Archive of SID

EPDM
*

rekabdarf@ripi.ir

EPDM

Tg

VOCl3/Al2Et3Cl3

K .

) (Al/V )(

) Ethylidene Norborene (ENB .

Vistalon 7500, Herlene563

) (FTIR ) oC (ML1+4

.
Al/V

:

) (EPDM

.
.

.

Al/V

) (Tg

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Al/V

1. Ethylene-Propylene-Diene

Archive of SID
...

)(ENB 5-Ethylidene-2- Norbornene

EPDM

) ( .

... .

) (LCB

].[

)(

Hexadiene1,4

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.

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.
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Archive of SID

EPDM

] .[

EPDM

EPDM

( .

CSTR

VCl4

] .[

[acethylacetonate=acac]V(acac)3 VOCl3 VO(OR)3

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. ENB

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1. Cross Linking
2. Chain Branching
3. Composition Distribution
4. HAAG & SANTOS
5. Cozewith

Archive of SID
...

) (

) GC (

] .[

K . K

].[

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* *

) (
.

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].[

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r2

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1. Aging Time

Archive of SID

Al/V

)(Al/V

Tg
)(K

Al/V
)(mol/mol

/
/

[diene]=* mol L-1 K

) (

V+3

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.

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) .(

)
(.

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V+3

Al/V

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Tg + K Al/V

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].[

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Archive of SID
...

)( mol/L

Tg .

Tg .

Tg

/ .

].[

Tg

Tg ).(

)Tg (K

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/
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) ([V]=/* )(

1. Ethylene Incorporation

Archive of SID

)(

] .[

) .(

( .

bar

)(]l+[

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Archive of SID
...

)(mol L-1 min-1

k11

k12

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/*
/*

/*
/*
/*

k22

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/*
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END

<

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1. Podolnyi et al

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Archive of SID

ENB

. Al/V

EPDM

.
Tg

Al/V

ENB

EPDM

ENB

[1] Hofman W., Rubber Technology Handbook, Hanser, Chapter 3, pp. 93-100, 1989.
[2] Karpeles R. & Grossi A.V., EPDM Rubber Technology, Handbook of Elastomers, 2nd Ed., Marcel Decker, Inc.,
2001.
[3] A.Riedel J. & Vander laan R., Ethylene Propylene Rubber, The Vanderbilt Rubber Handbook, 13th Ed., R.T.
Vanderbilt Co., Inc., 1990.
[4] Sobhanmanesh K., & Hajizadeh A., Comparative studies on ethylene/propylene/diene terpolymerization,
Iranian Polymer Journal, Vol. 13, No. 4, pp. 257, 2004.
[5]WakatsukiK.&sabaH.,PresentstateandfutureofEPDMsynthesis,International Polymer Science and
Technology, Vol. 21, No. 2, pp. 72-79, 1994.
[6]HaagM.C.&DosSantosJ.H.Z.,Residualmetalcontentinethylenepropylenedienemonomerssynthesized
usingvanadiumandzirconcenebasedcatalysts,J. Appl. polym. Sci, Vol. 74, pp. 1997-2003, 1999.

www.SID.ir

Archive of SID

...

[7] Cozewith C., Proceedings of the 73rd AIchE Meeting, Chicago, 1980.
[8]CozewithC.,VerStrateG.&JuS.,Nearmonodisperseethylenepropylenecopolymersbydirectziglernatta
polymerization.polymerization.preparation,characterization,properties,Macromolecules, Vol. 21, No. 12, pp.
33603371,1988.
[9]StrateG.V.,Encyclopediaofpolymerscienceandengineering,J. Wiley & Sons, Vol. 6 , pp. 522-525, 1986.
[10]CozewithC.&VerStrateG.,Ethylenepropylenecopolymers.reactivityratios,evaluation,andsignificance,
Macromolecules,Vol.4,No.4,pp.482489,1971.
[11]DolatkhaniM., Cramail H. &DeffieuxA., Linear nonconjugated dienesfrom biomass astermonomers in
EPDMsynthesis,conventionalversusmetallocenecatalysis,Macromol. Chem. Phys., Vol. 197, pp. 2481-2491,
1996.
[12]ZohouriG.H.,VakiliM.,JamjahR.,Nekoomanesh&AhmadjoS.,Studyofvariationinchemicalcomposition
ofEPDMelastomerssynthesizedwithzieglernattacatalystbasedonvanadiumduringterpolymerization,Iranian
Journal of Polymer Science & Tecnology (Persian Edition), Vol. 16, No. 5, pp. 327-332, 2004.
[13]MalmbergA.&LofgrenB.,Theproductionofethene/propene/5ethylidene2norborneneterpolymerusing
metallocenecatalysts:polymerization,characterizationandpropertiesofmetalloceneEPDM,J.Appl. polym. Sci.,
Vol. 66, pp. 35-44, 1997.
[14]HaagM.C.&DosSantosJ.H.Z.,SyntheticandcharacterizationofEPDMfilms,J. Appl. Polym. Sci., Vol. 63,
pp. 535-541, 1998.
[15]HaagM.C.&DosSantosJ.H.Z.,DynamicsimulationandexperimentalevaluationofEPDMterpolymeriza
tionwithvanadiumbasedcatalyst,Vol.70,pp.11731189,1998.
[16] Tanaglia T., Process for the production of ethylene-propylene elastomeric copolymers., U.S. Patent: 5804614,
1998.
[17]GardnerI.J.,CozewithC.&VerstrateG.,TheshapeofcalibrationcurveinIRanalysisofcopolymercompo
sition,Rubber chem.Technol., Vol. 44, pp. 1051, 1971.
[18]VerStrateG.,CozewithC.,WestR.K.&DavisW.M.,Blockcopolymerofpolyethyleneandethylenepro
pylenediene elastomer, synthesis, characterization and properties, Macromolecules, Vol. 32, pp. 3873-3850,
1999.

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