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TRNG I HC VINH
TRNG THPT CHUYN

THI KHO ST CHT LNG LP 12 LN III, NM 2014
Mn: HA HC KHI A, B
(Thi gian lm bi: 90 pht; 50 cu trc nghim)

H v tn .................................................................. S bo danh .......................... M thi 132
Cho khi lng nguyn t ca cc nguyn t (theo vC): C = 12; H = 1; O = 16; S = 32; Cu = 64; Fe = 56; Al = 27;
N = 14; Ba = 137; Na = 23; Mg = 24; Cl = 35,5; Si = 28; K = 39; Ag = 108; Br = 80; Li = 7; Ca = 40.
A. PHN CHUNG CHO TT C TH SINH (40 cu: T cu 1 n cu 40)
Cu 1: Hn hp M gm ankin X, anken Y (Y nhiu hn X mt nguyn t cacbon) v H
2
. Cho 0,25 mol hn hp M vo
bnh kn c cha mt t bt Ni un nng. Sau mt thi gian thu c hn hp N. t chy hon ton N thu c 0,35 mol
CO
2
v 0,35 mol H
2
O. Cng thc phn t ca X v Y ln lt l
A. C
4
H
6
v C
5
H
10
. B. C
3
H
4
v C
2
H
4
. C. C
3
H
4
v C
4
H
8
. D. C
2
H
2
v C
3
H
6
.
Cu 2: Hn hp X gm 2 axit cacboxylic. Trung ha m gam X bng mt lng va dung dch cha 0,3 mol KOH v 0,4
mol NaOH, thu c dung dch Y. C cn dung dch Y thu c 56,6 gam cht rn khan. Gi tr ca m l
A. 36,4. B. 30,1. C. 23,8. D. 46,2.
Cu 3: Hn hp X gm C
4
H
4
, C
4
H
2
, C
4
H
6
, C
4
H
8
v C
4
H
10
. T khi ca X so vi H
2
l 27. t chy hon ton X, cn dng
va V lt O
2
(ktc), thu c CO
2
v 0,03 mol H
2
O. Gi tr ca V l
A. 3,696. B. 1,232. C. 7,392. D. 2,464.
Cu 4: Cho 0,1 mol este X tc dng va vi dung dch cha 0,1 mol NaOH un nng, tng khi lng sn phm hu c
thu c l 12,8 gam. S ng phn cu to ca X tha mn cc iu kin trn l
A. 3. B. 5. C. 2. D. 4.
Cu 5: Cho mt s tnh cht: (1) nhit nng chy v nhit si thp; (2) mu trng bc v nh kim; (3) kiu mng tinh
th lp phng tm khi; (4) c tnh kh yu; (5) khng tan trong dung dch BaCl
2
. Cc tnh cht ca kim loi kim l
A. (1), (3), (4). B. (3), (5). C. (1), (2), (3), (5). D. (1), (2), (3).
Cu 6: Cho axit cacboxylic X phn ng vi cht Y thu c mt mui c cng thc phn t C
2
H
7
O
2
N (sn phm duy nht).
S cp X v Y tha mn iu kin trn l
A. 2. B. 3. C. 4. D. 1.
Cu 7: Pht biu no sau y l ng ?
A. Natri etylat khng phn ng vi nc.
B. Dung dch etylamin lm hng phenolphtalein.
C. Toluen khng lm mt mu dung dch KMnO
4
ngay c khi un nng.
D. Dung dch natri phenolat lm qu tm ha .
Cu 8: Dung dch no sau y c pH < 7 ?
A. Dung dch CH
3
COONa. B. Dung dch Na
2
CO
3
. C. Dung dch NH
4
NO
3
. D. Dung dch KCl.
Cu 9: Pht biu no sau y l sai ?
A. Gia cc phn t este khng to lin kt hiro lin phn t. B. Este va c tnh kh va c tnh oxi ha.
C. Poli(metyl metacrylat) c dng lm thy tinh hu c plexiglas. D. Este c tnh lng tnh.
Cu 10: Cho 25,8 gam hn hp X gm MOH, MHCO
3
v M
2
CO
3
(M l kim loi kim, MOH v MHCO
3
c s mol bng
nhau) tc dng vi lng d dung dch H
2
SO
4
long, sau khi kt thc cc phn ng thu c dung dch Y v 0,3 mol CO
2
.
Kim loi M l
A. K. B. Na. C. Li. D. Rb.
Cu 11: Ba cht hu c mch h X, Y, Z c cng cng thc phn t C
3
H
4
O
2
v c cc tnh cht sau: X, Y u c phn ng
cng hp vi Br
2
, cho 1 mol X hoc 1 mol Z tc dng vi lng d dung dch AgNO
3
trong NH
3
un nng, thu c ti a
4 mol Ag. Cc cht X, Y, Z ln lt l
A. OHCCH
2
CHO, CH
2
=CHCOOH, HCOOCH=CH
2
. B. HCOOCH=CH
2
, CH
2
=CHCOOH, OHCCH
2
CHO.
C. HCOOCH=CH
2
, CH
3
COCHO, OHCCH
2
CHO. D. CH
2
=CHCOOH, HCOOCH=CH
2
, OHCCH
2
CHO.
Cu 12: Ha tan ht hn hp X gm Fe, Cu v Ag trong V ml dung dch HNO
3
1M. Sau khi cc phn ng xy ra hon ton
thu c dung dch Y v 0,2 mol NO (sn phm kh duy nht). Gi tr ti thiu ca V l
A. 800. B. 400. C. 600. D. 200.
Cu 13: Cho 300 ml dung dch gm Ba(OH)
2
0,5M v KOH x mol/lt vo 50 ml dung dch Al
2
(SO
4
)
3
1M. Sau khi kt thc
cc phn ng thu c 36,9 gam kt ta. Gi tr ca x l
A. 0,75. B. 0,25. C. 0,50. D. 1,0.
Cu 14: Ha tan ht 0,02 mol KClO
3
trong lng d dung dch HCl c, thu c dung dch Y v kh Cl
2
. Hp th ht ton
b lng kh Cl
2
vo dung dch cha 0,06 mol NaBr, thu c m gam Br
2
(gi thit Cl
2
v Br
2
u phn ng khng ng k
vi H
2
O). Cc phn ng u xy ra hon ton. Gi tr ca m l
A. 4,80. B. 3,20. C. 3,84. D. 4,16.
Cu 15: Cho m gam hn hp X gm Na, K v Ba phn ng ht vi dung dch cha 0,1 mol FeCl
2
v 0,15 mol CuCl
2
. Kt
thc cc phn ng thu c kt ta Z, dung dch Y v 0,3 mol H
2
. C cn ton b dung dch Y thu c 40,15 gam cht rn
khan. Gi tr ca m l
A. 26,1. B. 36,9. C. 20,7. D. 30,9.
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Cu 16: Thy phn mt lng pentapeptit mch h X ch thu c 3,045 gam Ala-Gly-Gly; 3,48 gam Gly-Val; 7,5 gam
Gly; 2,34 gam Val; x mol Val-Ala v y mol Ala. T l x : y l
A. 11 : 16 hoc 6 : 1. B. 2 : 5 hoc 7 : 20. C. 2 : 5 hoc 11 : 16. D. 6 : 1 hoc 7 : 20.
Cu 17: Cho m gam hn hp X gm hai ancol n chc X
1
, X
2
ng ng k tip (
1 2
X X
M M < ), phn ng vi CuO nung
nng, thu c 0,25 mol H
2
O v hn hp Y gm hai anehit tng ng v hai ancol d. t chy hon ton Y thu c 0,5
mol CO
2
v 0,65 mol H
2
O. Mt khc, cho ton b lng Y trn tc dng vi lng d dung dch AgNO
3
trong NH
3
un
nng, kt thc cc phn ng thu c 0,9 mol Ag. Hiu sut to anehit ca X
1,
X
2
ln lt l
A. 50,00% v 66,67%. B. 33,33% v 50,00%. C. 66,67% v 33,33%. D. 66,67% v 50,00%.
Cu 18: in phn dung dch X gm x mol KCl v y mol Cu(NO
3
)
2
(in cc tr, mng ngn xp), khi nc bt u b in
phn c hai in cc th ngng in phn thu c dung dch Y (lm qu tm ha xanh), c khi lng gim 2,755 gam so
vi khi lng dung dch X ban u (gi thit nc bay hi khng ng k). Cho ton b lng Y trn tc dng vi dung
dch AgNO
3
d, kt thc phn ng thu c 2,32 gam kt ta. T l x : y l
A. 3 : 4. B. 4 : 3. C. 5 : 3. D. 10 : 3.
Cu 19: Cho cc s chuyn ha: X + H
2
SO
4
c Y + SO
2
+ H
2
O ; Y + H
2
O
anhsang
clorophin
Z + E
Z + H
2
O
1) amilaza
2) amilaza

X
Cht X l
A. saccaroz. B. mantoz. C. glucoz. D. fructoz.
Cu 20: Hn hp M gm SiH
4
v CH
4
. t chy hon ton mt lng hn hp M cn dng va 0,4 mol O
2
, thu c
sn phm kh X v m gam sn phm rn Y. Cho ton b lng X i qua dung dch Ca(OH)
2
ly d, kt thc phn ng thu
c 15 gam kt ta. Gi tr ca m l
A. 3. B. 15. C. 6. D. 12.
Cu 21: Cho dy cht: metan, canxi cacbua, nhm cacbua, bc axetilua. S cht trong dy trc tip to ra axetilen bng mt
phn ng l
A. 3. B. 2. C. 4. D. 1.
Cu 22: Dy ch gm cc cht tan hon ton trong lng d dung dch NaOH long nhit thng l
A. Al
2
O
3
, Ba, BaCl
2
, CaCO
3
. B. Pb(OH)
2
, Sn(OH)
2
, Cr(OH)
3
, Fe(OH)
3
.
C. NaCl, Al(OH)
3
, Al
2
O
3
, Zn. D. Al, ZnO, Cr
2
O
3
, Zn(OH)
2
.
Cu 23: Pht biu no sau y l ng ?
A. Trong t nhin, cc kim loi kim th ch tn ti dng hp cht.
B. Cc kim loi kim th u tc dng vi nc nhit thng.
C. Theo chiu tng dn ca in tch ht nhn, cc kim loi kim th (t beri n bari) c nhit si gim dn.
D. m chy nhm c th c dp tt bng kh cacbonic.
Cu 24: Hn hp M gm C
2
H
2
v hai anehit X
1
, X
2
ng ng k tip (
1 2
X X
M M < ). t chy hon ton mt lng M
cn dng va 0,3 mol O
2
, thu c 0,25 mol CO
2
v 0,225 mol H
2
O. Cng thc ca X
1
l
A. CH
3
CHO. B. OHCCHO. C. HCHO. D. CH
2
=CHCHO.
Cu 25: Oxit cao nht ca nguyn t R ng vi cng thc RO
2
. Trong hp cht kh ca n vi hiro, R chim 75% v khi
lng. Khng nh no sau y l sai ?
A. Lp ngoi cng ca nguyn t R ( trng thi c bn) c 2 electron c thn.
B. Phn t RO
2
l phn t phn cc.
C. m in ca nguyn t nguyn t R ln hn m in ca nguyn t nguyn t hiro.
D. Lin kt ha hc gia cc nguyn t trong phn t RO
2
l lin kt cng ha tr c cc.
Cu 26: Cation M
3+
c cu hnh electron phn lp ngoi cng l 3d
6
. Anion X

c cu hnh electron phn lp ngoi cng l

4p
6
. Cu hnh electron ca nguyn t M v X trng thi c bn ln lt l
A. [Ar]3d
9
v [Kr]5s
1
. B. [Ar]3d
9
v [Ar]3d
10
4s
2
4p
5
.
C. [Ar]3d
7
4s
2
v [Ar]3d
10
4s
2
4p
5
. D. [Ar]3d
7
4s
2
v [Kr]5s
1
.
Cu 27: Dy cc cht u c kh nng tham gia phn ng thy phn trong dung dch H
2
SO
4
long, nng l
A. xenluloz, poli(vinyl clorua), nilon-7. B. polistiren, amilopectin, poliacrilonitrin.
C. t lapsan, t axetat, polietilen. D. nilon-6,6, nilon-6, amiloz.
Cu 28: Cho phng trnh ha hc: FeS + HNO
3
Fe(NO
3
)
3
+ H
2
SO
4
+ NO + NO
2
+ H
2
O
(Bit t l th tch NO : NO
2
= 3 : 4). Sau khi cn bng phng trnh ha hc trn vi h s cc cht l nhng s nguyn
ti gin th h s ca cht b oxi ha l
A. 63. B. 102. C. 4. D. 13.
Cu 29: Cho s phn ng: C
2
H
4

HI
X
0
3
NH (1: 1) t ,
Y
dd NaOH
Z
Cc cht X, Y, Z ln lt l
A. C
2
H
5
I, C
2
H
5
NH
3
I, C
2
H
5
NH
2
. B. C
2
H
5
I, C
2
H
5
NH
2
, C
2
H
5
OH.
C. C
2
H
4
I
2
, C
2
H
4
(NH
2
)
2
, C
2
H
4
(OH)
2
. D. C
2
H
5
I, C
2
H
5
NH
3
I, C
2
H
5
OH.
Cu 30: Pht biu sai l
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A. Khi cho dung dch lng trng trng vo dung dch HNO
3
c thy xut hin kt ta mu tm.
B. trng thi kt tinh amino axit tn ti dng ion lng cc.
C. Amino axit l nhng cht rn dng tinh th khng mu, tan tt trong nc v c v hi ngt.
D. Dung dch lng trng trng c phn ng mu biure vi Cu(OH)
2
.
Cu 31: Cho cc phn ng ha hc sau:
(1) NaHS + NaOH (2) Ba(HS)
2
+ KOH (3) Na
2
S + HCl
(4) CuSO
4
+ Na
2
S (5) FeS + HCl (6) NH
4
HS + NaOH
Cc phn ng u c cng mt phng trnh ion rt gn l
A. (3), (4), (5). B. (1), (2). C. (1), (2), (6). D. (1), (6).
Cu 32: Cho cc cht: axit propionic (X), ancol propylic (Y), axetanehit (Z), axeton (T). Dy gm cc cht c sp xp
theo chiu tng dn nhit si t tri sang phi l
A. X, Y, Z, T. B. T, Z, Y, X. C. Z, T, Y, X. D. X, Y, T, Z.
Cu 33: Cho Fe vo dung dch gm Cu(NO
3
)
2
v AgNO
3
, sau khi cc phn ng xy ra hon ton thu c dung dch X
(gm 2 mui) v cht rn Y (gm 2 kim loi). B qua s thy phn ca cc mui. Hai mui trong X l
A. Fe(NO
3
)
2
v Fe(NO
3
)
3
. B. Fe(NO
3
)
3
v Cu(NO
3
)
2
. C. Fe(NO
3
)
3
v AgNO
3
. D. Fe(NO
3
)
2
v Cu(NO
3
)
2
.
Cu 34: Cht hu c X mch h, khng phn nhnh c cng thc phn t C
4
H
8
O
2
. Cho X tc dng vi hiro (xc tc Ni, t
0
)
thu c sn phm Y c kh nng ha tan Cu(OH)
2
. S ng phn cu to bn ca X tha mn cc iu kin trn l
A. 4. B. 5. C. 3. D. 7.
Cu 35: Hn hp M gm hai axit cacboxylic X v Y (X nhiu hn Y mt nguyn t cacbon). t chy hon ton 0,2 mol
M cn dng va V lt O
2
(ktc), thu c 0,45 mol CO
2
v 0,2 mol H
2
O. Gi tr ca V l
A. 7,84. B. 4,48. C. 12,32. D. 3,36.
Cu 36: C 6 dung dch ring bit, ng trong 6 l mt nhn: Na
2
CO
3
, NaHCO
3
, BaCl
2
, Ba(OH)
2
, H
2
SO
4
, Na
2
SO
4
. Khng
dng thm thuc th no khc bn ngoi v c php un nng c th phn bit c ti a bao nhiu dung dch ?
A. 5. B. 4. C. 6. D. 3.
Cu 37: Pht biu no sau y l sai ?
A. Dung dch saccaroz ha tan c Cu(OH)
2
. B. Cho nc brom vo phenol ly d, c kt ta trng xut hin.
C. Trong phn t axit benzoic, gc phenyl ht electron ca nhm cacboxyl nn n c lc axit mnh hn lc axit ca axit fomic.
D. Cho 2-clopropen tc dng vi hiroclorua thu c sn phm chnh l 2,2-iclopropan.
Cu 38: Ha tan ht 19,6 gam hn hp X gm Fe
3
O
4
v CuO bng mt lng va dung dch HCl 1M, thu c dung
dch Y. Cho Y tc dng vi lng d dung dch H
2
S, kt thc cc phn ng thu c 11,2 gam kt ta. Th tch dung dch
HCl 1M dng l
A. 300 ml. B. 600 ml. C. 400 ml. D. 615 ml.
Cu 39: Qu trnh xy ra trong pin in ha Fe - Cu v qu trnh xy ra khi nhng thanh hp kim Fe - Cu vo dung dch
HCl c c im chung l
A. u c kh H
2
thot ra trn b mt kim loi Cu. B. kim loi Cu b n mn in ha hc.
C. kim loi Fe ch b n mn ha hc. D. kim loi Fe u b n mn in ha hc.
Cu 40: Cho hn hp X gm Cu v Fe
3
O
4
vo lng d dung dch H
2
SO
4
long. Kt thc cc phn ng thu c dung dch Y v
cht rn Z. Dy ch gm cc cht m khi cho chng tc dng ln lt vi dung dch Y th u c phn ng oxi ha - kh xy ra l
A. KMnO
4
, NaNO
3
, Fe, Cl
2
. B. Fe
2
O
3
, K
2
MnO
4
, K
2
Cr
2
O
7
, HNO
3
.
C. BaCl
2
, Mg, SO
2
, KMnO
4
. D. NH
4
NO
3
, Mg(NO
3
)
2
, KCl, Cu.
B. PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II)
Phn I. Theo chng trnh Chun (10 cu: T cu 41 n cu 50)
Cu 41: t chy hon ton 0,2 mol hn hp M gm ankan X v axit cacboxylic Y (X v Y c cng s nguyn t cacbon
trong phn t), thu c 0,4 mol CO
2
v 0,4 mol H
2
O. Phn trm khi lng ca Y trong hn hp M l
A. 25%. B. 75%. C. 50%. D. 40%.
Cu 42: Cho phn ng ha hc sau: Na
2
S
2
O
3
(l) + H
2
SO
4
(l) Na
2
SO
4
(l) + SO
2
(k) + S (r) + H
2
O (l)
Khi thay i mt trong cc yu t (gi nguyn cc yu t khc):
(1) Tng nhit . (2) Tng nng Na
2
S
2
O
3
. (3) Gim nng H
2
SO
4
.
(4) Gim nng Na
2
SO
4
. (5) Gim p sut ca SO
2
.
C bao nhiu yu t trong cc yu t trn lm tng tc ca phn ng cho ?
A. 3. B. 4. C. 2. D. 1.
Cu 43: Cho 8 gam hn hp X gm Mg v Fe vo dung dch cha 0,1 mol CuCl
2
v 0,1 mol HCl. Sau khi kt thc cc phn
ng thu c kh H
2
, dung dch Y v 9,2 gam cht rn khan. Phn trm v khi lng ca Mg trong X l
A. 45,00%. B. 30,00%. C. 52,50%. D. 56,25%.
Cu 44: Pht biu no sau y l sai ?
A. Trong mi trng axit, Zn kh Cr
2+
thnh Cr.
B. CrO
3
tc dng c vi nc iu kin thng.
C. Cr
2
O
3
c dng to mu lc cho s, thy tinh.
D. Trong mi trng axit H
2
SO
4
long, ion Cr
2
O
2
7

oxi ha c I

thnh I
2
.
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Cu 45: Ha tan ht m gam hn hp M gm 2 oxit st trong lng d dung dch HCl, thu c dung dch X. Sc kh Cl
2
ti
d vo X thu c dung dch Y cha 40,625 gam mui. Nu cho m gam M trn tc dng ht vi dung dch HNO
3
long, d
th thu c 0,05 mol NO (sn phm kh duy nht). Gi tr ca m l
A. 23,6. B. 18,4. C. 19,6. D. 18,8.
Cu 46: Kh CO
2
c coi l nh hng n mi trng v
A. to bi cho mi trng. B. lm gim lng ma axit. C. gy hiu ng nh knh. D. rt c.
Cu 47: Oxi ha 0,3 mol C
2
H
4
bng O
2
(xc tc PdCl
2
, CuCl
2
) thu c hn hp kh X gm C
2
H
4
v CH
3
CHO. Cho ton b
lng X trn tc dng vi lng d dung dch AgNO
3
trong NH
3
un nng, kt thc phn ng thu c 0,3 mol Ag. Phn
trm th tch ca C
2
H
4
trong X l
A. 50%. B. 75%. C. 80%. D. 25%.
Cu 48: S ng phn cu to ca amin bc II c cng cng thc phn t C
4
H
11
N l
A. 2. B. 4. C. 1. D. 3.
Cu 49: Hn hp M gm xeton no, n chc, mch h X v anehit no, a chc Y (c mch cacbon h, khng phn
nhnh). Cho m gam M tc dng vi lng d dung dch AgNO
3
trong NH
3
un nng, kt thc phn ng thu c 0,8 mol
Ag. t chy hon ton m gam M trn, ri hp th ton b sn phm chy vo bnh ng dung dch NaOH, thy khi lng
ca bnh tng 30,5 gam. Khi lng ca Y c trong m gam hn hp M l
A. 11,6 gam. B. 23,2 gam. C. 28,8 gam. D. 14,4 gam.
Cu 50: Pht biu no sau y l sai ?
A. Glucoz, fructoz v mantoz u lm mt mu nc brom.
B. Metyl glicozit khng b oxi ha bi dung dch AgNO
3
trong NH
3
.
C. Saccaroz khng phn ng vi CH
3
OH (xc tc HCl khan).
D. Tinh bt v xenluloz u khng phn ng vi Cu(OH)
2
.
Phn II. Theo chng trnh Nng cao (10 cu: T cu 51 n cu 60)
Cu 51: Cho 10,2 gam axit cacboxylic n chc X phn ng ht vi dung dch cha 0,1 mol NaOH, thu c dung dch Y.
C cn dung dch Y thu c 12,85 gam cht rn khan. Bit X l hp cht thm. S ng phn cu to ca X tha mn cc
iu kin trn l
A. 4. B. 3. C. 2. D. 1.
Cu 52: Mt bnh kn dung tch 10 lt (khng i), c cha 7,5 mol kh SO
2
; 5 mol kh O
2
v mt t xc tc V
2
O
5
(th tch
khng ng k). Sau khi phn ng tng hp SO
3
t trng thi cn bng 450
0
C, O
2
chim 25% th tch hn hp kh thu
c. Hng s cn bng K
C
450
0
C ca phn ng c gi tr l
A. 12. B. 10. C. 16. D. 8.
Cu 53: Nung hn hp gm 0,64 gam Cu v 18 gam Fe(NO
3
)
2
trong bnh kn, chn khng. Sau khi cc phn ng xy ra
hon ton thu c hn hp kh X. Cho X phn ng ht vi H
2
O thu c 1,6 lt dung dch Y. Dung dch Y c pH (b
qua s in li ca H
2
O) l
A. 0,5. B. 1,0. C. 2,0. D. 0,8.
Cu 54: Hp th ht 0,7 mol CO
2
vo dung dch cha x mol NaOH v 1 mol KOH. Sau khi cc phn ng xy ra hon ton,
lm kh dung dch thu c 88 gam cht rn khan. Gi s trong qu trnh lm kh dung dch khng xy ra phn ng ha
hc. Gi tr ca x l
A. 0,3. B. 0,345. C. 0,5. D. 0,4.
Cu 55: Th t t tri sang phi ca cc cp oxi ha - kh trong dy in ha nh sau: Al
3+
/Al; Cr
2+
/Cr; Zn
2+
/Zn; Cr
3+
/Cr
2+

Cu
2+
/Cu; Ag
+
/Ag. Dy ch gm cc kim loi, ion u tc dng c vi ion Cr
3+
trong dung dch l
A. Al, Cr, Zn, Cu. B. Zn, Cr, Cu, Ag
+
. C. Al, Cr, Zn, Ag
+
. D. Al, Cr, Zn.
Cu 56: Pht biu no sau y l sai ?
A. Bc tip xc vi khng kh c H
2
S b bin i thnh Ag
2
S mu en.
B. Thic phn ng vi dung dch HNO
3
long to mui Sn (II).
C. Vng c tnh dn in v dn nhit tt nht trong cc kim loi.
D. ng khng tc dng vi dung dch H
2
SO
4
long.
Cu 57: Cho s chuyn ha: CHCCH
2
CH
2
Cl
0
2
HCl (1 : 1)
HgCl t ,
X
ddNaOHloang, unnongnhe
Y
2 4
0
H SO
170 C

c
Z
Trong X, Y, Z u l sn phm chnh. Cng thc ca Z l
A. CH
2
=CClCH=CH
2
. B. CH
3
COCH=CH
2
. C. CH
3
COCH
2
CH
2
OSO
3
H D. CH
2
=CHCH=CH
2
.
Cu 58: Pht biu no sau y l sai ?
A. HCHO v HCOOH u c phn ng trng bc. B. HCHO v HCOOH u lm mt mu nc brom.
C. HCHO c nhit si nh hn nhit si ca HCOOH.
D. HCHO v HCOOH u c phn ng cng vi H
2
(xc tc Ni, t
0
).
Cu 59: Dy gm cc cht c sp xp theo chiu tng dn lc baz t tri sang phi l
A. anilin, amoniac, imetylamin, etylamin. B. anilin, amoniac, etylamin, imetylamin.
C. amoniac, anilin, etylamin, imetylamin. D. amoniac, etylamin, imetylamin, anilin.
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Cu 60: Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu trnh l 75%. Hp th
ton b lng CO
2
sinh ra khi ln men m gam tinh bt vo dung dch Ba(OH)
2
, thu c 59,1 gam kt ta v dung dch X.
Bit khi lng X gim i so vi khi lng dung dch Ba(OH)
2
ban u l 32,7 gam. Gi tr ca m l
A. 64,80. B. 36,45. C. 129,60. D. 48,60.
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M Cu hi p n
132 1 D
132 2 A
132 3 B
132 4 D
132 5 D
132 6 A
132 7 B
132 8 C
132 9 D
132 10 C
132 11 B
132 12 A
132 13 B
132 14 C
132 15 C
132 16 B
132 17 D
132 18 D
132 19 B
132 20 A
132 21 A
132 22 C
132 23 A
132 24 C
132 25 B
132 26 C
132 27 D
132 28 D
132 29 A
132 30 A
132 31 B
132 32 C
132 33 D
132 34 A
132 35 B
132 36 C
132 37 C
132 38 B
132 39 D
132 40 A
132 41 B
132 42 C
132 43 B
132 44 A
132 45 D
132 46 C
132 47 A
132 48 D
132 49 A
132 50 A
132 51 A
132 52 C
132 53 B
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132 54 A
132 55 D
132 56 C
132 57 A
132 58 D
132 59 B
132 60 A