Cu 1.

Cho 2 hidrocacbon X v Y l ng ng ca nhau, phn t khi ca X gp

i phn t khi ca Y.
1. Cng thc tng qut ca 2 hidrocacbon l:
A. C
n
H
2n - 2
B. C
n
H
2n + 2
C. C
n
H
2n- 6
D. C
n
H
2n

2. Bit rng t khi hi ca hn hp ng th tch X v Y so vi kh C
2
H
6
bng 2,1.
Cng thc phn t ca X v Y ln lt l:
A. C
3
H
8
v C
6
H
14
. B. C
3
H
4
v C
6
H
8
C. C
3
H
6
v C
6
H
12
. D. Tt c
u sai
Cu 2. Cho cc cht kh sau: SO
2
, O
2
, CH
4
v N
2
. nhn bit cc cht kh trn,
trnh t no sau y l ng.
A. dung dch Ca(OH)
2
, que m. B. dung dch Br
2
, que m
C. dung dch clo, que m. D. A, B v C u ng.
Cu 3. t 10 cm
3
mt hidrocacbon bng 80 cm
3
oxi (ly d). Sn phm thu c
sau khi cho hi nc ngng t cn 65 cm
3
trong c 25 cm
3
oxi d. Cc th tch
trong cng iu kin. Xc nh CTPT ca hidrocacbon.
A. C
4
H
10
B. C
4
H
6
C. C
5
H
10
D. C
3
H
8

Cu 4. Mt hidrocacbon X c cng thc C
n
H
2n+ 2 - 2k
. Khi t X ta c t l s mol
ca CO
2
v H
2
O bng 2 (k hiu b), ng vi k nh nht. Cng thc phn t ca X
l:
A. C
2
H
4
B. C
2
H
6
C. C
2
H
2
D. C
6
H
6

Cu 5. Mt hn hp 2 ankan lin tip trong dy ng ng c t khi hi vi H
2
l
24,8.
1. Cng thc phn t ca 2 ankan l:
A. C
2
H
2
v C
3
H
4
B. C
2
H
4
v C
4
H
8

C. C
3
H
8
v C
5
H
12
D. Kt qu khc
2. Thnh phn phn trm v th tch ca 2 ankan l:
A. 30% v 70% B. 35% v 65%
C. 60% v 40% C. 50% v 50%
Cu 6. iu kin tiu chun c 1 hn hp kh gm 2 hidrocacbon no A v B, t
khi hi ca hn hp i vi H
2
l 12.
1. Khi lng CO
2
v hi H
2
O sinh ra khi t chy 15,68 lit hn hp ( kc).
A. 24,2 gam v 16,2 gam B. 48,4 gam v 32,4 gam
C. 40 gam v 30 gam D. Kt qu khc
2. Cng thc phn t ca A v B l:
A. CH
4
v C
2
H
6
B. CH
4
v C
3
H
8

C. CH
4
v C
4
H
10
D. C 3 cu A, B v C.
Cu 7. Cho hn hp 2 ankan A v B th kh, c t l s mol trong hn hp: n
A
:
n
B
= 1 : 4. Khi lng phn t trung bnh l 52,4. Cng thc phn t ca hai ankan
A v B ln lt l:
A. C
2
H
6
v C
4
H
10
B. C
5
H
12
v C
6
H
14

C. C
2
H
6
v C
3
H
8
D. C
4
H
10
v C
3
H
8

Cu 8. Hidrocacbon A c cng thc phn t l C
4
H
8
. C bao nhiu ng phn cu
to ng vi cng thc phn t ca A.
A. 4 B. 5 C. 6 D. 7
Cu 9. Cho cc hp cht sau: CH
3
CH
2
CH
2
CH
3
(A), CH
3
CH(CH
3
)CH
3
(B), CH
4

(C), CH
3
CH
2
CH
3
(D). Theo th t tng dn nhit si th:
A. (A) < (B) < (C) < (D) B. (D) < (C) < (B) < (A)
C. (B) < (C) < (A) < (D) D. (A) < (C) < (B) < (D)
Cu 10: Np mt hn hp kh c 20% th tch ankan A v 80% th tch O
2
(d)
vo kh nhin k. Sau khi cho n ri cho hi nc ngng t nhit ban u th
p sut trong kh nhin k gim i 2 ln. Thit lp cng thc phn t ca ankan A.
A. CH
4
. B. C
2
H
6
. C. C
3
H
8
. D.C
4
H
10
.
Cu 11: Nung m gam hn hp X gm 3 mui natri ca 3 axit no n chc vi
NaOH d thu c cht rn D v hn hp Y gm 3 ankan. T khi ca Y so vi
H
2
l 11,5. Cho D tc dng vi H
2
SO
4
d thu c 17,92 lt CO
2
(ktc).a. Gi tr
ca m l:
A. 42,0. B. 84,8. C. 42,4. D. 71,2.
b. Tn gi ca 1 trong 3 ankan thu c l:
A. metan. B. etan. C. propan. D. butan.

Cu 12. Trong cc tn gi di y, tn gi no khng ng: 4- metylhexan (1); 3-
metyl-4-clohexan (3); n-hexan (2); 2-metylbutan (4); 2-dimetylpropan (5)
A. (1), (5) v (3) B. (1), (2) v (5)
C. (4), (5) v (1) D. (4), (3) v (1)
Cu 13. Trong cc hp cht sau y, hp cht no c khng no bng 0:
CH
3
CH
3
(1), CH
2
=CH
2
(2), CH
4
(3), n-hexan (4), CH
2
=CH-CH=CH
2
(5), C
6
H
14
(6)
A. (1), (2) v (5) B. (1), (3), (4) v (6)
C. (1), (3) v (6) D. (2), (3) v (5)
Cu 14. Ankan no sau y ch cho 1 sn phm th duy nht khi tc dng vi Cl
2

theo t l mol (1 : 1):CH
3
CH
2
CH
3
(a), CH
4
(b),CH
3
C(CH
3
)
2
CH
3
(c), CH
3
CH
3
(d),
CH
3
CH(CH
3
)CH
3
(e)
A. (a), (e), (d) B. (b), (c), (d)
C. (c), (d), (e) D. (a), (b), (c), (e), (d)
Cu 15. iu ch 2,3-dimetyl butan (diisopropyl) t propan, th dy chuyn ha
no sau y l hp l nht (iu kin, xc tc xem nh c ).
A. Propan metan metyl clorua 2,3-dimetyl butan.
B. Propan isopropyl clorua 2,3-dimetyl butan.
C. Propan CH
2
=CH
2
CH
3
CH
2
Cl 2,3-dimetyl butan.
D. C 3 dy chuyn ha trn u ng.
Cu 16. Cho cc cu sau:
(a) Hidrocacbon no l hidrocacbon trong phn t ch c lin kt n
(b) Ankan l hidrocacbon no, mch cacbon khng vng.
(c) Hidrocacbon no l hp cht trong phn t ch c hai nguyn t l cacbon v
hidro.
(d) Ankan ch c ng phn mch cacbon.
Nhng cu ng l:
A. (a), (b), (d). B. (a), (c), (d). C. (a), (b), (c). D. (a), (b), (c), (d)
Cu 17. Cho hn hp cc ankan sau: pentan (si 36
0
C), hexan (si 69
0
C),
heptan (si 98
0
C), octan (si 126
0
C), nonan (si 151
0
C). C th tch ring
tng cht khi hn hp bng cch no sau y?
A. Chng ct li cun hi nc. B. Chng ct phn on.
C. Chng ct p sut thp. D. Chng ct thng.
Cu 18. Nhng sn phm no c to thnh khi oxi ha butan bng dung dch
KMnO
4
nhit cao.
A. CH
3
COOH. B. CO
2
v CH
3
CH
2
COOH.
C. HCOOH v CH
3
CH
2
COOH D. A, B v C u ng.
Cu 19. Cho 4 ng nghim ng hexan nh s (1), (2), (3) v (4). Cho vo mi
ng nghim tng cht sau: dung dch axit sunfuric long vo (1), dung dch natri
hidroxit vo (2), dung dch thuc tm vo (3), brom vo (4) ri t trn mi ng
nghim 1 mnh giy qu tm m:
1. Mu qu tm m s thay i nh th no?
A. (1), (2), (3), mu qu khng i mu; (4), mu qu chuyn sang mu .
B. (1), (2), mu qu khng i mu; (3), (4), mu qu chuyn sang mu .
C. (1), (2), qu khng i mu; (3), (4), mu qu chuyn sang mu xanh.
D. C 4 ng u khng lm qu i mu.
2. Khi un nng nh cc ng nghim trn v ngoi nh sng th mu giy qu s
thay i nh th no?
A. (1), (2), (3), mu qu khng i mu; (4), mu qu chuyn sang mu .
B. (1), (2), mu qu khng i mu; (3), (4), mu qu chuyn sang mu .
C. (1), (2), qu khng i mu; (3), (4), mu qu chuyn sang mu xanh.
D. C 4 ng u khng lm qu i mu.
Cu 20. Ankan X th kh, X tc dng vi Cl
2
theo t l mol 1 : 1, c chiu sng
thu c dn xut clo Y cha 70,3% clo theo khi lng. Cng thc phn t ca X
v Y tng ng l:
A. CH
4
, CH
3
Cl B. C
2
H
6
, C
2
H
5
Cl
C. C
3
H
8
, C
3
H
7
Cl D. A, B v C u ng
Cu 21. Phn trm khi lng ca nguyn t cacbon trong phn t ankan thay i
th no theo chiu tng s nguyn t cacbon trong dy ng ng
A. Tng dn. B. Gim dn.
C. Khng tng, khng gim. D. Khng theo qui lut no c.
Cu 22. Khi monoclo ha propan th thu c cc sn phm CH
3
CH
2
CH
2
Cl (X),
CH
3
CHClCH
3
(Y). Cho bit tc th tng i C bc I v C bc II tng ng
l 1 v 4,3. Phn trm ca cc sn phm (X) v (Y) l:
A. (X) 20%, (Y) 80% B. (X) 41,1%, (Y) 58,9%
C. (X) 30%, (Y) 70% D. (X) 50%, (Y) 50%
Cu 23. Nguyn t cacbon trong phn t ankan lai ha theo kiu no? Gc ha tr
l bao nhiu?
A. Lai ha sp, gc ha tr l 180
0
. B. Lai ha sp
2
, gc ha tr l 120
0
.
C. Lai ha sp
3
, gc ha tr l 109
0
28'.

D. Lai ha sp
3
d, gc ha tr l 90
0
.
Cu 24. t chy 2 lt hn hp 2 hydrocacbon A, B th kh v cng dy ng
ng cn 10 lt O
2
to thnh 6 lt CO
2
, cc th tch kh o kc. Xc nh CTPT
ca A,B bit V
A
= V
B

A. C
2
H
6
v

C
4
H
10
B. C
2
H
6
v

C
3
H
8

C. C
2
H
4
v

C
4
H
8
D. C
3
H
6
v

C
4
H
10


Cho C = 12, H = 1, O = 16, Cl = 35,5, S = 32, Mn = 55
Cu 25: 2,2,3,3-tetrametylbutan co bao nhieu nguyen t C va H trong phan
t ?
A. 8C,16H . B. 8C,14H C. 6C, 12H. D.8C,18H.

Cu 26: Dn hn hp kh A gm propan v xiclopropan i vo dung dch brom s quan st
c hin tng no sau y :
A. Mu ca dung dch nht dn, khng c kh thot ra.
B. Mu ca dung dch nht dn, v c kh thot ra.
C. Mu ca dung dch mt hn, khng cn kh thot ra.
D. Mu ca dung dch khng i.




Cu 27: Cho hn hp 2 ankan A v B th kh, c t l s mol trong hn hp: n
A
:
n
B
= 1 : 4. Khi lng phn t trung bnh l 52,4. Cng thc phn t ca hai ankan
A v B ln lt l:
A. C
2
H
6
v C
4
H
10
. B. C
5
H
12
v C
6
H
14
.
C. C
2
H
6
v C
3
H
8
. D. C
4
H
10
v C
3
H
8

Cu 28: Khi tin hnh craking 22,4 lt kh C
4
H
10
(ktc) thu c hn hp A gm
CH
4
, C
2
H
6
, C
2
H
4
, C
3
H
6
, C
4
H
8
, H
2
v C
4
H
10
d. t chy hon ton A thu c x
gam CO
2
v y gam H
2
O. Gi tr ca x v y tng ng l:
A. 176 v 180. B. 44 v 18. C. 44 v 72. D. 176 v 90.
Cu 29: Craking n-butan thu c 35 mol hn hp A gm H
2
, CH
4
, C
2
H
4
, C
2
H
6
,
C
3
H
6
, C
4
H
8
v mt phn butan cha b craking. Gi s ch c cc phn ng to ra
cc sn phm trn. Cho A qua bnh nc brom d thy cn li 20 mol kh. Nu t
chy hon ton A th thu c x mol CO
2
.
a. Hiu sut phn ng to hn hp A l:
A. 57,14%. B. 75,00%. C. 42,86%. D. 25,00%.
b. Gi tr ca x l:
A. 140. B. 70. C. 80. D. 40.
Cu 30: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp
Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi
H
2
bng 12. Cng thc phn t ca X l:
A. C
6
H
14
. B. C
3
H
8
. C. C
4
H
10
. D. C
5
H
12
.
Cu 31: Khi crackinh hon ton mt ankan X thu c hn hp Y (cc th tch kh
o cng iu kin nhit v p sut); t khi ca Y so vi H
2
bng 29. Cng
thc phn t ca X l:
A. C
6
H
14
. B. C
3
H
8
. C. C
4
H
10
. D. C
5
H
12
.
Cu 32: Craking 8,8 gam propan thu c hn hp A gm H
2
, CH
4
, C
2
H
4
, C
3
H
6
v
mt phn propan cha b craking. Bit hiu sut phn ng l 90%. Khi lng
phn t trung bnh ca A l:
A. 39,6. B. 23,16. C. 2,315. D. 3,96.
Cu 33: Craking 40 lt n-butan thu c 56 lt hn hp A gm H
2
, CH
4
, C
2
H
4
,
C
2
H
6
, C
3
H
6
, C
4
H
8
v mt phn n-butan cha b craking (cc th tch kh o cng
iu kin nhit v p sut). Gi s ch c cc phn ng to ra cc sn phm trn.
Hiu sut phn ng to hn hp A l:
A. 40%. B. 20%. C. 80%. D. 20%.
Cu 34: Craking m gam n-butan thu c hp A gm H
2
, CH
4
, C
2
H
4
, C
2
H
6
,
C
3
H
6
, C
4
H
8
v mt phn butan cha b craking. t chy hon ton A thu c 9
gam H
2
O v 17,6 gam CO
2
. Gi tr ca m l
A. 5,8. B. 11,6. C. 2,6. D. 23,2.
Cu 35: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan
bng oxi khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt
kh CO
2
( ktc) v 9,9 gam nc. Th tch khng kh ( ktc) nh nht cn dng
t chy hon ton lng kh thin nhin trn l
A. 70,0 lt. B. 78,4 lt. C. 84,0 lt. D. 56,0 lt.
Cu 36: t chy mt hn hp hirocacbon ta thu c 2,24 lt CO
2
(ktc) v 2,7
gam H
2
O th th tch O
2
tham gia phn ng chy (ktc) l:
A. 5,6 lt. B. 2,8 lt. C. 4,48 lt. D. 3,92 lt.
Cu 37: Hn hp kh A gm etan v propan. t chy hn hp A thu c kh
CO
2
v hi H
2
O theo t l th tch 11:15. Thnh phn % theo khi lng ca hn
hp l:
A. 18,52% ; 81,48%. B. 45% ; 55%.
C. 28,13% ; 71,87%. D. 25% ; 75%.
Cu 38: t chy hon ton mt hirocacbon X thu c 0,11 mol CO
2
v 0,132
mol H
2
O. Khi X tc dng vi kh clo thu c 4 sn phm monoclo. Tn gi ca X
l:
A. 2-metylbutan. B. etan.
C. 2,2-imetylpropan. D. 2-metylpropan.
Cu 39: Mt hn hp 2 ankan lin tip trong dy ng ng c t khi hi vi H
2

l 24,8.
a. Cng thc phn t ca 2 ankan l:
A. C
2
H
6
v C
3
H
8
. B. C
4
H
10
v C
5
H
12
. C. C
3
H
8
v C
4
H
10
. D. Kt qu khc
b. Thnh phn phn trm v th tch ca 2 ankan l:
A. 30% v 70%. B. 35% v 65%. C. 60% v 40%. D. 50% v 50%
Cu 40: iu kin tiu chun c 1 hn hp kh gm 2 hirocacbon no A v B, t
khi hi ca hn hp i vi H
2
l 12.
a. Khi lng CO
2
v hi H
2
O sinh ra khi t chy 15,68 lt hn hp ( ktc).
A. 24,2 gam v 16,2 gam. B. 48,4 gam v 32,4 gam.
C. 40 gam v 30 gam. D. Kt qu khc.
b. Cng thc phn t ca A v B l:
A. CH
4
v C
2
H
6
. B. CH
4
v C
3
H
8
.
C. CH
4
v C
4
H
10
. D. C A, B v C.
Cu 41: t 10 cm
3
mt hirocacbon bng 80 cm
3
oxi (ly d). Sn phm thu
c sau khi cho hi nc ngng t cn 65 cm
3
trong c 25 cm
3
oxi d. Cc th
tch trong cng iu kin. CTPT ca hirocacbon l:
A. C
4
H
10
. B. C
4
H
6
. C. C
5
H
10
. D. C
3
H
8

Cu 42: t chy hon ton hn hp X gm hai ankan k tip trong dy ng
ng c 24,2 gam CO
2
v 12,6 gam H
2
O. Cng thc phn t 2 ankan l:
A. CH
4
v C
2
H
6
. B. C
2
H
6
v C
3
H
8
. C. C
3
H
8
v C
4
H
10
. D. C
4
H
10
v C
5
H
12

Cu 43: X l hn hp 2 ankan. t chy ht 10,2 gam X cn 25,76 lt O
2
(ktc).
Hp th ton b sn phm chy vo nc vi trong d c m gam kt ta.
a. Gi tr m l:
A. 30,8 gam. B. 70 gam. C. 55 gam. D. 15 gam.
b. Cng thc phn t ca A v B l:
A. CH
4
v C
4
H
10
. B. C
2
H
6
v C
4
H
10
. C. C
3
H
8
v C
4
H
10
. D. C A, B v C.
Cu 44: Hirocacbon X chy cho th tch hi nc gp 1,2 ln th tch CO
2
(o
cng k). Khi tc dng vi clo to mt dn xut monoclo duy nht. X c tn l:
A. isobutan B. propan. C. etan. D. 2,2- imetylpropan.
Cu 45: t chy hon ton hn hp X gm 2 hirocacbon l ng ng lin tip,
sau phn ng thu c VCO
2
:VH
2
O =1:1,6 (o cng k). X gm:
A. CH
4
v C
2
H
6
. B. C
2
H
4
v C
3
H
6

C. C
2
H
2
v C
3
H
6
. D. C
3
H
8
v C
4
H
10
.
Cu 46: t chy hon ton 0,2 mol hirocacbon X. Hp th ton b sn phm
chy vo nc vi trong c 20 gam kt ta. Lc b kt ta ri un nng phn
nc lc li c 10 gam kt ta na. Vy X khng th l:
A. C
2
H
6
. B. C
2
H
4
. C. CH
4
. D. C
2
H
2

Cu 47: n gin ta xem xng l hn hp cc ng phn ca hexan v khng
kh gm 80% N
2
v 20% O
2
(theo th tch). T l th tch xng (hi) v khng kh
cn ly l bao nhiu xng c chy hon ton trong cc ng c t trong ?
A. 1: 9,5. B. 1: 47,5. C. 1:48. D. 1:50
Cu 48: t chy hon ton hn hp hai hirocacbon ng ng c khi lng
phn t hn km nhau 28 vC, ta thu c 4,48 l CO
2
(ktc) v 5,4 gam H
2
O.
CTPT ca 2 hirocacbon trn l:
A. C
2
H
4
v C
4
H
8
B. C
2
H
2
v C
4
H
6
.


C. C
3
H
4
v C
5
H
8
. D. CH
4
v C
3
H
8
.
Cu 49: Cho 224,00 lt metan (ktc) qua h quang c V lt hn hp A (ktc)
cha 12% C
2
H
2
;10% CH
4
; 78%H
2
(v th tch). Gi s ch xy ra 2 phn ng:
2CH
4
-> C
2
H
2
+ 3H
2
(1)
CH
4
-> C + 2H
2
(2)
Gi tr ca V l:
A. 407,27. B. 448,00. C. 520,18. D. 472,64.
Cu 50: t chy hon ton 2,24 lt hn hp A (ktc) gm CH
4
, C
2
H
6
v C
3
H
8
thu
c V lt kh CO
2
(ktc) v 7,2 gam H
2
O. Gi tr ca V l:
A. 5,60. B. 6,72. C. 4,48. D. 2,24.
Cu 51: t chy hon ton 6,72 lt hn hp A (ktc) gm CH
4
, C
2
H
6
, C
3
H
8
, C
2
H
4

v C
3
H
6
, thu c 11,2 lt kh CO
2
(ktc) v 12,6 gam H
2
O. Tng th tch ca C
2
H
4

v C
3
H
6
(ktc) trong hn hp A l:
A. 5,60. B. 3,36. C. 4,48. D. 2,24.
Cu 52: t chy hon ton hn hp A gm CH
4
, C
2
H
2
, C
3
H
4
, C
4
H
6
thu c x
mol CO
2
v 18x gam H
2
O. Phn trm th tch ca CH
4
trong A l:
A. 30%. B. 40%. C. 50%. D. 60%.
Cu 53: t chy hon ton hn hp kh X gm 2 hirocacbon A v B l ng
ng k tip thu c 96,8 gam CO
2
v 57,6 gam H
2
O. Cng thc phn t ca A
v B l:
A. CH
4
v C
2
H
6
. B. C
2
H
6
v C
3
H
8
.
C. C
3
H
8
v C
4
H
10
. D. C
4
H
10
v C
5
H
12

Cu 54: Hn hp kh X gm 2 hirocacbon A v B l ng ng k tip. t chy
X vi 64 gam O
2
(d) ri dn sn phm thu c qua bnh ng Ca(OH)
2
d thu
c 100 gam kt ta. Kh ra khi bnh c th tch 11,2 lt 0
o
C v 0,4 atm. Cng
thc phn t ca A v B l:
A. CH
4
v C
2
H
6
. B. C
2
H
6
v C
3
H
8
.
C. C
3
H
8
v C
4
H
10
. D. C
4
H
10
v C
5
H
12

Cu 55: Khi t chy hon ton V lt hn hp kh gm CH
4
, C
2
H
6
, C
3
H
8
(ktc) thu
c 44 gam CO
2
v 28,8 gam H
2
O. Gi tr ca V l:
A. 8,96. B. 11,20 C. 13,44. D. 15,68.
Cu 56: Khi t chy hon ton 7,84 lt hn hp kh gm CH
4
, C
2
H
6
, C
3
H
8
(ktc)
thu c 16,8 lt kh CO
2
(ktc) v x gam H
2
O. Gi tr ca x l:
A. 6,3. B. 13,5. C. 18,0. D. 19,8.
Cu 57: Khi t chy hon ton hn hp 2 ankan l ng ng k tip thu c
7,84 lt kh CO
2
(ktc) v 9,0 gam H
2
O. Cng thc phn t ca 2 ankan l:
A. CH
4
v C
2
H
6
. B. C
2
H
6
v C
3
H
8
.
C. C
3
H
8
v C
4
H
10
. D. C
4
H
10
v C
5
H
12
.