S GIO DC V O TO TNH NG NAI THI TH I HC, CAO NG NM 2014

TRNG THPT CHUYN LNG TH VINH Mn: HA HC; Khi A v Khi B

( thi c 6 trang) Thi gian lm bi: 90 pht, khng k thi gian pht
M thi 106
H, tn th sinh:
S bo danh:.
Cho nguyn t khi ca cc nguyn t:
H = 1; He = 4; C = 12; N = 14; O = 16; F = 19; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39;
Ca = 40; Cr = 52; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag =108; Sn = 119; Ba = 137.
I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: Cho 14,8 gam mt hp cht hu c n chc X cha C, H, O tc dng va vi 200 ml dung dch
KOH 1M, sau khi phn ng xy ra hon ton thu c dung dch Y cha m gam hn hp hai mui hu c.
Bit rng X c th lm mt mu nc brom. Gi tr m l
A. 24,2. B. 22,4. C. 27,2. D. 26,0.
Cu 2: Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc n gin nht.
Trong X, t l khi lng gia cc nguyn t l mC : mH : mO = 21 : 2 : 8. Bit rng 0,1 mol X phn ng va
vi 200 ml dung dch NaOH 0,5M. S cng thc cu to c th c ca X l
A. 5. B. 9. C. 7. D. 6.
Cu 3: Hn hp X gm lysin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch KOH
d, thu c dung dch Y cha (m + 8,075) gam mui. Mt khc, nu cho m gam X tc dng hon ton
vi dung dch HCl d, thu c dung dch Z cha (m + 8,395) gam mui. t chy hon ton m gam X th
cn va V lt kh O2 (ktc). Gi tr ca V l
A. 22,078. B. 23,352. C. 22,428. D. 24,808.
Cu 4: Cho 2 dung dch H2SO4 v HCOOH c cng nng mol/lt v c cc gi tr pH tng ng l x v
y. Bit rng c 50 phn t HCOOH th c 1 phn t HCOOH phn li v H2SO4 phn li hon ton c 2
nc. Mi quan h gia x v y l
A. y = 2x. B. y = 10x. C. y = x 1. D. y = x + 2.
Cu 5: Cho hn hp X gm ancol metylic, etylen glicol, glixerol c khi lng m gam. t chy hon ton
X thu c 4,368 lt kh CO2 (ktc) v 5,04 gam H2O. Cng m gam hn hp X trn cho tc dng va vi
kali thu c x gam cht rn. Gi tr ca x l
A. 13,43. B. 13,24. C. 7,49. D. 13,63.
Cu 6: Hp cht hu c X (cha C, H, O) trong oxi chim 50% v khi lng. T cht X thc hin
chuyn ho sau: X
o
+ CO
xt, t
Y
2 2
o
+ HOCH CH OH
xt, t
Z
o
+ Y
xt, t
T (C6H10O4).
Pht biu no sau y l khng ng?
A. Cht Z tc dng c vi kim loi Na v dung dch NaOH un nng.
B. Cht T tc dng vi NaOH (d) trong dung dch theo t l mol 1 : 2.
C. Cht Y v Z ha tan c Cu(OH)2 nhit thng.
D. Cht X v Y u tan v hn trong nc.
Cu 7: Ly V ml dung dch H3PO4 35% (d = 1,25 g/ml) em trn vi 200 ml dung dch KOH 1M thu c
dung dch X c cha 14,95 gam mui. Gi tr V l
A. 25,00. B. 33,60. C. 18,48. D. 16,80.
Cu 8: Thy phn hon ton 1 mol peptit X sinh ra 2 mol glyxin (Gly), 1 mol methionin (Met), 1 mol
phenylalanin (Phe) v 1 mol alanin (Ala). Dng cc phn ng c trng ngi ta xc nh c amino axit
u l Met v amnio axit ui l Phe. Thy phn tng phn thu c cc ipeptit MetGly, GlyAla v
GlyGly. Cu to ca X l
A. MetGlyAlaGlyPhe. B. PheGlyGly AlaMet.
C. MetAla GlyGlyPhe. D. MetGlyGlyAlaPhe.
Cu 9: Hn hp M gm axit cacboxylic X v este Y (u n chc v cng s nguyn t cacbon). Cho m
gam M phn ng va vi dung dch cha 0,35 mol NaOH, sinh ra 27,30 gam hn hp hai mui. Mt
khc, cng cho m gam M tc dng vi lng d dung dch AgNO3 trong NH3 un nng, kt thc phn ng
thu c 48,60 gam Ag. Cng thc ca X l
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A. C2H5COOH. B. HCOOH. C. CH3COOH. D. C2H3COOH.
Cu 10: Pht biu no sau y l sai?
A. Tnh baz ca amoniac mnh hn anilin nhng li yu hn metylamin v etylamin.
B. Mui phenylamoni clorua tan tt trong nc to dung dch c mi trng axit.
C. Anilin t tan trong nc to dung dch c mi trng baz lm qu tm ha xanh.
D. Metylamin, imetylamin, trimetylamin l nhng cht kh mi khai, tan nhiu trong nc.
Cu 11: Ha tan ht 22,50 gam kim loi Al trong dung dch H2SO4 thy thot ra 11,20 lt (ktc) hn hp kh
gm H2, SO2 (c t khi hi so vi metan l 1,675), dung dch X v cht rn Y. Bit cc phn ng xy ra
hon ton. S mol H2SO4 phn ng l
A. 1,45. B. 1,90. C. 0,70. D. 1,70.
Cu 12: Trong s cc pht biu sau:
(a) ng trng hp hexametyleniamin v axit aipic thu c t nilion-6,6.
(b) T visco v t xenluloz axetat thuc loi t nhn to.
(c) ng trng hp buta-1,3-ien vi acrilonitrin c xc tc Na c polime dng sn xut cao su buna-N.
(d) Sn phm trng hp metyl metacrylat c dng ch to t tng hp.
(e) T nilon-7, t capron v nilon-6,6 u thuc loi t poliamit.
Cc pht biu ng l
A. (a), (d), (e). B. (b), (d), (e). C. (a), (b), (c). D. (b), (c), (e).
Cu 13: Pht biu no sau y ng?
A. Glucoz, fructoz, saccaroz u tn ti dng mch h v dng mch vng.
B. Hiro ha hon ton glucoz (xc tc Ni, un nng) to ra hp cht a chc l sobitol.
C. Xenluloz v tinh bt u l polisaccarit, ch khc nhau v cu to ca gc glucoz.
D. Saccaroz b thy phn trong dung dch kim long, un nng to thnh glucoz v fructoz.
Cu 14: Nung 9,04 gam hn hp X gm MgCO3 v CaCO3 sau mt thi gian thu c 5,96 gam cht rn Y
v kh Z. Hp th hon ton kh Z bng 0,5 lt dung dch Ca(OH)2 x mol/lt v NaOH y mol/lt, sau khi phn
ng xong thu c dung dch T v 5,50 gam kt ta. Nu un nng k dung dch T th thu c thm m gam
kt ta na. Nu t l x : y = 12 th gi tr ca m l
A. 0,50. B. 1,50. C. 0,75. D. 1,00.
Cu 15: Cho phng trnh ha hc sau: FeS2 + KNO3 + KHSO4 Fe2(SO4)3 + K2SO4 + NO + H2O.
Tng h s (s nguyn, ti gin) ca tt c cc cht tham gia phn ng trong phng trnh trn l
A. 20. B. 44. C. 24. D. 52.
Cu 16: Pht biu no sau y ng?
A. Amino axit v mui amoni u c tnh lng tnh.
B. Hp cht H2NCH(CH3)CONHCH2CH2COOH l mt ipeptit.
C. Thnh phn ca protein ch gm cc gc amino axit.
D. C th phn bit ipeptit v protein bng thuc th Cu(OH)2/OH
-
.
Cu 17: Cho cc th nghim ho hc sau:
(a) Cho dung dch Na2S2O3 vo dung dch H2SO4 long.
(b) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng.
(c) Cho CaOCl2 tc dng vi dung dch HCl c.
(d) Cho kh SO2 tc dng vi kh H2S.
(e) Cho Si n cht tc dng vi dung dch NaOH.
(f) Cho kh O3 tc dng vi Ag.
(g) Nung SiO2 v Mg (t l mol 1 : 2) trong iu kin khng c khng kh.
S th nghim to ra n cht l
A. 7. B. 4. C. 5. D. 6.
Cu 18: Cho hn hp gm Zn, Al phn ng va vi dung dch gm HCl v 0,015 mol KNO3. Sau khi
kt thc cc phn ng thu c dung dch X cha 8,11 gam mui v 0,896 lt (ktc) hn hp kh Y gm hai
kh khng mu, trong c mt kh ha nu trong khng kh. Bit rng t khi ca Y so vi H2 l 4,50. Khi
lng Al tham gia phn ng l
A. 0,945 gam. B. 0,540 gam. C. 0,675 gam. D. 0,810 gam.
Cu 19: Cho 54,04 gam hn hp gm Cu, Fe3O4 vo dung dch HCl thu c dung dch X v cn 2,24 gam
cht rn khng tan. Cho dung dch AgNO3 d vo dung dch X thu c 0,98 lt kh Y khng mu ho nu
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ngoi khng kh (sn phm kh duy nht ca N
+5
, ktc) v m gam kt ta. Bit cc phn ng u xy ra
hon ton. Gi tr ca m l
A. 226,01. B. 268,54. C. 282,71. D. 277,99.
Cu 20: Dy gm cc cht u tc dng vi dung dch NaOH long, nng (d) to ancol l:
A. Metyl axetat, tristearin, benzyl axetat, peptit, isoamyl axetat.
B. Etyl acrylat, anlyl axetat, triolein, benzyl fomat, metyl benzoat.
C. Etyl axetat, triolein, benzyl fomat, vinyl axetat, imetyl oxalat.
D. Tristearin, etyl axetat, phenyl propionat, isoamyl axetat, metyl fomat.
Cu 21: Nung nng hn hp kh X gm H2, C3H4, C3H6 c Ni xc tc thu c 0,224 lt (ktc) hn hp kh
Y c t khi hi so vi H2 bng 8,35. Mt khc, nu t chy hon ton hn hp X ri hp th ht sn phm
chy vo 400 ml dung dch Ca(OH)2 0,015M thy khi lng dung dch tng ln m gam. Bit cc phn ng
u xy ra hon ton. Gi tr ca m l
A. 0,429. B. 0,831. C. 0,312. D. 0,681.
Cu 22: Pht biu no sau y l ng?
A. Trong hp cht vi oxi, nit c cng ha tr cao nht bng 5.
B. Flo, clo u c tnh oxi ha mnh v u oxi ha c nc.
C. Dn kh HI khng mu qua nc brom mu nu th thy dung dch sm mu hn.
D. Phng php sunfat c th dng iu ch HCl, HBr nhng khng th iu ch c HI.
Cu 23: Chia 156,60 gam hn hp X gm mt ancol no, n chc, mch h v mt axit no, hai chc, mch
h thnh ba phn bng nhau. Cho phn 1 tc dng ht vi natri d thot ra 15,12 lt kh hiro (ktc). t
chy hon ton phn 2 thu c 69,30 gam CO2. un nng phn 3 vi xc tc H2SO4 c thu c m gam
este a chc, vi hiu sut phn ng este ha l 80%. Gi tr ca m l
A. 24,21. B. 21,24. C. 23,76. D. 28,80.
Cu 24: Cho hn hp X c khi lng m gam gm bt Al v st oxit FexOy. Tin hnh phn ng nhit
nhm hn hp X trong iu kin khng c khng kh, thu c hn hp Y. Nghin nh, trn u X ri chia
thnh hai phn. Phn 1 c khi lng 14,49 gam c ho tan ht trong dung dch HNO3 un nng, c
dung dch Z v 3,696 lt kh NO (sn phm kh duy nht ca N
+5
, ktc). Cho phn 2 tc dng vi dung dch
NaOH d un nng thy gii phng 0,336 lt kh H2 (ktc) v cn li 2,52 gam cht rn. Cc phn ng u
xy ra hon ton. Cng thc st oxit v gi tr ca m ln lt l
A. Fe3O4 v 19,32. B. Fe2O3 v 19,32. C. Fe3O4 v 24,15. D. Fe2O3 v 24,15.
Cu 25: C cc dung dch ring bit sau: NaCl, AgNO3, Pb(NO3)2, NH4NO3, ZnCl2, CaCl2, CuSO4, FeCl2.
Khi sc kh H2S vo cc dung dch trn, s trng hp sinh ra kt ta l
A. 6. B. 5. C. 3. D. 4.
Cu 26: Cho cc pht biu sau:
(a) Kim loi kim u c cu trc lp phng tm khi v nhit nng chy tng dn t Li n Cs.
(b) Vn dng phn ng gia bt nhm v st oxit (hn hp tecmit) hn ng ray.
(c) Trong nhm IA, t Li n Cs, kh nng phn ng vi nc gim dn.
(d) C th iu ch Ba, Ca, Mg bng cch in phn nng chy mui clorua tng ng ca chng.
(e) Tt c cc mui cacbonat u km bn vi nhit.
(f) Tt c dung dch mui ca kim loi kim, kim th u c pH > 7.
S pht biu khng ng l
A. 3. B. 5. C. 4. D. 2.
Cu 27: Pht biu no sau y ng?
A. Sc kh Cl2 vo dung dch cha mui CrO2
-
trong mi trng kim to dung dch c mu da cam.
B. Trong mi trng axit, Zn c th kh c Cr
3+
thnh Cr.
C. Mt s cht v c v hu c nh S, P, C, C2H5OH bc chy khi tip xc vi CrO3.
D. Cho dung dch H2SO4 long vo dung dch Na2CrO4, dung dch chuyn t mu da cam sang mu
vng.
Cu 28: Hp cht X c cng thc phn t C3H10O3N2. Cho 15,25 gam X phn ng ht vi 300 ml dung dch
KOH 1M. C cn dung dch thu c sau phn ng th c phn hi cha hp cht hu c n chc v
phn cht rn khan ch cha m gam cc cht v c. Gi tr ca m l
A. 25,250. B. 12,625. C. 20,050. D. 22,425.
Cu 29: Thc hin cc th nghim sau:
(a) Cho Al vo dung dch FeCl3 d. (b) Cho kim loi Na vo dung dch CuSO4.
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(c) Cho dung dch AgNO3 vo dung dch Fe(NO3)2. (d) Cho dung dch Ba(NO3)2 vo dung dch KHSO4.
(e) Cho dung dch NaAlO2 vo dung dch HCl d. (f) Cho dung dch NaHCO3 vo dung dch BaCl2.
Sau khi kt thc phn ng, s trng hp xut hin kt ta l
A. 4. B. 2. C. 5. D. 3.
Cu 30: Nguyn t Y c ha tr cao nht i vi oxi gp 3 ln ha tr trong hp cht kh vi hiro. Gi M l
hp cht oxit cao nht, N l hp cht kh vi hiro ca Y. T khi hi ca N so vi M l 0,425. Pht biu no
sau y l ng?
A. Oxit cao nht ca Y iu kin thng l cht lng.
B. Phn t YO2 khng phn cc.
C. Oxit cao nht ca Y khng phn ng c vi dung dch BaCl2.
D. Trong bng tun hon cc nguyn t ha hc, Y thuc chu k 4, nhm VIA .
Cu 31: in phn dung dch gm 28,08 gam NaCl v m gam Cu(NO3)2 (in cc tr, mng ngn xp) n
khi khi lng dung dch gim 51,60 gam th ngng in phn thu c dung dch X. Cho thanh st vo X,
sau khi cc phn ng kt thc thy khi lng thanh st gim 6,24 gam v thu c kh NO (sn phm kh
duy nht ca N
+5
). Gi tr ca m l
A. 225,60. B. 157,92. C. 203,04. D. 180,48.
Cu 32: Xt cn bng ha hc: 3H2 (k) + Fe2O3 (r) 2Fe (r) + 3H2O (k) ; H > 0.
Cho cc pht biu sau v cn bng ha hc trn:
(a) Thm Fe2O3 vo th cn bng ha hc chuyn dch theo chiu thun.
(b) Np thm kh H2 vo th cn bng ha hc chuyn dch theo chiu thun.
(c) Tng p sut chung ca h th cn bng ha hc chuyn dch theo chiu thun.
(d) Tng nhit ca h th cn bng chuyn dch theo chiu nghch.
(e) Khi tng nhit th t khi ca hn hp kh so vi H2 gim i.
Trong cc pht biu trn, s pht biu ng l
A. 3. B. 4. C. 2. D. 1.
Cu 33: Mt loi cht bo c cha 30% triolein, 15% tripanmitin v 55% tristearin v khi lng. Cho m
kg cht bo trn phn ng va vi dung dch KOH un nng, thu c 1 tn x phng nguyn cht. Gi
tr ca m l
A. 920,05. B. 920,41. C. 968,68. D. 969,52.
Cu 34: Hn hp X gm hai anehit Y v Z (bit phn t khi ca Y nh hn ca Z). Cho 1,92 gam X tc
dng vi mt lng d dung dch AgNO3 trong NH3, sau khi cc phn ng kt thc, thu c 21,60 gam Ag
v dung dch E. Cho ton b E tc dng ht vi dung dch HCl (d), thu c 0,784 lt CO2 (ktc). Tn ca
Z l
A. anehit acrylic. B. anehit axetic.
C. anehit oxalic. D. anehit propionic.
Cu 35: Cho cc pht biu sau:
(a) CO l oxit trung tnh, khng tc dng vi nc, axit v dung dch kim iu kin thng.
(b) Trong cng nghip, sn xut kh SO2 bng cch cho dung dch HCl tc dng vi mui sunfit.
(c) dinh dng ca phn ln c nh gi bng phn trm khi lng ca photpho trong phn ln.
(d) Dn kh NH3 d vo dung dch FeCl3 thu c kt ta mu nu .
(e) Trong cc loi phn m, phn ure c dinh dng cao nht.
(f) Photpho hot ng ha hc mnh hn photpho trng.
S pht biu ng l
A. 1. B. 4. C. 2. D. 3.
Cu 36: Hp cht T to bi hai ion X
2+
v
2-
3
YZ
. Tng s electron ca ion
2-
3
YZ
bng 42 ht. Bit nguyn
t X, Y u c s proton bng s ntron. Khi lng phn t ca T bng 120 u. Nguyn t X l
A. Mg. B. Ca. C. S. D. Fe.
Cu 37: Cho cc cht sau y: stiren, phenol, glucoz, vinyl axetilen, saccaroz, benzen, axit fomic, anilin,
glixerol, metyl metacrylat. S cht c th lm mt mu nc brom l
A. 5. B. 6. C. 7. D. 8.
Cu 38: Hn hp kh X gm amin no, n chc, mch h Y v ankin Z. t chy hon ton 0,2 mol X, sinh
ra N2; 0,45 mol CO2 v 0,375 mol H2O. Cng thc ca Y, Z ln lt l
A. C3H9N v C2H2. B. C3H9N v C3H4.
C. C2H7N v C2H2. D. C2H7N v C3H4.
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Cu 39: Cho dy cc cht sau: Ca(HCO3)2, (NH4)2CO3, ZnO, CH3COONH4, Fe(NO3)2, Cr2O3, NaH2PO4,
Zn(OH)2. S cht trong dy va tc dng vi dung dch NaOH long va tc dng vi dung dch HCl long
l
A. 7. B. 8. C. 6. D. 9.
Cu 40: Nhng mt thanh Mg vo dung dch cha 0,40 mol Fe(NO3)3 v 0,025 mol Cu(NO3)2. Sau mt thi
gian, ly thanh kim loi ra, ra sch, cn li thy khi lng tng 5,80 gam so vi thanh kim loi ban u
(gi s kim loi sinh ra u bm vo thanh Mg). Khi lng Mg phn ng l
A. 12,60 gam. B. 9,24 gam. C. 12,00 gam. D. 10,44 gam.
II. PHN RING (10 cu)
Th sinh ch c lm mt trong hai phn (Phn A hoc Phn B)
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: Cho dy cc cht sau: CH3CH2OH, CH3CH2CH2CH3, CH3CHO, C2H4(OH)2, CH3COOC2H5,
CH3COONa, CH3OH. S cht trong dy bng mt phn ng trc tip to ra axit axetic l
A. 6. B. 5. C. 4. D. 3.
Cu 42: Cho 0,02 mol amino axit M (cha mt nhm -NH2) phn ng vi 300 ml dung dch HCl 0,1M thu
c hn hp X. phn ng ht vi cc cht trong hn hp X cn 350 ml dung dch NaOH 0,2M, sau
c cn cn thn dung dch to thnh thu c 6,255 gam mui khan. Bit M c cha vng benzen. S ng
phn cu to tha mn iu kin trn ca M l
A. 6. B. 7. C. 5. D. 8.
Cu 43: Trong mt bnh kn cha 0,40 mol axetilen; 0,30 mol metylaxetilen; 0,80 mol H2 v mt t bt Ni.
Nung nng bnh mt thi gian, thu c hn hp kh X c t khi so vi H2 bng 12,0. Sc X vo lng d
dung dch AgNO3 trong NH3 n phn ng hon ton, thu c m gam hn hp kt ta v c 10,1 gam hn
hp kh Z thot ra. Hn hp kh Z phn ng va vi 0,1 mol Br2 trong CCl4. Gi tr ca m l
A. 86,70. B. 77,40. C. 72,75. D. 82,05.
Cu 44: Cho cc pht biu sau:
(a) Nit lng c dng bo qun mu v cc mu vt sinh hc khc.
(b) Ozon trong khng kh l nguyn nhn chnh gy ra s bin i kh hu.
(c) Amoniac c s dng ch yu sn xut axit nitric, phn m.
(d) Clo c dng dit trng nc trong h thng cung cp nc sch.
S pht biu ng l
A. 4. B. 3. C. 1. D. 2.
Cu 45: Hn hp M gm ancol no, n chc, mch h X v anehit no, n chc, mch h Y. t chy
hon ton mt lng M cn dng va 2,80 lt O2 (ktc), sinh ra 2,24 lt kh CO2 (ktc). Y l
A. C2H5CHO. B. C3H7CHO. C. HCHO. D. CH3CHO.
Cu 46: Thy phn este X mch h c cng thc phn t C5H8O2 trong mi trng kim thu c hn hp
hai cht u c kh nng tham gia phn ng trng bc. S cht X tha mn tnh cht trn l
A. 5. B. 4. C. 2. D. 3.
Cu 47: X l dung dch Al2(SO4)3 a mol/lt, Y l dung dch Ba(OH)2 b mol/lt. Nu trn 200 ml dung dch X
vi 300 ml dung dch Y thu c 8,55 gam kt ta. Mt khc, nu trn 200 ml dung dch X vi 500 ml dung
dch Y thu c 12,045 gam kt ta. Gi tr ca a v b ln lt l
A. 0,10 v 0,05. B. 0,075 v 0,10.
C. 0,10 v 0,20. D. 0,05 v 0,075.
Cu 48: C 7 dung dch ring bit: Pb(NO3)2, CuSO4, ZnCl2, NaCl, MgSO4, FeCl3, AgNO3. Nhng vo mi
dung dch mt thanh Ni. S trng hp xut hin n mn in ho l
A. 2. B. 1. C. 3. D. 4.
Cu 49: Cho cc cp cht sau y phn ng vi nhau:
(1) KBr + dung dch H2SO4 c, nng (2) Cl2 + dung dch Ca(OH)2
(3) SO2 + dung dch KMnO4 (4) CO2 + nc Gia-ven
(5) FeS + dung dch HNO3 c, nng (6) dung dch NH3 + dung dch AlCl3
(7) CH3CHO + dung dch AgNO3/NH3, t
o
(8) CH2=CH2 + dung dch KMnO4
(9) Cu + dung dch Fe(NO3)3 (10) Na2SO3 + dung dch H2SO4 c, nng.
S trng hp xy ra phn ng oxi ha - kh l
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A. 8. B. 9. C. 7. D. 6.
Cu 50: Ha tan hon ton 19,2 gam hn hp gm Mg, Al, Fe cn va V ml dung dch hn hp X cha
HCl 1,0M v H2SO4 2,0M, sau khi phn ng xong thu c 11,2 lt H2 ( ktc) v a gam hn hp mui. Gi
tr ca a l
A. 41,95. B. 67,40. C. 64,70. D. 47,60.
B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Cho cc cp cht vi t l s mol tng ng nh sau:
(a) Fe3O4 v Cu (1:1) (b) Sn v CuS (2:1)
(c) Zn v Cu (1:1) (d) Fe2(SO4)3 v Cu (1:1)
(e) FeCl2 v Cu (2:1) (f) FeCl3 v Cu (1:1)
(g) Fe(NO3)2 v Cu (1:2) (h) Fe(NO3)3 v Cu (1:1)
S cp cht c th tan hon ton trong dung dch HCl long nng d l
A. 4. B. 6. C. 5. D. 3.
Cu 52: Khi kho st 10 lt nc th ngi ta thy rng n b nhim bn m miligam NaCN (gi s khng
cn tp cht khc) v pH ca loi nc ny l 7,4. Bit rng axit xianhiric (HCN) l mt axit yu c hng s
phn li axit Ka = 4,93.10
10
. Gi tr ca m l
A. 0,123. B. 0,125. C. 0,105. D. 0,103.
Cu 53: Cho 53,75 gam hn hp X gm kim loi Sn, Fe, Al tc dng va vi 25,20 lt kh Cl2 (ktc).
Mt khc, khi cho 0,40 mol hn hp X tc dng vi dung dch HCl nng d thu c 9,92 lt kh H2 (ktc).
Bit cc phn ng u xy ra hon ton. Khi lng ca kim loi Al trong 0,40 mol hn hp X l
A. 1,54 gam. B. 2,31 gam. C. 3,86 gam. D. 4,05 gam.
Cu 54: Ch dng thm cht ch th phenolphtalein th c th phn bit c bao nhiu dung dch trong cc
dung dch sau y: Na2CO3, NaHSO4, AlCl3, Fe(NO3)3, NaCl, Mg(NO3)2, Ba(NO3)2.
A. 6. B. 7. C. 4. D. 5.
Cu 55: Hp cht hu c X (C6HyOz) mch h, phn t cha mt loi nhm chc. Trong X oxi chim
44,44% theo khi lng. X tc dng vi NaOH to mui Y v cht hu c Z. Cho Y tc dng vi dung dch
HCl to ra cht hu c Y1 l ng phn ca Z. Cng thc cu to ca Z l
A. CH3CHO. B. HO-CH2-CHO.
C. CH3COOH. D. HO-CH2-CH2-CHO.
Cu 56: Cho dy cc cht sau y: C2H4, CH3COOCH=CH2, C2H2, CH3COOH, C2H5OH, CH3CHCl2,
CH3COONH4, CH3COONa. S cht trong dy c to ra t CH3CHO bng mt phn ng l
A. 2. B. 4. C. 5. D. 3.
Cu 57: Qu trnh xy ra trong pin in ha Zn Cu v qu trnh xy ra khi in phn dung dch CuSO4 vi
anot bng Zn c c im chung l
A. anot xy ra s oxi ha H2O v catot xy ra s kh ion Cu
2+
.
B. anot xy ra s oxi ha Zn v catot xy ra s kh ion Cu
2+
.
C. anot xy ra s kh H2O v catot xy ra s oxi ha ion Cu
2+
.
D. anot xy ra s kh Zn v catot xy ra s oxi ha ion Cu
2+
.
Cu 58: Cho cc vt liu sau: keo dn ure-fomanehit; t lapsan; t nilon-6,6; t enang; nha novolac;
t visco; t olon; t nilon-6. Trong cc vt liu trn, s vt liu c ch to t polime trng ngng l
A. 4. B. 6. C. 5. D. 7.
Cu 59: Cho xenluloz phn ng vi anhirit axetic (xc tc thch hp) ngi ta thu c thu c 79,05
gam hn hp rn X gm xenluloz triaxetat v xenluloz iaxetat. trung ha ht lng axit to ra cn
dng 362,50 ml dung dch NaOH 2,0M. Phn trm khi lng ca xenluloz iaxetat trong X l
A. 61,10%. B. 54,46%. C. 38,90%. D. 45,54%.
Cu 60: Hp cht X c dng H2NR(COOR)2. Thy phn hon ton mt lng cht X trong 250 ml dung
dch NaOH 1M ri c cn, thu c 4,60 gam mt ancol Y v 15,55 gam cht rn khan Z. un nng lng
ancol Y trn vi H2SO4 c 170
o
C thu c 0,075 mol anken vi hiu sut phn ng l 75%. Cho ton b
cht rn Z tc dng vi dung dch HCl d ri c cn, thu c m gam cht rn khan T (qu trnh c cn
khng xy ra phn ng). Gi tr ca m l
A. 17,95. B. 23,80. C. 20,15. D. 15,03.
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p n :
1. A 2. D 3. B 4. D 5. A 6. C 7. D
8. D 9. A 10. C 11. D 12. D 13. B 14. A
15. A 16. D 17. A 18. D 19. B 20. B 21. D
22. C 23. C 24. A 25. C 26. C 27. C 28. D
29. D 30. A 31. D 32. D 33. A 34. C 35. D
36. B 37. C 38. A 39. A 40. A 41. A 42. A
43. C 44. B 45. C 46. D 47. B 48. C 49. C
50. C 51. A 52. C 53. B 54. B 55. B 56. B
57. B 58. B 59. B 60. B
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