IIT 2009

CHEMISTRY
1.Ethanol containing some methanol is called
a) absolute spirit b) rectified spirit c) power alcohol d)
methylated spirit
2.Glycerol is a
a) primary alcohol b) monohydric alcohol c) secondary
alcohol d) trihydric alcohol
3.Which of the following can work as a dehydrating agent for alcohols?
a) 2!"# b) $l2"3 c) 3%"# d) all
#.%rimary and secondary alcohols on action of red hot copper gi&e
a) aldehydes and ketons respecti&ely b) ketones and aldehydes
respecti&ely c) only aldehydes d) only ketones
'.Which of the following groups will increase the acidity of phenol?
a) ("2 b) )( c) *halogens d) all
+.)2'" can be differentiated from )3" by
a) reaction with )l b) reaction with (3 c)
,odoform test d) solubility in water
-.Which of the following compound does not react with metallic sodium?
a) )3)")3 b) )3")3 c) )3)"" d)
)2'"
..Grignard reagent on reaction with acetone forms
a) tertiary alcohol b) secondary alcohol c) acetic acid
d) acetaldehyde
/.Which of the following does not gi&e yellow ppt.with ,2(a"?
a) )2'" b) )3)" c) )3)")3 d)
)"
10.Which of the following statements is correct?
a) phenol is less acidic than ethyl alcohol b) phenol is more acidic than
ethanol c) phenol is more acidic than carbonic acid d) phenol is more acidic
than )3)""
11.Which one has highest boiling point?
a) 1utan222ol b) Ethane c) 1utane d)
%entane
12.)on&ersion of ethyl alcohol into acetaldehyde is an e3ample of
a) reduction b) molecular rearrangement c)
hydrolysis d) o3idation
13.When wine is put in air4 it becomes sour due to
a) 1acteria b) "3idation of )2'" into )3)"" c)
&irus d) 5ormic acid formation
1#.,n the 6ibermann7s nitroso reaction4 se8uential changes in the colour of phenol occurs as
a) 1rown or redgreen deep blue b) 9ed deep blue green c)
9ed green white d) White red green
1'.Glycerol4 on heating with o3alic acid at 110) gi&es
a) Ethanol b) :ethanoic acid c) Ether d)
$cetone
1+.%henol gi&es ...........colour with neutral 5e)l3 solution
a) &iolet b) green c) red d) blue
1-.Which of the following has ma3imum hydrogen bonding?
a) ethyl amine b) ammonia c) ethyl alcohol d)
diethyl ether
1..Which of the following is the most suitable method for remo&ing the traces of water from ethanol?
a) eating with (a metal b) %assing dry )l through it c)
;istilling it d) 9eacting with :g.
1/.Which of the following is most acidic
a) phenol b) ben<yl alcohol c) m2 chlorophenold)
cyclohe3anol
20.$ fruity smell is obtained by the reaction of ethanol with
a) %)l' b) )3)")3 c) )3)"" d)
none of these
21.!il&er mirror is a test for
a) aldehydes b) thioalcohols c) acids d)
ethers
22.,n )anni<<aro7s reaction
a) aldehyde is con&erted into alcohol b) alcohol is con&erted into
aldehyde c) a primary amine is con&erted into isocyanide d)
aldehyde is con&erted into alcohol and sodium carbo3ylate
23.$ldehydes may be distinguished from ketones by the use of
a) )onc.2!"# b) 5ehling solution c) %yrogallol d)
Grignard7s reagent
2#.,n public urinals4 we obser&e some nascent smell. =his smell is due to
a) hydrolysis of urea of urine by urease of atmosphere into (3and )"2 b)
formation of sulphamic acid by urea of urine c) reaction of )"2 of atmosphere
with urea mononitrate in urine d) hydrogen present in air reacts with nitrogen forming (3
2'.,dentify > in the series ) 2 ) 2 1r * ydrolysis ? l 2 e3cess (a 2 )" 3
a) )2', b) )2'" c) ),3 d)
)3)"
2+.$ldehydes can be distinguished from ketones by using
a) !chiff7s reagent b) )onc.2!"# c) $nhy.>n)l2 d)
9esorcinol
2-.Which of the following gi&es iodoform on heating with a solution of ,2 containing (a2)"3?
a) ethyl alcohol b) acetonec) ethyl alcohol as well as acetone
d) methyl alcohol
2..1en<yl alcohol is obtained from ben<aldechyde by
a) 5itting7s reaction b) )lemenson7s reduction c) @olbe7s
reactiond) 9eduction with 6i$l#
2/.aloform reaction can be used for preparing
a) alogens b) ))l# c) ))l3 d) alides
30.Ethyl alcohol n o3idation with @2)r2"- gi&es
a) $cetic acid b) $cetaldehyde c) 5ormaldehyde d)
5ormic acid
31.eating a mi3ture of sodium ben<oate and soda lime gi&es
a) :ethane b) 1en<ene c) !odium ben<oate
d) )alcium ben<oate
32.Which of the following is least acidic?
a) )2'" b) )3)"" c) )+'" d)
)l)2)""
33.$mong the following the strongest acid is
a) )3)"" b) )2)l)2)"" c) )2)l)""
d) )3)2)""
3#.Ethyl alcohol reacts with acetyl chloride to form
a) Ethyl chloride b) $cetic acid c) :ethyl acetate d)
Ethyl acetate
3'.Which of the following statement about ben<aldehyde is not true?
a) reduces =ollen7s reagentb) undergoes $ldol condensation c)
undergoes )anni<<aro7s reaction d) forms an addition compound with
sodium hydrogen sulphite
3+.$cyl halide is formed by reacting %)l' with
a) $lcohol b) Ester c) $mide d) 1oth carbo3ylic
acids as well as esters
3-.5ormation is an a8ueous solution of
a) 5urfural b) 5luorescein c) 5ormaldehyde d)
5ormic acid
3..5rom the following &alues of dissociation constants of four acids which &alue represents the strongest
acid?
a) 2102 b) 0.02101 c) 310# d) 210#
3/.)yanohydrin of which of the following forms lactic acid
a) )" b) )3)")3 c) )3)" d)
)3)2)"
#0.%araaldehyde is a trimer of
a) 5ormaldehyde b) $cetaldehyde c) 1en<aldehyde d)
%ropionaldehyde
#1.,f ( and ! elements are presentin organic compound4 then during 6assaigne7s test both change into
a) (a2! and (a)( b) (a!)(c) (a2!"3 and (a2)"3
d) (a2! and (a)("
#2.=he type of isomerism e3hibited by)+'))+'() is
a) positionb) functional c) enantiomerism d)
functional as well as tautomerism
#3.;ye test can be used to distinguish between
a) Ethylamine and acetamide b) Ethylamine and aniline c)
Area and acetamide d) :ethylamine and ethylamine
##.$niline on heating with conc.("3B conc.2!"# mi3ture yields
a) o2 and p2(itroanilines b) m2(itroaniline c) $ black tarry
matter d) (o reaction
#'."n reduction secondary amine is gi&en by
a) nitroben<ene b) methyl cyanide c) nitroethane d)
methyl isocyanide
#+.,n the presence of acid4 the hydrolysis of methyl cyanide gi&es
a) methanoic acid b) ethanoic acid c) methylamine d)
methyl alcohol
#-.Gabriel synthesis is used for the preparation of
a) 1 $romatic amines b) 1 $liphatic amines c) 2
$mines d) =ertiary amines
#..9eduction of nitroben<ene in the presence of >nC(#)l gi&es
a) ydra<oben<ene b) (2%henyl hydro3ylamine c)
$niline d) $<oben<ene
#/.%rimary and secondary amines can be distinguished by
a) 1r2C@" b) )l" c) ("2 d) (3
'0.Which of the following is produced by reaction of 9)( in sodium and alcohol?
a) 9)"(2 b) 9)""(# c) 9)2(2 d)
9)23(2