TNG HP CC CHUYN LUYN THI I HC

MN HA HC NM HC 201 3 -201 4
1. Chuyn 1: cu to nguyn t v bng HTTH
2. Chuyn 2: S in ly
. Chuyn : t!ng h"# h$% h&c v' c(
). Chuyn ): *i to+n C,
2
t+c -.ng v/i -- 0i1
2. Chuyn 2: T!ng h"# hi3oc%cbon
4. Chuyn 4: bi t5# v %ncol6 %nhit6 78ton
9. Chuyn 9: bi t5# 8:t86 %7itc%cbo7ylic6 li#it
;. Chuyn ;: bi t5# v %1in6 %1ino%7it
G! LI N L"NG
<=*: htt#:>>viol8t.vn>v%nlongh%n%1
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
Chuyn ?1: cu to nguyn t v bng htth
C01 1. Tng s ht proton, ntron, electron trong hai nguyn t kim loi A v B l !", trong #$ tng s ht
mang #i%n nhi&u hn tng s ht kh'ng mang #i%n l !". ( ht mang #i%n c)a nguyn t B nhi&u hn c)a A l
". *+c #,nh hai kim loi A, B
C01 2. -ho hai nguyn t *, . c$ tng s ht l /0, trong #$ tng s ht mang #i%n l1n hn tng s ht kh'ng
mang #i%n l "!. ( ht mang #i%n c)a . l1n hn s ht mang #i%n c)a * l 2. *+c #,nh #i%n t3ch ht nh4n c)a
*, ..
C01 3. 5h4n t *. c$ tng s ht l !"6 ph4n t *." c$ tng s ht 00. 78y 9+c #,nh s khi c)a . :i;t r<ng
trong nguyn t ., s ht proton :<ng s ht ntron.
C01 4. =>t h?p ch@t ion A to tA ion =
"B
v *
"C
. Tng s ht trong ph4n t A l 0D. ( ht mang #i%n nhi&u hn
s ht kh'ng mang #i%n l "D ht. ( ht mang #i%n c)a ion *
"C
3t hn c)a ion =
"B
l ! ht. 78y cho :i;t trong
ion =
"B
c$ :ao nhiu ht mang #i%n E
C01 2. T3nh thnh phFn phFn G v& s lH?ng c+c #Ing v, c)a cac:on. Bi;t cac:on trong tJ nhin tIn ti hai #Ing
v, :&n l
"
- v
K
- v khi lH?ng nguyn t trung :Lnh c)a cac:on l ",D
C01 3. Mhi lH?ng nguyn t trung :Lnh c)a Ag l D/,2/, trong tJ nhin :c c$ hai #Ing v,, trong #$ #Ing v,
DN
Ag chi;m hm lH?ng !!G v& s lH?ng. *+c #,nh s khi c)a #Ing v, cOn li.
C01 4. PIng trong tJ nhin gIm c$ hai #Ing v, l
0K
-u v
0Q
-u. Mhi lH?ng nguyn t trung :Lnh c)a #Ing l
0K,Q!. aR T3nh phFn trSm hm lH?ng c)a #Ing v,
0K
-u.
:R T3nh s nguyn t
0Q
-u c$ trong m>t thanh -u nTng 0,KQ! gam.
cR T3nh phFn trSm khi lH?ng c)a
0K
-u trong -uUV7R".
C01 5. 7o tan !,2! gam =g kim loi :<ng Wung W,ch 7-l WH th@y tho+t ra D,! gam kh3 hi#ro.
aR *+c khi lH?ng nguyn t trung :Lnh c)a =g.
:R Mim loi =g cho X trn :ao gIm hai #Ing v, trong #$ c$ #Ing v,
"!
=g. *+c #,nh s khi c)a #Ing v, cOn li
:i;t tY s v& s lH?ng c)a hai loi #Ing v, l !Z.
C01 67 UAC"DD2R [guyn t c)a nguyn t * c$ tng s ht electron trong c+c ph4n l1p p l /. ( ht mang
#i%n c)a m>t nguyn t . nhi&u hn s ht mang #i%n c)a m>t nguyn t * l 2 ht. -+c nguyn t *
v . lFn lH?t l U:i;t s hi%u nguyn t c)a nguyn tZ [a \ 6 Al \ K6 5 \ Q6 -l \ /6 ]e \ "0R
A. Al v -l. B. Al v 5. -. [a v -l. ^. ]e v -l.
C01 10. UBC"DDR =>t ion =
KB
c$ tng s ht proton, ntron, electron l /N, trong #$ s ht mang #i%n nhi&u
hn s ht kh'ng mang #i%n l N. -@u hLnh electron c)a nguyn t = l
A. _Ar`KW
Q
!s

. B. _Ar`KW
0
!s
"
. -. _Ar`KW
0
!s

. ^. _Ar`KW
K
!s
"
.
CHUYN 2! 89 IN LY
1. UP7 BC"DD2R -ho W8y c+c ch@tZ MAlU(V!R"."7"V, -"7QV7, -"7""V UsaccaroaR, -7K-VV7, -aUV7R",
-7K-VV[7!. ( ch@t #i%n li l
A. K B. ! -. Q ^. "
2. UP7 BC"DD2R Tr>n DDml Wung W,ch c$ p7\ gIm 7-l v 7[VK v1i DDml Wung W,ch [aV7 nIng #> a
UmolblR thu #H?c "DDml Wung W,ch c$ p7\". ci+ tr, c)a a l U:i;t trong mdi Wung W,ch _7
B
`_V7
C
`\D
C!
R
A. D,Q B. D,KD -. D,DK ^. D,"
3. UP7 BC"DD2R -ho D,mol 5"VQ vo Wung W,ch chea D,KQ mol MV7. ^ung W,ch thu #H?c c$ c+c ch@tZ
A. MK5V!, M"75V! B. M"75V!, M7"5V! -. MK5V!, MV7 ^. 7K5V!,
M7"5V!
47 UP7 BC"DD2R Tr>n lfn g ml Wung W,ch [aV7 D,D= v1i g ml Wung W,ch 7-l D,DK= #H?c "g ml Wung W,ch
.. ^ung W,ch . c$ p7 l
A. ! B. K -. " ^.
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
27 UP7 AC"DDNR [ung 0,Q2 gam -uU[VKR" trong :Lnh k3n kh'ng chea kh'ng kh3, sau m>t thli gian thu #H?c
!,N0 gam ch@t rjn v hmn h?p kh3 *. 7@p thn hon ton * vo nH1c #o #H?c KDDml Wung W,ch .. ^ung W,ch .
c$ p7 :<ng
A. B. ! -. K ^. "
3. UP7 AC"DDNR ^8y gIm c+c ch@t #&u t+c Wnng v1i Wung W,ch 7-l lo8ng lZ
A. M[VK, -a-VK, ]eUV7RKB. =gU7-VKR", 7-VV[a, -uV
-. ]e(, Ba(V!, MV7 ^. Ag[VK, U[7!R"-VK, -u(
4. UP7 AC"DDNR ^ung W,ch * chea hmn h?p gIm [a"-VK ,Q= v M7-VK =. [hp tA tA tAng gidt cho #;n h;t
"DDml Wung W,ch 7-l = vo DDml Wung W,ch *, sinh ra g lit kh3 U#ktcR. ci+ tr, c)a g l
A. K,K0 B. ," -. !,!2 ^. ","!
5. UP7 AC"DDNR -$ nSm Wung W,ch #Jng ring :i%t trong nSm ng nghi%mZ U[7!R"(V!, ]e-l", -rU[VKRK, M"-VK,
AlU[VKRK. -ho Wung W,ch BaUV7R" #;n WH vo nSm Wung W,ch trn. (au khi phqn eng k;t thrc, s ng nghi%m c$
k;t t)a l
A. K B. Q -. " ^. !
6. UP7 BC"DDNR Tr>n DDml Wung W,ch hmn h?p gIm 7"(V! D,DQ= v 7-l D,= v1i DDml Wung W,ch hmn h?p
gIm [aV7 D,"= v BaUV7R" D,=, thu #H?c Wung W,ch *. ^ung W,ch * c$ p7 l
A. K,D B. ," -. ,D ^. ",2
10. UP7 BC"DDNR -ho c+c phqn eng h$a hdc sauZ
UR U[7!R"(V! B Ba-l" U"R -u(V! B BaU[VKR"
UKR [a"(V! B Ba-l" U!R 7"(V! B Ba(VK
UQR U[7!R"(V! B BaUV7R" U0R ]e"U(V!RK B BaU[VKR"
-+c phqn eng #&u c$ csng phHng trLnh ion rrt gdn lZ
A. UR, U"R, UKR, U0R B. UR, UKR, UQR, U0R -. U"R, UKR, U!R, U0R ^. UKR, U!R, UQR,
U0R
11. UP7 BC"DDNR -ho Wung W,ch * chea hmn h?p gIm -7K-VV7 D,= v -7K-VV[a D,=. Bi;t X "Q
D
-, Ma
c)a -7K-VV7 l ,/Q.D
CQ
v :p tua sJ ph4n li c)a nH1c. ci+ tr, p7 c)a Wung W,ch * X "Q
D
- l
A. ,DD B. !,"! -. ",22 ^. !,/0
12. UP7 AC"DDR ^ung W,ch * cheaZ D,D/ mol [a
B
6 D,D" mol (V!
"u
v 9 mol V7
C
. ^ung W,ch . c$ chea -lV!
C
,
[VK
C
v y mol 7
B
6 tng s mol -lV!
C
v [VK
C
l D,D!. Tr>n * v . #H?c DDml Wung W,ch v. ^ung W,ch v c$ p7
U:p tua sJ #i%n li c)a nH1cR l
A. " B. " -. K ^.
13. UP7 AC"DDR [hp tA tA tAng gidt #;n h;t KDml Wung W,ch 7-l = vo DDml Wung W,ch chea [a"-VK D,"=
v [a7-VK D,"=, sau phqn eng thu #H?c s mol -V" l
A. D,DQ B. D,D"D -. D,DD ^. D,DKD
14. UP7 AC"DDR -ho Wung W,ch * gImZ D,DD/ mol [a
B
6 D,DDK mol -a
"B
6 D,DD0 mol -l
C
6 D,DD0 mol 7-VK
C
v
D,DD mol [VK
C
. Po loi :p h;t -a
"B
trong * cFn m>t lH?ng vAa #) Wung W,ch chea aUgR -aUV7R". ci+ tr, c)a a l
A. D,!!! B. D,""" -. D,2D ^. D,"D
12. UP7 BC"DD/R Trong c+c Wung W,chZ 7[VK, [a-l, [a"(V!, -aUV7R", M7(V!, =gU[VKR". ^8y gIm c+c ch@t
#&u t+c Wnng #H?c v1i Wung W,ch BaU7-VKR" l
A. 7[VK, -aUV7R", M7(V!, =gU[VKR" B. 7[VK, -aUV7R", M7(V!, [a"(V!
-. [a-l, [a"(V!, -aUV7R" ^. 7[VK, [a-l, [a"(V!
13. UP7 BC"DD/R -ho :n phqn engZ
UR ]e B "7-l ]e-l" B 7"
U"R "[aV7 B U[7!R"(V! [a"(V! B "[7K B "7"V
UKR Ba-l" B [a"-VK Ba-VK B "[a-l
U!R "[7K B "7"V B ]e(V! ]eUV7R" B U[7!R"(V!
( phqn eng thu>c loi phqn eng a9itC:aa l
A. UR, U"R B. U"R, UKR -. U"R, U!R ^. UKR, U!R
14. UP7 AC"DD/R ^ung W,ch 7-l v Wung W,ch -7K-VV7 c$ csng nIng #> molbl, p7 c)a hai Wung W,ch tHng
eng l 9 v y. wuan h% gixa 9 v y l Ugiq thi;t, ce DD ph4n t -7K-VV7 thL c$ ph4n t #i%n liR
A. y \ DD9 B. y \ 9C" -. y \ "9 ^. y \ 9B"
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
15. UP7 AC"DD/R -ho W8y c+c ch@tZ -aU7-VKR", [7!-l, U[7!R"-VK, vn(V!, AlUV7RK, vnUV7R". ( ch@t trong
W8y c$ t3nh ch@t lHyng t3nh l
A. Q B. ! -. K ^. "
Chuyn ?: T !ng h"# v 0i1 loi6 #hi 0i1 6 h$% h&c v'
c(
C01 1. 7mn h?p * gIm Al, ]e9Vy. Ti;n hnh phqn eng nhi%t nh'm hon ton m gam hmn h?p * trong #i&u ki%n
kh'ng c$ kh'ng kh3 thu #H?c hmn h?p .. -hia . thnh " phFn.
5hFn cho t+c Wnng v1i Wung W,ch [aV7 WH thu #H?c ,DD2 l3t 7" U#ktcR v cOn li Q,D!g ch@t rjn kh'ng tan.
5hFn " c$ khi lH?ng "N,/Ngam, cho t+c Wnng v1i Wung W,ch 7[VK lo8ng WH thu #H?c 2,D0! l3t [V U#ktc, l sqn
phzm kh Wuy nh@tR. ci+ tr, c)a m v c'ng thec c)a o9it sjt lZ
A. KN,/" gam v ]eV B. KN,/" gam v ]eKV!
-. K2,N gam v ]eV ^. K0,!2 gam v ]eKV!
C01 27 7Oa tan h;t m gam Al trong Wung W,ch hmn h?p [aV7, [a[VK thu #H?c 0,D!2 l3t U#ktcR hmn h?p kh3
gIm [7K v 7" c$ tk l% mol tHng eng l !ZQ. ci+ tr, c)a m lZ
A. ,K! gam B. ",N0 gam -. D,2 gam ^. K,Q gam
C01 37 Po hOa tan m>t mzu vn trong Wung W,ch 7-l X "Q
D
- cFn "!K phrt. -{ng mzu vn #$ tan h;t trong Wung W,ch
7-l nhH trn X 0Q
D
- cFn K phrt. Po hOa tan h;t mzu vn #$ trong Wung W,ch 7-l c$ nIng #> nhH trn X !Q
D
- cFn thli
gian :ao l4uZ
A. N phrt B. 2 phrt -. "/ phrt ^. 2 phrt
C01 47 Tr>n Wung W,ch chea Ba
"B
6 [a
B
Z D,D! mol6 V7
C
Z D," mol6 v1i Wung W,ch chea M
B
6 7-VK
C
Z D,D0 mol6 -VK
"C
Z
D,DQ mol thu #H?c m gam k;t t)a. ci+ tr, c)a m lZ
A. Q,/0 gam B. K,N/ gam -. N,/ gam ^. ",0/ gam
C01 27 7Oa tan Q!,!! gam hmn h?p * gIm 5-lK v 5BrK vo nH1c #H?c Wung W,ch .. Po trung hOa hon ton
Wung W,ch . cFn QDD ml Wung W,ch MV7 ",0=. G khi lH?ng c)a 5-lK trong * lZ
A. "0,N0G B. ","Q -. 2,D2G ^. KD,KG
C01 37 [hi%t ph4n QD,Q0 gam M=nV! sau m>t thli gian thu #H?c !0,/" gam ch@t rjn. -ho ton :> lH?ng kh3
sinh ra phqn eng h;t v1i hmn h?p * gIm =g, ]e thu #H?c hmn h?p . nTng K,D! gam. 7Oa tan hon ton hmn
h?p . trong Wung W,ch 7"(V! #Tc, n$ng WH thu #H?c ,K!! l3t (V" U#ktcR. G khi lH?ng =g trong * lZ
A. Q",/G B. KN,KG -. "2,QG ^. !0,QG
C01 47 -ho "DD ml Wung W,ch MV7 D,N=6 BaUV7R" D,"= vo DD ml Wung W,ch 7"(V! D,K= v Al"U(V!RK D,K=.
(au khi c+c phqn eng 9qy ra hon ton, khi lH?ng k;t t)a thu #H?c lZ
A. N,K" gam B. D,22 gam -. ! gam ^. ",!! gam
C01 5. 7Oa tan hon ton hmn h?p gIm D,2 mol ]e(" v a mol -u"( :<ng Wung W,ch 7[VK vAa #) thu #H?c
Wung W,ch * chk chea mui sun|at v g l3t [V U#ktcR l sqn phzm kh Wuy nh@t. ci+ tr, c)a g lZ
A. !!,2 l3t B. "",! l3t -. "0,22 l3t ^. KK,0 l3t
C01 67 ^ung W,ch * chea c+c ion Z Ba
"B
, [a
B
, 7-VK
C
, -l
C
trong #$ s mol -l
C
l D,"!. -ho } Wung W,ch * t+c
Wnng v1i Wung W,ch [aV7 WH thu #H?c N,2Qg k;t t)a. -ho } Wung W,ch * t+c Wnng v1i Wung W,ch BaUV7R" WH
thu #H?c Q,/0g k;t t)a. [;u #un s'i Wung W,ch * #;n cn thL thu #H?c m gam ch@t rjn khan. ci+ tr, c)a m l Z
A. Q,2 B. 2,"N. -. K,0" ^. K0,Q2
C01 107 7mn h?p * gIm -u, ]e, =g. [;u cho D,22 gam * t+c Wnng v1i clo WH thL sau phqn eng thu #H?c
"2,"/Qg hmn h?p mui khan. =Tt kh+c D,!! mol * t+c Wnng v1i Wung W,ch 7-l WH thL thu #H?c Q,K/0 l3t 7"
U#ktcR. G khi lH?ng c)a -u trong * lZ
A. 0/,N"G B. Q2,2"G -. K/,"KG ^. !K,Q"G
C01 117 -ho Wung W,ch * gIm D,DN mol [a
B
6 D,DQ mol -a
"B
6 D,D2 mol -l
C
6 D, mol 7-VK
C
6 D,D mol [VK
C
. Po
loi :p h;t ion -a
"B
trong * cFn Wsng lH?ng vAa #) Wung W,ch chea a gam -aUV7R". ci+ tr, c)a a lZ
A. ",N0 B. !,!! -. /,! ^. K,/
C01 127 [ung 2,!"g hmn h?p * gIm Al, =g, ]e trong o9i sau m>t thli gian thu #H?c ,0"g hmn h?p .. 7Oa
tan hon ton . trong Wung W,ch 7[VK WH thu #H?c ,K!! l3t [V U#ktcR l sqn phzm kh Wuy nh@t. ( mol 7[VK
phqn eng lZ
A. D,Q0 mol B. D,0! mol -. D,!2 mol ^. D,/" mol
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
C01 137 * l Wung W,ch [a_AlUV7R!`. -ho tA tA #;n WH c+c Wung W,ch sau #4y vo Wung W,ch *Z Al-lK, [a7(V!,
7-l, Ba-l", kh3 -V". ( trHlng h?p thu #H?c k;t t)a sau phqn eng lZ
A. K B. ! -. " ^.
C01 14. Mh hon ton m gam o9it =9Vy cFn vAa #) D,/Q" l3t 7" U#ktcR thu #H?c "D,0g kim loi =. -ho ton
:> lH?ng kim loi ny t+c Wnng v1i Wung W,ch 7[VK lo8ng WH thu #H?c 2,D0! l3t [V U#ktcR l sqn phzm kh Wuy
nh@t. -'ng thec c)a =9Vy lZ
A. ]eV B. ]eKV! -. -r"VK ^. -u"V
C01 12. -ho /,g hmn h?p gIm kim loi ki&m * v kim loi ki&m th . t+c Wnng h;t v1i lH?ng WH Wung
W,ch 7-l lo8ng thu #H?c Q,0 l3t kh3 U#ktcR. 7ai kim loi * v . lFn lH?t lZ
A. M, -a B. ii, Be -. [a, =g ^. M, Ba
C01 137 7mn h?p * gIm V" v VK c$ tk khi so v1i 7" l 9. Po #t ch+y hon ton l3t hmn h?p . gIm -V v 7"
cFn D,! l3t hmn h?p *. Bi;t tk khi c)a . so v1i 7" :<ng /,Q v c+c tho t3ch kh3 #o X csng #i&u ki%n nhi%t #>, +p
su@t. ci+ tr, c)a 9 lZ
A. N," B. "",! -. /,0 ^. "D
C01 147 Thm tA tA /Dml Wung W,ch 7"(V! = vo DDml Wung W,ch [a"-VK = thu #H?c Wung W,ch .. -ho
BaUV7R" WH vo Wung W,ch . thL khi lH?ng k;t t)a thu #H?c lZ
A. "",""g B. ,2"g -. "2,Kg ^. 0,Kg
C01 157 -ho m gam MV7 vo " l3t Wung W,ch M7-VK a molbl thu #H?c " l3t Wung W,ch *. i@y l3t Wung W,ch *
t+c Wnng v1i Wung W,ch Ba-l" WH thu #H?c Q,/0g k;t t)a. =Tt kh+c, cho l3t Wung W,ch * vo Wung W,ch -a-l "
WH rIi #un n$ng, sau khi c+c phqn eng 9qy ra hon ton thu #H?c Dg k;t t)a. ci+ tr, c)a m v a lFn lH?t lZ
A. 2,N0g v D," = B. Q,0g v D,D! = -. !,!2g v D,D0 = ^. Q,D!g v D,D/ =
C01 16. -ho m gam :>t -u vo "DD ml Wung W,ch Ag[VK D,"=, sau phqn eng thu #H?c K,22g ch@t rjn * v Wung
W,ch .. -ho ",N"Qg :>t vn vo Wung W,ch . sau phqn eng thu #H?c Q,"0Qg ch@t rjn v v Wung W,ch chk chea mui
Wuy nh@t. ci+ tr, c)a m lZ
A. K,/ B. ",Q0 -. ,N" ^. K,"
C01 20. -ho Wung W,ch BaU7-VKR" lFn lH?t vo c+c Wung W,chZ -u(V!, [aV7, [a7(V!, M"-VK, -aUV7R",
7"(V!, 7[VK, =g-l", 7-l, -aU[VKR". ( trHlng h?p c$ phqn eng 9qy ra lZ
A. N B. 0 -. 2 ^. /
D01 217 7Oa tan hon ton KD,! gam ch@t rjn * gIm -u, -u(, -u"( v ( :<ng 7[VK WH th@y tho+t ra "D,0 l3t
kh3 [V Wuy nh@t U#ktcR v Wung W,ch .. Thm Wung W,ch BaUV7R" WH vo Wung W,ch . #H?c m gam k;t t)a.
ci+ tr, c)a m lZ
A. 2,QQ gam. B. Q,2Q gam. -. D,NQ gam. ^. "N,! gam.
C01 227 Tr>n "QD ml Wung W,ch 7-l D,D2 = v 7"(V! D,D= v1i "QD ml Wung W,ch BaUV7R" 9 =. Thu m gam
k;t t)a v QDDml Wung W,ch c$ p7 \ ". ci+ tr, c)a m v 9 lFn lH?t lZ
A. ,0Qg v D,D!= B. ,0Qg v D,D!= -. D,Q2"Qg v D,DK= ^. D,Q2"Q v D,D0=
C01 23. -ho a gam ]eKV! t+c Wnng vAa #) v1i lH?ng Wung W,ch 7[VK sao phqn eng thu #H?c Wung W,ch *.
-ho 7-l WH vo Wung W,ch * thL Wung W,ch thu #H?c hOa tan #H?c ti #a /,"2g -u. T3nh aZ
A. !,/0g B. K,/"g -. !,0!g ^. !,/0g
C01 24. -$ c+c Wung W,ch sauZ URZ M"-r"V/ B 7"(V!6 U"RZ 7"(V!#Tc6 UKRZ [a"(6 U!RZ 7-l6 UQRZ MBr6 U0RZ
]eU[VKR". Tr>n lFn lH?t c+c Wung W,ch v1i nhau tAng cTp m>t thL c$ :ao nhiu cTp c$ phqn eng 9qy ra, trong #$
:ao nhiu cTp 9qy ra phqn eng o9hC khZ
A. DC2 B. ~ 2 -. 2 ~ / ^. ~ /
C01 227 -c A #Jng D,K mol [a"-VK v D," mol [a7-VK. -c B #Jng D,! mol 7-l. P r@t tA tA cc A vo cc
B . ( mol -V" tho+t ra l gi+ tr, noE
A. D,! B. D,"Q -. D, ^. D,K
C01 23. Po m gam ph'i sjt ngoi kh'ng kh3, sau thli gian ]e :, o9i ho+ thnh hmn h?p * gIm ! ch@t rjn c$
khi lH?ng "/," gam. 7o tan vAa h;t * trong KDD ml Wung W,ch 7-l nIng #> a molbl th@y tho+t ra K,K0 l3t 7"
U#ktcR v Wung W,ch .. -ho ti;p Wung W,ch 7[VK t1i WH vo Wung W,ch . #H?c Wung W,ch v chea hmn h?p ]e-lK ,
]eU[VKRK , 7[VK WH v c$ ","! l3t [V Wuy nh@t tho+t ra U#ktcR. ci+ tr, c)a m v a lFn lH?t lZ
A. "",! gam v "= B. 0,2 gam v K= -. "",! gam v K= ^. 0,2 gam v "=
C01 247 Trong m>t cc nH1c c$ chea D,D mol [a
B
6 D,D mol Al
KB
6 D,DQ mol -a
"B
6 D,D mol =g
"B
6 D,D!Q mol
7-VK
C
6 D,D!Q mol -l
C
. Po lm m&m nH1c ceng #&u Wsng c+c c+chZ
A. Pun n$ng, [aK5V!, -aUV7R". B. [aK5V!, [a"-VK, 7-l.
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
-. [a"-VK, [aK5V!, [aV7 ^. Pun n$ng, [a"-VK, [aK5V!
C01 25. ^8y no sau #4y gIm t@t cq c+c ch@t c$ lin k;t cho nhn Uvi;t theo tuy tjc :+t tRZ
A. [a"-VK, -7K-VV[7!, (V", 7[VK, 7"(V! B. 7"-VK, 7"(V!, ["VQ, [7K, M"(
-. BaU[VKR", [7!-l, -V", 7K5V!, 7"(VK ^. 7[VK, 7"(VK, 5"VQ,-V, [a"(V!
C01 26. ^ung W,ch * chea a mol [aAlV"6 a mol [aV7 khi thm vo Wung W,ch * : mol hoTc ": mol 7-l thL
lH?ng k;t t)a #&u nhH nhau . TY s :ba c$ gi+ tr, lZ
A. B. D,0"Q -. ,0 ^. ,Q
C01 30. 7@p thn 0,/" l3t (V" U#ktcR vo "DD ml Wung W,ch MV7 =6 [aV7 D,2Q=6 Ba-l" D,!Q= sau #$ cho
ti;p KDDml Wung W,ch BaUV7R" D,= thu #H?c m gam k;t t)a, gi+ tr, c)a m lZ
A. "0,D! gam B. N,QK gam -. "2," gam ^. K,D" gam
C01 31. Pt ch+y hon ton hmn h?p gIm ]e(" v Ag"( v1i s mol :<ng nhau thu #H?c K,0N0 l3t (V" U#ktcR v
ch@t rjn B . -ho B t+c Wnng v1i Wung W,ch 7"(V! lo8ng WH, sau phqn eng hon ton th@y cOn li m gam ch@t rjn
kh'ng tan. ci+ tr, c)a m lZ
A. K,0! B. ,22 -. /,0 ^. 2,N
C01 32. -ho m gam Al vo QDDml Wung W,ch -uU[VKR" D,"=, Ag[VK D,=. (au khi phqn eng 9qy ra hon ton
thu #H?c ch@t rjn nTng UmB/,/R gam. ci+ tr, c)a m l Z
A. Q,"N B. !,D" -. ,QK ^. ,2N
C01 337 [ung n$ng m gam hmn h?p Al v ]e"VK Utrong m'i trHlng kh'ng c$ kh'ng kh3R #;n khi
phqn eng 9qy ra hon ton, thu #H?c hmn h?p rjn .. -hia . thnh hai phFn :<ng nhauZ
C 5hFn t+c Wnng v1i Wung W,ch 7"(V! lo8ng UWHR, sinh ra K,D2 l3t kh3 7" UX #ktcR6
C 5hFn " t+c Wnng v1i Wung W,ch [aV7 UWHR, sinh ra D,2! l3t kh3 7" UX #ktcR. ci+ tr, c)a m l
A. "",/Q B. ",!D. -. "N,!D. ^. "N,!K.
C01 347 ^fn tA tA g l3t kh3 -V UX #ktcR #i tua m>t ng se #Jng lH?ng WH hmn h?p rjn gIm -uV, ]e"VK UX nhi%t
#> caoR. (au khi c+c phqn eng 9qy ra hon ton, thu #H?c kh3 *. ^fn ton :> kh3 * X trn vo lH?ng WH Wung
W,ch -aUV7R" thL to thnh ! gam k;t t)a. ci+ tr, c)a g l
A. ,"D. B. D,2N0. -. D,!!2. ^. D,""!.
C01 327 Pt n$ng m>t hmn h?p gIm Al v 0 gam ]e"VK Utrong #i&u ki%n kh'ng c$ kh'ng kh3R #;n khi phqn eng
9qy ra hon ton, thu #H?c hmn h?p rjn *. -ho * t+c Wnng vAa #) v1i g ml Wung W,ch [aV7 = sinh ra K,K0 l3t
7" UX#ktcR. ci+ tr, c)a g l
A. QD. B. DD. -. "DD. ^. KDD.
C01 337 -ho luIng kh3 -V UWHR #i tua N, gam hmn h?p gIm -uV v Al"VK nung n$ng #;n khi phqn eng hon
ton, thu #H?c 2,K gam ch@t rjn. Mhi lH?ng -uV c$ trong hmn h?p :an #Fu l
A. D,2 gam. B. 2,K gam. -. ",D gam. ^. !,D gam.
C01 347 [ung n$ng m gam hmn h?p gIm Al v ]eKV! trong #i&u ki%n kh'ng c$ kh'ng kh3. (au khi phqn eng 9qy
ra hon ton, thu #H?c hmn h?p rjn *. -ho * t+c Wnng v1i Wung W,ch [aV7 UWHR thu #H?c Wung W,ch ., ch@t rjn
v v K,K0 l3t kh3 7" UX #ktcR. (nc kh3 -V" UWHR vo Wung W,ch ., thu #H?c KN gam k;t t)a. ci+ tr, c)a m l
A. !Q,0. B. !2,K. -. K0,/. ^. Q/,D.
C01 357 Mh hon ton m gam o9it =9Vy cFn vAa #) /,N" l3t kh3 -V U#ktcR, thu #H?c a gam kim loi =. 7Oa
tan h;t a gam = :<ng Wung W,ch 7"(V! #Tc n$ng UWHR, thu #H?c "D,0 l3t kh3 (V" Usqn phzm kh Wuy nh@t, X
#ktcR. V9it =9Vy l
A. -r"VK. B. ]eV. -. ]eKV!. ^. -rV
C01 36. Pi%n ph4n v1i #i%n cJc tr Wung W,ch Ag[VK trong thli gian ! phrt Q gi4y, cHlng #> WOng #i%n D,2A.
a. T3nh khi lH?ng Ag #8 #i&u ch; #H?c.
:. T3nh tho t3ch kh3 UPMT-R thu #H?c X -at't.
C01 40. Pi%n ph4n Wung W,ch -u(V! v1i #i%n cJc #Ing UPHlng k3nh mm, nhrng s4u trong Wung W,ch !cmR,
cHlng #> WOng #i%n ,"A. T3nh thli gian #o ton :> phFn anot nhrng vo Wung W,ch :i hOa tan h;t.
C01 41. Pi%n p4n "DDml Wung W,ch hmn h?p Wung W,ch gIm -u(V! D,= v =g(V! D,DQ= cho #; khi :jt #u
9u@t hi%n kh3 thL ngAng #i%n ph4n. T3nh khi lH?ng kim loi :+m vo -atot c)a :Lnh #i%n ph4n.
C01 427 -$ hai :Lnh #i%n ph4n mjc ni ti;pZ BLnh chea Wug W,ch Ag[VK, :Lnh " #Jng Wung W,ch (V!. Ti;n
hnh #i%n ph4n m>t thli gian rIi ngAng thL th@y -at't :Lnh tSng Q gam cOn -at't :Lnh " tSng ,!2 gam. TLm .
C01 43. -$ hai :Lnh #i%n ph4n mjc ni ti;pZ BLnh chea Dml Wung W,ch -u(V! D,=6 :Lnh " chea DDml Wung
W,ch [aV7 D,=. Ti;n hnh #i%n ph4n c$ mng ngSn 9p cho #;n khi X :Lnh " to ra Wung W,ch c$ p7 \ K thL
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
ngAng #i%n ph4n. ciq s tho t3ch Wung W,ch X " :Lnh kh'ng thay #i. T3nh nIng #> molbl c)a -u
"B
trong Wung
W,ch sau #i%n ph4n.
C01 447 Pi%n h4n Wung W,ch chea a mol -u(V! v : mol [aV7 UPi%n cJc tr, mng ngSn 9pR. *+c #,nh #i&u
ki%n v& mi lin tuan c)a a v : #o Wung W,nh sau #i%n ph4n lm 5henolphtalein chuyon sang mu hIng.
C01 427 -ho WOng #i%n m>t chi&u, cHlng #> kh'ng #i, tua hai :Lnh #i%n ph4n mjc ni ti;pZ BLnh chea DDml
Wung W,ch -u(V! D,D=6 :Lnh " chea DDml Wung W,ch Ag[VK D,D=. Ti;n hnh #i%n ph4n trong thli gian QDD
gi4y thL :Lnh " :jt #Fu 9u@t hi%n kh3 X -atot. T3nh tho t3ch kh3 UPMT-R 9u@t hi%n X -at't :Lnh
C01 437 [ung n$ng hmn h?p gIm D,! mol [" v ,0 mol 7" trong :Lnh k3n Uc$ 9rc t+cR rIi #Ha v& nhi%t #> t
D
-
th@y +p su@t trong :Lnh lrc ny l 5. (au #$ cho m>t lH?ng WH 7"(V! #Tc vo :Lnh Unhi%t #> lrc ny trong :Lnh
l t
D
-R #;n khi +p su@t n #,nh thL th@y +p su@t trong :Lnh lrc ny l 5" U5 \ ,/Q5"R. 7i%u su@t tng h?p [7K lZ
C01 447 7Oa tan hon ton hmn h?p * gIm D,DD" mol ]e(" v D,DDK mol ]e( vo lH?ng 7"(V! #Tc n$ng WH thu
#H?c kh3 *. 7@p thn * :<ng lH?ng vAa #) gml Wung W,ch M=nV! D,DQ=. g c$ gi+ tr, lZ
A. ""2 ml B. /" ml -. "2Dml ^. 22 ml
. QDG. B. 0Q,"QG. -. 0DG. ^. /QG.
Chuyn ?): * i t5# C,
2
t +c -.ng v/i -- 0i1
C01 17 7@p thn hon ton ","! l3t -V" U#ktcR vo Wung W,ch nH1c v'i trong c$ chea D,D/Q mol -aUV7R". (qn
phzm thu #H?c sau phqn eng gImZ
A. -hk c$ -a-VK B. -hk c$ -aU7-VKR"
-. -a-VK v -aU7-VKR" ^. -aU7-VKR" v -V"
C01 27 7@p thu h;t -V" vo Wung W,ch [aV7 #H?c Wung W,ch A. Bi;t r<ngZ-ho tA tA Wung W,ch 7-l vo Wung
W,ch A thL phqi m@t QDml WW 7-l = m1i th@y :jt #Fu c$ kh3 tho+t ra. =Tt kh+c cho WW BaUV7R" WH vo Wung
W,ch A #H?c /,22 gam k;t t)a. ^ung W,ch A cheaE
A. [a"-VK B. [a7-VK
-. [aV7 v [a7-VK ^. [a7-VK, [a"-VK
C01 3. ^fn Q,0 l3t -V" U#ktcR vo :Lnh chea "DDml Wung W,ch [aV7 nIng #> a =6 Wung W,ch thu #H?c c$ khq
nSng t+c Wnng ti #a DD ml Wung W,ch MV7 =. ci+ tr, c)a a lE
A. D,/Q B. ,Q -. " ^. ",Q
C01 4. UPi hdc khi A nSm "DD/R. 7@p thn hon ton ",022 l3t -V" U#ktcR vo ",Q l3t Wung W,ch BaUV7R" nIng
#> a molbl, thu #H?c Q,/0 gam k;t t)a. c3a tr, c)a a lE
A. D,DK" B. D,D!2 -. D,D0 ^. D,D!
C01 27 7@p thn ton :> D,2N0 l3t -V" vo K l3t WW -aUV7R" D,D= #H?cE
A. g k;t t)a B. "g k;t t)a
-. Kg k;t t)a ^. !g k;t t)a
C01 3. 7@p thn D,""!l3t -V" U#ktcR vo " l3t -aUV7R" D,D= ta thu #H?c m gam k;t t)a. c3a tr, c)a m lE
A. g B. ,Qg -. "g ^. ",Qg
C01 47 UPi hdc khi BC"DD/R. [ung K,! gam " mui cac:onat c)a " kim loi h$a tr, , #H?c 0,2 gam rjn v
kh3 *. kh3 * sinh ra cho h@p thn vo /Q ml Wung W,ch [aV7 =, khi lH?ng mui khan sau phqn eng lE
A. Q,2gam B. 0,Qgam -. !,"gam ^. 0,Kg
C01 57 Thi -V" vo WW chea D,D" mol BaUV7R". ci+ tr, khi lH?ng k;t t)a :i;n thin trong khoqng no khi -V"
:i;n thin trong khoqng tA D,DDQ mol #;n D,D"! molE
A. D gam #;n K,N!g B. D,N2Q gam #;n K,N!g
-. D gam #;n D,N2Qg ^. D,N2Qg #;n K,"Qg
C01 67 (nc ","! l3t U#ktcR -V" vo DDml hmn h?p Wung W,ch gIm MV7 = v BaUV7R" D,/Q=. (au khi kh3 :,
h@p thn hon ton th@y to m g k;t t)a. T3nh m
A. N,/g B. !,//Qg -. "K,0!g ^. 0,/!Qg
C01 107 (nc !,!2 l3t U#ktcR -V" vo DDml hmn h?p Wung W,ch gIm MV7 = v BaUV7R" D,/Q=. (au khi kh3 :,
h@p thn hon ton th@y to m g k;t t)a. T3nh m
A. "K,0!g B. !,//Qg -. N,2Qg ^. 0,/!Qg
C01 11. 7@p thn K,K0 l3t (V" U#ktcR vo D,Q l3t hmn h?p gIm [aV7 D,"= v MV7 D,"=. -' cn Wung W,ch sau
phqn eng thu #?c khi l?ng mui khan l
A. N,Qgam B. K,Qg -. ",0g ^. 2,K g
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
C01 12. -ho 0,/" lit kh3 -V" U#ktcR vo K2D ml WW [aV7 =, thu #H?c WW A. -ho DD ml WW BaUV7R" = vo
WW A #H?c m gam k;t t)a. c3a tr, m :<ngZ
A. N,/g B. Q,/0g -. QN,g ^.QQ,0g
C01 137 7@p thn h;t D,0/" l3t -V" U#ktcR vo :Lnh chea " l3t Wung W,ch -aUV7R" D,D=. Thm ti;p D,!gam
[aV7 vo :Lnh ny. Mhi lH?ng k;t t)a thu #H?c sau phqn eng lE
A. ,Qg B. "g -. ",Qg ^. Kg
C01 147 -ho D,D" mol -V" h@p thn :Xi "DD ml [aV7 D,= v -aUV7R" D,D=.Mhi lH?ng mui #H?c lE
A. ,"0gam B. "gam -. K,D0gam ^. !,N0 g
C01 12. 7@p thn !,!2 l3t -V" U#ktcR vo D,Q l3t [aV7 D,!= v MV7 D,"=. (au phqn eng #?c WW *. i@y b" *
t+c Wnng v1i BaUV7R" W, to m gam k;t t)a. m v tng khi l?ng mui khan sau c' cn * lFn l?t l
A. N,/ g v "D,0 g B. N,/gv K,0g
-. KN,!g v "D,0g ^. ,N/g v ",D0g
C01 13. 7@p thn ton :> D,K mol -V" vo Wung W,ch chea D,"Q mol -aUV7R". khi lH?ng Wung W,ch sau phqn
eng tSng hay giqm :ao nhiu gamE
A. TSng K,"gam B. TSng "Dgam
-. ciqm 0,2gam ^. ckam 0,2g
C01 14. -ho D,! mol -V" h@p thn h;t vo Wung W,ch chea D, mol -aUV7R". Ta nhn th@y khi lH?ng -a-VK
to ra l1n hn khi lH?ng -V" #8 Wsng nn khi lH?ng Wung W,ch cOn li giqm :ao nhiuE
A. ,2!g B. K,02 gam -. ",!! gam ^. D,N" gam
C01 15. -ho D,! mol -V" h@p thn h;t vo Wung W,ch chea D,D2mol -aUV7R". Ta nhn th@y khi lH?ng -a-VK
to ra nhp hn khi lH?ng -V" #8 Wsng nn khi lH?ng Wung W,ch cOn li tSng l :ao nhiuE
A. ",D2 gam B. ,D! gam -. !,0g ^. 0,!2 gam
C01 16. g l3t kh3 -V" U#ktcR vo ,Q l3t BaUV7R" D,= #H?c N,/ gam k;t t)a. c3a tr, l1n nh@t c)a g lE
A. ," B. ","! -. !,!2 ^. 0,/"
C01 20. ^fn 2,N0 lit -V" U#ktcR vo g lit WW -aUV7R" =, thu #H?c !Dg k;t t)a.c3a tr, g lZ
A.D," #;n D,K2 B. D,! -. D,! ^. \D,!
C01 21. Thi g ml U#ktcR -V" vo KDD ml WW -aUV7R" D,D"=, thu #H?c D,"g k;t t)a.c3a tr, g lZ
A. !!.2 hoTc 2N,0 B. !!,2 hoTc ""!
-. ""! ^. !!,2
C01 22. Thi g lit U#ktcR -V" vo DD ml WW -aUV7R" =, thu #H?c 0g k;t t)a. idc :p k;t t)a l@y WW #un n$ng
li c$ k;t t)a nxa. c3a tr, g lZ
A. K,K0 B. ,K!!
-. ,K!! hoTc K,K0 ^. K,K0 hoTc ,"
C01 23. ^fn g l3t -V" U#kcR vo KDDml WW -aUV7R" D,Q =. (au phqn eng #H?c Dg k;t t)a. g :<ngZ
A. ","! l3t B. K,K0 l3t -. !,!2 l3t ^. A,- #rng
C01 24. 7@p thn ton :> 9 mol -V" vo Wung W,ch chea D,DK mol -aUV7R" #H?c " gam k;t t)a. g3a tr, 9E
A. D,D" mol v D,D! mol B. D,D"mol v D,DQ mol
-. D,Dmol v D,DK mol ^. D,DKmol v D,D! mol
C01 22. Tk khi hi c)a * gIm -V" v (V" so v1i [" :<ng ".-ho D," l3t U#ktcR * tua QDDml WW BaUV7R". (au
th3 nghi%m phqi Wsng "Qml 7-l D,"= #o trung hOa BaUV7R" thAa. G mol mmi kh3 trong hmn h?p * lE
A. QD v QD B. !D v 0D
-. KD v /D ^. "D v 2D
C01 23. -ho Q,0 l3t hmn h?p * gIm [" v -V" U#ktcR #i chm tua Q l3t Wung W,ch -aUV7R" D,D"= #o phqn eng
9qy ra hon ton thu #H?c Q gam k;t t)a. T3nh tk khi hi c)a hmn h?p * so v1i 7".
A. 2,2 B. ,22 -. K/,0 ^. "
C01 24. 7@p thn h;t g l3t -V" U#ktcR vo KDD ml Wung W,ch [aV7 9 molbl #H?c D,0 gam [a"-VK v 2,! gam
[a7-VK. c3a tr, g, 9 lFn lH?t lE
A. !,!2l3t v = B. !,!2l3t v ,Q=
-. 0,/" l3t v = ^. Q,0 l3t v "=
C01 25. ('c -V" vo "DD ml hn hp Wung Wch gm MV7 = v BaUV7R" D,/Q=. (au khi kh : hp th'
hon ton thy to "K,0 g kt ta. Tnh g-V" Wng ktc
A. 2,Q" lt B. ",022 lt -. ","! lt ^. A,B #rng
C01 26. Pt ch+y hon ton D, mol etan rIi h@p thn ton :> sqn phzm ch+y vo :Lnh chea KDD ml WW [aV7
=. Mhi lH?ng mui thu #H?c sau phqn engE
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
A. 2,!g v D,0g B. 2!g v D0g
-. D,2!g v ,D0g ^. !,"g v Q,Kg
C01 30. Pt ch+y hon ton D, mol -"7Q7 rIi h@p thn ton :> sqn phzm ch+y vo :Lnh chea /Q ml WW
BaUV7R" " =. Tng khi lH?ng mui thu #H?c sau phqn eng lE UBa\K/R
A. K",0Q g B. N,/g -. ",NQg ^. KQ,/Qg
C01 317 UMhi AC"DD/R. Ba hiWrocac:on *, ., v l #Ing #ng k; ti;p trong #$ khi lH?ng ph4n t v g@p #'i
khi lH?ng ph4n t *. Pt ch+y D, mol ch@t ., sqn phzm kh3 h@p thn hon ton vo Wung W,ch -aUV7R" WH thu
#H?c s gam k;t t)a lE
A. "D B. !D -. KD ^. D
C01 32. Pt A gIm " hiWrocac:on lin ti;p. 7@p thn sqn phzm vo K l3t WW -aUV7R" D,D= #H?c k;t t)a v khi
lH?ng WW tSng ",!0g. -ho BaUV7R" vo li th@y c$ k;t t)a nxa. Tng khi lH?ng k;t t)a " lFn l 0,N!g. TLm khi
lH?ng mmi hiWrocac:on #8 WsngE
A. D,Kg v D,!!g B. Kg v !,!g
-. D,Kg v !!g ^. KDg v !!g
C01 337 Pt " rH?u metylic v etylic rIi h@p thn sqn phzm ch+y vo QDml BaUV7R" = th@y c$ k;t t)a v khi
lH?ng Wung W,ch giqm !,0g.Thm BaUV7R" WH vo c$ N,/g k;t t)a nxa. G khi lH?ng mmi rH?u lE
A. !D v 0D B. "D v 2D
-. KD,/ v 0N,K ^. Q2,2 v !,2"
C01 347 U P7 khi A nSm "DD/R. -ho m gam tinh :>t ln men thnh ancol etylic v1i 7\2G. Ton :> -V"
#H?c h@p thn vo WW -aUV7R", #H?c QQD gam k;t t)a v WW *. Pun * thu thm DD gam k;t t)a. m lE
A. QQD B. 2D -. 0QD ^. /QD
C01 327 Pt ch+y D,""Q mol rH?u #n chec A :<ng o9i vAa #). 7@p thn h;t sqn phzm ch+y vo DD ml WW
BaUV7R" ,Q= #H?c !,//Qg k;t t)a. H?u A c$ c'ng thec no WH1i #4yE
A. -7KV7 B. -"7QV7 -. -K7/V7 ^. -!7/V7
C01 337 Pt D gam ch@t A U-, 7, VR. 7@p thn sqn phzm ch+y vo 0DD ml [aV7 = th@y khi lH?ng WW tSng
"N," gam. Thm -a-l" WH vo WW spe c$ D gam k;t t)a. *+c #,nh A :i;t -T5T trsng v1i -TPc[.
A. -Q72V" B. -Q7DV" -. -Q70V! ^. -Q7"V
C01 347 Pt ",0 gam hiWrocac:on A rIi h@p thn sqn phzm vo :Lnh QDDml MV7, thm Ba-l" WH vo, sau peng
th@y N,/ gam k;t t)a. idc :p k;t t)a rIi thm BaUV7R" WH vo phFn nH1c ldc th@y N,/ gam kt)a nxa. *+c #,nh
-T5T A :i;t ND =A D.
A. -"7" B. -!7! -. -070 ^. -272
Chuyn ?2: bi t5# t!ng h"# v hi3oc%cbon
C01 1. Pt ch+y hon ton hmn h?p * gIm " hiWrocac:on mch hX csng WSy #Ing #ng h@p thn hon ton sqn
phzm vo ,2 l3t Wung W,ch -aUV7R" D,DQ= thu #H?c k;t t)a v khi lH?ng Wung W,ch tSng K,/2g. -ho BaUV7R"
WH vo Wung W,ch thu #H?c k;t t)a v tng khi lH?ng tng c>ng cq " lFn l 2,2Qg. Tk khi c)a * v1i 7" l "D.
^Sy #Ing Wng c)a hai hiWrocac:on lZ
a. Ankin :. AnkaWien c. Aren W. Ankin hoTc AnkaWien
C01 27 -ho hmn h?p kh3 * gIm " hiWrocac:on A, B mch thng v khi lH?ng ph4n t c)a A nhp hn khi
lH?ng ph4n t c)a B. Trong hmn h?p *, A chi;m /QG theo tho t3ch . Pt ch+y hon ton * cho sqn phzm ch+y
h@p thn tua :nh chea Wung W,ch BaUV7R" WH, sau th3 nghi%m khi lH?ng Wung W,ch trong :nh giqm ",/2g #Ing
thli thu #H?c N,/g k;t t)a. Bi;t tk khi hi c)a * #i v1i hiWro :<ng 2,Q v A, B csng WSy #Ing #ng.
R *+c #,nh WSy #Ing #ng c)a " hiWrocac:on
a. Ankan :. Anken c. Aren W. AnkaWien
"R Tm c'ng thec ph4n t c)a A, BE
a. -K70 v -!72 :. -"70 v -!7D
:. -!72 v -Q7D W. -"70 v -K72
C01 3. =mi hmn h?p * gIm " hiWrocac:on A, B U thu>c m>t trong K WSy #Ing #ng ankan, anken, ankinR s
nguyn t - trong mmi ph4n t nhp hn /6 A v B #H?c tr>n theo tk l% mol l Z". Pt ch+y hon ton !,2g hmn
h?p * :<ng o9i rIi thu ton :> sqn phzm lFn lH?t Wfn tua :nh chea Wung W,ch 7"(V! #Tc, WH6 :nh " chea 2NDml
Wung W,ch BaUV7R" = th khi lH?ng :nh tSng !,!g v X :nh " thu #H?c KK,N0g k;t t)a trjng.
*+c #,nh WSy #Ing #ng c)a A v B.
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
a. Ankin :. Anken c. AnkeWien W. Ankan
C01 4. Pt ch+y hon ton m>t hiWrocac:on * v1i m>t lH?ng vAa #) o9i. ^fn hmn h?p sqn phzm ch+y tua
7"(V! #m #Tc th tho t3ch kh3 giqm hn m>t na. ^Sy #Ing Wng c)a hiWrocac:on * lZ
a. Ankin :. Anken c. AnkeWien W. Ankan
C01 27 -ho " hiWrocac:on * v . #Ing #ng nhau, ph4n t khi c)a * g@p #'i ph4n t khi c)a ..
aR *+c #,nh c'ng thec tng tu+t c)a " hiWrocac:on.
a. -n7"n ~ " :. -n7"n B " :. -n7"n ~ 0 c. -n7"n
:R *+c #,nh c'ng thec ph4n t c)a * v ., :i;t r<ngZ Tk khi c)a hmn h?p #Ing tho t3ch * v . so v1i kh3 -"70
:<ng ",.
a. -K72 v -07! :. -K7! v -070
c. -K70 v -07" :. -4u - #rng
C01 3. Pt ch+y g UlitR hmn h?p kh3 * X #i&u ki%n tiu chuzn gIm " hiWrocac:on to thnh !,!g -V" v ,2g
7"V. -ho :i;t " hiWrocac:on tren csng hay kh+c WSy #Ing #ng v thu>c WSy #Ing #ng noE U -hk 9t c+c WSy
#Ing #ng #S hdc trong chHng trnhR.
a. -sng WSy #Ing #ng Anken hay csng WSy #Ing #ng 9icloankan.
:. Mh+c WSy #Ing #ngZ anken v 9icloankan.
c. Mh+c WSy #Ing #ngZ ankan v ankin U s mol :<ng nhauR
W. Mh+c WSy #Ing #ngZ ankan v ankaWien Us mol :<ng nhau R
C01 4. Pt ch+y hon ton ",2g m>t h?p ch@t hxu c * rIi cho ton :> sqn phzm h@p thn vo WW [aV7 th Wung
W,ch ny c$ khi lH?ng tSng thm ",!g, thu #H?c " mui ny c$ tk l% Z *+c #,nh WSy #Ing #ng c)a ch@t *.
a. a. Ankin :. Anken c. AnkaWien W. Ankan
C01 5. Pt ch+y hon ton ",2 ch@t hxu c * :<ng 0,/" lit V" U#ktcR chk to thnh kh3 -V" v hi nH1c c$ tho
t3ch :<ng nhau trong csng #i&u ki%n.
aR Tm WSy #Ing #ng c)a h?p ch@t hxu c *.
a. Anken :. Ankan c. AnkaWien W. M;t tuq kh+c
cR [;u cho ",2g * n$i trn vo Wung W,ch Br" WH th #H?c N,"g sqn phzm c>ng. Tm c'ng thec ph4n t.
a. -Q7D :. -!72 c. -!7D W. M;t tuq kh+c
C01 6. Pt ch+y " lit hmn h?p hai hiWrocac:on *, . X tho kh3 v csng WSy #Ing #ng, cFn D lit V" #o to thnh
0 lit -V" U c+c tho t3ch #&u X #ktcR.
aR *+c #,nh WSy #Ing #ng c)a " hiWrocac:onE
a. Ankan :. Anken c. Aren W. AnkaWien
C01 10. Pt ch+y hon ton "!,0! lit U"/,K
o
-6 atmR hmn h?p kh3 * gIm K hiWrocac:on #Ing #ng lin ti;p, thu
sqn phzm cho h@p thn h;t vo m>t :nh nH1c v'i trong WH thi khi lH?ng ton :nh tSng !N,!g v khi ldc thu
#H?c "/Dg k;t t)a trjng.
aR *+c #,nh WSy #Ing #ng c)a K hiWrocac:on
a. -n7"n ~ " :. -n7"n B " :. -n7"n ~ 0 W. -n7"n
:R *+c #,nh c'ng thec ph4n t K hiWrocac:onZ
a. -"7!, -K70 v -!72 :. -070, -/72 v -27D
:. -"70, -K72 v -!7D W. -"7", -K7! v -!70
C01 11. =>t hmn h?p gIm hai ch@t #Ing #ng ankan k; ti;p c$ kl "!,2g. Tho t3ch tHng eng l ," lit U#ktcR.
7Sy 9+c #,nh c'ng thec ph4n t c)a ankan.
a. -072 v -K72 :. -Q7" v -07!
c. -K72 v -!7D W. -4u - #rng
C01 127 -ho Q,0 lit hmn h?p hai ole|in l #Ing #ng k; ti;p nhau h?p nH1c Uc$ 9rc t+cR #H?c hmn h?p " rH?u.
-hia hmn h?p hai rH?u ny X Wng khan rIi chia lm " phFn :<ng nhau. 5hFn the nh@t phqn eng h;t v1i [a WH
thu #H?c 2!Dml kh3. Pt ch+y h;t phFn the hai rIi cho ton :> sqn phzm ch+y h@p thn vo :nh #Jng [aV7 WH
th khi lH?ng :nh [aV7 tSng K,/Qg.
-'ng thec ph4n t c)a hai ole|in lZ
a. -"70 v -K72 :. -K7! v -!70
c. -"7! v -K70 W. -!72 v -K70
C01 137 -ho 0,/" lit hmn h?p kh3 gIm " ole|in l>i tua nH1c :rom WH th@y khi lH?ng :nh tSng 0,2g. 7Sy tm
c'ng thec ph4n t c+c ole|in :i;t r<ng s nguyn t cac:on trong mmi ole|in kh'ng tu+ Q.
a. -"7! v -!72 :. -K70 v -!72
c. -Q7D v -07" W. -"7! v -!72 6 -K70 v -!72
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
C01 14. Pt ch+y Q0Dcm
K
hmn h?p kh3 U#ktcR gIm hai hiWrocac:on c$ csng s nguyn t cac:on ta thu #H?c
!,!g -V" v ,N"Qg hi nH1c. *+c #,nh c'ng thec ph4n t c+c hiWrocac:on.
a. -!72 v -!7D :. -!70 v -!7D
c. -!7! v -!7D W. -4u A, B, - chHa #) cTp #+p s
C01 127 Pt Dcm
K
m>t hiWrocac:on :<ng 2Dcm
K
o9i Ul@y WHR. (qn phzm thu #H?c sau khi cho 7"V ngHng tn cn
0Qcm
K
trong #$ "Qcm
K
l o9i. -+c tho t3ch #&u #o X #ktc. *+c #,nh c'ng thec ph4n t c)a hiWrocac:on.
a. -!7D :. -!70 c. -Q7D W. -K72
C01 137 =>t hmn h?p gIm hai hiWrocac:on mch hX. -ho 02Dml hmn h?p trn #i chm tua nH1c :rom WH.
(auk hi phqn eng hon ton c n li "Dml v lH?ng :rom tham gia phqn eng l !,Dg. =Tt kh+c n;u #t ch+y
hon ton 02Dml hmn h?p trn rIi cho ton :> sqn phzm ch+y h@p thn vo nH1c v'i trong WH th thu #H?c ",Qg
k;t t)a.
-'ng thec ph4n t c)a hai hiWrocac:on lZ
a. -!72 v -K70 :. -"70 v -7!
c. -!7D v -7! W. -K70 v -7!
C01 14. 7mn h?p kh3 A gIm hiWro, m>t para||in v hai ole|in l #Ing #ng lien ti;p. -ho Q0Dml A #i tua ng
chea :>t niken nung n$ng #H?c !!2ml hmn h?p kh3 A l>i tua :nh nH1c :rom th@y nH1c :rom nht mu m>t
phFn v khi lH?ng :nh nH1c :rom tSng thm D,K!Kg. 7mn h?p kh3 A" #i ra khpi :nh nH1c :rom chi;m tho t3ch
"N,"ml v c$ tk khi #i v1i kh'ng kh3 :<ng ,KK. ciq thi;t c+c phqn eng 9qy ra hon ton, c+c ole|in phqn
eng v1i tc #> :<ng nhau U ngha l tk l% v1i thnh phFn G tho t3ch c)a chrngR v c+c tho t3ch kh3 #o X #ktc. *+c
#,nh c'ng thec ph4n t c)a c+c hiWrocac:on.
a. -"7!6 -K70 v -Q7D :. -"706 -K70 v -!72
c. -K726 -!7D v -Q7" W. -"706 -!72 v -Q7D
C01 157 -ho D,0/" lit U#ktcR hmn h?p kh3 A gIm hai hiWrocac:on mch hX. -hia A thnh " phFn :<ng nhau. -ho
phFn tua Wung W,ch Br" WH, khi lH?ng Wung W,ch tSng *g, lH?ng Br" #S phqn eng h;t K,"g kh'ng c$ kh3 tho+t
ra khpi Wung W,ch. Pt ch+y phFn " v cho sqn phzm ch+y tua :nh Wung W,ch 5"VQ. (au #$ cho tua MV7 rjn.
(au th3 nghi%m :nh #Jng 5"VQ tSng .g v :nh #Jng MV7 tSng ,/0g. Tm c'ng thec ph4n t c)a " hiWrocac:on.
a. -"7! v -K70 :. -K70 v -!72
c. -"7! v -!70 hoTc -"7" v -K70 W. -4u - #rng
C01 167 -ho D,2N0 lit U#ktcR hmn h?p kh3 A gIm " hiWrocac:on mch hX. -hia A thnh " phFn :<ng nhauZ
5hFn Z -ho tua Wung W,ch Br" c$ thAa, lH?ng Br" nguyn ch@t phqn eng Q,0g
5hFn "Z Pt ch+y hon ton to ra ","g -V". Tm c'ng thec ph4n t " hiWrocac:on.
a. -!72 v -"7" :. -!7" v -"7!
c. -!72 v -"7" 6 -!7" v -"7! W. P+p s kh+c
C01 207 Tr>n h'n h?p * gIm hiWrocac:on B v1i 7" c$ WH W9b7" \ !,2. -ho * #i tua [i nung n$ng #;n phqn
eng hon ton #H?c hmn h?p *" c$ W*"b7" \ 2. -'ng thec ph4n t hiWrocac:on B lZ
a. -K70 :. -K7! c. -!72 W. -Q72
C01 217 Tr>n hmn h?p * gIm hiWrocac:on khi UAR v 7" v1i W*b7" \ 0,22. -ho * tua [i #un n$ng #;n khi
phqn eng hon ton thu #H?c hmn h?p . W.b7" \ K,0. *+c #,nh c'ng thec ph4n t c)a A.
a. -K7! :. -K70 c. -!70 W. -Q7"
C01 227 -ho ,Q02 lit hmn h?p kh3 * gIm " hiWrocac:on mch hX vo :nh nH1c :rom WH. (auk hi phqn eng
hon ton chk cn li !!2cm
K
kh3 tho+t ra v #S c$ 2 gam :rom phqn eng. =Tt kh+c, n;u #t ch+y hon ton lH?ng
* trn rIi Wfn ton :> sqn phzm ch+y vo :nh nH1c v'i trong th #H?c Qg k;t t)a. idc :p k;t t)a rIi #un n$ng
nH1c ldc, thu thm ti #a " gam k;t t)a nxa. U -+c tho t3ch kh3 #&u #H?c #o X #ktcR.
Tm c'ng thec c@u to " ph4n t hiWrocac:on.
a. -"7! v -!72 :. -K70 v -!72
c. -"7" v -Q7" W. -"70 v -K70
C01 237 -ho D,!" lit hmn h?p kh3 B gIm hai hiWrocac:on mch hX #i r@t chm tua :nh #Jng nH1c :rom WH.
(auk hi phqn eng hon ton th@y c$ D,"2 lit kh3 #i ra khpi :nh v c$ " gam :rom #S tham gia phqn eng. -+c tho
t3ch kh3 #o X #ktc. Tk khi hi c)a B so v1i hiWro l N. 7Sy 9+c #,nh c'ng thec ph4n t hai hiWrocac:on.
a. -"70 v -!70 :. -K72 v -"7"
c. -"70 v -!70 hoTc -K72 v -"7"
W. -K70 v -!70 hoTc -"72 v -"7"
C01 247 Pt ch+y hon ton K,"! gam hmn h?p * gIm " ch@t hxu c UAR v UBR kh+c WSy #Ing #ng, trong #$
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
UAR hn UBR m>t nguyn t cac:on,ngHli ta chk thu #H?c 7"V v N,"! gam -V". Bi;t tk khi hi c)a * #i v1i
hiWro l W9b7" \ K,Q. Tm c'ng thec ph4n t c)a UAR, UBRE
a. -"7! v -"7QV7 :. -"70 v -K72
c. -"7" v -7"V W. -K72V v -"70V
C01 227 Pt hon ton hmn h?p " hiWrocac:on *, . thu>c csng m>t WSy #Ing #ng Uankan, anken, ankinR, h@p
thu sqn phzm ch+y vo !,Q lit Wung W,ch -aUV7R" D,D"= th thu #H?c k;t t)a, khi lH?ng Wung W,ch tSng ln
K,/2g. -ho Wung W,ch BaUV7R" WH vo Wung W,ch thu #H?c k;t t)a. Tng k;t c)a " lFn nTng 2,2Qg. Bi;t r<ng s
mol * :<ng 0DG tng s mol *, . trong hmn h?p. *+c #,nh c'ng thec ph4n t c)a *, .E.
a. -"7! v -K70 :. -K7! v -Q70
c. -"70 v -K72 W. -"7" v -!70
C01 237 Pt ch+y m>t hiWrocac:on * mch hX, kh3 v1i ,N" gam kh3 o9i trong :nh k3n rIi cho c+c sqn phzm sau
phqn eng tua :nh m>t chea trong 7"(V! #Tc WH, :nh hai chea K,Q lit -aUV7R" D,D= thu #H?c Kg k;t t)a, kh3
Wuy nh@t :ay ra c$ tho t3ch D,""! lit #o X "/,K
o
- v , atm. *+c #,nh c'ng thec ph4n t c)a *, giq thi;t c+c
phqn eng 9qy ra hon ton.
a. -"7" :. -"72 c. -K72 hoTc -"7"
W. -K72 hoTc -"7" hoTc -7!
C01 247 -ho hmn h?p kh3 gIm hiWrocac:on A v o9i l@y WH, trong #$ c$ DG A theo tho t3ch vo m>t kh3 nhin
k;, to +p su@t atm X D
o
-. Bt tia la #i%n #o A ch+y hon ton rIi cho nH1c ngHng tn X D
o
- th +p su@t X trong
:nh giqm cn D,2 atm. Bi;t lH?ng o9i WH kh'ng tu+ QDG lH?ng o9i :an #Fu. 7Sy tm c'ng thec ph4n t c)a A.
a. -!72 :. -!7D c. -!7! W. -Q7"
C01 25. =>t hmn h?p gIm hai hiWrocac:on, mch hX, trong ph4n t mmi ch@t chea kh'ng tu+ m>t lien k;t :a
hay hai lien k;t #'i. ( cac:on mmi ch@t ti #a :<ng /. Pt ch+y hon ton D,DQ mol hmn h?p thu #H?c D,"Q mol
-V" v D,"K mol 7"V. Tm c'ng thec ph4n t c)a " hiWrocac:onE
a. -"7" v -/7! :. -Q72 v -Q7D
c. -Q72 v -Q7" W. P+p s A B B B -
C01 267 Pt ch+y m>t hiWrocac:on * v1i lH?ng vAa #) o9i. Ton :> sqn phzm ch+y #H?c Wfn tua :nh #Jng
can9i clorua khan c$ WH tho t3ch giqm #i hn m>t na. Bi;t r<ng * cac:on chi;m 2DG v& khi lH?ng. *+c #,nh
c'ng thec c@u to c)a *.
a. -K72 :. -"7! c. -!70 W. -"70
C01 307 Pt ch+y hai hiWrocac:on c$ csng c'ng thec tng tu+t -n7"n B " ~ "k thu #H?c sqn phzm sau khi #t ch+y
c$ khi lH?ng "",g. Mhi cho ton :> lH?ng sqn phzm ny vo !DDg Wung W,ch [aV7 th thu #H?c Wung W,ch
gIm hai mui c$ nIng #> N,DD"0G. Tk l% s mol hai mui l Z.
-ho :i;t tk l% s mol c)a chrng trong hmn h?p l Z" U theo chi&u khi lH?ng ph4n t tSng WFnR. Bi;t k K. -'ng
thec ph4n thec ph4n t c)a hai hiWrocac:on lZ
a. -"7! v -K70 :. -K72 v -!7D
c. -"7" v -K7! W. M;t tuq kh+c
C01 317 =>t hiWrocac:on * c$ c'ng thec -n7"n B " ~ "k. Mhi #t * ta #H?c tk l% s mol c)a -V" v 7"V :Sng " U k3
hi%u l :R, eng v1i k nhp nh@t. -'ng thec ph4n t c)a * lZ
a. -"7! :. -"70 c. -"7" W. -070
C01 327 -$ m>t hmn h?p hai hiWrocac:on A v B X tho kh3. 5h4n t khi c)a B l1n hn ph4n t khi c)a A "!
#v-. Tk khi hi so v1i 7" c)a B :<ng NbQ tk khi hi so v1i 7" c)a A. Mhi #t ch+y g lit hmn h?p thu #H?c ,"
lit -V" U#ktcR v 2,g 7"V. 7pi A v B l nhxng hiWrocac:on noE
a. -"72 v -!7D :. -"70 v -!70
c. -K72 v -Q7D W. M;t tuq kh+c
C01 337 Pt ch+y hon ton hmn h?p * gIm hi c)a hiWrocac:on A v kh3 o9i WH thu #H?c hmn h?p kh3 v hi.
im lnh hmn h?p ny, tho t3ch giqm QDG. [;u cho hmn h?p cn li tua MV7, tho t3ch giqm 2K,KG s cn li. *+c
#,nh c'ng thec ph4n t c)a hiWrocac:on.
a. -"70 :. -Q72 c. -Q7" W. -070
C01 347 Trong m>t hmn h?p kh3 * gIm hiWrocac:on A v kh3 o9i WH trong :nh rIi #t ch+y, sau khi 9ong,lm
lnh hmn h?p kh3 thu #H?c, nhn th@y tho t3ch giqm KK,KG so v1i tho t3ch hmn h?p thu #H?c. [;u Wfn hmn h?p
kh3 ti;p tnc tua Wung W,ch MV7 tho t3c :, giqm /QG s cn li. Tm c'ng thec ph4n t hiWrocac:on A.
a. -K70 :. -K7! c. -"70 W. -070
C01 327 nhi%t #> DD
o
-, khi lH?ng ph4n t trung :nh c)a hmn h?p gIm m>t s hiWrocac:on lien ti;p trong
csng WSy #Ing #ng no #$ :<ng 0!. (au khi lm lnh #o nhi%t #> phng th m>t s ch@t trong hmn h?p :, h$a
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
lpng. Mhi lH?ng ph4n t trung :nh c)a nhxng ch@t cn li X tho kh3 :<ng Q!, cn khi lH?ng ph4n t trung :nh
c)a nhxng ch@t lpng l /!. Tng khi lH?ng ph4n t c+c ch@t trong hmn h?p :an #Fu :<ng "Q" #v- v ph4n t
khi c)a #Ing #ng nTng nh@t :<ng " lFn c)a ph4n t khi c)a #Ing #ng nh nh@t. 7Sy 9+c #,nh c'ng thec
ph4n t c)a c+c ch@t trong hmn h?p :an #FuE
a. -K726 -!7D6 -Q7" :. -"70 v -K70 c. -!726 -Q7D v -07" W. M;t tuq kh+c
C01 337 =>t hmn h?p kh3 c$ khi lH?ng /,0g gIm ","! lit m>t hiWrocac:on mch thng A v ," lit m>t ankin
B U#ktcR. Pt ch+y hon ton hmn h?p trn rIi cho ton :> sqn phzm ch+y h@p thn h;t trong Wung W,ch BaUV7R"
WH th #H?c D2,KQg k;t t)a. A thu>c loi hiWrocac:on noE
a. -K7! v -!72 :. -"7" v -K72 c. -070 v -/72 W. M;t tuq kh+c
C01 34. 7mn h?p hai ole|in UX tho kh3R lien ti;p trong csng WSy #Ing #ng h?p nH1c to thnh " rH?u Um>t rH?u
c$ Wng mch nh+nhR hi%u su@t #&u :<ng !DG. Bi;t tho t3ch hmn h?p g lit UX D
o
-, atmR
-hia hmn h?p rH?u thnh " phFn :<ng nhau. -ho [a t+c Wnng v1i phFn thu #H?c ",!0! lit 7" UX "/,K
o
-, atmR.
Pun n$ng phFn " v1i 7"(V! #Tc to K,2Q"g hmn h?p K ete. QDG lH?ng rH?u c$ s nguyn t cac:on 3t hn v
!DG lH?ng rH?u c$ s nguyn t cac:on nhi&u hn #S to thnh ete. *+c #,nh c'ng thec ph4n t " ole|in.
a. -K70 v -!72 :. -"7! v -!72 c. -!72 v -Q7D W. -"7! v -K70
B T5 T c
C01 35;R Tr>n D,D" mol -"7" v D,DK mol 7" v1i ,02 lit V" U#kctR np vo m>t kh3 k; c$ tho t3ch ! lit rIi #t
ch+y.p su@t hmn h?p sau phqn khi t
o
\ DN,"
o
- lZ
a. D,KN" atm :. ,/0 atm c. D,/2! atm W. ,Q02 atm
ER -ho gam hmn h?p gIm 0,/" lit m>t hiWrocac:on mch hX A v "",! lit m>t ankin. Pt ch+y hmn h?p ny th
tiu thn "Q,/0 lit o9i. -+c tho t3ch #o trong #i&u ki%n tiu chuzn.
-'ng thec ph4n t c)a hiWrocac:on A v B lFn lH?t lZ
a. -"70 v -"7" :. -K70 v -K7! c. -"7" v -K7! W. -"7! v -"7"
C01 36;R Trong m>t :nh k3n tho t3ch Q,0 lit chea K,K0 lit 7" v ","! lit -"7! U#ktcR v m>t 3t :>t niken. Pt n$ng
:nh m>t thli gian, (au #$ lm lnh v& D
o
-, +p su@t trong :nh lrc #$ l p. [;u cho hmn h?p kh3 trong :nh sau
phqn eng l>i tua nH1c :rom th@y c$ D,2g Br" tham gia phqn eng.
7Sy t3nh phFn trSm phqn engZ
a. K,0QG :. 0K,KG c. N!,NQG W. DDG
ER Pt ch+y hon ton QD cm
K
hmn h?p kh3 A gIm -"70, -"7!, -"7" v 7" thu #H?c !Q cm
K
-V". =Tt kh+c nung
n$ng tho t3ch hmn h?p kh3 A #$ c$ mTt 5W 9rc t+c th thu #H?c !D cm
K
hmn h?p kh3 B. (au #$ cho hmn h?p kh3 B
tua [i #un n$ng cho m't kh3 Wuy nh@t. Uciq s c+c phqn eng 9qy ra hon tonR Thnh phFn phFn trSm theo tho
t3ch c+c kh3 trong hmn h?p A U 7", -"7", -"7!, -"70R lFn lH?t lZ
a. "DG, KDG, "DG,KDG :. "QG, QG, KDG, KDG
c. QQG, "DG, QG, DG W. M;t tuq kh+c
C01 40;R Pt ch+y 0D cm
K
hmn h?p ankin *, . l hai #Ing #ng lien ti;p nhau thu #H?c ""D cm
K
-V" U c+c tho
t3ch kh3 #o trong csng #i&u ki%nR. -'ng thec ph4n t c)a * v . lFn lH?t lZ
a. -"7" v -K7! :. -K7! v -!70 c. -!70 v -Q72 W. M;t tuq kh+c
EF =>t :nh k3n " lit X "/,K
o
- chea D,DK mol -"7"6 D,DQ mol -"7! v D,D! mol 7" c$ +p su@t p.
[;u trong :nh #S c$ m>t 3t :>t [i lm 9rc t+c U tho t3ch kh'ng #+ng koR, nung :nh #;n nhi%t #> cao #o phqn eng
9qy ra hon ton, sau #$ #Ha v& nhi%t #> :an #Fu #H?c h'n h?p kh3 A c$ +p su@t p". -ho hmn h?p A t+c Wnng v1i
lH?ng WH Wung W,ch Ag[VK trong [7K thu #H?c K,0g k;t t)a. 7Sy t3nh +p su@t p"Z
a. D,"// atm :. D,0N"Q atm c. ,D2 atm W. D,QQ! atm
C01 417 aR Pt ch+y hon ton ","! lit kh3 -"7! U#ktcR rIi h@p thn ton :> sqn phzm vo Wung W,ch chea ,
gam -aUV7R". 7pi sau khi h@p thn khi lH?ng phFn Wung W,ch tSng hay giqm :ao nhiu gamE
a. tSng !,2g :. giqm ",!g c. tSng ",!g W. giqm K,0g e. tSng K,0g
:R =>t hmn h?p A gIm D," mol -"7" v D,2 mol 7". -ho A tua [i nung n$ng,phqn eng kh'ng hon ton v
thu #H?c kh3 B. -ho B tua :nh Wung W,ch Br" WH, thu hmn h?p kh3 tho+t ra *. Pt ch+y hon ton * rIi cho ton
:> sqn phzm vo :nh chea Wung W,ch -aUV7R" WH, thu #H?c " gam k;t t)a v khi lH?ng :nh tSng ln 2,22
gam. T3nh #> tSng khi lH?ng c)a :nh Wung W,ch Br".
a. D,2"g :. ",!0g c. ,0!g W. K,"2g e. k;t tuq kh+c
C0142. aR Tr>n ," lit hmn h?p * gIm -K70 Uchi;m !DGgR v -K7! Uchi;m 0DGgR v1i 7" trong :nh k3n KK,0
lit c$ 3t :>t [i X #ktc. (au thli gian #t ch+y n$ng :nh v #Ha v& nhi%t #> :an #Fu th@y +p su@t kh3 trong :nh l
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
"bK atm. Bi;t khi cho hmn h?p tua Wung W,ch mui Ag
B
trong ammoniac tho t3ch c)a n$ giqm bD. 7Sy 9+c #,nh
thnh phFn v s mol hmn h?p kh3 thu #H?c sau phqn engZ
a. -K72 UD,Q molR v 7" UD,Q molR :. -K72 UD,N molR v -K70 UD,molR
c. -K72 UD,K molR v -K70 UD, molR W. -K7! UD, molR v 7" UD,Q molR
e. M;t tuq kh+c
:R =>t hmn h?p gIm -"7! v -K70, trong #$ -K70 chi;m /,!KG v& tho t3ch. =>t hmn h?p * gIm v 7" v1i
s mol :<ng Q lFn s mol 7". i@y N,!D2 lit * U#ktcR #ung n$ng v1i [i 9rc t+c, phqn eng hon ton, thu #H?c
hmn h?p kh3 v. Bi;t tk l% mol c)a " ankan sinh ra :<ng tk l% mol c)a " ole|in tHng eng :an #Fu.
( mol c+c kh3 -"70, -K72, -"7!, -K70 lFn lH?t lZ
a. D,D6 D,D06 D,D2 v D," :. D,DK6 D,D!6 D,D0 v D,"" c. D,D"6 D,DQ6 D,D2 v D," W. k;t tuq kh+c
C01437 aR Pt m>t hmn h?p gIm hai hiWrocac:on A, B Uc$ = hn km nhau "2gR th thu #H?c D,K mol -V" v
D,Q mol 7"V.-'ng thec ph4n t c)a A v B lFn lH?t lZ
a. -"70 v -K72 :. -7! v -!7D c. -7! v -"70 W. -7! v -K72
:R 7?p ch@t A c$ 2 nguyn t c)a hai nguyn t =A K". 7Sy lp lun # tm ra c'ng thec c)a AZ
a. -!7! :. -K7Q c. -"70 W. M;t tuq kh+c
C0144. aR 7mn h?p ^ gIm h?p ch@t -"70 v m>t ankin B U X tho kh3R tr>n v1i nhau theo tk l% mol Z. Thm V"
vo hmn h?p ^ #H?c hmn h?p ^ c$ tk khi so v1i 7" \ 2. 7Sy tm c'ng thec ph4n t c)a ankin BE
a. -K7! :. -"7" c. -!70 W. -Q72
:R Pt ch+y D,K mol hmn h?p " hiWrocac:on mch hX U thu>c trong s K loi hiWrocac:on para||in, ole|in v
ankinR c$ tk l% khi lH?ng ph4n t l ""bK, rIi cho sqn phzm sinh ra #i vo :nh WJng Wung W,ch BaUV7R" WH th
th@y :nh nTng thm !0,Qg v c$ !/,/Qg k;t t)a. hSy 9+c #,nh c'ng thec ph4n t hai hiWrocac:on.
a. -K72 v -K7! :. -"7" v -"70 c. -K72 v -K70 W. -K72 v -"7"
C0142. Pt ch+y hon ton m>t hmn h?p c$ tk l% mol :<ng nhau c)a ch@t -272 v m>t hiWrocac:on B trong o9it
thu #H?c -V" v hi nH1c theo tk l% tho t3ch KbD. Bi;t r<ng ch@t B chk to ra m>t sqn phzm Wuy nh@t chea m>t
nguyn t :rom trong ph4n t v khi lH?ng ph4n t WH1i Q" #v-. -h@t B c$ c'ng thec ph4n t lZ
a. -7! :. -Q7" c. -K70 W. -Q72
C0143. Pt ch+y hon ton K,"! gam hmn h?p * gIm hai ch@t huu9 c A v B kh+c WSy #Ing #ng, trong s
#$ A hn B m>t nguyn t cac:on, ngHli ta chk thu #H?c 7"V v N,!g gam -V". Bi;t tk khi hi c)a * #i v1i
7iWro l K,Q. -'ng thec ph4n t c)a A v : lZ
a. -7! v -"7" :. -7!V v -"7" c. -7"V v -"7" W. -7"V" v -"7"
C0144. Pt ch+y g lit hmn h?p * X #ktc gIm " hiWrocac:on to thnh !,!g -V" v ,2g 7"V.
7Sy cho :i;t hai hiWrocac:on trn csng hay kh+c WSy #Ing #ng v thu>c WSy #Ing #ng noE U chk 9t c+c WSy
#Ing #ng #S hdc trong chHng trnhR.
a. -sng WSy #Ing #ng cq hai hiWrocac:on l anken hay 9icloankan
:.Mh+c WSy #Ing #ngZ ankan v ankaWien
c.Mh+c WSy #Ing #ngZ ankin v ankan W.-4u A B B B - #&u #rng
C0145. Pt ch+y hon ton m>t hmn h?p A gIm " hiWrocac:on U #i&u ki%n thHlng, X tho kh3R, c$ khi lH?ng mol
ph4n t km nhau "2g, sqn phzm to thnh cho #i tua :nh #Jng 5"VQ v :nh -aV. Bnh #Jng 5"VQ nTng thm Ng
cn :nh #Jng -aV nTng thm K,"g.
aR -+c hiWrocac:on thu>c WSy #Ing #ng noE
a. ankan :. anken c. ankin W. aren
:R -'ng thec " hiWrocac:on lZ
a. -"7! v -!72 :. -"7" v -!70 c. -7! v -K72 W. M;t tuq kh+c
C01467 Pt ch+y hon ton hmn h?p hai hiWrocac:on #'ng #ng h@p thn hon ton sqn phzm sinh ra :<ng
BaUV7R" WH chea trong :nh th@y nTng thm "",g v c$ /2,2g k;t t)a trjng.
aR *+c #inh WSy #Ing #ng c)a " hiWrocac:on, :i;t chrng thu>c m>t trong :a WSy ankan, anken v ankin.
a. ankan :. ankin c. anken W. c4u A #rng
:R *+c #,nh hai hiWrocac:on #S cho, :i;t chrng U 9;p theo the tJ tSng WFn ph4n t khiR #H?c tr>n theo tk l% s
mol Z".
a. -"7! v -K70 :. -"7" v -K7! c. -K7! v -!70 W. -7! v -"70
C0120. A l hmn h?p kh3 U#ktcR gIm K hiWrocac:on *, ., v thu>c K WSy #Ing #ng. B l hmn h?p V" v VK c$ tk
khi so v1i hiWro :<ng N,". Po #t ch+y mol hmn h?p A cFn Q mol hmn h?p B, thu #H?c -V" v hi nH1c c$
s mol nhH nhau.
Mhi cho "",! lit hmn h?p A #i tua :nh nH1c :rom WH th@y c$ ," lit kh3 :ay ra, khi lH?ng :nh nH1c :rom tSng
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
"/g, cn khi cho "",! lit hmn h?p A #i tua Wung W,ch Ag[VK trong [7K th@y to thnh K",!g k;t t)a vng. -+c
kh3 #o #H?c X #ktc. Ba hiWrocac:on trong hmn h?p lZ
a. -K72, :utinC v :utaWieneC :. -!7D, :utinC v :utaWieneC
c. -Q7", :utinC v :utaWieneC hoTc :utaWiene CK
W. M;t tuq kh+c
C01217 =>t hmn h?p * gIm hiWrocac:on lien ti;p nhau trong WSy #Ing #ng c$ khi lH?ng D,Qg v c$ tho t3ch
hmn h?p l ",KQ" lit X DN,"
o
- v ",2at. 7 nhi%t #> 9ung D
o
-, m>t s hiWrocac:on Uc$ s - QR h$a lpngcon|
li hmn h?p . c$ tho t3ch ,"! lit X ",2at. Tk khi hi c)a hmn h?p . so v1i kh'ng kh3 :<ng ,!D". Tng ph4n t
khi c)a hmn h?p :<ng "2D.*+c #,nh WSy #Ing #ng c)a hiWrocac:on, :i;t r<ng ph4n t khi c)a c+c ch@t sau
csng :<ng ,Q lFn ph4n t khi c)a ch@t the K.
a. anken :. arken c. ankaWien aren
C01227 =>t hmn h?p * gIm hi hiWrocac:on mch hX A v 7" WH c$ tk khi hi v1i 7li :<ng K. -ho hmn h?p
* tua :>t [i nung n$ng trong #i&u ki%n #o 9qy ra phqn eng hon ton thu #H?c hmn h?p kh3 . c$ tk khi hi so
v1i 7e :<ng /,Q. Bi;t s nguyn t cac:on trong m>t mol A nhp hn /. -'ng thec ph4n t c)a A lZ
a. -K7! :. -!7! c. -Q7D W. -K70
C0123. Pt ch+y hon ton hiWrocac:on trong :nh k3n c$ tho t3ch D lit :<ng lH?ng kh'ng kh3 g@p #'i lH?ng cFn
thi;t. (au phqn eng lm lnh :nh 9ung D
o
- th@y +p su@t trong :nh l ,N!2 atm.
=Tt kh+c khi h@p thn lH?ng nH1c sinh ra :<ng "Qml Wung W,ch 7"(V! N2G U^ \ ,2!gbcm
K
R s #H?c Wung W,ch
c$ nIng #> NQ,/QG. Tm c'ng thec ph4n t c)a A :i;t n$ kh'ng c$ #Ing ph4n.
a. -K70 :. -"7" c. -"7! W. -070
C01247 -ho h?p ch@t c$ c'ng thec ph4n t -272, :i;t K,"g ch@t ny phqn eng h;t v1i Wung W,ch chea !,2g Br"
hoTc v1i ti #a ",022 lit 7" U#ktcR. 7iWro h$a -272 theo tk l% Z #H?c hiWrocac:on csng loi *. Mhi Brom h$a
m>t #Ing ph4n . c)a * v1i 9rc t+c :>t ]e theo tk l% mol Z #H?c m>t sqn phzm Wuy nh@t. -'ng thec c@u to
c)a -272 lZ
a. -07!U-7KR" :. -07Q-7\-7" c. -07Q-7"\-7K W. -4u : #rng
C0122. =>t hmn h?p hai ankan k; cn trong WSy #Ing #ng c$ tk khi hi v1i 7" l "!,2.
aR -'ng thec ph4n t c)a hai ankan lZ
a. -"7" v -K7! :. -"7! v -!72 c. -K72 v -Q7" W. M;t tuq kh+c
:R Thnh phFn G tho t3ch, thnh phFn hmn h?p lZ
a. KDG v /DG :. KQG v 0QG c. 0DG v !DG W. -sng QDG
C01237 #ktc c$ m>t hmn h?p kh3 hiWrocac:on no A v B tk khi hi so v1i hiWro l " UWhhb7" \ "R.
aR Tm khi lH?ng -V" v hi nH1c sinh ra khi #t Q,02 lit hmn h?p U X #ktcR
a. "!,"g v 0,"g :. !2,!g v K",!g c. !Dg v KDg W. M;t tuq kh+c
:R -'ng thec ph4n t c)a A v B lZ
a. -7! v -"70 :. -7! v -K72 c. -7! v -!7D W. -q :a c4u a B : B c
C01247 =>t hmn h?p gIm " kh3 hiWrocac:on mch hX. Tk khi hi hmn h?p so v1i 7" l /. #ktc !DDcm
K
hmn
h?p t+c Wnng vAa #) v1i /,!cm
K
Wung W,ch Br" D,"= v cn li "!Dcm
K
kh3. *+c #,nh c'ng thec ph4n t c)a hai
hiWrocac:on.
a. -"70 v -"7" :. -K72 v -K7! c. -"70 v -K7! W. -!7D v -"7"
C0125. 7mn h?p kh3 A gIm hai hiWrocac:on c$ csng s nguyn t cac:on U#ktcR.
aR Tm tk khi hi c)a hmn h?p A #i v1i [ito, :i;t r<ng Q0Dcm
K
hmn h?p #$ nTng ,K0"Qg.
a. ,N :. " c. ,0 W. k;t tuq kh+c
:R Pt ch+y gcm
K
hmn h?p A cho c+c sqn phzm phqn eng lFn lH?t tua :nh #Jng 5"VQ v :nh " #Jng BaUV7R"
th@y khi lH?ng :nh tSng ",K!g v :nh " tSng /,D!g. *+c #,nh c'ng thec ph4n t c)a c+c hiWrocac:on :i;t r<ng
c$ m>t hiWrocac:on l ole|in.
a. -!72 v -!70 :. -!72 v -!7! c. -!72 v -!7" W. -q :a c4u a B : B c
C0126. -ho D lit hmn h?p kh3 U X Q!
o
- v D,2D0! atmR gIm hai anken l>i tua :nh #Jng nH1c :rom WH th@y khi
lH?ng :nh nH1c :rom tSng ln 0,2g.
aR T3nh tng s mol c)a " anken.
a. D, mol :. D," mol c. D,K mol W. M;t tuq kh+c
:R 7Sy :i%n lun c+c cTp anken c$ tho c$ trong hmn h?p kh3 :an #Fu :i;t r<ng s nguyn t - trong mmi anken
kh'ng tu+ Q.
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
a. -Q7D v -"7! :. -Q7D v -K70 c. -Q7D v -!72 W. -q hai c4u a B :
C01307 -ho "K"cm
K
hmn h?p gIm ankan A v anken B X tho kh3 U s nguyn t - trong A, B nhH nhauR vo
nH1c :rom WH th@y khi lH?ng :nh tSng thm ,!g. Pt ch+y hon ton ch@t kh3 sau khi tua nH1c :rom v cho
sqn phzm ch+y vo Wung W,ch [aV7 WH thu #H?c 2Dml Wung W,ch mui D,Q=. -'ng thec ph4n t c)a A, B lZ
a. -"7! v -"70 :. -K72 v -!72 c. -!72 v -Q7" W. -"7! v -!7D
C01317 =>t hmn h?p gIm ankan v ankin. Pt ch+y hon ton hmn h?p ny thu #H?c ",0g 7"V. Mhi lH?ng o9i
cFn Wung cho phqn eng l K0,2g. Tho t3ch -V" sinh ra :<ng 2bK tho t3ch hmn h?p kh3 :an #Fu.
aR Tng s mol c)a hmn h?p :an #Fu lZ
a. D,K mol :. D," mol c. D,! mol W. M;t tuq kh+c
:R *+c #,nh c'ng thec c@u to c$ tho c)a ankan v ankin.
a. -K72 v -"7" :. -"70 v -K7! c. -!7D v -"7" W. -q hai c4u : B c
C0132. =>t hmn h?p gIm hai hiWrocac:on mch hX. -ho 2!Dml hmn h?p l>i tua Wung W,ch :rom WH th cn li
Q0Dml, #'ng thli c$ "g Br" tham gia phqn eng. [goi ra n;u #t ch+y hon ton 2!Dml hmn h?p rIi cho kh3 -V"
tua Wung W,ch -aUV7R" WH th #H?c 0,"Qg k;t t)a Uc+c kh3 #o X #ktcR.
-'ng thec ph4n t c)a " hiWrocac:on lZ
a. -7! v -!7D :. -"70 v -K70 c. -7! v -K70 W. M;t tuq kh+c
Chuyn ?4: bi t5# %ncol6 %n8hit6 78ton
A> *BA TCD EFC,G
Cu 1: -$ :ao nhiu ancol no :c ", #n chec mch hX, l #Ing ph4n c@u to c)a nhau m ph4n t c)a chrng c$
phFn trSm khi lH?ng - l Z 02,2G
Cu 2: =>t loi go chea /QG tinh :>t. i@y /2,"2 kg go ny #i n@u rH?u etylic , hi%u su@t pu c)a cq tu+
trLnh l 0DG. Mhi lH?ng ring c)a rH?u etylic l D,2 gbml. Tho t3ch rH?u thu #H?c lE
Cu 3: Pt ch+y hon ton "/,0 gam hmn h?p * gIm thu #H?c K",! gam
v g l3t U#ktcR. ci+ tr, c)a g l
Cu 4: T+ch nH1c hmn h?p #Ing mol * gIm metanol v etanol X c$ #Tc, thu #H?c sqn phzm
ete v .2 gam nH1c v1i hi%u su@t /DG.Mhi lH?ng hmn h?p * l
Cu 5: V9i h$a 0g rH?u #n chec thu #H?c 2,!g hmn h?p gIm anWehit, rH?u WH v nH1c. 7i%u su@t phqn
eng V* h$a rH?u #t :ao nhiu G
Cu 6: -ho m gam m>t ancol no, #n chec * tua :Lnh #Jng WH nung n$ng.(au khi phqn eng hon ton.
khi lH?ng ch@t rjn trong :Lnh giqm D.K"g.7mn h?p hi thu #H?c c$ tk khi #i v1i l Q.Q
Cu 7: -ho ,Q"g hmn h?p hai ancol #n chec l #Ing #ng k; ti;p nhau t+c Wnng v1i [a vAa #), sau phqn eng
thu #H?c ",2g ch@t rjn. -'ng thec ph4n t c)a hai ancol l
Cu 8: 7mn h?p * gIm ancol metylic v ancol no, #n chec A. -ho /,0g * t+c Wnng v1i [a WH thu #H?c ,02 l3t
U#ktcR, mTt kh+c o9i h$a hon ton /,0g * :<ng -uV U R rIi cho ton :> sqn phzm thu #H?c t+c Wnng v1i
Wung W,ch WH thu #H?c ",0g k;t t)a. -'ng thec c@u to c)a A lZ
Cu 9: Pt ch+y hon ton m gam hmn h?p * gIm hai ancol A v B thu>c csng W8y #Ing #ng thu #H?c 0,/" l3t
v /,0Qg . =Tt kh+c khi cho m gam hmn h?p * t+c Wnng v1i [a WH thu #H?c ",2 l3t . Bi;t tk khi
hi c)a mmi ch@t so v1i hi#ro #&u nhp hn !D, c+c tho t3ch kh3 #o X #ktc. A v B c$ c'ng thec ph4n t lFn lH?t l
Cu 10: Pun K",2g hmn h?p K ancol no, #n chec v1i #Tc X thu #H?c hmn h?p gIm c+c ete c$
s mol :<ng nhau v c$ khi lH?ng l ,"g. ( mol c)a mmi ete trong hmn h?p l gi+ tr, no WH1i #4y E
Cu 11: Pt ch+y hon ton D,K mol hmn h?p * gIm " rH?u lin ti;p trong W8y #Ing #ng Cu 24: V9i h$a h;t
D," mol rH?u #n chec A, B lin ti;p trong W8y #Ing #ng :<ng -uV #un n$ng #H?c hmn h?p * gIm " an#hit.
-ho * t+c Wnng v1i lH?ng WH Wung Wich #H?c Q!g :c. A, B l " rH?u no E
#H?c v D,Q mol . -'ng thec ph4n t " rH?u trn lFn lH?t lE
Cu 12: ^fn !g hi rH?u #n chec A tua -uV nung n$ng #H?c Q,0g hmn h?p hi. A l rH?u c$ c'ng thec c@u
to
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
Cu 13: Mhi ph4n t3ch ch@t hxu c A Uchea -,7,VR thL c$ . i@y hai rH?u #n chec
*, . #em #un n$ng v1i #Tc X nhi%t #> th3ch h?p thL thu #H?c A.-'ng thec Umch hXR A, *, . U:i;t A
l eteR l
Cu 14: H?u A t+c Wnng v1i WH cho m>t tho t3ch :<ng v1i tho t3ch hi rH?u A #8 Wsng. =Tt kh+c #t
ch+y h;t m>t tho t3ch hi rH?u A thu #H?c chHa #;n :a tho t3ch kh3 Uc+c tho t3ch #o X csng #i&u ki%nR.
H?u A c$ tn gdi
Cu 15: =>t hmn h?p * gIm " rH?u no #n chec A, B #Ing #ng k; ti;p. Pt ch+y D," mol * cFn D,D2 l3t
UWkcR. -'ng thec ph4n t v s mol c)a A v B l
Cu 16: 7mn h?p A gIm " rH?u. Pun n$ng m gam hmn h?p A v1i #m #Tc, thu #H?c K,Q2! l3t hmn h?p
" ole|in k; ti;p nhau trong W8y #Ing #ng U#ktcR. [;u #em #t ch+y h;t lH?ng ole|in ny, rIi cho h@p thn sqn
phzm ch+y trong :Lnh #Jng Wung W,ch [aV7 WH, thL khi lH?ng :Lnh tSng "!,2g. -+c phqn eng 9qy ra hon
ton. Tr, s c)a m l
Cu 17: =>t rH?u no #a chec mch hX *, c$ n nguyn t cac:on v m nh$m . -ho /,0 gam * phqn eng
v1i WH, thu #H?c D, mol kh3 . Biou thec lin h% gixa n v m l
Cu 18: -ho hmn h?p * gIm ancol etylic v ancol . thu>c Wfy #Ing #ng c)a ancol etylic, cho D./0 gam * t+c
Wnng h;t v1i [a th@y tho+t ra D,02 l3t kh3 U#kcR, cho :i;t tk l% s mol c)a ancol etylic v ancol . l "Z, c'ng
thec ph4n t c)a ancol . l
Cu 19: 7mn h?p rH?u * gIm " rH?u no mch hX A v B c$ csng s nguyn t - trong ph4n t. -hia !./gam
* thnh " phFn :<ng nhauZ
C 5hFn t+c Wnng h;t v1i [a to ra .02lit U#ktcR
C 5hFn " #t ch+y hon ton, sinh ra !,2Qgam kh3
-$ m@y cTp rH?u thoq m8n #i&u ki%n trn
Cu 20: Pt ch+y hon ton Q,0 l3t hi " rH?u no, #n chec thu #H?c /,2! l3t Uc+c tho t3ch #&u #o X #ktcR.
^fn ton :> sqn phzm ch+y vo :Lnh #Jng "DD ml Wung W,ch ,Q=. Mhi lH?ng Wung W,ch sau phqn
eng so v1i khi lH?ng Wung W,ch
Cu 21: 7mn h?p A gIm D, mol etylenglicol v D," mol ch@t * .Po #t ch+y hon ton hh A cFn ","2 l v
thu #H?c KQ,"g v N,2g .T3nh khi lH?ng ph4n t * U * chea -, 7 ,VR
Cu 22: Pun n$ng m>t hmn h?p gIm " rH?u v1i #Tc X thu #H?c ",0gam v /"gam hmn
h?p K ete c$ s mol :<ng nhau. -'ng thec hai rH?u lE
Cu 23: 7mn h?p * gIm ancol v " sqn phzm h?p nH1c c)a propen. Tk khi hi c)a * so v1i hi#ro :<ng "K.
-ho m gam * #i tua ng se #Jng -uV UWHR nung n$ng. (au khi c+c phqn eng 9qy ra hon ton, thu #H?c hmn
h?p . gIm K ch@t hxu c v hi nH1c, khi lH?ng ng se giqm K," gam. -ho . t+c Wnng hon ton v1i lH?ng WH
Wung W,ch Ag[VK trong [7K, to ra !2,0 gam Ag. Tinh phFn trSm khi lH?ng c)a propanCCol trong *
Cu 24: -ho m gam hmn h?p * gIm hai rH?u UancolR no, #n chec, k; ti;p nhau trong W8y #Ing #ng t+c Wnng
v1i -uV UWHR nung n$ng, thu #H?c m>t hmn h?p rjn v v m>t hmn h?p hi . Uc$ tk khi hi so v1i 7" l K,/QR.
-ho ton :> . phqn eng v1i m>t lH?ng WH Ag"V UhoTc Ag[VKR trong Wung W,ch [7K #un n$ng, sinh ra 0!,2
gam Ag. Ti nh gi+ tr, c)a m .
A. N,". B. /,!. -. 2,2. ^. /,2.
Cu 25: -ho /,2 gam h'n hp " ancol #n chHc k tip nhau trong Way #'ng #Sng tac Wung h t v i !,0 gam [a
#Hc ","Q gam ch4 t rSn. *ac #inh -T5T cua " ancol
Cu 26: -ho m gam m>t ancol UrH?uR no, #n chec * tua :Lnh #Jng -uV UWHR, nung n$ng. (au khi phqn eng
hon ton, khi lH?ng ch@t rjn trong :Lnh giqm D,K" gam. 7mn h?p hi thu #H?c c$ tk khi #i v1i hi#ro l Q,Q.
Ti nh gi+ tr, c)a m .
Cu 27: 7mn h?p * gIm hai ancol no, #n chec, mch hX, k; ti;p nhau trong W8y #Ing #ng. V9i ho+ hon ton
D," mol hmn h?p * c$ khi lH?ng m gam :<ng -uV X nhi%t #> th3ch h?p, thu #H?c hmn h?psqn phzm hxu c ..
-ho . t+c Wnng v1i m>t lH?ng WH Wung W,ch Ag[VK trong [7K, thu #H?c Q! gam Ag. Ti nh gi+ tr, c)a m.
Cu 28 : -ho [a WH vo m>t Wung W,ch gIm U-
"
7
Q
V7 B 7
"
VR th@y khi lH?ng 7
"
:ay ra :<ng K G khi lH?ng
Wung Wich #8 Wsng. Ti nh -G cua Wung Wi ch -"7QV7 :an #4u E
Cu 29: Pun n$ng hmn h?p hai ankanol lin ti;p trong W8y #Ing #ng v1i 7"(V! #Tc X !D
D
-, thu #H?c ",0
gam 7"V v KN," gam hmn h?p :a ete c$ s mol :<ng nhau.*ac #inh -T5T c)a hai ankanol
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
Cu 30 : Pun n$ng hmn h?p gIm hai rH?u UancolR #n chec, mch hX, k; ti;p nhau trong W8y #Ing #ng v1i
7
"
(V
!
#Tc X !D
o
-. (au khi c+c phqn eng k;t thrc, thu #H?c 0 gam hmn h?p gIm :a ete v ,2 gam nH1c. *ac
#inh c'ng thec ph4n t c)a hai rH?u trn
Cu 31 : Pun n$ng ancol #n chec * v1i 7"(V! #Tc X !D
o
- thu #H?c .. Tk khi hi c)a . #i v1i * l
,!K/Q. *ac #inh -T5T cu a *
Cu 32: Mhi #un n$ng m>t ancol #n chec no A v1i 7"(V! #Tc X #i&u ki%n nhi%t #> th3ch h?p thu #H?c sqn
phzm B c$ tk khi hi so v1i A l D,/. *ac #inh c'ng thec c)a A.
Cu 33: -ho ",Ng hmn h?p K ancol no, #n chec, mch hX tham gia phqn eng t+ch nH1c X #i&u ki%n th3ch h?p
thu #H?c hmn h?p * gIm " kh3 l #Ing #ng k; ti;p, c$ tk khi so v1i hmn h?p ancol :an #Fu l D,0Q
a. *+c #,nh -T5T c)a c+c ancol
:. [;u cho ton :> lH?ng ancol trn phqn eng vi -uV #un n$ng, sqn phzm thu #H?c cho t+c Wnng v1i lH?ng WH
WWAg[VKb[7K WH thu #H?c K/,2g kim loi :c. *+c #,nh phFn trSm khi lH?ng mmi ancol trong hmn h?p :an
#Fu
cu 34: Pt ch+y hOan tOan m gam hmn h?p * gIm :a ancol U#n chec, thu>c csng W8y #Ing #ngR, thu #H?c
2,N0 l3t kh3 -V" U#ktcR v ,/ gam 7"V. =Tt kh+c, n;u #un n$ng m gam * v1i 7"(V! #Tc tinh tng khi lH?ng
ete ti #a thu #H?c. A. /,2Q gam. B. /,!D gam. -. 0,QD gam.
^. Q,0D gam
cu 35: Pun n$ng hmn h?p hai ancol #n chec, mch hX v1i 7"(V! #Tc, thu #H?c hmn h?p gIm c+c ete. i@y /,"
gam m>t trong c+c ete #$ #em #t ch+y hon ton, thu #H?c 2,N0 l3t kh3 -V" UX #ktcR v /," gam 7"V. *ac #inh
-T5T cua hai ancol
-hia hmn h?p gIm hai ancol #n chec * v . Uph4n t khi c)a * nhp hn c)a .R l #Ing #ng k; ti;p thnh
hai phFn :<ng nhauZ
C Pt ch+y hon ton phFn thu #H?c Q,0 l3t -V
"
U#ktcR v 0,K gam 7
"
V.
C Pun n$ng phFn " v1i 7
"
(V
!
#Tc X !D
o
- to thnh ,"Q gam hmn h?p :a ete. 7o+ hi hon ton hmn h?p :a
ete trn, thu #H?c tho t3ch hi :<ng tho t3ch c)a D,!" gam [
"
Utrong csng #i&u ki%n nhi%t #>, +p su@tR. Ti nh
hi%u su@t phqn eng to ete c)a *, . .
A. "QG v KQG. B. "DG v !DG. -. !DG v "DG. ^. KDG v KDG.
Cu 36: Trong m>t :Lnh k3n Wung t3ch 0 l3t chea hmn h?p hi c)a K ancol #n chec, k; ti;p nhau trong W8y
#Ing #ng. cix nhhi%t #> :Lnh X K0,Q
D
- rIi :m thm vo :Lnh /,N"g o9i, th@y +p su@t :Lnh #t ,02 atm. Bt
tia la #i%n #o #t ch+y h;t hmn h?p, sqn phzm ch+y cho tua :Lnh #Jng Wung W,ch -aUV7R" WH th@y khi lH?ng
:Lnh tSng ln "",N"g, #Ing thli 9u@t hi%n KDg k;t t)a.
a. [;u sau khi :t tia la #i%n #o #t ch+y h;t hmn h?p, gix :Lnh X "/K
D
-, thL +p su@t trong :Lnh l :ao
nhiuE
:. *+c #,nh c'ng thec c)a K ancol
IIG HII TJP ANHITK LMT"N
C01 17 -ho D,2/ gam m>t an#ehit no #n chec * phqn eng hon ton v1i Ag[VK trong WW amoniac sinh ra K,"!
gam :c kim loi. -'ng thec c@u to c)a * l
A. -7K-7V. B. -7K-7"-7V. -. 7-7V. ^.-7K-7"-7"-7V.
C01 27 An#hit a9etic kh'ng tho #i&u ch; trJc ti;p tA ch@t no WH1i #4yZ
A.A9etilen B.ginyla9etat -.A9it a9etic ^.H?u tylic
C01 37 [hi%t #> s'i c)a an#hit th@p hn nhi%t #> s'i c)a rH?u tHng eng Wo.
A. An#ehit c$ khi lH?ng mol ph4n t : hn rH?u tHng eng.
B. An#ehit c$ lin k;t hy#r' gixa c+c ph4n t.
-. An#ehit nh hn nH1c.
^. An#ehit kh'ng c$ lin k;t hy#ro gixa c+c ph4n t.
C01 4. -o :ao nhiu #'ng ph4n c4u tao -Q7DV co kha nSng tham gia phan Hng trang gHng E
A. ". B. K. -. !. ^. Q.
C01 27 Trong s c+c t3nh ch@t sau, t3nh ch@t no kh'ng phqi l t3nh ch@t c)a an#ehit acrylic E
A T+c Wnng v1i Wung W,ch Br". B. T+c Wnng v1i rH?u metylic.
-. Trsng h?p. ^. T+c Wnng v1i V", t
o
.
C01 37 Po #i&u ch; -7K-7V tA Al!-K cFn 3t nh@t :ao nhiu phHng trLnh phqn engZ
A. " B. K -. ! ^. Q
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
C01 47 -h@t hxu c * chk chea loi nh$m chec, =A \ Q2. -ho 2,/g * t+c Wnng v1i Ag"D trong [7K WH thL thu
#H?c 0!,2g Ag. -'ng thec c@u to c)a * lZ
A. 7-7V B. -"7Q-7V
-. -7V ^. -7V
-7V -7"C-7V.
C01 57 -$ N gam hmn h?p A gIm -7K-7V v rH?u no #n chec * t+c Wnng v1i [a WH thu #H?c ," l3t kh3 7"
UPMT-R. -{ng N gam hmn h?p A X trn t+c Wnng v13 WW Ag[VK.[7K WH thu #H?c ",0 gam Ag.
-T5T c)a rH?u no #n chec * lZ
A. -7KV7. B. -"7QV7. -. -K7/V7. ^. -!7NV7.
C01 67 -hia hmn h?p gIm hai an#ehit no #n chec thnh hai phFn :<ng nhauZ
C Pt ch+y hon ton phFn the nh@t thu #H?c D,Q!g 7"V.
C 5hFn the hai c>ng 7"U[i, t
D
R thu #H?c hmn h?p *.
[;u #t ch+y hon ton * thL tho t3ch kh3 -V" thu #H?cUX #ktcR lZ
A. D," l3t B. D,0/" l3t -. ,02 l3t ^. ","! l3t
C01 107 7mn h?p A gIm hai anWehit #n chec l #ng #ng k; ti;p nhau. Mhi cho mol A t+c Wnng v1i Ag "V
WH trong WW [7K thu #H?c K mol Ag. A gImZ
AR 7-7V v -7K-7V BR -7K-7V v U-7VR"
-R -7K-7V v -7"\-7C-7V ^R 7-7V v -"7Q-7V
C01 11. -ho D,N"g hmn h?p gIm a9etilen v an#ehit a9etic phqn eng hon ton v1i Wung W,ch Ag[VKb[7K WH
thL thu #H?c Q,0!g hmn h?p rjn. Thnh phFn phFn trSm v& khi lH?ng c)a a9etilen trong hmn h?p lZ
A. "2,"0G B. K",N2G -. KQ,Q!G ^. "K,!QG
C01 127 V9i h$a mg rH?u #n chec :c m>t A :<ng -uV X nhi%t #> cao thL thu #H?c an#ehit B. 7mn h?p kh3 v
hi thu #H?c #H?c chia lm K phFn :<ng nhauZ
5hFn cho t+c Wnng v1i [a WH thL thu #H?c Q,0 l3t kh3 7" U#ktcR.
5hFn " cho t+c Wnng v1i Wung W,ch Ag[VKb[7K WH thL thu #H?c 0!,2g Ag.
5hFn K #em #t ch+y hon ton :<ng V" #H?c KK,0 l3t kh3 U#ktcR v "/g 7"V.
.7i%u su@t phqn eng o9i h$a rH?u thnh an#ehit lZ
A. 0DG B. K!G -. 0/G ^.0QG
". -'ng thec c@u to c)a A lZ
A. -"7QV7 B. -7KV7 -. -7"\-7C-7"V7 ^.-7"\-7C-7"-7"V7
C01 137 P't chay hoan toan m't an#ehit #n chHc no, mch h A c4n /,N" li t V" U#ktcR. 74p thu ht san ph4m
chay vao nHc v'i trong #Hc !D gam kt tua va Wung Wi ch *. Pun nong Wung Wich * la i co D gam kt tua nH a.
-'ng thHc ph4n tH A la
A. -7"V. B. -"7!V. -. -K70V. ^. -!72V
C01 147 -ho hmn h?p kh3 * gIm 7-7V v 7" #i tua ng se #Jng :>t [i nung n$ng. (au khi phqn eng 9qy ra
hon ton, thu #H?c hmn h?p kh3 . gIm hai ch@t hxu c. Pt ch+y h;t . thL thu #H?c ,/ gam 7"V v /,2! l3t
kh3 -V" UX #ktcR. 5hFn trSm theo tho t3ch c)a 7" trong * l
A. KQ,DDG. B. 0Q,DDG. -. QK,2QG. ^. !0,QG.
C01 12. *, ., v, T la ! an#ehit no h #n chH c #'ng #Sng lin tip, trong #o =T \ ",!=*. P't chay hoan toan
D, mol v r'i h4p thu h t san ph4m chay vao :inh #Hng Wung Wi ch -aUV7R " WH th4y kh'i lHng Wung Wich tSng
hay giam :ao nhiu gamE
A. TSng 2,0 gam. B. TSng K," gam. -. ciam ,! gam. ^. ciam KD gam.
C01 13. 7mn h?p * gIm K ancol#n chec A, B, -, trong #$ B, - l " ancol#Ing ph4n. Pt ch+y hon ton D,D2
mol * thu #H?c K,N0 gam 7"V v K,K0 l3t kh3 -V" U#ktcR. ( mol ancolA :<ng QbK tng s mol " ancol B B -.
gy c'ng thec ph4n t c)a c+c ancol lZ
A. -7!V v -K72V B. -7!V v -K70V -. -7!V v -K7!V
C01 14. -ho Q,0 gam hmn h?p " ancol #n chec, k; ti;p nhau trong W8y #Ing #ng t+c Wnng h;t v1i N," gam
[a, thu #H?c "!,Q gam ch@t rjn. 7ai ancol #$ lZ
A. -"7QV7 v -K7/V7 B. -K7QV7 v -!7/V7
-. -K7/V7 v -!7NV7 ^. -7KV7 v -"7QV7
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
C01 157 7mn h?p * gIm " an#ehit no c$ s mol :<ng nhau. -ho ",/Qg * vo :Lnh k3n tho t3ch g \ !," l3t, cho
* :ay hi X K0,Q
o
- thL +p su@t trong :Lnh l p \ "atm.-ho D,"g * t+c Wnng v1i WW Ag[VKb[7K vAa #) to ra
0!,2g Ag v " a9it hxu c. -'ng thec c)a " an#ehit lZ
A. -7K C -7V v -7V C-7V B. -7K C -7V v 7 C -7V
-. 7 C -7V v 7V- C -7" C -7V ^. -q A, B, - #&u #rng
C01 167 -ho 0,2 g * Uchea -,7,VR mch hX, kh'ng ph4n nh+nh phqn eng vAa #) v1i D,K mol Ag[VK trong
Wung W,ch [7K ,t
o
. *+c #,nh -T5T c)a * Z
A. -!7!V B. -K7"V" -. -"7!V ^. Mh'ng 9+c #,nh
C01 20. -ho D, mol an#ehit * t+c Wnng v1i Ag[VKb[7K WH, #un n$ng thu #H?c !K,"g Ag. 7i#ro ho+ * thu
#H?c .. Bi;t D, mol . phqn eng vAa #) v1i !,0g [a. -T-T thu gdn c)a * lZ
A. 7-7V B. -7K-7V -. V7-C-7V ^.-7K-7UV7R-7V
C01 21. Mhi o9i h$a Uc$ 9rc t+cR m gam hmn h?p . gIm 7C-7\V v -7KC-7\V :<ng o9i ta thu #H?c Um B
,0R gam hmn h?p v. ciq s hi%u su@t DDG. -On n;u cho m gam hmn h?p . t+c Wnng v1i Ag[VK WH trong
amoniac thL thu #H?c "Q,N" gam Ag. Thnh phFn G khi lH?ng c)a " a9it trong hmn h?p v l :ao nhiu.
A. !DG v 0DG B. "QG v /QG -. !G v 20G ^. 0G v 2!G
C01 227 =>t hmn h?p * gIm " ankanal #Ing #ng k; ti;p khi :, hi#ro ho+ hon ton cho ra hmn h?p " ancol c$
khi lH?ng l1n hn khi lH?ng * l g . * #t ch+y cho ra KD,2 g -V" . *+c #,nh -T5T c)a " ankanal v khi
lH?ng c)a chrng
A. Ng 7-7V6 2,2 g -7K-7V B. 2g -7K-7V6 2,2 g -"7Q-7V
-. !,Qg -"7Q-7V6 !,! g -K7/-7V ^. Ng -K7/-7V6 2,2 g -!7N-7V
C01 237 Trong m>t :Lnh k3n chea hi ch@t hxu c * Uc$ Wng -n7"nV"R mch hX v V" Us mol V" g@p #'i s
mol cFn cho phqn eng ch+yR X KN,N
D
-, +p su@t trong :Lnh l D,2 atm. Pt ch+y hon ton * sau #$ #Ha v& nhi%t
#> :an #Fu, +p su@t trong :Lnh lrc ny l D,NQ atm. * c$ -T5T lZ
A. -K70V" B. -"7!V" -. -!72V" ^. -7"V"
Chuyn ?9: %7it c%cbo7ylic6 8:t86 li#it
C01 17 7mn h?p * gIm " a9it hxu c #n chrc, #Ing #ng k; ti;p. i@y m gam * #em t+c Wnng h;t v1i "g [a
thL thu #H?c !,"/g ch@t rjn v D,KK0 l3t 7" U#ktcR. -{ng m gam * t+c Wnng vAa #) v1i 0DDml nH1c Br" D,DQ=.
-'ng thec ph4n t c)a hai a9it lZ
A. -K7"V" v -!7!V". B. -K7!V" v -!70V".
-. -!70V" v -Q72V" ^. -K70V" v -!72V".
C01 27 UMAh"DDNR. -ho a mol h?p ch@t hxu c * U chea -, 7, VR phqn eng hon ton v1i [a hoTc [a7-VK thL
#&u sinh ra a mol kh3. -h@t * lZ
A. tylen glycol B. A9it a#ipic
-. Ancol oChi#ro9i:enaylic ^. A9it KChi#ro9ipropanoic
C01 3. Tr>n #&u ancol etylic, a9it a9etic vo nH1c #H?c !g Wung W,ch *. Pem ton :> Wung W,ch * t+c Wnng vAa
#) v1i [a #H?c m gam ch@t rjn v ","! l3t kh3 7" U#ktcR. ci+ tr, c)a m lZ
A. K,Q! B. D,2 -. 2,! ^. !,!
C01 47 Pt ch+y hon ton D,Q mol m>t a9it cac:o9ylic #n chec, cFn vAa #) g l3t V" U#ktcR, thu #H?c D,!Q
mol -V" v D," mol 7"V. ci+ tr, c)a g lZ
A. 2,N0 B. ," -. 0,/" ^.K,!!
C01 27 -ho hmn h?p T gIm a9it cac:o9ylic #n chec *, ancol #n chec ., este c)a * v.. Mhi cho D,Q
mol hmn h?p T t+c Wnng v1i Wung W,ch [aV7 WH, #un n$ng thL thu #H?c D,! mol .. Thnh phFn G s mol c)a *
trong hmn h?p T lZ
A. KK,KKG B. 2DG -. !!,!!G ^. "DG
C01 3. 7mn h?p * gIm " a9it hxu c no, #n chec. Trung ho h;t 0,/g * :<ng Wung W,ch [aV7 rIi c' cn Wung
W,ch thu #H?c 2,Ng mui khan. -On khi cho 0,/g * t+c Wnng v1i lH?ng WH Wung W,ch Ag[VKb[7K thL thu #H?c
D,2g Ag. -'ng thec c)a " a9it lZ
A. 7-VV7 v -7K-VV7 B. 7-VV7 v -K7/-VV7
-. 7-VV7 v -"7Q-VV7 ^. 7-VV-7K v -7K-VV7
C01 4. -ho "Dg hmn h?p hai a9it no, #n chec t+c Wnng vAa #) v1i Wung W,ch [a"-VK thL thu #H?c g l3t kh3 -V"
U#ktcR v Wung W,ch mui. -' cn Wung W,ch thu #H?c "2,2g mui khan. ci+ tr, c)a g lZ
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
A. ","! B. Q,0 -. !,!2 ^. ,"
C01 57 Pt ch+y hon ton a mol hmn h?p * gIm " mui natri c)a " a9it no, #n chec l #Ing #ng k; ti;p nhau
cFn N,Q" l3t V" UX V
D
-, "atmR, phFn ch@t rjn cOn li sau khi #t c4n nTng D,0g. -T-T thu gdn c)a hai mui lZ
A. 7-VV[a v -7K-VV[a B. -7K-VV[a v -"7Q-VV[a
-. -K7/-VV[a v -!7N-VV[a ^. -"7Q-VV[a v -K7/-VV[a
C01 6. -ho hmn h?p * gIm ancol etylic v hmn h?p " a9it no, #n chec k; ti;p nhau trong W8y #Ing #ng, t+c
Wnng h;t v1i [a giqi ph$ng ra !,!2 l3t 7" U#ktcR. =Tt kh+c n;u #un n$ng hmn h?p * U9tZ 7"(V! #TcR thL c+c ch@t
trong hmn h?p * phqn eng vAa #) v1i nhau to thnh 0,"g hmn h?p este. -T-T thu gdn c)a " a9it lZ
A. 7-VV7 v -7K-VV7 B. -K7/-VV7 v -!7N-VV7
-. -7K-VV7 v -"7Q-VV7 ^. -07K-VV7 v -/7Q-VV7
C01 10. -ho /,0 gam -h@t * c'ng thec -!72V" t+c Wnng hon ton v1i DD ml Wung W,ch chea [aV7 ,Q= v
MV7 ,D=. (au phqn eng c' cn thu "D gam ch@t rjn. -'ng thec * l
A. 7-VVC-K7/ B. -"7Q-VV-7K -. -7K-VVC-"7Q ^. -K7/-VV7
C01 11Z Pt ch+y hon ton ",D gam hmn h?p gIm a9it acrylic, vinyl a9etat, metyl metacrylat. Ton :> sqn
phzm ch+y cho tua :Lnh #Jng 7"(V! #Tc th@y khi lH?ng :Lnh tSng m gam, :Lnh " #Jng -aUV7R" WH thu
#H?c N gam k;t t)a. m c$ gi+ tr, lZ
C01 127 -ho K,N" gam m>t este #n chec * t+c Wnng vAa #) v1i DDml MV7 D,!= thu #H?c 0,0 gam mui ..
A9it h$a . thu #H?c ch@t v. v c$ c'ng thec ph4n t lZ
A. -Q70V" B. -Q72VK -. -07"V" ^. -07"VK
C01 137 7ai este #n chec * v . l #Ing ph4n c)a nhau. Mhi h$a hi K,/ gam * , thu #H?c tho t3ch hi #rng
:<ng tho t3ch c)a ,! gam [" U #o X csng #i&u ki%nR. -T-T thu gdn c)a *, . lZ
A. -"7Q-VV-7K v -7K-VV-"7Q. B. 7-VV-K7Q v -"7K-VV-7K.
-. 7-VV-"7Q v -7K-VV-7K. ^. -"7K-VV-"7Q v -"7Q-VV-"7K.
C01 14. -ho ",2 gam ch@t hxu c A chk chea m>t loi nh$m chec t+c Wnng v1i l3t Wung W,ch [aV7 D,Q =,
thu #H?c "!,0 gam mui v D, mol ancol.-'ng thec c@u to thu gdn c)a A lZ
A. -K7/-VV-7K. B. -"7! U-VV-"7QR" -. U-"7Q-VVR"-"7! ^. U-7K-VVRK-K7Q
C01 127 7$a hi "/," gam m>t este * thu #H?c !,!2 l3t kh3 U tuy v& #ktcR. * phOng h$a * :<ng Wung W,ch
[aV7 U vAa #)R thu #H?c hmn h?p hai mui c)a natri.-'ng thec c)a este * l
A. -7K ~-VVC -07Q. B. -07Q ~ -VV ~ -7K.
-. -K7K ~ -VV ~ -!7Q. ^. -!7Q ~ -VV ~ -K7K.
C01 137 Pt ch+y hon ton m>t lH?ng este no, #n chec thL tho t3ch kh3 -V" sinh ra lu'n :<ng tho t3ch kh3 V"
cFn cho phqn eng U #o X csng #i&u ki%nR. -'ng thec c)a este lZ
A. -7K-VV-7K. B. 7-VV-"7Q. -. 7-VV-7K. ^. -7K-VV-"7Q.
C01 14. ste * kh'ng no, mch hX, c$ tk khi hi so v1i o9i :<ng K,"Q v khi tham gia phqn 9 phOng h$a to
ra m>t mui c)a a9it cac:o9ylic v m>t ch@t c$ khq nSng tham gia phqn eng tr+ng gHng. ( c'ng thec c@u to
phs h?p c)a * lZ
A. ". B. K. -. !. ^. Q.
C01 15. Th)y ph4n hon ton hmn h?p gIm hai este #n chec *, . l #Ing ph4n c@u to c)a nhau cFn DDml
Wung W,ch [aV7 =, thu #H?c /,2Q gam hmn h?p hai mui c)a hai a9it l #Ing #ng k; ti;p v !,NQ gam hai
ancol :c . -'ng thec c@u to v phFn trSm khi lH?ng c)a hai este l
A. 7-VV-7"-7"-7K /QG, -7K-VV-"7Q "QGB. 7-VV-"7Q !QG, -7K-VV-7K QQG
-. 7-VV-"7Q QQG, -7K-VV-7K !QG ^. 7-VV-7"-7"-7K "QG, -7K-VV-"7Q
/QG
C01 16. ste * c$ c'ng thec #n giqn nh@t l -"7!V. Pun s'i !,! gam * v1i "DD gam Wung W,ch [aV7 KG #;n
khi phqn eng hon ton. tA Wung W,ch sau phqn eng thu #H?c 2, gam ch@t rjn khan. -'ng thec c)a * lZ
A. -"7Q-VV-7K B. -7K-VV-"7Q -. 7-VV-7"-7"-7K ^. 7-VV-7U-7KR"
C01 20. Th)y ph4n !,K gam este * #n chec mch hX Uc$ 9rc t+c a9itR #;n khi phqn eng hon ton thu #H?c
hmn h?p hai ch@t hxu c . v v. -ho ., v phqn eng v1i Wung W,ch WH Ag[VKb[7K thu #H?c ",0 gam :c.
-'ng thec c@u to c)a * lZ
A. -7K-VV-7\-7" B. 7-VV-7\-7C-7K -. 7-VV-7"-7\-7" ^. 7-VV-U-7KR\-7"
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
C01 21. -ho hmn h?p * gIm ancol metylic v hai a9it cac:o9ylic Uno, #n chec, k; ti;p nhau trong W8y #Ing
#ngR t+c Wnng h;t v1i [a, giqi ph$ng ra 0,/" l3t kh3 7"U#ktcR. [;u #un n$ng hmn h?p * Uc$ 7"(V!#Tc lm 9rc
t+cR thL c+c ch@t trong hmn h?p phqn eng vAa #) v1i nhau to thnh "Q gam hmn h?p este Uhi%u su@t DDGR. 7ai
a9it trong hmn h?p * l
A. 7-VV7 v -7K-VV7. B. -7K-VV7 v -"7Q-VV7.
-. -"7Q-VV7 v -K7/-VV7. ^. -K7/-VV7 v -!7N-VV7.
U Trch TSH A 2010 R
C01 22Z * phOng ho+ hon ton ""," gam hmn h?p gIm hai este 7-VV-"7Q v -7K-VV-7K :<ng Wung
W,ch [aV7 = U#un n$ngR. Tho t3ch Wung W,ch [aV7 ti thiou cFn Wsng l
A. !DD ml. B. KDD ml. -. QD ml. ^. "DD ml.
C01 23Z * phOng ho+ hon ton /,"! gam ch@t :o cFn vAa #) D,D0 mol [aV7. -' cn Wung W,ch sau phqn
eng thu #H?c khi lH?ng 9 phOng l
A. 0,02 gam. B. 2,K2 gam. -. 2,"! gam. ^. /,2D gam.
C01 24! * phOng h$a 2,2 gam etyl a9etat :<ng "DD ml Wung W,ch [aV7 D,"=. (au khi phqn eng 9qy ra hon
ton, c' cn Wung W,ch thu #H?c ch@t rjn khan c$ khi lH?ng l Ucho 7 \ , - \ ", V \ 0, [a \ "KR
A. K,"2 gam. B. 2,Q0 gam. -. 2," gam. ^. D,! gam
C01 22. UT(P7 ~ B ~ "DDR7mn h?p * gIm a9it panmitic, a9it stearic v a9it linoleic. Po trung hOa m gam *
cFn !D ml Wung W,ch [aV7 =. =Tt kh+c, n;u #t ch+y hon ton m gam * thL thu #H?c Q,"K" l3t kh3 -V"
U#ktcR v ,/ gam 7"V. ( mol c)a a9it linoleic trong m gam hmn h?p * l
A. D,DQ. B. D,DD. -. D,D"D. ^. D,DDQ
C01 23Z UT(P7 ~ B ~ "DDR 7mn h?p v gIm hai a9it cac:o9ylic #n chec * v . U=* =.R c$ tng khi
lH?ng l 2," gam. -ho v t+c Wnng vAa #) v1i Wung W,ch [aV7, thu #H?c Wung W,ch chea ,Q gam mui. =Tt
kh+c, n;u cho v t+c Wnng v1i m>t lH?ng WH Wung W,ch Ag[VK trong [7K, thu #H?c ",0 gam Ag. -'ng thec v
phFn trSm khi lH?ng c)a * trong v l
A. -K7Q-VV7 v Q!,22G. B. -"7K-VV7 v !K,NDG.
-. -"7Q-VV7 v Q0,DG. ^. 7-VV7 v !Q,"G.
C01 24! 7mn h?p * gIm " a9it cac:o9ylic no, #n chec A,B. -ho "0,2 gam *ho tan hon ton vo nH1c rIi
chia lm " phFn :<ng nhauZ
C 5hFn Z 5hqn eng h;t v1i Wung W,ch Ag[VK trong [7K l@y WH, thu #H?c ",0 gam Ag kim loi.
C 5hFn "Z -Fn #rng DD ml Wung W,ch MV7 "= #o trung ho. TLm " a9it.
C01 25! 7mn h?p A gIm a9it v " anWehit, cq K #&u no, #n chec. i@y m gam A t+c Wnng h;t v1i Wung W,ch
Ag[VKb[7K #H?c Q!g Ag. ^sng "m gam A t+c Wnng v1i lH?ng WH Wung W,ch [a"-VK thu #H?c D,00 l3t -V".
=Tt kh+c phqi Wsng D,!/" l3t o9i m1i #) #o #t ch+y h;t m gam A. iH?ng a9it sau tr+ng :c c$ tho trung ho
#H?c QD ml Wung W,ch MV7 D,Q=. 78y cho :i;t -T5T, -T-T c)a c+c ch@t trong A. Bi;t c+c g kh3 #o X "/,K
D
-
v +p su@t atm. 7 \ DDG.
C01 26Z 7mn h?p * gIm hai a9it hxu c no, #n chec, mch hX. Trung ho 2,K gam * :<ng Wung W,ch [aV7
rIi c' cn Wung W,ch sau phqn eng thu #H?c ,0 gam mui khan. =Tt kh+c, n;u cho 2,K gam * t+c Wnng v1i
lH?ng WH Wung W,ch Ag[VK trong [7K thL thu #H?c ",0 gam :c. -'ng thec c)a " a9it lZ
A. 7-VV76 -"7Q-VV7 B. 7-VV76 -7K-VV7
-. -"7Q-VV76 -K7/-VV7 ^. -7K-VV76 -"7Q-VV7
C01 30! -ho hmn h?p gIm D, mol 7-VV7 v D," mol 7-7V t+c Wnng h;t v1i Ag[VK b[7K WH thL khi lH?ng
Ag thu #H?c l Z A. D2 g B. D,2 g -. 0!,2 g ^. 0,!2 g
C01 31Z -ho Q,/0 gam a9it hxu c #n chec t+c Wnng h;t v1i #+ v'i thu #H?c /,"2 gam mui. -ho :i;t tn a9it
trn
A. A9it a9etic B. A9it |omic -. A9it propionic ^. A9it acrylic
C01 32Z A l m>t hmn h?p c+c ch@t hxu c gIm m>t para|in, m>t rH?u #n chec v m>t a9it hxu c #n
che-.Pt ch+y hon m gam hmn h?p A :<ng m>t lH?ng kh'ng kh3 vAa #) Ukh'ng kh3 gIm
"DG V9i v 2DG [it theo tho t3ch.. -ho c+c ch@t sau phqn eng ch+y h@p thn vo :Lnh #Jng Wung W,ch
BaUV7R"

lH?ng WH. -$ "Q,!! l3t m>t kh3 tr tho+t ra U#kt-.v khi lH?ng :Lnh #Jng Wung W,ch BaUV7R"

tSng
thm /K,0 gam. Tr, s c)a m lZ
A. K/,/0 gam B. Mh'ng #) Wx ki%n #o t3nh -. "Q," gam ^. "2,2 gam
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
C01 33Z 7mn h?p * gIm rH?u #n chec v a9it #n chec. -hia * thnh K phFn :<ng nhauZ
C 5hFn Z t+c Wnng v1i [a WH th@y :ay ra Q,0 l3t 7" UPMT-R.
C 5hFn Z Pt ch+y hon ton thu "0,22 l -V" UPMT-R.
C 5hFn Z #un v1i a9it sun|uric #Tc thu #H?c "D,! gam este c$ tk khi so v1i nit l K,0!. *+c #,nh -T5T c)a
" rH?u a9it trong hmn h?p :an #Fu v khi lH?ng c)a chrng.
P(Z " T7
-"7QV7 v -"7Q-VV76 -K7/V7 v -7K-VV7
C01 34Z 7mn h?p gIm hai anWehit #n chec A v B #H?c chia thnh " phFn :<ng nhauZ
C 5hFn #un n$ng v1i Wung W,ch Ag[VKb[7K thL to ra D,2 gam Ag
C 5hFn " o9i ho+ to thnh hai a9it tHng eng sau #$ cho " a9it ny phqn eng v1i "QD ml Wung W,ch
[aV7 D,"0= #H?c Wung W,ch A. #o trung ho lH?ng [aV7 WH trong Wung W,ch A cFn Wsng #rng DD ml Wung
W,ch 7-l D,"Q=. c' cn Wung W,ch A, #em #t ch+y ch@t rjn c' cn to #H?c K,Q" gam -V" v D,N gam 7"V.
-T5T c)a " anWehit A v B lZ
A. 7-7V v -"7Q-7V B. 7-7V v -"7K-7V
-. 7-7V v -7K-7V ^. -7K-7V v -"7Q-7V
C01 32Z -h@t * l 7VCC-VV7 t+c Wnng v1i -uV, #un n$ng to ra anWehit. K,Q gam * t+c Wnng v1i [a"-VK
to ra 0,2 gam mui v -V". TLm c@u to c)a *.
A. -7KC-7UV7RC-VV7 B. -7KC-7UV7RC-7C-VV7
-. 7VC-7"C-7"C-VV7 ^. Mh'ng 9+c #,nh
C01 33! -ho D,D! mol m>t hmn h?p * gIm -7"\-7C-VV76 -7K-VV7 v -7"\-7C-7V phqn eng vAa #)
v1i Wung W,ch 0,! gam Brom. =Tt kh+c, #o trung ho D,D! mol * cFn Wsng vAa #) !D ml Wung W,ch [aV7
D,/Q=, Mhi lH?ng -7"\-7C-VV7 trong * lZ
A. ,!! B. ",22 -. D,/" ^. D,Q0
C01 347 7mn h?p * gIm a9it hxu c . no, #n chec v a9it hxu c v hai chec U. nhi&u hn v m>t nguyn t
cac:onR. -hia * thnh " phFn :<ng nhau. -ho phFn t+c Wnng h;t v1i [a, sinh ra D,"Q mol 7". Pt ch+y hon
ton phFn ", sinh ra D,/ mol -V". -T-T thu gdn v G khi lH?ng c)a v trong hmn h?p * l
A. 7VV-C-VV7 v /D,2/G B. 7VV-C-7"C-VV7 v "N,KG
-. 7VV-C-VV7 v QQ,!"G ^. 7VV-C-7"C-VV7 v /D,2/G
C01 35. 7ai este l #Ing ph4n c)a nhau Wo c+c a9it no #n chec v ancol no #n chec to thnh. Po 9 phOng
h$a ""," gam hmn h?p hai este phqi Wsng h;t " gam [aV7 nguyn ch@t. -+c mui thu #H?c c$ khi lH?ng ",2
gam. *+c #,nh -T-T c)a hai este E
C01 367 * l hmn h?p hai este l #Ing ph4n c)a nhau. csng #i&u ki%n lit hi * nTng g@p hai lFn lit V"
.Th)y ph4n KQ," gam * :<ng ! lit WW [aV7 D,"= #H?c WW . . -' cn WW. thu #H?c !!,0 gam ch@t rjn khan .
Bi;t hai este Wo ancol no #n chec v a9it no #n chec to thnh. *+c #,nh -T-T c)a c+c este E
C01 407 7mn h?p y l hai este #n chec mch hX l #Ing ph4n c)a nhau . -ho m gam . t+c Wnng vAa #) v1i DD
ml WW [aV7 D,Q= thu #H?c m>t mui v hmn h?p hai ancol. Pt ch+y hon ton m gam . cFn Q,0 lit V" !,!2 lit
-V" U#&u X #ktcR. *+c #,nh -T-T c)a hai este trong . E
C01 41. 7mn h?p gIm hai ch@t hxu c A , B csng chec. Pun K,0 gam v1i WW [aV7 thu #H?c sqn phzm
gIm m>t mui Wuy nh@t c)a m>t a9it #n chec ,kh'ng no v hmn h?p hai ancol no #n chec k; ti;p nhau . Pt
hon ton "/," gam cFn Wsng h;t KK,0 lit V" thu #H?c "N," lit -V" v 7"V U X csng #ktc R. *+c #,nh -T5T
c)a A v B E
C01 42. 7mn h?p * gIm " este #n chec A, B. -ho N,N gam hmn h?p * phqn eng v1i [aV7 vAa #) thL thu
#H?c "D,Q gam m>t mui v hmn h?p hai ancol #Ing #ng k; ti;p. -ho hmn h?p " ancol thu #H?c phqn eng v1i
[a WH thL th@y c$ ",2 l3t 7" U#ktcR. *+c #,nh -T-T c)a A, B.
C01 43. 7mn h?p * gIm " este #n chec A, B. Pun n$ng 0," gam hmn h?p * v1i [aV7 vAa #) thL thu #H?c
Q gam hmn h?p " mui c)a " a9it #Ing #ng k; ti;p v m>t ancol. Pt ch+y hon ton lH?ng ancol thu #H?c thL
th@y to ra /,0 gam -V" v D,2 gam 7"V. *+c #,nh -T-T c)a A, B.
C01 447 =>t hmn h?p * gIm hai ch@t hxu c A, B Uchea -, 7, VR #&u #n chec. -ho hmn h?p * phqn eng vAa
#) v1i DDml WW [aV7 Q= thu #H?c !K,2 gam hmn h?p hai mui c)a hai a9it no #n chec v m>t ancol no #n
chec . . -ho ton :> . t+c Wnng h;t v1i v1i [atri thu #H?c K,K0 lit 7" U#ktcR. *+c #,nh -T-T c)a A, B :i;t
=B\ =A B "2
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
C01 427 -ho K,! gam hmn h?p = gIm hai ch@t hxu c #n chec * , . U chk chea - ,7 ,V R t+c Wnng vAa #) v1i
! gam [aV7 thu #H?c mui c)a m>t a9it hxu c #n chec v N," gam m>t ancol. iH?ng ancol thu #H?c cho t+c
Wnng v1i [a WH th@y tho+t ra ","! lit kh3 7" U#ktcR. *+c #,nh -T-T c)a *, .
C01 43. 7mn h?p * gIm " ch@t hxu c #n chec. -ho D, mol hh * t+c Wnng vAa #) D, mol [aV7, c' cn
Wung W,ch sau phqn eng thu #H?c /,K0 gam hmn h?p mui v ancol .. V9i h$a hon ton ancol . :<ng -uV thu
#H?c an#ehit. -ho ton :> lH?ng an#ehit #$ t+c Wnng v1i Ag[VKb [7K thu #H?c "Q,N" gam Ag. *+c #,nh c'ng
thec c)a " ch@t trong hmn h?p *.
C01 44. Pt ch+y ,0 gam m>t este * #n chec thu #H?c K,Q" gam -V" v ,Q" gam 7"V. -ho D gam * t+c
Wnng v1i Wung W,ch [aV7 UvAa #)R, c' cn Wung W,ch sau phqn eng thu #H?c ! gam mui khan .. -ho . t+c
Wnng v1i a9it v' c lo8ng thu #H?c v kh'ng ph4n nh+nh. *+c #,nh c'ng thec c@u to c)a v
C01 45. Th)y ph4n este #n chec no :<ng Wung W,ch [aV7 thu #H?c mui khan c$ khi lH?ng ph4n t :<ng
"!b"N khi lH?ng ph4n t .Tk khi hi c)a #i v1i kh'ng kh3 :<ng !. *+c #,nh -T-T c)a .
C01 46. -ho D, mol este * #n chec vo DD gam Wung W,ch [aV7 2G, #un n$ng #o phqn eng th)y ph4n hon
ton thu #H?c D gam Wung W,ch. -' cn Wung W,ch sau phqn eng thu #H?c !,2 gam ch@t rjn khan. 78y cho
:i;t * c$ tho c$ :ao nhiu c'ng thec c@u to E
C01 207 Pun n$ng D gam este * #n chec v1i "DD ml Wung W,ch [aV7 ,Q= Ul@y WHR. -' cn Wung W,ch sau
phqn eng thu #H?c ch@t rjn c c$ khi lH?ng /,!g v m>t ancol .. P& hi#rat h$a . thu #H?c ","! l3t anken.
U7i%u su@t t+ch nH1c #t DDGR. *+c #,nh -T-T c)a *
C01 21. Mhi cho D,Q mol este #n chec * t+c Wnng v1i Wung W,ch [aV7 UWHR, sau khi phqn eng k;t thrc thL
lH?ng [aV7 phqn eng l " gam v tng khi lH?ng sqn phzm hxu c thu #H?c l "N,/ gam. *+c #,nh -T-T
c)a *
C01 22. Pun n$ng h?p ch@t * v1i 7"V U9rc t+c 7
B
R #H?c a9it hxu c . v ancol v #n chec. -ho hi v #i tua ng
#Jng -uV, t
D
#H?c h?p ch@t T c$ khq nSng tham gia phqn eng tr+ng :c. Pt ch+y hon ton ",2 gam * phqi Wsng h;t
K,N" l3t o9i UX #ktcR, #H?c kh3 -V" v hi nH1c theo tk l% tho t3chZ
" "
-V 7 V
g Z g KZ " =
. Bi;t
"
.
[
W ", Q/ =
.
C01 237 =>t este #n chec * :i;t W*bV" \ K,"Q . *+c #,nh -T-T c)a * trong mmi trHlng h?p sauZ
a. "D gam * t+c Wnng v1i KDD ml WW [aV7 = . -' cn WW sau phqn eng thu #H?c "K," gam :8 rjn.
:. D.Q mol * t+c Wnng vAa #) v1i WW [aV7 . -' cn WW sau phqn eng thu " gam mui khan U mch
kh'ng nh+nh R
Chuyn ?;: %1in6 %1ino%7it
C01 1! -ho W8y chuyon h$aZ cly9in
+[aV7
*
+7-l
. 6
cly9in
+7-l
v
+[aV7
T.
. v T lFn lH?t lZ
A. #&u l -l7K[-7"-VV[a B. -l7K[-7"-VV7 v -l7K[-7"-VV[a
-. -l7K[-7"-VV[a v 7"[-7"-VV[a ^. -l7K[-7"-VV7 v 7"[-7"-VV[a
C01 2! -ho :i;t s amin :c c)a -!7[Z
A. B. " -. K ^.!
C01 3! -/7N[ c$ :ao nhiu #Ing ph4n thmE
A. K B. ! -. Q ^. 0
C01 4! -K7N[ co :ao nhiu #'ng ph4n aminE
A. " B. K -. ! ^. Q
C01 2! -ho -T-TZ -7K[7-"7Q goi tn theo Wanh phap thay thE
A. tyl metyl amin B. [C =etyl etan amin
-. [C etyl metan amin ^. [, [C Pi metyl amin
C01 3! 5hqn eng no sau #4y c)a anilin kh'ng 9qy ra Z
A. -07Q[7" B 7"(V! B. -07Q[7K-l B [aV7 UWWR
-. -07Q[7" B Br"UWWR ^. -07Q[7" B [aV7.
C01 4! 5hHng trLnh ch+y c)a amin -n7"nBK[, ce mol amin trn cFn Wsng lH?ng '9y lZ
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
A. U0nBKRb! B. U"nBKRb" -. U0nBKRb" ^. U"nBKRb!.
C01 5! Mhi cho etylamin vo Wung W,ch ]e-lK ,hi%n tH?ng no 9qy ra c$Z
A. kh3 :ay ra B. k;t t)a mu #p n4u
-. kh3 msi khai :ay ra ^.Mh'ng hi%n tH?ng gL.
C01 6! (jp 9p nao sau #4y la #ungE
A. -07Q[7" -"7Q[7" B. -7K[7" [7K -"7Q[7"
-. -"7Q[7" -7K[7" -07Q[7" ^. -07Q[7"-7K[7" [7K
C01 10! -'ng thec chung c)a amin no #n chec, mch hX lZ
A. -n7"nB[ B. -n7"nB[7" -. -n7"nBK[ ^. -97y[
C01 11! -h@t tham gia phqn eng trsng ngHng l
A. -"7QV7. B. -7" \ -7-VV7. -. 7"[-7"-VV7. ^. -7K-VV7.
C01 12! Po nhn :i;t K ch@t hxu c 7"[-7"-VV7, 7VV--7U[7"R-VV7, 7"[-7U[7"R-VV7, ta chk cFn
th v1i m>t trong c+c ch@t no sau #4yZ
A. [aV7 B. 7-l -. wsy t3m ^. -7KV7b7-l
C01 13! -ho c+c ch@tZ etyl a9etat, anilin, ancol UrH?uR etylic, a9it acrylic, phenol, phenylamoni clorua, . Trong
c+c ch@t ny, s ch@t t+c Wnng #H?c v1i Wung W,ch [aV7 l
A. !. B. 0. -. Q. ^. K.
C01 14! -ho c+c loi h?p ch@tZ aminoa9it U*R, mui amoni c)a a9it cac:o9ylic U.R, amin UvR, este c)a
aminoa9it UTR. ^8y gIm c+c loi h?p ch@t #&u t+c Wnng #H?c v1i Wung W,ch [aV7 v #&u t+c Wnng #H?c v1i
Wung W,ch 7-l l
A. *, ., v, T. B. *, ., T. -. *, ., v. ^. ., v, T.
C01 12! ThJc hi%n phqn eng trsng ngHng " aminoa9it Z cli9in v Alanin s #ipept3t thu #H?c ti #a lZ
A. B." -.K ^.!
C01 13! Mhi th)y ph4n tripeptit 7"[ ~-7U-7KR-VC[7C-7"C-VC[7C-7"C-VV7 s to ra c+c aminoa9it
A. 7"[-7"-VV7 v -7K-7U[7"R-VV7 B. 7"[-7"-7U-7KR-VV7 v 7"[-7"-VV7
-. 7"[-7U-7KR-VV7 v 7"[-7U[7"R-VV7 ^. -7K-7U[7"R-7"-VV7 v 7"[-7"-VV7
C01 14! Po cheng minh t3nh lHyng t3nh c)a [7"C-7"C-VV7 U*R , ta cho * t+c Wnng v1i
A. 7-l, [aV7. B. [a"-VK, 7-l. -. 7[VK, -7K-VV7. ^. [aV7, [7K.
C01 15! =ot amino a9it cos co4ng thsc pha4n t la -!7N[V". (o+ ong pha4n amino a9it la
A. K B. ! -. Q ^. 0
C01 16! -ho N,2Q gam hmn h?p " amin #n chec, :c m>t t+c Wnng vAa #) v1i Wung W,ch 7-l thu #H?c
2,N/Q g mui. Mhi lH?ng c)a 7-l phqi Wsng lZ
A. N,Q"g B. N,"Qg -. N,"Qg ^. N,Q"g
C01 20! Pt ch+y m>t amin no #n chec * thu #H?c -V" v 7"V v1i tk l% mol "ZK. * lZ
A. tyl amin B. tyl metyl amin -. Trietyl amin ^. B v - #&u #rng
C01 21! =>t amin no #n chec * c$ thnh phFn G v& [ l "K,/KG theo khi lH?ng. * lZ
A. -7K[7" B. -"7Q[7" -. -K7/[7" ^. -K7Q[7"
C01 22! Po trung ho K,g m>t amin #n chec cFn DDml Wung W,ch 7-l =. Amin #$ lZ
A. -7Q[ -. -K7N[ B. -"7/[ ^. -K7/[
C01 23! -ho /,0 g hh hai amin #n chHc, :4c m't k tip nhau, tac Wung vH a #u vi "DDml WW 7-l =.
-T-T cu a hai amin trn la
A. -7K[7", -7K[7-7K, B. -7K[7", -"7Q[7"
-. -"7Q[7",-K7/[7" ^. P+p +n kha c
C01 24! -ho D, mol * UCamino a9it Wng 7"[-VV7R phqn eng h;t v1i 7-l to ,Q gam mui. * lZ
A. cly9in B. Alanin -. 5henylalanin ^. galin
C01 22! -ho Camino a9it mch thng * c$ c'ng thec 7"[U-VV7R" phqn eng h;t v1i D, mol [aV7 to
N,QQ gam mui. * lZ
A. A9it "Caminopropan#ioic B. A9it "Camino:utan#ioic
-. A9it "Caminopentan#ioic ^. A9it "Caminohe9an#ioic
C01 23! Pt ch+y hon ton amol m>t aminoa9it * #H?c "a mol -V" v ",Qa mol nH1c. * c$ -T5T lZ
A. -"7Q[V! B. -"7Q["V" -. -"7Q[V" ^. -!7D["V"
C01 24! D, mol aminoa9it * phqn eng vAa #) v1i DDml Wung W,ch 7-l "=. =Tt kh+c2g * c{ng phqn eng
vAa #) v1i "DDml Wung W,ch 7-l trn. * c$ khi lH?ng ph4n t l
G#$% &#'(! L)# *( L%(+ T,-.(+ THPT L' H%/(
A. "D B. ND -. 0D ^. 2D
C01 25! -ho c+c Wung W,ch Z UR 7"[-7"-VV7 6 U"R -l7K[C-7"-VV7 6
UKR 7"[-7"-VV[a 6 U!R 7"[_-7"`"-7U[7"R-VV7 6 UQR 7VV-_-7"`"-7U[7"R-VV7
( Wung W,ch lm tu- t3m h$a #p lZ
A. UKR B. U"R -. UR, U!R ^. U"R, UQR
C01 26! (jp 9;p c+c h?p ch@t sau theo the tJ giqm WFn t3nh :aaZ
UR -07Q[7" 6 U"R -"7Q[7" 6 UKR U-07QR"[7 6 U!R U-"7QR"[7 6 UQR [aV7 6 U0R [7K
A. UQR U!R U"R U0R UR UKR B. UQR U!R U"R UR UKR U0R
-. UR UKR UQR U!R U"R U0R ^. U0R U!R UKR UQR UR U"R.
C01 30! T3nh :aa c)a c+c ch@t tSng WFn theo the tJZ
A. [7K -7K-7"[7" -7K[7-7K -07Q[7"
B. [7K -07Q[7" -7K[7-7K -7K-7"[7"
-. -07Q[7" [7K -7K[7-7K -7K-7"[7"
^. -07Q[7" [7K -7K-7"[7" -7K[7-7K
C01 31! -$ c+c Wung W,ch ring :i%t sauZ -07QC[7K-l UphenylamonicloruaR, 7"[-7"-7"-7U[7"R-VV7,
-l7K[C-7"C-VV7, 7VV--7"C-7"C-7U[7"RC-VV7, 7"[C-7"C-VV[a.
( lH?ng c+c Wung W,ch c$ p7 / l
A. ". B. Q. -. !. ^. K.
C01 32! ng v'si co4ng thsc -!7[ cos so+ ong pha4n amin :ac " laZ
A. K. B. !. -. Q. ^. 0.
C01 33! [hn :i;t :a Wung W,ch chea :a ch@t gli9in, metylamin, a9it a9tic ngHli ta WsngZ
A . wu- t3m B . ^ung W,ch [aV7
- . ^ung W,ch 7-l ^ . T@t cq #&u #rng.
C01 34! Pi&u khng #,nh no sau #4y kh'ng #rngZ
A . -+c aminoa9it #&u tan #H?c trong nH1c.
B . 5h4n t lH?ng c)a m>t aminoa9it chea m>t nh$m ~[7" v m>t nh$m ~-VV7 lu'n l s l.
- . Th)y ph4n protein trong m'i trHlng a9it thu #H?c hmn h?p c+c aminoa9it.
^ . -+c Wung W,ch chea c+c amino a9it #&u lm #i mu tu- t3m.
C01 32! coi tn -T-TZ -7K-7"-7U[7"R-VV7 theo Wanh phap thay th
A. A9it "Camino :utanoic B. A9it "C amino propionic
B. A9it KCamino :utiric ^. A9it "C amino :utiric
C01 33! ng v i -T5T -!7N[V" co :ao nhiu amino a9it la #'ng ph4n cua nhauE
A. K B. ! -. Q ^. 0
C01 34! -'ng thHc nao sau #4y #ung v i tn go iZ A9it "Camino propanonic
A. 7"[-7"-VV7 B. 7VV--7"-7"[7"
-. -7"C-7U[7"R-VV7 ^. -7K-7U[7"R-VV7
C01 35! A9it amino a9etic tac Wung #Hc :ao nhiu ch4 t cho WH i #4yZ U#i&u ki%n co #uR [aV7, [a, -7K-7V,
-7KV7, 7"(V!
A. " B. K -. ! ^. Q
C01 36! Pt ch+y hon ton hmn h?p " amin no, #n chec, mch hX #Ing #ng lin ti;p, ta thu #H?c tk l% tho
t3ch
"
"
Q
2
CO
H O
V
V
=
UX csng #i&u ki%nR. -'ng thec c)a " amin l
A. -7K[7" , -"7Q[7" B. -K7/[7" , -!7N[7"
-. -"7Q[7" , -K7/[7" ^. -!7N[7" , -Q7[7"
C01 40! -ho N,K gam ankyl amin t+c Wnng v1i WW ]e-lK WH thu #H?c D,/ gam k;t t)a. ankyl amin l
A. -7K[7" B. -"7Q[7" -. -K7/[7" ^. -!7N[7"
C01 41! -ho lH?ng WH anilin phqn eng v1i WW chea D,DQ mol 7"(V! lo8ng, lH?ng mui thu #H?c :<ngZ
A. "2,! gam B. 2,2 gam -. N, gam ^. !," gam
C01 42! * l m>t Caminoa9it mch thng chk chea m>t nh$m ~[7" v m>t nh$m C-VV7. -ho D,K gam *
t+c Wnng v1i WW 7-l WH thu #H?c K,NQ gam mui clorua c)a *. -T-T thu gdn c)a * lZ
A. -7K-7U[7"R-VV7 B. 7"[-7"-VV7
-. 7"[-7"-7"-VV7 ^. -7K-7"-7U[7"R-VV7
25
T:;(: <=(+>?& @:%; :A; HBHTN-HCGHNhiuy%n thi #i hdc h$a hdc nSm hdc "D"C"DK. =di thjc
mjc v& #& :i 9in lin h% s#t 065722273233 hoTc #,a chk eCmail :vtn.tb@g1%il.co1
C01 43! -ho /,Q gam a9it aminoa9etic U7"[C-7"C-VV7R phqn eng h;t v1i Wung W,ch [aV7. (au phqn eng,
khi lH?ng mui thu #H?c l U-ho 7 \ , - \ ", V \ 0, [a \ "KR
A. ,DQ gam. B. N,2 gam. -. /,Q gam. ^. N,/ gam.
C01 44! Pt ch+y h;t amol aminoa9it * :<ng V9i vAa #) rIi ngHng tn hi nH1c #H?c ",Qa mol hmn h?p -V"
v [". -'ng thec ph4n t c)a * lZ
A. -"7Q[V" B. -K7/[V" -. -K7/["V! ^. -Q7[V"
C01 42! D,Dmol aminoa9it * t+c Wnng vAa #) v1i QDml WW 7-l D,"=. -' cn WW sau phqn eng #H?c ,2KQg
mui khan. Mhi lH?ng ph4n t c)a * l Z
A. 2N B. DK -. / ^. !/
C01 43! ste * #H?c #i&u ch; tA

Camino a9it v ancol metylic. Tk khi hi c)a * so v1i hiWro :<ng !!,Q.
-'ng thec c@u to c)a * lZ
A. -7K~-7U[7"R~-VV-7K. B. 7"[C-7"-7"C-VV7
-. 7"[~-7"~-VV-7K. ^. 7"[~-7"~-7U[7"R~-VV-7K.
C01 44! -ho W8y c+c ch@tZ -07Q[7" UanilinR, 7"[-7"-VV7, -7K-7"-VV7, -7K-7"-7"[7", -07QV7
UphenolR. ( ch@t trong W8y t+c Wnng #H?c v1i Wung W,ch 7-l l
A. !. B. ". -. K. ^. Q.
C01 45! ( #Ing ph4n tripeptit to thnh tA ph4n t gly9in v " ph4n t alanin l
A. ". B. K. -. Q. ^. !.
C01 46! TA gly9in UclyR v alanin UAlaR c$ tho to ra m@y #ipeptitE
A. B. " -. K ^. !
C01 20! cli9in kh'ng t+c Wnng v1i
A. 7"(V! lo8ng. B. -a-VK. -. -"7QV7. ^. [a-l.