THI TUYN SINH I HC NM 2014

Mn thi : HA, khi B - M : 739

THI GM 50 CU (T CU 1 N CU 50) DNH CHO TT C TH SINH.
Cho bit nguyn t khi ca cc nguyn t :
H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5;
K= 39; Fe = 56; Cu = 64; Ag=108; Ba = 137.
Cu 1 : Cho s phn ng sau:
R + 2HCl
(long)

o
t
RCl
2
+ H
2

2R + 3Cl
2

o
t
2RCl
3

R(OH)
3
+ NaOH
(long)
NaRO
2
+ 2H
2
O
Kim loi R l
A. Cr. B. Al. C. Mg. D. Fe.
Cr+2HCl
0
t
CrCl
2
+H
2
2Cr+3Cl
2
0
t
2CrCl
3

Cr(OH)
3
+NaOH NaCrO
2
+2H
2
O
Cu 2 : Hp th hon ton 3,36 lt kh CO
2
(ktc) vo dung dch cha 0,15 mol NaOH v 0,1 mol
Ba(OH)
2
, thu c m gam kt ta. Gi tr ca m l
A. 14,775. B. 9,850. C. 29,550. D. 19,700.
S mol OH

:s mol CO
2
=0,35:0,15=2,73>2=>s mol CO
3
2
=0,15>s mol Ba
2+
=0,1
=>m=0,1197=19,7
Cu 3 : Cho phn ng: SO
2
+ 2KMnO
4
+ H
2
O K
2
SO
4
+ MnSO
4
+ H
2
SO
4
.
Trong phng trnh ha hc ca phn ng trn, khi h s ca KMnO
4
l 2 th h s ca SO
2
l
A. 5. B. 6. C. 4. D. 7.
5SO
2
+2KMnO
4
+2H
2
OK
2
SO
4
+2MnSO
4
+2H
2
SO
4
Cu 4: Phng trnh ha hc no sau y khng ng?
A. Ca + 2H
2
O Ca(OH)
2
+ H
2
. B. 2Al + Fe
2
O
3

o
t
Al
2
O
3
+ 2Fe.
C. 4Cr + 3O
2

o
t
2Cr
2
O
3
. D. 2Fe + 3H
2
SO
4(long)
Fe
2
(SO
4
)
3
+ 3H
2
.
Fe+H
2
SO
4
longFeSO
4
+H
2

Cu 5: Nung hn hp gm 0,12 mol Al v 0,04 mol Fe
2
O
4
mt thi gian, thu c hn hp rn X.
Ha tan hon ton X trong dung dch HCl d thu c 0,15 mol kh H
2
v m gam mui. Gi tr ca
m l
A. 34,10. B. 32,58. C. 31,97. D. 33,39.
0,12 27 0, 04 (3 56 4 2 35, 5) 0,15 2 35, 5 31, 97 m = + + + =
Cu 6: t chy hon ton 0,2 mol hn hp X gm mt ankan v mt anken, thu c 0,35 mol
CO
2
v 0,4 mol H
2
O. Phn trm s mol ca anken trong X l
A. 40%. B. 50%. C. 25%. D. 75%.
Gi x l phn trm anken trong hn hp
0, 2 (1 ) 0, 4 0, 35 0, 75 x x = =
Cu 7: Cht X c cng thc phn t C
6
H
8
O
4
. Cho 1 mol X phn ng ht vi dung dch NaOH, thu
c cht Y v 2 mol cht Z. un Z vi dung dch H
2
SO
4
c, thu c imetyl ete. Cht Y phn
ng vi dung dch H
2
SO
4
long (d), thu c cht T. Cho T phn ng vi HBr, thu c hai sn
phm l ng phn cu to ca nhau. Pht biu no sau y ng?
A. Cht T khng c ng phn hnh hc.
B. Cht X phn ng vi H
2
(Ni, t
0
) theo t l mol 1 : 3.
C. Cht Y c cng thc phn t C
4
H
4
O
4
Na
2
.
D. Cht Z lm mt mu nc brom.
bt bo ho=3
Z : CH
3
OH
X : CH
3
OOC-C(=CH
2
)-COOCH
3

T: HOOC-C(=CH
2
)-COOH (=>khng c ng phn hnh hc)
Y : NaOOC-C(=CH
2
)-COONa
Cu 8: Nung nng hn hp bt X gm a mol Fe v b mol S trong kh tr, hiu sut phn ng bng
50%, thu c hn hp rn Y. Cho Y vo dung dch HCl d, sau khi cc phn ng xy ra hon
ton, thu c hn hp kh Z c t khi so vi H
2
bng 5. T l a : b bng
A. 2 : 1. B. 1 : 1. C. 3 : 1. D. 3 : 2.
2
2
34 10 3
1
10 2 1
H
H S
n
n

= = >

=>
0, 5 3
0, 5 1
a b
b

= =>
2
1
a
b
=
Cu 9: t chy hon ton 0,1 mol mt ancol n chc trong 0,7 mol O
2
(d), thu c tng s
mol cc kh v hi bng 1 mol. Khi lng ancol ban u em t chy l
A. 8,6 gam. B. 6,0 gam. C. 9,0 gam. D. 7,4 gam.
C
x
H
y
O+(x+y/4-0,5)O
2
xCO
2
+(y/2)H
2
O
S mol hn hp sau phn ng
0,1x+0,05y+0,7-0,1x-0,025y+0,05=1=>y=10
V y2x+2 v 0,1(x+y/4-0,5)<0,7=>4x<5=>x=4
m=0,174=7,4
Cu 10: Hai este X, Y c cng cng thc phn t C
8
H
8
O
2
v cha vng benzene trong phn t.
Cho 6,8 gam hn hp gm X v Y tc dng vi dung dch NaOH d, un nng, lng NaOH phn
ng ti a l 0,06 mol, thu c dung dch Z cha 4,7 gam ba mui. Khi lng mui ca axit
cacboxylic c phn t khi ln hn trong Z l
A. 0,82 gam. B. 0,68 gam. C. 2,72 gam. D. 3,40 gam.
S mol hn hp =6,8:136=0,05
CH
3
COOC
6
H
5
0,01 mol
HCOOCH
2
C
6
H
5
0,04 mol
m=0,0182=0,82
D s liu 4,7 gam ch cn 3 mui l . (v s mol NaOH>s mol hn hp)
Cu 11: Cho bt Fe vo dung dch AgNO
3
d, sau khi phn ng xy ra hon ton, thu c dung
dch gm cc cht tan:
A. Fe(NO
3
)
2
, AgNO
3
, Fe(NO
3
)
3
. B. Fe(NO
3
)
2
, AgNO
3
.
C. Fe(NO
3
)
3
, AgNO
3
. D. Fe(NO
3
)
2
, Fe(NO
3
)
3
.
Fe+3AgNO
3
Fe(NO
3
)
3
+3Ag
Cu 12: Tri cy c bo qun lu hn trong mi trng v trng. Trong thc t, ngi ta s
dng nc ozon bo qun tri cy. ng dng trn da vo tnh cht no sau y?
A. Ozon tr v mt ha hc. B. Ozon l cht kh c mi c trng.
C. Ozon l cht c tnh oxi ha mnh. D. Ozon khng tc dng c vi nc.
Cu 13: Trng hp hirocacbon no sau y to ra polime dung sn xut cao su buna?
A. 2-metylbuta-1,3-ien. B. Penta-1,3-ien.
C. But-2-en. D. Buta-1,3-ien.
nCH
2
=CH-CH=CH
2
Na
(-CH
2
-CH=CH-CH
2
-)
n

Cu 14: S ng phn cu to c cng thc phn t C
8
H
10
O, cha vng benzen, tc dng c vi
Na, khng tc dng vi dung dch NaOH l
A. 3. B. 5. C. 6. D. 4.
C
6
H
5
CH(OH)-CH
3
; C
6
H
5
-CH
2
CH
2
OH
C
6
H
4
(CH
3
)(CH
2
OH) (o-,m-,p-)
Cu 15: Dung dch X gm 0,1 mol K
+
; 0,2 mol Mg
2+
; 0,1 mol Na
+
; 0,2 mol Cl
-
v a mol Y
2-
. C
cn dung dch X, thu c m gam mui khan. Ion Y
2-
v gi tr ca m l
A.
2
4
SO

v 56,5. B.
2
3
CO

v 30,1. C.
2
4
SO

v 37,3. D.
2
3
CO

v 42,1.
Loi B v D v Mg
2+
phn ng vi CO
3
2

a=0,139+0,224+0,123+0,235,5+ (0,1+0,22+0,1-0,2):296=37,3
Cu 16: Hn hp X gm cht Y (C
2
H
8
N
2
O
4
) v cht Z (C
4
H
8
N
2
O
3
); trong , Y l mui ca axit
a chc, Z l ipeptit mch h. Cho 25,6 gam X tc dng vi dung dch NaOH d, un nng, thu
c 0,2 mol kh. Mt khc 25,6 gam X tc dng vi dung dch HCl d, thu c m gam cht hu
c. Gi tr ca m l
A. 20,15. B. 31,30. C. 23,80. D. 16,95.
Y : (COONH
4
)
2
v Z : Gly-Gly
25, 6 0, 2: 2 124
0, 2: 2 90 2 111, 5 31, 3
132

+ =
Cu 17: Trng hp no sau y khng to ra CH
3
CHO?
A. Oxi ha CH
3
COOH.
B. Oxi ha khng hon ton C
2
H
5
OH bng CuO un nng.
C. Cho CHCH cng H
2
O (t
0
, xc tc HgSO
4
, H
2
SO
4
).
D. Thy phn CH
3
COOCH=CH
2
bng dung dch KOH un nng.
Cu 18: Cho 3,48 gam bt Mg tan ht trong dung dch hn hp gm HCl (d) v KNO
3
, thu c
dung dch X cha m gam mui v 0,56 lt (ktc) hn hp kh Y gm N
2
v H
2
. Kh Y c t khi so
vi H
2
bng 11,4. Gi tr ca m l
A. 16,085. B. 14,485. C. 18,300. D. 18,035.
S mol N
2
=0,025(22,8-2):26=0,02; s mol H
2
=0,005
S mol NH
4
+
=(3,48:242-0,0210-0,052):8=0,01
m=3,48:2495+(0,022+0,01)74,5+0,0153,5=18,035
Cu 19: Cho mui X tc dng vi dung dch NaOH d, thu c dung dch cha hai cht tan. Mt
khc, cho a gam dung dch mui X tc dng vi a gam dung dch Ba(OH)
2
, thu c 2a gam dung
dch Y. Cng thc ca X l
A. KHS. B. NaHSO
4
. C. NaHS. D. KHSO
3
.
Cho mui X tc dng vi dung dch NaOH d, thu c dung dch cha hai cht tan =>X l mui
ca Natri=>loi A
a+a=2a=>Khng c kt ta=>loi B,D
Cu 20: Chia 20,8 gam hn hp gm hai anehit n chc l ng ng k tip thnh hai phn
bng nhau:
- Phn mt tc dng hon ton vi lng d dung dch AgNO
3
trong NH
3
un nng, thu c
108 gam Ag.
- Phn hai tc dng hon ton vi H
2
d (xc tc Ni, t
0
), thu c hn hp X gm hai ancol Y
v Z (M
Y
< M
Z
). un nng X vi H
2
SO
4
c 140
0
C, thu c 4,52 gam hn hp ba ete. Bit hiu
sut phn ng to ete ca Y bng 50%.
Hiu sut phn ng to ete ca Z bng
A. 40%. B. 60%. C. 30%. D. 50%.
Trong mi phn :
2
2
10, 4 10, 4
41, 6
0, 25
andehit
andehit
M
n
= < = =>HCHO(0,2);CH
3
CHO(0,1)(gii h 30x+44y=10,4 v 4x+2y=1)
Gi h l hiu sut to ete ca Z :
0, 2 0, 5 (32 0, 5 18) 0,1 (46 0, 5 18) 4, 52 h + = =>h=0,6
Cu 21: Thy phn hon ton 0,1 mol este X bng NaOH, thu c mt mui ca axit cacboxylic
Y v 7,6 gam ancol Z. Cht Y c phn ng trng bc, Z ha tan c Cu(OH)
2
cho dung dch mu
xanh lam. Cng thc cu to ca X l
A. HCOOCH
2
CH
2
CH
2
OOCH. B. HCOOCH
2
CH
2
OOCCH
3
.
C. CH
3
COOCH
2
CH
2
OOCCH
3
. D. HCOOCH
2
CH(CH
3
)OOCH.
Y: HOOH v M
Z
=76=>C
3
H
6
(OH)
2
=>X : HCOOCH
2
CH(CH
3
)OOCH
Cu 22: Axit no sau y l axit bo?
A. Axit axetic B. Axit glutamic C. Axit stearic D. Axit aipic
Cu 23: Ancol no sau y c s nguyn t cacbon bng s nhm -OH?
A. Propan-1,2-iol B. Glixerol C. Ancol benzylic D. Ancol etylic
Glixerol : C
3
H
5
(OH)
3

Cu 24: Cho phn ng ha hc :
2
NaOH HCl NaCl H O + +
Phn ng ha hc no sau y c cng phng trnh ion thu gn vi phn ng trn?
A. ( )
2
2
2KOH FeCL Fe OH 2KCl + +
B.
3 2 3 2
NaOH NaHCO Na CO H O + +
C.
4 3 2
NaOH NH CL NaCl NH H O + + +
D.
3 3 2
KOH HNO KNO H O + +
Cu 25: Nung nng bnh kn cha a mol hn hp NH
3
v O
2
(c xc tc Pt) chuyn ton b NH
3

thnh NO. Lm ngui v thm nc vo bnh, lc u thu c 1 lt dung dch HNO
3
c pH = 1,
cn li 0,25 mol kh O
2
. Bit cc phn ng xy ra hon ton. Gi tr ca a l
A. 0,1 B. 0,4 C. 0,3 D. 0,2
Sau phn ng N
3
+8eN
+5
v O
2
+4e2O
2

8
0,1 (1 ) 0, 25
4
a a = + + =>a=0,4
Cu 26: Cc dung dch no sau y u c tc dng vi Al
2
O
3
?
A. NaSO
4
, HNO
3
B. HNO
3
, KNO
3
C. HCl, NaOH D. NaCl, NaOH
Al
2
O
3
+6HCl2AlCl
3
+3H
2
O
Al
2
O
3
+2NaOH2NaAlO
2
+H
2
O
Cu 27: Hai nguyn t X v Y cng mt chu k trong bng tun hon cc nguyn t ha hc, X
thuc nhm IIA, Y thuc nhm IIIA (
X Y
Z Z 51 + = ). Pht biu no sau y ng?
A. Kim loi X khng kh c ion
2
Cu
+
trong dung dch
B. Hp cht vi oxi ca X c dng
2 7
X O
C. Trong nguyn t nguyn t X c 25 proton
D. nhit thng X khng kh c
2
H O
Z
X
+Z
Y
=51; Z
Y
-Z
X
=11=>Z
X
=20 (Ca) v Z
Y
=31(Ga)
Ca+2H
2
OCa(OH)
2
+2H
2
; Cu
2+
+2OH

Cu(OH)
2

Cu 28: Tin hnh cc th nghim sau
(a) Cho dung dch NH
3
vo dung dch BaCl
2

(b) Sc kh SO
2
vo dung dch H
2
S
(c) Cho dung dch AgNO
3
vo dung dch H
3
PO
4

(d) Cho dung dch AgNO
3
vo dung dch HCl
(e) Cho dung dch AgNO
3
vo dung dch HF
Sau khi kt thc th nghim, s trng hp thu c kt ta l
A. 2 B.3 C. 5 D. 4
Sc kh SO
2
vo dung dch H
2
S=>S
Cho dung dch AgNO
3
vo dung dch HCl=>AgCl
Cu 29: Hn hp X gm ba peptit u mch h c t l mol tng ng l 1 : 1 :3. Thy phn hon
ton m gam X, thu c hn hp sn phm gm 14,24 gam alanin v 8,19 gam valin. Bit tng s
lin kt peptit trong phn t ca ba peptit trong X nh hn 13. Gi tr ca m l
A. 18,83 B. 18,29 C. 19,19 D. 18,47
S mol Ala=0,16 mol v s mol Val=0,07 mol
S mol alanin: s mol valin=16:7
7=>12:12:31
16=>12:12:34
(3+3+4)k<13=>k<1,3=>k=1
=>Ala
2
Val
2
; Ala
2
Val
2
;Ala
4
Val
m=(0,16-0,07):3*401+(0,16-(0,16-0,07):3*4):2*358=19,19
Cu 30: Ha tan ht 10,24 gam hn hp X gm Fe v Fe
3
O
4
bng dung dch cha 0,1 mol H
2
SO
4

v 0,5 mol HNO
3
, thu c dung dch Y v hn hp gm 0,1 mol NO v a mol NO
2
(khng cn sn
phm kh no khc). Chia dung dch Y thnh hai phn bng nhau:
- Phn mt tc dng vi 500 ml dung dch KOH 0,4M, thu c 5,35 gam mt cht kt ta
- Phn hai tc dng vi dung dch Ba(OH)
2
d, thu c m gam kt ta.
Bit cc phn ng xy ra hon ton. Gi tr ca m l
A. 20,62 B. 41,24 C. 20,21 D. 31,86
H
+
d trong dung dch Y : (0,50,4-5,35 :1073)2=0,1 mol
Gi x,y ln lt l s mol Fe, Fe
3
O
4
trong hn hp X
3x+y=0,3+a
56x+232y=10,24
3x+9y+0,1+a=0,5+0,2-0,1
=>x=0,1 ; y=0,02 v a=0,02
m=(0,1+0,023) :2107+0,1 :2233=20,21
Cu 31: Thc hin phn ng sau trong bnh kn: ( ) ( ) ( )
2 2
H k Br k 2HBr k +
Lc u nng hi Br
2
l 0,072 mol/l. Sau 2 pht, nng hi Br
2
cn li l 0,048 mol/l.
Tc trung bnh ca phn ng tnh theo Br
2
trong khong thi gian trn l
A.
4
8 10 .

mol/(l.s) B.
4
6 10 .

mol/(l.s) C.
4
4 10 .

mol/(l.s) D.
4
2 10 .

mol/(l.s)
V=(0,072-0,048):120=
4
2 10 .

mol/(l.s)
Cu 32: Kim loi no sau y tan ht trong nc d nhit thng
A. Na B. Fe C. Mg D. Al
2Na+2H
2
O2NaOH+H
2

Cu 33: Trong cng nghip, sn xut axit H
3
PO
4
c tinh khit v nng cao, ngi ta lm
cch no sau y?
A. Cho dung dch H
2
SO
4
c, nng tc dng vi qung apatit.
B. t chy photpho trong oxi d, cho sn phm tc dng vi nc.
C. Cho photpho tc dng vi dung dch HNO
3
c, nng.
D. Cho dung dch axit H
2
SO
4
c, nng tc dng vi qung photphorit
2 2
+O +H O
2 5 3 4
P P O H PO
Cu 34: Cho m gam P
2
O
5
tc dng vi 253,5 ml dung dch NaOH 2M, sau khi cc phn ng xy ra
hon ton thu c dung dch X. C cn dung dch X, thu c 3m gam cht rn khan. Gi tr ca
m l
A. 21,30 B. 8,52 C. 12,78 D. 7,81
c lng
NaH
2
PO
4
Na
2
HPO
4
Na
3
PO
4

1 1 1
2 120 1, 69 3; 2 142 2 3; 2 164 2, 30 3
142 142 142
= < = < = <
=>Cht rn gm Na
3
PO
4
v NaOH d
2 (98 3 18) 0, 2535 2 40 3
142
m
m + = =>m=8,52
Cu 35: Poli(etylen terephtalat) c iu ch bng phn ng vi axit teraphtalic vi cht no sau
y?
A. Etylen glicol B. Etilen C. Glixerol D. Ancol etylic
nHOOCC
6
H
4
COOH+nHOCH
2
CH
2
OH(-OHC
6
H
4
COOCH
2
-CH
2
-O-)
n
+2nH
2
O

Cu 36: Cho cc cht sau : etilen, axetilen, phenol (C
6
H
5
OH) , buta-1,3-ien, toluen, anilin. S cht
lm mt mu nc brom iu kin thng l
A. 4 B. 2 C. 5 D. 3
etilen, axetilen, phenol (C
6
H
5
OH) , buta-1,3-ien, anilin
Cu 37: Ion X
2+
c cu hnh electron trng thi c bn
2 2 6
1s 2s 2p . Nguyn t X l
A. Ne (Z = 10) B. Mg (Z = 12) C. Na (Z = 11) D. O (Z = 8)
2 2 6 2
X
X 1s 2s 2p 3s Z 12 Mg : ( ) =
Cu 38: Mt bnh kn ch cha cc cht sau: axetilen (0,5 mol), vinylaxetilen (0,4 mol), hiro (0,65
mol) v mt t bt niken. Nung nng bnh mt thi gian, thu c hn hp kh X c t khi so vi
H
2
bng 19,5. Kh X phn ng va vi 0,7 mol AgNO
3
trong dung dch NH
3
, thu c m gam
kt ta v 10,08 lt hn hp kh Y (ktc). Kh Y phn ng ti a vi 0,55 mol Br
2
trong dung dch.
Gi tr ca m l
A. 76,1. B. 92,0. C. 75,9. D. 91,8.
S mol kh to kt ta=(0,526+0,452+0,652):39-10,08:22,4=0,45
Gi x v y ln lt l s mol axetilen v vinylaxetilen trong X
x+y=0,45 v 2x+y=0,7=>x=0,25 v y=0,2=>m=0,25240+0,2159=91,8
Cu 39: Cho X, Y, Z, T l cc cht khc nhau trong s 4 cht: CH
3
NH
2,
NH
3
, C
6
H
5
OH (phenol),
C
6
H
5
NH
2
(anilin) v cc tnh cht c ghi trong bng sau:
Cht X Y Z T
Nhiit si (
o
C) 182 184 -6,7 -33,4
pH (dung dch nng
0,001M)
6,48 7,82 10,81 10,12
Nhn xt no sau y ng?
A. Y l C
6
H
5
OH. B. Z l CH
3
NH
2
C. T l C
6
H
5
NH
2
D. X l NH
3

X : C
6
H
5
OH (nhit si cao nht : cht rn)
Y : C
6
H
5
NH
2
(nhit si cao th nh : cht lng)
Z,T : kh m tnh baz CH
3
NH
2
>NH
3
=>Z l CH
3
NH
2
v T l NH
3

Cu 40: Cho dy chuyn ha sau:
2 2
CO H O NaOH
X Y X
+ + +

Cng thc ca X l
A. NaOH B. Na
2
CO
3
C.NaHCO
3
D. Na
2
O.
2 2
CO H O NaOH
2 3 3 2 3
X(Na CO ) Y(NaHCO ) X(Na CO )
+ + +

Cu 41: Cho cc phn ng sau:
(a)
0
t
2 (hoi)
C H O + (b) Si + dung dch NaOH
(c)
0
t
FeO CO + (d) O
3
+ Ag
(e)
0
t
3 2
Cu(NO ) (f)
0
t
4
KMnO
S phn ng sinh ra n cht l
A. 4. B. 3. C. 5. D. 6.
(a)
0
t
2 (hoi)
C H O + CO+H
2
(b) Si +2NaOH+H
2
O Na
2
SiO
3
+2H
2

(c)
0
t
FeO CO + Fe+CO
2
(d) O
3
+2Ag Ag
2
O+O
2

(e) 2
0
t
3 2
Cu(NO ) 2CuO+4NO
2
+O
2
(f) 2
0
t
4
KMnO K
2
MnO
4
+MnO
2
+O
2

Cu 42: Dung dch axit acrylic (CH
2
=CH-COOH) khng phn ng c vi cht no sau y?
A. Na
2
CO
3
B. Mg(NO
3
)
2
C. Br
2
D. NaOH.
Cu 43: Hn hp X gm hai mui R
2
CO
3
v RHCO
3
. Chia 44,7 gam X thnh ba phn bng nhau:
- Phn mt tc dng hon ton vi dung dch Ba(OH)
2
d thu c 35,46 gam kt ta.
- Phn hai tc dng hon ton vi dung dch BaCl
2
d, thu c 7,88 gam kt ta.
- Phn ba tc dng ti a vi V ml dung dch KOH 2M.
Gi tr ca V l
A. 180. B.200. C.110. D. 70.
Trong mi phn : R
2
CO
3
: 0,04 mol v RHCO
3
: 0,14
0,04(2R+60)+0,14(R+61)=44,7:3=>R=18(NH
4
+
)
V=(0,042+0,142):2=0,18 lt=180ml
Cu 44: Cho hnh v m t th nghim iu ch kh Cl
2
t MnO
2
v dung dch HCl:

Kh Cl
2
dinh ra thng ln hi nc v hiro clorua. thu c kh Cl
2
kh th bnh (1) v bnh
(2) ln lt ng
A. dung dch NaOH v dung dch H
2
SO
4
c. B. dung dch H
2
SO
4
c v dung dch NaCl.
C. dung dch H
2
SO
4
c v dung dch AgNO
3
. D. dung dch NaCl v dung dch H
-2
SO
4
c.
Bnh th 1 ng dung dch NaCl hp th HCl nhng khng hp th Cl
2

Cl
2
+H
2
O

2H
+
+Cl

+ClO

(1)
S c mt Cl
-
(dung dch NaCl) lm cn bng (1) chuyn dch sang tri lm gim tan Cl
2

Bnh th 2 hp th hi nc.
Cu 45: Cho hn hp X gm Al v Mg tc dng vi 1 lt dung dch gm AgNO
3
a mol/l v
Cu(NO
3
)
2
2a mol/l, thu c 45,2 gam cht rn Y. Cho Y tc dng vi dung dch H
2
SO
4
c, nng
(d), thu c 7,84 lt kh SO
2
( ktc, l sn phm kh duy nht). Bit cc phn ng xy ra hon
ton. Gi tr ca a l
A. 0,25. B. 0,30. C. 0,15. D. 0,20.
Gi s Y ch c a mol Ag : a=45,2:108=>a=0,4185<0,352
Gi s Y c a mol Ag v 2a mol Cu : 108a+264a=45,2=>a=113:590
5a=0,9576>0,352
=>Hn hp X c a mol Ag v (45,2-108a):64 mol Cu
a+(45,2-108a):642=0,352=>a=0,3
Cu 46: Trong phn t propen c s lin kt xich ma (o) l
A. 7. B. 6. C. 8. D. 9.
Proprn : CH
3
-CH=CH
2

=>propen c 2 lin kt o
C-C
v 6 lin kt o
C-H

Cu 47: Amino axit X trong phn t ch cha hai loi nhm chc. Cho 0,1 mol X tc dng va
vi 0,2 mol NaOH, thu c 17,7 gam mui. S nguyn t hiro trong phn t X l
A. 9. B. 6. C. 7. D. 8.
S mol nhm COOH=2; M
mui
=177=>M
aminoaxit
=133 (s l =>s nhm NH
2
l s l);
=>(H
2
N)
x
R(COOH)
2
=133=>R+16x=43=>x=1 v R=27=>X : H
2
NC
2
H
3
(COOH)
2
=>7H
Cu 48: Anehit axetic th hin tnh oxi ho trong phn ng no sau y?
A.
0
Ni t
3 2 3 2
CH CHO H CH CH OH
,
+
B.
0
t
3 2 2 2
2CH CHO 5O 4CO 4H O + +
C.
3 2 2 3
CH CHO Br H O CH COOH 2HBr + + +
D.
3 3 3 2 3 4 4 3
CH CHO 2AgNO 3NH H O CH COONH 2NH NO 2Ag + + + + +
0
1 1
Ni t
3 2 3 2
CH CHO H CH CH OH
,
+
+ =>s oxi ho gim xung=> tnh oxi ho
Cu 49: Glucoz v fructoz u
A. c cng thc phn t C
6
H
10
O
5
. B. c phn ng trng bc.
C. thuc loi isaccarit. D. c nhm CH=O trong phn t.
Cu 50: C bao nhiu tripeptit (mch h) khi thy phn hon ton u thu c sn phm gm
alanin v glyxin?
A. 8. B. 5. C. 7. D. 6.
Ala-Ala-Gly; Gly-Ala-Ala; Ala-Gly-Ala; Gly-Ala-Gly; Gly-Gly-Ala; Ala-Gly-Gly

Th.s Hong Vn Chung (THPT chuyn Bn Tre)