Chuyn : IN PHN

I - NH NGHA
in phn la dung nng lng in thc hin phn ng oxi hoa - kh xy ra trn catot va anot
Tai catot (cc m) xy ra qua trinh kh (nhn e)
Tai Anot (cc dong) xy ra qua trinh oxi hoa (cho e)
Khac voi phn ng oxi hoa kh thng thong, phn ng in phn do tac dung cua in nng va cac cht trong
mi trong in phn khng trc tip cho nhau e ma phi truyn qua dy dn.
II CC trng hp in phn
1. in phn nng chy
Phong phap phn nong chy chi ap dung iu ch cac kim loai hoat ng rt manh nh: Na, K, Mg, Ca, Ba, Al
a) in phn nng chy oxit: ch dng iu ch Al
6
NaAlF
2 3 2
2Al O 4Al3O
* Tac dung cua Na3AlF6 (criolit):
Ha nhit cho phn ng
Tng kh nng dn in cho Al
Ngn chn s tip xuc cua oxi khng khi voi Al
Qu trnh in phn:
Catot (-):
3
2Al 6e 2Al
Anot ()
Do n cc m bng grapht (than ch) nn b khY snh ra anot n mn.
2-
2
2
2 2
6O -6e 3O
2CO 2CO
2COO 2CO



Phng trnh phn ng n phn cho c 2 cc :
dpnc
2 3 2
dpnc
2 3
dpnc
2 3 2
2Al O 4Al3O
Al O 3C 2Al3CO
2Al O 3C 4Al3CO



KhY anot snh ra thng hn hp khY CO, CO
2
v O
2
. O n gn ng ta thng ch xt
phng trnh:
6
NaAlF
2 3 2
2Al O 4Al3O
b) in phn nng chy hiroxit (Ch p dng O Ou ch cc km o kOm:
Na, K)
Tng qut:
dpnc
2 2
1
2MOH 2M O H O (MNa, K,...)
2

Catot (-): 2M
+
+2e

2M Anot (+): 2OH

-
-2e

2 2
1
O H O
2

c) in phn nng chy mui clorua (Ch p dng O Ou ch km o kOm v
kOm th)
Tng qut:
dpnc
x 2
2MCl 2MxCl (x1,2)
2. in phn dung dch
- p dng O Ou ch cc km o trung bnh, yu.
- Trong n phn dung dch nc g mt va tr quan trng.
+ L m trng O cc caton v anon d chuyOn vO 2 cc.
+ kh nc tham ga vo qu trnh n phn.
catot:

2
2H 2e H anot:
-
2 2
1
2OH -2e O H O
2

VO bn chEt nc nguyn chEt khng b n phn do n qu n ( I=0). Do vy mun
n phn nc cn ho thm cc chEt n y mnh nh: mu tan, axt mnh, baz
mnh...
Bin son: Nguyn !"n #h$
1
Chuyn : IN PHN
vit c cc phng trnh in ly mt cch y c chnh xc, chng ta cn l !
mt "# $y t%c &inh nghim "a 'y(
Quy tc 1: Qu trnh !h" xy ra # catot
+ Cc on km o t A tr vO u dy thc t khng b kh thnh on km o kh n
phn dung dch
+ Cc on sau A th b kh thnh km o, v th t u tn ngc t d n.
Trong c bt ch on H
+
un b kh cu cng trong dy u tn trn.
Quy tc $: Qu trnh oxi ho # anot
u tn 1: cc km o trung bnh v yu.
u tn 2:
2- - - - -
S ~I ~Br ~Cl ~OH
- Nu kh n phn anot cha ng th km o v anon (on m) th anon khng
b n phn.
- Cc anon cha ox nh:
- 2- 2- 2- 3- -
3 4 3 3 4 4
NO ;SO ;CO ;SO ;PO ;ClO . co nh khng n phn.
III - nh lut in phn
A Q A It
m .
n F n 96500
Trong :
+ m: s gam dng sm phEm snh ra trn n cc
+ n: s eectron trao
+ O = It: n ng I qua dung dch v cng dnh n I, th gan t v c n
v cuong; I (A); t(gy)
+ F: hng s Faraday; 1F = 96487 C

96500C
+
A
n
: g ng ng n ho, g tt ng ng, kY hu .
%%% &ng '(ng c)a ph*ng php in phn:
)* i+ ch mt "# &im l,-i(
.* i+ ch mt "# phi &im( /
.
0 1
.
0 2
.
0 3l
.
4* i+ ch mt "# hp ch5t( 6mn1
7
0 8a1/0 /
.
1
.
, n9c :iav;n<
7* =inh ch mt "# &im l,-i( 3, >?, @n, 2;, Ag, A<
B* C- in(
in ph'n v9i an,t tan c DEng tr,ng &F thGt m- in, nhHm ?I, v &im l,-i&hJi ?K Ln
mMn v t-, vN Op ch, vGt m-* =r,ng m- in, an,t l &im l,-i DEng m- nh( 3, Ag, A,
3r, 8i** cat,t l vGt cn c m-* P9p m- r5t mJng thQng cR Dy tS( B*)T
UB
n )*)T
U4
cm*
I! !n d"ng
A #$i tp %&u
+,i 1: n phn dung dch KC
-ii:
Phng trnh n :
-
2
-
H O H OH
KCl K Cl



+ catot: (-): K
+
; H
+
, trong K
+
khng b n phn (theo quy tc 1)

2
2H 2e H
K
+

K
+
+ anot (-):
-
OH
;
-
Cl
th th t n phn :
-
Cl >
-
OH (theo quy tc 2 - u tn 2)
-
2
2Cl -2e Cl
-
OH

-
OH
Do phng trnh n phn :
Bin son: Nguyn !"n #h$
%
Chuyn : IN PHN
2KC + 2H
2
O
dpdd

2KOH + H
2
+ C
2
Nu
-
Cl
ht th n t
-
OH
tham ga qu trnh n phn:
-
2 2
1
2OH -2e O H O
2

Nh vy, n y nc n phn v KOH ng va trn xc tc:
dpdd
2 2 2 KOH
1
H O H O
2

+,i $: n phn dung dch CuSO
4
-ii:
+ catot: (-): Cu
2+
; H
+
: Cu
2+
+2e

Cu
+ anot (-):
2-
4
SO ;
-
OH :
-
2 2
1
2OH -2e O H O
2

Do phng trnh n phn : CuSO
4
+ H
2
O
dpdd

Cu + H
2
SO
4
+
2
1
O
2

+,i .: n phn dung dch CuSO
4
v ant Cu
G:
+ catot: (-): Cu
2+
; H
+
: Cu
2+
+2e

Cu
+ anot (-): Cu;
-
OH : Cu - 2e

Cu
2+
Nh vy, catot Cu snh ra bao nhu th anot b tan ra bEy nhu; trc v sau n
phn ng CuSO
4
khng . Ou trnh ny dng O m v tnh uyn km o nguyn
chEt.
+,i /: n phn dung dch hn hp CuSO
4
a mo v KBr b mo.
-ii:
- - 2 2-
H O H OH ; KBr K Br ; CuSO Cu SO
2 4 4



+catot (-):
2
H ; K ; Cu
th t n phn
2
Cu ~H
cn K
+
khng b n phn
2
Cu 2e Cu
ht
2
Cu
th

2
2H 2e H
+ Anot (+):
- - 2-
OH ; Br ; SO
4
th t n phn :
- -
Br ~OH
; cn
2-
SO
4
khng b n
phn.
-
Br -2e Br
2

ht Br
-
th
-
2 2
1
2OH -2e O H O
2

Phng trnh n phn:
dpdd
CuSO 2KBr CuBr K SO
4 2 2 4

+ Nu: b > 2a th KBr d :
dpdd
2KBr2H O H Br 2KOH
2 2 2
m.n.x

+ Nu: b < 2a th CuSO
4
d: CuSO
4
+ H
2
O
dpdd

Cu + H
2
SO
4
+
2
1
O
2

+ Nu b = 2a
dpdd
2 2 2 KOH
1
H O H O
2

+,i 0: n phn dung dch CuC
2
, n cc tr bng dng n 5A trong 45 pht 20
gy.TYnh kh ng km o snh ra trn catot v khY snh ra anot ( ktc).
-ii:
PT n phn:
dpdd
CuCl CuCl
2 2

p dng cng thc c:
2 2
6452720 4,512
m 4,512 g n nCu 0,0705 mol V 0,070522,41,5792 lit
Cu Cl Cl
296500 64

# - #$i tp t' gi(i
Bin son: Nguyn !"n #h$
&
Chuyn : IN PHN
+,i 1 : Trong qu trnh n phn nhng caton s d chuyOn vO:
A. Cc dng, y xy ra s ox ho B. Cc dng, y xy ra s kh
C. Cc m, y xy ra s ox ho D. Cc m, y xy ra s kh
+,i $: Ou trnh xy ra t cc n cc kh n phn dung dch AgNO3 :
A. Cc dng : Kh on NO3
-
B. Cc m : Ox ho on NO3
-

C. Cc m : Kh on Ag
+
D. Cc dng : Kh H2O
+,i .: Mt dung dch X cha ng th NaNO3, Cu(NO3)2, Fe(NO3)3, Zn(NO3)2, AgNO3. Th t cc
km o thot ra catot kh n phn dung dch trn :
A.Ag, Fe,Cu, Zn, Na B. Ag, Fe, Cu, Zn C. Ag, Cu, Fe D.Ag,Cu, Fe, Zn, Na
+,i / Phn ng n phn nng chy no d y b vt sa sn phEm?
A. A2O3
dpnc

2A+3/2O2 B. 2NaOH
dpnc

2Na+O2+ H2
C. 2NaC
dpnc

2Na+C2 D. CaBr2
dpnc

Ca + Br2
+,i 0 Dy gm cc km o c Ou ch trong cng nghp bng phng php n phn hp
chEt nng chy ca chng . (H KHI A 2007)
A. Na, Ca, Zn B. Na, Cu, A C. Na, Ca, A D. Fe, Ca, A
+,i 1: Kh n phn hn hp dung dch NaC v CuSO4 , nu dung dch sau kh n phn ho
tan c NaHCO3 th s xy trng hp no sau y:
A. NaC d B. NaC d hoc CuSO4 d
C. CuSO4 d D. NaC v CuSO4 b n phn ht
+,i 2: n phn dung dch cha a mo CuSO4 v b mo NaC ( v n cc tr , c mng ngn
xp ) . O dung dch sau n phn m phenophtaen chuyOn sang mu hng th Ou kn
ca a v b ( bt on SO4
2-
khng b n phn trong dung dch ) (H KHI b 2007)
A. b > 2a B. b =2a C. b < 2a D. 2b =a
+,i 3: Kh n phn c vch ngn dung dch gm NaC, HC . Sau mt th gan n phn xc
nh xy ra trng hp no sau y, trng hp no ng :
A. Dung dch thu c c m qu tYm ha B. Dung dch thu c khng mu qu
tYm
C. Dung dch thu c m xanh qu tYm D. A, B, C Ou ng
+,i 4 5 ng dng no d y khng ph ng dng ca s n phn ?
A. Ou ch mt s km o, ph km v hp
chEt
B. Thng qua cc phn ng O sn snh ra
dng n
C. Tnh ch mt s k.o nh Cu, Pb, Zn, Fe,
Ag, Au...
D. M Zn, sn, N, Ag, Au... bv v trang
trY km o
+,i 16 5 n phn n ht 0,1 mo Cu (NO3)2 trong dung dch v n tc tr, th sau n
phn kh ng dung dch gm bao nhu gam
A. 1,6g B. 6,4g C. 8,0 gam D. 18,8g
+,i 115 TYnh thO tYch khY (ktc) thu c kh n phn ht 0,1 mo NaC trong dung dch v
n cc tr, mng ngn xp.
A. 0,024 t B. 1,120 t C. 2,240 t D. 4,489 t
+,i 1$: n phn dd CuC2 v n cc tr , sau mt th gan thu c 0,32 gam Cu catot v
mt ng khY X anot. HEp th hon ton ng khY X trn vo 200 m d dNaOH nht thng).
Sau phn ng nng NaOH cn 0,05M ( g tht thO tYch ca dung dch NaOH khng
thay ). Nng ban u ca dung dch NaOH . (H KHI A 2007)
A. 0,15 M B. 0,2M C. 0,1 M D. 0,05M
+,i 1.: n phn 200 m dung dch CuSO4 v n cc tr bng dng n mt chOu I = 9,65
A. Kh thO tYch khY thot ra c ha n cc Ou 1,12 Yt (ktc) th dng n phn. Kh -
ng km o snh ra katt v th gan n phn :
A. 3,2gam v1000 s B. 2,2 gam v 800 s C. 6,4 gam v 3600 s D. 5,4 gam v 1800 s
+,i 1/5 phn 200m dd CuSO4 0,5 M v FeSO4 0,5M trong 15 pht v n cc tr v dng
n I= 5A s thu c catot:
A. ch c ng B. Va ng, va st
C. ch c st D. va ng va st v ng m km o t a
+,i 10: n phn dung dch CuSO4 bng n cc tr v dng n c cng I = 0,5A trong
th gan 1930 gy th kh ng ng v thO tYch khY O2 snh ra
A: 0, 64g v 0,112 t B: 0, 32g v 0, 056 C: 0, 96g v 0, 168 D: 1, 28g v 0, 224
Bin son: Nguyn !"n #h$
'
Chuyn : IN PHN
Yt Yt Yt
+,i 11: n phn 200m dung dch hn hp gm HC 0,1M v CuSO4 0,5M bng n cc tr.
Kh katt c 3,2g Cu th thO tYch khY thot ra ant
A : 0, 56 Yt B : 0, 84 Yt C : 0, 672 Yt D : 0,448 t
+,i 12: n phn dd cha 0,2 mo FeSO4 v 0,06mo HC v dng n 1,34 A trong 2 g (n
cc tr, c mng ngn). B qua s ho tan ca co trong nc v co hu suEt n phn 100%.
Kh ng km o thot ra katot v thO tYch khY thot ra anot (ktc) n t :
A. 1,12 g Fe v 0, 896 t hn hp khY C2 , O2. B. 1,12 g Fe v 1, 12 t hn hp khY C2 v
O2.
C. 11,2 g Fe v 1, 12 t hn hp khY C2 v
O2.
D. 1,12 g Fe v 8, 96 t hn hp khY C2 v O
+,i 13: Dung dch cha ng th 0,01 mo NaC; 0,02 mo CuC2; 0,01 mo FeC3; 0,06 mo
CaC2. Km o u tn thot ra catot kh n phn dung dch trn :
A. Fe B. Zn C. Cu D. Ca
+,i 14: Natr, canx, mage, nhm c sn xuEt trong cng nghp bng phng php no:
A. Phng php thu uyn. B. Phng php nht uyn.
C. Phng php n phn. D. Phng php n phn hp chEt nng
chy.
+,i $6: T.tYch khY hro snh ra kh .phn dd cha cng mt ng NaC c mng ngn (1) v
khng c mng ngn (2) :
A. bng nhau. B. (2) gEp (1).
C. (1) gEp (2). D. khng xc nh.
+,i $1: Trong qu trnh n phn dung dch KC, qu trnh no sau y xy ra cc dng
(anot)
A. on C

b ox ho. B. on C

b kh.
C. on K
+
b kh. D. on K
+
b ox ho.
+,i $$: n phn v n cc tr dung dch mu corua ca km o ho tr (II) v cng
dng n 3A. Sau 1930 gy, thEy kh ng catot tng1,92 gam. Km o trong mu corua trn
km o no d y
A. N B. Zn C. Cu D. Fe
+,i $.: n phn dng n cc tr dung dch mu sunfat km o ho tr II v cng dng
n 3A. Sau 1930 gy thEy kh ng catot tng 1,92 gam, Cho bt tn km o trong mu
sunfat (cho Fe = 56, N = 59, Cu = 64, Zn = 65)
A. Fe B. Ca C. Cu D. Mg
+,i $/: Ou no khng ng trong cc Ou sau:
A. n phn dung dch NaC thEy pH dung dch tng dn
B. n phn dung dch CuSO4 thEy pH dung dch gm dn
C. n phn dung dch NaC + CuSO4 thEy pH dung dch khng
D. n phn dung dch NaC + HC thEy pH dung dch tng dn
(co thO tYch dung dch kh n phn khng , kh c mt NaC th dng thm mng
ngn)
+,i $0 n phn d dcha a mo CuSO4 v b mo NaC (v n cc tr c mng ngn xp). O d
d sau kh n phn m phenophtaen chuyOn sang mu hng th Ou kn ca a v b
(bt on SO4
2-
khng b n phn trong dung dch)
A. b > 2a B. b = 2a C. b < 2a D. 2b = a
+,i $1: Tn hnh n phn hon ton dung dch X cha AgNO3 v Cu(NO3)2 thu c 56 gam
hn hp km o catot v 4,48 Yt khY anot (ktc). S mo AgNO3 v Cu(NO3)2 trong X n t
(cho Ag = 108, Cu = 64)
A. 0,2 v 0,3 B. 0,3 v 0,4 C. 0,4 v 0,2 D. 0,4 v 0,2
+,i $2: phn 100m dung dch A cha ng th HC 0,1M v NaC 0,2 M v n cc tr c
mng ngn xp t kh anot thot ra 0,224 Yt khY (ktc) th ngng phn. D d sau kh phn
c pH (co thO tYch d d thay khng ng kO)
A. 6 B. 7 C. 12 D. 13
+,i $3: p n ht 0,1 mo Cu(NO3)2 trong dd v n cc tr, th sau phn kh ng d dch
gm bao nhu gam ?
A. 1,6 gam B. 6,4 gam C. 8,0 gam D. 18,8 gam
Bin son: Nguyn !"n #h$
(
Chuyn : IN PHN
+,i $4: Ou ch Cu t dung dch Cu(NO3)2 bng phng php no th thu c Cu tnh kht
99,999% ?
A. Phng php thy uyn. B. Phng php nht uyn
C. Phng php n phn D. C A, B, C
+,i .6: Kh phn 25,98 gam otua ca mt km o X nng chy, th thu c 12,69 gam ot.
Cho bt cthc mu otua
A. KI B. CaI2 C. NaI D. CsI
+,i .1: Trong cng nghp natr hroxt c sn xuEt bng phng php
A. n phn dung dch NaC, khng c mng ngn n cc
B. n phn dung dch NaNO3, khng c mng ngn n cc
C. n phn dung dch NaC, c mng ngn n cc
D. n phn NaC nng chy
+,i .$:n phn dung dch CuC2 v n cc tr, sau mt th gan thu c 0,32 gam Cu
catot v mt ng khY X anot. HEp th hon ton ng khY X trn vo 200 m dung dch NaOH (
nht thng). Sau phn ng, nng NaOH cn 0,05M (g tht thO tYch dung dch
khng thay ). Nng ban u ca dung dch NaOH (cho Cu = 64)
A. 0,15M B. 0,2M C. 0,1M D. 0,05M
+,i ..: Ho tan 40 gam mu CdSO4 b Em vo nc. O n phn ht cam trong dung
dch cn dng dng n 2,144A v th gan 4 g. Phn trm nc cha trong mu
A. 18,4% B. 16,8% C. 18,6% D. 16%
+,i ./: n phn 300m dung dch CuSO4 0,2M v cng dng n 3,86A. Kh ng km
o thu c catot sau kh n phn 20 pht (cho Cu = 64; S = 32; O = 16)
A. 1,28 gam B.1,536 gam C. 1,92 gam D. 3,84 gam
+,i .0: n phn dung dch MSO4 kh anot thu c 0,672 Yt khY (ktc) th thEy kh ng
catot tng 3,84 gam. Km o M (cho Cu = 64; Fe = 56; N = 59; Zn = 65)
A. Cu B. Fe C. N D. Zn
+,i .1: n phn nng chy mu corua ca km o M, anot thu c 1,568 Yt khY (ktc),
kh ng km o thu c catot 2,8 gam. Km o M
A. Mg B. Na C. K D. Ca
+,i .2: C 200m dung dch hn hp Cu(NO3)2 v AgNO3. O n phn ht on km o trong
dung dch cn dng dng n 0,402A, th gan 4 g, trn catot thot ra 3,44 gam km o. Nng
mo/t ca Cu(NO3)2 v AgNO3
A. 0,1 v 0,2 B. 0,01 v 0,1 C. 0,1 v 0,01 D. 0,1 v 0,1
+,i .3: Tn hnh n phn (c mng ngn xp) 500 m dung dch cha hn hp HC 0,02M v
NaC 0,2M. Sau kh anot bay ra 0,448 Yt khY ( ktc) th ngng n phn. Cn bao nhu m
dung dch HNO3 0,1M O trung ho dung dch thu c sau n phn
A. 200 m B. 300 m C. 250 m D. 400 m
+,i .4: Ho tan 1,28 gam CuSO4 vo nc r em n phn t hon ton, sau mt th gan thu
c 800 m dung dch c pH = 2. Hu suEt phn ng n phn
A. 62,5% B. 50% C. 75% D. 80%
+,i /6: Ho tan 5 gam mu ngm nc CuSO4.nH2O r em n phn t hon ton, thu c
dung dch A. Trung ho dung dch A cn dung dch cha 1,6 gam NaOH. G tr ca n
A. 4 B. 5 C. 6 D. 8
+,i /1: n phn d d mt mu ntrat km o v hu suEt dng n 100%, cng dng
n khng 7,72A trong th gan 9 pht 22,5 gy. Sau kh kt thc kh ng catot tng
n 4,86 gam do km o bm vo. Km o
A. Cu B. Ag C. Hg D. Pb
+,i /$: Tn hnh phn (c mng ngn xp) dung dch X cha hn hp gm 0,02 mo HC v
0,05 mo NaC v Cng dng n 1,93A trong th gan 3000 gy, thu c dung dch Y.
Nu cho qu tYm vo X v Y th thEy
A. X m qu tYm, Y m xanh qu tYm.
B. X m qu tYm, Y m qu tYm.
C. X qu tYm, Y khng mu qu tYm.
D. X khng mu qu tYm, Y m xanh qu tYm.
Cu '&: Co cac qua trinh in phn sau:
(1) in phn dung dich CuSO4 voi anot lam bng kim loai Cu.
(2) in phn dung dich FeSO4 voi 2 in cc bng graphit.
Bin son: Nguyn !"n #h$
)
Chuyn : IN PHN
(3) in phn Al2O3 nong chy voi 2 in cc bng than chi.
(4) in phn dung dich NaCl voi anot bng than chi va catot bng thep.
Cac qua trinh in phn ma cc dong bi mon la
*.(1),(2). B.(1),(3). C.(2),(3). +.(3),(4).
Cu '': p mt dd gm a mol CuSO4 va b mol NaCl. Nu b ~ 2a ma o catot cha co khi thoat ra thi dd sau phn cha
*. Na

, SO4
2-
, Cl
-
. B. Na

, SO4
2-
, Cu
2
. C. Na

, Cl
-
. +. Na

, SO4
2-
, Cu
2
, Cl
-
.
Cu '(: in phn (in cc tro, mang ngn xp) mt dung dich gm a mol CuSO4 va b mol NaCl. Dung dich sau in
phn co th hoa tan c kim loai nhm, mi quan h giua a va b la
*. 2ab B. 2a~b. C. 2a b. D. 2a # b.
Cu '): Khi in phn in cc tro co mang ngn dung dich hn hp gm NaCl va CuSO4 n khi NaCl va
CuSO4 u ht nu dung dich sau in phn hoa tan c Fe thi
*. NaCl ht troc CuSO4. B. CuSO4 ht troc NaCl.
C. NaCl va CuSO4 cung ht. +. xy ra trong hp A hoc B.
Cu ',: Sn phm thu c khi in phn NaOH nong chy la gi ?
*. O catot (-): Na va o anot (): O2 va H2O. B. O catot (-): Na2O va o anot (): O2 va H2.
C. O catot (-): Na va o anot (): O2 va H2. +. O catot (-): Na2O va o anot (): O2 va H2O.
Cu '-: Dy cac kim loai u co th c iu ch bng phong phap in phn dung dich mui cua chung la:
*. Fe, Cu, Ag. B. Mg, Zn, Cu. C. Al, Fe, Cr. +. Ba, Ag, Au.
Cu '.: in phn dung dich CuSO4 voi in cc tro, cong dong 5A. Khi o anot co 4g khi oxi bay ra thi
ngng. iu nao sau y lun ung ?
*. Khi lng ng thu c o catot la 16g. B. Thoi gian in phn la 9650 giy.
C. pH cua dung dich trong qua trinh in phn lun gim. +. Khng co khi thoat ra o catot.
Cu (/: in phn nong chy mui clorua cua mt kim loai kim, thu c 0,896 lit khi (ktc) o anot va 3,12
gam kim loai o catot. Cng thc cua mui in phn la:
*. NaCl. B. LiCl. C. KCl. +. CsCl.
Cu (1: in phn nong chy Al2O3 voi anot than chi (hiu sut in phn 100) thu c m kg Al o catot va
67,2 m
3
(o ktc) hn hp khi X co ti khi so voi hiro bng 16. Ly 2,24 lit (o ktc) hn hp khi X suc vao dung
dich noc vi trong (d) thu c 2 gam kt tua. Gia tri cua m la
*. 54,0. B. 75,6. C. 67,5. +. 108,0.
Cu (%: in phn dung dich cha HCl va KCl voi mang ngn xp, sau mt thoi gian thu c dung dich chi
cha mt cht tan va co pH 12. Vy:
*. chi co HCl bi in phn. B. chi co KCl bi in phn.
C.HCl va KCl u bi in phn ht. +. HCl bi in phn ht, KCl bi in phn mt phn
Cu (&: in phn co mang ngn 500 ml dung dich cha hn hp gm CuCl2 0,1M va NaCl 0,5M (in cc tro,
hiu sut in phn 100) voi cong dong in 5A trong 3860 giy. Dung dich thu c sau in phn co kh
nng hoa tan m gam Al. Gia tri lon nht cua m la *. 4,05. B. 2,70. C. 1,35. +. 5,40.
Cu (': in phn 200 ml dung dich hn hp gm HCl 0,1M va CuSO4 0,5M bng in cc tro. Khi o
catot co 3,2 gam Cu thi th tich khi thoat ra o anot
*.0,672 lit. B.0,84 lit. C.6,72 lit. +.0,448 lit.
Cu ((: Khi pdd CuSO4 ngoi ta thy k.lg catt tng ung bng k.lg anot gim. iu o chng to ngoi ta dung
*. catot Cu. B. catot troC. anot Cu. +. anot tro.
Cu (): in phn 100 ml hn hp dung dich gm FeCl3 1M , FeCl2 2M , CuCl2 1M va HCl 2M voi in cc tro
co mang ngn xp cong dong in la 5A trong 2 gio 40 phut 50 giy o catot thu c
*.5,6g Fe. B.2,8g Fe. C.6,4g Cu. +.4,6g Cu.
Cu (,: in phn dung dich KCl voi in cc tro, mang ngn xp thoi gian 16,1 phut dong in I 5A thu
c 500ml dung dich A. pH cua dung dich A co gia tri la
*. 12,7. B. 1. C. 13. +. 1,3.
Cu (-: in phn 200 ml dung dich CuSO4 voi I1,93A toi khi catot bt u co bot khi thoat ra thi dung lai,
cn thoi gian la 250 giy. Th tich khi thu c o anot (ktc) la
*. 28ml. B. 0,28ml. C. 56ml. +. 280ml.
Cu (.: in phn 100ml dung dich CuSO4 0,1M cho n khi vua bt u sui bot bn catot thi ngung in phn.
pH dung dich ngay khi y voi hiu sut 100 (th tich dung dich c xem nh khng i, ly lg2 0,30) la
*. pH 1,0. B. pH 0,7. C. pH 1,3. +. pH 2,0.
Bin son: Nguyn !"n #h$
,
Chuyn : IN PHN
Cu )/: in phn 100 ml dung dich CuSO4 0,2 M voi I 9,65Ampe. Tinh khi lng Cu bam ln catot khi thoi
gian in phn t1 200 s, t2 500s ln lt la:
*. 0,32g va 0,64g. B. 0,64g va 1,28g. C. 0,64g va 1,32g. +. 0,32g va 1,28g.
Cu )1: in phn dung dich hn hp cha 0,1 mol FeCl3, 0,2 mol CuCl2 va 0,1 mol HCl (in cc tro, mang
ngn xp). Khi o catot bt u sui bot khi thi dung in phn. Tai thoi im nay khi lng catot tng :
*. 0,0 gam. B. 5,6 gam. C. 12,8 gam. +. 18,4 gam.
Cu )%: Co hai binh phn mc ni tip: Binh (1) cha 100ml dd CuSO4 0,1M; Binh (2) cha 100ml ddNaCl
0,1M tin hanh in phn co mang ngn cho toi khi o binh hai tao ra dung dich co pH13 thi ngng in phn.
Gi s th tich dung dich o hai binh khng i. Nng mol cua Cu
2
trong dung dich binh (1) sau in phn la:
*. 0,04M. B. 0,10M. C. 0,05M. +. 0,08M.
Cu )&: Tin hanh in phn hoan toan dung dich X cha 200 ml dd AgNO3 va Cu(NO3)2 thu c 56 gam hn
hp kim loai o catot va 4,48 lit khi o anot (ktc). Nng mol AgNO3 va Cu (NO3)2 trong X ln lt la
*.2M va 1M. B. 1M va 2M. C. 2M va 4M. +. 4M va 2M.
Cu )': Co hai binh .phn mc ni tip nhau. Binh 1 cha dd CuCl2, binh 2 cha dd AgNO3. Tin hanh phn
voi in cc tro, kt thuc phn thy catot cua binh 1 tng ln 1,6gam. Khi lng catot cua binh 2 tng ln la
*. 10,80 gam. B. 5,40 gam. C. 2,52 gam. +. 3,24 gam.
Cu )(: in phn dung dich hn hp cha 0,1 mol FeCl3, 0,2 mol CuCl2 va 0,1 mol HCl (in cc tro, mang
ngn xp). Khi o catot bt u sui bot khi thi dung in phn. Tai thoi im nay khi lng catot tng
*. 0,0 gam. B. 5,6 gam. C. 12,8 gam. +. 18,4 gam.
Cu )): in phn dung dich NaCl n ht (co mang ngn, in cc tro), cong dong in 1,61A thi ht 60
phut. Thm 0,03 mol H2SO4 vao dung dich sau in phn thi thu c mui voi khi lng
*. 4,26 gam. B. 8,52 gam. C. 2,13 gam. +. 6,39 gam.
Cu ),: Sau mt thoi gian in phn 100 ml dung dich CuSO4 voi in cc tro, khi lng dung dich gim 4
gam. lam kt tua ht ion Cu
2
con lai trong dung dich sau khi in phn cn dung 50 ml dung dich H2S 0,5M.
nng mol/l cua dung dich CuSO4 troc luc in phn la
*. 0,375M. B. 0,420M. C. 0,735M +. 0,750M.
Cu )-: phn 200ml dd Fe(NO3)2. Voi dong in mt chiu cong dong in 1A trong 32 phut 10 giy thi vua
phn ht Fe
2
, ngung in phn va yn dd mt thoi gian thi thu c 0,28 g kim loai. Khi lng dung dich gim la
*. 0,16 gam. B. 0,72 gam. C. 0,59 gam. +. 1,44 gam.
Cu ).: phn 2 lit dd hn hp gm NaCl va CuSO4 n khi H2O bi .phn o hai cc thi dung lai, tai catot thu
1,28 g kim loai va anot thu 0,336 lit khi (o ktc). Coi th tich dd khng i thi pH cua dung dich thu c bng.
*. 3. B. 2. C. 12. +. 13
Cu 1%%: in phn 100ml dung dich CuSO4 nng 0,5M voi in cc tro mt thoi gian thi thy khi lng catot tng
1gam. Nu dung dong in mt chiu co cong 1A, thi thoi gian in phn ti thiu la
*. 0,45 gio. B. 40 phut 15 giy. C. 0,65 gio. +. 50 phut 15 giy.
Cu ,/: Co 2 binh in phn mc ni tip binh 1 cha CuCl2, binh 2 cha AgNO3. Khi o anot cua binh 1 thoat ra
22,4 lit mt khi duy nht thi o anot cua binh 2 thoat ra bao nhiu lit khi? (Bit cac th tich o o cung kin).
*. 11,2 lit . B. 22,4 lit. C. 33,6 lit. +. 44,8 lit.
Cu ,%: iu ch 1 tn clo bng cach in phn nong chy NaCl ngoi ta phi dung ti thiu la 1,735 tn
NaCl. Vy hiu sut cua qua trinh la:
*. 59. B. 85. C. 90. +. 95.
Cu ,&: in phn 100 ml dung dich CuSO4 0,2 M va AgNO3 0,1 M.voi cong dong in I 3,86 A. Tinh thoi
gian in phn c mt khi lng kim loai bam bn catot la 1,72g.
*. 250s. B. 1000s. C. 500s. +. 750s.
Cu ,': p 200 ml dd Cu(NO3)2 n khi bt u co khi thoat ra o catot thi ngung. yn dd cho n khi klng
khng i thi klng catot tng 3,2 g so voi luc cha phn. nng mol/l cua dd Cu(NO3)2 troc phn ng la:
*. 0,5 M. B. 0,9 M. C. 1 M. +. 1,5 M.
Cu ,(: p 200ml dd CuSO4 voi in cc tro bng dong in mt chiu I 9,65 A. Khi th tich khi thoat ra o c
hai in cc u la1,12 lit (ktc) thi dung in phn. Khi lng kim loai sinh ra o catot va thoi gian phn la:
*. 3,2g va 2000s. B. 2,2 g va 800s. C. 6,4g va 3600s. +. 5,4g va 800s.
Cu ,): in phn 200 ml dung dich hn hp gm HCl 0,1M va FeSO4 0,5M bng in cc tro.
Khi o catot co 5,6 gam Cu thi th tich khi thoat ra o anot
*.0,672 lit. B.0,84 lit. C.1,344 lit. +.0,448 lit.
Bin son: Nguyn !"n #h$
-
Chuyn : IN PHN
Cu ,,: in phn 200 ml dung dich hn hp gm HCl 0,1M va CuCl2 0,5M bng in cc tro. Khi o catot
co 3,2 gam Cu thi th tich khi thoat ra o anot
*.0,672 lit. B.1,12 lit. C.6,72 lit. +.0,448 lit.
Cu ,-: Cho mt dong in co cong I khng i i qua 2 binh in phn mc ni tip,binh 1 cha
100ml dung dichCuSO4 0,01M, binh 2 cha 100 ml dung dich AgNO3 0,01M. Bit rng sau thoi gian
in phn 500s thi bn binh 2 xut hin khi bn catot, tinh cong I va khi lng Cu bam bn catot o binh
1 va th tich khi (ktc) xut hin bn anot cua binh 1.
*.0,193A;0,032g Cu;5,6 ml O2. B. 0,193A;0,032g Cu;11,2 ml O2.
C.0,386A;0,64g Cu;22,4 ml O2. +. 0,193A;0,032g Cu;22,4 ml O2.
Cu ,.: in phn 400 ml dung dich cha 2 mui KCl va CuCl2 voi in cc tro va mang ngn cho n khi o
anot thoat ra 3,36lit khi(ktc) thi ngung in phn. trung hoa dung dich sau in phn cn 100 ml dd HNO3
1M. Dung dich sau khi trung hoa tac dung voi AgNO3 d sinh ra 2,87 (gam) kt tua trng. Tinh nng mol cua
mi mui trong dung dich troc in phn.
*. |CuCl2|0,25M,|KCl|0,03M. B. |CuCl2|0,25M,|KCl|3M.
C. |CuCl2|2,5M,|KCl|0,3M. +. |CuCl2|0,25M,|KCl|0,3M.
Cu -/: p 200 ml dd CuSO4(dung dich X) voi in cc tro sau thoi gian ngung p thi thy klng X gim. Dd
sau p tdung vua u voi 500ml dd BaCl2 0,3M tao ktua trng. Cho bit klng ring dd CuSO4 la 1,25g/ml; sau
iphn lng H2O bay hoi khng ang k. Nng mol/lit va nng dung dich CuSO4 troc in phn la?
*. 0,35M, 8. B. 0,52, 10. C. 0,75M, 9,6. +. 0,49M, 12.
Cu -1: p 200ml dd Y gm KCl 0,1M va Cu(NO3)2 0,2M voi cong dong in 5A trong thoi gian 1158 giy,
in cc tro, mang ngn xp. Gi s noc bay hoi khng ang k. gim khi lng cua dd sau khi p la
*. 3,59 gam. B. 2,31 gam. C. 1,67 gam. +. 2,95 gam
Cu -%: in phn dung dich X cha 0,4 mol M(NO3)2 (voi in cc tro) trong thoi gian 48 phut 15 giy, thu
c 11,52 gam kimloai M tai catot va 2,016 lit khi (ktc) tai ant.Tn kim loai M va cong dong in la
*. Fe va 24A. B. Zn va 12A. C. Ni va 24A. +. Cu va 12A.
Cu -&: p 500ml dd AgNO3 voi in cc tro cho n khi catot bt u co khi thoat ra thi ngung p . trung
hoa dd sau p cn 800ml dd NaOH 1M. Nng mol AgNO3 va thoi gian in phn la bao nhiu bit I20A
*. 0,8M, 3860s. B. 1,6M, 3860s. C. 1,6M, 360s +. 0,4M, 380s.
Cu -': in phn (in cc tro, mang ngn xp) mt dung dich cha m gam hn hp CuSO4 va NaCl cho toi khi
noc bt u bi in phn o c hai in cc thi dung lai. O anot thu c 0,448 lit khi (o ktc). Dung dich sau in
phn co th hoa tan ti a 0,68g Al2O3.
$. Khi lng cua m la
*. 4,47. B. 5.97. C. c A va B. +. #t qu khac.
0. Khi lng catot tng ln trong qua trinh in phn la
*. 0,85. B. 1,92. C. c A va B. +. #t qu khac.
c. Khi lng dung dich gim trong qua trinh in phn la
*. 2,29. B. 2,95. C. c A va B. +. #t qu khac.
Bin son: Nguyn !"n #h$
.