui. Gi tr m l
Cu 29: Cho a (gam) st vo dung dch cha y mol CuSO
4
v z mol H
2
SO
4
long, sau phn ng hon ton thu c
kh H
2
, a (gam) ng v dung dch ch cha mt cht tan duy nht. Mi quan h gia y v z l
A. y = 5z. B. y = z. C. y = 7z. D. y = 3z.
Cu 30: Cho cn bng sau: A2(k) + 3B2(k) 2D(k). Khi tng nhit , t khi ca hn hp kh gim.
Pht biu no sau y ng?
A. Phn ng thun l thu nhit. Khi tng nhit , cn bng (1) chuyn dch v phn ng thun
B. Phn ng thun l ta nhit. Khi tng nhit , cn bng (1) chuyn dch v phn ng nghch
C. Phn ng thun l thu nhit. Khi tng nhit , cn bng (1) chuyn dch v phn ng nghch
D. Phn ng thun l ta nhit. Khi tng nhit , cn bng (1) chuyn dch v phn ng thun
Cu 31: Cho 1 mol aminoaxit X phn ng vi dung dch HCl d thu c m
1
gam mui Y. Cng 1 mol aminoaxit X
phn ng vi dung dch NaOH d thu c m
2
gam mui Z. Bit m
2
m
1
= 7,5. Cng thc phn t ca X l :
176 | L O V E B O O K . V N
A. C
4
H
10
O
2
N . C
5
H
9
O
4
N . C
4
H
8
O
4
N . C
5
H
11
O
2
N.
Cu 32: Cho cc phn ng sau: (1)AgNO
3
+ Fe(NO
3
)
2
Fe(NO
3
)
3
+ Ag
(2) Mn + 2HCl MnCl
2
+ H
2

(3) 3Ag + 4HNO
3
3AgNO
3
+ NO + 2H
2
O
Th t tng dn tnh oxi ha ca cc ion l:
. NO
3
(H
+
), Ag
+
; Fe
3+
; Mn
2+
. Mn
2+
; Fe
3+
; Ag
+
; NO
3
(H
+
)
C. Mn
2+
; Fe
3+
; NO
3
(H
+
); Ag
+
D. NO
3
(H
+
); Mn
2+
; Fe
3+
; Ag
+

Cu 33: Ho tan ht 10,24 gam Cu bng 200 ml dung dch HNO
3
3M c dung dch A. Thm 400 ml dung dch
NaOH 1M vo dung dch A. Lc kt ta, c cn dung dch ri nung cht rn n khi lng khng i c 26,44
gam cht rn. S mol HNO
3
phn ng vi Cu l:
A. 0,568 mol B. 0,48 mol C. 0,4 mol. D. 0,56 mol
Cu 34: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M,
thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp
th ht sn phm chy vo bnh ng dung dch Ca(OH)
2
(d) th khi lng dung dch trong bnh gim 2,66 gam.
Cng thc ca hai hp cht hu c trong X l
A. HCOOH v HCOOC
2
H
5
. C
2
H
5
COOH v C
2
H
5
COOCH
3
.
C. HCOOH v HCOOC
3
H
7
. CH
3
COOH v CH
3
COOC
2
H
5

Cu 35: Hn hp X gm 2 andehit A v B. Oxi ho 7,2 gam hn hp X bng dung dch AgNO
3
d trong NH
3
sau
axit ho thu c 2 axit tng ng. Trung ho ht lng axit bng dung dch NaOH , sau nung nng hn hp
vi vi ti xt thu c 3,36 lt hn hp kh, cho hn hp kh vo 300 ml dung dch KMnO
4
1M trong H
2
SO
4
thy
th tch hn hp gim i 1/3 ng thi mu tm ca dung dch b nht mu. Bit s nguyn t cacbon trong A ln
hn trong B mt nguyn t (cc kh u o ktc). Cho bit cng thc cu to ca A v B:
A. CH
3
CHO v C
2
H
5
CHO B. CH
2
= CH CHO v CH
3
CHO
C. C
3
H
7
CHO v CH
3
CHO D. HCHO v CH
3
CHO
Cu 36: Pht biu no sau y sai:
A. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit
B. Phn nhm c cng thc l K
2
SO
4
. Al
2
(SO
4
)
3
. 24H
2
O
C. Tt c cc protein u tan trong nc to dung dch keo
D. Qung st manhetit c thnh phn chnh l Fe
3
O
4
.
Cu 37: Cho phng trnh phn ng: Fe
3
O
4
+KMnO
4
+KHSO
4
Fe
2
(SO
4
)
3
+ MnSO
4
+K
2
SO
4
+H
2
O. H s
cn bng (l nhng s nguyn dng ti gin nht) ca H
2
O trong cn bng trn l
A. 49. B. 47. C. 48. D. 50.
Cu 38: Dung dch A cha 0,1 mol NaOH v 0,3 mol Na[Al(OH)
4
]. Th tch HCl cc i cn cho vo dung dch A
xut hin 15,6 gam kt ta l :
A. 700ml B. 600ml C. 800 ml D. 900 ml
Cu 39: Trung ho 3,88 gam hn hp X gm 2 axit cacboxylic mch h, no, n chc bng dung dch NaOH, c
cn dung dch sau phn ng thu c 5,2 gam mui khan. Nu t chy hon ton 3,88 gam X th th tch oxi ktc
cn l:
Cu 40: X phng ho 10kg cht bo c ch s axit bng 7 bng dung dch cha 1,4kg NaOH. Khi lng x phng
thu c l :
A. 11,2458kg B. 10,475 kg C. 11,268 kg D. 10,3425kg
PHN DNH CHO TH SINH BAN NNG CAO (T cu 41 n cu 50)
Cu 41: Cho 0,04 mol mt hn hp X gm CH
2
= CH CH
2
OH, CH
3
COOH v CH
2
= CH CHO phn ng va
vi dung dch NaHCO
3
d thu c 0,224 lit kh ktc. Mt khc, 0,04 mol X phn ng cn 1,12 lt H
2
, xt Ni, un
nng. Khi lng ca CH
2
= CH CH
2
OH trong X l :
177 | G S T T G R O U P
Cu 42: Cho 3,87 gam hn hp 2 kim loi Al v Mg vo 250 ml dung dch X gm HCl 1M v H
2
SO
4
0,5 M thu c
dung dch B v 4,368 lt kh H
2
(ktc). Cho dung dch B tc dng vi V ml dung dch hn hp gm NaOH 0,2M v
Ba(OH)
2
0,1 M. Th tch dung dch B cn thit tc dng vi dung dch A cho kt ta ln nht l
A. 2,75 lt. B. 1,2 lt. C. 1,475 lt. D. 1,25 lt.
A. Trong dung dch, H
2
N CH
2
COOH cn tn ti dng ion lng cc H
3
N +CH
2
COO
B. Hp cht H
2
N CH
2
COOH
3
N CH
3
l este ca glyxin (hay glixin).
C. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt.
D. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl.
Cu 44: Cho cc phn t v ion sau: HSO
4
; C
3
H
6
; N
2
O; N
2
O
5
; H
2
O
2
; NO
3
; Cl
2
; H
3
PO
4
; C
2
H
5
OH; CO
2
. S phn t
ch cha lin kt cng ha tr khng phn cc l
A. 6 B. 5 C. 4 D. 3
(1) Cho dung dch FeCl
2
tc dng vi dung dch AgNO
3

(2) nc Javen trong khng kh mt thi gian.
(3) Bnh nc vi trong ngoi khng kh.
(4) Sc kh sunfur vo dung dch thuc tm.
(5) Ngm dy ng trong bnh ng dung dch HCl trong khng kh h ming bnh.
S th nghim xy ra phn ng oxi ha kh l
A. 3 B. 5 C. 4 D. 2
Cu 46: Cho cc cht: axetilen, vinylaxetilen, metylxiclopropan, cumen, stiren, xiclohexan, xiclopropan v
xiclopentan. Trong cc cht trn, s cht phn ng c vi dung dch brom l
A. 4. B. 5. C. 3. D. 6.
Cu 47: Cho 37,95g hn hp hai mui MgCO
3
v RCO
3
vo 100ml dd H
2
SO
4
long thy c 1,12 lt CO
2
(ktc) thot
ra, dung dch A v cht rn B. C cn dung dch A thu c 4g mui khan. Nung cht rn B n khi lng khng
i th thu c rn B
1
v 4,48 lt CO
2
(kc). Bit trong hn hp u c t l RCO
3
MgCO
3
n : n = 3: 2 . Khi lng
cht rn B
1
v nguyn t R l:
A. 26,95g v Ba. B. 27,85g v Ba. C. 27,85g v Ca. D. 26,95g v Ca.
Cu 48: t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O
2
, thu c 23,52
lt kh CO
2
v 18,9 gam H
2
O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M, c cn dung dch sau
phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z (MY < MZ). Cc th tch
kh u o iu kin tiu chun. T l a : b l
A. 3 : 5. B. 2 : 3. C. 3 : 2. D. 4 : 3.
Cu 49: Thm t t 100g dung dch H
2
SO
4
98% vo nc v iu chnh c 1 lt dung dch X. Phi thm vo
1 lt dung dch X bao nhiu lt dung dch NaOH 1,5M thu c dung dch c pH = 13?
A. 3,00M. B. 1,14 lt C. 1,24 lt D. 1,50 lt
Cu 50: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn
thu c hn hp kh Y. Cho Y qua dung dch H
2
SO
4
c, thu c hn hp kh Z c t khi i vi hiro bng 19.
S ng phn mch h ca X l
A. 1 B. 3 C. 2 D. 4
PHN DNH CHO TH SINH BAN C BN (T cu 51 n cu 60)
Cu 51: Thc hin cc th nghim sau iu kin thng:
(a) Cho kim loi liti tc dng vi kh nit;
(b) Sc kh hiro iotua vo dung dch mui st (III) Clorua;
(c) Cho bc kim loi vo dung dch st (III) Clorua;
(d) Dn kh amoniac vo bnh ng kh clo;
(e) Cho phn m ure vo nc;
(g) Nhng thanh st vo dung dch H
2
SO
4
98%;
178 | L O V E B O O K . V N
(h) Sc kh imetyl amin vo dung dch phenylamoni clorua;
(i) Cho dung dch axit axetic vo dung dch natri phenolat.
S th nghim xy ra phn ng l
A. 7. B. 6. C. 4. D. 5.
Cu 52: Trong mt cc nc cha a mol Ca
2+
, b mol Mg
2+
v c mol HCO
3
. Khi thm V lt dung dch Ca(OH)

2
(nng
x mol/l) lm gim cng ca nc th ngi ta thy cng trong nc l nh nht. Biu thc lin h
gia V, a, b, x l:
A. xV = b + a B. xV =2b + a C. xV = b + 2a D. 2xV = b + a
Cu 53: Cho dy cc cht: CO
2
, H
2
S, MgO, Cl
2
, CCl
4
. S cht trong dy m phn t ch cha lin kt cng ha tr c
cc l:
A. 3. B. 4. C. 2. D. 1.
Cu 54: Loi t no sau y c iu ch bng phn ng trng ngng?
A. T lapsan. B. T vinilon. C. T olon. D. T clorin.
(a) Nhit phn NH
4
NO
3
;
(b) Cho dung dch Fe(NO
3
)
2
vo dung dch H
2
SO
4
(long);
(c) un nng C
2
H
5
Br vi KOH trong etanol;
(d) Sc kh NO
2
vo dung dch Ba(OH)
2
;
(e) Sc kh Clo vo dung dch KOH nhit thng;
(g) Nhit phn KClO
3
c xc tc MnO
2
.
S th nghim xy ra phn ng oxi ha - kh ni phn t l
A. 4. B. 1. C. 3. D. 2.
Cu 56: Th nghim c xy ra s n mn in ha l:
A. Nhng thanh magie vo dung dch H
2
S B. Nhng thanh st vo dung dch Fe
2
(SO
4
)
3
.
C. Nhng thanh st vo dung dch CuCl
2
. D. Nhng thanh ng vo dung dch FeCl
3
.
Cu 57: Pht biu sai l:
A. Monosaccarit khng c phn ng thy phn.
B. Thy phn hon ton tinh bt v xenluloz u thu c glucoz.
C. Glucoz, saccaroz v mantoz u c kh nng lm mt mu nc brom.
D. Mantoz c kh nng lm mt mu dung dch thuc tm.
Cu 58: Cho dy cc cht: o-Crezol, p-Xilen, isopren, glucoz, fructoz, mantoz, saccaroz, alanin, catechol, axit
benzoic, kh sunfur, metylxiclopropan, xiclobutan v kh clo. S cht trong dy c kh nng lm mt mu dung
dch nc brom nhit thng l
A. 10. B. 9. C. 8. D. 7.
Cu 59: Cho dy cc cht: Canxi hirocacbonat, amoni photphat, etylamoni fomat, amoni axetat, etyl metanoat.
S cht trong dy va phn ng c vi dung dch HCl va phn ng c vi dung dch NaOH l
A. 2. B. 3. C. 5. D. 4.
Cu 60: Mt loi khong cht c cha 48,9% oxi; 10,3% nhm v cn li l silic v natri v khi lng. Phn trm
khi lng ca silic trong khong cht l
A. 32,1%. B. 21,7%. C. 38,4%. D. 20,3%.

P N

1A 2B 3B 4D 5D 6D 7B 8A 9B 10A
11B 12A 13A 14C 15A 16C 17D 18D 19B 20A
21C 22C 23A 24C 25D 26C 27C 28D 29C 30B
31B 32B 33D 34A 35B 36C 37C 38D 39D 40D
41C 42D 43B 44B 45C 46B 47A 48D 49D 50D
51B 52B 53A 54A 55A 56C 57C 58C 59C 60A
179 | G S T T G R O U P
s 26

Cu 1: T C
2
H
4
, cht v c v iu kin y . S phn ng t nht to thnh natri axetat v etylen glicol
l
A. 6 B. 3. C. 4. D. 5.
Cu 2: C cc pht biu sau:
(1) S, P, C
2
H
5
OH u bc chy khi tip xc vi CrO
3
.
(2) Ion Fe
3+
c cu hnh electron vit gn l [Ar]3d
5
.
(3) Bt nhm t bc chy khi tip xc vi kh Clo.
(4) Phn chua c cng thc l Na
2
SO
4
.Al
2
(SO
4
)
3
.24H
2
O.
S pht biu ng l
A. 2 B. 4 C. 3 D. 1
Cu 3: in phn dung dch cha hn hp CuSO
4

v KCl vi in cc tr, mng ngn xp, khi thy kh thot
ra 2 in cc th ngng li thy c 448 ml kh (ktc) thot ra anot. Dung dch sau in phn c th ha tan
ti a 0,8 gam MgO. Khi lng dd sau in phn gim bao nhiu gam?
Cu 4: Cho cc cht sau phn ng vi nhau tng i mt: dd HCl, dd CrCl
3
, dd NaOH, dd NH
3
, Cr
2
O
3
. S lng cc
cp cht xy ra phn ng trong iu kin c l
A. 6. B. 8. C. 7. D. 9.
A. Ancol o-hiroxibenzylic l sn phm trung gian trong qu trnh iu ch nha novolac t phenol v
fomanehit.
B. T nilon-6,6 thuc loi t poliamit, c iu ch bng phn ng ng trng hp cc monome tng ng.
C. T visco, t xenluloz axetat, t nitron cng thuc loi t nhn to.
D. Cao su buna-S thu c khi cho cao su buna tc dng vi lu hunh.
Cu 6: Cho cc qu trnh ha hc:
1. Sc kh H
2
S vo dung dch FeCl
3

2. Dung dch AlCl
3

tc dng vi dung dch Na
2
S
3. Hidrat ha C
2
H
4

4. Nhit phn CaOCl
2

5. KF tc dng vi H
2
SO
4

c, nng 6. in phn dung dch NaCl
7. Al
4
C
3

tc dng vi dung dch HCl 8. n mn gang, thp trong khng kh m
C bao nhiu qu trnh xy ra phn ng oxi ha kh?
A. 7 B. 6 C. 5 D. 4
Cu 7: Cc cht kh sau: SO
2
, NO
2
, Cl
2
, N
2
O, H
2
S, CO
2
. Cc cht kh khi tc dng vi dung dch NaOH ( nhit
thng) lun to ra 2 mui l
A. SO
2
, CO
2
, H
2
S B. NO
2
, SO
2
, CO
2
C. Cl
2
, NO
2
D. CO
2
, Cl
2
, N
2
O
Cu 8: Cho 61,2 gam hn hp X gm Cu v Fe
3
O
4

tc dng vi dung dch HNO
3

long, un nng v khuy u.
Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc), dung dch Y
v 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l
A. 137,1. B. 151,5. C. 97,5. D. 108,9.
Cu 9: n cht kim loi Crom c cu trc tinh th vi phn rng trong tinh th chim 32%. Khi lng ring
ca kim loi crom l 7,19 gam/cm
3
. Bn knh nguyn t crom (tng i) l (1A
o

=10
-8

cm)
A. 1,2. 10
-8

cm B. 1,25A
o

C. 1,68A
o

D. 1,5.10
-10
m
Cu 10: Ly 0,3 mol hn hp X gm H
2
NC
3
H
5
(COOH)
2
v H
2
NCH
2
COOH cho vo 400 ml dung dch HCl 1M
th thu c dung dch Y. Y tc dng va vi 800ml dung dch NaOH 1M thu c dung dch Z. Lm bay hi
180 | L O V E B O O K . V N
Z thu c m gam cht rn khan, gi tr ca m l
Cu 11: Cht no dng nhn bit ra cc cht ring bit Na, Al, Mg, Al
2
O
3

v trong qu trnh nhn bit chng
cn dng ti thiu bao nhiu phn ng?
. dd Na
2
CO
3
v 4 phn ng . dd NaOH v 2 phn ng . H
2
O v 3 phn ng . H
2
O v 2 phn ng
Cu 12: Cho cc cht sau: Al(OH)
3
, CH
3
COOH; K
2
S, H
2
O, NaHCO
3
, Zn(OH)
2
, Al, KHSO
4
, (NH
4
)
2
CO
3
, Zn. S cht c
tnh lng tnh theo Bronsted l
A. 7 B. 6 C. 5 D. 4
Cu 13: Cho m gam hn hp G gm Al, Fe, Cu, Mg nung trong bnh cha oxi sau mt thi gian thu c 2,63 gam
hn hp H. Ha tan ht H trong dung dch HNO
3
d, thu c 0,448 lt kh NO (sn phm kh duy nht, ktc).
S mol HNO
3

tham gia phn ng l 0,14 mol, gi tr ca m l.
A. 2,15 B. 2,36 C. 2,42 D. 2,47
Cu 14: Cho kh CO
2
, dung dch KHSO
4

vo hai ng nghim cha dung dch natri phenolat. Cho dung dch
NaOH, dung dch HCl vo hai ng nghim cha dung dch phenylamoni clorua. Hin tng dung dch b vn
c s xy ra
A. 3 ng nghim. B. 1 ng nghim. C. C 4 ng nghim. D. 2 ng nghim.
Cu 15: Thc hin phn ng nhit nhm (khng c khng kh) m gam hn hp X gm Al v Fe
3
O
4
, hiu sut
100%. Chia cht rn Y thu c lm 2 phn, phn 1 c khi lng nh hn phn 2. Cho phn 2 tc dng dd HCl
d, thu c 9,828 lt H
2
(kc). Nu bit phn 1 c cha 3,78 gam Fe, 3,06 gam Al
2
O
3

v 1,4175 gam Al th gi
tr ca m l
A. 22,02 B. 43, 875 C. 16,51 D. 33,03
Cu 16: m gam Fe ngoi khng kh mt thi gian thu c 6,24 gam cht rn X gm Fe v cc oxit. Ho tan
ht X trong 130 ml dd HNO
3

4M(va ) thu c kh NO
2
(sn phm kh duy nht). Cho dd sau phn ng tc
dng vi dd NaOH d, lc kt ta, em nung n khi lng khng i c a gam cht rn Y. Gi tr m v a
ln lt l
A. 5,6 v 8 gam B. 5,6 v 12 gam C. 11,2 v 12 gam D. 11,2 v 8 gam
1.Nguyn t cc nguyn t halogen u c 7 electron lp ngoi cng.
2.Cc nguyn t halogen ch c s oxi ha -1 trong mi hp cht.
3.Cc nguyn t halogen c m in gim dn theo th t: F > Cl > Br > I.
4.Cc hidro halogenua u l nhng cht kh, dung dch ca chng trong nc u c tnh axit mnh.
5.Tnh kh ca cc hidro halogenua tng dn theo th t: HF < HCl < HBr < HI.
6.Cc mui bc halogenua u khng tan trong nc.
7.Trong t nhin cc halogen tn ti ch yu dng n cht.
S pht biu sai l
A. 2 B. 3 C. 5 D. 4
Cu 18: Cho hn hp X gm C
3
H
7
COOH, C
4
H
8
(NH
2
)
2
, HO CH
2
CH = CHCH
2
OH. t chy hon ton m
gam hn hp X, sn phm chy hp th hon ton vo dung dch Ca(OH)
2

thy to ra 20g kt ta v dung dch
Y. un nng dung dch Y thy xut hin kt ta. C cn dung dch Y ri nung cht rn thu c n khi lng
khng i thu c 5,6 gam cht rn. Gi tr ca m l
A. 8,2 B. 5,4 C. 8,8 D. 7,2
Cu 19: C cc ha cht: K
2
Cr
2
O
7
, HCl, KMnO
4
, MnO
2
, NaCl, HClO, H
2
SO
4
, KClO
3
. Nhng ha cht c s dng
iu ch Cl
2

trong phng th nghim l
A. K
2
Cr
2
O
7
, HCl, KMnO
4
, MnO
2
, KClO
3
. B. K
2
Cr
2
O
7
, HCl, KMnO
4
, MnO
2
, NaCl, HClO.

C. K
2
Cr
2
O
7
, HCl, KMnO
4
, MnO
2
, NaCl, HClO, H
2
SO
4
. D. K
2
Cr
2
O
7
, HCl, KMnO
4
, MnO
2
, HClO.

181 | G S T T G R O U P
3
H
6
O
2
c x ng phn lm qu tm ha ; y ng phn tc dng c
vi dd NaOH, nhng khng tc dng vi Na; z ng phn tc dng c vi dd NaOH v dd AgNO
3
/NH
3

v t
ng phn va tc dng c vi Na, va tc dng c vi dd AgNO
3
/NH
3
. Khng nh no sau y khng
ng?
A. z = 0 B. y = 2 C. x = 1 D. t = 2
Cu 21: Cho (1) Etanol; (2) Vinylaxetylen; (3) Isopren; (4) 2-phenyletanol-1. Tp hp no c th iu ch
c cao su buna-S bng 3 phn ng?
A. (3)+(4). B. (2)+(3). C. (1)+(3). D. (1)+(4).
Cu 22: Cho cc este: vinyl axetat, vinyl benzoat, etyl axetat, isoamyl axetat, phenyl axetat, anlyl axetat, s este
c th iu ch trc tip bng phn ng ca axit v ancol tng ng (c H
2
SO
4

c lm xc tc) l
A. 5 B. 3 C. 4 D. 2
Cu 23: Mt hn hp gm axit no n chc X v ancol no n chc Y c khi lng phn t bng nhau. Chia hn
hp ra 2 phn bng nhau: Phn 1 tc dng vi Na d thu c 0,56 lt H
2
. t chy hon ton phn 2 sinh ra
2,688 lt kh CO
2
. Cng thc phn t v phn trm khi lng X, Y trong hn hp l (cc th tch kh o ktc)
A. HCOOH 40% ; C
2
H
5
OH 60% B. CH
3
COOH 40% ; C
3
H
7
OH 60%
C. CH
3
COOH 60% ; C
3
H
7
OH 40% D. HCOOH 60% ; C
2
H
5
OH 40%
Cu 24: t chy hon ton hn hp Q gm 2 ankin X, Y. Hp th ton b sn phm chy vo 4,5 lt dung dch
Ca(OH)
2
0,02M thu c kt kt ta v khi lng dung dch tng 3,78 gam so vi ban u. Cho dung dch
Ba(OH)
2

va vo dung dch thu thm kt ta. Tng kt ta 2 ln l 18,85 gam. Bit rng s mol ca X bng
60% tng s mol ca X v Y c trong hn hp Q. Cc phn ng xy ra hon ton. Cng thc ca X, Y ln lt l
A. C
4
H
6
v C
2
H
2

B. C
2
H
2
v C
3
H
4

C. C
2
H
2
v C
4
H
6
D. C
3
H
4
v C
2
H
6

Cu 25: Cho m gam Fe tan ht trong 400ml dung dch FeCl
3
1M thu c dung dch Y. C cn dung dch Y thu
c 71,72 gam cht rn khan. ho tan m gam Fe cn ti thiu bao nhiu ml dd HNO
3
1M (bit sn phm kh
duy nht l NO)?
A. 320 ml. B. 160 ml. C. 480 ml. D. 540 ml.
Cu 26: Cho cc cht sau y phn ng vi nhau:
(1) SO
2
+Br
2
+H
2
O (2)Br
2
+HI (3) Br
2
+H
2
O
(4) Cl
2
+Br
2
+H
2
O (5)H
2
S + Br
2

(6) PBr
3
+
+H
2
O

(7)
NaBr (rn) +
+
+H
2
SO
4
(c))

S trng hp khng to ra HBr l
A. 3 B. 2 C. 4 D. 1
Cu 27: Hn hp M gm axit X, ancol Y v este Z c to ra t X v Y, tt c u n chc; trong s mol X
gp hai ln s mol Y. Bit 17,35 g M tc dng va vi dd cha 0,2 mol NaOH, ng thi thu c 16,4 g mui
khan v 8,05 g ancol . Cng thc X, Y, Z l
A. HCOOH, C
3
H
7
OH, HCOOC
3
H
7
. B. CH
3
COOH, C
2
H
5
OH, CH
3
COOC
2
H
5
.
C. CH
3
COOH, CH
3
OH, CH
3
COOCH
3
. D. HCOOH, CH
3
OH, HCOOCH
3
.

Cu 28: Trong cc cht sau: HCHO, CH
3
Cl, CH
3
COOCH
3
, CH
3
ONa, CH
3
OCH
3
, CO, CH
2
Cl
2

c bao nhiu cht to ra
metanol bng 1 phn ng?
A. 3 B. 6 C. 4 D. 5
Cu 29: Cht hu c Y
1
trong phn t ch cha mt loi nhm chc, c phn trm khi lng C v H tng ng
bng 49,315% v 6,85%, cn li l oxi. T khi hi ca Y
1

so vi khng kh xp x bng 5,034. Cho Y
1
tc dng
vi dung dch NaOH, sinh ra mt mui (Y
2
) v mt ancol (Y
3
). Nung mui
Y
2

vi hn hp vi ti xt thu c
mt hirocacbon n gin nht. Cng thc Y
2
v Y
3

ln lt l
A. NaOOCCH
2
COONa v CH
3
OH. B. CH
3
COONa v CH
3
CH
2
CH
2
OH
C. CH
3
COONa v HOCH
2
CH
2
OH D. HCOONa v HOCH
2
CH
2
CH
2
CH
2
OH
Cu 30: mnh tnh axit c xp tng dn theo dy sau:
182 | L O V E B O O K . V N
A. CH
3
COOH < HCOOH < H
2
CO
3
< HClO B. H
2
CO
3
< CH
3
COOH < HCOOH < HClO
C. HCOOH < CH
3
COOH < H
2
CO
3
< HClO D. HClO < H
2
CO
3
< CH
3
COOH < HCOOH
: Trong s : Benzen
CH
2
=CHCH
3
(xt)
A
1.O
2
,2H
2
O,H
+
B
+HCN
D
H
2
O,H
+
E
H
2
SO
4
F. F l:
A. axeton B. axit metacrylic C. axit acrylic D. axit propionic
Cu 32: Cho 200 ml dung dch X gm Ba(OH)
2
0,5M v Na[Al(OH)
4
] 1,5M. Thm t t dung dch H
2
SO
4
0,5M
vo dung dch X cho n khi kt ta to thnh b tan mt phn, phn kt ta cn li em nung n khi lng
khng i thu c 24,32 gam cht rn Z. Th tch dung dch H
2
SO
4

dng l
A. 0,67 lt. B. 1,1 lt C. 0,55 lt. D. 1,34 lt.
Cu 33: Cho s bin ha sau: Al X Y Z Al. X, Y, Z ln lt l
A. Al
2
(SO
4
)
3
, AlCl
3
, Al(OH)
3

B. AlCl
3
, Al(OH)
3
, Al
2
O
3
C.
Al(NO
3
)
3
, AlCl
3
, Al
2
O
3

D. Al(NO
3
)
3
, NaAlO
2
, Al
2
O
3

Cu 34: Cho m gam hn hp bt X gm a mol Fe
2
O
3
, a mol Fe
3
O
4
, a mol FeO. Nu ho tan m gam X bng V lt
dd HCl 2M th va . Nu dn 1 lung kh CO d qua ng s nung nng cha m gam X th phn ng xong ch
cn li 33,6 gam Fe. Gi tr ca V l
A. 0,8 B. 1,0 C. 1,2 D. 0,6
Cu 35: Hn hp A gm 1 ankan v 1 anken, t chy A thu c a mol H
2
O v b mol CO
2
. Hi t s T = a / b c
gi tr trong khong no?
A. 1 < T < 1,5 B. 1,5 < T < 2 C. 0,5 < T < 2 D. 1 < T < 2
1.Cc dd glyxin, alanin, lysin u khng lm i mu qu.
2. Lin kt peptit l lin kt to ra gia 2 n v - aminoaxit
3. Cho Cu(OH)
2
/NaOH vo dd protein s xut hin mu tm c trng.
4. Peptit l nhng hp cht cha cc gc -amino axit lin kt vi nhau bng nhng lin kt peptit.
5. Protein n gin c to thnh ch t cc -amino axit.
6. Protein phc tp to thnh t cc protein n gin cng vi thnh phn phi protein. S nhn
xt ng l
A. 4 B. 6 C. 3 D. 5
Cu 37: Ha tan hon ton hn hp gm Na
2
O, BaCl
2
, NaHCO
3
, KHCO
3

c s mol mi cht bng nhau vo nc
ri un nng nh. Sau khi kt thc th nghim c dung dch A. Dung dch A c pH
A. > 7. B. 0 C. < 7 D. = 7
Cu 38: Cho tan hon ton 8,0 gam hn hp X gm FeS v FeS
2
trong dd HNO
3

va thu c kh NO v dd Y.
Cho dd Ba(OH)
2

vo dd Y tc dng ht vi cc cht trong dd Y. Kt ta to thnh em nung ngoi khng
kh n khi lng khng i c 32,03 gam cht rn Z. Khi lng FeS
2
trong X v th tch kh NO (ktc) thu
c l
A. 4,4 gam v 1,12 lt. B. 3,6 gam v 6,72 lt. C. 3,6 gam v 3,36 lt. D. 4,4 gam v 2,24 lt
Cu 39: C th dng H
2
SO
4

c lm kh c cc kh:
A. O
2
, H
2
, NO
2
, H
2
S, Cl
2

B. Cl
2
, SO
2
, CO
2
, NO
2
, H
2
S C. O
2
, H
2
, SO
3,
N
2

D. N
2
, H
2
, SO
2
, CO
2

Cu 40: linh ng ca nguyn t H trong nhm OH ca cc cht: ancol etylic, axit axetic, axit propionic, axit
phenic, axit picric c sp xp theo th t tng dn
A. ancol etylic, axit axetic, axit propionic, axit phenic, axit picric.
B. ancol etylic, axit axetic, axit propionic, axit picric, axit phenic.
C. ancol etylic, axit phenic, axit propionic, axit axetic, axit picric.
D. ancol etylic, axit phenic, axit picric, axit axetic, axit propionic.
Cu 41: Khi ng trng hp isopren vi acrilonitrin ta thu c polime B. Khi t chy m gam B bng oxi (va
) thu c hn hp cha 58,33% CO
2

v th tch. T l mt xch isopren v acrilonitrin trong polime B
tng ng l
183 | G S T T G R O U P
A. 2:1 B. 1:2 C. 3:1 D. 1:3
Cu 42: X v Y ln lt l cc tripeptit v tetrapeptit c to thnh t cng mt amino axit no mch h, c mt
nhm COOH v mt nhm NH
2
. t chy hon ton 0,1 mol Y thu c sn phm gm CO
2
, H
2
O, N
2
, trong
tng khi lng ca CO
2
v H
2
O l 47,8 gam. Nu t chy hon ton 0,3 mol X cn bao nhiu mol O
2
?
Cu 43: Khi in phn dung dch NiSO
4

vi in cc Ni: Cho bit cc trnh no sau y xy ra in cc?
A. Catt: S kh ion Ni
2+
; Ant s oxi ha Ni thnh ion Ni
2+
.

B. Catt: S oxi ha Ni
2+
; Ant: S kh Ni thnh Ni
2+
.

C. Catt: S oxi ha Ni
2+
; Ant: S kh ion H
2
O sinh ra O
2
.

D. Catot: s kh ion
Ni
2+
; Ant: S oxi ha phn t H
2
O sinh ra O
2
.

Cu 44: un nng hn hp etanol v butan-2-ol vi H
2
SO
4
m c th tng s cc cht: anken v ete ti a
c th thu c l
A. 4 B. 7 C. 6 D. 5
Cu 45: Trong s cc polime sau: si bng (1), t tm (2), len (3), t visco (4), t enang (5), t axetat (6), t
nilon-6,6 (7). S t thuc loi poli peptit v poliamit l
A. 3 B. 2 C. 1 D. 4
Cu 46: Cho dy bin ha sau: Xiclo propan
+Br
2
X
1
+NaOH d,t
X
2
+CuO d,t
X
3
. Khi cho 0,1 mol cht X
3
tc dng vi
AgNO
3
d trong dung dch NH
3
, un nng th thu c khi lng Ag l
Cu 47: Cho cc cht sau tc dng vi nhau trong dung dch
1) KI + FeCl
3

2) HI + FeO 3) KI + O
3
+ H
2
O
4) KI + H
2
O
2

5) Pb(NO
3
)
2
+ KI 6) Cl
2
+ KI
7) KI + K
2
Cr
2
O
7
+ H
2
SO
4
long
S phn ng ha hc to ra sn phm I2
l
A. 5. B. 4. C. 7. D. 6.
Cu 48: x phng ho 10 kg cht bo c ch s axit bng 7, ngi ta un cht bo vi dd cha 1,42 kg
NaOH. Sau khi phn ng hon ton, mun trung ho NaOH d cn 500 ml dd HCl 1M. Khi lng x phng
nguyn cht to ra l
Cu 49: Dung dch nc cha 0,005 mol Na
+
; 0,01 mol Cl
-
; 0,005 mol Mg
2+

; 0,01 mol Ca
2+
, a mol HCO
3
. Tnh gi
tr ca a v xc nh xem sau khi un si mt hi lu, nc cn cng khng ?
A. 0,025 ; nc khng cn cng B. 0,025 ; nc cn cng
C. 0,0125 ; nc khng cn cng D. 0,0125 ; nc cn cng
Cu 50: Hp th ht 4,48 (l) buta-1,3-ien (ktc) vo 250ml dd Brom1M, iu kin thch hp n khi brom
mt mu hon ton thu c hn hp lng X (ch cha dn xut brom), trong khi lng sn phm cng 1,4
gp 4 ln khi lng sn phm cng 1,2. Khi lng sn phm cng 1,2 trong X l
A. 6,42g B. 12,84g C. 1,605g D. 16,05g

P N

1B 2C 3D 4A 5A 6C 7C 8B 9B 10C
11C 12C 13A 14A 15D 16A 17D 18C 19A 20A
21D 22B 23C 24C 25A 26A 27B 28D 29C 30D
31B 32D 33B 34A 35D 36D 37A 38B 39D 40C
41D 42D 43A 44B 45D 46A 47A 48C 49C 50A

184 | L O V E B O O K . V N
s 27
Cu 1: Hn hp X gm Al, Cu c khi lng 59g. Ha tan X trong 3 lt dung dch HNO
3
xM c hn hp Y gm
NO, N
2
(mi kim loi ch to mt kh) v li mt cht rn khng tan. Bit d
Y kk
= 1, V
Y
= 13,44 (lt). Tnh khi
lng ca Al, Cu v x.
A. 27g Al; 32g Cu; 1,6M B. 35g Al; 24g Cu; 1,2M C. 27g Al, 32g Cu; 1,4M D. 33,5g Al; 25,5g Cu; 1,6M
Cu 2: Ho tan 11,6 gam hn hp X gm Fe, FeO, Fe2O3 trong dung dch HNO3 d, thu c sn phm kh gm V
lt hn hp kh gm NO v NO2 ( ktc) c t khi so vi hiro bng 19. Mt khc nu un nng X vi CO d th
sau phn ng hon ton thu c 9,52 gam Fe. Gi tr ca V l:
A. 2,24. B. 2,80. C. 4,48. D. 1,12.
Cu 3: hidro ha hon ton 0,025 mol hn hp X gm hai anehit c khi lng 1,64 gam, cn 1,12 lt H
2
(ktc).
Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch AgNO
3
NH
3
th thu c 8,64 gam Ag.
Cng thc cu to ca hai anehit trong X l:
A. CH
2
(CHO)
2
v OHC-CHO B. HCHO v CH
2
(CHO)
2

C. CH
2
= C(CH
3
)CHO v OHC-CHO D. CH
2
= CHCHO v CH
2
(CHO)
2

Cu 4:Cho hn hp X gm hi 3 ru A, B, C vo mt bnh kn dung tch 16 lt cha 13,44 gam oxi. Khi ru bay
hi ht 109,2 th p sut trong bnh l 0,98 atm. Bit sn phm chy gm 3,78 gam nc v 6,16 gam CO
2
.
Trong X ru B v C c s nguyn t C bng nhau v 3n
A
= 5(n
B
+n
C
). Cng thc phn t ca A, B, C ln lt l:
(Bit chng u khng to kt ta vi AgNO
3
NH
3
)
A. CH
3
OH, C
3
H
5
OH, C
3
H
7
OH B. CH
3
OH, C
3
H
3
OH, C
3
H
7
OH
C. C
2
H
5
OH, C
3
H
5
OH, C
3
H
7
OH D. CH
3
OH, C
4
H
9
OH, C
4
H
7
OH
Cu 5: Cho m gam Na vo 100 ml dung dch AlCl3 2M, sau phn ng thu c 7,8 gam kt ta. Gi tr ca m l:
A. 16,1 gam. B. 10,8 gam hoc 6,9 gam. C. 6,9 gam. D. 6,9 gam hoc 16,1 gam.
Cu 6: Cho 14,2 gam P2O5 vo 100 ml dung dch cha hn hp NaOH 1M v KOH 2M thu c dung dch X. Cc
anion c mt trong dung dch X l:
A. H
2
PO
4
v PO
4
3
. B. PO
4
3
v OH
. C. HPO
4
2
v PO
4
3
. D. H
2
PO
4
v HPO
4
2
.
Cu 7: Cho phn ng oxi ha - kh sau: Al + HNO3 Al(NO3)3 + N2 + N2O + H2O. Vi t l mol gia N2 v N2O =
2:3 v h s l cc s nguyn ti gin, th h s ca HNO3 trong phn ng l:
A. 142. B. 162. C. 22. D. 24.
Cu 8: Th t cc cht xp theo chiu tng dn lc axit l:
A. CH3COOH<HCOOH<CH2ClCH2COOH<CH3CHClCOOH.
B. CH2ClCH2COOH<CH3CHClCOOH<CH3COOH<HCOOH.
C. HCOOH<CH3COOH<CH2ClCH2COOH<CH3CHClCOOH.
D. HCOOH<CH3COOH<CH3CHClCOOH<CH2ClCH2COOH.
Cu 9: Ha tan 14,6 gam hn hp X gm Fe, Mg v Al bng 400ml dung dch cha ng thi H
2
SO
4
2M v HCl 1M
thu c dung dch A v kh B. Nhn nh no sau y l ng?
A. Trong A vn cn d axit B. Trong A lng kim loi v axit cng d
C. Trong A khng c axit d D. Ch c H
2
SO
4
phn ng, HCl cn nguyn
Cu 10: Phn t MX
3
c tng s ht proton, notron v electron bng 196, trong s ht mang in nhiu hn
s ht khng mang in l 60. Khi lng nguyn t ca X ln hn ca M l 8. Tng s ht trong X
nhiu hn
trong M
+
l 14. Cng thc ca MX
3
l:
A. CrCl
3
B. FeCl
3
C. AlCl
3
D. SnCl
3

Cu 11: Hp th hon ton 2,688 lt CO2 (ktc) cn va 2,5 lt dung dch hn hp gm Ba(OH)2 a mol/lt v
NaOH 0,04M thu c 15,76g kt ta. Gi tr ca a l:
A. 0,025M. B. 0,02M. C. 0,048M. D. 0,032M.
185 | G S T T G R O U P
Cu 12: t t m gam H2SO4.2SO3 vo 500ml dung dch c pH = 14 gm NaOH v KOH, sau phn ng hon ton
thy dung dch thu c c pH = 0 (coi th tch dung dch khng i sau khi phn ng). Gi tr ca m l:
A. 43 gam. B. 86 gam. C. 129 gam. D. 64,5 gam.
Cu 13: Cho 0,1 mol -aminoaxit X tc dng vi 50 ml dung dch HCl 1 M thu c dung dch A; dung dch A tc
dng vi 250 ml dung dch NaOH 1M thu c dung dch B. C cn dung dch B cn li 20,625 gam cht rn
khan. Cng thc ca X l:
A. HOOCCH2CH2CH(NH2)COOH. B. NH2CH2COOH.
C. CH3CH(NH2)COOH. D. HOOCCH2CH(NH2)COOH.
Cu 14: Cho cc cht sau: (NH4)2CO3; Na2HPO3;KHSO4; CH3COONH3CH3; Glyxin; Al2O3; Zn. S cht lng tnh trong
cc hp cht trn l:
A. 7. B. 5. C. 6. D. 4.
Cu 15:Cho hai hp cht hu c X, Y c cng cng thc phn t l C
3
H
7
NO
2
. Khi phn ng vi NaOH, X to ra
H
2
NCH
2
COONa v hp cht hu c Z; cn Y to ra CH
2
= CHCOOONa v kh T. Cc cht Z v T ln lt l:
A. CH
3
OH v CH
3
NH
2
B. C
2
H
5
OH v N
2
C. CH
3
OH v NH
3
D. CH
3
NH
2
v NH
3

Cu 16: Hn hp X gm Al, Fe2O3, Cu c s mol bng nhau. Hn hp X c th tan hon ton trong dung dch no
sau y?
A. dung dchNH3 d. B. dung dchHCl d. C. dung dchAgNO3 d. D. dung dchNaOH d.
Cu 17: Cho lng kh CO qua ng s ng m gam Fe2O3 nung nng, sau mt thi gian thu c 19,32g hn hp gm Fe,
FeO, Fe3O4, Fe2O3 (hn hp X). Ha tan ht X bng HNO3 c, nng, d thu c 5,824 lt kh NO2 (sn phm kh duy
nht, o ktc). Gi tr ca m l:
A. 23,48g. B. 21,4g. C. 13,24g. D. 26,60g.
Cu 18: Ha tan hon ton hn hp gm 0,12mol FeS2 v a mol Cu2S vo axit HNO3 (va ) thu c dung dch
X (ch cha 2 mui sunfat) v kh NO (sn phm kh duy nht). Cho dung dch X tc dng vi dung dch BaCl2 d
thu c m gam kt ta. Gi tr ca m l:
A. 69,9. B. 46,6. C. 65,24. D. 23,3.
Cu 19: t t FeCl2 vo dung dch AgNO3, sau phn ng thu c kt ta X gm 2 cht rn v dung dch Y. Dung
dch Y ha tan c Cu v dung dch Y lm mt mu dung dch cha KMnO4 (trong mi trng axit). Cc cht
trong dung dch Y l:
A. Ag
+
, Fe
3+
. B. Ag
+
, Fe
2+
. C. Fe
2+
, Fe
3+
. D. Fe
2+
, Fe
3+
v Ag
+
.
Cu 20: Dung dch A cha Ca(OH)2. Cho 0,06 mol CO2 vo dung dch A thu c 4m gam kt ta cn khi cho 0,08
mol CO2 vo dung dch A th thu c 2m gam kt ta. Gi tr ca m l:
A. 1,5 B. 1,0. C. 3,0. D. 2,2.
(a) Anehit va c tnh oxi ha, va c tnh kh.
(b) Phenol tham gia phn ng th brom kh hn benzen.
(c) Anehit tc dng vi H2 (d) c xc tc Ni, un nng, thu c ancol bc I.
(d) Dung dch axit axetic tc dng c vi Cu(OH)2.
(e) Dung dch phenol trong nc lm qu tm ha .
(f) Trong cng nghip, axeton c sn xut t cumen.
S pht biu ng trong s cc pht biu trn l:
A. 5. B. 2. C. 3. D. 4.
Cu 22: Hn hp X gm axit n chc A, ancol n chc B v este E c iu ch t A v B.t chy 9,6 gam hn
hp X thu c 8,64 gam H2O v 8,96 lt kh CO2 (ktc). Bit trong X, ancol B chim 50% v s mol. S mol ancol
B trong 9,6 gam hn hp X l:
A. 0,075. B. 0,08. C. 0,06. D. 0,09.
186 | L O V E B O O K . V N
Cu 23: Chia 11,2 lt hn hp X (ktc) gm 2 hidrocacbon th kh mch h c s lin kt hn km nhau l 1
thnh hai phn bng nhau:
Phn 1: Cho qua 800ml dung dch brom 0,75M. Sau khi kt thc phn ng thy dung dch brom c nng 0,25M
(coi th tch thay i khng ng k)
Phn 2: t chy hon ton hn hp, sn phm chy cho qua dung dch Ba(OH)
2
d thy thu c 118,2 gam kt
ta.
Hai hidrocacbon trong X v % th tch ca chng trong hn hp l:
A. C
2
H
2
(60%) v C
3
H
6
(40%) B. C
2
H
2
(40%) v C
3
H
6
(60%)
C. C
2
H
4
(60%) v C
3
H
4
(40%) D. C
2
H
4
(40%) v C
3
H
4
(60%)
Cu 24: Ha tan hon ton 14,6 gam hn hp X gm Al v Sn bng dung dch HCl (d), thu c 5,6 lt kh H
2

(ktc). Th tch kh O
2
(ktc) cn phn ng hon ton vi 14,6 gam hn hp X l:
A. 3,92 lt B. 1,68 lt C. 2,80 lt D. 4,48 lt
Cu 25: Hn hp P gm a cht hidrocacbon mch A
1
, A
2
, A
a
c dng C
n
H
m
trong m lp thnh mt cp s
cng c tng l 32 v cng sai d
m
= 4. Cc hidrocacbon ny c phn t khi ln lt l M
1
, M
2
, M
a
trong tng
cc khi lng phn t l 212 v t M
1
n M
a1
to thnh mt cp s cng c cng sai d
M
= 16. Cng thc phn
t cc hidrocacbon l:
A. C
2
H
4
, C
3
H
8
, C
4
H
10
, C
5
H
10
B. C
2
H
2
, C
3
H
6
, C
4
H
10
, C
5
H
12

C. C
3
H
4
, C
3
H
8
, C
5
H
12
, C
5
H
8
D. C
2
H
2
, C
3
H
6
, C
4
H
10
, C
6
H
14

Cu 26: X l ancol bc II c cng thc phn t C6H14O. un nng X vi H2SO4 c 170
0
C ch to mt anken duy
nht. Tn ca (X) l:
A. 3,3-imetylbutan-2- ol. B. 2,3-imetylbutan-3-ol.
C. 2,2-imetylbutan-3-ol. D. 2,3-imetylbutan-2-ol.
Cu 27: Cho l km nng 100g vo 100ml dung dch hn hp gm Cu(NO3)2 0,8M v AgNO3 0,2M; sau mt thi
gian ly l kim loi ra nh, sy kh cn c 101,45g (gi thit cc kim loi sinh ra u bm vo l km). Khi
lng km tham gia phn ng l :
Cu 28: Ha tan 16,8g hn hp gm 2 mui M2CO3 v M2SO3 (M l kim loi kim) vo dung dch HCl d, thu c
3,36 lt hn hp kh (ktc). Kim loi kim l:
A. Li. B. Rb. C. K. D. Na.
Cu 29: Cho m gam hn hp M gm 2 axit X, Y (Y nhiu hn X 1 nhm COOH) phn ng ht vi dung dch NaOH
to ra (m+88) gam mui. Nu cho ton b lng M trn tc dng vi lng d dung dch AgNO
3
NH
3
, sau phn
ng thu c 43,2 gam Ag v 13,8 gam mui amoni ca axit hu c. Cng thc ca Y v gi tr ca m ln lt l:
A. HOOC-COOH v 18,2g B. HOOC-COOH v 27,2g C. CH
2
(COOH)
2
v 30g D. CH
2
(COOH)
2
v 19,6g
Cu 30: C cc dung dch ring bit khng dn nhn: NH4Cl, AlCl3, FeCl3, Na2SO4, (NH4)2SO4, NaCl. Thuc th cn
thit nhn bit tt c cc dung dch trn l:
A. dung dchNaHSO4. B. dung dchNaOH. C. dung dchBa(OH)2. D. dung dchBaCl2.
Cu 31: Mt cht hu c X (cha mt loi chc, v ch cha C, H, O). Khi cho 2,9g X phn ng vi dung dch
AgNO3/NH3 d thu c 21,6g Ag. Vy X c th l:
A. CH2(CHO)2. B. OHC CHO. C. HCHO. D. CH3 CHO.
Cu 32: Ha tan ht hn hp X gm Fe v Mg bng mt lng va dung dch HCl 20% thu c dung dch Y.
Nng ca FeCl
2
trong dung dch Y l 15,757%. Nng phn trm ca MgCl
2
trong dung dch Y l:
A. 11,787% B. 84,243% C. 88,213% D. 15,757%
Cu 33: Khi cho dung dch Na2CO3 d vo dung dch cha ion Ba
2+
, Fe
3+,
Al
3+
, NO
3
th kt ta thu c gm:
A. BaCO3, Al(OH)3. B. Al(OH)3, Fe(OH)3.
187 | G S T T G R O U P
C. BaCO3, Al(OH)3, Fe(OH)3. D. BaCO3, Fe(OH)3.
Cu 34: Cho hn hp gm 0,4 mol Fe v 0,2 mol Zn vo 200 ml dung dch hn hp gm Cu(NO3)2 1M v AgNO3
3M. Sau khi phn ng xong, khi lng dung dch gim:
Cu 35: Cho s chuyn ho: C
6
H
5
C CH
+HCl
X
+HCl
Y
+2NaOH
Z. Trong X, Y, Z u l sn phm chnh. Cng
thc ca Z l:
A. C6H5CH2CH2OH. B. C6H5CH(OH)CH2OH. C. C6H5COCH3. D. C6H5CH(OH)CH3.
Cu 36: C 5 dung dch sau: Ba(OH)2, FeCl2, Pb(NO3)2, CuSO4, FeCl3. Khi sc kh H2S qua 5 dung dch trn, c bao
nhiu trng hp c phn ng sinh kt ta?
A. 4. B. 2. C. 1. D. 3.
Cu 37: Ba hp cht hu c X, Y, Z c cng cng thc phn t C3H4O2. X v Y u tham gia phn ng trng bc; X,
Z c phn ng cng hp Br2; Z tc dng vi NaHCO3. Cng thc cu to ca X, Y, Z ln lt l:
A. HCO-CH2-CHO; HCOOCH=CH2; CH2=CH-COOH.
B. HCOOCH=CH2; CH2=CH-COOH; HCO-CH2-CHO.
C. HCOOCH=CH2; HCO-CH2-CHO; CH2=CH-COOH.
D. CH3-CO-CHO; HCOOCH=CH2; CH2=CH-COOH.
Cu 38: Hp cht hu c X c cng thc phn t l C4H6O4. Cho X phn ng vi NaOH un nng to ra mt mui
Y v mt ancol Z. t chy Y th sn phm to ra khng c nc. Cng thc ca X l:
A. HCOOCH2CH2OOCH. B. HOOCCH2COOCH3. C. HOOC-COOC2H5. D. CH3OOC-COOCH3.
(1) Sc kh SO2 vo dung dch K2Cr2O7 trong H2SO4 long.
(2) Sc kh SO2 vo dung dch HNO3 c.
(3) Sc kh SO2 vo dung dch Ca(OH)2.
(4) Cho KMnO4 vo dung dch HCl c.
(5) Cho SiO2 vo dung dch HF.
(6) Cho CrO3 vo dung dch NaOH.
S th nghim c phn ng oxi ha - kh xy ra l:
A. 6. B. 4. C. 3. D. 5.
2
H
7
O
2
N c bao nhiu cht va phn ng c vi dung dch NaOH, va phn
ng c vi dung dch HCl?
A. 1 B. 2 C. 3 D. 4
Cu 41: t chy hon ton 2 lt hn hp kh gm ankin X v hirocacbon Y cn dng 4,5 lt kh O2 sinh ra 3 lt kh
CO2 (cc th tch kh o cng iu kin nhit , p sut). Cng thc phn t ca X v Y ln lt l:
A. C2H2 v CH4. B. C3H4 v CH4. C. C2H2 v C2H4. D. C3H4 v C2H6.
Cu 42:Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C
7
H
8
O
2
, tc dng c vi Na v
NaOH. Bit rng khi cho X tc dng vi Na d, s mol H
2
thu c bng s mol X tham gia phn ng v X ch tc
dng c vi NaOH theo t l mol 1:1. Cng thc cu to thu gn ca X l:
A. CH
3
OC
6
H
4
OH B. CH
3
C
6
H
3
(OH)
2
C. HOC
6
H
4
CH
2
OH D. C
6
H
5
CH(OH)
2

Cu 43: Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht m
khi nhit phn to ra lng O2 t nht l:
A. KMnO4. B. KNO3. C. AgNO3. D. KClO3.
Cu 44: Protein A c khi lng phn t l 50000 vc. Thy phn 100 gam A thu c 33,998 gam alanin. S mt
xch alanin trong phn t A l:
A. 191. B. 382. C. 562. D. 208.
188 | L O V E B O O K . V N
Cu 45: X v Y ln lt l cc tripeptit v hexapeptit c to thnh t cng mt amino axit no, mch h, c mt
nhm COOH v mt nhm NH2. t chy hon ton 0,1 mol X bng O2 va thu c sn phm gm CO2, H2O
v N2 c tng khi lng l 40,5 gam. Nu cho 0,15 mol Y tc dng hon ton vi NaOH (ly d 20% so vi lng
cn thit), sau phn ng c cn dung dch th thu c bao nhiu gam cht rn?
Cu 46: Hirocacbon X c cng thc phn t C6H10. X tc dng vi dung dch AgNO3/NH3 to ra kt ta vng. Khi
hiro ha hon ton X thu c neo-hexan. Tn gi ca X l:
A. 2,2-imetylbut-3-in. B. 2,2-imetylbut-2-in. C. 3,3-imetylbut-1-in. D. 3,3-imetylpent-1-in.
Cu 47: Thy phn 95,76g saccaroz trong mi trng axit vi hiu sut phn ng t 75% thu c hn hp X.
Trung ha axit trong X bng NaOH thu c hn hp Y. Cho Y tc dng vi dung dch AgNO3/NH3 d un nng
thu c m gam Ag kt ta. Gi tr ca m l:
Cu 48: Cho x mol Fe tc dng vi dung dch cha y mol HNO3 to ra kh NO (sn phm kh duy nht) v dung
dch X cha cc ion Fe
3+
, Fe
2+
, NO
3
. Biu thc lin h gia x v y l:

.
y
4
< <
3y
8
. x =
y
4
. x >
3y
8
.
y
8
< <
y
4

Cu 49: Khi cho 0,15 mol este n chc X tc dng vi NaOH d phi dng ht 12 gam NaOH v tng khi lng
sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tha mn l:
A. 5. B. 2. C. 4. D. 6.
Cu 50: Trong bng tun hon cc nguyn t ho hc, nguyn t X nhm IIA, nguyn t Y nhm VA. Cng thc
ca hp cht to thnh t 2 nguyn t trn c dng:
A. X5Y2. B. X2Y5. C. X3Y2. D. X2Y3.

P N

1A 2B 3D 4A 5D 6D 7B 8B 9A 10C
11D 12A 13D 14D 15C 16B 17B 18A 19C 20B
21D 22B 23A 24A 25D 26A 27A 28D 29C 30C
31B 32A 33C 34A 35C 36D 37C 38D 39B 40B
41A 42C 43C 44A 45D 46C 47C 48A 49C 50C

189 | G S T T G R O U P
s 28

Cu 1.em nung hn hp A gm 2 kim loi: x mol Fe v 0,15 mol Cu trong khng kh mt thi gian, thu c 63,2
gam hn hp B, gm 2 kim loi trn v hn hp cc oxit ca chng. em hon tan ht lng hn hp B trn bng
dung dch H
2
SO
4
m c th thu c 0,3 mol SO
2
. Gi tr ca x l:
Cu 2. Trn 100ml dung dch c pH=1 gm HCl v HNO3 vi 100ml dung dch NaOH nng a (mol/l) thu c
200ml dung dch c pH=12. Gi tr ca a l (bit trong mi dung dch [H
+
][OH
]=10
-14
)
A. 0,03 B. 0,30 C. 0,12 D. 0,15
Cu 3.Thy phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100000 vC th s
mt xch alanin c trong phn t X l:
A. 453 B. 382 C. 328 D. 479
Cu 4.Hp cht hu c X c cng thc phn t C8H11N, X tan c trong axit. Cho X tc dng vi HNO2 to ra hp
cht Y c cng thc phn t C8H10O. un nng Y vi dung dch H2SO4 c to ra hp cht Z. Trng hp Z thu c
polistiren. S ng phn ca X tha mn l
A. 3 B. 2 C. 1 D. 4
Cu 5. Cho hn hp A gm Al, Fe vo dung dch B c cha Cu(NO3)2 v AgNO3. Sau khi phn ng xy ra hon ton
thu c dung dch C; Cho dung dch NaOH d vo C c kt ta D gm hai hiroxit kim loi. Trong dung dch C
c cha
A. Al(NO3)3, Fe(NO3)2 v Cu(NO3)2 B. Al(NO3)3 v Fe(NO3)2
C. Al(NO3)3 v Fe(NO3)3 v Fe(NO3)2 D.Al(NO3)3 v Fe(NO3)3
Cu 6.in phn 100 ml dung dch CuSO4 1M vi in cc tr trong thi gian 25 pht 44 giy, cng dng
in l 5A th dng li. Khi lng dung dch gim l
Cu 7. Cho phn ng CO(k) + H2O(k) CO2 (k) + H2 (k) (H <0)
Trong cc yu t: (1) tng nhit , (2) thm lng CO, (3) thm mt lng H2, (4) gim p sut chung ca h,
(5) dng cht xc tc. S yu t lm chuyn dch cn bng l
A. 2. B. 4. C. 3. D. 5.
Cu 8. Thy phn hon ton mt cht bo bng dung dch NaOH, sau phn ng thu c 2,78 gam C15H31COONa;
m2 gam C17H31COONa v m3 gam C17H35COONa. Gi tr ca m2 v m3 ln lt l
A.3,02 gam v 3,05 gam B. 6,04 gam v 6,12 gam
Cu 9.C bao nhiu cht hoc dung dch sau y cho phn ng vi nc brm: glucoz, fructoz, saccaroz,
mantoz, ancol etylic, anehit axetic, axit fomic, axit benzoic, phenol v anilin?
A.6 B. 5 C. 7 D. 8
Cu 10. - Cho a gam Fe ( d) vo V1 lit Cu(NO3)2 1M thu c m gam rn.
- Cho a gam Fe (d) vo V2 lit AgNO3 1M, sau phn ng thu c m gam rn.
Mi lin h V1 v V2 l
A. 10V1 = V2 B. V1 = 10V2 C. V1 = 2V2 D. V1 = V2
Cu 11. Hn hp X gm axetilen, etilen v hidrocacbon A chy hon ton thu c CO2 v H2O theo t l mol 1:1.
Dn X i qua bnh ng dung dch brom d thy khi lng bnh tng ln 0,82 gam, kh thot ra khi bnh em
t chy hon ton thu c 1,32 gam CO2 v 0,72 gam H2O. % V ca A trong X l
A. 75 B. 50 C. 33,33 D. 25
Cu 12.Nhit si ca cc cht CH3Cl, CH3OH, HCOOH, CH4 tng theo th t l
A.CH4 < CH3OH < HCOOH < CH3Cl. B. CH4< CH3Cl < CH3OH < HCOOH.
C. CH3Cl < CH4< CH3OH < HCOOH. D. CH3Cl < CH3OH < CH4< HCOOH.
Cu 13. Cho dy cht: phenyl clorua, sec-butylclorua, natriphenolat, phenylamoni clorua, tinh bt, amoni axetat,
crezol. S cht trong dy khng tc dng vi dung dch NaOH long nhit thng l
190 | L O V E B O O K . V N
A.3 B. 6 C.5 D. 4
Cu 14. Ngi ta iu ch etyl axetat t xenluloz v cc cht v c theo s sau: xenluloz glucoz
ancol etylic axit axetic etyl axetat. Tnh khi lng xenluloz cn dng c th iu ch c 1 mol etyl
axetat. Bit hiu sut chung ca qu trnh t 40%.
A. 162 gam B. 405 gam C. 202,5 gam D. 506,25 gam
Cu 15. t chy hon ton 2,24 lt (ktc) hn hp kh gm: CH4, C2H4, C2H6, C3H8 thu c 6,16 gam CO2 v 4,14
gam H2O. S mol C2H4 trong hn hp trn l
Cu 16. Ho tan ht m gam Al2(SO4)3 vo nc c dung dch X. Cho 360 ml dung dch NaOH 1M vo dung dch
X, thu c 2a gam kt ta. Mt khc, nu cho 400 ml dung dch NaOH 1M vo dung dch th thu c a gam kt
ta. Cc phn ng xy ra hon ton, gi tr ca m l
A. 19,55. B. 15,39. C. 20,52. D. 18,81.
Cu 17. Hirocacbon X chy cho th tch hi nc gp 1,2 ln th tch CO2 (o cng iu kin). Khi tc dng vi
clo to mt dn xut monoclo duy nht. X c tn l
A.etan. B.propan. C.isobutan. D. 2,2- imetylpropan
Cu 18. Hin tng no xy ra trong th nghim sau: Cho 0,1 mol Na vo 100 ml dung dch cha CuSO4 1M v
H2SO4 1M (long)?
A. Ch c kh bay ln.
B. Ch c kt ta.
C. C kh bay ln v c kt ta mu xanh.
D. C kh bay ln v c kt ta mu xanh sau kt ta li tan.
Cu 19. xc nh ru ca dung dch ancol etylic (X) ngi ta ly 10ml dung dch X cho tc dng vi Na d thu
c 2,564 lt H2 (ktc). Tnh ru ca X (bit ancol etylic nguyn cht c d=0,8g/ml, nc c d=1g/ml).
A.85,58
0
B. 91,0
0
C. 92,5
0
D. 87,5
0

Cu 20. Ln men 45 gam glucoz thy c 4,48 lt CO2 (ktc) bay ra v cn hn hp cht hu c X gm C2H5OH v
glucoz d. t chy hon ton X th s mol CO2 thu c l
A.1,3 mol B. 1,2 mol C. 1,5 mol D. 1,15 mol
Cu 21. Hn hp X gm Al, Fe2O3 c khi lng 21,67 gam. Tin hnh phn ng nhit nhm hn hp X trong iu
kin khng c khng kh. Ha tan hon ton hn hp cht rn sau phn ng bng dung dch NaOH d thu c
2,016 lt H2 (ktc) v 12,4 gam cht rn khng tan. Hiu sut ca phn ng nhit nhm l
A. 80% B. 75% C. 60% D. 71,43%
Cu 22. Cho 17,9 gam hn hp gm Fe, Cu v Al vo bnh ng 200 gam dung dch H2SO4 24,01%. Sau khi cc
phn ng xy ra hon ton, thu c 9,6 gam cht rn v c 5,6 lt kh (ktc) thot ra.Thm tip vo bnh 10,2
gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng
mui trong dung dch l
A.2,688 lt v 59,18 gam B.2,24 lt v 59,18 gam C. 2,688 lt v 67,7 gam D. 2,24 lt v 56,3 gam
Cu 23.Cho cc cht sau: CH3COOCH2CH2Cl, ClH3N-CH2COOH, C6H5Cl (thm), HCOOC6H5 (thm), C6H5COOCH3
(thm), HO-C6H4-CH2OH (thm), CH3CCl3, CH3COOC(Cl2)-CH3. C bao nhiu cht khi tc dng vi NaOH c d,
nhit v p sut cao cho sn phm c 2 mui?
A.7 B. 4 C. 5 D. 6
Cu 24.Phng php iu ch polime no sau y l ng?
A. ng trng hp axit terephtalic v etylen glicol iu ch c poli(etylen-terephtalat)
B. Trng hp caprolactam to t nilon-6
C. Trng hp ancol vinylic iu ch poli(vinyl ancol)
D. ng trng ngng buta-1,3-ien v vinylxianua iu ch cao su buna-N
Cu 25. Cho V lt (ktc) hn hp kh gm 2 olefin lin tip nhau trong cng dy ng ng hp nc (xc tc H
+
)
thu c 12,9 gam hn hp X gm 3 ancol. un nng X trong H2SO4 c 140
0
C thu c 10,65 gam hn hp Y
gm 6 ete khan. Gi s hiu sut cc phn ng l 100%. Cng thc phn t ca 2 olefin v gi tr ca V l
191 | G S T T G R O U P
A. C2H4, C3H6, 5,6 lt B. C4H8, C5H10, 5,6 lt C. C3H6, C4H8, 4,48 lt D. C2H4, C3H6, 4,48 lt
Cu 26.Cho Cacbon (C) ln lt tc dng vi Al, H2O, CuO, HNO3 c, H2SO4 c, KClO3, CO2 iu kin thch
hp. S phn ng m trong C ng vai tr l cht kh?
A. 6. B.4. C.5. D.7.
Cu 27. C 5 dung dch ring bit l: CuCl2, FeCl3, AgNO3, HCl v HCl c ln CuCl2. Nhng vo mi dung dch mt
thanh Fe nguyn cht. S trng hp xut hin n mn in ha l
A. 3 B. 4 C. 2 D. 1
Cu 28. Cho cc phn ng ha hc sau:
(1) (NH4)2SO4 + BaCl2 (2) CuSO4 + Ba(NO3)2
(3) Na2SO4 + BaCl2 (4) H2SO4 + BaSO3
(5) (NH4)2SO4 + Ba(OH)2 (6) Fe2(SO4)3 + Ba(NO3)2
Cc phn ng u c cng 1 phng trnh ion rt gn l
A. (1), (2), (3), (6) B. (2), (3), (4), (6) C. (1), (3), (5), (6) D. (3), (4), (5), (6)
Cu 29. X l este c to bi axit 2 chc, mch h v ancol no, 2 chc, mch h c cng thc n gin nht l
C3H2O2. hidro ha hon ton 1 mol X (xc tc Ni, t
0
) cn bao nhiu mol H2?
A.2 mol B.4 mol C. 3 mol D.1 mol
Cu 30. Nung 13,4 gam hn hp 2 mui cacbonat ca hai kim loi ho tr 2, thu c 6,8 gam cht rn v kh X.
lng kh X sinh ra cho hp th vo 75 ml dung dch NaOH 1M, khi lng mui khan thu c sau phn ng l
A. 6,5 g B. 4,2 g C. 5,8 g D. 6,3 g
Cu 31.A, B, D l 3 hp cht thm c cng thc phn t l C7H6Cl2. Khi un nng vi dung dch NaOH long, th A
phn ng theo t l mol 1: 2, B phn ng theo t l mol 1:1, cn D khng phn ng. S ng phn cu to ca A,
B, D l
A. 1, 3, 4 B. 1, 2, 3 C. 1, 3, 5 D. 1, 3, 6
Cu 32.Cho 28,2 gam hn hp hai ancol n chc tc dng ht vi 11,5 gam Na, sau phn ng thu 39,3 gam cht
rn. Nu un 28,2 gam hn hp trn vi H2SO4 c 140
0
C, th thu c bao nhiu gam ete
A. 23,7 gam B.19,2 gam C. 24,6 gam D. 21,0 gam
Cu 33. Cho cc dung dch sau: NaOH, BaCl2, KHSO4, Al2(SO4)3, (NH4)2SO4. phn bit cc dung dch trn, dng
thuc th no trong s cc thuc th sau th s cn tin hnh t th nghim nht?
A. H2SO4 B. KOH C. Qu tm D. Ba(OH)2
Cu 34. Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng ddung dch HCl
c, cht to ra lng kh Cl2 nhiu nht l
A. KMnO4. B. K2Cr2O7. C. CaOCl2. D. MnO2.
Cu 35.Phn ng no sau y chng t Fe
2+
c tnh kh yu hn so vi Cu?
A. Fe + Cu
2+
Fe
2+
+ Cu B. Fe
2+
+ CuCu
2+
+ Fe
C. Cu
2+
+ 2Fe
2+
2Fe
3+
+ Cu D. 2Fe
3+
+ Cu 2Fe
2+
+ Cu
2+
Cu 36.Hn hp A gm 2 axit cacboxylic n chc X, Y. Cho 13,4 gam A ha tan ht vo nc ri cho tc dng vi
AgNO3/NH3 d c 21,6 gam Ag. Mt khc cng lng hn hp trn trung ha va vi 100 ml dung dch
NaOH 2M. Cng thc cu to ca X, Y l
A. HCOOH, CH3COOH B. CH3COOH, C2H5COOH
C. HCOOH, C2H5COOH D. HCOOH, C3H7COOH
Cu 37. Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste
c to ra ti a l
A. 8. B.4. C. 6. D. 3.
Cu 38. Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn t ca nguyn t Y cng
c electron mc nng lng 3p v c mt electron lp ngoi cng. Nguyn t X v Y c s electron hn km
nhau l 2. Nguyn t X, Y ln lt l
A. kim loi v kh him. B. kim loi v kim loi.
C. phi kim v kim loi. D. kh him v kim loi.
192 | L O V E B O O K . V N
Cu 39. Cho 8,04 gam hn hp hi gm CH3CHO v C2H2 tc dng hon ton vi dung dch AgNO3/NH3 thu c
55,2 gam kt ta. Cho kt ta ny vo dung dch HCl d, sau khi kt thc phn ng cn li m gam cht khng tan.
Gi tr ca m l
A. 61,78 B. 55,2 C. 21,6 D. 41,69
Cu 40. Ha tan 19,5 gam hn hp gm Na2O v Al2O3 trong nc thu c 500 ml dung dch A trong sut. Thm
dn dung dch HCl 1M vo dung dch A n khi xut hin kt ta th dng li thy th tch dung dch HCl cn dng
l 100 ml. Phn trm s mol mi cht trong A ln lt l
A.45% v 55% B. 25% v 75% C. 30% v 70% D. 60 % v 40%
Cu 41. Hn hp X gm phenol v anilin. Ly m gam X tc dng va vi 200 ml dung dch HCl 1M thu c
hn hp Y. Cho hn hp Y tc dng ht vi 500 ml dung dch NaOH 1M, ri c cn thy cn li 31,3 gam cht rn
khan. Gi tr ca m l
A. 18,7 B. 28 C. 65,6 D. 14
Cu 42. Cc nguyn t thuc nhm IA, theo chiu tng dn ca in tch ht nhn th
A. Bn knh nguyn t tng dn. B.Tnh kh gim dn.
C. Nng lng ion ho tng dn. D. m in tng dn.
Cu 43.Khi lng tripeptit c to thnh t 178 gam alanin v 75 gam glyxin l
A.199g B.235g C.217g D.253 g
Cu 44.Cho Na tc dng vi 100ml dung dch AlCl3 thu c 5,6 lt H2(ktc) v kt ta. Lc kt ta ri em nung
n khi lng khng i thu c 5,1 gam cht rn. Nng mol/l ca dung dch AlCl3 l
A. 1,5M. B. 1,0M. C. 2,5M. D. 2,0M.
Cu 45. Dung dch Y gm Al
3+
; Fe
2+
; 0,05 mol Na
+
; 0,1 mol SO
4
2
; 0,015 mol Cl
. Cho V lt dung dch NaOH 1M vo

dung dch Y thu c kt ta ln nht th gi tr ca V l
A. 0,30. B. 0,40. C. 0,165. D. 0,35.
Cu 46. Cho x gam P2O5 tc dng ht vi 388 ml dung dch NaOH 2M. C cn dung dch sau phn ng thu c 3x
gam cht rn. Gi tr ca x l
A. 17,04. B. 14,2. C. 11,36. D. 12,78.
Cu 47.Fomalin hay fomon (dng bo qun xc ng vt chng thi ra) l
A. Dung dch HCHO 25%- 30% v th tch trong nc
B. Ancol C2H5OH 46
o

C. Dung dch CH3CHO 40% v th tch trong nc
D. Dung dch HCHO 37%-40% v khi lng trong nc
Cu 48. t chy hon ton hn hp gm 2 este no, h, n chc cn 5,68 g kh oxi v thu c 3,248 lt kh CO2
(ktc). Cho hn hp este trn tc dng va vi KOH thu c 2 ancol l ng ng k tip v 3,92 g mui ca
mt axit hu c. Cng thc cu to ca 2 este l
A. C3H7COOCH3 v CH3COOC2H5. B. HCOOCH3 v HCOOC2H5.
C. CH3COOCH3 v CH3COOC2H5. D. C2H5COOCH3 v C2H5COOC2H5.
Cu 49.Tng s proton trong ht nhn nguyn t X v Y l 25. Y thuc nhm VIIA. dng n gin n cht X tc
dng vi Y. Khng nh no sau y ng?
A. Cng thc oxit cao nht ca X l Y2O. B.X l kim loi, Y l phi kim.
C. Cng thc oxit cao nht ca X l XO3. D. trng thi c bn X c 2 electron c thn.
Cu 50. Cho kh H2S tc dng vi cc cht: dung dch NaOH, kh clo, nc clo, dung dch KMnO4/H
+
, kh oxi d un
nng, dung dch FeCl3, dung dch ZnCl2, Pb(NO3)2, KClO3. S trng hp xy ra phn ng v s trng hp trong
lu hunh b oxi ha ln S
+6
l
A. 6 v 1 B. 9 v 3 C. 8 v 1 D. 6 v 2

193 | G S T T G R O U P
1A 2C 3B 4B 5A 6A 7C 8C 9A 10B
11D 12B 13D 14B 15C 16D 17D 18A 19A 20A
21B 22C 23C 24B 25A 26D 27A 28A 29A 30D
31A 32C 33C 34B 35D 36D 37C 38C 39A 40D
41B 42A 43C 44A 45C 46C 47D 48C 49D 50C

194 | L O V E B O O K . V N
s 29

Cu 1: Ngi ta tin hnh cc th nghim sau:
Th nghim 1: Cho 0,1 mol ancol X mch h vi 0,2 mol ancol Y mch h tc dng vi Na d thu c 5,6 lt H
2

(ktc).
Th nghim 2: Cho 0,2 mol ancol X vi 0,1 mol ancol Y tc dng vi Na d thu c 7,84 lt H
2
(ktc).
Th nghim 3: Cho hn hp E gm 0,2 mol X v 0,1 mol Y em t chy hon ton thu c 35,2 gam CO
2
.
Vy X, Y l:
A. Ancol propylic v etilenglicol B. Propan 1, 2 iol v ancol etylic
C. Glixerol v ancol etylic D. Glixerol v ancol metylic
Cu 2: Thu phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32gam
Ala-Ala v 27,72 gam Ala-Ala-Ala.Gi tr m l
A. 88,2 B. 81,54 C. 90,6 D. 111,74
Cu 3: Hn hp X c khi lng 9,28 gam gm N2 v H2 (N2 c ly d so vi H2). Nung nng X mt thi gian
trong bnh kn c xc tc thu c hn hp kh Y c t khi so vi He bng 2,68. Bit hiu sut ca phn ng tng
hp NH3 t 28%. Thnh phn phn trm v khi lng ca hn hp X l
A. 84,48% v 15,52% B. 90,52% v 9,48% C. 28% v 72% D. 30% v 70%
Cu 4:Hp cht M c to thnh t cation X
+
v anion Y
2
. Mi ion u do 5 nguyn t ca hai nguyn t to
nn. Tng s proton trong X
+
l 11, tng s electron trong Y
2
l 50. Bit rng 2 nguyn t trong Y
2
thuc cng
mt phn nhm v thuc 2 chu k lin tip nhau trong bng tun hon. M c cng thc phn t l:
A. (NH
4
)
3
PO
4
B. NH
4
IO
4
C. NH
4
ClO
4
D. (NH
4
)
2
SO
4

Cu 5:Hn hp X gm mt ancol v mt axit hu c. Chia X thnh 3 phn bng nhau:
Cho phn 1 tc dng ht vi Na thu c 3,36 lt kh khng mu (ktc).
t chy hon ton phn 2 thu c 39,6 gam CO
2
.
Thc hin phn ng este ha phn 3 thu c este Y. t chy hon ton 15,3 gam Y thy to thnh 16,8 lt CO
2

(ktc) v 13,5 gam H
2
O.
S cng thc cu to c th c ca Y l:
A. 4 B. 6 C. 8 D. 9
Cu 6: Cho tng cht C, Fe, BaCl2, , Fe3O4, FeCO3, FeS, H2S, HI, AgNO3, HCl, Na2SO3, FeSO4 ln lt tc dng vi H2SO4
c, nng. S phn ng thuc loi phn ng oxi ha - kh l:
A. 7 B. 6 C. 9 D. 8
Cu 7: Dy gm cc cht no sau y u c tnh lng tnh?
A. ZnCl2, AlCl3, NaAlO2, NaHCO3, H2NCH2COOH
B. AlCl3, H2O, NaHCO3, Zn(OH)2, ZnO
C. Al, NaHCO3, NaAlO2, ZnO, Be(OH)2
D. H2O, Zn(OH)2, HOOC-COONa, H2NCH2COOH, NaHCO3
Cu 8: Cho cc dung dch mui sau: Na2CO3, AlCl3, C6H5ONa, CH3COOK, CH3NH3Cl, CuSO4, NaHCO3, NH4NO3, BaCl2,
K2SO4, C2H5ONa, NaAlO2. S dung dch mui c mi trng khng phi trung tnh l:
A. 9 B. 12 C. 10 D. 11
Cu 9: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin (3); p-metylanilin (4); metylamin (5); imetylamin (6).
Th t tng dn lc baz ca cc cht l:
A. (2) < (3) < (4) < (1) < (5) < (6) B. (3) < (2) < (4) < (1) < (5) < (6)
C. (2) > (3) > (4) > (1) > (5) > (6) D. (3) < (1) < (4) < (2) < (5) < (6)
Cu 10: Cho dung dch amoniac 1M c in li l 0,43%. Hng s bazo v pH ca dung dch l:
A. K
b
= 3,714.10
5
v pH = 2,37 B. K
b
= 3,24.10
1
v pH = 13,63
C. K
b
= 1,857.10
5
v pH = 11,63 D. K
b
= 1,857.10
5
v pH = 2,37
Cu 11: Hp cht X c to ra t ancol n chc v amino axit cha mt chc axit v mt chc amin. X c cng
thc phn t trng vi cng thc n gin nht. t chy hon ton 0,89 gam X cn va 1,2 gam O2 v to
195 | G S T T G R O U P
ra 1,32 gam CO2, 0,63 gam H2O. Khi cho 0,89 gam X tc dng vi 200 ml dung dch NaOH 1M ri c cn th khi
lng cht rn khan thu c l
Cu 12: Cho 0,1 mol hp cht ha c c cng thc phn t CH6O3N2 tc dng vi dung dch cha 0,2 mol NaOH un nng,
sau khi phn ng xy ra hon ton thu c cht kh lm xanh giy qu tm m v dung dch Y. C cn dung dch Y thu c
m gam rn khan. Gi tr ca m l
A. 21,8 B. 12,5 C. 8,5 D. 15
Cu 13: Cho cn bng sau: CH
3
COOH+C
2
H
5
OH CH
3
COOC
2
H
5
+H
2
O, K
C
= 4
Khi cho 1 mol axit tc dng vi 1,6 mol ancol, khi h t n trng thi cn bng th hiu sut ca phn ng l
A. 50% B. 66,67% C. 33,33% D. 80%
Cu 14: Cho 30 gam hn hp gm 2 cht hu c A v B mch h ch c nhm chc OH v COOH, trong A c
2 nhm chc khc nhau v B ch c mt nhm chc tc dng ht vi Na kim loi gii phng 6,72 lt H
2
(ktc). Mt
khc, nu trung ha 30 gam hn hp trn cn 0,8 lt dung dch NaOH 0,5M. Khi t chy A cng nh B u thu
c n
CO
2
= n
H
2
O
. Bit gc hidrocacbon trong A ln hn trong B. Cho bit cng thc cu to ca A v B?
A. CH
2
(COOH)
2
, CH
3
COOH B. HO(CH
2
)
2
COOH, CH
3
COOH
C. (COOH)
2
, CH
3
COOH D. Kt qu khc
Cu 15: Nhn xt no sau y khng ng?
A. Khi in phn dung dch NaCl c mng ngn ta thu c kh H2 Ant
B. Cu, Fe, Ni l nhm kim loi c th iu ch c theo c 3 phng php: thu luyn, nhit luyn, in phn.
C. lm gim nhit nng chy ca Al2O3, khi in phn nng chy Al2O3 ngi ta cho thm 3NaF.AlF3 vo.
D. S khc nhau v bn cht gia n mn ho hc v n mn in ho l cch dch chuyn electron t kim loi
n mn sang mi trng.
Cu 16: Khi cho mt loi cao su Buna-S tc dng vi brom(trong CCl4) ngi ta nhn thy c 1,05 gam cao su
c th tc dng ht vi 0,8g brom. T l gia s mt xch butadien v stiren trong loi cao su ni trn l
A. 3:4 B. 3:2 C. 2:3 D. 4:4
Cu 17: Nhm cc vt liu c iu ch t polime to ra do phn ng trng hp l
A. T nilon-6,6, poli(metyl metacrylat) , thu tinh plexiglas, t nitron
B. Cao su, t lapsan, thu tinh plexiglas, poli(vinyl) clorua, t nitron
C. T lapsan, t axetat, thu tinh plexiglas, poli(vinyl) clorua, polietilen
D. Cao su, t capron , thu tinh plexiglas, poli(vinyl) clorua, t nitron
Cu 18: Cho phng trnh phn ng: 2A(k) + B (k) 2X (k) + 2Y(k). Ngi ta trn 4 cht, mi cht 1 mol vo
bnh kn dung tch 2 lt (khng i). Khi cn bng, lng cht X l 1,6 mol. Hng s cn bng ca phn ng ny l
A. 33,44. B. 29,26 C. 58,51 D. 40,96.
Cu 19: Ch dng thm Cu(OH)2 c th phn bit c tt c cc dung dch ring bit sau trong dy no sau y?
A. Glucoz, mantoz, glixerol, anehit axetic
B. Glucoz, glixerol, lng trng trng, ancol etylic
C. Lng trng trng, glucoz, fructoz, glixerol
D. Saccaroz, glixerol, anehit axetic, ancol etylic
Cu 20: Cho phn ng: K2Cr2O7 + K2SO3 + KHSO4 K2SO4 + Cr2(SO4)3 + H2O. Sau khi cn bng tng cc h s
(nguyn, ti gin) ca phng trnh thu c l:
A. 41 B. 21 C. 19 D. 25
Cu 21: t chy hon ton mt hn hp X (gm glucoz, anehit fomic, axit axetic) cn 2,24 lt O2 (ktc). Dn
sn phm chy qua bnh ng dung dch Ca(OH)2 (d), thy khi lng bnh tng m gam. Gi tr ca m l
A. 3,1 B. 12,4 C. 4,4 D. 6,2
Cu 22: Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X); HOCH2-CH2-CH2OH (Y); HOCH2-CHOH-
CH2OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CHOH-CH2OH (T). Nhng cht tc dng c vi Cu(OH)2 to thnh
dung dch mu xanh lam l
A. Z, R, T B. X, Z, T C. X, Y, R, T D. X, Y, Z, T
196 | L O V E B O O K . V N
Cu 23: Qu trnh sn xut amoniac trong cng nghip da trn phn ng thun nghch sau:
N2(k) + 3H2(k) 2NH3(k). H = -92 kJ
Khi phn ng t ti trng thi cn bng, nhng thay i no di y lm cho cn bng chuyn dch theo chiu
thun to ra nhiu amoniac: (1) Tng nhit ; (2) Tng p sut; (3) Thm cht xc tc; (4) Gim nhit ; (5)
Ly NH3 ra khi h
A. (2), (3), (4), (5). B. (2), (3), (5). C. (1), (2), (3), (5). D. (2), (4), (5).
Cu 24: Cho s sau:
MnO2 + HCl c(t
0
) kh X + (1) ; Na2SO3 + H2SO4 (c, t
0
) kh Y + (2) ;
NH4Cl + NaOH (t
0
) kh Z + .(3) ; NaCl (r) + H2SO4 (c, t
0
cao) kh G + . (4) ;
Cu + HNO3 (c, nng) kh E + . (5) ; FeS + HCl (t
0
) kh F + . (6) ;
Nhng kh tc dng c vi dung dch NaOH iu kin thng l?
A. X, Y, G, E, F B. X, Y, Z,G C. X, Y, G D. X, Y, Z, G, E, F
Cu 25: Cho hn hp kh X (gm 0,009 mol NO2 v 0,0015 mol O2) phn ng hon ton vi nc thu c dung
dch Y (cha mt cht tan) v V ml (ktc) kh khng mu duy nht. Trn Y vi dung dch cha 0,01 mol NaOH thu
c 200 ml dung dch Z. Ga tr ca V v pH ca dung dch Z ln lt l
A. 67,2 v 12,3 B. 67,2 v 12 C. 22,4 v 2 D. 22,4 v 12
Cu 26: Trong mt bnh kn cha hn hp M gm hidrocacbon X v H
2
vi Ni. Nung nng bnh mt thi gian ta
thu c mt kh N duy nht. t chy N, thu c 8,8 gam CO
2
v 5,4 gam H
2
O. Bit V
M
= 3V
N
. Cng thc ca X
l:
A. C
3
H
4
B. C
3
H
8
C. C
2
H
2
D. C
2
H
4

Cu 27: Hon tan hon ton 5,94 gam hn hp 2 mui clorua ca 2 kim loi u thuc nhm IIA vo nc c
dung dch X. kt ta ht ion Cl
c trong dung dch X ngi ta cho ton b lng dung dch X trn tc dng
va vi dung dch AgNO
3
. Kt thc th nghim, thu c dung dch Y v 17,22 gam kt ta. C cn dung dch Y,
khi lng mui khan thu c l:
Cu 28: Cho dng H2 i qua ng s ng 0,2 mol hn hp FeO v Fe2O3 nung nng sau mt thi gian thu c 1,89
gam H2Ov 22,4 gam hn hp cht rn X. Ho tan hon ton cht rn X trong dung dch HNO3 thu c V lit kh
NO (ktc) l sn phm kh duy nht. Gi tr ca V l
A. 2,24 B. 0,75 C. 3,73 D. 4,48
Cu 29: R l nguyn t m nguyn t c phn lp electron ngoi cng l np
2n+1
(n l s th t ca lp electron).
C cc nhn xt sau v R:
(I) Tng s ht mang in ca nguyn t R l 18.
(II) S electron lp ngoi cng trong nguyn t R l 7.
(III) Cng thc ca oxit cao nht to ra t R l R2O7.
(IV) Dung dch NaR tc dng vi dung dch AgNO3 to kt ta.
S nhn xt ng l:
A. 1 B. 4 C. 2 D. 3
Cu 30: t 15,2 gam hn hp X gm Cu v Fe trong kh Cl2 thu c hn hp cht rn Y. Cho Y vo nc d, thu
c dung dch Z v 3,2 gam kim loi. Dung dch Z tc dng c vi ti a 0,1 mol KMnO4 trong dung dch H2SO4
(khng to ra SO2). Phn trm khi lng ca Fe trong hn hp X l
A. 72,915% B. 64,00% C. 36,842% D. 66,667%
Cu 31: Cho 5,04 lt (ktc) hn hp kh X gm C2H2 v H2 qua bt niken nung nng thu c hn hp Y ch cha
3 hirocacbon. Y c t khi so vi H2 l 14,25. Cho Y tc dng vi dung dch nc brom d. S mol brom phn ng
l
A. 0,075 B. 0,225 C. 0,75 D. 0,0225
Cu 32: A l hn hp kh gm SO2 v CO2 c t khi hi so vi H2 l 27. Dn a mol hn hp kh A qua bnh ng 1
lt dung dch NaOH 1,5a M, sau phn ng c cn dung dch thu c m gam mui. Biu thc lin h gia m v a l
A. m=116a B. m=141a C. m=105a D. m=103.5a
197 | G S T T G R O U P
Cu 33: Cho 6,9 gam hn hp X gm 2 ancol no, n chc (Y v Z) tc dng vi Na d thu c 1,68 lt H2(ktc).
Cn khi oxi ho 6,9 gam hn hp X bi CuO d, nung nng thu c hn hp T gm 2 sn phm hu c tng
ng vi Y v Z. Cho T tc dng vi lng d dung dch AgNO3 trong NH3 th thu c 43,2 gam Ag. Cng thc hai
ancol trong axit l:
A. CH3OH v CH3CH(CH3)CH2OH B. CH3OH v CH3CH(OH)CH2CH3
C. CH3CH2OH v CH3CH2CH3OH D. CH3OH v CH3CH(OH)CH3
Cu 34: Cho s : X
+2H
2
Y
+CuO
Z
+O
2
Axit 2-metylpropanoiC. X c th l cht no?
A. OHC C(CH3) CHO B. CH3CH(CH3)CH2OH
C. CH3 CH(CH3) CHO D. CH2 = C(CH3) CHO
Cu 35: Trong s cc cht: H2O, CH3COONa, Na2HPO3, NaH2PO3, Na2HPO4, NaHS, Al2(SO4)3, NaHSO4, CH3COONH4,
Al(OH)3, ZnO, CrO, HOOC-COONa, HOOC-CH2NH3Cl, s cht lng tnh l
A. 8. B. 9. C. 10. D. 7.
K2Cr2O7 + 14HBr 3Br2 + 2KBr + 2CrBr3 + 7H2O
Br2 +2NaI 2NaBr + I2
Khng nh no sau y l ng?
A. Tnh oxi ho: I2> Br2 B. Tnh oxi ho: I2> Cr
2
O
7
2

C. Tnh kh: Br
> Cr
3+
D. Tnh kh: Cr
3+
> I

Cu 37: Thy phn dung dch cha 34,2 gam mantoz mt thi gian. Ly ton b sn phm thu c sau phn
ng thy phn cho tc dng vi lng d dung dch AgNO3 trong NH3, sau phn ng hon ton thu c 31,32
gam Ag. Hiu sut ca phn ng thy phn mantoz l:
A. 45% B. 25% C. 50% D. 55%
Cu 38: in phn vi in cc tr 500ml dung dch CuSO4 n khi thu c 1,12 lt kh (ktc) anot th dng
li. Ngm mt l st vo dung dch sau in phn n khi phn ng hon ton th thy l st tng 0,8 gam. Nng
mol ca dung dch CuSO4 ban u l
A. 0,4M B. 3,6M C. 1,8M D. 1,5M
Cu 39: Cho cc phn ng sau :
-Nhm cacbua phn ng vi nc; -Canxi cacbua phn ng vi dung dch HCl;
-Natri axetat tc dng vi vi ti xt ; -Bc axetylua phn ng vi dung dch HCl;
-un nng metanol vi H2SO4 c 170
o
C; -un nng etanol vi H2SO4 c 170
o
C.
C bao nhiu trng hp to ra hirocacbon:
A. 6 B. 3 C. 5 D. 4
Cu 40: Cho Fe3O4 vo dung dch HCl (va ) thu c dung dch X. Cho cc ha cht sau: Cu, Mg, Ag, AgNO3,
Na2CO3, NaHCO3, NaOH, NH3. Hy cho bit c bao nhiu ha cht tc dng c vi dung dch X.
A. 8 B. 5 C. 7 D. 6
Cu 41: Hp cht X c cha vng benzen v c CTPT l C7H6Cl2. Thy phn X trong NaOH c, nhit cao, p
sut cao thu c cht Y c cng thc C7H7O2NA. Hy cho bit X c bao nhiu CTCT:
A. 6 B. 5 C. 3 D. 4
Cu 42:Ha tan mt mui c cng thc MX
2
(M l kim loi, X l halogen). Chia dung dch thnh hai phn bng
nhau:
Phn 1 cho tc dng vi dung dch AgNO
3
d thu c 5,74 gam kt ta.
Phn 2: Nhng thanh Fe vo sau khi kt thc phn ng thy thanh Fe tng thm 0,16 gam.
Cng thc ca mui l:
A. CuCl
2
B. FeCl
2
C. MgBr
2
D. CuI
2

Cu 43: Cho dung dch X cha 0,1 mol Al
3+
, 0,2 mol Mg
2+
, 0,2 mol NO3
-
, x mol Cl
-
, y mol Cu
2+

- Nu cho dung dch X tc dng vi dung dch AgNO3 d th thu c 86,1 gam kt ta
- Nu cho 850 ml dung dch NaOH 1M vo dung dch X th khi lng kt ta thu c l
198 | L O V E B O O K . V N
Cu 44: Cho hn hp gm x mol FeS2 v 0,2 mol Cu2S tc dng vi HNO3 long un nng thu c dung dch A ch
cha mui sunfat ca cc kim loi v gii phng kh NO. Gi tr ca x l:
A. 0,2 B. 0,8 C. 0,4 D. 0,6
Cu 45: Cho t t 150 ml dung dch HCl 1M vo 500 ml dung dch A gm Na2CO3 v NaHCO3 th thu c 1,008 lt
kh (ktc) v dung dch B. Cho dung dch B tc dng vi dung dch Ba(OH)2 d th thu c 29,55 g kt ta. Nng
mol ca Na2CO3 v NaHCO3 trong dung dch A ln lt l:
Cu 46: Hy cho bit nhng cht no sau y c khi hiro ha cho cng sn phm ?
A. etilen, axetilen v propanien B. but-1-en; buta-1,3-ien; vinyl axetilen
C. etyl benzen, p-Xilen, stiren D. propen, propin, isobutilen
Cu 47: Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon
ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2
( ktc). Phn trm theo th tch ca H2 trong X l
A. 65,00% B. 53,85% C. 46,15% D. 35,00%
Cu 48: Cho cc ht vi m: O
2-
, Al
3+
, Al, Na, Mg
2+
, Mg. Dy no sau y c xp ng th t bn knh ht?
A. Al
3+
< Mg
2+
< Al < Mg < Na < O
2-
B. Na < Mg < Al < Al
3+
<Mg
2+
< O
2-

C. Na < Mg < Mg
2+
< Al
3+
< Al < O
2-
D. Al
3+
< Mg
2+
< O
2-
< Al < Mg < Na
Cu 49: Cu hnh electron ca mt ion X
3+
l: 1s
2
2s
2
2p
6
3s
2
3p
6
3d
5
. Trong bng tun hon cc nguyn t ho hc,
nguyn t X thuc:
A. Chu k 4, nhm VIIIA B. Chu k 4, nhm VIIIB
C. Chu k 4, nhm IIB D. Chu k 3, nhm VIIIB
Cu 50: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6
(benzen), CH3CHO. S cht trong dy phn ng c vi nc brom l
A. 6 B. 5 C. 8 D. 7

P N

1C 2B 3A 4D 5B 6D 7D 8C 9B 10C
11D 12B 13D 14D 15A 16C 17D 18B 19B 20D
21D 22B 23D 24A 25D 26C 27C 28A 29B 30C
31A 32C 33B 34D 35A 36C 37A 38C 39C 40C
41C 42A 43D 44C 45A 46B 47B 48A 49B 50A

199 | G S T T G R O U P
s 30

Cu 1. Ha tan hon ton 2,44 gam hn hp bt X gm Fe
x
O
y
v Cu bng dung dch H
2
SO
4
c nng d. Sau phn
ng thu c 0,504 lt kh SO
2
(sn phm kh duy nht, ktc) v dung dch cha 6,6 gam mui sunfat. Phn trm
khi lng ca Cu trong hn hp X l:
A. 39,34% B. 65,57% C. 26,23% D. 13,11%
Cu 2. Mt mu cht bo c ch s axit bng 7, ch s x phng ha l 191,8. X phng ha 1 tn mu cht bo ni
trn (hiu sut bng a%) thu c 885,195 kg mui natri ca axit bo. Bit 5% khi lng cht bo ny khng
phi l triaxyl glixerol hoc axit bo. Ga tr ca a l
A. 95. B. 89,79. C. 90. D. 99,72.
Cu 3. Cho cc cht: etan, etyl clorua, etylamin, etyl axetat, axit axetic, anehit axetic, axeton, ancol etylic, phenol.
S cht to c lin kt hiro lin phn t l
A. 2. B. 3. C. 4. D. 5.
Cu 4. Hn hp X gm CuSO4, FeSO4, Fe2(SO4)3 c cha 21,92% S v khi lng. Ly 200 gam hn hp X tc dng
vi dung dch NaOH d, lc ly kt ta em nung trong khng kh n khi lng khng i thu c 93,6 gam
cht rn. Thnh phn phn trm v khi lng ca FeSO4 trong hn hp X l
A. 41,8%. B. 34,2%. C. 19%. D. 30,4%.
Cu 5. C bao nhiu gam KClO3 tch ra khi dung dch khi lm lnh 350 gam dung dch KClO3 bo ha 80
o
C
xung 20
o
C. Bit tan ca KClO3 80
o
C v 20
o
C ln lt l 40 gam/100 gam nc v 8 gam/100 gam nc.
Cu 6. Cho cc cht: natri hiroxit (1), imetylamin (2), etylamin (3), natri etylat (4), p-metylanilin (5), amoniac
(6), anilin (7), p-nitroanilin (8), natri metylat (9) , metylamin (10). Th t gim dn lc baz l:
A. (4), (9), (1), (2), (3), (10), (5), (6), (7), (8).
B. (4), (9), (1), (2), (3), (10), (6), (5), (7), (8).
C. (1), (4), (9), (2), (3), (10), (6), (5), (8), (7).
D. (9), (4), (1), (2), (3), (10), (6), (5), (7), (8).
Cu 7. t chy hon ton mt hidrocacbon X thy V
H
2
O
> 1,5V
CO
2
( cng iu kin nhit , p sut). T X v
cc cht v c cn thit c th iu ch c anilin. S phn ng ti thiu phi thc hin l:
A. 2 B. 3 C. 4 D. 6
Cu 8. Thy phn hon ton 22,2 gam mt nitrua kim loi bng nc to ra kh X. Oxi ha X (vi hiu sut 80%)
bng O2 (xc tc Pt) thu c 5,376 lt (ktc) NO. Kim loi trong nitrua l
A. Mg. B. Ca. C. Na. D. Al.
Cu 9. Hn hp kh O2, SO2 c t l th tch tng ng l 1:2. a hn hp vo thp tng hp, sau phn ng thy
th tch kh i ra gim 1/10 so vi ban u. Thnh phn phn trm v th tch ca SO3 trong hn hp sau phn
ng l
A. 33,333%. B. 11,111%. C. 66,667%. D. 22,222%.
Cu 10. Kh thi ca mt nh my c cha cc cht: HCl, HF, SO2, N2, Cl2, H2S. loi b kh c trc khi xy ra
kh quyn ngi ta dng
A. dung dch KMnO4. B. dung dch Br2. C. dung dch CaCl2. D. dung dch Ca(OH)2.
Cu 11. Trong s cc cht: axetyl clorua, anhirit axetic, axit nitric, brom, kali hiroxit, axit axectic, anehit fomiC.
S cht phn ng c vi phenol l
A. 7. B. 4. C. 5. D. 6.
Cu 12. Thnh phn phn trm v khi lng ca nguyn t R trong oxit cao nht v trong hp cht kh vi hiro
tng ng l a% v b%, vi a:b = 0,425. Tng s electron trn cc phn lp p ca nguyn t R l
A. 10. B. 8. C. 9. D. 11.
Cu 13. Cht X c cng thc phn t l C4H6O2 v ch cha mt loi nhm chC. T X v cc cht v c cn thit
bng 3 phn ng lin tip c th iu ch c cao su Buna. Vy s cng thc cu to ca X tha mn iu kin
trn l
200 | L O V E B O O K . V N
A. 4. B. 1. C. 3. D. 2.
Cu 14. Ha tan hon ton m gam hn hp D (gm Fe3O4 v FeO vi s mol bng nhau) vo dung dch H2SO4 long,
d, thu c dung dch X. Dung dch X phn ng va vi 400 gam dung dch Br2 2%. Ga tr ca m l
A. 30,4. B. 11,6. C. 15,2. D. 22,8.
Cu 15. Cho cc polime sau: nha rezol (1), nha bakelit (2), xenluloz (3), amiloz (4), amilopectin (5), cao
su thin nhin (6), cao su lu ha (7). Nhng polime cu trc mng khng gian l:
A. (2), (7). B. (5), (7). C. (2), (6), (7). D. (2), (5), (7).
Cu 16. Ha tan ht 52 gam kim loi M trong 739 gam dung dch HNO
3
, kt thc phn ng thu c 0,2 mol NO,
0,1 mol N
2
O v 0,02 mol N
2
. Bit khng c phn ng to mui NH
4
NO
3
v HNO
3
ly d 15% so vi lng cn
thit. Kim loi M v nng % ca HNO
3
ban u ln lt l:
A. Cr v 20 B. Zn v 20 C. Cr v 21,96 D. Zn v 17,39
Cu 17. Cho V lt (ktc) CO2 vo 300 ml dung dch cha NaOH 0,5M v Na2CO3 0,4M, thu c dung dch X cha
29,97 gam hn hp mui. Gi tr ca V l
A. 3,36. B. 5,60. C. 5,04. D. 6,048.
Cu 18. Xt cn bng: N2O4(k) 2NO2(k) 25
o
C. Khi chuyn dch sang mt trng thi cn bng mi, nu nng
ca N2O4 tng ln 36 ln th nng ca NO2
A. gim xung 6 ln. B. tng ln 18 ln. C. tng ln 6 ln. D. gim xung 18 ln.
Cu 19. Dy gm cc hp cht ion l:
A. NH4NO3, NaH, KF, CuSO4. B. HF, Al(NO3)3, CaH2, NaOH, MgO.
C. BeH2, FeS, C2H5NH3Cl, Na3N. D. HNO3, Na2HPO4, CaCO3, H2Cr2O7.
Cu 20. Cng thc n gin nht ca axit cacboxylic X (c mch cacbon khng phn nhnh) l CHO. S nguyn t
hiro trong gc hirocacbon ca phn t X l
A. 5. B. 4. C. 2. D. 3.
Cu 21. in phn dung dch X cha 0,3 mol AgNO3 v 0,1 mol Cu(NO3)2 vi anot lm bng Cu trong thi gian
11580 giy, cng dng in I = 5A. Khi lng kim loi to ra catot l
A. 58 gam. B. 38,8 gam. C. 48,4 gam. D. 42 gam.
Cu 22. Hn hp X gm Mg (0,1 mol), Al (0,04 mol), Zn (0,15 mol). Cho X tc dng vi dung dch HNO3, sau phn
ng thy khi lng dung dch tng 13,23 gam. S mol HNO3 tham gia phn ng l
Cu 23. Pht biu sai l:
A. Cc phn t v ion: CH4, CCl4, NH
4
+

u c cu trc hnh t din u.
B. Gc t do etyl v gc ankyl etyl u c in tch quy c bng 1-.
C. Cc phn t: etilen, ivinyl, benzen u c cu trc phng.
D. 4 nguyn t C ca phn t but-2-in u thuc cng mt ng thng.
Cu 24. Trong s cc cht: H2O, CH3COONa, Na2HPO3, NaH2PO3, Na2HPO4, NaHS, Al2(SO4)3, NaHSO4, CH3COONH4,
Al(OH)3, ZnO, CrO, HOOC-COONa, HOOC-CH2NH3Cl, s cht lng tnh l
A. 7. B. 9. C. 8. D. 10.
Cu 25. Trong s cc cht: canxi cacbua, canxi oxit, nhm cacbua, nhm sunfua, natri hirua, natri peoxit, Kali, flo,
ure. S cht khi tc dng vi nc c th sinh ra cht kh l
A. 7. B. 6. C. 5 D. 8.
Cu 26. Cho m gam ancol X tc dng ht vi Na thu c 0,1 mol H2. Mt khc, oxi ha m gam ancol X bng CuO
d thu c sn phm hu c Y. Cho Y tc dng vi lng d AgNO3/NH3 thu c 0,8 mol Ag. Thnh phn phn
trm v khi lng ca cacbon trong X l
A. 38,71%. B. 52,17%. C. 60% D. 37,5%.
Cu 27. Cho hn hp kh X (gm 0,009 mol NO2 v 0,0015 mol O2) phn ng hon ton vi nc thu c dung
dch Y (cha mt cht tan) v V ml (ktc) kh khng mu duy nht. Trn Y vi dung dch cha 0,01 mol NaOH thu
c 200 ml dung dch Z. Ga tr ca V v pH ca dung dch Z ln lt l
A. 22,4 v 12. B. 67,2 v 12,3. C. 22,4 v 2. D. 67,2 v 12.
201 | G S T T G R O U P
Cu 28. Tin hnh cc th nghim sau:
1) Cho anehit axetic tc dng vi HCN thu c cht hu c X. Thy phn X trong mi trng axit v c long
thu c cht hu c Y.
2) Cho etyl bromua tc dng vi Mg trong dung mi ete:
-Ly sn phm thu c cho tc dng vi CO2 thu c cht Z. Cho Z tc dng vi dung dch HCl thu c cht
hu c T.
- Nu ly sn phm thu c cho tc dng vi nc thu c cht hu c Q.
Cc cht Y, T, Q ln lt l:
A. Axit propionic, etyl clorua, etan. B. Axit propionic, etyl clorua, ancol etylic.
C. Axit lactic, axit propionic, ancol etylic. D. Axit lactic, axit propionic, etan.
Cu 29. Trong s cc cht: glucoz, fructoz, saccaroz, mantoz, cht khng phn ng c vi H2/Ni, t
o
l
A. fructoz. B. saccaroz. C. glucoz. D. mantoz.
Cu 30. Cho 27,15 gam tyrosin tc dng vi 225 ml dung dch HCl 1M thu c dung dch X. Cho X tc dng vi
600 ml dung dch NaOH 1M thu c dung dch Y. Tng khi lng cht rn khan thu c khi c cn cn thn
dung dch Y l
Cu 31. Cho 15,5 gam photpho tc dng va vi 74,55 gam clo. Ton b cc cht sau phn ng c ha tan
vo mt lng nc d thu c dung dch X. trung ha dung dch X cn s mol NaOH l
Cu 32. Mt nonapeptit c cng thc l Arg-Pro-Pro-Gly- Phe- Ser- Pro- Phe- Arg. Khi thy phn khng han ton
peptit ny c th thu c ti a s tripeptit m thnh phn c cha gc phenylalanin (Phe) l
A. 4. B. 5. C. 3. D. 6.
Cu 33. Cho m gam Cu tc dng vi dung dch cha Fe(NO3)3 v HCl, sau phn ng thu c dung dch X (cha 2
cht tan) v 20,16 lt (ktc) kh NO. Ga tr ln nht ca m l
A. 86,4. B. 105,6. C. 96,0. D. 172,8.
Cu 34. Trong s cc cht: anehit axetic, anehit fomic, anehit oxalic, axeton, axit fomic, natri fomat, etyl fomat.
C bao nhiu cht tha mn iu kin sau: Khi cho tc dng vi lng d dung dch AgNO3/NH3, sn phm mui
thu c cho tc dng vi dung dch NaOH hoc vi dung dch H2SO4 un nng u c kh v c thot ra.
A. 3. B. 5. C. 4. D. 2.
Cu 35. T khi hi ca este X, mch h (cha C, H, O) i vi hn hp kh (CO, C2H4) c gi tr trong khong (2,5;
2,6). Cho 10,8 gam este X tc dng vi dung dch NaOH d (hiu sut bng 80%) thu c hn hp Y. Cho Y tc
dng hon tan vi lng d dung dch AgNO3/NH3 thu c khi lng bc l
Cu 36. Trong t nhin Cl tn ti ch yu 2 ng v
37
Cl v
35
Cl. Thnh phn phn trm v khi lng ca
35
Cl
trong mui AlCl3 l
A. 59,83%. B. 19.66%. C. 75%. D. 58.99%.
Cu 37. Mt loi mn ca cha 60% xenluloz c dng lm nguyn liu sn xut ancol etyliC. Nu dng 1 tn
mn ca trn c th sn xut c bao nhiu lt cn 70
o
? (bit hiu sut ca qu trnh l 70%, khi lng ring
ca ancol etylic nguyn cht l 0,8 g/ml).
A. 298,125 lt. B. 542,734 lt. C. 425,926 lt. D. 365,675 lt.
Cu 38. Chuyn ha hon ton 4,2 gam anehit X mch h bng phn ng trng gng vi dung dch AgNO
3
NH
3

d ri cho lng Ag thu c tc dng ht vi dung dch HNO
3
to ra 3,792 lt NO
2
27 v 740 mmHg. Tn gi
ca X l anehit:
A. fomic B. Axetic C. Acrylic D. oxalic
Cu 39. Thc hin phn ng vi ti xt (hiu sut bng 100%) i vi 32,2 gam hn hp X gm 2 mui natri ca
2 axit cacboxylic thu c 6,72 lt (ktc) hn hp kh Y. Nung Y vi mt t xc tc Ni n khi phn ng xy ra hon
ton thu c 4,48 lt (ktc) hn hp kh Z c kh nng lm mt mu nc brom. Hai mui trong X l
A. (COONa)2 v C2H2(COONa)2. B. HCOONa v (COONa)2.
202 | L O V E B O O K . V N
C. (COONa)2 v C2H3COONa. D. HCOONa v C2H3COONa.
Cu 40. Cc ha cht c s dng trong qu trnh phn bit cc dung dch Na2SO3, Na2CO3, NaHCO3, NaHSO3 l
A. dung dch CaCl2 v dung dch HCl. B. dung dch CaCl2 v dung dch Br2.
C. dung dch Ca(OH)2 v dung dch Br2. D. dung dch Ca(OH)2 v dung dch HCl.
Cu 41. Trong s cc cu sau:
a) Cc cht: amoniac, etylamin, hiro, ancol metylic u kh c ng (II) oxit khi nung nng.
b) Propen v xiclopropan khi cng brom u cho cng mt sn phm.
c) Cc cht rn: km hiroxit, bc oxit, bc clorua u tan c trong dung dch amoniac m c.
d) Khi cho dung dch natri stearat vo dung dch canxi hirocacbonat c kt ta to thnh.
e) Stiren v toluen u c kh nng lm mt mu dung dch thuc tm.
S cu ng l
A. 3. B. 5. C. 4. D. 2.
Cu 42. Qu trnh sn xut amoniac trong cng nghip da trn phn ng thun nghch sau:
N2(k) + 3H2(k) 2NH3(k). H = -92 kJ
thun to ra nhiu amoniac:
(1) Tng nhit . (2) Tng p sut.
(3) Thm cht xc tc. (4) Gim nhit .
(5) Ly NH3 ra khi h
A. (2), (3), (4), (5). B. (1), (2), (3), (5). C. (2), (4), (5). D. (2), (3), (5).
Cu 43. C cc dung dch long ca cc mui sau: MgCl2, AlCl3, FeCl3, FeCl2, CdCl2, BaCl2, CuCl2. Khi cho dung dch
Na2Svo cc dung dch mui trn. S trng hp phn ng sinh ra cht kt ta l
A. 5. B. 6. C. 7. D. 4.
Cu 44. Cho phn ng sau: KMnO4 + C6H12O6 + H2SO4 MnSO4 + K2SO4 + CO2 + H2O, vi h s cc
cht trong phng trnh ha hc l nhng s nguyn ti gin. Tng h s ca cc cht phn ng l
A. 164. B. 197. C. 65. D. 29.
Cu 45. Cho lung kh hiro qua ng ng 32 gam Fe2O3 t nng. Sau mt thi gian, thy khi lng cht rn
trong ng cn li l 29,6 gam gm Fe3O4, FeO, Fe v Fe2O3 d. em ton b cht rn ny ha tan ht trong dung
dch HNO3 d, thy thot ra V lt (ktc) kh NO l sn phm kh duy nht. Gi tr ca V l
A. 1,12. B. 2,24. C. 4,48. D. 6,72.
Cu 46. Mt cht hu c X c phn trm khi lng cc nguyn t (trong phn t) l 31,19%C, 9%H, 18,19%N v
cn li l oxi. Bit cng thc phn t ca X trng vi cng thc n gin nht. Nu cho 11,55 gam X tc dng ht
vi 100ml dung dch NaOH aM, ri c cn dung dch sau phn ng th thu c 18,3 gam cht rn Y. Gi tr ca a
l:
A. 3,525M B. 3M hay 3,252M C. 3M D. 3M hay 3,525M
Cu 47. Trong s cc cht: clobenzen, toluen, nitrobenzen, anilin, phenol, axit benzoic, benzanehit, naphtalen, p-
xilen, cumen, p-crezol, s cht tham gia phn ng th nhn thm d hn so vi benzen l
A. 7. B. 9. C. 8. D. 6.
Cu 48. Cho 27,25 gam hn hp X gm Mg, Al, Fe, Cu tc dng vi O2 thu c m gam hn hp cht rn Y. Cho
ton b Y tc dng vi dung dch H2SO4 c, nng, thu c dung dch Z (cha 5 mui, vi tng khi lng mui
l 96,85 gam) v 10,64 lt (ktc) kh SO2 duy nht. Ga tr ca m l
A. 34,85. B. 20,45. C. 38,85. D. 31,25.
Cu 49. Cho hn hp kh X gm 3 hirocacbon X1, X2, X3 thuc 3 dy ng ng v hn hp kh Y gm O2, O3 (t
khi Y i vi hiro bng 19). Trn X vi Y theo t l th tch VX : VY = 1,5 : 3,2 ri t chy hn hp thu c, sau
phn ng ch c CO2 v hi nc vi t l th tch tng g l 1,3 : 1,2. T khi ca hn hp X so v H2 l
A. 12. B. 10. C. 14. D. 16.
203 | G S T T G R O U P
Cu 50. Cho 2 ming Zn c cng khi lng v cng kch thc vo cc (1) dng dung dch HCl d v cc (2) ng
dung dch HCl d c thm mt t CuCl2. (Hai dung dch HCl c cng nng mol/l). Hy cho bit kt lun no sau
y khng ng?
A. Kh cc (1) thot ra chm hn cc (2).
B. Lng kh cc (1) thot ra t hn cc (2).
C. cc (1) xy ra s n mn ha hc, cc (2) c xy ra s n mn in ha.
D. Km cc (2) tan nhanh hn cc (1)

P N

1C 2C 3C 4D 5A 6B 7C 8B 9D 10D
11C 12A 13C 14C 15A 16B 17C 18C 19A 20C
21D 22D 23B 24C 25D 26D 27A 28D 29B 30B
31C 32B 33C 34D 35A 36D 37C 38C 39C 40B
41C 42C 43B 44B 45B 46D 47A 48D 49A 50B

204 | L O V E B O O K . V N
s 31

A. Phn ng oxi ha kh l phn ng lun xy ra ng thi s oxi ha v s kh.
B. Phn ng oxi ha kh l phn ng trong c s thay i s oxi ha ca mt s nguyn t.
C. Phn ng oxi ha kh l phn ng c s thay i s oxi ha ca tt c cc nguyn t.
D. Phn ng oxi ha kh l phn ng ng thi c tc nhn kh v tc nhn oxi ha.
Cu 2: Nung hn hp rn FeCO
3
, FeS
2
trong bnh kn cha va khng kh (oxi chim 20% th tch cn li l
nit) sau phn ng hon ton a bnh v nhit ban u thu c cht rn duy nht Fe
2
O
3
v hn hp kh; p
sut trong bnh sau phn ng bng
67
70
ln so vi p sut trc phn ng. Phn trm khi lng ca FeS
2
trong
hn hp ban u l
A. 15,6% B. 83,8% C. 16,2% D. 83,44%
Cu3: Xt cn bng Fe
2
O
3
(r) +3CO (k) 2Fe (r) +3CO
2
(k). Biu thc hng s cn bng ca h l:
A. K =
[Fe]
2
[CO
2
]
3
[Fe
2
O
3
][CO]
3
B. K =
[Fe
2
O
3
][CO]
3
[Fe]
2
[CO
2
]
3
C. K =
[CO]
3
[CO
2
]
3
D. K =
[CO
2
]
3
[CO]
3

Cu 4: Cho 22,4 lt (ktc) hn hp E gm x mol C2H4, z mol C2H2, y mol H2 (d(E/He)=3,6) qua bnh ng Ni nung
nng, sau mt thi gian phn ng th thu c 15,68 lt hn hp kh G (ktc). Dn ton b kh G li chm vo bnh
ng dung dch Brom d, khi lng Brom phn ng l 80 gam. Gi tr x v y ln lt l
A. 0,3mol v 0,4 mol. B. 0,2 mol v 0,5 mol.
C. 0,3 mol v 0,2 mol. D. 0,2 mol v 0,3 mol.
Cu 5: Ha tan hn hp Na2CO3, KHCO3, Ba(HCO3)2 (trong s mol Na2CO3 v KHCO3 bng nhau) vo nc lc
thu c dung dch X v m gam kt ta Y. Chia ton b dung dch X thnh hai phn bng nhau. Phn 1 phn ng
va vi dung dch cha 0,08 mol NaOH. Nh t t dung dch HCl vo phn 2 n khi lng kh thot ra l ln
nht th tn ht 0,12 mol HCl. Gi tr m l
A. 4,925 gam. B. 1,970 gam. C. 3,940 gam. D.7,880 gam.
Cu 6: Cho 31,65g hn hp rn R , RO phn ng va vi m (g) dung dch HCl 14,6% thu c 1 mui v 6,72
lit kh H
2
(ktc).Bit nng phn trm ca mui trong dung dch l 23,9%. Tnh phn trm khi lng ca R
trong hn hp ban u
A. 61,61% B. 24,3% C. 38,39% D. 75,7%
Cu 7: in phn vi in cc tr dung dch cha 0,4 mol AgNO3 vi cng dng in 4,32 A, trong thi gian t
giy thu c dung dch X (hiu sut qu trnh in phn l 100%). Cho 12,64 gam bt Fe vo X thy thot ra kh
NO (sn phm kh duy nht) v sau cc phn ng hon ton thu c 20,4 gam cht rn. Gi tr ca t l
A. 3574,07 giy B. 5361,1giy C. 8935,2 giy D. 2685 giy
Cu 8: Dung dch Z gm Na
2
CO
3
0,4, KHCO
3
xM. Thm t t 0,5 lit dung dch Z vo 500ml dung dch HCl 1M sau
phn ng hon ton thu c kh v dung dch Y. Cho dung dch Ba(OH)
2
d vo dung dch Y sau phn ng hon
ton thu c 78,8g kt ta. Gi tr x l
A. 1,2 B. 1,6 C. 0,8 D. 2
Cu 9: Hn hp X gm cc kim loi Ba, Mg v Al. Chia hn hp X thnh 3 phn bng nhau:
Phn 1 ha tan trong nc d thu c 0,896 lt H
2
.
Phn 2 ha tan trong dung dch NaOH d thu c 6,944 lt H
2
.
Phn 3 ha tan trong HCl d thu c 9,184 lt H
2
.
Cc kh u o ktc, coi Mg khng phn ng vi nc. Khi lng Ba v Mg c trong hn hp X l:
A. 4,8 gam v 2,74 gam B. 2,4 gam v 1,37 gam
Cu 10: Khi vt bng gang, thp b n mn in ho trong khng kh m, nhn nh no sau y ng?
A. Tinh th cacbon l cc m, xy ra qu trnh oxi ho.
205 | G S T T G R O U P
B. Tinh th st l cc m, xy ra qu trnh oxi ho.
C. Tinh th st l cc dng, xy ra qu trnh kh.
D. Tinh th cacbon l cc dng, xy ra qu trnh oxi ho.
Cu 11: Nh t t 900ml dung dch Ba(OH)2 1M (dung dch X) vo 500 ml dung dch Al2(SO4)3 x(M) (dung dch
Y) th sau phn ng ta thu c kt ta l 1,60465m gam. Nu trn 1200ml dung dch X trn vo 500ml dung
dch Y th kt ta thu c c khi lng bng m gam. Gi tr x l
A. 0,4 B. 0,5 C. 0,2 D. 1
Cu 12: Thi hi nc qua than nng thu c hn hp kh A kh (H2, CO, CO2). Cho A qua Ca(OH)2 d thu
c 1,4 gam kt ta, cn li hn hp kh B kh (H2, CO). Mt lng kh B tc dng va ht vi 8,96g CuO. Thnh
phn % theo th tch ca CO2 trong A l:
A. 33,33% B. 11,11% C. 20,00% D. 30,12%.
Cu13: Cho phng trnh phn ng:
FeS2 + Cu2S + HNO3
t
o
Fe2(SO4)3 + CuSO4 + NO + H2O
Tng cc h s ca cc sn phm ( ti gin) l:
A. 100 B. 69 C. 118 D. 39
Cu 14: t chy hon ton m (g) mt polime sinh ra t phn ng ng trng hp isopren v acrilonitrin bng
lng khng kh va thu c hn hp kh v hi trong cha 76,8 % nitr (khng kh cha 20% oxi v th
tch cn li l nitr). T l mt xch isopren vi acrinitrin trong polime l (hiu sut cc phn ng u l 100%)
A. 1:2 B. 2:3 C. 1:3 D. 4:3
Cu 15: Trong cc khng nh sau, c my khng nh ng?
(1) Nhit si v nhit nng chy ca cc halogen tng dn theo th t F2, Cl2, Br2, I2.
(2) Cc anion Cl
, Br
, I
u to kt ta mu trng vi Ag
+
, cn F
th khng.
(3) Cho kh clo i qua nc vi un nng, ly dung dch thu c trn vi kali clorua v lm lnh, ta s thu
c kali peclorat kt tinh.
(4) Khi cho F2 tc dng vi dung dch NaOH long lnh, xy ra phn ng t oxi ha, t kh.
(5) Freon l mt cht do cha flo c tnh bn cao vi cc dung mi v ha cht, c dng lm cht trng
ph ln cho hoc ni chng dnh.
(6) Dung dch NaF long c dng lm thuc chng su rng.
A. 2 B. 5 C. 3 D. 4
Cu 16: Cho tt c cc ng phn mch h c cng cng thc phn t C2H4O2 ln lt tc dng vi: Na, NaOH,
NaHCO3. S phn ng xy ra l:
A. 2. B. 5. C. 4 D. 3
Cu 17: Hn hp A gm 2 ancol n chc X, Y ng ng k tip nhau trong dy (M
X
< M
Y
). Chia A thnh 2 phn
bng nhau:
P1: t chy hon ton thu c 5,6 lit kh cacbonic (ktc) v 6,3 g nc.
P2: un vi axit sunfuric c 140 to thnh 1,25 g hn hp 3 ete c s mol l 0,015mol
Hiu sut phn ng to ete ca X,Y l:
A. 40% v 40% B. 25% v 45% C. 45% v 25% D. 40% v 20%
Cu18: Khi bn m ure cho cy ngi ta khng bn cng vi
A. NH4NO3 B. phn kali C. phn ln D. Vi
Cu 19: Trong cng nghip ngi ta iu ch nc giaven bng cch:
A. Cho kh Cl2 i t t qua dung dch NaOH, Na2CO3
B. in phn dung dch NaCl khng mng ngn
C. Sc kh Cl2 vo dung dch KOH
D. Cho kh Cl2 vo dung dch Na2CO3
206 | L O V E B O O K . V N
Cu 20: t chy hon ton 4,4 gam sunfua ca kim loi M (cng thc MS) trong oxi d. Cht rn sau phn ng
em ha tan trong mt lng va dung dch HNO
3
37,8% thy nng % ca mui trong dung dch l 4,72%.
Khi lm lnh dung dch ny th thot ra 8,08 gam mui rn. Lc tch mui rn thy nng % ca mui trong
dung dch l 34,7%. Cng thc mui rn tch ra sau phn ng l:
A. Fe(NO
3
)
2
. 9H
2
O B. Cu(NO
3
)
2
. 5H
2
O C. Fe(NO
3
)
3
. 9H
2
O D. A, B, C u sai
Cu 21: Thu phn hon ton 1 mol pentapeptit A thu c 431g cc aminoaxit (no ch cha 1 gc COOH, 1
gc -NH2). Khi thu phn khng hon ton A thu c: Gly-Ala, Gly-gly; Gly-Ala-Val, Vla-gly-gly; khng thu c
Gly-gly-val v Val-Ala-Gly. Trong phn t A cha s gc ca Gly l:
A. 3 B. 2 C. 1 D. 4
Cu 22: Ho tan m (g) FeCO3 vo dung dch HCl 80%. Sau phn ng hon ton thu dung dch Y, trong Y nng
phn trm ca HCl l 37,1%. Cho vo dung dch Y k (g) BaCO3 sau phn ng hon ton thu c dung dch Z c
nng ca HCl l 19,7%. Nng phn trm ca mui trong dung dch Y v 1 mui trong Z ln lt l:
A. 41,72% v 33,45% B. 10,5% v 31,2%
C. 10,5% v 33,45% D. 44,72% v 33,45%
Cu 23: Bnh A cha 7,28 lit (ktc) hn hp X gm SO
2
, SO
2
(xc tc thch hp), d
X H
2
= 23,385. Nung bnh mt

thi gian, thu c hn hp Y gm SO
2
, O
2
, SO
3
, dn Y qua bnh ng Ba(OH)
2
d; sau phn ng hon ton thu
c 34,15 g kt ta. Hiu sut phn ng tng hp SO
3
l:
A. 36,5% B. 25% C. 75% D. 28,57%
Cu 24: Ho tan a (g) Fe vo dung dch HCl thu c 2,24 lt kh (ktc) v dung dch D. C cn dung dch D thu
c m (g) mui khan. Cho khi lng mui trn vo 100ml dung dch KMnO
4
H
+
0,25M sau phn ng hon
ton thu V lt kh (ktc). Gi tr V l:
A. 2,24 B. 0,28 C. 1,4 D. 0,336
Cu 25: Cho cc khng nh sau:
1. Trong phn t N
2
cha 1 lin kt 3 nn iu kin thng N
2
khng tc dng vi kim loi no.
2. Nguyn t c cu hnh e phn lp ngoi cng l 4s
1
nm th 19 trong bng tun hon ha hc.
3. Trong ht nhn nguyn t s notron ln hn hoc bng s proton
4. iu kin thng tt c cc kim loi u th rn
5. Cho cc cht: N2, H2, NH3, NaCl, HCl, H2O, N
2
, CO
2
. S cht trong dy m phn t ch cha lin kt cng ha
tr phn cc l 4
6. V tnh kh ca CO kh mnh nn c th dng CO
2
dp tt cc m chy ca tt c cc kim loi.
S khng nh sai l:
A. 1 B. 3 C. 4 D. 5
+
, Fe
3+
, SO
4
2
, dung dch Y cha Ba
2+
, OH
, S
2
phn ng ha hc?
A. 7 B. 5 C. 8 D. 6
Cu 27: Phn ng no sau y xy ra c hai qu trnh luyn gang v luyn gang thnh thp?
A. FeO + CO Fe + CO2 B. S + O2
SO2
C. SiO2 + CaO CaSiO3 D. FeO + Mn Fe + MnO
Cu 28: Cho mt s tnh cht: l cht kt tinh khng mu (1); c v ngt (2); tan trong nc (3); ho tan Cu(OH)2
(4); lm mt mu nc brom (5); tham gia phn ng trng bc (6); b thu phn trong mi trng kim long
nng (7). Cc tnh cht ca saccaroz l
A. (3), (2), (4) , (1). B. (1), (5), (4), (3) .
C. (2), (3), (6) , (5), (4). D. (1), (2), (3), (4), (7).
Cu 29: Trong cc khng nh sau s pht biu no di y khng chnh xc?
1. Protein phn ng vi Cu(OH)2, to ra sn phm c mu tm.
2. Protein phn ng vi HNO3 c, to kt ta mu vng.
3. Khi un nng dung dch protein, protein ng t.
4. Cc protein u tan trong nc
207 | G S T T G R O U P
5. Cu trc bc I ca protein dc gi vng nh lin kt peptit
A. 3 B. 2 C. 1 D. 4
Cu 30: Cht hu c X mch h c t khi hi so vi heli l 14. t chy hon ton X trong oxi va ch thu
c CO
2
v H
2
O. Bit X phn ng c vi dung dch Brom. S cng thc cu to c th c l:
A. 5 B. 7 C. 6 D. 4
Cu 31: Cho V lt CO2 (ktc) hp th ht trong dung dch cha 0,2 mol Ba(OH)2 v 0,1 mol NaOH. Sau phn ng
xy ra hon ton thu c kt ta v dung dch cha 21,35 gam mui. Gi tr ca V l
A. 7,84 B. 8,96 C. 6,72 D. 8,4
Cu 32: Trong cc loi t sau: t lapsan, vinyl ancol, PPF, t visco, t xenluloz axetat, PVA, t capron, t olon , t enang ,
nilon-6,6. S cht c iu ch bng phn ng trng ngng l
A. 1. B. 4. C. 3. D. 2.
A. Phn t mantoz do 2 gc oglucoz lin kt vi nhau qua nguyn t oxi, gc th nht C1, gc th hai
C4 (C1OC4)
B. Phn t saccaroz do 2 gc oglucoz v fructoz lin kt vi nhau qua nguyn t oxi, gc oglucoz
C1, gc fructoz C4(C1OC4)
C. Tinh bt c 2 loi lin kt o[1,4]glicozit v o[1,6]glicozit
D. Xenluloz c cc lin kt [1,4]glicozit
Cu 34: m ur c iu ch bng cch cho amoniac tc dng vi CO2 nhit 180 200
o
C, di p sut
khong 200 atm. thu c 6 kg m ur th th tch amoniac (ktc) dng l (gi s hiu sut t 80%)
A. 2800 lt. B. 4480 lt . C. 5600 lt. D. 3584 lt.
Cu 35: Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng ng tc dng vi
CuO (d) nung nng, sau phn ng hon ton thu mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi
H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, sinh
ra 64,8 gam Ag. Gi tr ca m l
A. 7,8. B. 8,8. C. 7,4. D. 9,2.
Cu 36: Nhn xt no sau y ng?
1. Cho cn bng N2 + 3H2 2NH3, nu s dng thm sc tc hiu sut phn ng s tng.
2. Mi cn bng ha hc u chuyn dch khi thay i 1 trong 3 yu t: nng , nhit v p sut
3. Cho cn bng N2 + 3H2 2NH3 trng thi cn bng. Thm H2 vo , trng thi cn bng mi, ch c
NH3 c nng cao hn so vi trng thi cn bng c
4. Cho cn bng 2NO2 (nu) N2O4 (khng mu). Nu ngm bnh trn vo nc thy mu nu trong bnh nht
dn chng t chiu nghch ca phn ng c H > 0.
A. 1 B. 2 C. 3 D. 4
Cu 37: Trong t nhin ng v
37
Cl chim 24,23% s nguyn t clo. Nguyn t khi trung bnh ca clo bng 35,5.
Thnh phn phn trm v khi lng ca
37
Cl c trong HClO4 l (vi
1
H,
16
O):
A. 9,82%. B. 8,65%. C. 8,56%. D. 8,92%
Cu 38: C 6 gi bt ring bit c mu tng t nhau: CuO, FeO, Fe3O4, MnO2, Ag2O v hn hp Fe + FeO. Thuc
th phn bit c 6 gi bt trn l:
A. dung dch HCl B. dung dch H2O2 C. dung dch HNO3 c D. dung dch H2SO4 long
A. Cacbon monoxit v silic ioxit l oxit axit.
B. Nitrophotka l hn hp ca NH4H2PO4 v KNO3.
C. Photpho trng c cu trc mng tinh th nguyn t, photpho c cu trc polime
D. Thu tinh lng l dung dch m c ca Na2SiO3 v K2SiO3
208 | L O V E B O O K . V N
Cu 40: Nhng thanh kim loi A vo dung dch ng sunfat. Sau mt thi gian ly thanh kim loi ra thy khi
lng bin i 0,05%. Mt khc,nu nhng thanh kim loi tn vo dung dch ch nitrat th thy khi lng thanh
kim loi tng 7,1%. Bit rng s mol CuSO4 v Pb(NO3)2 tham gia phn ng bng nhau. Kim loi A l:
A. Mg B. Fe C. Zn D. Sn
Cu 41: Mt hn hp A gm Al2O3, K2O, CuO.
-Nu thm vo hn hp vo nc d cn li 15g cht rn.
-Nu thm vo hn hp A 50% lng Al2O3 ri ha tan vo nc d th cn li 21g cht rn.
-Nu thm vo hn hp A 75% lng Al2O3 ban u ri lm th nghim nh trn th cn li 25g cht rn.
Khi lng K2O trong hn hp A l:
A. 32,9g B. 17,16g C. 28,2g D. 16,58g
Cu 42: C 5 dung dch ring bit: HCl, CuSO4, Fe2(SO4)3, HCl c ln CuSO4, AgNO3. Nhng vo mi dung dch mt
thanh Fe nguyn cht. S trng hp xut hin n mn in ha l:
A. 3 B. 2 C. 1 D. 4
Cu 43: Mt loi m cha 40% triolein, 20% tripanmitin v 40% tristearin (v khi lng). X phng ha hon
ton m gam m trn thu c 138 gam glixerol. Gi tr ca m l:
A. 1,326 kg B. 1,335 kg C. 1,304 kg D. 1,209 kg
Cu 44: Nung 70,8g hn hp A gm Cu v 1 mui nitrat ca kim loi R (c t l mol gia 2 cht l 1,75) trong bnh
kn khng c khng kh, sau cc phn ng hon ton thu m (g) rn Y. Ho tan va rn Y bng 300ml H
2
SO
4
2M.
Cng thc ca mui trong A l
A. Fe(NO
3
)
2
B. Cu(NO
3
)
2
C. Fe(NO
3
)
3
D. KNO
3

Cu 45: t chy hon ton 12,5 gam mt hirocacbon X mch h (l cht kh iu kin thng), ri em ton
b sn phm chy hp th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn ng thu c 108,35 gam kt ta
v phn dung dch gim 59,85 gam. S nguyn t hiro trong phn t X l
A. 2. B. 8. C. 6. D. 4.
Cu 46: Hn hp A gm Fe, Cu, Al, Mg (c t l mol tng ng l 1:1:2:2). Ho tan 22,2g hn hp A cn va
950ml dung dch HNO
3
2M sau cc phn ng hon ton thu dung dch X v V lit (ktc) hn hp kh Y gm NO, N
2
,
N
2
O, NO
2
;bit n
NO
2
= n
N
2
. C cn rt cn thn dung dch X thu c 117,2g mui. Gi tr V l:
A. 5,04 B. 6,72 C. 8,86 D. 7,84
Cu 47: Chia 57,51g hn hp 1 oxit kim loi kim v kim loi kim th thnh 2 phn:
Phn 1: Ho tan trong dung dch HCl d, c cn dung dch thu c 34,02g mui; ly mui in phn nng chy
thu c V (lit) kh anot
Phn 2: Ho tan trong axit nitric d thu c dung dch,c cn thu c 96,66g mui khan
Gi tr ca V l:
A. 12,096 B. 8,064 C. 13,3056 D. 6,048
Cu 48: Ha tan hn hp bt gm m gam Cu v 5m gam Fe3O4 vo dung dch H2SO4 (long, rt d), sau khi cc
phn ng kt thc ch thu c dung dch X. Dung dch X lm mt mu va 49 ml dung dch KMnO4 1M. Gi tr
ca m l
A. 2,32. B. 7,20. C. 5,80 D. 4,64
Cu 49: Trong cng nghip, axeton c iu ch t:
A. cumen B. xiclopropan. C. propan-2-ol. D. propan-1-ol
Cu 50: X phng ho hon ton 0,1 mol mt este no n chc bng 26 gam dung dch MOH 28% (M l kim loi
kim) ri tin hnh chng ct sn phm thu c 26,12 gam cht lng X v 12,88 gam cht rn khan Y. t chy
hon ton cht rn Y thu c V lt CO2 (ktc), H2O v 8,97 gam mt mui duy nht. Gi tr ca V l.
A. 5,264 lt. B. 14,224 lt. C. 6,160 lt. D. 5,600

209 | G S T T G R O U P
1C 2B 3D 4B 5D 6A 7B 8A 9D 10B
11A 12B 13B 14C 15D 16B 17D 18D 19B 20C
21A 22A 23D 24B 25C 26D 27A 28A 29C 30B
31A 32C 33B 34C 35A 36A 37D 38A 39D 40C
41D 42A 43C 44C 45A 46A 47D 48D 49A 50A

210 | L O V E B O O K . V N
Phn ng oxi ha kh l phn ng lun xy ra ng
s 32
Cu 1: X l mt anehit khng no, n chc, mch h. t chy hon ton 0,025 mol X cn dng ht 2,8 lt O
2

(ktc). Mt khc X cng hp H
2
cn th tch H
2
bng 2 ln th tch X phn ng (cc th tch o cng iu kin).
Cng thc phn t ca X l
A. C
4
H
6
O B. C
3
H
4
O C. C
4
H
4
O D. C
5
H
8
O
Cu 2: lm sch kh CO2 b ln tp cht kh HCl v hi nc th cho hn hp ln lt qua cc bnh ng (lng
d):
A. dung dch P2O5 v dung dch NaHCO3 B. dung dch Na2CO3 v P2O5
C. dung dch P2O5 v dung dch H2SO4 D. dung dch NaHCO3 v P2O5.
Cu 3: t chy hon ton 8,9 gam hp cht hu c E thu c 13,2 gam CO2, 6,3 gam H2O v 1,12 lt N2 (ktc). T
khi hi ca E so vi hiro l 44,5. Khi E phn ng vi dung dch NaOH un nng, sn phm thu c c metanol.
Cng thc cu to ca E l:
A. CH3CH(NH2)COOCH3 B. H2NCH2CH2COOCH3. C. H2NCH2COOCH3 D. CH3COOCH2NH2
Cu 4: Cho a mol mt anehit X tc dng vi 4a mol H2, c Ni xc tc, un nng. Sau khi phn ng xy ra hon
ton, thu c 2a mol hn hp cc cht, trong c cht hu c Y. Cho lng Y tc dng vi lng Na d th thu
c a mol H2. X l:
A. anehit thuc dy ng ng ca anehit acrylic.
B. anehit n chc, khng no c 2 lin kt i C=C hoc 1 lin kt C
trong phn t.
C. anehit khng no, c cha hai nhm chc anehit .
D. anehit no cha hai nhm chc.
Cu 5: Cho cc phng trnh phn ng sau:
a/ Fe + AgNO3 d b/ FeCO3 + HNO3
c/ Si + NaOH + H2O
t
o
d/ etilen glicol + Cu(OH)2
e/ CH3CHO + KMnO4 + H2SO4 f/ FeS + HNO3 c, nng
g/ Ca(HCO3)2

t
o
h/ SiO2 + NaOH
Dy gm cc phn ng thuc loi phn ng oxi ha - kh l:
A. a, b, e, f B. b, c, d,f, g. C. a, b, c, f D. a, b, c, e,f
Cu 6: Ha tan ht m gam Al v FexOy bng dung dch HNO3 thu c hn hp sn phm kh gm 0,05 mol NO;
0,03 mol N2O v dung dch B. C cn dung dch B thu c 37,95 gam hn hp mui khan. Nu ha tan lng
mui ny vo dung dch xt d th thu c 6,42 gam kt ta nu . Gi tr ca m v cng thc ca FexOy l:
A. 7,29 gam v FeO B. 9,72 gam v Fe2O3 C. 7,29 gam v Fe3O4. D. 9,72 gam v Fe3O4
Cu 7: Thu phn hon ton 1 mol pentapeptit Y thu c 3 mol glyxin, 1 mol valin v 1 mol alanin. Khi thu phn
khng hon ton Y th thu c cc ipeptit Ala Gly, Gly Val v 1 tripeptit Gly -Gly-Gly. Cng thc ca
pentapeptit l:
A. Gly-Ala-Gly-Val-Gly. B. Ala-Gly-Gly-Gly-Val C. Gly-Ala-Gly-Gly-Val D. Gly-Gly-Ala-Gly-Val
Cu 8: Cho hn hp M gm Fe, FeO, Fe
2
O
3
. Dng H
2
d i qua 4,72 gam hn hp M nung nng thu c 3,92 gam
Fe. Mt khc cho 4,72 gam M vo lng d dung dch CuSO
4
thu c 4,96 gam cht rn. Cho rng hiu sut cc
phn ng l 100%. Phn trm khi lng Fe, FeO v Fe
2
O
3
trong M ln lt l:
A. 30,51; 35,59; 33,90 B. 35,59; 30,51; 33,90 C. 30,51; 37,62; 31,87 D. 35,59; 30,51; 33,90
Cu 9: Cho s biu din chui bin ha sau: Cu
2
O
+O
2
d,t
o
cao
X
+CO d,t
o
cao
Y
+HCl,O
2
d,t
o
Z. Z l:
A. CuCl B. CuCl, CuCl2. C. CuCl2 D. Cu2Cl2
Cu 10: Ha tan hon ton 7,33 gam kim loi M c ha tr 2 v oxit ca n vo nc thu c dung dch X c pH
= 13 Kim loi M l:
A. Ca B. Ba C. K D. Na
Cu 11: Mt hn hp bt gm hai kim loi Mg v Al c chia thnh hai phn bng nhau:
211 | G S T T G R O U P
- Phn I: Cho tc dng ht vi dung dch HCl d thu c 3,36 lt kh H2 (ktc)
- Phn II: Ha tan ht trong dung dch HNO3 long d, thu c V lt (ktc) mt cht kh khng mu, ha nu
trong khng kh. Gi tr ca V l:
A. 5,6 lt. B. 4,48 lt C. 2,24 lt D. 3,36 lt
Cu 12: Xenluloz trinitrat l cht d chy v n mnh c iu ch t xenluloz v axit nitric. sn xut 59,4
gam xenluloz trinitrat th th tch axit nitric 99,67% (c khi lng ring l 1,52 g/ml) cn dng l: (Bit hiu
sut phn ng l 90%).
A. 28,6 ml B. 32,5 ml C. 26,5 ml D. 27,72 ml
Cu 13: Cho hp cht hu c X c mch cacbon khng phn nhnh cha C, H, O. un X vi 200ml dung dch KOH
1M thu c dung dch Y. trung ha KOH d trong Y cn 80ml dung dch HCl 0,5M thu c dung dch Z. C
cn dung dch Z nhn c 7,36 gam hn hp hai ancol n chc v 18,34 gam hn hp hai mui. Cng thc cu
to ca X l:
A. CH
3
CH
2
CH
2
COOCH
2
CH = CH
2
B. CH
3
OCOCH = CHCH
2
COOC
2
H
5

C. CH
3
OCOCH
2
CH = CHCH
2
COOCH
3
D. CH
3
OCOCH = CHCOOCH
2
CH
2
CH
3

Cu 14: em nung cc cht sau: KNO3, NH4NO3, NH4NO2, NH4Cl, Ba(HCO3)2, AgNO3, NH4HCO3, FeCO3, Cu(NO3)2
c s nhit phn xy ra (nu c) th c th thu c bao nhiu kh khc nhau (khng k hi nc)?
A. 7 B. 5 C. 8 D. 6
Cu 15: Cho s phn ng sau: X
H
2
d,Ni,t
o
Y
CuO,t
o
Z
O
2
,xc tc
axit isobutiric. Bit X, Y, Z l cc hp cht hu c
mch h khc nhau. C bao nhiu cng thc cu to ca X tha mn tnh cht trn?
A. 5 B. 4 C. 3 D. 2
Cu 16: Este X c iu ch t aminoaxit glutamic v ancol etylic. Cho 0,1 mol X vo 200 ml dung dch NaOH
1,5M, sau khi phn ng xy ra hon ton, c cn cn thn dung dch thu c cht rn G. Cho ton b cht rn G
vo dung dch HCl d, sau c cn cn thn li thu c m gam cht rn E. Gi tr ca m l:
A. 26,4 g. B. 18,35 g C. 30,05 g D. 35,9 g
Cu 17: Cho 200 ml dung dch H3PO4 1,5M tc dng vi 250 ml dung dch NaOH 2M. Sau phn ng thu c mui:
A. NaH2PO4 v Na2HPO4 B. Na2HPO4. C. Na2HPO4 v Na3PO4 D. NaH2PO4 v Na3PO4
Cu 18: Trong mt bnh thp c dung tch 5,6 lt (khng cha khng kh), ngi ta cho vo 32 gam NH4NO2.
a bnh v nhit 0 sau khi un nng mui ny b phn tch hon ton. Nu coi th tch ca H2O l
khng ng k th p sut trung bnh sau phn ng l:
A. 6 atm B. 2 atm C. 2,25 atm D. 2,5 atm
Cu 19: Cho 13,36 gam hn hp A gm Cu v Fe3O4 vo dung dch H2SO4 c d, thu c V lt kh SO2 (ktc) v
dung dch B. Cho dung dch B tc dng vi dung dch NaOH d thu c kt ta C, nung kt ta ny n khi
lng khng i thu c 15,2 gam cht rn D. Gi tr ca V l:
A. 2,240 lit B. 3,324 lt C. 2,576 lt. D. 3,360 lt
Cu 20: T cht no di y khng th trc tip iu ch axeton?
A. anehit propionic B. ancol i-propylic C. cumen D. metylaxetilen
Cu 21: Cho hai cht hu c X v Y c cng cng thc phn t C3H7O2N . X v Y thc hin cc chuyn ho sau:
X
+[H]
amin v Y
+HCl
Z
+NaOH
C
3
H
6
O
2
NNa
Tng s ng phn ca X v Y tha mn l:
A. 5 B. 6 C. 2 D. 4
Cu 22: Cho m gam Fe
x
O
y
tc dng vi CO, ung nng, ch c phn ng CO kh oxit st, thu c 5,76 gam hn
hp cht rn X v hn hp hai kh gm CO
2
v CO. Cho hn hp hai kh trn hp th vo lng nc vi trong d
th thu c 4 gam kt tA. em ha tan ht 5,76 gam cht rn trn bng dung dch HNO
3
long th c kh NO
thot ra v thu c 19,36 gam mt mui duy nht. Tr s ca m v cng thc ca Fe
x
O
y
l
A. 6,40; Fe
3
O
4
B. 9,28; Fe
2
O
3
C. 9,28; FeO D. 6,40; Fe
2
O
3

Cu 23: Chia 7,8 gam hn hp ancol etylic v mt ng ng ca n thnh hai phn bng nhau.
- Phn I: Tc dng vi Na d thu c 1,12 lt kh (ktc).
212 | L O V E B O O K . V N
- Phn II: Tc dng vi 30 gam CH3COOH (c mt H2SO4 c). Hiu sut phn ng l 80%.
Tng khi lng este thu c l:
A. 8,1 gam B. 8,8 gam C. 7,28 gam. D. 6,48 gam
Cu 24: Cho cc cht sau: NH4HCO3, NaHSO4, Ba(HSO3)2, NaH2PO4, SiO2, Si, Mg, MgO, CuS. S cht phn ng c
vi dung dch HCl l:
A. 6 B. 7 C. 5 D. 8
Cu 25: T benzen cng etilen c etylbenzen, ri t etylbenzen em hiro ha c stiren v em trng
hp th thu c polistiren. Khi lng benzen cn dng sn xut c 1 tn polistiren. Bit hiu sut ca cc
qu trnh ln lt l 80%; 80% v 90%:
A. 1302 kg B. 1200 kg C. 1456 kg D. 1507 kg.
Cu 26: Dung dch A cha cc ion sau: Mg
2+
, Ba
2+
, Ca
2+
, 0,1 mol Cl
v 0,2 mol NO
3
. Thm dn V lt dung dch

K2CO3 1M vo dung dch A n khi c lng kt ta ln nht. Gi tr ca V l:
A. 250 ml B. 200 ml C. 150 ml. D. 300 ml
1. Alanin lm qu tm ha xanh.
2. Axit glutamic lm qu tm ha .
3. Lysin lm qu tm ha xanh.
4. Axit - amino caproic l nguyn liu sn xut nilon-7.
5. Tt c cc peptit u c phn ng mu Biure.
6. Phn t ipeptit c 2 lin kt peptit.
S nhn nh ng l:
A. 5 B. 2 C. 3 D. 6
Cu 28: Pirit st tc dng vi dung dch H2SO4 m c, nng theo phn ng:
FeS2 + H2SO4 (c, nng) Fe2(SO4)3 + SO2 + H2O
Pht biu ng l:
A. 2 mol FeS2 oxi ha 14 mol H2SO4
B. 1 mol FeS2 phn ng va vi 7 mol H2SO4
C. FeS2 va ng vai tr cht oxi ha, va ng vai tr cht kh.
D. Phn ng va gia cht oxi ha v cht kh theo t l 7 : 1.
Cu 29: Cho phn ng : Al + HNO3 Al(NO3)3 + NO2 + NO + N2O + H2O
T l th tch kh thu c l: V
NO
2
: V
NO
: V
N
2
O
= 1: 2: 3. H s nguyn ti gin ca HNO3 l:
A. 120 B. 31 C. 48 D. 124
Cu 30: A l mt l mt dn xut monoclo no, mch h m khi t chy a mol A th thu c 5a mol CO2. A ph
hp vi s chuyn ha di y (mi mi tn l mt phn ng):
A B (ancol bc 1) D E (ancol bc 2) F G (ancol bc 3). A l:
A. 1-clo-2-metylbutan B. 1-clo-2,2-imetylpropan
C. 1-clo-3-metylbutan. D. 2-clo-3-metylbutan
Cu 31: Nhm cha nhng kh thi u c th x l bng dung dch Ca(OH)2 d l:
A. CO2, SO2, H2S, Cl2 B. CO2, C2H4, H2S, Cl2 C. NO2, CO2, NH3, Cl2 D. HCl, CO2, C2H4, SO2.
Cu 32: Trong s cc polime sau: t tm, si bng, len, t enan, t visco, si ay, nilon-6,6; t xenluloz axetat.
Loi t c ngun gc xenluloz l:
A. t tm, si bng, nilon-6,6 B. si bng, len, t enan, nilon-6,6
C. si bng, len, t xenluloz axetat, t visco D. t visco, si bng, si ay, t xenluloz axetat.
Cu 33: Cc aminoaxit no c th phn ng vi tt c cc cht trong nhm no sau y.
A. dung dch NaOH, dung dch Br2, dung dch HCl, CH3OH
B. dung dch Ca(OH)2, dung dch thuc tm, dung dch H2SO4, C2H5OH
C. dung dch NaOH, dung dch HCl, C2H5COOH, C2H5OH
D. dung dch H2SO4, dung dch HNO3, CH3OC2H5, dung dch thuc tm.
213 | G S T T G R O U P
Cu 34: C 200 ml dung dch A cha H2SO4; FeSO4 v mt mui sunfat ca kim loi M c ha tr 2. Cho 20 ml dung
dch B gm BaCl2 0,4M v NaOH 0,5M vo dung dch A th dung dch A va ht axit H2SO4. Cho thm 130 ml dung
dch B vo na th c mt lng kt ta. Lc kt ta thu c dung dch C. Cn phi dng 20ml dung dch HCl
0,25M trung ha dung dch C. Trong dung dch C cha cc ion l: (M l kim loi c hiroxit khng tan v khng
c tnh lng tnh)
A. Na
+
, Ba
2+
, Cl
v OH
. B. Na
+
, Ba
2+
, OH

C. Na
+
, Cl
v OH
. D. Na
+
, Cl
, OH
v SO
4
2
.
Cu 35: Mt nh my sn xut glucoz t khoai m (c m, sn). Hiu sut phn ng l 80%. Nu nh my sn xut
c 360 tn glucoz trong mt ngy v thu hi c phn tinh bt cn d ln men ru nhm sn xut cn
700 dng trong y t, th trong mt ngy nh my sn xut c ti a th tch cn 700 l: (bit etanol c khi
lng ring 0,79g/ml, hiu sut ln men ru t tinh bt c thu hi vi hiu sut 100%)
A. 80 m
3
B. 83,18 m
3
C. 70,25 m
3
D. 66,546 m
3

Cu 36: X, Y l 2 nguyn t kim loi thuc nhm IIA. Bit ZX < ZY v ZX + ZY = 32) Pht biu ng v X v Y l:
A. Nng lng ion ha I1 ca X < Y. B. Bn knh nguyn t ca X > Y.
C. Tnh kim loi ca X > Y. D. X, Y u c 2 electron lp ngoi cng.
Cu 37: Ch dng mt thuc th no di y phn bit c etanal; propan-2-on v pent-1-in?
A. H2/Ni, t B. dung dch AgNO3 C. dung dch Br2 D. dung dch Na2CO3
Cu 38: Cho hn hp A gm cc hi v kh: 0,1 mol Benzen; 0,2 mol Toluen; 0,3 mol Stiren v 1,4 mol Hiro vo
mt bnh kn, c cht xc tc Ni. un nng bnh kn mt thi gian, thu c hn hp B gm cc cht: Xiclohexan,
Metyl xiclohexan, Etyl xiclohexan, Benzen, Toluen, Etyl benzen v Hiro. t chy hon ton lng hn hp B
trn, ri cho hp th ht sn phm chy vo bnh ng dung dch nc vi c d, hp th ht sn phm chy.
tng khi lng bnh ng nc vi l:
Cu 39: Cho 0,92 gam hn hp gm axetilen v anehit axetic phn ng hon ton vi dung dch AgNO3 trong NH3
thu c 5,64 gam hn hp rn. Thnh phn % theo khi lng cc cht trong hn hp u ln lt l:
A. 28,74% v 71,26% B. 28,26% v 71,74% C. 28,71% v 74,26% D. 26,28% v 74,71%
Cu 40: in phn 200 ml dung dch Ni(NO3)2 0,0625M, in cc tr. Sau mt thi gian in phn, thu c dung
dch c pH = 1. Coi th tch dung dch khng thay i trong qu trnh in phn. Phn trm Ni(NO3)2 in phn
l:
A. 80% B. 100% C. 70% D. 60%
Cu 41: Mt loi m ng vt cha 20% tristearoylglixerol; 30% tripanmitoylglixerol v 50% trioleoyglixerol (v
khi lng). Khi lng mui thu c khi x phng ha 1 tn m trn bng dung dch NaOH (gi s hiu sut
qu trnh t 90%) l:
A. 1030 kg B. 1093 kg. C. 1215 kg D. 929 kg
Cu 42: Ho tan ht hn hp FeS2, FeCO3 bng dung dch HNO3 c, nng c dung dch X v 4,48 lt (ktc) hn
hp kh Y c t khi so vi hiro bng 22,75. Hp th ton b kh Y vo 300 ml dung dch NaOH 1 M c dung
dch Z. Cc cht tan trong Z gm
A. NaHCO3, Na2CO3, NaNO3, NaNO2. B. Na2CO3, NaNO3, NaOH.
C. Na2CO3, NaNO3, NaNO2, NaOH. D. NaHCO3, NaNO3, Na2CO3.
Cu 43: in phn dung dch hn hp gm KBr, CuCl2, HCl v FeCl3 n khi xut hin kh hai in cc. Th t
cc ion b in phn katot l:
A. Cu
2+
, H
+
, Fe
3+
, K
+
, H
2
O B. Br
, Cl
, H
2
O
C. Fe
3+
, Cu
2+
, H
+
, H
2
O D. Fe
3+
, Cu
2+
, H
+
, Fe
2+
, H
2
O
Cu 44: Hn hp rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan hon ton trong dung dch no
sau y:
A. AgNO3 d. B. NaOH d C. NH3 d D. HCl d
Cu 45: Cho 20 gam hn hp gm 3 amin no, n chc l ng ng k tip nhau tc dng va vi dung dch
HCl 1M c cn dung dch thu c 31,68 gam mui. Th tch dung dch HCl dng l:
214 | L O V E B O O K . V N
A. 160 ml B. 16 ml C. 320 ml. D. 32 ml
Cu 46: Cho cc qu trnh xy ra khi n mn st trong khng kh:
(1) Fe Fe
2+
+ 2e
(2) O2 + 2H2O + 4e 4OH

(3) 2H
+
+ 2e H2
4) Fe
2+
+2OH
Fe(OH)2
(5) 2Fe(OH)2 + 1/2O2 + H2O 2Fe(OH)3
(6) 2Fe + 3/2O2 + nH2O Fe2O3.nH2O
Qu trnh no xy ra trn in cc dng cacbon ?
A. (6) B. (2) v (3) C. (1) D. (4) v (5)
Cu 47: Cho cc dung dch sau: phenyl amoniclorua; anilin; natri phenolat; phenol; amoni clorua; axit axetic;
alanin; lysin; etanol; natri etylat; natri clorua; natri cacbonat. Tng s dung dch lm i mu qu tm l:
A. 7 B. 8 C. 6 D. 9
Cu 48: t chy ht hn hp X gm butan, xiclobutan, xiclopentan v xiclohecxan th thu c 0,375 mol CO2 v
0,40 mol H2O. Phn trm khi lng ca butan trong hn hp trn l:
A. 68,76% B. 31,24% C. 27,36% D. 72,64%
Cu 49: Cho cc tnh cht sau:
1. Tham gia phn ng hiro ha
2. Khi thu phn to thnh glucoz v fructoz.
3. Cht rn kt tinh khng mu.
4. Tham gia phn ng trng gng
5. Phn ng vi ng (II) hiroxit.
Nhng tnh cht ng ca saccaroz l:
A. 2, 3, 5 B. 1, 2, 3, 5 C. 1, 2, 3, 4 D. 3, 4, 5.
Cu 50: Mt dung dch cha x mol KAlO2 tc dng vi dung dch cha y mol HCl. iu kin sau phn ng thu
c lng kt ta ln nht l:
A. x < 2y B. x < y C. y < x D. x = y

1A 2D 3C 4C 5D 6A 7B 8B 9C 10B
11C 12D 13D 14A 15D 16D 17A 18B 19C 20A
21D 22S 23D 24C 25A 26C 27B 28B 29A 30C
31A 32D 33C 34D 35B 36D 37B 38B 39B 40A
41D 42C 43D 44D 45C 46A 47A 48C 49A 50D

215 | G S T T G R O U P
s 33

Cu 1: C hai hn hp X v Y c pha trn t cc ancol no n chc cng dy ng ng (mi hn hp ch c 2
ancol). Khi cho X hoc Y tc dng hon ton vi Na d u thu c 5,6 lt H
2
(ktc) v khi t chy X hoc Y u
cn 47,04 lt O
2
(ktc). Hai ancol no sau y khng phi l ca X hoc Y?
A. CH
3
OH v C
3
H
7
OH B. C
2
H
5
OH v C
3
H
7
OH C. CH
3
OH v C
2
H
5
OH D. C
2
H
5
OH v C
4
H
9
OH
Cu 2: Oxit ca X phn ng vi nc to ra dung dch lm qu tm. Oxit ca Y phn ng vi nc to ra dung
dch lm xanh qu tm. Oxit ca Z tc dng vi c dung dch axit v dung dch kim. X, Y, Z l cc nguyn t cng
chu k, th t sp xp theo theo chiu tng dn tnh kim loi ca ba nguyn t trn l:
A. Y, Z, X. B. X, Z, Y. C. X, Y, Z. D. Z, Y, X.
Cu 3: Polime no sau y c to thnh t phn ng ng trng ngng.
A. nilon-6,6 B. Nilon-6 C. thu tinh hu c D. Cao su buna-S
Cu 4: Trong phng th nghim thng iu ch CO2 t CaCO3 v dung dch HCl, do CO2 b ln mt t hi nc
v kh hiro clorua. c CO2 tinh khit nn cho hn hp kh ny ln lt qua cc bnh cha.
A. Dung dch Na2CO3 v dung dch H2SO4 c B. Dung dch NaHCO3 v CaO khan
C. Dung dch NaHCO3 v dung dch H2SO4 c D. P2O5 khan v dung dch NaCl
Cu 5: t chy hon ton 0,05 mol mt anken A thu c 4,48 lt CO2 (ktc). Cho A tc dng vi dung dch HBr
ch cho mt sn phm duy nht. Cng thc cu to ca A l
A. CH2=CH2 B. (CH3)2C=C(CH3)2 C. CH3CH=CHCH3 D. CH2=C(CH3)2
Cu 6: Thc hin phn ng nhit nhm vi 4,86 gam Al v m gam Fe3O4. Ch c oxit kim loi b kh to kim loi.
em ha tan cc cht thu c sau phn ng nhit nhm bng dung dch Ba(OH)2 d th khng thy cht kh to
ra v cui cng cn li 23,52 gam cht rn. Cc phn ng xy ra hon ton. Tr s ca m l:
A. 12,18 B. 27,84 C. 15,66 D. 174,00
Cu 7: Tin hnh cc th nghim: Cho FeO vo dung dch H2SO4 c nng; cho AgNO3 vo dung dch HCl; cho Fe
vo dung dch Fe(NO3)3 ; cho Ag vo dung dch Fe(NO3)3; cho Fe(NO3)2 vo dung dch HCl; cho Cu vo dung dch
Fe(NO3)2; cho AgNO3 vo dung dch Fe(NO3)2; CaCO3 cho vo dung dch HNO3. S trng hp xy ra phn ng oxi
ha kh l.
A. 7 B. 6 C. 5 D. 4
Cu 8: Cho dy chuyn ha sau: CH3CH2CHOHCH3
H
2
SO
4
,170
E
Br
2
(dd)
F. Bit E l sn phm chnh, cc cht phn
ng vi nhau theo t l 1:1 v s mol. Cng thc cu to ca E v F ln lt l cc cp cht trong dy no di y?
A. CH3CH2CH=CH2, CH3CH2CHBrCH2Br B. CH3CH=CHCH3, CH3CH2CBrCH3
C. CH3CH=CHCH3, CH3CHBrCHBrCH3 D. CH3CH2CH=CH2, CH2BrCH2BrCH=CH2
Cu 9: Cho dung dch X cha 0,1 mol FeCl2, 0,2 mol FeSO4. Th tch dung dch KMnO4 1,0M trong H2SO4 (long)
va oxi ha ht cc cht trong X l:
A. 0,1 lt. B. 0,2 lt. C. 0,3 lt. D. 0,4 lt.
Cu 10: Xt cc loi hp cht hu c mch h sau: Ancol n chc no, h (X); anehit n chc no, h (Y); ancol
n chc khng no, h c mt lin kt i (Z); anehit n chc khng no, h c mt lin kt i (T). ng vi
cng thc chung CnH2nO ch c hai cht, l nhng cht no sau y.
A. Y, Z B. X, Y C. Z, T D. X, T
Cu 11: Trong cc mui amoni : NH
4
Cl, NH
4
NO
2
, NH
4
NO
3
, NH
4
HCO
3
, (NH
4
)
2
SO
4
, (NH
4
)
2
CO
3
mui no b nhit
phn thnh kh NH
3
?
A. NH
4
Cl, NH
4
NO
3
, (NH
4
)
2
SO
4
, NH
4
HCO
3
. B. NH
4
Cl, (NH
4
)
2
SO
4
, NH
4
NO
2
, (NH
4
)
2
CO
3

C. NH
4
Cl, (NH
4
)
2
SO
4
, NH
4
HCO
3
, (NH
4
)
2
CO
3
D. NH
4
Cl, NH
4
NO
2
, NH
4
NO
3
, NH
4
NO
3
, (NH
4
)
2
SO
4

Cu 12: PVC c iu ch t kh thin nhin theo s :
CH4
15%
C2H2
95%
CH2 = CHCl
90%
PVC. Th tch kh thin nhin (ktc) cn iu ch ra mt tn PVC l (Bit kh
thin nhin cha 95% metan v th tch).
A. 141 m
3
B. 6154,144 m
3
C. 2915 m
3
D. 5883,246 m
3

216 | L O V E B O O K . V N
Cu 13: Trong mt bnh kn dung tch 16 lt cha hn hp CO, CO
2
v O
2
d. Th tch O
2
nhiu gp i th tch CO.
Bt tia la in t chy hon ton hn hp, th tch kh trong bnh gim 2 lt. Bit cc th tch kh trong bnh c
o cng iu kin nhit v p sut. Thnh phn % theo th tch ca CO, CO
2
v O
2
trong hn hp ban u ln
lt l:
A. 25%, 25% v 50% B. 25%, 50% v 25% C. 50%, 25% v 25% D. 35%, 35% v 30%
Cu 14: C 6 ng phn A
1
, A
2
, A
3
, A
4
, A
5
v A
6
ca C
4
H
8
. Trong 4 cht A
1
, A
2
, A
3
, A
4
lm mt mu dung dch
brom ngay c trong bng ti cn A
5
v A
6
th khng lm mt mu dung dch brom. Khi tc dng vi H
2
(Ni, t) th
ba cht A
1
, A
2
, A
3
cho cng mt sn phm duy nht. Hai cht A
1
v A
2
l ng phn hnh hc ca nhau. Nhit
si ca A
1
nh hn A
2
v ca A
5
nh hn ca A
6
. iu khng nh no sau y v cu to ha hc ca 6 ng phn
trn l khng ng?
A. A
1
, A
2
, A
3
, A
4
l cc anken, trong A
1
, A
2
, A
3
c mch cacbon thng cn A
4
c mch cacbon phn nhnh.
B. A
1
l cis but 2 en v A
2
l trans but 2 en.
C. A
5
l xiclobutan.
D. A
6
l metylxiclopropan.
Cu 15: Nhit phn hon ton m gam BaCO3 thu c kh X. Hp th ht X vo 1,25 lt dung dch gm Ba(OH)2
0,16M v KOH 0,08 M, thu c dung dch Y v 29,55 gam kt ta, un nng dung dch Y li thu c kt ta. Gi
tr ca m l.
A. 68,95 B. 29,55 C. 49,25 D. 88,65
Cu 16: X phng ho hon ton 66,6g hn hp 2 este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH thu c
hn hp X gm 2 ancol. ung nng hn hp X vi H2SO4 c 140 sau khi phn ng xy ra hon ton thu c
m (g) H2O. Gi tr m l:
A. 18g B. 8,1g C. 16,2g D. 4,05g
Cu 17: Hn hp X gm FeO, Fe2O3 v Fe3O4 trong s mol FeO bng s mol Fe2O3 phn ng va vi 800 ml
dung dch Y gm HCl 0,5M v H2SO4 0,25M. Tng khi lng mui khan thu c khi c cn dung dch sau phn
ng l.
Cu 18: Cho cc cht sau: axit phenic (hay phenol) (1), axit axetic (2), axit cacbonic (3), axit sunfuric (4). Tnh axit
ca chng bin i theo chiu.
A. 1>2>3>4 B. 4>2>3>1 C. 4>3>2>1 D. 3>4>2>1
Cu 19: Hn hp X gm Ba v Al. Cho m gam X vo mt lng d nc th thot ra 0,896 lt kh (ktc). Nu cng
cho m gam X vo dung dch NaOH d th c 1,232 lt kh (ktc). Gi tr ca m l.
A. 2,37 B. 2,46 C. 3,83 D. 2,18
Cu 20: Cho s sau: X
+Cl
2
Y
+NaOH
Z
+CuO
T
+AgNO
3
NH
3
G (amoni acrylat). Cc cht (X) v (Z) c th l nhng

cht c ghi dy no sau y?
A. C3H6 v CH2=CH-CH2-OH B. C2H6 v CH2=CH-CHO
C. C3H6 v CH2=CH-CHO D. C3H8 v CH2=CH-CH2-OH
Cu 21: Phng trnh ion thu gn ca phn ng no di y khng c dng: HCO
3
+H
+
H2O + CO2
A. KHCO3 + NH4HSO4 B. NaHCO3 + HF C. Ca(HCO3)2 + HCl D. NH4HCO3 + HClO4
Cu 22: ng phn X ca C5H12 khi tc dng vi clo di nh sng khuych tn ch to mt sn phm mono clo
duy nht c tn gi l :
A. n pentan B. 2 metyl butan C. 2,2 imetyl propan D. C A, B, C u ng.
Cu 23: Tin hnh hai th nghim.
Th nghim 1: Cho 8,0 gam Cu tc dng vi 150 ml dung dch HNO3 1M, kt thc phn ng thu c x mol kh NO
sn phm kh duy nht.
Th nghim 2: Cho 8,0 gam Cu tc dng vi 150 ml dung dch gm HNO3 1M v H2SO4 0,25M, kt thc phn ng
thu c y mol kh NO sn phm kh duy nht. Quan h gia x v y l:
A. x=y B. x=2y C. 1,5x=y D. 2x=y
Cu 24: X l hp cht thm c cng thc phn t C7H8O, s ng phn ca X phn ng vi Na gii phng kh H2l.
217 | G S T T G R O U P
A. 4 B. 3 C. 2 D. 5
Cu 25: Cho hn hp bt gm 2,7 gam Al v 11,2 gam Fe vo 540 ml dung dch AgNO3 1M. Sau khi cc phn ng
xy ra hon ton, thu c m gam cht rn. Gi tr ca m l
A. 3,24. B. 64,8. C. 59,4. D. 62,8.
Cu 26: Cho mt hn hp A cha NH3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol
HCl. A cng phn ng va vi 0,075 mol Br2 to kt tA. Lng cc cht NH3, C6H5NH2 v C6H5OH ln lt
bng?
A. 0,01 mol; 0,005 mol v 0,02 mol B. 0,005 mol; 0,005 mol v 0,02 mol
C. 0,005 mol; 0,02 mol v 0,005 mol D. 0,01 mol; 0,005 mol v 0,005 mol
Cu 27: Ho tan hon ton 51,24 gam hn hp X gm R2CO3 v RHSO3 (R l kim loi kim) bng dung dch HCl d,
thu c 8,96 lt hn hp kh Y ktc. R l kim loi no sau y.
A. Li B. Na C. K D. Rb
Cu 28: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui
khan. Cng thc cu to thu gn ca X l:
A. H2NCH2COOH. B. H2NCH2CH2COOH. C. CH3CH(NH2)COOH. D. CH3CH2CH(NH2)COOH.
Cu 29: Cho 16,8 gam Fe tan ht trong dung dch HNO3 thu c dung dch X (khng c NH
4
+
) v V lt hn hp kh
Y ( ktc) gm N2O v NO c t l mol tng ng 1:2. X tc dng vi dung dch NaOH d , ly kt ta thu c
nung trong chn khng ti khi lng khng i c 22,4 gam cht rn. Gi tr ca V l.
A. 2,24 B. 3,36 C. 1,44 D. 4,32
Cu 30: Cu tc dng vi dung dch bc nitrat theo phng trnh ion rt gn:
Cu + 2Ag
+
Cu
2+
+ 2Ag. Trong cc kt lun sau, kt lun sai l:
A. Cu
2+
c tnh oxi ho yu hn Ag
+
B. Cu c tnh kh yu hn Ag
C. Ag
+
c tnh oxi ho mnh hn Cu
2+
D. Ag c tnh kh yu hn Cu
Cu 31: Cho m gam hn hp G gm Al, Fe, Cu, Mg nung trong bnh cha oxi sau mt thi gian thu c 2,63 gam
hn hp H. Ha tan ht H trong dung dch HNO3 d, thu c 0,448 lt kh NO (sn phm kh duy nht, ktc).
S mol HNO3 tham gia phn ng l 0,14 mol, gi tr ca m l.
A. 2,15 B. 2,47 C. 2,36 D. 2,42
Cu 32: un nng hn hp gm 2 ancol ng ng lin tip vi H2SO4 140. Sau khi kt thc phn ng thu c
6(g) hn hp 3 ete v 1,8g H2O. Cng thc phn t 2 ancol trn l:
A. CH3OH v C2H5OH B. C2H5OH v C3H7OH C. C3H5OH v C4H7OH D. C3H7OH v C4H9OH
Cu 33: C cc dung dch: HCl, HNO3, NaOH, AgNO3, NaNO3 ng trong cc l ring bit b mt nhn. Ch dng thm
mt thuc th no cho di y nhn bit.
A. Cu B. Dung dch H2SO4 C. Dung dch BaCl2 D. Dung dch Ca(NO3)2
Cu 34: t chy hon ton 0,1 mol ancol no X cn dng 7,84 lt oxi (ktc). Cng thc ca X l:
A. C3H5(OH)3 B. C3H6(OH)2 C. C3H5OH D. Kt qu khc
Cu 35: Cho 2,00 mol NaOH vo dung dch X c cha a mol HCl v 0,48 mol Al(NO3)3 kt thc phn ng thu c
21,84 gam kt tA. Gi tr nh nht ca a l.
A. 0,42 B. 1,16 C. 0,36 D. 0,84
Cu 36: Hn hp 2 este no n chc mch h. t chy hon ton mt lng X cn dng va 3,976 lit O2 ktc,
thu c 6,38g CO2. Mt khc X tc dng vi dung dch NaOH thu c mt mui v 2 ancol l ng ng lin tip.
Cng thc phn t 2 este l:
A. C2H4O2 v C3H6O2 B. C3H6O2 v C4H8O2 C. C3H4O2 v C4H6O2 D. C4H8O2 v C5H10O2
Cu 37: Cho hn hp A gm 0,20 mol Al, 0,41 mol Fe phn ng vi V lt dung dch HNO3 1,25M, kt thc phn ng
thu c dung dch B, hn hp G gm 0,05 mol N2O v 0,04 mol N2 v cn 6,16 gam kim loi. Gi tr V l
A. 1,184 B. 1,482 C. 1,344 D. 1,104
Cu 38: Sp xp cc cht sau y theo tnh baz gim dn? C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH( 3) (C2H5)2NH
(4), NaOH (5), NH3 (6).
A. 1>3>5>4>2>6 B. 5>4>2>6>1>3 C. 5>4>2>1>3>6 D. 6>4>3>5>1>2
218 | L O V E B O O K . V N
Cu 39: Phn ng C6H5ONa + CO2 + H2O C6H5OH + NaHCO3 xy ra c l do.
A. Phenol c tnh axit yu hn axit cacbonic B. Phenol c tnh axit mnh hn axit cacbonic
C. Phenol c tnh oxi ha yu hn axit cacbonic D. Phenol c tnh oxi ha mnh hn axit cacbonic
Cu 40: Phn ng ha hc no sau y trong cc phn ng ha hc v c lun lun l phn ng oxi ha kh.
A. Phn ng th B. Phn ng ha hp C. Phn ng phn hu D. Phn ng axit baz
Cu 41: C 2 hp cht hu c (X); (Y) cha cc nguyn t C, H, O khi lng phn t u bng 74. Bit (X) tc
dng c vi Na, c (X) v (Y) u tc dng c vi NaOH v dung dch AgNO3/NH3. Vy (X), (Y) c th l.
A. C4H9OH v CH3COOCH3 B. OHC-COOH v HCOOC2H5
C. OHC-COOH v C2H5COOCH3 D. CH3COOCH3 v HOC2H4CHO
Cu 42: Cng thc no di y ng
A. C3H5(OH)2 B. C4H5OCl2 C. C3H5Cl3 D. CH4N
Cu 43: Trong t nhin oxi c ba ng v O,
8
16
O
8
17
, O
8
18
, hiro c ba ng v H
1
1
, H
1
2
, H
1
3
. S phn t H2O c th to ra
l:
A. 12 B. 18 C. 15 D. 9
Cu 44: Dn hi ca 3,0 gam etanol i qua ng s nung nng cha bt CuO (ly d). Lm lnh ngng t sn
phm hi i qua khi ng s, c cht lng X. Khi X phn ng hon ton vi lng d dung dch AgNO3/NH3
thy c 8,1 gam bc kt ta. Hiu sut ca qut trnh oxi ha etanol l.
A. 57,5% B. 60% C. 55,7% D. 75%
Cu 45: Bit X l mt aminoaxit. Khi cho 0,01mol X phn ng va vi 80ml dung dch HCl 0,125M v thu c
1,835g mui khan. Mt khc khi cho 0,01 mol X tc dng vi dung dch NaOH th cn 200ml dung dch NaOH 0,1M.
CTPT ca X l:
A. C2H5(NH2)COOH B. C3H6(NH2)COOH C. C3H5(NH2)COOH D. C3H5(NH2)(COOH)2
Cu 46: Trong s n mn tm tn (l st trng km) khi ngoi khng kh m th:
A. St b n mn, km c bo v. B. Km b kh, st b oxi ho.
C. Km l cc m, st l cc dng. D. St b kh, km b oxi ho.
Cu 47: Ln men m gam tinh bt thnh ancol etylic vi hiu sut 81%. Ton b lng CO2 sinh ra hp th hon
ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch X. un k dung dch X thu thm c 100
gam kt ta. Ga tr ca m l:
A. 550 B. 810 C. 650 D. 750
Cu 48: Cho t t 100 ml dung dch A cha H2SO4 0,5M v HCl 1,5M vo 200 ml dung dch B gm KHCO3 0,5M v
Na2CO3 1,0M. thu c V (lit) kh CO2 (ktc) v dung dch X. Cho dung dch Ba(OH)2 n d vo dung dch X thu
c m gam kt ta. Gi tr ca m v V ln lt l:
A. 60,90 gam v 1,12 lit B. 49,25 gam v 1,12 lit C. 39,40 gam v 2,24 lit D. 29,55 gam v 2,24 lit
Cu 49: Hn hp X gm 1 ankin th kh v Hir c t khi hi so vi CH4 l 0,425. Nung nng hn hp X vi xc
tc Ni phn ng hon ton thu c hn hp kh Y c t khi hi so vi CH4 l 0,8. Cho Y i qua bnh ng dung
dch Brm d, khi lng bnh tng ln bao nhiu gam:
A. 8 B. 16 C. Bnh Br2 khng tng D. Khng tnh c
Cu 50: Dung dch X cha NaOH 0,1M. Dung dch Y c pH=1. Trn 2,525 lt dung dch X vi 2,475 lt dung dch Y
thu c 5,0 lt dung dch Z. Tnh pH ca dung dch Z.
A. 12 B. 10 C. 11 D. 3

P N

1C 2A 3A 4C 5D 6B 7D 8C 9A 10A
11C 12D 13A 14D 15C 16B 17B 18B 19D 20A
21B 22C 23C 24A 25D 26B 27C 28D 29B 30B
31A 32A 33A 34A 35C 36B 37A 38B 39A 40A
41B 42C 43B 44A 45D 46C 47D 48A 49C 50C
219 | G S T T G R O U P

Cu 1: p n C
Ta c n
H
2
= 0,25 mol, s mol ancol bng 2 ln s mol kh Hidro n
ancol
= 2n
H
2
= 0,5 mol
Gi s mol CO
2
l x s mol H
2
O = x +0,5 (v ancol no n chc nn ta c n
H
2
O
n
CO
2
= n
ancol
)
Ta c n
O2
= 2,1 mol . X v Y u cha cc ancol n chc nn n
O
trong ancol bng n
ancol

Theo bo ton Oxi ta c: 2x +0,5 = 2,1.2 +0,5
n
CO
2
= 1,4 mol; ta c C =
n
CO
2
n
ancol
=
1,4
0,5
= 2,8
v trong p n C, ta c C < 2 nn chn
Cu 2: p n A
V khi oxit ca X phn ng vi nc, dung dch thu c lm qu tm nn dung dch c tnh axit nn
oxit ca X l oxit axit
Tng t, oxit ca Y phn ng vi nc to ra dung dch c tnh baz oxit ca Y l oxit baz
V oxit ca Z tc dng vi c dung dch axit v dung dch kim nn oxit ca Z l oxit lng tnh
Suy ra Y l kim loi mnh, X l phi kim, tnh kim loi ca Z yu hn Y v ln hn X
Cu 3: p n A
Nilon-6,6 l sn phm ca phn ng ng trng ngng hexametyleniamin v axit adipic
Cu 4: p n C
Dng NaHCO
3
v H
2
SO
4
va thu c CO
2
tinh khit va lm tng lng kh CO
2

Ta nn s dng cch thu c cht tinh khit ng thi tng lng cht cn iu ch
Cu 5: p n D
Ta c n
CO2
= 0,2 mol nh vy s C trong cng thc ca A =
0,2
0,05
= 4
loi p n v
Chn p n v p n c ng phn cis trans, khi phn ng vi HBr to ra 2 sn phm
Cu 6: p n B
n
Al
= 0,18 mol
8Al +3Fe
3
O
4
t
o
4Al
2
O
3
+9Fe
Khi ha tan cc cht thu c sau phn ng nhit nhm bng dung dch Ba(OH)
2
, khng c cht kh thot
ra nn Al phn ng ht.
n
Fe
=
0,18.9
8
= 0,2025 m
Fe
= 11,34 m
Fe
3
O
4
d = 23,52 11,34 = 12,18 g
m
Fe
3
O
4
=
11,34
56.3
. 232 +12,18 = 27,84 g
Cu 7: p n D
Cc trng hp xy ra phn ng oxi ha kh l:
Cho FeO vo dung dch H
2
SO
4
c nng
Cho Fe vo dung dch Fe(NO
3
)
3

Cho Fe(NO
3
)
2
vo dung dch HCl
Cho AgNO
3
vo dung dch Fe(NO
3
)
2

Cu 8: p n C
Theo quy tc mc cp nhi cp: E l sn phm chnh E l but 2 en
Cu 9: p n A
Dung dch KMnO
4
s oxi ha ion Fe
2+
thnh Fe
3+
v oxi ha ion Cl
thnh CL
2

Ta c tng s mol e nhng = n
Fe
2+ +n
Cl
= 0,5 mol
Mn
+7
+5eMn
+2
n
Mn
+7 =
0,5
5
= 0,1 mol
220 | L O V E B O O K . V N
n
KMnO
4
= 0,1 V
dd KMnO
4
= 0,1.1 = 0,1 (lt)
Cu 10: p n A
X l ancol n chc, no, h nn c dng C
n
H
2n+2

T l andehi n chc khng no, h c mt lin i nn c dng C
n
H
2n2
O
Cu 11: p n C
NH
4
Cl
t
o
NH
3
+HCl
(NH
4
)
2
SO
4
t
o
2NH
3
+H
2
SO
4

NH
4
HCO
3
t
o
NH
3
+H
2
O +CO
2

(NH
4
)
2
CO
3
t
o
2NH
3
+H
2
O +CO
2

Cc cu cn li sai do khi nhit phn NH
4
NO
2
v NH
4
NO
3
khng thu c NH
3
:
NH
4
NO
3
t
o
N
2
O +2H
2
O
NH
4
NO
2
t
o
N
2
+2H
2
O
Cu 12: p n D
Ta c khi khi lng tnh bng n v kg th th tch tnh bng n v m
3

m
PVC
= 1000 (kg) m
CH
2
CHCl
= 1111,1 n
CH
2
CHCl
= 17,77 n
C
2
H
2
= 18,71
n
CH
4
= 249,51 V
CH
4
= 5589, 08 V
kh thin nhin
=
5589,08.100
95
= 5883,246 (m
3
)
Cu 13: p n A
2CO +O
2
t
o
2CO
2

Ta thy s th tch kh gim chnh l s th tch O
2
phn ng
V
CO
= 2V
kh gim
= 4 (lt) V
O2
= 8 (lt) v V
CO2
= 16 4 8 = 4 (lt)
Cu 14: p n D
V metylxiclopropan c vng 3 cnh lm mt mu dung dch Br
2
nn khng nh l khng ng
Cu 15: p n C
BaCO
3
t
o
BaO +CO
2

V sau khi un nng dd Y vn thu c kt ta nn trong Y cn c Ba(HCO
3
)
2

n
BaCO
3
thu c ln u =
22,95
197
= 0,15 mol, n
Ba(HCO
3
)
2
= 0,2 0,15 = 0,05 mol
n
CO
2
= n
BaCO
3
+2n
Ba(HCO
3
)
2
= 0,15 +0,05.2 = 0,25 (mol)
m = 0,25.197 = 49,25 g
Cu 16: p n B
Ta c n
este
=
66,6
74
= 0,9 mol n
ancol
= 0,9 mol (v s mol ancol bng s mol este)
Khi un nng hn hp X vi H
2
SO
4
c 140
0
C, xy ra phn ng to ete
n
H
2
O
=
n
ancol
2
=
0,9
2
= 0,45 mol m
H
2
O
= 0,45.18 = 8,1 (g)
Cu 17: p n B
n
HCl
= 0,4 mol n
H
2
SO
4
= 0,2 mol
V s mol ca FeO v Fe
2
O
3
bng nhau, m trong Fe
3
O
4
s mol ca FeO bng s mol Fe
2
O
3

Ta coi trong hn hp X ch gm FeO v Fe
2
O
3
t s mol hai cht ln lt l x v y
Ta c h phng trnh {
2x y = 0
2x +3y = 0,4 +0,2.2
{
x = 0,1
y = 0,2
n
Fe
= 0,3 mol
Vy khi lng mui khan thu c l: 0,3.56 +0,4.0,4 +0,2.96 = 50,2 (g)
Cu 18: p n B
T phn ng C
6
H
5
ONa +CO
2
+H
2
O C
6
H
5
OH+NaHCO
3

221 | G S T T G R O U P
tnh axit ca H
2
CO
3
mnh hn tnh axit ca phenol
Cu 19: p n D
Khi cho hn hp X vo nc d, ch mt phn Al phn ng vi OH
do Ba phn ng to ra
Khi cho X vo dung dch NaOH d th c Ba v Al u phn ng ht.
phn ng 1:
Ba +2H
2
O Ba(OH)
2
+H
2

Al +H
2
O +OH
AlO
2
+
3
2
H
2

n
kh
= 0,04 mol
t s mol Ba l x ta c phng trnh x +3x = 0,04 x = 0,01
phn ng 2:
n
kh
= 0,055 mol ta c: n
Al
=
0,055 0,01
3
2
= 0,03 (mol)
vy m = 0,01.137 +0,03.27 = 2,18 g
Cu 20: p n A
V T trng bc ra amonicrylat nn T l CH
2
CHCHO (andehit)
Suy ra Z l ancol CH
2
CHCH
2
OH
Li c Z khng no nn X l C
3
H
6

Cu 21: p n B
V HF l cht in ly yu nn phng trnh ion rt gn phi c cht phn ng HF
Cu 22: p n C
Cu 23: p n C
3Cu +8H
+
+2NO
3
3Cu
2+
+2NO +4H
2
O
t phng trnh trn trong th nghim 1 v 2 ta tnh c n
NO
ln lt l 0,0375 v 0,05625 mol
Cu 24: p n A
X l cht thm c 1 O trong phn t, tc dng vi Na to kh H
2
X l ancol hoc phenol
C
6
H
4
OHCH
3
(3 ng phn)
C
6
H
5
CH
2
OH (1 ng phn)
Cu 25: p n D
n
Al
= 0,1 mol; n
Fe
= 0,2 mol; n
Ag
= 0,54 mol
Ta c st d, n
Fe
phn ng =
(0,54 0,1.3)
2
= 0,12 n
Fe
d = 0,2 0,12 = 0,08 (mol)
Vy m = 0,08.56 +0,54.108 = 62,8 (g)
Cu 26: p n B
Gi s mol ca NH
3
, C
6
H
5
NH
2
, C
6
H
5
OH ln lt l x, y, z
Ta c C
6
H
5
OH phn ng vi NaOH. NH
3
v C
6
H
5
NH
2
phn ng vi HCl
C
6
H
5
NH
2
v C
6
H
5
OH phn ng vi Br
2
to kt ta vi t l 1: 3
Ta c h phng trnh: {
z = 0,02
x +y = 0,01
y +z =
0,075
3
{
x = 0,005
y = 0,005
z = 0,02

Cu 27: p n C
Gi s mol R
2
CO
3
v RHSO
3
l x v y, ta c h phng trnh:
{
(2R +60)x +(R +61)y = 51,24
x +y =
8,96
22,4
= 0,4

Th trc tip p n ta c R l K
Cu 28: p n D
Khi amino axit tc dng vi HCl, phn t khi ca sn phm s tng ln 36,5
222 | L O V E B O O K . V N
Theo nh lut tng gim khi lng n
X
= n
HCl
=
13,95 10,3
36,5
= 0,1 mol
M
X
=
10,3
0,1
= 103 p n
Cu 29: p n B
n
Fe
= 0,3 mol. Ta c 22,4 gam cht rn l oxit st, nn n
O
=
22,4 16,8
16
= 0,35 mol
n
e Fe nhng
= 0,35.2 = 0,7 (mol)
n
e nhn
= 0,7 mol
Gi s mol N
2
O v NO ln lt l x v y, ta c h {
2x y = 0
8x +3y = 0,7
{
x = 0,05
y = 0,1

Vy V = (0,05 +0,1). 22,4 = 3,36 (lt)
Cu 30: p n B
Cu c tnh kh mnh hn Ag
Cu 31: p n A
NO l sn phm kh duy nht, n
NO
= 0,02 mol
Ta c s mol e kim loi nhng = n
NO
3
= 0,14 0,02 = 0,12 (mol)
S mol e m kh O
2
nhn l: 0,12 0,02.3 = 0,06 (mol)
n
O
2
= 0,015 mol m
O
2
= 0,48 g
m = m
H
m
O
2
= 2,63 0,48 = 2,15 (g)
Cu 32: p n A
n
H
2
O
= 0,1 mol n
ancol
= 2n
H
2
O
= 0,2 mol (v 2 mol ancol phn ng to 1 mol H
2
O)
M
ancol
=
6 +1,8
0,2
= 39 p n
Cu 33: p n A
Dng Cu ta nhn c HNO
3
: Cu tan, c kh thot ra, dung dch chuyn mu xanh
Cu cng nhn c AgNO
3
: c lp kim loi bc tch ra dung dch, dd chuyn mu xanh
Dng AgNO
3
nhn c HCl (c kt ta trng)
Dng dung dch CuNO
3
(khi Cu phn ng vi bc nitrat) nhn c NaOH (kt ta trng)
Cht cn li l NaNO
3

Cu 34: p n A
n
ancol
= 0,1 mol; n
O
2
= 0,35 mol
Cc p n u c dng C
3
H
8
O
n

Ta c phng trnh phn ng: C
3
H
8
O
n
+
10 n
2
O
2
t
o
3CO
2
+4H
2
O
1
10 n
2

Ta c phng trnh: 0,1.0,5. (10 n) = 0,35 n = 3 p n
Cu 35: p n C
n
Al(OH)
3
= 0,28 mol
a nh nht th NaOH phi ha tanmt phn kt ta hidroxit nhm
n
NaOH
phn ng vi Al
3+
l 0,28.3 +(0,48 0,28). 4 = 1,64 mol
Vy gi tr nh nht ca a l 2 1,64 = 0,36 (mol)
Cu 36: p n B
n
O
2
= 0,1775 mol; n
CO
2
= 0,145 mol
V este no n chc mch h nn n
H
2
O
= n
CO
2
= 0,145 mol
Theo bo ton oxi, n
este
=
n
O (este)
2
=
0,145.3 0,1775.2
2
= 0,04 (mol)
223 | G S T T G R O U P
Theo bo ton khi lng, ta c m este = 3,31 g
M
este
=
3,31
0,04
= 82,75 chn p n
Cu 37: p n A
6,16 gam kim loi l Fe, v Fe d nn Fe Fe
2+
v khng to ion Fe
3+

n
Fe phn ng
= 0,41
6,16
56
= 0,3 mol
n
e nhng
= 0,2.3 +0,3.2 = 1,2 (mol)
Vy trong sn phm c NH
4
NO
3
, n
NH
4
NO
3
=
1,2 0,05.8 0,04.10
8
= 0,05 mol
Theo nh lut bo ton N:
S mol HNO
3
= n
NO
3
+n
NH
4
NO
3
+2n
N
2
O
+2n
N
2
1,2 +0,05.2 +0,05.2 +0,04.2 = 1,48 mol
V =
n
HNO
3
C
M
=
1,48
1,25
= 1,184 (lt)
Cu 38: p n B
V NaOH l baz mnh nn c tnh baz mnh hn cc amin
Tnh baz ca amin ph thuc vo nhmR lin kt vi N
Cc nhm CH
3
, C
2
H
5
y e, lm tng tnh baz cho amin
NhmC
6
H
5
ht e, lm gim tnh baz ca amin
Cu 39: p n A
Phenol c tnh axit yu hn axit cacbonic nn b axit cacbonic y ra khi mui Natri phenolat
Cu 40: p n A
Phn ng th trong cc phn ng ha hc v c l phn ng m mt nguyn t c hot ng ha
hc mnh hn thay th nguyn t hot ng ha hc yu hn trong hp cht ca nguyn t .
V l n cht phn ng vi hp cht lun l phn ng oxi ha kh.
Cu 41: p n B
V X v Y tc dng c vi AgNO
3
/NH
3
nn ch c tha mn.
Cu 42: p n C
Cu 43: p n B
Chn 1 nguyn t O: c 3 cch chn
S cp H c th chn l 6 (1 1,2 2,3 3,1 2,2 3,3 1)
c 18 phn t H
2
O c th to thnh
Cu 44: p n A
n
CH
3
CH
2
OH
=
3
46
mol
CH
3
CH
2
OH+CuO
t
o
CH
3
CHO +Cu +H
2
O
n
Ag
= 0,075 mol n
CH
3
CHO
= 0,0375 mol
Vy H =
0,0375
3/46
. 100%= 57,5 (%)
Cu 45: p n D
n
HCl
= 0,01 mol; n
NaOH
= 0,02 mol
S mol HCl bng s mol X v s mol NaOH bng 2 ln s mol X
trong X c 1 nhmNH
2
v 2 nhmCOOH p n
Cu 46: p n C
y l s n mn in ha
Cu 47: p n D
V khi un nng dung dch X to ra kt ta nn trong X vn cn Ca(HCO
3
)
2

224 | L O V E B O O K . V N
Ta c n
CO
2
=
550
100
+2.
100
100
= 7,5 mol
V 1 mol tinh bt 2 mol CO
2
m
tinh bt
=
7,5
2
.
100
81
. 162 = 750 (g)
Cu 48: p n A
Kt ta bao gm BaSO
4
v BaCO
3

n
H
+ = 0,1.2.0,5 +0,1.1,5 = 0,25 mol
n
CO
3
2 = 0,2 mol; n
HCO
3
= 0,1 mol
Vy n
CO
2
= 0,05 mol V = 1,12 (l)
m = m
BaSO
4
+m
BaCO
3
= 0,05.233 +0,25.197 = 60,9 (g)
Cu 49: p n C
Sau khi nung nng hn hp X, t khi hi ca Y = 12,8 < M
CH
4
nn H
2
d
Vy cc kh trong Y u no
nn khi Y qua bnh Br
2
, khng c phn ng xy ra bnh Br
2
khng tng
Cu 50: p n C
n
OH
= 0,1.2,525 = 0,2525 mol; n
H
+ = 2,475.0,1 = 0,2475 mol
Khi trn dung dch X v Y: n
OH
= 0,2525 0,2475 = 0,005 (mol) [OH
] = 0,001 M
pOH
dd Z
= 3 pH
dd Z
= 14 3 = 11

225 | G S T T G R O U P
s 34

Cu 1: t chy hon ton 2 amin no n chc mch h l ng ng k tip thu c V
CO
2
: V
H
2
O
= 7: 13. Nu cho
24,9 gam hn hp X tc dng va vi hn hp Y gm HCOOH v CH
3
COOH c t l mol tng ng l 1:3 th
khi lng mui thu c l:
A. 54,6 B. 50,4 C. 58,8 D. 26,1
Cu 2: Cho 18,2 gam hn hp X gm Al, Cu vo 100ml dung dch Y cha HNO3 2M v H2SO412M ri un nng thu
c dung dch Z v 8,96 lit Kh M (kc) gm NO v SO2 (ngoi ra khng c sn phm kh no khc), t khi ca
M so vi H2 l 23,5. Tng khi lng cht tan trong dung dch Z l:
A. 96,8gam. B. 115,2gam C. 66,2gam D. 129,6gam
Cu 3: Khi lng phn t trung bnh ca xenlulozo trong si bng l 1750000 vc, cn trong si gai l 5900000
vc. S mt xch trung bnh trong cng thc phn t xenlulozo ca mi loi si tng ng l:
A. 10802 v 36420 B. 12500 v 32640 C. 32450 v 38740 D. 16780 v 27900
Cu 5: Trn m gam dung dch AlCl3 13,35% vi m gam dung dch Al2(SO4)3 17,1% thu c 350 gam dung dch A
trong s mol ion Cl
bng 1,5 ln s mol SO

4
2
. Thm 81,515 gam Ba vo dung dch A thu c bao nhiu gam
kt ta?
Cu 4: Cho 6,72 lt hn hp X gm 2 hidrocacbon mch h th kh thnh 2 phn bng nhau:
Phn 1: Cho tc dng vi dung dch brom d thy c 16 gam Br
2
phn ng.
Phn 2: t chy hon ton thu c 17,6 gam CO
2
.
Bit rng 2 hodrocacbon trong X hn km nhau mt nguyn t C. Hai hidrocacbon trong X v phn trm th tch
ca chng l:
A. CH
4
(66,67%); C
3
H
4
(33,33%)
B. C
2
H
2
(33,33%); C
3
H
8
(66,67%) hoc C
2
H
6
(33,33%); C
3
H
6
(66,67%)
C. Ch c th C
2
H
6
(33,33%); C
3
H
6
(66,67%)
D. Ch c th C
2
H
2
(33,33%); C
3
H
8
(66,67%)
Cu 5: Ha tan hn hp gm Mg v Al vo dung dch HNO
3
va thu c dung dch X khng cha mui amoni
v 0,336 lt N
2
O (ktc) thot ra duy nht. Nu cho t t dung dch NaOH 1M vo dung dch X n khi khi lng
kt ta t gi tr 2,52 gam th th tch dung dch NaOH ti thiu dng l 90ml (gi s Mg(OH)
2
kt ta ht
trc khi Al(OH)
3
bt u kt ta trong dung dch kim). Phn trm khi lng ca Mg trong hn hp ban u
l:
A. 42,86% B. 57,14% C. 36% D. 69,23%
Cu 6: Hp th hon ton 3,36 lt CO
2
(ktc) vo 100 ml dung dch gm Na
2
CO
3
0,25M v KOH a
mol/lt, sau khi cc phn ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch
Ca(NO3)
2
(d), thu c 7,5 gam kt ta. Gi tr ca a l
A. 2,0. B. 1,2. C. 1,0. D. 1,4.
A. Nguyn t ca nguyn t phi kim lun c 4, 5, 6 hoc 7 electron lp ngoi cng, cn nguyn t ca nguyn
t kim loi lun ch c 1, 2 hay 3 electron lp ngoi cng.
B. So vi nguyn t phi kim cng chu k, nguyn t ca nguyn t kim loi c bn knh nguyn t ln hn,
nng lng ion ha nh hn.
C. Cc kim loi thng c nh kim, c tnh do v c kh nng dn in, dn nhit cn cc phi kim thng
khng c nhng tnh cht ny.
D. Trong phn ng ha hc, kim loi lun ch ng vai tr cht kh, cn phi kim thng c th l cht kh
hoc cht oxi ha.
Cu 8: Cht X c cng thc phn t l C4H6O2Cl2. Khi cho X phn ng vi dung dch NaOH thu c CH2OHCOONa,
etylenglycol v NaCl. Cng thc cu to ca X l:
A. CH2Cl-COO-CH2-CH2Cl. B. CH2Cl-COO-CHCl-CH3. C. CHCl2-COOCH2CH3. D. CH3-COO-CHCl-CH2Cl.
226 | L O V E B O O K . V N
Cu 9: C 4 ha cht : metylamin (1), phenylamin (2), iphenylamin (3), imetylamin (4). Th t tng dn lc baz
l :
A. (1) < (3) < (2) < (4). B. (4) < (1) < (2) < (3).
C. (3) < (2) < (1) < (4). D. (2) < (3) < (1) < (4).
Cu 10: Ln men 1 tn tinh bt cha 5% tp cht tr thnh ancol etylic, hiu sut mi qu trnh ln men l 85%.
Nu em pha long ancol thnh ancol 40
o
(khi lng ring ca ancol etylic nguyn cht l 0,8 g/cm
3
) th th
tch dung dch ancol thu c l
A. 1225,1 lt B. 1852,1 lt C. 1812,1 lt D. 1218,1 lt
Cu 11: Hn hp M gm ancol no, n chc X v axit cacboxylic Y, u mch h v c cng s nguyn t cacbon.
Tng s mol ca hn hp M l 0,5mol (s mol X nh hn s mol Y). Nu t chy hon ton M thu c 33,6 lit
kh CO2 (kc) v 25,2g H2O. Mt khc, nu un nng M vi H2SO4 c thc hin phn ng Este ha vi hiu sut
l 75%. Tnh khi lng Este thu c:
A. 22,8 gam. B. 25,65 gam C. 17,1 gam. D. 18,24 gam.
Cu 12: Th tch dung dch Ba(OH)2 0,025M cn cho vo 100ml dung dch hn hp gm HNO3 v HCl c pH = 1,
thu c dung dch c pH =2 l :
A. 0,224 lt B. 0, 336 lt C. 0,15 lt D. 0,448 lt
Cu 13: Ho tan ht mt lng S v 0,01 mol Cu2S trong dung dch HNO3 c nng, sau khi phn ng hon ton
dung dch thu c ch c 1 cht tan v sn phm kh l kh NO2 duy nht. Hp th ht lng NO2 ny vo 200ml
dung dch NaOH 1M, ri c cn dung dch sau phn ng thu c m gam cht rn khan. Gi tr ca m l:
Cu 14: Cho 16,8 lt (ktc) hn hp X gm hiro v vinylaxetilen, t khi ca X so vi heli bng 3. Nung nng hn
hp X (xc tc Ni) mt thi gian thu c hn hp kh Y c t khi so vi heli bng 5. Dn hn hp Y qua bnh
ng nc brom d thy phn ng xy ra hon ton. Tnh khi lng brom tham gia phn ng?
Cu 15: Nguyn t X c tng s electron trong phn lp p l 9. Nguyn t Y c tng s ht c bn (p, n, e) l 82, s
ht mang in nhiu hn s ht khng mang in l 22. X v Y l cc nguyn t:
A. N v Co B. P v Fe C. F v Fe D. P v Ni
Cu 16: C 200 ml dung dch hn hp Cu(NO3)2 v AgNO3, in phn ht ion kim loi trong dung dch cn dng
cng dng in 0,402A trong 4 gi. Sau khi in phn xong thy c 3,44 gam kim loi bm catot. Nng
mol ca Cu(NO3)2 v AgNO3 trong hn hp u ln lt l:
A. 0,1 M v 0,2 M B. 0,2 M v 0,1 M C. 0,2 M v 0,2 M D. 0,1 M v 0,1 M
Cu 17: Khi cho Ba(OH)2 d vo dung dch cha FeCl3 , CuSO4 , AlCl3 thu c kt ta. Nung kt ta trong khng
kh n khi khi lng khng i, thu c cht rn X. Trong cht rn X gm:
A. Fe2O3 , CuO B. Fe2O3 , CuO , BaSO4 C. Fe3O4 , CuO , BaSO4 D. FeO , CuO , Al2O3
Cu 18: Ha tan m gam hn hp Cu v Fe2O3 trong dung dch HCl d, thu c dung dch X v cn 6,4 gam cht
rn khng tan. C cn dung dch X thu c 46,68 gam cht rn khan. Gi tr ca m?
A. 36,48 gam. B. 48,96 gam. C. 33.28 gam. D. 26,88 gam.
Cu 19: Thi mt lung CO d qua ng s ng hn hp Fe3O4 v CuO nung nng n phn ng hon ton, ta thu
c 2,32 g hn hp kim loi. Kh thot ra cho vo bnh ng nc vi trong d thy c 5g kt ta trng. Khi
lng hn hp 2 oxit kim loi ban u l bao nhiu?
A. 4,2g. B. 3,12g C. 3,22g D. 4g
Cu 20: Thy phn hp cht:
H2N-CH(CH3)-CO-HN-CH2-CH2-CO-HN-CH2-CO-HN-CH(C6H5)-COOH th thu c bao nhiu -Aminoaxi?
A. 2. B. 3. C. 4 D. 5.
Cu 21: Sn phm chnh to thnh khi cho 2-brombutan tc dng vi dung dch KOH/ancol, un nng
A. but-2-en. B. but-2-ol. C. but-1-en. D. metylxiclopropan.
Cu 22: linh ng ca nguyn t hiro trong phn t cc cht sau gim dn theo th t
A. axit axetic > ancol etylic > phenol > ancol benzylic
B. ancol benzylic > ancol etylic > phenol > axit axetic
C. axit axetic > phenol > ancol etylic > ancol benzylic
D. phenol > ancol benzylic > axit axetic > ancol etylic
Cu 23: nhn bit cc cht etanol, propenol, etylenglicol, phenol c th dung cp cht:
227 | G S T T G R O U P
A. Nc brom v dung dch NaOH B. Nc brom v Cu(OH)
2

C. Dung dch NaOH v Cu(OH)
2
D. Dung dch KMnO
4
v Cu(OH)
2

Cu 24: Cho phn ng: FeS + HNO3 Fe(NO3)3 +H2SO4 + NO + H2O. Tng h s cn bng ca phn ng trn l:
A. 14 B. 23 C. 21 D. 25
Cu 25: Hn hp M gm mt ru no A v mt axit n chc B, c hai u mch h. t chy hon ton 0,4 mol
hn hp M phi dng mt lng va 30,24 lt O
2
, sn phm sinh ra gm 52,8 gam CO
2
v 19,8 gam H
2
O. Trong
M hai cht A v B c cng s nguyn t C v n
B
> n
A
. Cng thc ca A, B v s mol ca chng ln lt l:
A. C
3
H
6
(OH)
2
: 0,15 mol; C
3
H
4
O
4
: 0,25 mol B. C
3
H
6
(OH)
2
: 0,15 mol; C
3
H
4
O
2
: 0,25 mol
C. C
3
H
7
OH: 0,1 mol; C
3
H
4
O
4
: 0,3 mol D. C
3
H
6
(OH)
2
: 0,1 mol; C
3
H
4
O
2
: 0,3 mol
Cu 26: Thnh phn chnh ca kh than t l:
A. CO, CO2, H2, NO2 B. CO, CO2, H2, N2 C. CH4, CO2, H2, N2 D. CO, CO2, NH3, N2
Cu 27: em nung hn hp A gm hai kim loi: x mol Fe v 015 mol Cu trong khng kh mt thi gian thu c
63,2 gam hn hp B (gm hai kim loi trn v hn hp cc oxit ca chng). em ha tan ht lng hn hp B trn
bng dung dch dung dch H
2
SO
4
m c thu thu c 0,3 mol SO
2
. Gi tr ca x l:
Cu 28: Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55
gam hn hp mui khan. Khi lng NaOH tham gia phn ng l:
A. 31 gam B. 32,26 gam C. 30 gam D. 31,45 gam
Cu 29: Thm NaOH vo dung dch cha 0,01 mol HCl v 0,01 mol AlCl3. Lng kt ta thu c ln nht v nh
nht ng vi s mol NaOH ln lt l:
A. 0,04 mol v
>
0,05 mol B. 0,02 mol v
>
0,03 mol
C. 0,03 mol v
>
0,04 mol D. 0,01 mol v
>
0,02 mol
Cu 30: Cc anion n nguyn t X
, Y
2
, R
2
ln lt c s ht mang in l 19, 18, 34. Dy sp xp X, Y, R theo th
t gim dn ca tnh phi kim l :
A. X>Y>R B. R>X>Y C. R>Y>X D. X>R>Y
Cu 31: X l -aminoaxit mch thng. Bit rng, 0,01 mol X tc dng va vi 80 ml dung dch HCl 0,125M, thu
c 1,835 gam mui. Mt khc, nu cho 2,940 gam X tc dng va vi NaOH th thu c 3,820 gam mui. Tn
gi ca X l.
A. glyxin. B. alanin. C. axit glutamic. D. lysin.
Cu 32: Ha tan hon ton 17,4 g hn hp 3 kim loi Al, Fe, Mg trong dung dch HCl thy thot ra 13,44 lit kh H2
(ktc). Cn nu cho 34,8 g hn hp tc dng vi dung dch CuSO4 d, lc ly cht rn thu c sau phn ng
tc dng vi dung dch HNO3 th thu c bao nhiu lit khi NO (ktc). (sn phm khng to ra NH
4
+
).
A. 3,36 (lit). B. 8,96 (lit). C. 4,48 (lit). D. 17,92 (lit).
Cu 33: Cho bin ha sau: Xenluloz A B C Caosubuna. A, B, C l nhng cht no.
A. CH3COOH,C2H5OH, CH3CHO.
B. C6H12O6(glucoz), C2H5OH, CH2=CH CH=CH2
C. C6H12O6(glucoz), CH3COOH, HCOOH
D. CH3CHO, CH3COOH, C2H5OH.
Cu 34: Cho hn hp X gm ancol metylic v hai axit cacboxylic (no, n chc, k tip nhau trong dy ng ng)
tc dng ht vi Na, gii phng ra 6,72 lt kh H2 (ktc). Nu un nng hn hp X (c H2SO4 c lm xc tc) th
cc cht trong hn hp phn ng va vi nhau to thnh 25 gam hn hp este (gi thit phn ng este ha t
hiu sut 100%). Hai axit trong hn hp X l
A. CH3COOH; C2H5COOH. B. HCOOH; CH3COOH.
C. C2H5COOH; C3H7COOH. D. C2H7COOH; C4H9COOH.
Cu 35: Cho phn ng thun nghch trng thi cn bng: H2(k) + Cl2(k) 2HCl , H <0
Cn bng s chuyn dch theo chiu nghch khi tng:
A. Nng H2 B. p sut C. Nng Cl2 D. Nhit
Cu 36: Este n chc X c t khi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M (un
nng). C cn dung dch thu c 28 gam cht rn khan. Cng thc cu to ca X l.
A. CH2=CH-CH2-COOCH3 B. CH2=CH- COO-CH2-CH3
C. CH3-CH2-COO-CH=CH2 D. CH3-COO-CH=CH-CH3
228 | L O V E B O O K . V N
Cu 37: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l:
A. anilin, metyl amin, amoniac. B. amoni clorua, metyl amin, natri hiroxit.
C. anilin, amoniac, natri hiroxit. D. metyl amin, amoniac, natri axetat.
Cu 38: X phng ho mt este no, n chc X bng NaOH thu c cht hu c Y duy nht cha Na. C cn dung
dch, nung vi vi ti xt thu c mt ancol Z v mt mui v c. t chy hon ton m gam X thu c CO2 v
hi nc theo t l th tch l 3:2. Cng thc phn t ca X l:
A. C3H4O2. B. C2H4O2. C. C3H6O2. D. C4H6O2.
Cu 39: Cho cc cht: axit propionic (X), axit axetic (Y), ancol etylic (Z) v imetyl ete (T). Dy gm cc cht c
sp xp theo chiu tng dn nhit si l
A. Y, T, X, Z. B. Z, T, Y, X. C. T, X, Y, Z. D. T, Z, Y, X.
Cu 40: Cho t t nc brom vo mt hn hp gm phenol v stiren n khi ngng mt mu th ht 300 gam dung
dch nc brom c nng 3,2%. trung ha hn hp cn dng 14,4ml dung dch NaOH 10% (d=1,1gam/cm
3
).
Thnh phn phn trm theo khi lng ca phenol trong hn hp ban u l:
A. 40,4% B. 59,6% C. 36,90% D. 63,4%
Cu 41: Cho s chuyn ho: Fe3O4 + dung dch HI (d) X + Y + H2O. Bit X v Y l sn phm cui cng ca
qu trnh chuyn ho. Cc cht X v Y l:
A. FeI3 v I2 B. Fe v I2. C. FeI3 v FeI2 D. FeI2 v I2
Cu 42: un nng 13,875 gam mt ankyl clorua Y vi dung dch NaOH, tch b lp hu c, axit ha phn cn li
bng dung dch HNO3, nh tip vo dung dch AgNO3 thy to thnh 21,525 gam kt ta. CTPT ca Y l
A. C2H5Cl. B. C3H7Cl. C. C4H9Cl. D. C5H11Cl.
Cu 43: E l hp cht hu c ch cha mt loi nhm chc, cng thc phn t l C6H8O4. Thy phn E (xc tc axit)
thu c ancol X v 2 axit cacboxylic Y, Z c cng thc phn t l CH2O2 v C3H4O2. Ancol X l:
A. ancol etylic. B. etylen glicol. C. ancol anlylic. D. ancol metylic.
Cu 44: Ha tan hon tan 16,2g mt kim loi cha r ha tr bng dung dch HNO3 c 5,6 lt ktc hn hp A
nng 7,2g gm N2 v NO. Kim loi cho l:
A. Cu B. Zn C. Fe D. Al
Cu 45: Qu trnh xy ra in cc catot ca bnh in phn dung dch CuCl2 l :
A. Cu
2+
+ 2e Cu B. Cu Cu
2+
+ 2e C. Cl
-1e Cl D. Cl + 1e Cl

Cu 46: Trn u 0,54 gam bt Al vi bt Fe
2
O
3
v CuO ri tin hnh phn ng nhit nhm thu c hn hp X.
Cho X tc dng ht vi dung dch HNO
3
th c hn hp kh NO v NO
2
c t l mol tng ng 1:3. Th tch kh
NO v NO
2
(ktc) trong hn hp ln lt l:
A. 0,224 lt v 0,672 lt B. 2,24 lt v 6,72 lt C. 0,672 lt v 0,224 lt D. 6,72 lt v 2,24 lt
Cu 47: Hn hp M gm xeton X v anken Y. t chy hon ton mt lng M cn dng va 12,32 lt O
2
(ktc)
sinh ra 8,96 lt CO
2
v 7,2 gam H
2
O. Cng thc cu to thu gn ca X l:
A. CH
3
OCH
3
B. CH
3
OC
2
H
5
C. CH
3
COCH
2
COCH
3
D. C
2
H
5
COCH
3

Cu 48: Chn pht biu khng ng?
A. Cc hp cht CrO, Cr(OH)2 tc dng c vi dung dch HCl; Cr2O3 tc dng c vi dung dch NaOH
B. Hp cht Cr (II) c tnh kh c trng, cn hp cht Cr(VI) c tnh oxi ho mnh
C. Thm dung dch kim vo dung dch mui icromat, mui ny chuyn thnh mui cromat
D. Cc hp cht Cr2O3, Cr(OH)3, CrO, Cr(OH)2 u c tnh cht lng tnh.
Cu 49: Cho dung dch cha a mol Ba[Al(OH)
4
]
2
tc dng va vi dung dch cha b mol HCl. khng cn kt
ta th iu kin cn v l:
A. b 8a B. b=4a C. b 10a D. b = 6a
Cu 50: X l mt Tetrapeptit cu to t Aminoaxit A, trong phn t A c 1 nhm (-NH2) v 1 nhm (-COOH), no,
mch h. Trong A oxi chim 42,67% khi lng. Thy phn m gam X trong mi trng axit th thu c 28,35(g)
tripeptit; 79,2(g) ipeptit v 101,25(g) A. Gi tr ca m l?
A. 184,5. B. 258,3. C. 405,9. D. 202,95.

P N

1C 2B 3A 4B 5B 6A 7A 8A 9C 10D
229 | G S T T G R O U P
11C 12C 13D 14D 15B 16D 17B 18C 19B 20B
21A 22C 23B 24A 25B 26B 27D 28A 29A 30A
31C 32D 33B 34A 35D 36C 37D 38A 39D 40C
41D 42C 43B 44D 45A 46A 47C 48D 49A 50A

230 | L O V E B O O K . V N
s 35

Cu 1: Hn hp A gm tetrapeptit X mch h v tripeptit Y mch h (X, Y u c to t cc -aminoaxit mch
h, cha mt nhm -COOH v mt nhm -NH2 trong phn t) c t l s mol nX : nY = 1 : 3. un nng 68,10 gam
hn hp A vi 780 ml dung dch NaOH 1M (va ), sau khi phn ng kt thc thu c dung dch Z. C cn dung
dch thu c m gam mui. Gi tr ca m l:
A. 94,98 gam. B. 97,14 gam. C. 64,98 gam. D. 65,13 gam
Cu 2: Hn hp X gm mt anehit khng no c mt lin kt i, n chc, mch h (A) v mt anehit no, hai
chc, mch h (B) c cng s nguyn t C. t chy hon ton 9,2 gam hn hp X thu c 10,08 lt CO
2
(ktc).
Mt khc, cho 9,2 gam hn hp X tc dng ht vi dung dch AgNO
3
NH
3
thu c 43,2 gam Ag. Cng thc ca
(A), (B) ln lt l:
A. CH
3
CHO v (CHO)
2
B. C
3
H
5
CHO v C
2
H
4
(CHO)
2

C. C
4
H
7
CHO v C
3
H
6
(CHO)
2
D. C
2
H
3
CHO v CH
2
(CHO)
2

Cu 3:Cho cc th nghim sau:
(1) Nh t t dung dch NaOH cho n d vo dung dch AlCl3.
(2) Sc t t kh CO2 cho n d vo dung dch NaAl(OH)4 (hay NaAlO2).
(3) Sc t t kh CO2 cho n d vo dung dch Ba(OH)2.
(4) Sc t t kh CO2 cho n d vo dung dch C6H5ONa.
(5) Nh t t dung dch NH3 cho n d vo dung dch ZnCl2.
(6) Nh t t dung dch HCl cho n d vo dung dch NaAl(OH)4 (hay NaAlO2).
S th nghim cui cng thu c kt ta l
A. 4 B. 2 C. 1 D. 3
Cu 4: Trong cc cht sau: nc, metylamin, ancol etylic, axit axetic, axeton, axetanehit, glixerol, etylclorua, tristearin.
C bao nhiu cht m gia cc phn t ca n c th c lin kt hiro?
A. 5 B. 8 C. 7 D. 6
Cu 5: Ha tan ht 17,44 gam hn hp gm Fe, Fe3O4, Fe2O3, CuO, Cu, Mg, MgO (trong oxi chim 18,35% v khi
lng) trong dung dch HNO3 long d, kt thc cc phn ng thu c dung dch Y v 0,56 lt (ktc) hn hp kh
Z gm N2 v N2O. T khi ca Z so vi H2 l 18,8. Cho dung dch NaOH ti d vo Y ri un nng, khng c kh thot
ra. S mol HNO3 phn ng vi X l
A. 0,67 B. 0,47 C. 0,57 D. 0,37
Cu 6: C mt s nhn xt v cacbohirat nh sau:
(1) Saccaroz, tinh bt v xenluloz u c th b thu phn.
(2) Glucoz, mantoz, Fructoz u tc dng c vi Cu(OH)
2
OH
v u b kh bi dung dch
AgNO3/NH3.
(3) Tinh bt v xenluloz l ng phn cu to ca nhau.
(4) Phn t tinh bt c cu to bi nhiu gc -glucoz.
(5) Thu phn saccaroz trong mi trng axit thu c fructoz v glucoz.
(6) Glucoz c dng lm thuc, dng trng rut phch, trng gng.
Trong cc nhn xt trn, s nhn xt ng l
A.3 B. 4 C. 5 D.2
Cu 7: trung ha 25,6 gam hn hp 2 axit cacboxylic a chc cn dng 1 lt dung dch hn hp NaOH 0,2M v
Ba(OH)2 0,1M. sau phn ng c cn thu c khi lng mui khan l:
Cu 8: Cho cc cht sau: C2H5OH, C6H5OH, C6H5NH2, dung dch C6H5ONa, dung dch NaOH, dung dch CH3COOH,
dung dch HCl. Cho tng cp cht tc dng vi nhau iu kin thch hp, s cp cht c phn ng xy ra l
A. 9 B. 8 C. 12 D. 10
Cu 9: Cho m gam hn hp X gm FeO, Fe3O4 v Fe2O3 tan trong H2SO4 long va c dung dch Y trong sut.
Chia Y lm 2 phn bng nhau. Phn 1, c cn c 31,6 gam hn hp mui khan. Phn 2, cho mt lung Cl2 d i
qua cho n phn ng hon ton ri c cn c 33,375 gam hn hp mui khan. Gi tr m l
Cu 10: Ha tan mt lng ancol X vo nc thu c 6,4 gam dung dch Y, nng ca X trong Y l 71,875%. Cho 6,4 gam
dung dch Y tc dng vi lng d Na thu c 2,8 lt H2 (ktc). S nguyn t H c trong cng thc phn t ancol X l:
A. 10 B. 4 C. 8 D. 6
231 | G S T T G R O U P
Cu 11: t chy hon ton 4,872 gam mt hirocacbon X, dn sn phm chy qua bnh ng dung dch nc vi
trong. Sau phn ng thu c 27,93 gam kt ta v thy khi lng dung dch gim 5,586 gam. Cng thc phn
t ca X l
A. CH4 B. C4H8 C.C3H6 D. C4H10
Cu 12: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi
NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng. S cht X l:
A. 8 B. 9 C. 10 D. 7
Cu 13: X l hn hp kh H2 v N2 c t khi i vi oxi bng 0,225. Dn X vo bnh kn c xc tc bt st, un nng
th thu c hn hp kh Y c t khi i vi oxi bng 0,25. Hiu sut ca qu trnh tng hp NH3 l
A. 15% B. 25% C. 20% D. 30%
Cu 14: Pht biu no sau y l sai?
A. CO2 tan trong nc nhiu hn SO2 cng iu kin nhit , p sut.
B. SO2 l phn t phn cc, CO2 l phn t khng phn cc.
C. SO2 c tnh kh, CO2 khng c tnh kh.
D. SO2 c dng chng nm mc cho lng thc, thc phm; cn nc kh (CO2 rn) dng bo qun
thc phm.
Cu 15: Nhit phn hon ton hn hp 2 mui KNO3 v Fe(NO3)2, sau phn ng thu c hn hp X gm 2 kh c
t khi so vi H2 bng 21,6. Phn trm khi lng ca Fe(NO3)2 trong hn hp ban u l
A. 60,00% B. 78,09% C. 34,30% D. 40,00%
Cu 16: Ha tan hon ton hn hp X gm 0,002 mol FeS2 v 0,003 mol FeS vo lng d dung dch H2SO4 c
nng thu c kh X. Ton b kh X hp th ht vo dung dch KMnO4 va thu c dung dch Y khng mu c
pH = 2. Th tch (lt) ca dung dch Y l
A. 11,4 B. 22,8 C. 2,28 D. 1,14
Cu 17: Cho m
1
gam Al vo 100ml dung dch gm Cu(NO
3
)
2
0,3M v AgNO
3
0,3M. Sau khi cc phn ng xy ra
hon ton th thu c m
2
gam cht rn X. Nu cho m
2
gam X tc dng vi lng d dung dch HCl th thu c
0,336 lt kh ( ktc). Gi tr ca m
1
v m
2
ln lt l:
A. 8,10 v 5,43 B. 1,08 v 5,43 C. 0,54 v 5,16 D. 1,08 v 5,16
(1) Cho dung dch Fe(NO3)2 vo dung dch HCl (5) Cho dung dch NaHCO3 vo dung dch NaOH
(2) Cho CuS + dung dch HCl (6) Cho dung dch NH4NO3 vo dung dch NaOH
(3) Cho FeS + dung dch HCl (7) Cho Zn vo dung dch NaHSO4
(4) Cho dung dch AlCl3 vo dung dch Na2CO3
S th nghim c to ra cht kh l:
A. 4 B. 5 C. 6 D. 3
Cu 19: Trn 3 dung dch HCl 0,3M; H
2
SO
4
0,2M v H
3
PO
4
0,1M vi nhng th tch bng nhau thu c dung dch
X. Dung dch Y gm NaOH 0,1M v Ba(OH)
2
0,2M. trung ha 300ml dung dch X cn va V ml dung dch Y.
Gi tr ca V l
A. 600 B. 1000 C. 200 D. 333,3
Cu 20: Cho cc cht sau y: Cl
2
, Na
2
CO
3
, CO
2
, HCl, NaHCO
3
, H
2
SO
4
long, NaCl, Ba(HCO
3
)
2
, NaHSO4, NH
4
Cl,
MgCO
3
, SO
2
. Dung dch Ca(OH)
2
tc dng c vi bao nhiu cht?
A.9 B. 11 C. 12 D. 10
Cu 21: in phn c mng ngn in cc tr 2 lt dung dch cha 0,2 mol CuCl2 v 0,4 mol BaCl2 cho n khi c
dung dch c pH =13 th dng in phn. Xem th tch dung dch khng i. Hy cho bit th tch kh ln lt thu
c hai in cc catot, anot (ktc) l
A. 4,48 lt v 44,8 lt B. 2,24 lt v 4,48 lt C. 2,24 lt v 6,72 lt D. 6,72 lt v 2,24 lt
Cu 22: Cho cc cht: t capron, t lapsan, t nilon -7, t olon, keo dn ure-fomanehit, cao su isopren, poli(metyl
metacrilat), t axetat, nha novolac. S cht c to t phn ng trng hp l:
A. 3 B. 4 C. 1 D. 2
Cu 23: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen),
CH3CHO. S cht trong dy phn ng c vi dung dch nc brom l :
A. 7 B. 6 C. 5 D. 8
Cu 24: S ancol ng phn cu to ca nhau c cng thc phn t C
5
H
12
O, tc dng vi CuO un nng sinh ra
anehit l
A. 4 B. 5 C. 3 D. 2
232 | L O V E B O O K . V N
Cu 25: Mt cht hu c X mch h, khng phn nhnh, ch cha C, H, O. Trong phn t X ch cha cc nhm chc
c nguyn t H linh ng, X c kh nng ha tan Cu(OH)2. Khi cho X tc dng vi Na d th thu c s mol H2
bng s mol ca X phn ng. Bit X c khi lng phn t bng 90 vc. X c s cng thc cu to ph hp l:
A. 7 B. 6 C. 5 D. 4
Cu 26: T cc cht ring bit: CuSO
4
, CaCO
3
, FeS iu ch c c 3 kim loi Cu, Ca v Fe th s phn ng ti
thiu phi thc hin l: (cc iu kin khc c )
A. 4 B. 5 C. 6 D. 7
Cu 27: Cho 0,3 mol hn hp X gm CH3CHO, CH2=CHCOOH v CH
C-COOH phn ng ht vi dung dch AgNO3/

NH3 (d) thu c 41 gam hn hp kt ta. Mt khc, khi cho 0,3 mol X tc dng vi NaHCO3 d, th thu c
4,48 lt kh CO2 ( ktc). Khi lng ca CH
C-COOH trong X l:
A.14,0 gam B. 10,5 gam C. 3,5 gam D. 7,0 gam
Cu 28: Cho phn ng: C6H5-CH=CH2 + KMnO4 C6H5COOK + K2CO3 + MnO2 + KOH + H2O
Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ha hc ca phn ng trn l:
A. 24 B. 27 C. 34 D. 31
Cu 29: Ha tan 64 gam hn hp mui gm CuSO4, Fe2(SO4)3, MgSO4 trong S chim 25% v khi lng vo
nc c dung dch X. Cho X tc dng vi dung dch Ba(OH)2 va thu c m gam kt ta. Gi tr ca m l
A. 116,5 B. 233,0 C. 149,5 D. 50,0
Cu 30: Cho 1,5 gam hirocacbon X tc dng vi lng d dung dch AgNO3/ NH3, thu c 7,92 gam kt ta vng
nht. Mt khc 1,68 lt kh X ( ktc) c th lm mt mu c ti a V lt dung dch Br2 1M. Gi tr ca V l:
A. 0,3 B. 0,2 C. 0,15 D. 0,25
Cu 31: Cho 0,81 gam Al v 6,72 gam Fe vo 100 ml dung dch Cu(NO3)2, lc k Cu(NO3)2 phn ng ht th c
cht rn c khi lng 9,76 gam. Nng mol Cu(NO3)2 trong dung dch l
A. 0,75 M B. 0,35 M C. 0,42 M D. 0,65 M
Cu 32: Hn hp X gm hiro, propen, propanal, ancol alylic. t 1 mol hn hp X thu c 40,32 lt CO2 (ktc).
un X vi bt Ni mt thi gian thu c hn hp Y c t khi so vi X l 1,25. Nu ly 0,1 mol hn hp Y th tc
dng va vi V lt dung dch Br2 0,2M. Gi tr ca V l
A. 0,20 lt B. 0,40 lt C. 0,30 lit D. 0,25 lit
Cu 33: t chy hon ton mt hn hp X: glucoz, fructoz, metanal v axit etanoic, cn 3,36 lt O2 (ktc). Dn
sn phm chy qua bnh ng dung dch Ca(OH)2 d, sau phn ng hon ton thu c m gam kt ta. Gi tr ca
m l :
A. 15,0 B. 12,0 C. 10,0 D.20,5
Cu 34: Trong cng nghip, ngi ta iu ch HNO
3
theo s sau:
NH
3
NO NO
2
HNO
3

Bit hiu sut ca ton b qu trnh iu ch HNO
3
l 70%, t 22,4 lt NH
3
(ktc) s iu ch c bao nhiu gam
HNO
3
?
A. 22,05 B. 44,1 C. 63,0 D. 4,41
Cu 35: Hn hp X gm mt axit cacboxylic n chc Y, mt ancol n chc Z, mt este to ra t Y v Z. Khi t
chy hon ton 6,2 gam X th thu c 0,31 mol CO2 v 0,28 mol H2O. Cn khi cho 6,2 gam X phn ng va vi
50 ml dung dch NaOH 1M, un nng, th thu c 0,04 mol Z. Thnh phn % s mol ca axit Y trong hn hp X
l:
A. 36,72% B. 42,86% C. 57,14% D. 32,15%
(1) Cho dung dch H2O2 vo dung dch KI (5) Sc kh O3 vo dung dch KI
(2) Cho dung dch Na2S2O3 vo dung dch H2SO4 long (6) Sc kh H2S vo dung dch FeCl3
(3) Sc kh SO2 vo dung dch H2S (7) t chy Ag2S trong O2
(4) un nng hn hp SiO2 v Mg
S th nghim c th to ra n cht l
A. 5 B. 7 C. 4 D. 2
Cu 37: Cc cht : CH3CH2COOH (1), CH3COOCH3 (2), CH3CH2CH2OH (3), CH3CH(OH)CH3 (4); CH3CH2CH3 (5)
c xp theo th nhit si gim dn l:
A.(3) > (5)> (1) > (4)> (2) B. (3) > (1) > (4) > (5) > (2)
C.(1) > (3) > (4) > (2) > (5) D. (1) > (2) > (3) > (4) > (5)
Cu 38: Ha tan vo nc 3,38 gam hn hp mui cacbonat v hidrocacbonat ca mt kim loi M ha tr I sau
cho thm vo dung dch trn mt lng d dung dch HCl thu c 0,672 lt kh ktc. Kim loi M l:
A. Na B. K C. Cs D. Ag
233 | G S T T G R O U P
Cu 39: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t C). Chia X thnh hai phn
bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt H
2
(ktc). t chy hon ton phn hai, sinh ra 26,4
gam CO
2
. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l:
A. CH2(COOH)2 v 70,87% B.HOOC-COOH v 60,00%
C.CH
2
(COOH)
2
v 54,88% D. HOOC-COOH v 42,86%
Cu 40: Ion A
3+
c cu hnh electron phn lp cui cng l 3d
10
. V tr ca A trong bng tun hon l:
A. chu k 4, nhm VIIIB B. chu k 4, nhm IIIB C. chu k 4, nhm VIIB D. Chu k 4, nhm IIIA
Cu 41: Dy ion sp xp theo chiu gim dn tnh oxi ha l:
A. Fe
3+
, Cu
2+
, Ag
+
, Fe
2+
, H
+

B. Fe
3+
, Ag
+
, Cu
2+
, H
+
, Fe
2+

C. Ag
+
, Fe
3+
, Cu
2+
, H
+
, Fe
2+
D. Ag
+
, Cu
2+
, Fe
3+
, Fe
2+
, H
+

Cu 42: Khi oxi ha C2H5OH bng CuO nung nng, thu c hn hp hi X ch gm CH3CHO, H2O, v C2H5OH d. X
c khi lng phn t trung bnh bng 36 vc. Hiu sut phn ng oxi ha C2H5OH l:
A. 26,0% B. 87,5% C. 25,0% D. 50,0%
Cu 43: Dy cc ion no sau y c th cng tn ti trong mt dung dch:
A. Fe
3+
, Cl
, NH
4
+
, SO
4
2
, S
2

B. Mg
2+
, HCO
3
, SO
4
2
, NH
4
+

C. Fe
2+
, H
+
, Na
+
, Cl
, NO
3
D. Al
3+
, K
+
, Br
, NO
3
, CO
3
2

Cu 44: Hp th ht 4,48 lt buta - 1,3 - ien ( ktc) vo 250 ml dung dch Br2 1M, iu kin thch hp n khi
dung dch brom mt mu hon ton thu c hn hp sn phm X, trong khi lng sn phm cng 1,4 gp 4
ln khi lng sn phm cng 1,2. Khi lng ca sn phm cng 1,2 c trong hn hp X l:
Cu 45: Khi ni v peptit v protein, pht biuno sau y l ng?
A.Thy phn hon ton protein n gin thu c cc -amino axit.
B. Tt c cc peptit v protein u c phn ng mu biure vi Cu(OH)
2
.
C. Lin kt ca nhm CO vi nhm NH gia hai n v amino axit c gi l lin kt peptit.
D. Oligopeptit l cc peptit c t 2 n 10 lin kt peptit.
Cu 46: Cho cc cht sau: axetilen, axit fomic, fomanehit, phenyl fomat, glucz, anehit axetic, metyl axetat,
mantoz, natri fomat, axeton. S cht c th tham gia phn ng trng bc l
A.8 B.5 C. 7 D. 6
(1) N2(k) + 3H2(k)2NH3(k) (3) 2SO2(k) + O2(k)2SO3(k)
(2) 2C(r) + O2(k)2CO(k) (4) H2(k)+ Cl2(k)2HCl(k)
Khi tng p sut, s cn bng chuyn dch theo chiu thun l
A. 1 B. 4 C. 2 D. 3
Cu 48: Cho t t dung dch NH3 n d vo dung dch cha cc mui Cu(NO3)2, Zn(NO3)2, Fe(NO3)2, Al(NO3)3,
Ni(NO3)2, AgNO3. Lc kt ta nung trong khng kh n khi lng khng i thu c cht rn gm cc cht:
A. Ag2O, Fe2O3, Al2O3 B. Fe2O3, Al2O3 C. NiO, Ag, Fe2O3, Al2O3 D. Ag, Fe2O3
Cu 49: Dy no sau y gm tt c cc ion gy nhim ngun nc:
A. Cl
, NO
3
, Hg
2+
, Cr
3+
, As
3+
B. SO
4
2
, Br
, Mg
2+
, Mn
2+
, H
+

C. Ag
+
, Cd
2+
, K
+
, NO
3
, HCO
3

D. CO
3
2
, Cl
, Cu
2+
, Ca
2+
, Na
+

Cu 50: Cho 100 gam hp kim ca Fe, Cr, Al tc dng vi dung dch NaOH d thot ra 5,04 lt kh (ktc) v mt
phn rn khng tan. Lc ly phn khng tan em ho tan ht bng dung dch HCl d (khng c khng kh) thot
ra 38,8 lt kh (ktc). Thnh phn % khi lng cc cht trong hp kim l
A.4,05%Al; 83,66%Fe v 12,29%Cr. B.4,05%Al;13,66%Fe v 82,29%Cr.
C.13,66%Al;82,29%Fe v 4,05%Cr. D.4,05%Al;82,29%Fe v 13,66%Cr.

P N

1A 2D 3B 4A 5A 6B 7B 8A 9C 10C
11D 12B 13B 14A 15B 16C 17B 18B 19C 20D
21C 22B 23B 24A 25A 26B 27D 28C 29C 30A
31D 32D 33A 34B 35B 36B 37C 38B 39D 40D
41C 42D 43B 44D 45A 46C 47C 48B 49A 50A

234 | L O V E B O O K . V N
s 36

Cu 1: Ha tan 160 gam hn hp A gm AlCl
3
, FeCl
2
, FeCl
3
vo nc c dung dch B. Chia dung dch B thnh 2 phn
bng nhau:
in phn phn 1 trong 77200 giy bng dng in 2A. Thm t t dung dch NaOH vo dung dch sau in phn thy
khng xut hin kt ta. Bit qu trnh in phn cha xy ra qu trnh in phn nc c hai in cc.
Cho 1,68 lt dung dch NaOH 0,5M vo phn 2 thu c m gam kt ta Al(OH)
3
.
Gi tr nh nht ca m gn vi gi tr no sau y nht?
Cu 2: Thuc th no sau y dng phn bit Fe, FeO v FeS?
A. Dung dch HCl long, nng B. Dung dch H
2
SO
4
c nng
C. Dung dch NaOH c nng D. Dung dch HNO
3
long, nng
Cu 3: Hp cht X mch h c cng thc phn t l C
4
H
9
NO
2
. Cho 10,3 gam X phn ng va vi dung dch NaOH
sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c
kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l:
A. 8,2 B. 10,8 C. 9,4 D. 9,6
Cu 4: Dn 7,1 gam hn hp hi ca 2 ancol no, n chc k tip nhau trong dy ng ng qua CuO d, un nng. Sau
phn ng hon ton thu c 10,3 gam hn hp hi Y. Dn hn hp hi Y vo dung dch AgNO
3
d trong NH
3
, un
nng, sau phn ng hon ton thu c Ag c khi lng l:
Cu 5: Dy cht no sau y c th s dng iu ch trc tip axetanehit?
A. metanol, etilen, axetilen B. Etanol, etilen, axetilen
C. etanol, butan, etilen D. Glucozo, etilen, vinyl axetat
Cu 6: Hn hp X gm ankin Y v H
2
c t l mol l 1:2. Dn 13,44 lt hn hp X (ktc) qua Ni, nung nng thu c hn
hp Z c t khi so vi H
2
l 11. Dn hn hp Z qua dung dch Br
2
d, sau phn ng hon ton thy c 32 gam Br
2

phn ng. Cng thc ca ankin Y l:
A. C
2
H
2
B. C
4
H
6
C. C
3
H
4
D. C
5
H
8

Cu 7: Dy cc cht no sau y l cc hp cht ion?
A. AlCl
3
, HCl, NaOH B. HNO
3
, CaC
2
, NH
4
Cl C. KNO
3
, NaF, H
2
O D. NaCl, CaO, NH
4
Cl
Cu 8: Cho cc cht sau: (1) etyl amin, (2) imetyl amin, (3) p metyl anilin, (4) benzyl amin. S sp xp no ng vi
tnh bazo ca cc cht ?
A. (4)>(2)>(3)>(1) B. (1)>(2)>(4)>(3) C. (2)>(1)>(3)>(4) D. (2)>(1)>(4)>(3)
Cu 9: Nh t t dung dch H
2
SO
4
long vo dung dch X cha 0,1 mol Na
2
CO
3
v 0,2 mol NaHCO
3
, thu c dung dch
Y v 4,48 lt kh CO
2
(ktc). Tnh khi lng kt ta thu c khi cho dung dch Ba(OH)
2
d vo dung dch Y?
Cu 10: Khi lm th nghim vi photpho trng, cn c ch no di y?
A. Cm photpho trng bng tay c eo gng cao su.
B. Dng cp gp nhanh mu photpho trng ra khi l v ngm ngay vo chu ng y nc khi cha dng n.
C. Trnh cho photpho trng tip xc vi nc.
D. C th photpho trng ngoi khng kh.
Cu 11: Dy cc dung dch no sau y, khi in phn (in cc tr, mng ngn) c s tng pH ca dung dch?
A. KCl, KOH, HNO
3
B. CuSO
4
, HCl, NaNO
3
C. NaOH, KNO
3
, KCl D. NaOH, BaCl
2
, HCl
Cu 12: Ancol X no a chc mch h (c s nhm OH t hn s nguyn t C). t chy hon ton 0,1 mol X cn dng
12,32 lt kh O
2
(ktc). Mt khc, dung dch X hon tan c Cu(OH)
2
nhit thng to dung dch xanh lam. X c
bao nhiu cng thc cu to?
A. 3 B. 4 C. 5 D. 6
Cu 13: Ha tan hon ton mt lng Fe trong 200 gam dung dch HNO
3
nng 63% un nng thu c kh NO
2
(sn
phm kh duy nht). Trong dung dch sau phn ng, nng % ca HNO
3
l 36,92%. Th tch kh NO
2
(o 27 v
1,12 atm) thot ra l:
A. 9,92 lt B. 9,15 lt C. 9,89 lt D. 9,74 lt
(1) Sc kh CO
2
vo dung dch natri aluminat (4) Dung dch NaOH d vo dung dch AlCl
3

(2) Cho dung dch NH
3
d vo dung dch AlCl
3
(5) Dung dch NaOH d vo dung dch Ba(HCO
3
)
2

(3) Sc kh H
2
S vo dung dch AgNO
3

Nhng trng hp thu c kt ta sau phn ng l:
235 | G S T T G R O U P
A. (2), (3), (5) B. (1), (2), (5) C. (1), (2), (3), (5) D. (2), (3), (4), (5)
Cu 15: Cho dy cc dung dch sau: NaHSO
4
, NH
4
Cl, CuSO
4
, K
2
CO
3
, ClH
3
NCH
2
COOH, NaCl v AlCl
3
. S dung dch c
pH<7 l:
A. 3 B. 4 C. 5 D. 6
Cu 16: Ha toan hon ton 19,2 gam hn hp X gm Fe, FeO, Fe
3
O
4
v Fe
2
O
3
trong 400ml dung dch HNO
3
3M (d)
un nng, thu c dung dch Y v V lt kh NO (ktc) (NO l sn phm kh duy nht ca NO
3
). Cho 350ml dung dch

NaOH 2M vo dung dch Y thu c 21,4 gam kt ta. Gi tr ca V l:
A. 3,36 lt B. 5,04 lt C. 5,60 lt D. 4,48 lt
(1) Thy phn hon ton este no, n chc mch h trong dung dch kim thu c mui v ancol.
(2) Phn ng este ha gia axit cacboxylic vi ancol (xc tc H
2
SO
4
c) l phn ng thun nghch.
(3) Trong phn ng este ha gia axit axetic v etanol (xc tc H
2
SO
4
c), nguyn t O ca phn t H
2
O c ngun
gc t axit.
(4) t chy hon ton este no mch h lun thu c CO
2
v H
2
O c s mol bng nhau.
(5) Cc axit bo u l cc axit cacboxylic n chc v c s nguyn t C chn.
S pht biu ng l:
A. 2 B. 3 C. 4 D. 5
Cu 18: Cho s phn ng:
CH
3
COONa
vi ti xt,t
X
Cl
2
,as 1:1
Y
dd NaOH,t
Z
CuO,t
T
X, Y, Z, T l cc hp cht hu c, cng thc ca T l:
A. CH
2
O
2
B. CH
3
CHO C. CH
3
OH D. HCHO
Cu 19: Cho mt s tnh cht: c dng si (1), tan trong nc (2), tan trong nc Svayde (3), phn ng vi axit nitric
c (xc tc H
2
SO
4
c) (4), tham gia phn ng trng bc (5), b thy phn trong dung dch axit un nng (6). Cc tnh
cht ca xenlulozo l:
A. (3), (4), (5), (6) B. (1), (3), (4), (6) C. (2), (3), (4), (5) D. (1), (2), (3), (4)
Cu 20: Hn hp X gm C
n
H
n
2
m
2
+3
CHO v C
n
H
2m+1
CH
2
OH (u mch h v m, n l cc s nguyn). Cho X phn ng
va vi khng n 3,2 gam brom trong nc. Mt khc ton b lng X trn phn ng vi dung dch
AgNO
3
NH
3
, kt thc phn ng thu c 2,16 gam Ag. t chy hon ton C
n
H
n
2
m
2
+3
CHO th th tch oxi (ktc) cn
dng l:
A. 0,56 lt B. 0,224 lt C. (0,336n+0,28) lt D. 1,12 lt
Cu 21: Axit Malic (2 hidroxi butandioic) c trong qu to. Cho m gam axit Malic tc dng vi Na d thu c V
1
lt kh
H
2
. Mt khc, cho m gam axit Malic tc dng vi NaHCO
3
d thu c V
2
lt kh CO
2
(th tch cc kh o cng iu
kin). Mi quan h gia V
1
v V
2
l:
A. V
1
= 0,5V
2
B. V
1
= V
2
C. V
1
= 0,75V
2
D. V
1
= 1,5V
2

Cu 22: C 6 dung dch ring r sau: BaCl
2
, MgCl
2
, FeCl
2
, FeCl
3
, NH
4
Cl, (NH
4
)
2
SO
4
. C th nhn bit 6 dung dch
trn bng kim loi:
A. Al. B. Na. C. Mg. D. Cu.
Cu 23: Thy ngn d bay hi v rt c. Nu chng may nhit k thy ngn b v th cht c th dng kh thy
ngn l:
A. Bt Fe B. Bt lu hunh C. Nc D. Na
Cu 24: Cho dung dch hn hp gm NH4Cl 0,05M v NH3 0,05M. Bit rng hng s phn li baz ca NH3 25
0
C l
1,8.10
5
v b qua s phn li ca H2O. Vy pH ca dung dch 25
0
C l
A. 4,74 B. 5,12 C. 9,26 D. 4,31
Cu 25: t chy hon ton 22,23 gam mt cacbohirat X, cn dng va 0,78 mol O2. Cng thc n gin
nht ca X l
A. C6H10O5 B.C6H12O6 C. CH2O D. C12H22O11
Cu 26: trung ha m gam dung dch axit cacboxylic n chc X nng 8,64% cn dng m gam dung dch NaOH
nng C%. Sau phn ng thu c dung dch cha cht tan c nng 5,64%. Cng thc ca X v gi tr ca C tng
ng l:
A. CH
3
COOH v 5,76 B. HCOOH v 7,5 C. C
2
H
5
COOH v 4,6 D. CH
2
= CHCOOH v 4,8
Cu 27: Cho mt hn hp X cha NH
3
, C
6
H
5
NH
2
v C
6
H
5
OH. X c trung ha bi 0,02 mol NaOH hoc 0,01 mol HCl.
X cng phn ng va vi 0,075 mol brom to kt ta. S mol NH
3
v C
6
H
5
OH ln lt l:
A. 0,01 mol v 0,02 mol B. 0,005 mol v 0,02 mol C. 0,005 mol v 0,01 mol D. 0,01 mol v 0,01 mol
Cu 28: Cho cc hp cht hu c: etylenglicol (1), glyxin (2), axit axetic (3), axit acrylic (4), axit glutamic (5) v 2
metylpropenol (6). Cht c kh nng tham gia phn ng trng ngng l:
236 | L O V E B O O K . V N
A. 1, 2, 5 B. 3, 4, 5 C. 1, 4, 5 D. 2, 3, 4
Cu 29: Cho m gam Zn vo dung dch cha 0,1 mol AgNO
3
v 0,15 mol Cu(NO
3
)
2
, sau mt thi gian thu c 26,9 gam
kt ta v dung dch X cha 2 mui. Tch ly kt ta, thm tip 5,6 gam bt st vo dung dch X, sau khi cc phn ng
hon ton thu c 6 gam kt ta. Gi tr ca m l:
Cu 30: Cho KI tc dng ht vi KMnO
4
trong mi trng H
2
SO
4
, ngi ta thu c 1,51 gam MnSO
4
. S mol I
2
to
thnh v KI tham gia phn ng ln lt l:
A. 0,00025 v 0,0005 B. 0,025 v 0,05 C. 0,25 v 0,50 D. 0,0025 v 0,005
Cu 31: Hy cho bit pht biu no sau y khng ng?
A. Trong cc axit: HF, HCl, HBr th HBr c tnh axit mnh nht.
B. Ozon c tnh oxi ha v kh nng hot ng hn O
2
.
C. Kh nng phn ng ca Cl
2
km hn ca O
2
.
D. Tnh kh ca H
2
S ln hn ca nc.
Cu 32: Cht hu c X c cng thc phn t l C
4
H
9
O
2
N. Cho 5,15 gam X tc dng vi dung dch NaOH (ly d 25% so
vi lng phn ng) un nng. Sau phn ng hon ton, c cn dung dch thu c 6,05 gam cht rn khan. Cng thc
ca X l:
A. H
2
NCH
2
COOC
2
H
5
B. H
2
NC
3
H
6
COOH C. C
2
H
3
COONH
3
CH
3
D. H
2
NC
2
H
4
COOCH
3

Cu 33: Hidro ha hon ton anehit X (xc tc Ni, t) thu c ancol Y. Mt khc, oxi ha X thu c axit cacboylic Z.
Thc hin phn ng este ha gia Y v Z (xc tc H
2
SO
4
c) thu c este M c cng thc phn t l C
6
H
10
O
2
. Cng
thc ca X l:
A. CH
2
= CHCHO B. CH
2
(CHO)
2
C. C
2
H
5
CHO D. CH
2
= CHCH
2
CHO
(1) Trong dung dch, tng nng cc ion dng bng nng cc ion m.
(2) Dy cc cht: CaCO
3
, HBr v NaOH u l cc cht in li mnh.
(3) Trong 3 dung dch cng pH l HCOOH, HCl v H
2
SO
4
, dung dch c nng ln nht l HCOOH.
(4) Phn ng axit bazo xy ra theo chiu to ra cht c tnh axit v bazo yu hn.
(5) Phn ng trao i ion trong dung dch khng kem theo s thay i s oxi ha.
S pht biu ng l:
A. 2 B. 3 C. 4 D. 5
Cu 35: Cho cc phn ng oxi ha kh sau:
(1) H
2
O
2
MnO
2
(2) AgNO
3
t

(3) Cl
2
+KOH
t
(4) KClO
3
t

(5) Cl
2
+NaOH (6) KMnO
4
t

(7) Ca(HCO
3
)
2
t
(8) CuO +NH
3
t

Trong s cc phn ng trn, c bao nhiu phn ng oxi ha kh ni phn t?
A. 3 B. 4 C. 5 D. 6
Cu 36: Ly 22,35 gam hn hp mui clorua ca kim loi kim A v kim loi kim th B (A, B thuc 2 chu k lin tip
nhau trong bng tun hon ha hc) tc dng vi dung dch AgNO
3
d thu c 43,05 gam kt ta. A v B ln lt l:
A. K v Sr B. Rb v Ca C. Na v Ca D. K v Mg
Cu 37: Hp th ht V lt kh CO
2
vo dung dch cha 0,39 mol Ca(OH)
2
thu c a gam kt ta. Tch ly kt ta, sau
thm tip 0,4V lt kh CO
2
na, thu thm 0,2a gam kt ta. Th tch cc kh o ktc. Gi tr ca V l:
A. 7,84 lt B. 5,6 lt C. 8,4 lt D. 6,72 lt
Cu 38: 0,1 mol axit A tc dng va vi 0,2 mol NaHCO
3
. t chy 0,1 mol A th khi lng nc vt qu 3,6 gam.
Cng thc cu to thu gn ca A l:
A. C
2
H
5
COOH B. HOOCC CCOOH C. HOOCCH = CHCOOH D. HOOC(CH
2
)
2
COOH
Cu 39: Cho hn hp gm Fe v Cu tc dng vi cc ha cht sau: (1) dung dch HCl, (2) kh oxi, t, (3) dung dch NaOH,
(4) dung dch H
2
SO
4
c ngui, (5) dung dch FeCl
3
. S ha cht ch tc dng vi 1 trong 2 kim loi l:
A. 2 B. 3 C. 4 D. 5
Cu 40: Cho cc cht sau: Cu, FeS
2
, Na
2
SO
3
, S, NaCl, Cu
2
O, KBr v Fe
3
O
4
tc dng vi dung dch H
2
SO
4
c nng. S
trng hp xy ra phn ng oxi ha kh l:
A. 4 B. 5 C. 6 D. 7
Cu 41: Hn hp X gm hai kim loi kim th Y v Z thuc hai chu k k tip nhau (M
Y
< M
Z
). Cho m gam hn hp X vo
nc d thy thot ra V lt kh H
2
. Mt khc, cho m gam hn hp X vo dung dch HCl d, sau phn ng hon ton thy
thot ra 3V lt H
2
(th tch cc kh o cng iu kin). Phn trm khi lng ca Y trong hn hp X l:
237 | G S T T G R O U P
A. 54,5% B. 33,3% C. 66,7% D. 45,5%
Cu 42: Hn hp tecmit c dng hn gn cc ng ray c thnh phn l:
A. Cr v Fe
3
O
4
B. C v Fe
2
O
3
C. Al v Fe
2
O
3
D. Al v Cr
2
O
3

Cu 43: Mt hn hp X o 100, 1 atm gm anken A v H
2
c t l th tch tng ng l 1:1. Cho X qua Ni nung nng
thu c hn hp Y (hiu sut H%). Bit d
Y H
2
= 23,2. Cng thc no ca A khng ng?

A. C
3
H
6
B. C
4
H
8
C. C
5
H
10
D. C
7
H
14

Cu 44: Ha tan 58,4 gam hn hp mui khan AlCl
3
v CrCl
3
vo nc, thm d dung dch NaOH vo sau tip
tc thm nc clo ri li thm d dung dch BaCl
2
th thu c 50,6 gam kt ta. Thnh phn % khi lng ca
cc mui trong hn hp u l
A. 45,7% AlCl
3
v 54,3% CrCl
3
. B. 46,7% AlCl
3
v 53,3% CrCl
3
.
C. 47,7% AlCl
3
v 52,3%

CrCl
3
. D. 48,7% AlCl
3
v 51,3% CrCl
3
.
(1) Anehit va c tnh oxi ho va c tnh kh.
(2) Phenol tham gia phn ng th brom kh hn benzen.
(3) Amin bc 2 c lc baz mnh hn amin bc 1.
(4) Ch dng dung dch KMnO4 c th phn bit c toluen, benzen v stiren
(5) Phenol c tnh axit nn dung dch phenol trong nc lm qu tm ho .
(6) Trong cng nghip, axeton v phenol c sn xut t cumen.
(7) un nng C2H5Br vi KOH/C2H5OH thu c sn phm l C2H5OH.
S pht biu lun ng l
A. 3 B. 5 C. 2 D. 4
Cu 46: X l hp cht hu c, mch h ch cha mt loi nhm chc. t chy hon ton X ch thu c CO2 v H2O. Khi lm
bay hi hon ton 4,5 gam X thu c th tch bng th tch ca 2,1 gam kh N2 ( cng iu kin). S cng thc cu to ca
X tha mn l:
A.6 B. 3 C.5 D. 4
Cu 47: Thu phn hon ton 1,8 gam mt este n chc X, ri cho ton b sn phm tc dng vi lng d dung
dch AgNO3/ NH3 sau khi phn ng xong thu c 10,8 gam Ag. Cng thc phn t ca X l:
A. C3H4O2 B.C4H4O2 C. C4H6O2 D. C2H4O2
Cu 48: Cho dy cht: FeO, Fe, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3, FeCO3, FeS2.
S cht ng vai tr l cht kh khi phn ng vi HNO3 c nng d trong dy trn l:
A. 7 B. 6 C. 9 D. 8
Cu 49: Cho 6 hp cht hu c ng vi 6 cng thc phn t: C2H2; C2H4; CH2O; CH2O2 (mch h); C2H2O3 (mch
h); C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dung
dch AgNO3 trong NH3 to ra kt ta l
A.5 B. 2 C. 4 D. 3
Cu 50: Cho phenol tc dng vi cc ha cht sau: (1) NaOH; (2) HNO
3
c/xc tc H
2
SO
4
c; (3) nc brom; (4) HCl
c; (5) HCHO (xc tc H
+
, t); (6) NaHCO
3
. S ha cht phn ng vi phenol l:
A. 3 B. 4 C. 5 D. 6

P N

1A 2A 3C 4A 5B 6C 7D 8C 9B 10B
11D 12A 13C 14C 15C 16D 17B 18D 19B 20A
21C 22B 23B 24C 25D 26D 27B 28A 29D 30B
31C 32D 33A 34B 35A 36B 37D 38D 39A 40C
41A 42C 43D 44A 45A 46C 47A 48D 49A 50B

238 | L O V E B O O K . V N
239 | G S T T G R O U P
s 37

Cu 1: Mt dy st ni vi mt dy ng mt u, u cn li nhng vo dung dch mui n. Ti ch ni ca hai
dy kim loi xy ra hin tng g?
A. Electron di chuyn t Fe sang Cu. B. Ion Fe
2+
thu thm 2e to ra Fe
C. Ion Cu
2+
thu thm 2e to ra Cu D. Electron di chuyn t Cu sang Fe
Cu 2: Chia hn hp hai andehit no n chc thnh hai phn bng nhau
- t chy hon ton phn th nht thu c 0,54 gam nc.
- Phn th hai cng H2 (Ni, t
0
) thu c hn hp X gm 2 ancol no v andehit d
Nu t chy hon ton hn hp X th th tch kh CO2 (ktc) thu c l
Cu 3: Nhn nh no sau y khng ng
A. Gi tr Ka ca mt axit ph thuc vo nng axit B. Gi tr Ka ca mt axit ph thuc vo bn cht axit
C. Gi tr Ka ca mt axit ph thuc vo nhit D. Gi tr Ka cng ln th lc axit cng mnh
Cu 4: Hp kim Cu-Zn (45% Zn) c tnh cng, bn hn Cu dng ch to cc chi tit my, ch to thit b dng
trong ng tu bin gi l
A. ng thau B. ng bch C. Vng 9 cara D. ng thanh
Cu 5: tc dng ht vi 100g lipit c ch s axit bng 7 phi dng 17,92 gam KOH. Tnh khi lng x phng
thu c.
Cu 6: Khi iu ch etylen t ancol etylic v H2SO4 c khong 170
0
C th kh etylen thu c thng c ln CO2,
SO2, hi nc. loi b cc cht trn cn dng cch no sau y
A. Dn hn hp kh i qua dung dch brom d v bnh cha H2SO4 c, d
B. Dn hn hp kh i qua dung dch KMnO4 d v bnh cha Ca(OH)2, d
C. Dn hn hp kh ln lt qua dung dch brom d, NOH d v bnh cha Ca(OH)2, d
D. Dn hn hp kh ln lt qua dung dch NOH d v bnh cha P2O5 khan
Cu 7: C hao amin bc nht. A l ng ng ca anilin v B l ng ng ca metylamin. t chy hon ton 3,21
gam A thu c 336 cm
3
N2 (ktc) v t chy hon ton B cho hn hp kh trong t l V
CO
2
: V
H
2
O
= 2: 3. Cng
thc ca A, B ln lt l
A. CH3C6H4NH2 v CH3(CH2)3NH2 B. C2H5C6H5NH2 v CH3(CH2)2NH2
C. CH3C6H4NH2 v CH3(CH2)4NH2 D. CH3C6H4NH2 v CH3(CH2)2NH2
Cu 8: Cho 11,6 gam mui FeCO3 tc dng vi dung dch HNO3 va , thu c hn hp kh CO2, NO v dung dch
X. Thm vo dung dch X mt lng HCl (d) th thu c dung dch ho tan ti a bao nhiu gam bt ng, bit
rng kh bay ra l NO.
A. 3,2 gam B. 32 gam C. 28,8 gam D. 14,4 gam
Cu 9: in phn dung dch hn hp gm 0,2 mol CuSO4 v 0,12 mol NaCl vi in cc tr trong thi gian 4 gi
v I=1,34A. Khi lng lim loi thu c catot v khi lng kh thot ra anot(ktc) ln lt l
A. 6,4 gam Cu v 13,44 l kh B. 6,4 gam Cu v 1,792 l kh
C. 3,2 gam Cu v 1,344 l kh A. 3,2 gam Cu v 1,792 l kh
Cu 10: Cho chui chuyn ha sau C
7
H
8
HNO
3
(1:1) H
2
SO
4
X
Zn HCl
Y
HNO
2
Z. X, Y, Z l cc hp cht hu c, thnh
phn ch yu ca Z l
A. o- Metylanilin, p-Metylanilin B. o-Crezol, m-Crezol
C. o-Crezol, p-Crezol D. Axit o-phtalic, Axit p-phtalic
Cu 11: Nhit si ca cc cht c xp theo th t tng dn
A. C2H5Cl < CH3COOCH3< C2H5OH < CH3COOH B. CH3COOCH3< C2H5Cl < C2H5OH < CH3COOH
C. C2H5Cl < CH3COOH< CH3COOCH3< CH3CHO D.CH3COOH < HCOOH < CH3COOH < C2H5F
Cu 12: C 2,62 gam cao su Buna-S phn ng va ht vi 1,6 gam brom trong dung dch CCl4. T l s mt xch
butadien v stiren trong phn t cao su Buna S l
A. 2: 3 B. 1: 2 C. 1: 3 D. 3: 5
Cu 13: Kt lun no sau y l sai
A. Dung dch HCl c pH = 2 th CM = 0,01M B. Dung dch H2SO4 c pH = 0,7 th CM = 0,50M
C. Dung dch Ba(OH)2 c pH = 11 th CM = 0,0005M D. Dung dch NaOH c pH = 12,3 th CM = 0,020M
Cu 14: Nguyn t ca nguyn t X c lp ngoi cng l 3p. Nguyn t ca nguyn t Y c phn lp ngoi cng l
3s. Tng s electron ca 2 phn lp ngoi cng ca X v Y l 7. Bit rng X v Y d dng phn ng vi nhau. S
hiu nguyn t X v Y tng ng l
240 | L O V E B O O K . V N
A. 13 v 15 B. 18 v 11 C. 17 v 12 D. 11 v 16
(1) 3Fe (r) +4H
2
O Fe
3
O
4
(r) +4H
2
(k) H = +35 Kcal
(2) CO
2
(k) +H
2
(k) H
2
O (h) +CO (k) H = +10 Kcal
(3) 2SO
3
(k) 2SO
2
(k) +O
2
(k) H = +22,08 KCal
(4) O
2
(k) +2H
2
(k) 2H
2
O (h) H = 115,6 KCal
Chn phn ng khi tng p sut cn bng chuyn dch theo chiu nghch
A. (3) v (4) B. (4) C. (3) D. (1) v (2)
Cu 16: Hp th V lit CO2 (ktc) vo 200ml dung dch NaOH 1M thu c dung dch X. Khi cho CaCl2 d vo dung
dch X thu c kt ta v dung dch Y, un nng Y li thy kt ta xut hin. Gi tr ca V l
A. 1,12 < V < 2,24 B. 2,24 < V < 4,48 C. 4,48 V D. V 1,12
Cu 17: Sacaroz c tnh cht no trong s cc tnh cht sau:
1. Polisacarit 2. Khi tinh th khng mu
3. khi thu phn to thnh glucoz v fructoz 4. Tham gia phn ng trng gng
5. Phn ng vi Cu(OH)2.
Nhng tnh cht no ng
A. 1, 2, 3, 4 B. 2, 3, 5 C. 1, 2, 3, 5 D. 3, 4, 5.
Cu 18: Cho 0,1 mol cht X (C2H8O3N2) tc dng vi dung dch cha 0,2 mol NaOH un nng thu c cht kh lm
xanh gy qu tm t v dung dch Y. C cn dung dch Y thu c m gam cht rn khan. Chn gi tr ng ca m.
A. 12,5 gam B. 21,8 gam C. 5,7 gam D. 15 gam
Cu 19: Cho dancol = 0,8g/ml v dnc = 1,0g/ml . Nu cho natri d vo 115 ml ancol etylic 15
0
th th tch kh thot
ra l(ktc)
Cu 20: Cho x mol Fe tan hon ton trong dung dch cha y mol HNO
3
(x: y = 16: 61) thu c mt sn phm kh
duy nht v dung dch ch cha mui nitrat. S mol e do lng st trn nhng khi b ha tan l:
A. y B. 3x C. 2x D. 0,75y
Cu 21: Trn 12,0 gam hn hp bt Cu, Fe vi 8,0gam S thu c hn hp X. Nung X trong bnh kn khng c
khng kh, sau mt thi gian thu c hn hp Y. Ho tan ht Y trong dung dch HNO3 c, nng, d thu c kh
NO2 duy nht l hai mui sunfat. Phn trm khi lng Cu trong hn hp u l
A. 61,36% B. 63,52% C. 55,14% D. 53,33%
Cu 22: Kh 1,6 gam hn hp 2 andehit no bng kh H2 thu c hn hp 2 ru. un nng hn hp hai ru ny
vi H2SO4 c 180
0
C thu c hn hp 2 olefin l ng ng k tip. t chy hai olefin ny c 3,52gam CO2.
Bit cc phn ng xy ra hon ton. Cng thc ca hai andehit l
A. CH3CHO, C2H5CHO B. CH3CHO, CH2(CHO)2 C. C2H5CHO, C3H7CHO D.HCHO, CH3CHO
Cu 23: Cho 30 gam hn hp CaCO3 v KHCO3 tc dng ht vi HNO3 thu c kh Y, dn kh Y qua 500ml dung
dch Ba(OH)2 2M thu c kt ta Z, khi lng ca Z l (gam)
A. 59,6 B 59,5 C. 59,1 D. 59,3
Cu 24: iu no sau y khng ng?
A. Cht do l vt liu b bin dng di tc dng ca nhit p sut m vn gi nguyn bin dng khi
khng tc dng
B. T tm, bng, len l polime thin nhin
C. T visco, t axetat l t tng hp
D. Nilon 6-6 v t capron l poliamit
Cu 25: Hn hp X gm C
n
H
2n1
CHO, C
n
H
2n1
COOH, C
n
H
2n1
CH
2
OH (u mch h, n nguyn dng). Cho 2,8
gam X phn ng va vi 8,8 gam brom trong nc. Mt khc cho ton b lng X trn phn ng vi lng d
dung dch AgNO
3
NH
3
, kt thc phn ng thu c 2,16 gam Ag. Phn trm khi lng ca C
n
H
2n1
CHO trong X
l:
A. 26,63% B. 22,22% C. 20,00% D. 16,42%
Cu 26: Cho dung dch NH3 d vo dung dch X cha hn hp AlCl3, ZnCl2, FeCl3 thu c kt ta Y. Nung kt ta
Y n khi lng khng i c cht rn Z, cho lung H2 d i qua Z nung nng n phn ng hon ton thu
c cht rn T. Trong T c cha
A. Fe B. Al2O3, ZnO v Fe C. Al2O3, Zn D. Al2O3 v Fe
Cu 27: Dy gm cc hidrocacbon tc dng vi Clo theo t l s mol 1:1 (chiu sng) u thu c 4 dn xut
monoclo l
A. Metylxiclopentan v isopentan B. 2,2-imetylpentan v 2,3-imetylbutan
241 | G S T T G R O U P
C. isopentan v 2,2-imetylbutan D. 2,3-imetylbutan v metylxiclopentan.
Cu 28: Hn hp X gm HCHO v CH3CHO. Khi oxy ha (hiu sut 100%) m gam X thu c hn hp Y gm 2 axit
tng ng c d
X Y
= a, gi tr ca a l
A. 1,36 < a < 1,53 B. 1,26 < a < 1,47 C. 1,62 < a < 1,75 D. 1,45 < a < 1,50
Cu 29: Trong dy cc cht sau, cht no l polime
A. Sacaroz, PE, t tm, protein B. vi, cht bo, du n, glucoz, du ho
C. X phng, protein, cht bo, xenluloz, t nhn to. D. Tinh bt, xenluloz, cao su, t, PVC
Cu 30: Dy no sau y xp theo chiu gim dn bn knh ion
A. O
2
, F
, Na
+
, Mg
2+
, Al
3+
B. Al
3+
, Mg
2+
, Na
+
, O
2
, F

C. Mg
2+
, O
2
, Al
3+
, F
, Na
+
D. Al
3+
, Mg
2+
, Na
+
, F
, O
2

Cu 31: Nc clo c tnh ty mu v st trng l do
A. Clo l cht oxi ha mnh B. Clo l cht kh tan trong nc
C. C cha oxi nguyn t l tc nhn oxi ha mnh D. C cha axit hipoclor l tc nhn oxi ha mnh
Cu 32: Ho tan hn hp cha 0,15 mol Mg v 0,15 mol Al vo dung dch hn hp cha 0,15 mol Cu(NO3)2 v
0,525 mol AgNO3. Khi phn ng xong cht rn thu c l (gam)
A. 32,4 B. 66,3 C. 56,7 D. 63,9
Cu 33: Ho tan hon ton m gam bt Al vo dung dch HNO3 va thu c 8,96 lt (ktc) hn hp kh X gm
NO v N2O c t khi so vi H2 l 20,25. Lng dung dch HNO3 31,5% cn ly l (gam)
A. 300 B. 680 C. 600 D. 340
Cu 34: Thnh phn chnh ca amophot, mt loi phn bn phc hp l
A. (NH4)2HPO4 v Ca(HPO4)2 B. Ca(HPO4)2
C. NH4H2PO4 v(NH4)2HPO4 D. NH4H2PO4 v Ca(HPO4)2
Cu 35: Gi tr pH tng dn ca cc dung dch c cng nng mol/l no sau y l ng (xt 25
0
C)
A. C6H5NH2, CH3NH2, NaOH, Ba(OH)2 B. NH3, CH3NH2, C6H5NH2, NaOH, Ba(OH)2
C. Ba(OH)2, NaOH, CH3NH2, C6H5OH D. NaOH, CH3NH2,NH3, Ba(OH)2, C6H5OH
Cu 36: X phng ha este C5H10O2 thu c mt ancol. un ancol ny vi H2SO4 c 170
0
C c hn hp cc
olefin, este l
A. CH3COOCH(CH3)2 B.HCOOCH(CH2)3CH3 C. HCOOCH(CH3)C2H5 D. CH3COOCH2CH2CH3
Cu 37: Cho phng trnh ion thu gn nh sau: aZn +bNO
3
+cOH
dZnO
2
2
+eNH
3
+fH
2
O. Tng h s (s
nguyn ti gin) cc cht tham gia phn ng l
A. 11 B. 10 C. 9 D.12
Cu 38: Cho 16,54 gam hp kim ca Fe, Cr, Al tc dng vi dung dch NaOH d thot ra 0,672 lt H2 (ktc) v mt
phn cht rn khng tan. Lc ly phn cht rn khng tan em phn ng ht vi dung dch HCl (d, khng c
khng kh) thy thot ra 6,72 lit kh ktc. % khi lng ca Cr trong hp kim l (%)
A. 28,69 B. 12,29 C. 82,29 D. 4,05
Cu 39: Ho tan ht 2,08 gam hn hp Fe v Cu bng dung dch HNO3 thu c dung dch X v 672ml NO (ktc).
Thm t t 1,2 gam Mg vo dung dch X n khi phn ng hon ton thu c 224ml kh NO, dung dch Y v m
gam cht rn khng tan. Gi tr ca m l (gam)
A. 1,71 B. 1,44 C. 1,52 D. 0,84
Cu 40: Cho cc th nghim sau
(1) Sc kh CO2 vo dung dch NaAlO2 (hay Na[Al(OH)4])
(2) Sc kh NH3 vo dung dch AlCl3
(3) Nh t t n d dung dch HCl long vo dung dch NaAlO2 (hay Na[Al(OH)4])
Nhng th nghim c hin tng ging nhau l
A. (1), (2) v (3) B. (2) v (3) C. (1) v (3) D. (1) v (2)
Cu 41: Hn hp X gm FeO, Fe3O4 v Fe2O3 . kh hon ton 3,04 gam hn hp X cn va 0,1gam H2. Ho
tan ht 3,04g X bng H2SO4 c, nng thu c kh SO2 ktc, th tch kh SO2 thu c l (ml)
A. 336 B. 448 C. 224 D. 112
Cu 42: Thuc th duy nht no sau y ( iu kin thch hp) c th dng phn bit cc cht lng sau: Stiren,
benzen, toluen
A. Dung dch KMnO4 B. Dung dch Brom
C. Dung dch AgNO3/NH3 D. Cu(OH)2
Cu 43: Cho 0,1 mol CH
3
COOH vo cc cha 30ml dung dch ROH 20% (d = 1,2 gam/ml, R l mt kim loi nhm
IA). C cn dung dch sau phn ng, ri t chy hon ton cht rn khan cn li. Sau khi t chy th cn li 9,54
gam cht rn v c m gam hn hp gm CO
2
v hi nc bay ra. Gi tr ca m l:
242 | L O V E B O O K . V N
Cu 44: C bao nhiu ng phn este mch thng c cng thc phn t C6H10O4 khi tc dng vi NaOH to ra mt
mui v mt ru.
A. 5 B. 4 C. 3 D.2
Cu 45: un nng 0,1mol este ch cha mt loi nhm chc X vi lng va dung dch NaOH thu c 13,4
gam mui ca axit hu c a chc B v 9,2 gam ru n chc C. Cho C bay hi 127
0
C v 600mmHg s chim
th tch 8,32 lit. Cng thc cu to ca X l
A. (COOC3H5)2 B. (CH2)2 (COOC2H5)2 C.(COOC2H5)2 D. CH(COOCH3)2
Cu 46: Cho glyxin tc dng vi alanin th to ra ti a bao nhiu tripeptit
A. 5 B. 8 C. 4 D.6
Cu 47: Khi trn cc cht kh: H2 v O2 (1), NO v O2 (2), CO v O2(3) v NH3 vi HCl th cc trng hp c th tch
gim ngay nhit thng so vi tng th tch ca tng kh l
A. (3) v (4) B. (1) v (2) C.(1), (2) v (4) D. (2) v (4)
Cu 48: Khi in phn dung dch hn hp MgCl2, FeCl3 v CuCl2 th th t b kh catot l
A. Fe
3+
, Cu
2+
, Fe
2+
, H2O B. Fe
3+
, Cu
2+
, Mg
2+
, H2O
C. Cu
2+
,Fe
3+
, Mg
2+
, H2O D. Fe
3+
, Cu
2+
,Fe
2+
, Mg
2+

Cu 49: C 2 anken X, Y l ng ng lin tip nhau, trong M
X
< M
Y
. Hidrat ha hn hp X, Y c H
2
SO
4
lm xc
tc, to ra hn hp gm 3 ancol. t chy hon ton 1,94 gam hn hp ancol thu c 2,24 lt kh CO
2
(ktc). Vy:
A. Y l but 2 en B. X l etilen C. Y l propen D. Y l isobuten.
Cu 50: Hn hp M gm hai cht CH3COOH v NH2CH2COOH. trung ho m gam hn hp M cn 100ml dung dch
HCl 1M. Ton b sn phm thu c sau phn ng li tc dng va vi 300ml dung dch NaOH 1M. Thnh phn
phn trm theo khi lng ca cc cht CH3COOH v NH2CH2COOH trong hn hp M ln lt l
A. 40 v 60 B. 72,8 v 27,2 C. 61,54 v 38,46 D. 44,44 v 55,56

P N

1A 2C 3A 4A 5B 6D 7D 8B 9B 10C
11A 12B 13B 14C 15C 16B 17B 18A 19B 20D
21D 22A 23C 24C 25C 26D 27A 28A 29D 30A
31D 32D 33B 34C 35A 36C 37D 38B 39C 40D
41C 42A 43B 44B 45C 46B 47D 48A 49A 50D

243 | G S T T G R O U P
s 38

Cu 1: Th tch HCl 1M cn cho vo 500ml dung dch NaAlO2 0,1M thu c 0,78g kt ta l:
A. 0,01lit; 0,17lit B. 0,01lit; 0,2lit C. 0,2lit; 0,1lit D. 0,01lit; 0,15lit
Cu 2: Cho 200 ml dung dch KOH 0,65M phn ng vi 100 ml dung dch H2SO4 a M,sau phn ng thu c dung
dch X c kh nng phn ng va vi 0,78 gam Al(OH)3. Nng mol/l ca dung dch H2SO4 l:
A. 0,8M B. 0,6M C. 0,8M hoc 1,2M D. 0,6M hoc 0,8M
Cu 3: Cho 23,52 gam hn hp 3 kim loi Mg, Fe v Cu vo 200ml dung dch HNO
3
3,4M. Khuy u nhn thy
thot ra mt cht kh duy nht khng mu d b ha nu trong khng kh v cn d mt kim loi cha tan ht.
tip t t dung dch H
2
SO
4
5M vo ng thi khuy u, cht kh trn li thot ra cho n khi kim loi va tan ht
th dng ng 44ml, thu c dung dch A. Ly mt na dung dch A, ri cho dung dch NaOH vo n d, lc
phn kt ta, ra nhiu ln bng nc ri em nung ngoi khng kh n khi lng khng i thu c cht rn
B cn nng 15,6 gam. Tnh khi lng Fe trong hn hp ban u.
A. 15,36g B. 1,44g C. 6,72g D. 2,88g
Cu 4: C 5 dung dch ring bit: CuCl2, ZnCl2, FeCl3, NiCl2. Nu thm dung dch KOH d vo, sau thm tip NH3
d vo. S dung dch cho kt ta thu c sau th nghim l:
A. 2. B. 1. C. 3. D. 4
Cu 5: Ancol no mch h A cha n nguyn t C v m nhm OH trong cu to phn t. Cho 14,8 g A tc dng ht
vi Na cho 2,24 lt H2 (ktc). Mi quan h gia n v m l.
A. 2m = 2n+1 B. 28m = 7n+2 C. 7m = n+3 D. 29m = 7n+1
Cu 6: Trong t nhin nguyn t Bo c 2 ng v B
5
10
v B
5
11
. Nguyn t khi trung bnh ca Bo l 10,81. Phn trm
khi lng ca B
5
10
c trong mt phn t axit Boric H3BO3 (MH = 1; MO = 16) l:
A. 14,42% B. 19% C. 81% D. 3,07%
Cu 7: Cho 4,96 gam hn hp A gm Ca v CaC
2
tc dng ht vi nc thu c 2,24 lt hn hp kh B. un hn
hp kh B c mt xc tc thch hp thu c hn hp kh X. Ly 1/2 hn hp X trn vi 1,68 lt O
2
trong bnh kn
dung tch 4 lt (khng c khng kh). Cc th tch kh o ktc. Bt tia la in t chy ri gi nhit bnh
109,2. p sut trong bnh nhit ny l
A. 0,784 atm B. 0,384 atm C. 0,874 atm D. 2 atm
Cu 8: 95 c 1877 gam dung dch CuSO
4
bo ha. C bao nhiu gam CuSO
4
. 5H
2
O kt tinh khi lm lnh dung
dch xung 25? Bit tan ca CuSO
4
95 v 25 ln lt l 87,7g/100g H
2
O v 40g/100g H
2
O?
A. 745,31g B. 477,00g C. 861,75g D. 961,75g
Cu 9: kh hon ton 0,15 mol hn hp hai anehit n chc cn 4,2 lt kh H2 ktc. xi ha ht 0,15 mol hn
hp hai anehit ny bng dung dch AgNO3 d trong NH3 thu c 56,7 gam Ag. Hai anehit trong hn hp l.
A. HCHO , C2H3CHO B. HCHO , CH3CHO
C. CH3CHO , C2H3CHO D. CH3CHO, CH2=C(CH3)-CHO
Cu 10: Chn cu sai.
A. C th iu ch Br2 bng phn ng gia Cl2 vi NaBr
B. Mui AgNO3 khng bn d b phn tch khi c nh sng
C. C th iu ch HBr bng phn ng NaBr vi H2SO4 c
D. C th iu ch HCl, HF bng phn ng gia mui NaCl ,NaF vi H2SO4c
Cu 11: Cho a mol HCHO tc dng vi dng dch AgNO3 d/NH3, kt thc phn ng thu c x gam Ag. Oxi ha a
mol HCHO bng oxi vi hiu sut 50% thu c hn hp B. Cho ton b B tc dng vi dng dch AgNO3 d/NH3,
kt thc phn ng thu c y gam Ag. T s x/y l.
A. 4/3 B. 2/1 C. 5/3 D. 7/5
Cu 12: Cho cc cht: (1) Fe(NO3)2; (2) Cu(NO3)2; (3) Fe(NO3)3; (4) AgNO3; (5) Fe. Nhng cp cht tc dng vi
nhau l
A. 1-2; 2-4; 3-5; 4-5 B. 1-2; 2-3; 4-5 C. 1-4; 2-5; 3-5; 4-5 D. 2-4; 3-4; 3-5; 4-5
244 | L O V E B O O K . V N
Cu 13: Cho 0,17 mol NaOH vo 20 gam bo trung tnh ri un nng ln, khi phn ng xy ra hon ton ngi ta
thu c dung dch c tnh baz, trung ho dung dch ny phi dng ht 0,10 mol HCl. Tnh khi lng NaOH
cn x phng ho 1 tn cht bo trn?
A. 2,14 tn B. 1,41 tn C. 0,41 tn D.0,14 tn
Cu 14: C 3 ng nghim ng 3 dung dch: Cu(NO3)2; Pb(NO3)2; Zn(NO3)2 c nh s theo th t ng l 1, 2,
3. Nhng 3 l km (ging ht nhau) X, Y, Z vo 3 ng th khi lng mi l km s (gi s kim loi to ra bm ht
vo l km):
A. X gim, Y tng, Z khng i. B. X tng, Y gim, Z khng i.
C. X gim, Y gim, Z khng i. D. X tng, Y tng, Z khng i.
Cu 15: Trt t tng dn tnh baz ca dy no sau y l khng ng?
A. C6H5NH2 < NH3 B. NH3 < CH3NH2 < C2H5NH2
C. CH3CH2NH2 < (CH3)2NH D. p CH3C6H4NH2 < p O2NC6H4NH2
Cu 16: Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO c tng khi lng bng
2,60 gam. Mt khc, trung ho 0,04 mol X cn dng va 100 ml dung dch NaOH 0,30 M. X l phn ng va
vi dung dch cha m gam brom. Gi tr ca m l.
A. 4,8 B. 6,4 C. 8,4 D. 11,2
Cu 17: Cho hn hp A gm Al v Fe
3
O
4
. Nung A nhit cao phn ng xy ra hon ton thu c hn hp
B. Nghin nh hn hp B, trn u, chia lm hai phn khng bng nhau:
Phn 1 (phn t) tc dng vi dung dch NaOH d thu c 1,176 lt kh H
2
. Tch ring cht khng tan em ha
tan trong dung dch HCl d thu c 1,008 lt kh.
Phn 2 (phn nhiu) cho tc dng vi dung dch HCl d thu c 6,552 lt kh.
Th tch cc kh o ktc. Tnh khi lng hn hp A v phn trm khi lng ca Al trong hn hp A.
A. 22,02g v 63,22% B. 22,02g v 36,78% C. 16,515g v 63,22% D. 16,515g v 36,78%
Cu 18: Cho 8,4g Fe vo cc ng 200ml dung dch Cu(NO3)2 0,75M. Kt thc phn ng lc b cht rn khng tan,
thm tip vo cc dung dch HCl d. Hi sau khi phn ng xong th tch kh NO (ktc) thu c l bao nhiu (bit
NO l sn phm kh duy nht).
A. 1,12lit B. 0,112 lit C. 0,896 lit D. 3,36 lit
Cu 19: t chy hon ton 6,72 gam kim loi M vi oxi thu c 9,28 gam cht rn. Nu cho 5,04 gam M tc dng
ht vi dung dch HNO
3
d thu c dung dch X v kh NO (sn phm kh duy nht). Th tch kh NO (ktc) thu
c l:
A. 1,344 lt B. 2,016 lt C. 1,792 lt D. 2,24 lt
Cu 20: Hp cht A tc dng c vi K, AgNO3/NH3, khng tc dng vi NaOH. Khi cho A tc dng vi H2/Ni, t
0

to ra ancol ha tan c Cu(OH)2 to ra dung dch mu xanh lam. Cng thc cu to ca A l:
A. C2H5OH B. HOCH2CH2CHO C. HCOOCH3 D. CH3CH(OH)CHO
Cu 21: Trong cc cht: metyl xiclopropan; xiclobutan; but-1-in; ivinyl; buta-1,3- ien; isopren. S cht c kh
nng tc dng vi H2 to ra butan l.
A. 4 B. 5 C. 6 D. 3
Cu 22: Hp th 4,48 lt CO2 (ktc) vo 0,5 lt NaOH 0,4M v KOH 0,2M. Sau phn ng c dung dch X. Ly 1/2
X tc dng vi Ba(OH)2 d, to m gam kt ta. m v tng khi lng mui trong X ln lt l:
A. 19,7g v 20,6g B. 19,7gv 13,6g C. 39,4g v 20,6g D. 1,97g v 2,06g
Cu 23: Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C6H12O6 (fructoz), vinyl axetilen. S cht trong
dy tham gia c phn ng trng bc l
A. 6 B. 5 C. 3 D. 4
Cu 24: Mt dung dch X cha cc ion: Mg
2+
, SO
4
2
, NH
4
+
v Cl
. Chia X thnh hai phn bng nhau:

Phn 1 tc dng vi dung dch NaOH d, un nng thu c 0,58 gam kt ta v 0,672 lt kh (ktc).
Phn 2 tc dng vi dung dch BaCl
2
d thu c 4,66 gam kt ta.
Tng khi lng cc cht tan trong dung dch X l
A. 3,055g B. 4,110g C. 5,110g D. 6,110g
245 | G S T T G R O U P
Cu 25: Cho dy cc cht: glucoz, CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, anilin, phenol, benzen, metyl
xiclopropan, xiclobutan. S cht trong dy phn ng c vi nc brom l
A. 6 B. 9 C. 8 D. 7
Cu 26: Cho m gam Fe tan va trong dung dch hn hp HCl v FeCl3 thu c dung dch X ch cha mt mui
duy nht v 5,6 lt H2 (ktc). C cn dung dch X thu c 85,09 gam mui khan. m nhn gi tr no ?
A. 14 B. 20,16 C. 21,84 D. 23,52
Cu 27: C ba hp cht X (phenol); Y (ancol benzylic); Z (ancol anlylic). Khi cho ln lt cc cht trn tc dng
vi tng cht: K, dung dch NaOH, nc brom. C cc nhn nh sau:
(1). (X), (Y), (Z) u phn ng vi K. (2) (X), (Y), (Z) u phn ng vi NaOH.
(3). Ch c (X), (Z) phn ng vi nc brom. (4) Ch c (X) phn ng vi nc brom.
Cc nhn nh ng l:
A. (1), (4) B. (2), (3), (4) C. (1), (3), (4) D. (1), (3)
Cu 28: Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn t ca nguyn t Y cng
c electron mc nng lng 3p v c mt electron lp ngoi cng. Nguyn t X v Y c s electron hn km
nhau l 2. Nguyn t X, Y ln lt l
A. kh him v kim loi. B. kim loi v kim loi. C. phi kim v kim loi. D. kim loi v kh him.
Cu 29: un nng hn hp kh X (0,05 mol Vinylaxetilen v 0,12 mol H2) trong bnh kn (xc tc Ni), thu c hn
hp kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc phn ng c 1568ml hn hp kh Z (ktc)
thot ra. t ht Z thu c 896ml kh CO2 (ktc). Khi lng brom tham gia phn ng l.
Cu 30: Hn hp A gm bt Al v M. Ha tan hon ton 8,6 gam A bng dung dch HCl d th thu c 6,72 lt kh
(ktc). Nu nung nng 17,2 gam A trong khng kh th thu c cht rn nng 20,4 gam. Ly 17,2 gam A tc dng
va vi dung dch H
2
SO
4
c nng thu c V lt (ktc) kh SO
2
duy nht v dung dch B. Cho cc phn ng
xy ra hon ton. Gi tr ca V l:
A. 13,44 lt B. 22,4 lt C. 16,8 lt D. 26,88 lt
Cu 31: C bao nhiu dn xut halogen c cng thc phn t C4H8Cl2 khi tc dng vi dung dch NaOH, un nng
to ra sn phm khng tham gia phn ng trng bc.
A. 7 B. 8 C. 5 D. 6
Cu 32: Cho s phn ng H
2
S
+NaOH
X
+NaOH
Y
+Cu(NO
3
)
2
Z
X, Y, Z l cc hp cht cha lu hunh. X, Y, Z ln lt l:
A. Na
2
S, NaHS, CuS
2
B. Na
2
S, NaHS, CuS
C. NaHS, Na
2
S, CuS D. NaHS, Na
2
S, CuS
2

A. Thy tinh lng l dung dch m c ca Na
2
SiO
3
v K
2
SiO
3
.
B. CO v SiO
2
l oxit axit.
C. Nitrophotka l hn hp ca NH
4
H
2
PO
4
v KNO
3
.
D. Photpho trng c cu trc mng tinh th nguyn t, photpho c cu trc polime.
Cu 34: Xt phn ng M + H2SO4 M
3+
+ X + H2O. X l cht no nu tng s e m M nhng l 24?
A. H2S B. SO2 C. S D. SO3
Cu 35: Cho 15,6 gam hn hp hai ancol (ru) n chc, k tip nhau trong dy ng ng tc dng ht vi
10,35 gam Na, thu c 25,65 gam cht rn. Hai ancol l:
A. CH3OH v C2H5OH. B. C3H7OH v C4H9OH. C. C2H5OH v C3H7OH. D. C3H5OH v C4H7OH.
Cu 36: Nh t t dung dch NaOH vo dung dch X th thy dung dch vn c. Nh tip dung dch NaOH vo thy
dung dch trong sut tr li. Sau nh t t dung dch H
2
SO
4
long vo thy dung dch vn c, nh tip dung
dch H
2
SO
4
vo li thy dung dch tr nn trong sut. Dung dch X l
A. Mg(NO
3
)
2
B. AlCl
3
C. Ba(HCO
3
)
2
D. NaAlO
2

Cu 37: Cho 20 gam bt hn hp gm Al v Cu tc dng vi 500ml dung dch NaOH nng a mol/l ti khi ngng
thot kh th thu c 6,72 lt H
2
(ktc) v cn li m
1
gam cht rn A. Ha tan hon ton A bi dung dch HNO
3

246 | L O V E B O O K . V N
long thu c dung dch B v kh NO duy nht. Cho B tc dng vi lng d dung dch NH
3
thu c 31,2 gam
kt ta C. Mt khc, nu cng cho 20 gam bt trn tc dng vi 500ml dung dch HNO
3
b mol/l cho ti khi ngng
thot kh th thu c 6,72 lt kh NO duy nht (ktc) v cn li m
2
gam cht rn. Gi tr ca a v b l
Cu 38: Cho 13,5 gam hn hp Cl2 v Br2 c t l s mol l 5 : 2 vo mt dung dch cha 42g gam NaI, kt thc
phn ng khi lng mui thu c sau khi c cn dung dch l:
A. 21,7g B. 19,85g C. 19,25g D. 19,94g
Cu 39: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3
mol. t hiu sut cc i l 80% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l
(bit cc phn ng este ho thc hin cng nhit )
A. 0,4 B. 0,8 C. 1,6 D. 3,2
Cu 40: Mt dung dch X cha ng thi NaNO3, Cu(NO3)2, Fe(NO3)3, Zn(NO3)2, AgNO3. Th t cc kim loi thot
ra catot khi in phn dung dch trn vi in cc tr l:
A. Ag, Cu, Fe, Zn, Na B. Ag, Fe, Cu, Zn C. Ag, Cu, Fe, Zn D. Ag, Cu, Fe
Cu 41: Xp theo th t tng dn linh ng nguyn t H trong nhm OH trong phn t ca cc cht sau: C2H5OH
(1), CH3COOH (2), C2H3COOH (3), C6H5OH (4), HOH (5) l:
A. (5) < (1) < (4) < (2) < (3). B. (1) < (3) < (2) < (4) < (5) .
C. (1) < (5) < (4) < (2) < (3). D. (1) < (2) < (3) < (4) < (5) .
Cu 42: Dy gm cc cht u tc dng vi dung dch mui st (III) clorua l:
A. HBr, NaNO3, K2S, HNO3, HI. B. HCl, H2SO4, NaI, K2S, Pb(NO3)2.
C. Na2S, K2SO4, AgNO3, Pb(NO3)2, NaOH. D. KI, H2S, K2CO3, HI, AgNO3.
Cu 43: Trong bnh kn cha 3,5 mol hn hp gm H2, mt amin n chc v 4,0 mol O2. Bt tia la in t
chy hon ton hn hp thu c 1,0 mol CO2, 0,5 mol N2, 0,5 mol O2 v a mol H2O. Cng thc phn t ca amin
l
A. CH5N B. C2H7N C. C3H6N D. C3H5N
Cu 44: Ho tan a (g) hn hp Na2CO3 v KHCO3 vo nc c 400ml dung dch A. Cho t t 100ml dung dch
HCl1,5M vo dung dch A thu c dung dch B v 1,008lit kh ktc. Cho B tc dng vi lng d dung dch
Ba(OH)2 th thu c 29,55g kt ta. Gi tr ca a l:
A. 20g B. 20,3g C. 20,13g D. 21g
Cu 45: Hp cht X c cng thc phn t C3H9O2N tc dng vi dung dch NaOH, un nng nh thu c mui Y
v kh T lm hng dung dch phenolphtalein. Cho Y tc dng vi NaOH rn, nung nng thu c CH4. Tn gi ca
X l.
A. Amoni propionat B. Metyl amoni axetat C. Etyl amoni axetat D. Metyl amoni fomat
Cu 46: Tin hnh phn ng nhit nhm 21,4g hn hp bt X gm Al v Fe2O3 trong iu kin khng c khng kh,
(cho bit sn phm to thnh Fe) thu c hn hp Y. Cho hn hp Y thu c tc dng ht vi dung dch HCl d
thu c dung dch Z. Cho Z tc dng vi dung dch NaOH d thu c kt ta E. Nung E ngoi khng kh n khi
lng khng i thu c 16g cht rn. Khi lng mi cht trong X ln lt l:
A. 4,4g v 17g B. 5,4g v 16g C. 6,4g v 15g D. 7,4g v 14g
Cu 47: Cho hn hp hai amin n chc bc I c t khi so vi hidro l 19 (bit c mt amin c s mol bng 0,15)
tc dng vi dung dch
3
d thu c kt ta X. em nung X n khi lng khng i thu c 8 gam cht
rn. Cng thc ca hai amin l
A. CH
3
NH
2
v C
2
H
5
NH
2
B. CH
3
NH
2
v C
2
H
3
NH
2
C. C
2
H
5
NH
2
v C
2
H
3
NH
2
D. CH
3
NH
2
v CH
3
NHCH
3

Cu 48: t chy hon ton mt lng hn hp M gm ancol X, axit cacboxylic Y v este Z (u no, n chc mch
h v Y, Z c cng s nguyn t C) cn dng va 12,32 lt O
2
(ktc), sinh ra 11,2 lt CO
2
(ktc). Cng thc ca
Y l:
A. HCOOH B. C
2
H
5
COOH C. CH
3
(CH
2
)
2
COOH D. CH
3
COOH
247 | G S T T G R O U P
Cu 49: Ha tan hon ton 13,92 gam hn hp X gm MgO, FeO v Fe2O3 phi dng va ht 520 ml dung dch HCl
1M. Mt khc, khi ly 0,27 mol hn hp X t nng trong ng s khng c khng kh ri thi mt lung H2 d i
qua phn ng xy ra hon ton th thu c m gam cht rn v 4,86 gam nc. Xc nh m?
A. 16,56 B. 20,88 C. 25,06 D. 16,02
Cu 50: Polime c cu trc mng khng gian (mng li) l
A. PVC. B. Cao su lu ha C. PE D. Amilopectin

P N

1A 2D 3C 4B 5C 6A 7A 8D 9A 10D
11A 12C 13D 14A 15D 16A 17B 18D 19B 20D
21B 22A 23D 24D 25D 26C 27D 28C 29B 30D
31A 32C 33A 34A 35C 36B 37A 38D 39C 40C
41C 42D 43A 44C 45B 46B 47A 48D 49A 50B

248 | L O V E B O O K . V N
Cu 1: p n A
NaAlO2 + H2O + HCl NaCl + Al(OH)3 (1)
Al(OH)3 + 3HCl AlCl3 + 3 H2O (2)
TH1: Ch xy ra phn ng (1): n
HCl
= n
Al(OH)
3
= 0,01 V
dung dch
= 0,01 lt
TH2: Xy ra phn ng (1) v (2): n
HCl
= 0,05 +3(0,05 0,01) = 0,17 V
dung dch
= 0,17 (lt)
Cu 2: p n D
H2SO4 + 2KOH K2SO4 + 2H2O
TH1 : H2SO4 d
3H2SO4 + 2Al(OH)3 Al2(SO4)3 + 6H2O
0,015 0,01
n
H
2
SO
4
d
= 0,1a 0,065 = 0,015 a = 0,8
TH2: KOH d
KOH + Al(OH)3 KAlO2 + 2H2O
0,01 0,01
n
KOH d
= 0,13 2a = 0,01 a = 0,6
Cu3 : p n C
t s mol Fe, Mg, Cu ln lt l a, b, c
4H
+
+ NO
3
+ 3e NO + 2H
2
O
Khi cho Fe, Mg, Cu vo HNO3 0,68 0,170,51
Khi cho thm H2SO4 vo 0,44 0,110,33
n
e nhn
= n
e cho
= 0,51 +0,33 = 0,84 = 2a +2b +2c (1)
Sau khi nung ngoi khng kh, Fe
2+
b oxi ha ln Fe
3+

S mol oxi c trong hn hp oxit:
15,6 .2 23,52
16
= 0,48
n
e
= 0,96 = 3a +2b +2c (2)
T (1) v (2) suy ra a =0,12 m
Fe
= 6,72 g
Cu 4: p n B
Dung dch tha mn l dung dch FeCl
3
. Cc kt ta Cu(OH)
2
v Ni(OH)
2
tan trong dung dch NH
3
to
phc.
Cu 5: p n C
2 R(OH)m + 2mNa 2R(ONa)m +m H2
0,2/m 0,1
Vi m = 1 M
A
= 74 A: C
4
H
10
O
Vi m = 2 M
A
= 37 (loi)
Vi m = 3 M
A
= 24,67 (loi)
Cu 6: p n A
C {
% B
11
= a
% B
10
= b
th {
11a +10b = 10,81
a +b = 1
{
a = 0,81
b = 0,19

Phn trm khi lng B
11
trong H
3
BO
3
l
0,81 .11
3 +10,81 +16.3
. 100% = 14,42%
Cu 7: p n A
Ca + 2H2O Ca(OH)2 + H2
CaC2 + 2H2O Ca(OH)2 + C2H2
t s mol Ca v CaC2 l a, b
C {
m
hn hp
= 40a +64b = 4,96
a +b = 0,1
{
a = 0,06
b = 0,04

249 | G S T T G R O U P
{
0,02 mol C
2
H
2
0,03 mol H
2
0,075 mol O
2
Nung t
{
0,04 mol CO
2
0,05 mol H
2
O
0,01 mol O
2
d

M PV = nRT nn P =
nRT
V
= 0,785 (atm)
Cu 8: p n D
95C, khi lng CuSO
4
trong 1877g dung dch bo ha l
87,7
187,7
. 1877 = 877 g
t s mol CuSO4.5H2O l a
C% (25) =
40
140
=
877 160a
1877 250a
a = 3,847
Vy m
CuSO
4
.5H
2
O
= 961,75
Cu 9: p n A
n
anehit
= 0,15 (1)
n
H
2
= 0,1875 (2)
n
Ag
= 0,525 (3)
T (1) v (2) suy ra 1 anehit c 2 lin kt , 1 anehit c 1 lin kt
T (1) v (3) suy ra 1 anehit tc dng vi AgNO
3
to 4 Ag, anehit cn li to 2Ag
Do p n ng l A.
Cu 10: p n D
Cu 11: p n A
HCHO
[O]
HCOOH
HCHO
AgNO
3
4Ag
HCOOH
AgNO
3
2Ag
C {
x = 4a. 108
y = (2a +a). 108
x
y
=
4
3

Cu 12: p n C
Cu 13: p n D
Khi lng NaOH tham gia x phng ha 20g cht bo: (0,17 0,1).40 = 2,8 g
Do : Khi lng NaOH tham gia x phng ha 1 tn cht bo:
1
20
. 2,8 = 0,14 (tn)
Cu 14 : p n A
Cu 15: p n D
Cu 16: p n A
Gi {
n
CH
2
=CHCOOH
= a
n
CH
3
COOH
= b
n
CH
2
=CHCHO
= c
c {
n
hn hp
= a +b +c = 0,04
m
hn hp
= 72a +60b +56c = 2,6
n
axit
= a +b = 0,03
{
a = 0,02
b = 0,01
c = 0,01

n
Br
2
= a +c = 0,03 m
Br
2
= 4,8 (gam)
Cu 17: p n B
Phn 1: 2Al (d) + 2NaOH + 2H2O 2 NaAlO2 + 3H2
0,035 0,0525
Fe + HCl FeCl2 + H2
0,045 0,045
9. n
Al d
= 7. n
Fe

Phn 2 : 2Al + 6HCl 2AlCl3 + 3H2
Fe + HCl FeCl2 + H2
250 | L O V E B O O K . V N
n
H
2
=
3
2
n
Al
+n
Fe
=
39
14
n
Al
= 0,2925 n
Al d
= 0,105
n
Al d
= 0,14; n
Fe
= 0,18

8Al + 3Fe3O4 9Fe + 4Al2O3
0,16 0,06 0,18
n
Al (A)
= 0,3 mol %m
Al
=
0,3.27
22,02
. 100%= 36,78%
Cu 18: p n D
Fe + Cu(NO3)2 Fe(NO3)2 + Cu
0,15 0,15 0,15 0,15
4H
+
+ NO
3
+ 3e NO + 2H
2
O
Fe
2+
Fe
3+
+1e Cu Cu
2+
+2e
n
e nhn
= n
e cho
= 0,15 +0,15.2 = 0,45 n
NO
= 0,15 V = 3,36 (lt)
Cu 19: p n B
Gi n l s oxi ha ca M khi phn ng vi oxi.
C n
O
2
=
9,28 6,72
32
= 0,08
V n
e cho
= n
e nhn
nn 4n
O
2
= n. n
M
6,72
M
. n = 0,32 M = 21n
Vi n nguyn th khng c kim loi tha mn, do M l Fe vi n =
8
3

T d dng xc nh c n
NO
= n
Fe
= 0,09 (mol)
Cu 20: p n D
Cu 21: p n B
Cu 22: p n A
n
CO
2
= 0,2; n
NaOH
= 0,2; n
KOH
= 0,1
CO
2
+OH
HCO
3
CO
2
+2OH
CO
3
2
+H
2
O
a a a b 2b b
C {
a +b = 0,2
a +2b = 0,3
{
a = 0,1
b = 0,1

m
mui (X)
= m
Na
+ +m
K
+ +m
HCO
3
+m
CO
3
2 = 20,6 (gam)
Khi cho Ba(OH)2 vo
OH
+HCO
3
CO
3
2
+H
2
O
0,05 0,05
CO
3
2
+Ba
2+
BaCO
3

0,1 0,1 0,1
Vy m
kt ta
= 0,1.197 = 19,7 (gam)
Cu 23: p n D
Cc cht tha mn l: HCHO, HCOOH, CH3CHO, C6H12O6 (fructoz).
Cu 24: p n D
Phn 1 Mg
2+
+ 2OH
Mg(OH)2
0,01 0,01
NH
4
+

+ OH
NH3+ H2O
0,03 0,03
Phn 2 Ba
2+
+ SO
4
2

BaSO4
0,02 0,02
Theo nh lut bo ton in tch: 2n
Mg
2+ +n
NH
4
+ = n
SO
4
2 +n
Cl

251 | G S T T G R O U P
n
Cl
= 0,01 m
mui
= 6,11 (gam)
Cu 25: p n D
Cc cht tha mn l: glucoz, C2H2, C2H4, CH2=CH-COOH, anilin, phenol, metyl xiclopropan
Cu 26: p n C
Dung dch X ch cha mt mui l FeCl2
Fe + HCl FeCl2 + H2 Fe + 2FeCl3 3FeCl2
0,25 0,25 0,25 0,14 0,42
m
Fe
= 21,84 g
Cu 27: p n D
Cu 28: p n C
Cu 29: p n B
Hn hp Z gm a mol H2 v b mol C4H10
C {
a +b = 0,07
4a = 0,04
{
a = 0,01
b = 0,06

n
lin kt
= n
H
2
phn ng
+n
Br
2
n
Br
2
= 015 0,06 = 0,09 m
Br
2
= 14,4 (gam)
Cu 30: p n D
+) Nu M l kim loi ng trc H: n
H
2
= 0,3 n
e trao i
= 0,6
n
O
2
=
2.0,6
4
= 0,3 (mol) m
cht rn
= 17,2 +32.0,3 = 26,8 gam > 20,4 (gam) loi
+) Nu M l kim loi ng sau H: n
H
2
= 0,3 n
Al (8,6 gam A)
= 0,2
m
cht rn
> m
Al
2
O
3
= 0,2.102 = 20,4 (gam) loi
Do M phi l phi kim, khi nung vi O
2
to oxit v cht kh.
V A tc dng vi dung dch H
2
SO
4
c nng th ch thu c SO
2
duy nht nn M l S.
D dng tnh c trong 17,2 gam A cha 0,4 mol Al v 0,2 mol S.
n
e trao i
= 0,4.3 +0,2.4 = 2 (mol) n
SO
2
=
n
e trao i
2
+n
S
= 1,2 (mol)
Cu 31: p n A
V C
4
H
8
Cl
2
c 2 nguyn t Cl trong phn t nn C
4
H
8
Cl
2
phn ng vi dung dch NaOH long un nng
to ra sn phm c phn ng trng gng th hai nguyn t Cl ny phi cng nh vo nguyn t C bc I.
Do cc cng thc cu to tha mn yu cu l:
CH
3
CH
2
CHClCH
2
Cl, CH
3
CHClCH
2
CH
2
Cl, CH
2
ClCH
2
CH
2
CH
2
Cl, CH
3
(CHCl)
2
CH
3
, (CH
3
)
2
CClCH
2
Cl,
CH
2
ClCH(CH
3
)CH
2
Cl, CH
3
CH
2
CCl
2
CH
3
.
Vy c 7 cng thc cu to tha mn.
Cu 32: p n C
Do X tc dng c vi NaOH nn X l NaHS, khi Y l Na
2
S v Z l CuS
Cu 33: p n A
Cu 34: p n A
Cu 35: p n C
2Na + 2ROH 2RONa + H2
0,3 0,3 0,15
M
ROH
= 52 2 ancol l C
2
H
6
O v C
3
H
8
O
Cu 36: p n B
Cu 37: p n A
2NaOH + 2Al + H2O NaAlO2 + 3H2
0,2 0,2 0,3
a = 0,4 M
4H
+
+NO
3

+ 3e NO + 2H2O
1,2 0,3
b = 2,4 M
252 | L O V E B O O K . V N
Cu 38: p n D
Gi n
Cl
2
= 5a; n
Br
2
= 2a
Suy ra 71.5a +160.2a = 13,5 a = 0,02
X2 + 2NaI 2NaX + I2 (X2 : Cl2, Br2)
0,14 0,28 0,28
m
mui
= 19,94 g
Cu 39: p n C
CH
3
COOH +C
2
H
5
OH CH
3
COOC
2
H
5
+H
2
O
Ban u 1 1
Cn bng
1
3

1
3

2
3

2
3

K
C
=
[CH
3
COOC
2
H
5
][H
2
O]
[CH
3
COOH][C
2
H
5
OH]
= 4.
hiu sut t 80%
CH
3
COOH +C
2
H
5
OH CH
3
COOC
2
H
5
+H
2
O
Ban u 1 a
Cn bng 0,2 a 0,8 0,8 0,8
K
C
=
0,8
2
0,2(a 0,8)
= 4 a = 1,6
Cu 40: p n C
Cu 41: p n C
Cu 42: p n D
Cu 43: p n A
n
C
n
N
=
n
CO
2
2n
N
2
= 1 Chn p n
Cu 44: p n C
H
+
+ CO
3
2
HCO
3

0,105 0,105
H
+
+ HCO
3
H2O + CO2
0,045 0,045
n
Na
2
CO
3
= 0,105 mol (1)
Khi cho B tc dng vi Ba(OH)2
OH
+ HCO
3
H
2
O + CO
3
2

CO
3
2
+ Ba
2+
BaCO
3

n
HCO
3
= n
BaCO
3
= 0,15 n
KHCO
3
= 0,15 +0,045 0,105 = 0,09 (2)
T (1) v (2) suy ra a = 20,13
Cu 45: p n B
Cu 46: p n B
Fe
2
O
3
+Al,t
o
2Fe
+HCl
2FeCl
2
+NaOH
2Fe(OH)
2
t
o
Fe
2
O
3

m
Fe
2
O
3
= 16 (gam) m
Al
= 5,4 (gam)
Cu 47: p n A
t cng thc cah ai amin l RNH2
FeCl3 + 3RNH2 + 3H2O Fe(OH)3 + 3RNH3Cl
2Fe(OH)3
t
o
Fe2O3 + 3H2O
n
Fe
2
O
3
= 0,05 n
RNH
2
= 0,3 2 amin c t l mol 1: 1 R
1
+R
2
= 44
Do p n ng l A.
Cu 48: p n D
253 | G S T T G R O U P
V Y v Z c cng s nguyn t C nn Y, Z l ng phn ca nhau.
Gi cng thc phn t ca X v Y ln lt l C
m
H
2m+2
O v C
n
H
2n
O
2
.
Gi s mol ca X l a, tng s mol ca Y v Z l b.
T phng trnh t chy c {
a.
3n
2
+b.
3m2
2
= 0,55 (1)
am+bn = 0,5 (2)
b = 0,2
Do 0,2n < 0,5 n < 2,5 = 2
Cu 49: p n A
t s mol MgO, FeO, Fe2O3 trong 13,92g hn hp X ln lt l a, b, c
S mol 3 cht trong 0,27mol X ln lt l ka, kb, kc
{
m
hn hp
= 40a +72a +160c = 13,92 (1)
n
HCl
= 2a +2b +6c = 0,52 (2)
k(a +b +c) = 0,27 (3)
m
H
2
O
= 18k(b +3c) = 4,86 (4)

T (3) v (4)
18(b +3c)
a +b +c
= 18 2c a = 0 (5)
T (1), (2) v (5) c a = 0,08; b = 0,06; c = 0,04 k = 1,5
m
rn
= m
MgO
+m
Fe
= 16,56 (gam)
Cu 50: p n B

254 | L O V E B O O K . V N
s 39

Cu 1: Tin hnh phn ng nhit nhm hon ton m gam hn hp X gm bt Al v FexOy trong iu kin khng c
khng kh thu c hn hp Y. Nghin nh, trn u hn hp Y ri chia thnh 2 phn:
Phn 1 c khi lng 14,49 gam c ha tan ht trong dung dch HNO3 long, d, un nng thu c dung
dch Z v 0,165 mol NO (sn phm kh duy nht).
Phn 2 em tc dng vi dung dch NaOH d un nng thu c 0,015 mol kh H2 v cn li 2,52 gam cht rn.
Cng thc ca oxit st v gi tr ca m ln lt l
A. Fe3O4 v 28,98. B. Fe2O3 v 28,98. C. Fe3O4 v 19,32. D. FeO v 19,32.
Cu 2: Cho 2,74 gam Ba vo 100 ml dung dch hn hp HCl 0,2M v CuSO4 0,3M thu c m gam kt ta. Gi tr ca m
l
A. 2,94. B. 1,96. C. 5,64. D. 4,66.
Cu 3: St c s hiu nguyn t l 26, Fe
3+
c cu hnh l:
A. [Ar]3d
5
B. [Ar]3d
5
4s
1
C. [Ar]3d
10
4s
2
D. [Ar]3d
3
4s
2

Cu 4: Hp cht X l dn xut ca benzen c cng thc phn t C8H10O2. X tc dng NaOH theo t l mol 1:1. Mt
khc, khi cho X tc dng vi Na d th s mol H2 thu c ng bng s mol X phn ng. Nu tch mt phn t
nc t X th thu c sn phm c kh nng trng hp to thnh polime. S cng thc cu to ca X l
A. 3. B. 6. C. 7. D. 4.
Cu 5: Hn hp A gm mt axit no, h, n chc v hai axit khng no, h, n chc (gc hirocacbon cha mt
lin kt i), k tip nhau trong dy ng ng. Cho A tc dng hon ton vi 150 ml dung dch NaOH 2,0 M.
trung ha va ht lng NaOH d cn thm vo 100 ml dung dch HCl 1,0 M c dung dch D. C cn cn thn D
thu c 22,89 gam cht rn khan. Mt khc t chy hon ton A ri cho ton b sn phm chy hp th ht vo
bnh ng lng d dung dch NaOH c, khi lng bnh tng thm 26,72 gam. Phn trm khi lng ca axit
khng no c khi lng phn t nh hn trong hn hp A l
A. 35,52% B. 40,82% C. 44,24% D. 22,78%
Cu 6: C ba dung dch, mi dung dch cha mt cht theo th t A, B, C tho mn cc th nghim:
A + B (c kt ta xut hin); B + C (c kt ta xut hin); A + C (c kt ta xut hin ng thi c kh thot
ra)
Cho cc cht A, B, C ln lt l
(1) H2SO4, BaCl2, Na2CO3. (2) (NH4)2CO3, Ba(NO3)2, H2SO4. (3) Ba(HCO3)2, Ba(OH)2, H2SO4.
(4) HCl, AgNO3, Fe(NO3)2. (5) (NH4)2CO3, H2SO4, Ba(OH)2. (6) BaS, FeCl2, H2SO4 long.
S dy cht tha mn cc th nghim trn l
A. 3. B. 1. C. 4. D. 2.
Cu 7: Cho 9,3 gam cht X c cng thc phn t C3H12N2O3 un nng vi 2 lt dung dch KOH 0,1M. Sau khi phn
ng hon ton thu c mt cht kh lm qu tm m i thnh xanh v dung dch Y ch cha cht v c. C cn
dung dch Y thu c khi lng cht rn khan l
Cu 8: Cho m gam hn hp X gm axit axetic, axit benzoic, axit aipic, axit oxalic tc dng va vi dung dch NaOH
thu c a gam mui. Cng cho m gam hn hp X ni trn tc dng vi Ca(OH)2 va thu c b gam mui. Biu
thc lin h gia m, a v b l
A. 3m = 22b-19a. B. 9m = 20a-11b. C. 3m = 11b-10a. D. 8m = 19a-11b.
Cu 9: Cao su buna-N c to ra do phn ng ng trng hp gia buta-1,3-ien vi acrilonitrin. t chy hon
ton mt lng cao su buna-N vi khng kh va (cha 80% N2 v 20% O2 v th tch), sau a hn hp
sau phn ng v 136,5
o
C thu c hn hp kh v hi Y (cha 14,41% CO2 v th tch). T l s mt xch gia buta-
1,3-ien v acrilonitrin l
A. 1:2. B. 2:3. C. 3:2. D. 2:1.
255 | G S T T G R O U P
(1) Peptit cha t hai gc -aminoaxit tr ln th c phn ng mu biure.
(2) T tm l loi t thin nhin.
(3) ng vi cng thc phn t C3H7O2N c hai ng phn aminoaxit.
(4) Cc cht HCOOH, HCOONa v HCOOCH3 u tham gia phn ng trng bc.
(5) Hn hp CaF2 v H2SO4 c n mn c thu tinh.
(6) Amophot l hn hp gm (NH4)2HPO4 v (NH4)3PO4 thu c khi cho NH3 tc dng vi H3PO4.
(7) Cc cht: Cl2, NO2, P, SO2, N2, Fe3O4, S, H2O2 u va c tnh oxi ha, va c tnh kh.
Trong cc nhn nh trn, s nhn nh ng l
A. 4. B. 7. C. 5. D. 6.
Cu 11: Nung nng a mol hn hp X gm C2H2 v H2 trong bnh kn c xc tc thch hp thu c hn hp kh Y. Dn Y
qua lng d dung dch AgNO3 trong NH3, sau khi phn ng hon ton thu c 24 gam kt ta v hn hp kh Z. Hn
hp Z lm mt mu ti a 40 gam brom trong dung dch v cn li hn hp kh T. t chy hon ton hn hp T thu
c 11,7 gam nc. Gi tr ca a l
A. 1,00. B. 0,80. C. 1,50. D. 1,25.
Cu 12: Amin X n chc, mch h c nit chim 16,092% (v khi lng). S ng phn amin bc hai ca X l
A. 6. B. 7. C. 4. D. 5.
Cu 13: Ha tan ht mt lng kim loi Na cn V ml ancol (ru) etylic 46
0
thu c 63,84 lt H2(ktc). Bit khi lng
ring ca ru etylic nguyn cht l 0,8 g/ml. Gi tr nh nht ca V l
A. 100. B. 180. C. 150. D. 120.
Cu 14: Nung m gam bt Cu trong oxi thu c 24,8 gam hn hp rn X gm Cu, CuO v Cu
2
O. Ha tan hon ton
X bng H
2
SO
4
c, nng thu c 4,48 lt (ktc) kh SO
2
duy nht. Tnh gi tr ca m.
A. 15,48 B. 20,32 C. 22,4 D. 9,68
(1) Cho dung dch Ba(OH)2 vo dung dch NaHCO3.
(2) Cho dung dch Al2(SO4)3 ti d vo dung dch NaAlO2 (hoc dung dch Na[Al(OH)4]).
(3) Sc kh CH3NH2 ti d vo dung dch FeCl3.
(4) Sc kh propilen vo dung dch KMnO4.
(5) Sc kh CO2 vo dung dch Na2SiO3.
(6) Sc kh NH3 ti d vo dung dch AgNO3.
Sau khi cc phn ng kt thc, s th nghim thu c kt ta l
A. 6. B. 4. C. 3. D. 5.
Cu 16: Cho cc dung dch: K2CO3, C6H5ONa, CH3NH3Cl, KHSO4, Na[Al(OH)4] hay NaAlO2, Al(NO3)3, NaHCO3,
NH4NO3, C2H5ONa, CH3NH2, lysin, valin. S dung dch c pH > 7 l
A. 8. B. 9. C. 7. D. 10.
(1) Cc cht phenol, axit photphoric u cht l cht rn iu kin thng.
(2) H2SO4 l cht lng khng mu, bc khi mnh trong khng kh m, D=1,53 g/cm
3
, si 86
0
C.
(3) Cht dng lm nguyn liu ch to thuc sng khng khi l xenluloz.
(4) Poliacrilonitrin l cht khng cha lin kt pi ().
Trong cc pht biu trn, s pht biu ng l
A. 4. B. 3. C. 1. D. 2.
Cu 18: Cho 0,03 mol hn hp X gm R-COOH v R-COOM (M l kim loi kim, R l gc hirocacbon) tc dng vi
0,02 mol Ba(OH)2. trung ha lng Ba(OH)2 d cn 200 ml dung dch HCl 0,1M ri c cn dung dch sau cc
phn ng trn thu c 6,03 gam cht rn khan. Axit R-COOH c tn gi l
A. axit butiric. B. axit axetic. C. axit acrylic. D. axit propionic.
256 | L O V E B O O K . V N
Cu 19: X v Y ln lt l tripeptit v hexapeptit c to thnh t cng mt aminoaxit no mch h, c mt nhm
-COOH v mt nhm -NH2. t chy hon ton 0,1 mol X bng O2 va thu c sn phm gm CO2, H2O v N2
c tng khi lng l 40,5 gam. Nu cho 0,15 mol Y tc dng hon ton vi dung dch NaOH (ly d 20% so vi
lng cn thit), sau phn ng c cn dung dch thu c khi lng cht rn khan l
Cu 20: Cho 3 cht hu c X, Y, Z (mch thng, ch cha C, H, O) u c khi lng mol l 82 (trong X v Y l
ng phn ca nhau). Bit 1,0 mol X hoc Z tc dng va vi 3,0 mol AgNO3 trong dung dch NH3; 1,0 mol Y
tc dng va vi 4,0 mol AgNO3 trong dung dch NH3. Kt lun khng ng khi nhn xt v X, Y, Z l
A. S lin kt trong X, Y v Z ln lt l 4, 4 v 3.
B. S nhm chc -CHO trong X, Y v Z ln lt l 1,2 v 1.
C. Phn trm khi lng ca hiro trong X l 7,32% v trong Z l 2,44%.
D. Phn trm khi lng oxi trong X l 39,02% v trong Z l 19,51%.
Cu 21: Hp cht hu c X c cha cacbon, hiro, oxi. Phn tch nh lng cho kt qu: 46,15% C; 4,62% H;
49,23% O (v khi lng). Bit phn t khi ca X nh hn 200 vC. Khi un X vi dung dch NaOH d thu c
mt mui Y v mt ancol Z mch h u thun chc (khng tp chc). S ng phn cu to ca X l
A. 6. B. 7. C. 3. D. 4.
Cu 22: Hn hp X gm 0,1 mol anehit metacrylic v 0,3 mol kh hiro. Nung nng hn hp X mt thi gian, c
mt cht xc tc Ni thu c hn hp hi Y c t khi hi so vi He bng 95/12. Dn ton b hn hp Y qua dung
dch brom nc d th thy ht a mol Br2. Gi tr ca a l
A. 0,04. B. 0,02. C. 0,20. D. 0,08.
Cu 23: un nng m gam hn hp X (R-COO-R1; R-COO-R2) vi 500 ml dung dch NaOH 1,38M thu c dung dch
Y v 15,4 gam hn hp T gm hai ancol n chc l ng ng lin tip. Cho ton b lng T tc dng vi Na d
thu c 5,04 lt kh hiro (ktc). C cn Y thu c cht rn ri ly cht rn ny em nung vi CaO xc tc n
khi phn ng xy ra hon ton thu c 7,2 gam mt kh. Gi tr ca m l
A. 34,51. B. 31,00. C. 20,44. D. 40,60.
Cu 24: Cho cc cht: phenylamoni clorua, phenyl clorua, m-crezol, ancol benzylic, natri phenolat, phenol, anilin.
S cht trong dy tc dng c vi dung dch NaOH long, un nng l
A. 3. B. 2. C. 4. D. 5.
Cu 25: So snh tnh cht ca glucoz, tinh bt, saccaroz, xenluloz.
(1) C 4 cht u d tan trong nc v u c cc nhm -OH.
(2) Tr xenluloz, cn li glucoz, tinh bt, saccaroz u c th tham gia phn ng trng bc.
(3) C 4 cht u b thy phn trong mi trng axit.
(4) Khi t chy hon ton 4 cht trn u thu c s mol CO2 v H2O bng nhau.
(5) C 4 cht u l cc cht rn, mu trng.
Trong cc so snh trn, s so snh khng ng l
A. 5. B. 3. C. 2. D. 4.
Cu 26: Cho cc kt lun sau:
(1) t chy hirocacbon thu c
2 2
H O CO
n n >
th hirocacbon l ankan.
(2) t chy hirocacbon thu c
2 2
H O CO
n n =
th hirocacbon l anken.
(3) t chy ankin th c
2 2
H O CO
n n <
v nankin =
2 2
CO H O
n n
.
(4) Tt c cc ankin u c th tham gia phn ng th bi AgNO3/NH3.
(5) Tt c cc anken i xng u c ng phn hnh hc.
(6) Anilin l cht lng, khng mu, t tan trong nc, nng hn nc. lu trong khng kh, anilin c nhum mu
en v b oxi ho.
(7) Cao su buna c tnh n hi v bn tt hn cao su thin nhin.
(8) Toluen v stiren u lm mt mu dung dch thuc tm iu kin thng.
257 | G S T T G R O U P
Trong cc kt lun trn, s kt lun ng l:
A. 3. B. 5. C. 6. D. 4.
Cu 27: Cho cc dung dch: HCl (X1); KNO3 (X2) ; HCl + KNO3 (X3) ; Fe(NO3)3 (X4); AgNO3 (X5). Dung dch c th
ho tan c bt Cu l:
A. X1, X3, X4 ;X5 B. X3, X4 ;X5 C. X1, X2 ;X3 ;X4 D. X2; X3, X4
(1) iu ch t nilon-6,6 bng phn ng trng ngng gia axit aipic v hexametylen iamin.
(2) iu ch poli (vinyl ancol) bng phn ng trng hp ancol vinylic.
(3) Cao su buna-S c iu ch bng phn ng ng trng hp gia buta-1,3-ien vi stiren.
(4) Trong mt nguyn t, s khi bng tng s ht proton v ntron.
(5) Trong in phn dung dch NaCl, trn catot xy ra s oxi ho nc.
(6) T xenluloz axetat thuc loi t ha hc.
(7) Nitrophotka l hn hp gm KNO3 v (NH4)2HPO4.
(8) Ancol etylic v axit fomic c khi lng phn t bng nhau nn l cc cht ng phn vi nhau.
Trong cc pht biu trn, s pht biu khng ng l
A. 7. B. 5. C. 4. D. 6.
Cu 29: Cho 23 gam hn hp X gm Al, Cu, Fe tc dng vi 400ml dung dch CuSO
4
1M n khi phn ng xong thu c
dung dch Z v m gam hn hp T gm 2 kim loi. Cho Z tc dng vi dung dch NaOH thu c lng kt ta ln nht l 24,6
gam. Gi tr ca m l:
A. 37,6. B. 27,7. C. 19,8. D. 42,1.
Cu 30: t chy hon ton 0,1 mol mt loi cht bo X thu c CO2 v H2O hn km nhau 0,6 mol. Tnh th tch
dung dch Br2 0,5M ti a phn ng ht vi 0,3 mol cht bo X ?
A. 0,36 lt. B. 2,40 lt. C. 1,20 lit. D. 1,60 lt.
Cu 31: Cho m gam bt kim loi R ha tr 2 vo dung dch CuSO4 d. Sau phn ng hon ton, khi lng cht rn
thu c gim 0,24 gam so vi khi lng cht rn ban u. Cng cho m gam bt kim loi trn vo dung dch
AgNO3 d, n khi phn ng hon ton, khi lng cht rn thu c tng 0,52 gam so vi khi lng cht rn
ban u. Kim loi R l
A. Sn. B. Zn. C. Cd. D. Pb.
Cu 32: Xt cn bng trong bnh kn c dung tch khng i: X(kh) 2Y(kh)
Ban u cho 1 mol kh X vo bnh, khi t n trng thi cn bng th thy: Ti thi im 35
0
C trong bnh c
0,730 mol X; Ti thi im 45
0
C trong bnh c 0,623 mol X.
C cc pht biu sau v cn bng trn:
(1) Phn ng thun l phn ng thu nhit.
(2) Khi tng p sut, cn bng chuyn dch theo chiu nghch.
(3) Thm tip Y vo hn hp cn bng th lm cho cn bng chuyn dch theo chiu nghch.
(4) Thm xc tc thch hp vo hn hp cn bng th cn bng vn khng chuyn dch.
Trong cc pht biu trn, s pht biu ng l
A. 3. B. 2. C. 4. D. 1.
Cu 33: Cho cc nhn xt sau:
(1) Metylamin, imetylamin, trimetylamin v etylamin l nhng cht kh, mi khai kh chu, tan nhiu trong
nc.
(2) Anilin lm qu tm m i thnh mu xanh.
(3) Alanin lm qu tm m chuyn mu .
(4) Phenol l mt axit yu nhng c th lm qu tm m chuyn thnh mu .
(5) Trong cc axit HF, HCl, HBr, HI th HI l axit c tnh kh mnh nht.
(6) Oxi c th phn ng trc tip vi Cl2 iu kin thng.
(7) Cho dung dch AgNO3 vo 4 l ng cc dung dch HF, HCl, HBr, HI, th c 4 l u c kt ta.
(8) Khi pha long H2SO4 c th nn t t nc vo axit.
258 | L O V E B O O K . V N
Trong s cc nhn xt trn, s nhn xt khng ng l
A. 5. B. 6. C. 8. D. 7.
Cu 34: t m gam hn hp X gm Fe, Cu, Mg, Zn trong oxi thu c 29,7 gam hn hp cht rn Y. Ha tan ht Y bng
dung dch HNO3 c nng d thu c 17,92 lit kh NO2 (ktc). Cho m gam hn hp X tc dng vi dung dch H2SO4
c, nng, d thu c dung dch Z cha 84,1 gam mui v kh SO2. Bit rng NO2 v SO2 l cc sn phm kh duy nht
ca HNO3 v H2SO4. Gi tr ca m l
A. 20,9. B. 20,1. C. 26,5. D. 23,3.
Cu 35: Cho cc phng trnh phn ng:

(1) dung dch FeCl2 + dung dch AgNO3 d (2) Hg + S (3) F2 + H2O
(4) NH4Cl + NaNO2
to
(5) K + H2O (6) H2S + O2 d
to

(7) SO2 + dung dch Br2 (8) Mg + dung dch HCl (9) Ag + O3
(10) KMnO4
to
(11) MnO2 + HCl c
to
(12) dung dch FeCl3 + Cu
Trong cc phn ng trn, s phn ng to n cht l
A. 9. B. 6. C. 7. D. 8.
Cu 36: Mi phn t XY3 c tng s ht proton, ntron, electron bng 196, trong s ht mng in nhiu hn
ht khng mang in l 60. S ht proton ca nguyn t X t hn s ht proton ca nguyn t Y l 4.
Thc hin phn ng: X + HNO3 T + NO + N2O + H2O.
Bit t l mol ca NO v N2O l 3:1. Tng h s (nguyn, ti gin) ca cc cht trong phn ng trn l
A. 143. B. 145. C. 146. D. 144.
Cu 37: Trng hp no di y hn hp cht rn khng b ha tan ht (gi thit cc phn ng xy ra hon
ton)?
A. Cho hn hp cha 0,10 mol Cu v 0,10 mol Ag vo dung dch HNO3 c, nng cha 0,5 mol HNO3.
B. Cho hn hp cha 0,10 mol Mg v 0,10 mol Zn vo dung dch cha 0,5 mol HCl.
C. Cho hn hp cha 0,05 mol Ba v 0,10 mol Al vo nc d.
D. Cho hn hp cha 0,10 mol Fe2O3 v 0,10 mol Cu vo dung dch HCl d.
Cu 38: Nhit phn 50,56 gam KMnO4, sau mt thi gian thu c 46,72 gam cht rn. Cho ton b lng kh sinh
ra phn ng ht vi hn hp X gm Mg, Fe thu c hn hp Y nng 13,04 gam. Ha tan hon ton hn hp Y trong
dung dch H2SO4 c, nng, d thu c 1,344 lt SO2 ktc (sn phm kh duy nht). Phn trm khi lng ca
Mg trong hn hp X l
A. 39,13%. B. 46,15%. C. 28,15%. D. 52,17%.
Cu 39: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch NaOH 0,5M thu c
mt mui v 448 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm
chy vo bnh ng dung dch Ca(OH)2 d th khi lng bnh tng 8,68 gam. Cng thc ca hai hp cht hu c trong X
l
A. C2H5COOH v C2H5COOCH3. B. HCOOH v HCOOC2H5.
C. CH3COOH v CH3COOCH3. D. CH3COOH v CH3COOC2H5.
Cu 40: in phn vi in cc tr dung dch cha 0,3 mol AgNO3 bng cng dng in 2,68 ampe, trong thi
gian t (gi) thu c dung dch X. Cho 22,4 gam bt Fe vo dung dch X thy thot ra kh NO (sn phm kh duy
nht) thu c 34,28 gam cht rn. Cc phn ng xy ra hon ton. Gi tr ca t l
A. 1,25. B. 1,30. C. 1,00. D. 1,20.
Cu 41: Hn hp kh X gm SO2 v khng kh c t l th tch tng ng l 1:5. un nng hn hp X vi xc tc
V2O5 trong mt bnh kn c dung tch khng i thu c hn hp kh Y. T khi hi ca X so vi Y l 0,93. Khng
kh c 20% th tch l O2 v 80% th tch l N2. Hiu sut ca phn ng oxi ha SO2 l
A. 84%. B. 75%. C. 80%. D. 42%.
259 | G S T T G R O U P
Cu 42: Ha tan hon ton hn hp FeS v FeCO3 bng dung dch HNO3 c, nng, d thu c hn hp gm 2 kh CO2
v NO2 (NO2 l sn phm kh duy nht ca HNO3) c t khi hi so vi hiro bng 22,909. Phn trm khi lng ca
FeS trong hn hp ban u l
A. 44,47%. B. 43,14%. C. 83,66%. D. 56,86%.
Cu 43: Thy phn ht mt lng pentapeptit T thu c 32,88 gam Ala-Gly-Ala-Gly; 10,85 gam Ala-Gly-Ala; 16,24
gam Ala-Gly-Gly; 26,28 gam Ala-Gly; 8,9 gam Alanin; cn li l Glyxin v Gly-Gly vi t l mol tng ng l 1:10.
Tng khi lng Gly-Gly v Glyxin trong hn hp sn phm l
Cu 44: Hn hp X gm hiro, propen, propanal, ancol alylic (CH2=CH-CH2OH). t chy hon ton 1 mol hn
hp X thu c 40,32 lt CO2 (ktc). un X vi bt Ni, sau mt thi gian thu c hn hp Y, c
Y
X
d 1, 25 = . Dn
0,1 mol hn hp Y qua dung dch brom d, thy ht m gam brom. Gi tr ca m l
A. 12,0. B. 16,0. C. 4,0. D. 8,0.
(1) Sc kh etilen vo dung dch KMnO4

long.
(2) Cho hi ancol etylic i qua bt CuO nung nng.
(3) Sc kh etilen vo dung dch Br2

trong CCl4.
(4) Cho dung dch glucoz vo dung dch AgNO3

trong NH3

d, un nng.
(5) Cho Fe3O4

vo dung dch H2SO4

c, nng.
(6) Cho dung dch HCl vo dung dch Fe(NO3)2.
(7) Cho FeS vo dung dch HCl.
(8) Cho Si vo dung dch NaOH c, nng.
Trong cc th nghim trn, s th nghim c xy ra phn ng oxi ha-kh l
A. 4. B. 6. C. 7. D. 5.
Cu 46: Ln men m kg go cha 80% tinh bt iu ch c 10 lt ru (ancol) etylic 36,8
0
. Bit hiu sut c qu
trnh iu ch l 50% v khi lng ring ca ru nguyn cht l 0,8 gam/ml. Gi tr ca m l
A. 16,200. B. 20,250. C. 8,100. D. 12,960.
Cu 47: Thc hin phn ng crackinh m gam isobutan thu c hn hp X ch c cc hirocacbon. Dn hn hp X qua
dung dch cha 6,4 gam brom, thy brom phn ng ht v c 4,704 lt hn hp kh Y (ktc) thot ra. T khi hi ca Y so
vi H2 l 117/7. Gi tr ca m l
A. 10,44. B. 8,70. C. 9,28. D. 8,12.
Cu 48: Cho cc kt qu so snh sau:
(1) Tnh axit: CH3COOH > HCOOH. (2) Tnh baz: C2H5NH2 > CH3NH2.
(3) Tnh tan trong nc: CH3NH2 > CH3CH2CH2NH2. (4) S ng phn: C3H8O > C3H9N.
(5) Nhit si: CH3COOH > CH3CHO.
Trong s cc so snh trn, s so snh ng l:
A. 3. B. 4. C. 5. D. 2.
Cu 49: Ho tan hon ton 8,4 gam Fe cn V ml dung dch HNO3 0,5M thu c kh NO (sn phm kh duy nht). Gi tr nh
nht ca V l
A. 400. B. 1200. C. 800. D. 600.
Cu 50: Nhit phn hon ton hn hp T gm Fe(NO3)2 v Al(NO3)3 thu c hn hp kh X. Trn hn hp kh X
vi 112 ml kh O2 (ktc) thu c hn hp kh Y. Hp th hon ton hn hp kh Y vo 3,5 lt H2O (khng thy c
kh thot ra) thu c dung dch c pH = 1,7. Phn trm khi lng ca Fe(NO3)2 trong hn hp T l
A. 62,83%. B. 50,26%. C. 56,54%. D. 75,39%.

P N

1C 2C 3A 4B 5D 6B 7B 8A 9B 10C
260 | L O V E B O O K . V N
11D 12A 13C 14C 15D 16C 17D 18D 19B 20C
21A 22A 23D 24A 25A 26A 27B 28C 29A 30B
31C 32C 33B 34C 35D 36B 37A 38A 39D 40B
41D 42B 43B 44D 45C 46D 47B 48A 49C 50A

261 | G S T T G R O U P
s 40

Cu 1. S ng phn ancol, mch h tc dng vi Cu(OH)2 iu kin thng to dung dch xanh lam ng vi
cng thc phn t
C
4
H
10
O
2 l
A.6 B.2 C.4 D.3
Cu 2. t chy hn hp hai hidrocacbon ng ng k tip, thu c 17,92 lt kh CO2(ktc) v 19,8 gam H2O.
Thnh phn phn trm theo khi lng ca hidrocacbon c nguyn t khi nh hn l :
A. 25,42%. B. 33,33%. C. 74,58%. D. 66,67%.
Cu 3. Phn ng no sau y l ng :
A. CH
3
CH
2
Cl +AgNO
3
CH
3
CH
2
NO
3
+AgCl.
B. CH
2
= CHCl +H
2
O
t
CH
3
CHO +HCl.
C. CH
2
= CH CH
2
Br +NaOH
t
CH
2
= CH CH
2
OH +NaBr.
D. C
6
H
5
CH
2
Br +2NaOH
t
C
6
H
5
CH
2
ONa +NaBr +H
2
O.
1. Ancol pentan-3-ol khi tch nc 170 to ra mt anken duy nht.
2. Xiclopentan khng b oxi ha bi thuc tm nhit thng, nhng li c phn ng khi un nng.
3. un nng ru metylic nhit t 140 n 170, xc tc H
2
SO
4
c ch thu c mt sn phm hu c
duy nht.
4. Phenol phn ng vi brom nhit thng to ra kt ta mu vng nht.
5. Phn ng gia etilenglicol v Cu(OH)
2
/NaOH gi l phn ng mu biur (to phc cht mu xanh lam).
6. T CO, bng t nht hai phn ng c th iu ch axit axetic.
S pht biu khng ng l:
A. 3. B. 4. C. 5. D. 6.
Cu 5.Cht hu c X ng thi tha mn 3 iu kin:
- Tc dng vi Na
2
CO
3
to kh khng mu.
- C phn ng trng gng.
- C s nguyn t oxi l nh nht.
S nguyn t oxi ca X l:
A. 1. B. 3. C. 2. D. 4.
Cu 6. Du chui (isoamylaxetat) c tng hp t ancol isoamylic (3-metylbutan-1-ol) v axit axetic. Gi s hiu
sut ca phn ng tng hp l 40%, khi lng ancol cn dng thu c 26 gam du chui l:
A. 44 gam. B. 17,6 gam. C. 7,04 gam. D. 30 gam.
Cu 7.Pht biu no sau y l sai:
A. Andehit acrylic c kh nng tham gia phn ng trng bc.
B. Andehit acrylic phn ng vi Br
2
theo t l 1:2.
C. T andehit acylic c th iu ch axit acrylic bng mt phn ng.
D. Thy tinh hu c c tn gi l poli(metylacrylat).
Cu 8. X phng ha hon ton m gam tristearin bng NaOH, tng khi lng cc sn phm hu c to ra l 303
gam. Gi tr ca m l:
A. 276. B. 267. C. 286. D. 268.
Cu 9. Nhn nh no v amin l ng:
A. Cc amin l thnh phn to nn tht, c, l cht dinh dng cn thit i vi c th sng.
B. Amin l sn phm thu c khi thay th mt hay nhiu nguyn t H trong phn t NH
3
bng mt hay nhiu
gc hidrocacbon.
C. Etylamin l cht kh iu kin thng, c mi thm d chu.
D. S nguyn t H ca amin khng th l s l.
262 | L O V E B O O K . V N
Cu 10.Chia m gam glyxin thnh 2 phn, trong phn th nht gp 4 ln phn th 2. Phn th nht cho tc dng
vi 9,53 gam NaOH, c cn thu c m1 gam cht rn. Phn th hai cho tc dng vi 200ml dung dch HCl 0,1M,
c cn thu c m2 gam cht rn. Bit rng m
1
= 5m
2
. Gi tr ca m l:
A. 15. B. 16,875. C. 18,75. D. 19,5.
1. Lin kt -CO-NH- gia 2 n v aminoaxit c gi l lin kt peptit.
2. M chnh (bt ngt) l mui inatriglutamat.
3. Dung dch lysin trong nc lm qu tm ha xanh.
4. Mi peptit u c phn ng mu biure.
5. Mi protein u c phn ng mu biure.
6. Cc peptit u b thy phn trong mi trng kim.
S pht biu ng l:
A. 0. B. 1. C. 2. D. 3.
Cu 12. Cho 120,6 gam hn hp ng mantozo v glucozo phn ng vi AgNO
3
/NH
3
(d), thu c 86,4 gam
kt ta. Cng em 120,6 gam hn hp trn, thy phn hon ton trong mi trng axit, ri cho sn phm to
thnh phn ng vi dung dch Br
2
. Lng Br
2
b mt mu trong phn ng trn l:
A. 2 mol. B. 1,4 mol. C. 0,8 mol. D. 0,4 mol.
Cu 13. Polime thuc loi polieste l:
A. T nitron. B. T capron. C. T lapsan. D. T tm.
Cu 14. un nng 20,8 gam axetilen trong iu kin thch hp, thu c V lt(ktc) hn hp X (gi s phn ng
ch to thnh vinylaxetilen). Cho hn hp X phn ng vi AgNO
3
/NH
3
d, to thnh 95,7 gam kt ta. Gi tr ca
V l :
A. 11,2. B. 10,08. C. 8,96. D. 13,44.
Cu 15. Thc hin phn ng gia 94 gam phenol v 51 gam anhidrit axetic trong iu kin thch hp (gi s phn
ng xy ra hon ton), thu c hn hp X. Cho X phn ng vi NaOH va , c cn dung dch thu c m gam
mui. Gi tr ca m l:
A. 116. B. 198. C. 157. D. 176.
Cu 16. Pht biu no sau y l sai:
A. T etilen c th iu ch trc tip andehit axetic.
B. T ancol etylic c th iu ch trc tip butadien.
C. T butan c th iu ch trc tip axit axetic.
D. T metanal c th iu ch trc tip metan.
Cu 17.Cht no sau y c ng phn hnh hc:
A. But-1-en. B. Axit linoleic
C. Axit acrylic. D. Glixerol.
Cu 18. Cho 15,84 gam este no n chc mch h phn ng va ht vi 30ml dung dch ROH 20%(c khi lng
ring 1,2g/ml, R l kim loi kim). Sau phn ng c cn dung dch c cht rn X. t chy hon ton X thu c
9,54 gam R
2
CO
3
v hn hp gm CO
2
, H
2
O. Kim loi R v este ban u c cu to l:
A. K v HCOOCH
3
. B. Li v CH
3
COOC
2
H
5
.
C. Na v CH
3
COOC
2
H
5
. D. Na v HCOOC
2
H
5
.
Cu 19. t chy hon ton m gam hn hp X gm hai ancol ng ng k tip, cho sn phm chy qua bnh cha
dung dch Ca(OH)
2
d thy khi lng bnh tng 19,1 gam v c 25 gam kt ta. Nu oxi ha ht m gam X bng
CuO d, ly sn phm thu c cho tc dng vi dung dch AgNO
3
/NH
3
d, un nng c x gam Ag. Gi tr ca
x l (bit hiu sut cc phn ng l 100%):
Cu 20. Cho m gam mt axit hu c n chc X tc dng va vi 100 gam dung dch cha hn hp Na
2
CO
3

5,3% v NaOH 0,8%. Sau phn ng thu c dung dch ch cha mt mui Y nng 7,9%. Gi tr ca m l:
A. 5,3. B. 5,52. C. 7,20. D. 2,76.
263 | G S T T G R O U P
Cu 21: X, Y l 2 nguyn t kim loi thuc cng mt nhm A trong bng tun hon. Bit ZX < ZY v ZX + ZY = 32. Kt lun
no sau y l ng i vi X, Y ?
A. Tnh kim loi ca X > Y. B. X, Y u c 2 electron lp ngoi cng.
C. Nng lng ion ha I1 ca X < Y. D. Bn knh nguyn t ca X > Y.
Cu 22: Cho R l mt nguyn t m cc nguyn t c phn lp ngoi cng l np
2n+1
, trong n l s th t ca lp.
C cc nhn nh sau v R:
1. Tng s ht mang in cu R l 18
2. S e lp ngoi cng trong nguyn t R l 7
3. Cng thc oxit cao nht to ra t R l R2O7
4. NaR tc dng vi dd AgNO3 to kt ta.
S nhn xt ng l:
A. 1 B. 4 C. 2 D. 3
Cu 23: Cho phn ng sau: Cr2S3 + Mn(NO3)2 + K2CO3 K2CrO4 + K2SO4 + K2MnO4 + NO + CO2
Sau khi cn bng phng trnh ha hc trn, tng h s nguyn ti gin ca cc cht phn ng l
A. 116. B. 36. C. 106. D. 16.
Cu 24: Cho 11,5 gam hn hp gm Al, Cu v Mg c s mol bng nhau tc dng va vi dd cha a mol HNO3
thu c dd X v 2,688 lt (ktc) hn hp gm 3 kh N2, N2O, NO2 (trong s mol N2 bng s mol N2O) lm bay
hi nc ca dd X th thu c 55,9 gam mui khan. Gi tr ca a l:
A. 0,468 B. 0,880 C. 0,648 D. 0,905
Cu 25. Tin hnh cc th nghim sau:
(a) Cho dung dch Ba(OH)2 vo dung dch NaHCO3.
(b) Cho dung dch Al2(SO4)3 ti d vo dung dch NaAlO2 (hoc dung dch Na[Al(OH)4].
(c) Sc kh CH3NH2 ti d vo dung dch FeCl3.
(d) Sc kh propilen vo dung dch KMnO4.
(e) Sc kh CO2 vo dung dch Na2SiO3.
(g) Sc kh H2S vo dung dch SO2.
(h) Sc kh NH3 ti d vo dung dch AgNO3.
Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta?
A. 3 B. 4 C. 5 D. 6
Cu 26: Nung nng hn hp gm 0,5 mol N2 v 1,5 mol H2 trong bnh kn (xc tc) ri a v t
o
C th thy p sut
l p1. Sau cho mt lng d dd H2SO4 c vo bnh (nhit l t
o
C) th p sut l p2 (p1=1,75p2). Hiu sut tng
hp NH3 l:
A. 40% B. 60% C. 50% D. 70%.
Cu 27: C 5 mu kim loi: Ba, Mg, Fe, Ag, Al. Nu ch dng dung dch H2SO4 long c th nhn bit c nhng
kim loi no?
A. Ba v Ag B. C 5 kim loi C. Ba, Ag v Al D. Ba, Ag, Fe
Cu 28: X l dung dch cha a mol Na2CO3, Y l dung dch cha b mol H2SO4. Khi cho t t X vo Y hoc ngc li
u thu c th tch khi nh nhau (trong cng iu kin). Mi tng quan gia a v b l
A. 2a<b B. a>2b C. a<b D. 2a>b
Cu 29: Hn hp X gm Al, Fe2O3 c khi lng 21,67 gam. Tin hnh phn ng nhit nhm hn hp X trong iu
kin khng c khng kh. Ha tan hon ton hn hp cht rn sau phn ng bng dung dch NaOH d thu c
2,016 lt H2 (ktc) v 12,4 gam cht rn khng tan. Hiu sut ca phn ng nhit nhm l:
A. 80%. B. 75%. C. 60%. D. 71,43%.
Cu 30: Qu trnh sn xut amoniac trong cng nghip da trn phn ng thun nghch sau:
N2(k) + 3H2(k) 2NH3(k). H = -92 kJ
thun to ra nhiu amoniac:
(1) Tng nhit . (3) Thm cht xc tc. (5) Ly NH3 ra khi h
264 | L O V E B O O K . V N
(2) Tng p sut. (4) Gim nhit .
A. (2), (3), (4), (5). B. (1), (2), (3), (5). C. (2), (4), (5). D. (2), (3), (5).
Cu 31: Dy gm cc kim loi u tc dng vi nc nhit thng to ra cc mi trng kim l:
A. Li, K, Ca. B. Zn, Na, Ba. C. Fe, K, Ba. D. Be, Na, Ca.
Cu 32: Hai cc ng dd HCl t trn 2 a cn A, B. Cn trng thi cn bng. Cho 5 gam CaCO3 vo cc A v 4,784
gam M2CO3 (M l kim loi kim) vo cc B. Sau khi2 mui tan hon ton, cn tr li v tr cn bng. Xc nh
kim loi M.
A. Kali B. Cexi C. Liti D. Natri
Cu 33: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na2O v Al2O3; Cu v FeCl3; BaCl2
v CuSO4; Ba v NaHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l:
A. 4. B. 1. C. 3. D. 2
Cu 34:Sc 4,48 lt kh CO2
(ktc) vo 2 ltdungdch hn hp Ba(OH)2
2x mol/lv NaOH x mol/l. Sau khi cc phn
ng xy ra hon ton thu c 19,7 gam kt ta. Gi tr ca x l:
A.0,025 hoc 0,03. B. 0,03. C. 0,025. D. 0,025 hoc 0,02.
Cu 35: in phn 150 ml dung dch AgNO
3
1M vi in cc tr trong t gi, cng dng in khng i1,34
A (hiu sut qu trnh in phn l 100%), thu c cht rnX, dung dch Y v kh Z. Cho 13 gam Fe vo Y, sau
khi cc phn ng kt thc thu c14,9 gam hn hp kim loi v kh NO(sn phm kh duy nht ca N
+5
). Gi
tr ca t l:
A.1,0. B. 3,0. C. 2,0. D. 1,5.
Cu 36: Cho hn hp bt Al, Fe vo dung dch cha Cu(NO
3
)
2
v AgNO
3
. Sau khi cc phn ng xy ra hon ton,
thu c hn hp rn gm ba kim loi l:
A. Al, Fe, Ag. B. Fe,Cu, Ag. C. Al, Fe, Cu. D. Al, Cu, Ag.
Cu 37: Ly 10,7 gam mui MCl tc dng hon ton vi 250ml dung dch AgNO3 1M th thu c dung dch A v
28,7 gam kt ta. C cn A thu c hn hp mui X. Nhit phn hon ton X th thu c m gam cht rn. Xc
nh m?
Cu 38. Cho cc tinh th sau: nc , nc kh, than ch, mui n, silic, iot, photpho trng, ng knh, glyxin,
st, thch anh, lu hunh t phng, axit photphoric. S tinh th thuc loi tinh th nguyn t v thuc loi tinh
th phn t ln lt l:
A. 2 v 9 B. 4 v 6 C. 3 v 7 D. 3 v 9
Cu 39. C hai thanh kim loi Zn v Cu ni vi nhau bng dy dn, v cng nhng vo dung dch H2SO4 long thy
c hin tng sau: bt kh thot ra chm thanh Zn nhng li thot ra rt nhanh thanh Cu. Vy kt lun no sau
y v th nghim trn l ng?
A. Zn va b n mn ha hc, va b n mn in ha hc, nhng tc n mn in ha hc nh hn
B. Zn ch b n mn in ha hc vi tc ln, Cu khng b n mn
C. Zn b n mn ha hc, Cu b n mn in ha hc, tc n mn in ha hc ln hn
D. Zn va b n mn ha hc, va b n mn in ha hc, nhng tc n mn in ha hc ln hn
Cu 40. 30
o
C, phn ng: aA + bB cC + dD, kt thc sau 40 pht. Bit rng, c tng nhit ln 10
o
C th tc
phn ng tng ln 2 ln. Nu thc hin phn ng 60
o
C th phn ng trn kt thc sau:
A. 5 pht B. 10 pht C. 30 pht D. 20 pht
Cu 41: Cho m gam bt Cu vo 200ml dung dch AgNO
3
0,2M, sau phn ng thu c 3,88 gam cht rn X v dung
dch Y. Cho 2,925 gam bt Zn vo dung dch Y sau phn ng thu c 5,265 gam cht rn Z v dung dch ch cha
mt mui duy nht. Gi tr ca m l:
A. 3,17 B. 2,56 C. 1,92 D. 3,2
Cu 42: Thc hin phn ng este ha gia 1 mol CH
3
COOH v 2 mol C
2
H
5
OH. Sau phn ng thu c 0,5 mol este.
Cng vi 1 mol CH
3
COOH trong iu kin phn ng nh trn, mun thu c 0,75 mol este sau phn ng th cn
dng bao nhiu mol ancol ban u?
A. 6,5 B. 7,5 C. 8,5 D. 9,5
265 | G S T T G R O U P
Cu 43: Xc nh cht X trong phn ng sau:
NaNO
2
+K
2
Cr
2
O
7
+X NaNO
3
+Cr
2
(SO
4
)
3
+K
2
SO
4
+H
2
O
A. Na
2
SO
4
B. H
2
SO
4
C. K
2
SO
4
D. KOH
A. Tt c cc nguyn t trong phn t benzen u nm trong cng mt mt phng.
B. Benzen l mt cht kh trong iu kin thng v c mi thm.
C. Toluen lm mt mu dung dch thuc tm nhanh hn benzen.
D. Benzen khng tan trong nc v nh hn nc.
Cu 45: un hp cht hu c X (C
5
H
10
O
2
) vi dung dch NaOH d thu c mui A v ancol B. Nung A vi NaOH
rn thu c hidrocacbon C c t khi so vi hidro bng 15. Hp cht hu c B khi b oxi ha bi CuO un nng
thu c sn phm D c phn ng vi Cu(OH)
2
/OH
to kt ta gch. Cng thc cu to ca X l:

A. CH
3
COOCH(CH
3
)
2
B. CH
3
CH
2
COOCH
2
CH
3

C. CH
3
CH
2
COOCH = CH
2
D. CH
2
= CHCOOCH
2
CH
3

+ MnO
2
tc dng vi dung dch HCl c
+ Nhit phn KClO
3

+ Nung hn hp CH
3
COONa vi NaOH/CaO
+ Nhit phn NaNO
3

+ Ha tan FeS trong dung dch HCl.
S th nghim to ra sn phm gy nhim mi trng l:
A. 2 B. 3 C. 4 D. 5
Cu 47: Nhn xt no sau y khng ng?
A. Nh dung dch iot vo h tinh bt thy c mu xanh, un si ln thy mt mu, ngui li xut hin mu
xanh.
B. Trong ht cy ci thng cha nhiu tinh bt.
C. Trng ung c mi sc ca SO
2
.
D. Nh dung dch iot vo mt lt chui xanh thy ming chui chuyn t mu trng sang mu xanh nhng nu
nh vo lt chui chn th khng c hin tng .
Cu 48: Hp cht hu c X cha cc nguyn t C, H, O, N trong N chim 15,73% v khi lng. Cht X tc dng
c vi NaOH v HCl u theo t l 1 : 1 v s mol. Cht X c sn trong thin nhin v tn ti trng thi rn.
Cng thc cu to ca X c th l:
A. CH
3
CH(NH
2
)COOH B. CH
2
= CHCOONH
4

C. HCOOCH
2
CH
2
NH
2
D. H
2
NCH
2
CH
2
COOH
Cu 49: Cn ly bao nhiu gam tinh th CuSO
4
. 5H
2
O v bao nhiu gam dung dch CuSO
4
8% iu ch c 280
gam dung dch CuSO
4
16%?
A. 120 gam CuSO
4
. 5H
2
O v 440 gam dung dch CuSO
4
8%.
B. 30 gam CuSO
4
. 5H
2
4
8%.
C. 80 gam CuSO
4
. 5H
2
4
8%.
D. 40 gam CuSO
4
. 5H
2
4
8%.
Cu 50: Ha tan hon ton 5 gam hn hp X gm 2 mui khan FeSO
4
v Fe
2
(SO
4
)
3
vo nc. Dung dch thu c
tc dng va vi 0,79 gam KMnO
4
trong mi trng H
2
SO
4
. Phn trm khi lng ca Fe
2
(SO
3
)
3
trong hn
hp ban u l:
A. 76,0% B. 15,2% C. 84,4% D. 24,0%

P N

1D 2A 3C 4C 5C 6A 7D 8B 9B 10A
11D 12B 13C 14A 15B 16D 17B 18C 19C 20B
266 | L O V E B O O K . V N
21B 22C 23B 24D 25D 26B 27B 28C 29B 30C
31A 32D 33B 34B 35C 36B 37A 38B 39D 40A
41D 42B 43B 44A 45B 46B 47C 48A 49D 50D

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40 de Phien Ban 2014

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GSTT GROUP

(phng trnh th hai).

(phng trnh th nht).

COOH + HCl ClH

. Cho V lit dung dch NaOH 1M,

l 0,24. Cho dung dch X tc

c im chung l c cng s electron.

= 49,875 thu c 21,9375 gam hn hp X

c im chung l c cng s electron.

tng ln nhng kt ta tng nh hn t l y.

d v ha tan mt phn kt ta.

Fe(NO3)3 + NaOb + H2O.

; C3H6; N2O; N2O5; H2O2; NO

; Cl2; H3PO4; C2H5OH; CO2. S phn t v

< 2,5 66,7 < M

= 5,8. Dn A (ktc) qua bt Ni nung nng cho n khi cc phn ng

Dung dch (II): Na

; Dung dch (IV): Na

; Dung dch (VI): Fe

. in li ca axit s tng khi no?

> 29 g/mol. B. p = 2 atm, M

= 44,5. t chy hon ton 8,9 gam A thu c

(14n +2)x +14my = 80

). Bit ti le mol cu a 2 ion Ca

. Khi thm V lt dung dch Ca(OH)

. Biu thc lin h gia x v y l:

. Cho V lt dung dch NaOH 1M vo

= 23,385. Nung bnh mt

. Thm dn V lt dung dch

G (amoni acrylat). Cc cht (X) v (Z) c th l nhng

bng 1,5 ln s mol SO

C-COOH phn ng ht vi dung dch AgNO3/

). Cho 350ml dung dch

= 23,2. Cng thc no ca A khng ng?

. Chia X thnh hai phn bng nhau:

to kt ta gch. Cng thc cu to ca X l:

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