[1] Redox reaction vale package ke level -2 objective ka 1st question... {page no.

57}


Answer:

Notice that H, O and K have fixed valency in this case. Only oxidation number of carbon can
change
KHC
2
O
4
. HC
2
O
4
.2H
2
O is acting as a reducing agent therefore it will get oxidized. Thus Balance
the equation with respect to carbon, because only carbon will undergo change in oxidation state
from +3 to +4


KHC
2
O
4
. HC
2
O
4
.2H
2
O ------> 4 CO
2


O.N. of C = +3 x 4 =12 O.N. of C = +4 x 4 = +16

Change in oxidation number = n-factor = 16 12 = 4

Equivalent weight = M/n-factor
= M/4



[2] how fast is the electron travelling moving if its wavelength equal to the distance it travels in
one second??


Answer:

= distance travelled in 1 second = V
n
= 2r
n
/ time period


In terms of V
n
youll get

V
n
= 2.18 x 10
8
z/n cm/s












[3] calculate the the equivalent weight of K4[FE(CN)6} in the following reation-

K4[Fe(CN)6] ---- 4 K
+1
+ Fe
+3
+ 6 CO2 + 6 NO
3

-1


O.N. of K = +1 x 4 = 4 O.N. of K = +1 x 4 = 4
O.N. of Fe = +2 O.N. of Fe = +3
O.N. of C = +2 x 6 = 12 O.N. of C = +4 x 6 = 24
O.N. of N = -3 x 6 = - 18 O.N. of N = +5 x 6 = 30

Change in O.N. of K = 4 4 = 0
Change in O.N. of Fe = 3 2 = 1
Change in O.N. of C = 24 - 12 = 12
Change in O.N. of N = 30 ( -18) = 48

Total change in O.N = 1 + 12 + 48 = 61
Equivalent weight of K
4
[Fe(CN)
6
] = M/61