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Code No: C5101
JAWAHARLAL NEHRU TECHNOLOGICAL UNIVERSITY HYDERABAD
M.Tech I SEMESTER EXAMINATIONS, APRIL/MAY-2013
ADVANCED CHEMICAL ENGINEERING THERMODYNAMICS
(CHEMICAL ENGINEERING)
Time: 3hours Max.Marks:60
Answer any five questions
All questions carry equal marks
- - -

1. Derive Maxwell relations from first principles and how they are useful in
determining thermodynamic properties.

2. What is phase equilibria? Derive the criteria for multicomponent multi phase
equilibrium.

3.a) Differentiate between statistical and classical thermodynamics.
b) Write about the canonical ensemble.

4.a) Explain Mies potential- energy function for non-polar molecules.
b) What is molecular theory of corresponding states?

5. What is LLE? Describe about LLE with neat diagram.

6. Explain Scatchard - Hildebrand theory to find activity coefficients.

7. Derive the relation between the standard Gibbs-energy change and the
equilibrium constant, K RT G ln =
.

8.
Discuss the following:
a) lattice models
b) Exergy analysis of a process.




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