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TRNG I HC VINH
TRNG THPT CHUYN

THI KHO ST CHT LNG LP 12 LN I, NM 2014
Mn: HA HC KHI A, B
(Thi gian lm bi: 90 pht; 50 cu trc nghim)

H v tn .................................................................. S bo danh .......................... M thi 359
Cho khi lng nguyn t ca cc nguyn t (theo vC): C = 12; H = 1; O = 16; S = 32; Cu = 64; Fe = 56; Cr = 52; Al = 27; N = 14;
Ca = 40; Ba = 137; Na = 23; Mg = 24; Cl = 35,5; Zn = 65; K = 39; Ag = 108; Br = 80; P = 31.
A. PHN CHUNG CHO TT C TH SINH (40 cu: T cu 1 n cu 40)
Cu 1: Hp cht thm X c cng thc phn t C
7
H
8
O
2
; 1 mol X phn ng va vi 2 lt dung dch NaOH 1M. S ng phn cu
to tha mn iu kin trn ca X l
A. 8. B. 7. C. 5. D. 6.
Cu 2: Cho hai h cn bng sau trong hai bnh kn:
C (r) + CO
2
(k) 2CO(k) ; H = 172 kJ; CO (k) + H
2
O (k) CO
2
(k) + H
2
(k) ; H = - 41 kJ
C bao nhiu iu kin trong cc iu kin sau y lm cc cn bng trn chuyn dch ngc chiu nhau (gi nguyn cc iu
kin khc)?
(1) Tng nhit . (2) Thm kh CO
2
vo. (3) Thm kh H
2
vo.
(4) Tng p sut. (5) Dng cht xc tc. (6) Thm kh CO vo.
A. 5. B. 2. C. 4. D. 3.
Cu 3: Cho s phn ng:
C
2
H
2

0
t xt ,
X
2
0
3
H
Pd PbCO t / ,
Y
0
HBr (1 : 1)
80 C
Z
Trong X, Y, Z u l cc sn phm chnh. Cng thc cu to thu gn ca Z l
A. CH
2
=CHCHBrCH
3
. B. CH
2
=CHCH
2
CH
2
Br. C. CH
3
CH=CHCH
2
Br. D. CH
3
CBr=CHCH
3
.
Cu 4: Thy phn hon ton 7,55 gam Gly-Ala-Val-Gly trong dung dch cha 0,02 mol NaOH un nng, thu c dung dch X.
Cho X tc dng vi 100 ml dung dch HCl 1M. Sau khi kt thc cc phn ng thu c dung dch Y. C cn cn thn dung dch Y
thu c m gam cht rn khan. Gi tr ca m l
A. 11,21. B. 12,72. C. 11,57. D. 12,99.
Cu 5: Tin hnh cc th nghim sau:
(1) Cho dung dch Na
2
CO
3
vo dung dch AlCl
3
. (2) Sc kh H
2
S vo dung dch FeSO
4
.
(3) Sc kh CO
2
ti d vo dung dch NaAlO
2
(hoc Na[Al(OH)
4
]. (4) Sc kh NH
3
ti d vo dung dch Al(NO
3
)
3
.
(5) Sc kh H
2
S vo dung dch CuSO
4
. (6) Cho dung dch Na
2
S
2
O
3
vo dung dch H
2
SO
4
long.
Sau khi kt thc cc phn ng, c bao nhiu th nghim thu c kt ta?
A. 6. B. 5. C. 4. D. 3.
Cu 6: Hn hp kh X gm CO, CO
2
v N
2
, t khi ca X so vi H
2
l 19. Cho m gam X phn ng hon ton vi 100 ml dung dch
Y cha NaOH 2M v Na
2
CO
3
1,5M, thu c dung dch Z. Cho Z tc dng vi lng d dung dch CaCl
2
, sau khi kt thc phn
ng thu c 10 gam kt ta. Gi tr ca m l
A. 15,2. B. 9,5. C. 13,3. D. 30,4.
Cu 7: Hn hp M gm anehit X v xeton Y. t chy hon ton m gam M cn dng va 0,4 mol O
2
, thu c 0,35 mol CO
2

v 0,35 mol H
2
O. S mol ca Y trong m gam M c th l
A. 0,08 mol. B. 0,10 mol. C. 0,05 mol. D. 0,06 mol.
Cu 8: Cho cc pht biu sau:
(1) Trong hp cht vi oxi, nit c cng ha tr cao nht bng 5. (2) CaOCl
2
l mui kp.
(3) dinh dng ca phn ln c nh gi bng hm lng phn trm photpho trong phn ln.
(4) Amophot l hn hp cc mui (NH
4
)
2
HPO
4
v (NH
4
)
3
PO
4
.
(5) Phn hn hp cha nit, photpho, kali c gi chung l phn NPK.
(6) Bn nhiu phn m amoni s lm tng chua ca t.
S pht biu ng l
A. 1. B. 4. C. 2. D. 3.
Cu 9: Dy gm cc ion (khng k s in li ca H
2
O) cng tn ti trong mt dung dch l
A. Fe
2+
, K
+
, OH

, Cl

. B. Ba
2+
, HSO
4

, K
+
, NO
3

. C. Al
3+
, Na
+
, S
2
, NO
3

. D. Cu
2+
, NO
3

, H
+
, Cl

.
Cu 10: Pht biu no sau y l sai ?
A. Trong cc hp cht, nguyn t kim loi kim ch c s oxi ha + 1.
B. Theo chiu tng dn in tch ht nhn, cc kim loi kim (t liti n xesi) c nhit nng chy gim dn.
C. Kim loi kim dng iu ch mt s kim loi khc bng phng php thy luyn.
D. Cc kim loi kim u tc dng vi nc nhit thng.
Cu 11: Dung dch X gm NaOH x mol/l v Ba(OH)
2
y mol/l v dung dch Y gm NaOH y mol/l v Ba(OH)
2
x mol/l. Hp th ht
0,04 mol CO
2
vo 200 ml dung dch X, thu c dung dch M v 1,97 gam kt ta. Nu hp th ht 0,0325 mol CO
2
vo 200 ml
dung dch Y th thu c dung dch N v 1,4775 gam kt ta. Bit hai dung dch M v N phn ng vi dung dch KHSO
4
u sinh
ra kt ta trng, cc phn ng u xy ra hon ton. Gi tr ca x v y ln lt l
A. 0,1 v 0,075. B. 0,05 v 0,1. C. 0,075 v 0,1. D. 0,1 v 0,05.
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Cu 12: Hp cht mch h X, c cng thc phn t C
4
H
8
O
3
. Khi cho X tc dng vi dung dch NaOH un nng, thu c mui Y
v ancol Z. Ancol Z ha tan c Cu(OH)
2
. S ng phn cu to tha mn iu kin trn ca X l
A. 3. B. 1. C. 2. D. 4.
Cu 13: S ipeptit mch h ti a c th to ra t mt dung dch gm: H
2
NCH
2
CH
2
COOH, CH
3
CH(NH
2
)COOH,
H
2
NCH
2
COOH l
A. 3. B. 2. C. 9. D. 4.
Cu 14: Cho 7,6 gam hn hp X gm Mg v Ca phn ng va vi 4,48 lt (ktc) hn hp kh Y gm Cl
2
v O
2
thu c 19,85
gam cht rn Z ch gm cc mui clorua v cc oxit kim loi. Khi lng ca Mg trong 7,6 gam X l
A. 2,4 gam. B. 1,8 gam. C. 4,6 gam. D. 3,6 gam.
Cu 15: Hn hp kh X gm O
2
v O
3
, t khi ca X so vi H
2
l 17,6. Hn hp kh Y gm C
2
H
4
v CH
4
, t khi ca Y so vi H
2

l 11. Th tch hn hp kh X (ktc) ti thiu cn dng t chy hon ton 0,044 mol hn hp kh Y l
A. 3,36 lt. B. 2,24 lt. C. 1,12 lt. D. 4,48 lt.
Cu 16: Cho mt s tnh cht sau: (1) cu trc mch khng phn nhnh; (2) tan trong nc; (3) phn ng vi Cu(OH)
2
; (4) b thy
phn trong mi trng kim long, nng; (5) tham gia phn ng trng bc; (6) tan trong dung dch [Cu(NH
3
)
4
](OH)
2
; (7) phn ng
vi HNO
3
c (xc tc H
2
SO
4
c). Cc tnh cht ca xenluloz l
A. (3), (6), (7). B. (1), (4), (6), (7). C. (2), (3), (5), (6). D. (1), (6), (7).
Cu 17: Cho 200 ml dung dch H
3
PO
4
1M vo 500 ml dung dch KOH 1M. Mui to thnh v khi lng tng ng khi kt thc
cc phn ng (b qua s thy phn ca cc mui) l
A. K
2
HPO
4
17,4 gam; K
3
PO
4
21,2 gam. B. KH
2
PO
4
13,6 gam; K
2
HPO
4
17,4 gam.
C. KH
2
PO
4
20,4 gam; K
2
HPO
4
8,7 gam. D. KH
2
PO
4
26,1 gam; K
3
PO
4
10,6 gam.
Cu 18: Khi ni v kim loi kim th, pht biu no sau y l sai ?
A. Cc kim loi canxi v stronti c cng kiu mng tinh th lp phng tm din.
B. T beri n bari kh nng phn ng vi H
2
O gim dn.
C. Phng php c bn iu ch kim loi kim th l in phn mui clorua nng chy ca chng.
D. Khi t nng, cc kim loi kim th u bc chy trong khng kh.
Cu 19: Mt mu nc cng c cha cc ion: Ca
2+
, Mg
2+
, HCO
3

, Cl

, SO
2
4

. Cht lm mm mu nc cng trn l

A. HCl. B. NaHCO
3
. C. Na
3
PO
4
. D. BaCl
2
.
Cu 20: Cho dy cc cht: phenyl clorua, benzyl clorua, etylmetyl ete, mantoz, tinh bt, nilon - 6, poli(vinyl axetat), t visco,
protein, metylamoni clorua. S cht trong dy tc dng c vi dung dch NaOH long, un nng l
A. 8. B. 7. C. 6. D. 5.
Cu 21: Hn hp X gm C
3
H
6
, C
4
H
10
, C
2
H
2
v H
2
. Cho m gam X vo bnh kn c cha mt t bt Ni lm xc tc. Nung nng bnh
thu c hn hp Y. t chy hon ton Y cn dng va V lt O
2
(ktc). Sn phm chy cho hp th ht vo bnh ng nc
vi trong d, thu c mt dung dch c khi lng gim 21,45 gam. Nu cho Y i qua bnh ng lng d dung dch brom trong
CCl
4
th c 24 gam brom phn ng. Mt khc, cho 11,2 lt (ktc) hn hp X i qua bnh ng dung dch brom d trong CCl
4
, thy
c 64 gam brom phn ng. Bit cc phn ng u xy ra hon ton. Gi tr ca V l
A. 21,00. B. 14,28. C. 10,50. D. 28,56.
Cu 22: Cho nguyn t ca cc nguyn t: X (Z = 11); Y (Z = 12); L (Z = 17); E (Z = 16); G (Z = 8); Q (Z = 9); T (Z = 18);
M (Z = 19). Trng hp no sau y ch gm cc nguyn t v ion c cng cu hnh electron?
A. X
+
, Y
2+
, G
2
, L

. B. L

, E
2
, T, M
+
. C. X
+
, Y
2+
, G
2
, Q. D. Q

, E
2
, T, M
+
.
Cu 23: Cho dy gm 7 dung dch ring bit: H
2
N[CH
2
]
4
CH(NH
2
)COOH, HOOC[CH
2
]
2
CH(NH
2
)COOH, H
2
NCH
2
COONa,
ClH
3
NCH
2
COOH, CH
3
CH(NH
2
)COOH, C
6
H
5
ONa (natri phenolat), C
6
H
5
NH
3
Cl (phenylamoni clorua). S dung dch trong dy c pH > 7 l
A. 2. B. 5. C. 3. D. 4.
Cu 24: Cht no sau y cha c 3 loi lin kt (ion, cng ho tr, cho - nhn)?
A. K
2
CO
3
. B. NaHCO
3
. C. NaNO
3
. D. HNO
3
.
Cu 25: Cho cc pht biu sau:
(1) Anehit va c tnh oxi ha va c tnh kh. (2) Cc phn t phenol khng to lin kt hiro lin phn t.
(3) Xiclopropan khng lm mt mu dung dch KMnO
4
. (4) Benzen khng lm mt mu dung dch brom.
(5) Natri fomat tham gia phn ng trng bc.
Cc pht biu ng l
A. (2), (4), (5). B. (1), (5). C. (1), (3), (5). D. (1), (3), (4), (5).
Cu 26: Trng hp no sau y khng xy ra phn ng ha hc?
A. Sc kh CO
2
vo dung dch NaClO. B. Cho kim loi Be vo H
2
O.
C. Sc kh Cl
2
vo dung dch FeSO
4
. D. Cho kim loi Al vo dung dch HNO
3
long, ngui.
Cu 27: Cho dy cht: C
2
H
4
, C
2
H
5
OH, CH
3
COOH, CH
3
COOC
2
H
3
, C
2
H
2
. S cht trong dy trc tip to ra t CH
3
CHO bng mt
phn ng l
A. 2. B. 5. C. 4. D. 3.
Cu 28: C cc dung dch ring bit: Cu(NO
3
)
2
, HCl, FeCl
3
, AgNO
3
, Mg(NO
3
)
2
, NiSO
4
. Nhng vo mi dung dch mt thanh st
nguyn cht. S trng hp xut hin n mn ha hc l
A. 5. B. 3. C. 6. D. 4.
Cu 29: Cho Zn ti d vo dung dch gm HCl; 0,05 mol NaNO
3
v 0,1 mol KNO
3
. Sau khi kt thc cc phn ng thu c dung
dch X cha m gam mui; 0,125 mol hn hp kh Y gm hai kh khng mu, trong c mt kh ha nu trong khng kh. T khi
ca Y so vi H
2
l 12,2. Gi tr ca m l
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A. 61,375. B. 64,05. C. 57,975. D. 49,775.
Cu 30: Hn hp M gm mt anken v hai amin no, n chc, mch h X v Y l ng ng k tip nhau (M
X
< M
Y
). t chy
hon ton mt lng M cn dng va 0,225 mol O
2
, thu c H
2
O, N
2
v 0,12 mol CO
2
. Cng thc phn t ca Y l
A. C
3
H
9
N. B. C
2
H
7
N. C. C
4
H
11
N. D. CH
5
N.
Cu 31: Cho m gam hn hp bt X gm Mg v Fe vo 200 ml dung dch cha CuCl
2
0,5M v HCl 1M. Sau khi cc phn ng xy
ra hon ton, thu c m gam hn hp Y gm hai kim loi. Khi lng ca Mg trong m gam hn hp X l
A. 2,4 gam. B. 4,8 gam. C. 3,6 gam. D. 1,2 gam.
Cu 32: t chy hon ton mt amin n chc, mch h X bng mt lng khng kh (cha 20% th tch O
2
, cn li l N
2
) va
, thu c 0,08 mol CO
2
; 0,1 mol H
2
O v 0,54 mol N
2
. Khng nh no sau y l ng ?
A. S nguyn t H trong phn t X l 7. B. Gia cc phn t X khng c lin kt hiro lin phn t.
C. X khng phn ng vi HNO
2
. D. S ng phn cu to tha mn iu kin trn ca X l 1.
Cu 33: Hn hp M gm ancol X, axit cacboxylic Y (u no, n chc, mch h) v este Z to ra t X v Y. t chy hon ton
m gam M cn dng va 0,18 mol O
2
, sinh ra 0,14 mol CO
2
. Cho m gam M trn vo 500 ml dung dch NaOH 0,1M un nng,
sau khi kt thc cc phn ng thu c dung dch N. C cn dung dch N cn li 3,68 gam cht rn khan. Cng thc ca Y l
A. C
2
H
5
COOH. B. HCOOH. C. C
3
H
7
COOH. D. CH
3
COOH.
Cu 34: ng dng no sau y khng phi ca kh SO
2
?
A. Sn xut axit sunfuric. B. Ty trng giy, bt giy.
C. Kh trng nc sinh hot. D. Chng nm mc cho lng thc, thc phm.
Cu 35: Hn hp X gm hai ancol X
1
v X
2
(
1 2
X X
M M < ). un nng X vi H
2
SO
4
c thu c 0,03 mol H
2
O v hn hp Y
gm hai anken ng ng lin tip, ba ete v hai ancol d. t chy hon ton Y thu c 0,13 mol CO
2
v 0,15 mol H
2
O. Cng
thc phn t ca X
1
l
A. C
2
H
5
OH. B. C
3
H
7
OH. C. CH
3
OH. D. C
3
H
5
OH.
Cu 36: Dy gm cc polime c cu trc mch phn nhnh l
A. amilopectin, glicogen, poli(metyl metacrylat). B. amilopectin, glicogen.
C. t visco, amilopectin, poli isopren. D. nha novolac, t nitron, poli(vinyl clorua).
Cu 37: Cho 200 ml dung dch gm KOH 1M v NaOH 0,75M vo 100 ml dung dch AlCl
3
1M. Sau khi kt thc cc phn ng
thu c m gam kt ta. Gi tr ca m l
A. 3,90. B. 11,70. C. 7,80. D. 5,85.
Cu 38: Hn hp M gm hai este n chc. Cho m gam M tc dng vi lng d dung dch NaOH un nng, thu c 17 gam
mt mui v 12,4 gam hn hp N gm hai anehit thuc cng dy ng ng. T khi hi ca N so vi H
2
l 24,8. Cho m gam M
phn ng vi lng d dung dch AgNO
3
trong NH
3
un nng, thu c ti a a gam Ag. Bit cc phn ng u xy ra hon ton.
Gi tr ca m v a ln lt l
A. 25,15 v 108. B. 25,15 v 54. C. 19,40 v 108. D. 19,40 v 54.
Cu 39: Ha tan ht hn hp X gm FeS
2
, Cu
2
S v Cu trong V ml dung dch HNO
3
1M. Sau khi cc phn ng xy ra hon ton
thu c dung dch Y ch cha hai mui sunfat v 5,376 lt NO (sn phm kh duy nht, ktc). Gi tr ca V l
A. 960. B. 240. C. 120. D. 480.
Cu 40: Hn hp M gm 4 axit cacboxylic. Cho m gam M phn ng ht vi dung dch NaHCO
3
, thu c 0,1 mol CO
2
. t chy
hon ton m gam M cn dng va 0,09 mol O
2
, sinh ra 0,14 mol CO
2
. Gi tr ca m l
A. 5,80. B. 5,03. C. 5,08. D. 3,48.
B. PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II)
Phn I. Theo chng trnh Chun (10 cu: T cu 41 n cu 50)
Cu 41: Thc hin phn ng nhit nhm hn hp gm Al v Cr
2
O
3
trong iu kin khng c khng kh. Sau mt thi gian thu
c 21,95 gam hn hp X. Chia X thnh hai phn bng nhau. Cho phn 1 vo lng d dung dch HCl long nng, thu c 3,36
lt H
2
(ktc). Ha tan phn 2 vo lng d dung dch NaOH c nng, thu c 1,68 lt H
2
(ktc). Bit cc phn ng ca phn 1 v
phn 2 u xy ra hon ton. Hiu sut phn ng nhit nhm l
A. 30,0% B. 60,0%. C. 75,0%. D. 37,5%.
Cu 42: Qu trnh xy ra trong pin in ha Zn Cu v qu trnh xy ra khi in phn dung dch CuSO
4
vi anot bng Zn c c
im chung l
A. anot xy ra s kh H
2
O v catot xy ra s oxi ha ion Cu
2+
.
B. anot xy ra s oxi ha H
2
O v catot xy ra s kh ion Cu
2+
.
C. anot xy ra s oxi ha Zn v catot xy ra s kh ion Cu
2+
.
D. anot xy ra s kh Zn v catot xy ra s oxi ha ion Cu
2+
.
Cu 43: Khng nh no sau y l ng ?
A. Dung dch ancol etylic trong nc tn ti 3 loi lin kt hiro. B. Axit fomic khng lm mt mu nc brom.
C. Khi tc dng vi hiro, xeton b kh thnh ancol bc I tng ng. D. Glixerol tan v hn trong nc v c v ngt.
Cu 44: Thy phn hon ton m gam pentapeptit M mch h, thu c hn hp X gm hai - amino axit X
1
, X
2
(u no, mch
h, phn t c mt nhm NH
2
v mt nhm COOH). t chy hon ton hn hp X trn cn dng va 2,268 lt O
2
(ktc), ch
thu c H
2
O, N
2
v 1,792 lt CO
2
(ktc). Gi tr ca m l
A. 2,295. B. 1,935. C. 2,806. D. 1,806.
Cu 45: Ha tan ht 2,24 gam bt Fe vo 120 ml dung dch HCl 1M, thu c dung dch X. Cho X tc dng vi lng d dung
dch AgNO
3
, sau khi kt thc cc phn ng thu c V lt kh NO (sn phm kh duy nht, ktc) v m gam cht rn. Gi tr ca m
v V ln lt l
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A. 17,22 v 0,224. B. 1,08 v 0,224. C. 18,3 v 0,448. D. 18,3 v 0,224
Cu 46: Thc hin cc th nghim sau: (1) Cho Fe
2
O
3
vo dung dch HI. (2) Cho Cu vo dung dch FeCl
3
.
(3) Cho dung dch HCl vo dung dch Fe(NO
3
)
2
. (4) Sc kh SO
2
vo dung dch KMnO
4
.
(5) Sc kh CO
2
vo dung dch NaOH. (6) Sc kh O
2
vo dung dch KI.
S th nghim c phn ng oxi ha - kh xy ra l
A. 5. B. 2. C. 3. D. 4.
Cu 47: Hn hp X gm hai axit cacboxylic. Cho m gam X phn ng vi lng d dung dch AgNO
3
trong NH
3
un nng, kt
thc cc phn ng thu c 21,6 gam Ag. Cho ton b lng X trn phn ng va vi 200 ml dung dch NaOH 1M, thu c
dung dch Y. C cn dung dch Y cn li 13,5 gam cht rn khan. Cng thc ca hai axit cacboxylic l
A. HCOOH v HOOCCOOH. B. CH
3
COOH v HOOCCOOH.
C. HCOOH v C
2
H
3
COOH. D. HCOOH v C
2
H
5
COOH.
Cu 48: Pht biu no sau y l sai khi so snh tnh cht ha hc ca C
2
H
2
v CH
3
CHO ?
A. C
2
H
2
v CH
3
CHO u lm mt mu nc brom. B. C
2
H
2
v CH
3
CHO u c phn ng trng bc.
C. C
2
H
2
v CH
3
CHO u c phn ng cng vi H
2
(xc tc Ni, t
0
). D. C
2
H
2
v CH
3
CHO u lm mt mu dung dch KMnO
4
.
Cu 49: Cho cc pht biu sau:
(1) Amiloz c cu trc mch phn nhnh. (2) Fructoz lm mt mu nc brom.
(3) Saccaroz khng b oxi ha bi dung dch AgNO
3
trong NH
3
, un nng.
(4) Xenluloz trinitrat c dng lm thuc sng. (5) Thy phn mantoz thu c glucoz v fructoz.
(6) Saccaroz ch c cu to dng mch vng.
S pht biu ng l
A. 2. B. 4. C. 1. D. 3.
Cu 50: Ha tan hn hp X gm 3,2 gam Cu v 23,2 gam Fe
3
O
4
bng lng d dung dch H
2
SO
4
long, thu c dung dch Y.
Cho dung dch NaOH d vo Y thu c kt ta Z. Nung Z trong khng kh n khi lng khng i, thu c m gam cht rn.
Bit cc phn ng u xy ra hon ton. Gi tr ca m l
A. 28,0. B. 26,4 C. 27,2. D. 24,0.
Phn II. Theo chng trnh Nng cao (10 cu: T cu 51 n cu 60)
Cu 51: Nhn xt no sau y l sai ?
A. Cho dung dch K
2
Cr
2
O
7
vo dung dch Ba(NO
3
)
2
xut hin kt ta mu vng ti.
B. Cr(OH)
2
tan trong dung dch NaOH khi c mt O
2
.
C. Trong mi trng kim, ion CrO
2
4

(mu vng) phn ng vi H

2
O sinh ra ion Cr
2
O
2
7

(mu da cam).
D. Trong mi trng axit H
2
SO
4
long, ion Cr
2
O
2
7

oxi ha c H
2
S thnh S.
Cu 52: Cho 11,25 gam hn hp bt gm Zn v Cu vo 250 ml dung dch AgNO
3
1M. Sau khi cc phn ng xy ra hon ton, thu
c dung dch X v 30,2 gam cht rn. Khi lng ca Cu trong hn hp ban u l
A. 8,0 gam. B. 4,8 gam. C. 6,4 gam. D. 3,2 gam.
Cu 53: Hn hp M gm axit axetic v anehit X. t chy hon ton m gam M cn dng va 0,13 mol O
2
, sinh ra 0,1 mol
CO
2
v 0,1 mol H
2
O. Cho ton b lng M trn vo lng d dung dch AgNO
3
trong NH
3
un nng, sau khi kt thc cc phn
ng thu c 0,04 mol Ag. Cng thc ca X l
A. C
3
H
7
CHO. B. HCHO. C. CH
3
CHO. D. C
2
H
5
CHO.
Cu 54: Cho s chuyn ha:
X
HBr (1:1)
Y
0
dd NaOHlong
t
Z
0
CuO
t
T
3 3
0
dd AgNO NH
t
/
CH
3
CH
2
COONH
4

Trong Y, Z, T l cc sn phm chnh. Cht X l
A. propen. B. xiclopropan. C. propin. D. eten.
Cu 55: Cho hn hp kh gm N
2
v H
2
vo bnh kn, chn khng (dung tch khng i), c cha sn cht xc tc. Sau khi nung
nng bnh mt thi gian ri a v nhit ban u, thy p sut trong bnh gim 18,4% so vi p sut ban u. T khi ca hn
hp kh thu c sau phn ng so vi H
2
l 6,164. Hiu sut phn ng tng hp NH
3
l
A. 29,67%. B. 60%. C. 70,33%. D. 40%.
Cu 56: Thc hin cc th nghim sau:
(1) Cho kim loi Mg ti d vo dung dch FeCl
3
. (2) Cho kim loi Na vo dung dch CuSO
4
.
(3) Cho AgNO
3
vo dung dch Fe(NO
3
)
2
. (4) Nhit phn AgNO
3
.
(5) Cho kh CO i qua ng ng bt Al
2
O
3
nung nng.
Cc th nghim thu c kim loi khi kt thc cc phn ng l
A. (1), (2), (3), (4). B. (1), (3), (4). C. (2), (5). D. (1), (3), (4), (5).
Cu 57: Cho 0,1 mol este n chc X tc dng va vi 200 ml dung dch NaOH 1M un nng, thu c 19,8 gam hn hp hai
mui. S ng phn cu to tha mn iu kin trn ca X l
A. 5. B. 2. C. 4. D. 3.
Cu 58: Cho cc chuyn ha sau: X + H
2
O
0
xt t ,
Y; Y + Br
2
+ H
2
O Axit gluconic + HBr
Axit gluconic + NaHCO
3
Z + Natri gluconat + H
2
O; Z + H
2
O
nhsng
clorophin
X + E
Cc cht X, Y ln lt l
A. xenluloz, glucoz. B. tinh bt, glucoz. C. tinh bt, fructoz. D. saccaroz, glucoz.
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Cu 59: Cho 0,1 mol amino axit M phn ng va vi 80 ml dung dch HCl 1,25M. C cn cn thn dung dch to thnh thu
c 17,35 gam mui khan. Bit M l hp cht thm. S ng phn cu to tha mn iu kin trn ca M l
A. 4. B. 2. C. 1. D. 3.
Cu 60: Cho dy cht: Al, Al(OH)
3
, NaHCO
3
, (NH
4
)
2
CO
3
, CH
3
COONH
4
, CH
3
COOC
2
H
5
, Na
2
HPO
3
. S cht trong dy c tnh
lng tnh l
A. 7. B. 5. C. 4. D. 6.

----------- HT ----------
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trng i hc vinh p n mn ha HC ln 1 - nm 2014
trng thpt chuyn

M Cu hi p n M Cu hi p n M Cu hi p n M Cu hi p n
135 1 A 205 1 C 359 1 D 487 1 D
135 2 B 205 2 C 359 2 D 487 2 A
135 3 B 205 3 B 359 3 A 487 3 B
135 4 D 205 4 C 359 4 D 487 4 D
135 5 D 205 5 A 359 5 B 487 5 D
135 6 A 205 6 D 359 6 A 487 6 C
135 7 D 205 7 A 359 7 C 487 7 A
135 8 A 205 8 D 359 8 C 487 8 B
135 9 D 205 9 D 359 9 D 487 9 B
135 10 C 205 10 A 359 10 C 487 10 A
135 11 B 205 11 B 359 11 B 487 11 A
135 12 C 205 12 C 359 12 A 487 12 B
135 13 C 205 13 C 359 13 D 487 13 A
135 14 C 205 14 A 359 14 D 487 14 C
135 15 B 205 15 A 359 15 B 487 15 D
135 16 B 205 16 D 359 16 D 487 16 A
135 17 D 205 17 D 359 17 A 487 17 B
135 18 D 205 18 B 359 18 B 487 18 B
135 19 B 205 19 D 359 19 C 487 19 D
135 20 A 205 20 A 359 20 D 487 20 A
135 21 C 205 21 C 359 21 A 487 21 C
135 22 C 205 22 B 359 22 B 487 22 C
135 23 A 205 23 B 359 23 C 487 23 D
135 24 C 205 24 A 359 24 C 487 24 C
135 25 B 205 25 C 359 25 D 487 25 D
135 26 C 205 26 D 359 26 B 487 26 B
135 27 D 205 27 C 359 27 A 487 27 C
135 28 D 205 28 A 359 28 A 487 28 D
135 29 A 205 29 B 359 29 B 487 29 A
135 30 B 205 30 B 359 30 B 487 30 A
135 31 B 205 31 B 359 31 C 487 31 B
135 32 A 205 32 B 359 32 D 487 32 D
135 33 D 205 33 C 359 33 A 487 33 C
135 34 C 205 34 D 359 34 C 487 34 B
135 35 B 205 35 C 359 35 A 487 35 B
135 36 C 205 36 A 359 36 B 487 36 C
135 37 A 205 37 B 359 37 A 487 37 A
135 38 A 205 38 A 359 38 C 487 38 C
135 39 D 205 39 D 359 39 B 487 39 D
135 40 A 205 40 D 359 40 C 487 40 C
135 41 A 205 41 C 359 41 C 487 41 C
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135 42 C 205 42 B 359 42 C 487 42 D
135 43 B 205 43 C 359 43 D 487 43 A
135 44 D 205 44 B 359 44 B 487 44 C
135 45 D 205 45 A 359 45 D 487 45 B
135 46 C 205 46 A 359 46 D 487 46 D
135 47 A 205 47 B 359 47 A 487 47 B
135 48 B 205 48 D 359 48 B 487 48 A
135 49 A 205 49 B 359 49 D 487 49 A
135 50 A 205 50 D 359 50 A 487 50 B
135 51 A 205 51 C 359 51 C 487 51 A
135 52 C 205 52 B 359 52 A 487 52 B
135 53 B 205 53 B 359 53 A 487 53 D
135 54 A 205 54 C 359 54 B 487 54 B
135 55 D 205 55 A 359 55 D 487 55 D
135 56 C 205 56 D 359 56 B 487 56 C
135 57 D 205 57 B 359 57 C 487 57 A
135 58 B 205 58 A 359 58 B 487 58 C
135 59 A 205 59 B 359 59 D 487 59 A
135 60 A 205 60 D 359 60 C 487 60 B