Quang ph Raman

1. Gii thiu
Quang ph Raman l mt phng
tin:
Nhn din qu
X l qu.
Nguyn l
Phn tch nh sng pht ra t mu
vt khi chiu chm tia.
Vic s dng laser cho php phn
tch thnh phn cu to mu vt rt
nh.
L k thut tn x nh sng chn
on c cu bn trong ca phn t v
tinh th.
L qu trnh tn x khng n hi
gia phtn v mt lng t dao
ng mng sau va chm nng lng
phtn gim i hoc tng ln.
Phng php nghin cu
Phng php c in:
Phn tch bng knh hin vi
o ch s khc x
Tm ra ph hp th ca cc phin ...
Cc xt nghim c thc hin ch
yu trn cc khong vt
Quang ph k UV-VIS, FTIR, ED-XRF
l nhng phng php v m cung
cp thng tin v v b mt ca .
Quang ph k Raman:phng php
nghin cu qu hin i vi knh
hin vi, h ng tiu cho php phn
tch cc v tr bn di ca mu.
S kt hp: - vi quan st
- phn tch Raman
To nn phng php vi phn tch
Raman c bit hu ch gip xc nh
tnh xc thc, ngun gc ca qu
v cc vt nt trong ngc.
Da vo ph thu c ta c thng tin
v mc nng lng dao ng ca
nguyn t, phn t hay mng tinh
th.
Cc mc nng lng ny l c trng
dng phn bit nguyn t ny vi
nguyn t khc.
Khuyt im
Xc xut xy ra tn x Raman rt nh
quan st phi tng cng vch
Raman v tch vch Raman ra khi
vch chnh bng php bin i
Fourier.
cng vch ln dng phng
php cng hng CARS hay SERS
2. Quang ph k Raman
Cu to
My quang ph Raman Renishaw
1000
My d CCD Peltier
Laser 514nm cng sut 25mW
Cc thu knh c phng i x5,
x10, x20 v x50
phn gii 2cm
-1
.
3. ng dng
Ngi ta thng a vo cc khong
trng cc cht t nhin tng cng
mu sc ca ngc.
Cht s dng bao gm: nha thng,
nha tng hp epoxi, nha nhn
to... iu ny i hi mt phng
php nhn bit cc cht.
4. Quang ph Raman ca cc
cht ph
Cht hu c s dng n vo
c ghi ph gm 42 mu c m t
vi quang ph Raman v lu gi
so snh gm: du, sp, nha,nha
epoxi, opticon, palma, cht liu mi
gi l permasafe..
Tnh cht quang ca ngc c lin
quan n cc cht n.
Mu ph chun

Ph cho thy cc cc tr khc nhau
ph thuc thnh phn ha hc.
C mt s bin i cng nh do
s lo ha v tin trnh oxi ha. nh
chnh thc ca ph vng bc sng
thp 1.441cm
-1
, 1.455cm
-1
v
1.666cm
-1
.
Ph tiu biu

5. Xc nh cht n trong ngc
bng ph Raman

Nhn xt
C mt s nh khc bit gia cc dng ph
Crom cha trong ngc c th cho hunh
quang vo khong 2.500cm
-1
mc ny c
mt s nh ca nhng cht ph gia 2.700
v 3.100cm
-1
.
Hnh 3:s khc nhau gia ph ca ngc
bch,nha epoxi v opticon.
Hnh 4:khi gp mt vt nt ph c th thay
i ph thuc vo mc nhiu hay t v
ngc cha nha c mt dng ph khc

6. Nhn bit ngc i mu
x l
Sp, nha..c a vo ngc to mu
sc phong ph v n nh. iu ny c
thc hin trn ngc xp hoc ngc trng.
Ngc trng cht lng thp c th x l
bng mt mu sp hoc du c mu
xanh mong mun.
S khc bit gia ngc A (khng ch bin),
B (ngm tm vi cht khng mu) v C
(ngm tm vi cht mu) c nhn dng
vi ph Raman.

7. nh hng ca p sut, nhit
ln x l kim cng
Kim cng khng mu c iu ch p
sut v nhit cao vic iu ch ch hiu
qu trn kim cng loi II.
Kim cng loi II cha mt s lng thp
nit khng b pht hin bi ph hng ngoi,
trong sut di nh sng t ngoi bc sng
254nm, lm gim mu sc ca kim cng
lm chng dng nh khng mu bng cch
x l nhit trn 1960
o
C.
Phng php nhn dng l so snh ph
cc loi vi quang ph Raman.

Mu c lm lnh nit lng, cho php chiu tia laser
v iu chnh nhit trong thi gian iu ch, cc
php o cho thy nhit dao ng t -170
o
C n -
196
o
C
Cng b kim cng khng mu u tin vo nm
1999, nghin cu c thc hin nhit phng
theo cc bo co nh ph 637nm -575nm, cng
ph 1.332cm
-1

8. Phn tch Raman ca ngc
mu nhn to v san h
Ngc trai en t nhin him hn ngc trai
trng do gi tr cao hn v cn thit phi
sn xut gi
Ngc c ngm trong AgNO
3
to mu en.
iu ny c th nhn thy bng ph Raman,
ngc trai nhum vi AgNO
3
hin th 1 nh
240cm
-1
khng c trong ngc trai en t
nhin.
Cc chiu x v thuc nhum hu c cng
c dng nhiu; ngc trai c mu en t
nhin c vng nh thp hn ngc trai en
nhn to do hunh quang Raman cao ca
cht hu c.

-San h
San h t nhin rt t c mu v hng c dng
nhiu trong trang sc
mu ca san h c t carotenoid, cht c cha 100
sc t mu t vng n tm thy trong cy c cng
thc C
40
H
50
.
Do him,gi tr cao cng vi lut bo v nhiu quc
gia, san h nhum ngy cng xut hin nhiu
quang ph Raman l phng php tch cc cho php
phn bit mu gi vic xc nh da trn ph ca
caroten, nh ph ca caroten khong 1.130cm
-1
v
1.520cm
-1,
thuc nhum c nh gia 1.200cm
-1
v
1.650cm
-1
.

Tm li:
Cc v d c chn lm ni bt
ng dng ca phn tch Raman trong
phn tch qu,san h..nh vo:
-kh nng phn bit cc loi cht
hu c
-ph Raman rt nhy i vi vic
thay i cc cu trc trong tinh th