1/6

PHIU AN TON HA CHT

PHOTPHO VNG

S CAS: 7723-14-0
S UN:1381
S ng k EC:015-001-00-1
S ch th nguy him ca cc t chc xp loi : 4.6 (Theo ph
lc I - Ngh nh 104/2009/N-CP).
S ng k danh mc Quc gia khc : Cha c thng tin.

I. NHN DNG HA CHT
- Tn thng gi ca cht: Photpho vng
M sn phm : PPVNMSDS001 - Tn thng mi: yellow phosphorus
- Tn khc: Phosphorus
- Tn nh cung cp hoc nhp khu: Cng ty TNHH
MTV Ha Cht C Bn Min Nam
a ch: 22 L T Trng, phng Bn Ngh, qun I,
Tp. H Ch Minh, Vit Nam.
a ch lin h trong trng hp khn cp:
1.Cng ty TNHH mt thnh vin Ha Cht
C Bn Min Nam
- a ch: 22 L T Trng , qun I, Tp.H Ch
Minh , Vit Nam
- Tel: (84.8)8223484, 8296620, 8225373
- Fax: (84.8)8243166
2. Cng ty c phn Pht pho Vit Nam
- a ch: Khu cng nghip Tng long -
huyn Bo Thng - Tnh Lo Cai - Vit Nam.
- T: 020.3863488
- Fax : 020.3863037
- Tn nh sn xut: Cng ty C phn Photpho Vit
Nam.
a ch: Khu cng nghip Tng long - huyn Bo
Thng - Tnh Lo Cai - Vit Nam.
- Mc ch s dng:
S dng quan trng nht l trong thng mi ca P4
l sn xut phn bn. P4 cng c s dng rng
ri trong cc loi vt liu n, dim, pho hoa, thuc
tr su, thuc nh rng v cht ty ra, axit
phtphoric, ph gia thc n chn nui gia sc
II. THNG TIN V THNH PHN CC CHT
Tn thnh phn nguy him S CAS
Cng thc
ha hc
Hm lng
(% theo trng lng )
Photpho (%) 7723-14-0 P4 Min 99,90
Hm lng cn khng tan (%) Max 0.1
Hm lng Asen (ppm) 7740-38-2 As Max 120
III. NHN DNG C TNH NGUY HIM CA HA CHT
1. Mc xp loi nguy him: Theo GHS
a. Nguy him C l
Lp nguy
him
Phn loi K hiu T bo hiu
Cng b nguy
him
Phn loi thch hp
Cht rn chy
c
Loi 2

Cnh bo
Cht rn c th
chy c
UNRTDG Class: 4.2;
PG III
b. Nguy him i vi sc khe
Lp nguy
him
Phn loi K hiu T bo hiu
Cng b nguy
him
Phn loi thch hp
D ng h
Hp
/ d ng da.
D ng h
hp : khng
th phn
loi khng
th,

D ng h
hp
D ng da
D ng h hp
D ngda
H hp: khng c
thng tin .
Da: mc d c m t
rng d ng da khng
c cng nhn khi
2/6

D ngda :
khng th
phn loi
kim tra trn ln (ca
IUCLID 2000), gi
nh rng n khng th
phn loi v khng c
thng tin, ph nhn
mi nguy him theo
Priority1
c. Nguy him i vi mi trng
Lp nguy him Phn loi K hiu T bo hiu
Cng b nguy
him
Phn loi thch hp
Nguy hi n mi
trng nc
Khng phn
loi
- - - Cha c thng tin
Nguy hi n mi
trng thy sinh
Khng phn
loi
- - - Cha c thng tin .
Theo UN
Loi 4 nhm 4.2 Cc cht d t bc chy
Loi 6 nhm 6.1 Cc cht c hi
( S hiu nguy him 46 theo ngh nh s 104/2009/N-CP)
2. Cnh bo nguy him :
- Chy, n hoc c khi tip xc: L cht c, d t bc chy khi tip xc vi oxi, sinh ra kh c
v gy bng i vi ngi, nh hng n mi trng xung quanh.
- Lu khi tip xc, bo qun, s dng: Khng c tip xc trc tip, phi dng kp chuyn
dng. Khi tip xc s dng phng tin bo v c nhn c bit ( Qun o, gng tay, ng chng
chy, khu trang phng c), khng c tip xc trc tip vi khng kh, oxi, cch ly vi cc
cht oxi ho mnh, bo qun nhng ni thong mt v lun ngm chm trong nc, cha ng
trong cc thit b cha kn m bo tnh c l ho.
3. Cc ng tip xc v triu chng
- ng mt: Khi b vng bn vo mt gy ra bng nng, tn thng n mt.
- ng th: Khi ht phi hi pht pho, sn phm chy ca pht pho vi nng vt qu gii
hn cho php gy kh th, au hng, c th gy ngt nu ht phi nhiu.
- ng da: B vng bn vo gy bng nng, nu lng ln c th xm nhp vo c th nh m,
xng, m t bo.
- ng tiu ha: gy ng c ho cht, nu b nng c th nh hng n tnh mng.
IV. BIN PHP S CU V Y T
1. Trng hp tai nn tip xc theo ng mt (b vng, dy vo mt): Ra nhiu ln bng
nc sch, sau s dng dung dch CuSO
4
1%, hoc NaHCO
3
nng 5% ra, a n c s
yt nu b nng.
2. Trng hp tai nn tip xc trn da (b dy vo da) Ra nhiu ln bng nc sch, sau s
dng dung dch CuSO
4
1%, hoc NaHCO
3
5% ra, a n c s yt nu b nng.
3. Trng hp tai nn tip xc theo ng h hp (ht th phi dng hi, kh): a ra ni
thong kh,h hp nhn to, a n c s yt nu b nng.
4. Trng hp tai nn theo ng tiu ha (n, ung nut nhm ha cht): Cho sc ming nhiu
ln, ch c gy nn nu cn tnh.
5. Lu i vi bc s iu tr: tt c cc trng hp b tai nn bng v pht pho khng c s
dng nc oxi gi ra.
V. BIN PHP X L KHI C HA HON
1. Xp loi v tnh chy : Cht d t bc chy trong khng kh.
2. Sn phm to ra khi b chy: P
2
O
5
, ngoi ra c th c cc hp cht ca axit phtphorc,
phtphin.
3. Cc tc nhn gy chy, n: B d r, do tip xc vi khng kh, oxi, cc cht oxi ho mnh, tia
la, va p, ma st
4. Cc cht dp chy thch hp v hng dn bin php cha chy, bin php kt hp khc:
3/6

+Cht cha chy: Nc, bnh CO
2
, ct, hoc t st khi cn thit.
+Bip php cha chy:
Dng nc phun bao trm vo ni c pht pho gy chy, hoc dng ct, t, bnh cha chy nu
chy vi khi lng pht pho nh, chuyn ton b pht pho vo ngm trong nc, hoc lm ngp
ton b khi lng pht pho gy chy. Khng cho pht pho tip xc vi khng kh, oxi v cc cht
oxi ho mnh.
5. Phng tin, trang phc bo h cn thit khi cha chy:
+ Phng tin cha chy: Bnh cha chy, ct, t, vi cha chy. Khu vc thao tc vi pht pho
phi lun c ngun nc phng chy.
+Trang phc: c qun o, gng tay, giy ng chng chy, mt l phng c.
6. Cc lu c bit v chy, n: Pht pho l cht d chy v sinh nhit mnh dn n ly lan
nhanh. Khi xy ra s c chy ln phi khn cp cch ly ngun pht chy vi khu vc xung quanh,
s tn ngi v ti sn xung quanh khu vc chy, ng u gi dp chy. Khng phun mnh
vo ni chy pht pho m phun nc thu hp dn m chy.
VI. BIN PHP PHNG NGA, NG PH KHI C S C
1. Khi trn , d r mc nh: lp tc tm ngun nc phun vo (hoc di vo), ct, t dp
vo ni b d r cch ly vi khng kh, dng nc di vo lm lnh phn pht pho trn ,
sau thu gom pht pho trn vo thit b cha c sn nc, hon ton pht pho chm
trong nc.
2. Khi trn , d r ln din rng.
Ban u xc nh mc d r, trn . Nu pht chy th trin khai ton b cc phng tin
cha chy nh bnh cu ho, vi cu ho ngn chn v dp tt m chy. Ngn nga khng cho
m chy lan rng v chy li, s dng cc dng c thu gom pht pho chuyn vo cc b, bn
cha c sn nc. Nu khi lng pht pho qu ln th dng t, ct p khoanh vng v x
y nc lm ngp sau thu gom dn pht pho. Hoc dng dung dch vi sa phun ph ln
m chy.
3. X l trn khi vn chuyn
i vi trng hp ang vn chuyn, tm phng n cch ly ho cht ra xa khu dn c, tm ngun
nc v phng tin cha chy, t ct c th s dng c dp m chy. Khc phc hin
tng d r, hoc trn . Thu gom pht pho vo cc bn c cha sn nc.
Trong trng hp khn cp: in thoi cho cc n v cha chy chuyn nghip c h tr.
VII. YU CU V CT GI
1. Bin php, iu kin cn p dng khi s dng, thao tc vi ha cht nguy him:
Cc c s s dng phi c bin php phng chng chy n m bo x l s c khi xy ra, c bin
php ng cu v s l cc s c ho cht.
Ni thao tc s dng phi thng thong, khng c cc nguyn nhn, yu t c th c th gy chy,
cht oxi hoa mnh, cc thit b phi m bo an ton, khng d r.
Ngi thao tc phi c tp hun an ton, c th tham gia x l cc s c c th xy ra. Phi s
dng phng tin bo v c nhn ph hp ( Qun o, gng tay, ng chng chy, mt l phng
c). Khi thao tc khng c pht pho tip xc vi khng kh. Khi vn chuyn tun th
theo nguyn tc vn chuyn ho cht c hi bng ng b.
2. Bin php, iu kin cn p dng khi bo qun:
Ni bo qun phi c bin php phng chng chy n m bo x l s c khi xy ra, c bin
php ng cu v x l cc s c ho cht.
Cc thng cha pht pho pha trn phi c lp nc dy >15cm.
Ni bo qun v xung quanh phi thng thong, nhit khng qu 40
O
C, khng c cc yu t c
th c th gy chy, xa ngun nhit, cht oxi ho mnh, thit b cha ng phi m bo an ton,
khng d r.
Khng c xp chng trc tip cc phuy cha pht pho ln nhau, khng c xp nging ng.
Ngoi nhn vin trng gi kho khng c cho ngi khc ra vo khi khng c phn cng.
Khng c lm cc cng vic khc trong khu bo qun ho cht pht pho.
VIII. TC NG LN NGI V YU CU V THIT B BO V C NHN
1. Cc bin php hn ch tip xc cn thit:
4/6

Tuyt i khng c tip xc trc tip vi pht pho, phi dng kp chuyn dng gp pht pho
hoc cc vt dng gin tip nh cuc, xng xc, thu gom, san chit pht pho.
2. Cc phng tin bo h c nhn khi lm vic
- Bo v mt: eo knh bo h trng nu cn thit.
- Bo v thn th: S dng bo h lao ng chng chy, m nha cng, khu trang hoc mt l
phng c. ( Qun o da, qun o chng chy).
- Bo v tay: gng tay cao su, gng tay da, chng chy.
- Bo v chn: ng cao su, giy da.
3. Phng tin bo h trong trng hp x l s c:
Qun o chng chy, chng axit, giy da, gng tay da, khu trang phng c hoc mt l phng
c c bnh dng kh, m bo him u.
4. Cc bin php v sinh:
Tm ra bng nc lnh sch s sau khi thao tc v tip xc vi pht pho. Khng c n ung
khi lm vic, bo h lao ng khng c mang v nh.
IX. C TNH L, HA CA HA CHT
Trng thi vt l: dng sp im si (
0
C): 277
Mu sc: mu vng hoc trng. im nng chy (
0
C): 44.1
Mi c trng: khng mi
im bng chy (
0
C) (Flash point) theo phng
php xc nh: nhit phng t bc chy khi
tip xc vi khng kh.
p sut ha hi (mm Hg) nhit , p
sut tiu chun: 100.000Pa i vi:
Pht pho en 431
O
C
Pht pho 276
O
C
Nhit t chy (
0
C): t bc chy nhit
thng khi tip xc vi khng kh.
ha tan trong nc : 0.003 g/lt Khi lng ring (kg/m
3
): 1.880
X. MC N NH V KH NNG HOT NG CA HA CHT
1. Tnh n nh ( bn nhit, nhy vi tc nhn ma st, va p...) Pht pho l ho cht d t
pht chy, khi c oxi ngay c trong iu kin nhit bnh thng cng c th t pht chy. Ch
n nh khi ngm trong nc.
2. Kh nng phn ng:
- Phn ng phn hy v sn phm ca phn ng phn hy: Pht pho tu thuc vo iu kin c th
chuyn ho thnh pht pho en v pht pho .
- Cc phn ng nguy him : Pht pho d chy trong khng kh sinh nhit gy bng cho ngi v
chy thc vt.
- Cc cht c phn ng sinh nhit, kh c hi, cc cht khng bo qun chung...: Pht pho d tc
dng vi oxi to thnh P
2
O
5
, nu c hi nc to thnh cc dng ca axit pht pho rc, c tnh n
mn cao v c tnh cao, ngoi ra c th to thnh PH
3
c tnh cao vi ngi v sinh vt. Pht
pho d phn ng vi cc ho cht c tnh oxi ho mnh nh Halogen, oxi, kim, kim loi sinh ra
cc hp cht c tnh c cao nh PH
3
, ZnP
XI. THNG TIN V C TNH
Tn thnh phn Loi ngng Kt qu
ng
tip xc
Sinh vt th
Pht pho vng LD 50 mg

Da, h hp... Chut,
Pht pho dng kh Gii hn tip xc 0.1 mg/m
3
H hp
Pht pho dng kh
Gii hn trong mi
trng lm vic
0.003
mg/m
3

H hp
Pht pho xm nhp vo c th xm nhp vo c th 0.01 g
C th gy
cht ngi
1. Cc nh hng mn tnh vi ngi : Nu xm nhp vo c th vi liu lng nhiu s gy tc
hi cp: ho, kh th, th gp, au hng, m man bt tnh dn n t vong.
2. Cc nh hng c khc: Tip xc nhiu gy n mn da, phi c th gy ph phi. C th tc
ng n gan, thn, tip xc lu di c th nh hng n xng. Nut phi pht pho c th b hu
5/6



hoi gan, tim v thn.
XII. THNG TIN V SINH THI
1. c tnh vi sinh vt
Tn thnh phn
Loi
sinh vt
Chu k nh
hng
Kt qu
Pht pho tan trong nc C, to
Cha c
thng tin

Khi b chy to thnh Axit photphoric
v ha tan vo trong nc
C, to
Thay i PH ca nc, c th
gy cht sinh vt
Khi P
4
chy sinh ra P
2
O
5
, PH
3
,
photphoric
Gy c vi ngi v sinh vt
2. Tc ng trong mi trng
- Mc phn hy sinh hc: Phn ln c thc vt, sinh vt hp thu to nn cu to chng.
- Sn phm ca qu trnh phn hy sinh hc:Cha c thng tin.
- Mc c tnh ca sn phm phn hy sinh hc: C th gy nn hin tng ph dng thc v
ng vt.
XIII. YU CU TRONG VIC THI B
1. Thng tin quy nh tiu hy (thng tin v lut php): Khng c thi trc tip ra mi trng.
2. Xp loi nguy him ca cht thi: 02 10 01(theo thng t 12/2011/TT-BTNMT ngy
14/04/2011.)
3. Bin php tiu hy: t trong thng kn v cho hp th vo nc to thnh axit photphoric, tc
dng vi cc kim loi v oxit kim loi, kim. C th chuyn ho thnh pht pho en, .
4. Sn phm ca qu trnh tiu hy, bin php x l: Cc sn phm c gc photphat, c th ti
s dng.
XIV. YU CU TRONG VN CHUYN
Tn quy nh
S
UN
Tn vn
chuyn
ng bin
Loi, nhm
hng nguy him
Quy cch
ng gi
Nhn vn
chuyn
Thng tin
b sung
Quy nh v vn
chuyn hng nguy
him ca Vit Nam:
104/2009N-CP

1381

d chy, c
4.2 +6.1
ng trong cc
thng phuy
bng tn

Quy nh v vn
chuyn hng nguy
him quc t

XV. QUY CHUN K THUT V QUY NH PHP LUT PHI TUN TH
1. Tnh trng khai bo, ng k cc quc gia khu vc trn th gii : Cha c thng tin.
2. Phn loi nguy him theo quc gia khai bo, ng k :Mc nguy him : 1.
XVI. THNG TIN CN THIT KHC
Ngy thng bin son phiu: thng 02 nm 2012
Ngy thng sa i, b sung gn nht: thng 02 nm 2012
Tn t chc, c nhn son tho: Cng ty TNHH MTV Ha cht C bn Min Nam
Lu ngi c:
Nhng thng tin trong Phiu an ton ha cht ny c bin son da trn cc kin thc hp l v
mi nht v ha cht nguy him v phi c s dng thc hin cc bin php ngn nga ri
ro, tai nn.
Ha cht nguy him trong Phiu ny c th c nhng tnh cht nguy him khc ty theo hon cnh
s dng v tip xc