Trang 1/4 - M thi 570- KHI B

S GIO DC & O TO
TRNG THPT CHUYN QUNG BNH

LN 1 Ngy 15/3/2014
THI TH TUYN SINH I HC, CAO NG
MN: HO KHI B
Thi gian lm bi: 90 pht; khng k thi gian pht
(50 cu trc nghim)


M thi: 570
(Th sinh khng c s dng ti liu)
H, tn th sinh:..................................................................... S bo danh: .............................

Cho bit nguyn t khi (theo vC) ca cc nguyn t: H = 1; He = 4; Li = 7; Be = 9; C = 12; N = 14; O = 16; Na = 23;
Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Rb = 85; Sr =
88; Ag = 108; Sn = 119; Cs = 133; Ba = 137; Pb = 207.

I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: Cho 0,5 mol Mg v 0,2 mol Mg(NO
3
)
2
vo bnh kn khng c oxi ri nung nhit cao n phn ng hon ton
thu c hn hp cht rn X. Hn hp cht rn X tc dng vi nhiu nht 500 ml dung dch Fe(NO
3
)
3
c nng aM. Gi
tr ca a l
A. 0,667. B. 0,4. C. 2. D. 1,2.
Cu 2: Cho cc cht: NaHSO
3
; NaHCO
3
; KHS; NH
4
Cl; AlCl
3
; CH
3
COONH
4
, Al
2
O
3
, Zn, ZnO, NaHSO
4
. S cht lng
tnh l
A. 8. B. 7. C. 6. D. 5.
Cu 3: Cho cc nguyn t X (Z = 11); Y(Z = 13); T(Z=17). Nhn xt no sau y l ng?
A. Oxit v hiroxit ca X, Y, T u l cht lng tnh.
B. Nguyn t cc nguyn t X, Y, T trng thi c bn u c 1 electron c thn.
C. Cc hp cht to bi X vi T v Y vi T u l hp cht ion.
D. Theo chiu X, Y, T bn knh ca cc nguyn t tng ng tng dn.
Cu 5: Cho s sau:
C
2
H
5
OH
T
Y Z CH
4
NaOH
axit metacrylic
F Poli(metyl metacrylat)
X

Cng thc cu to ca X l
A. CH
2
=CHOOCC
2
H
5
. B. CH
2
=C(CH
3
)OOCC
2
H
5
. C. CH
2
=C(CH
3
) COOC
2
H
5
. D. CH
2
=CHCOOC
2
H
5

Cu 6: Cho cc cht NaCl, FeS
2
, Fe(NO
3
)
2
, NaBr, CaCO
3
, NaI. C bao nhiu cht m khi tc dng vi dung dch H
2
SO
4

c, un nng th c phn ng oxi ha-kh xy ra?
A. 5. B. 3. C. 6. D. 4.
Cu 7: x phng ho 10 kg cht bo c ch s axit bng 7, ngi ta un cht bo vi dd cha 1,42 kg NaOH. Sau
khi phn ng hon ton, mun trung ho NaOH d cn 500 ml dd HCl 1M. Khi lng x phng nguyn cht to ra l
A. 11230,3 gam B. 10365,0 gam C. 10342,5 gam D. 14301,7 gam
Cu 8: Nhn xt no sau y sai?
Cu 9: Trong cc phn ng sau:
1, dung dch Na
2
CO
3
+ H
2
SO
4
2, dung dch NaHCO
3
+ FeCl
3
3, dung dch Na
2
CO
3
+ CaCl
2

4, dung dch NaHCO
3
+ Ba(OH)
2
5, dung dch(NH
4
)
2
SO
4
+ Ca(OH)
2
6, dung dch Na
2
S + AlCl
3

Cc phn ng c to ng thi c kt ta v kh bay ra l:
A. 1, 3, 6 B. 2, 5 C. 2, 3, 5 D. 2, 5, 6
Cu 10: Cho phn ng : 3H
2
(kh) + Fe
2
O
3
(rn) 2Fe + 3H
2
O (hi) Nhn nh no sau y l ng?
A. Nghin nh Fe
2
O
3
cn bng ha hc chuyn dch theo chiu thun
B. Thm Fe
2
O
3
cn bng ha hc chuyn dch theo chiu thun
C. Thm H
2
vo h

cn bng ha hc chuyn dch theo chiu thun
D. Tng p sut cn bng ha hc chuyn dch theo chiu thun
Cu 11: Nhn nh no sau y khng ng?
A. Cc xeton khi cho phn ng vi H
2
u sinh ra ancol bc 2.
B. Axeton khng lm mt mu dung dch KMnO
4
iu kin thng.
C. Tr axetilen, cc ankin khi cng nc u cho sn phm chnh l xeton.
D. Cc hp cht c cha nhm >C=O u phn ng vi nc Brm.
A. Cc dung dch glixin, alanin, lysin u khng lm i mu qu
B. Polipeptit km bn trong mi trng axit v baz
C. lin kt peptit l lin kt ca nhm CO vi nhm NH gia 2 n v -aminoaxit
D. Cho Cu(OH)
2
trong mi trng kim vo dung dch protein s xut hin mu tm xanh
Cu 4: Cho cc th nghim sau
(1) Sc SO
3
vo dung dch BaCl
2
(2) Cho SO
2
vo dung dch Ba(OH)
2
d
(3) Cho dung dch KOH vo dung dch Ba(HCO
3
)
2
(4) Cho dung dch H
2
S vo dung dch FeCl
2

(5) Cho NH
3
d vo dung dch AlCl
3
S th nghim thu c kt ta l
A. 5. B. 3. C. 4. D. 2.
Trang 2/4 - M thi 570- KHI B
Cu 12: 4,2 gam st trong khng kh mt thi gian thu c 5,32 gam hn hp X gm st v cc oxit ca n. Ha tan
ht X bng dung dch HNO
3
, thy sinh ra 0,448 lt kh NO (ktc, sn phm kh duy nht) v dung dch Y. Vy khi lng
mui khan thu c khi c cn dung dch Y l
A. 13,5 gam. B. 18,15 gam. C. 16,6 gam. D. 15,98 gam.
Cu 13: Nguyn t ca nguyn t X c tng s ht electron trong cc phn lp p l 7. S ht mang in ca mt nguyn
t Y nhiu hn s ht mang in ca mt nguyn t X l 8 ht. Cc nguyn t X v Y ln lt l (bit s hiu nguyn t
ca nguyn t:
A. Al v Cl. B. Al v P. C. Fe v Cl. D. Na v Cl.
Cu 14: Nung hn hp bt KClO
3
, KMnO
4
, Zn mt thi gian. Ly hn hp sn phm rn cho vo dung dch H
2
SO
4
long
th thu c hn hp kh. Hn hp l
A. H
2
, Cl
2
v O
2
. B. Cl
2
v O
2
. C. Cl
2
v H
2
. D. O
2
v H
2
.
Cu 15: Cho cc phn ng sau:
(1) Cu(NO
3
)
2

0
t
(2) H
2
NCH
2
COOH + HNO
2
(3) NH
3
+ CuO
0
t

(4) NH
4
NO
2

0
t
(5) C
6
H
5
NH
2
+ HNO
2

) ( HCl
0
5 0
(6) (NH
4
)
2
CO
3

0
t

Cc phn ng thu c N
2
l
A. 4, 5, 6. B. 2, 3, 4. C. 1, 2, 3. D. 3, 4, 5.
Cu 16: Nung 18,4 gam hn hp 2 mui cacbonat ca 2 kim loi ha tr 2, thu c 9,6 gam cht rn v kh X. Lng kh X sinh ra
cho hp th vo 150 ml dung dch NaOH 2M, khi lng mui khan thu c sau phn ng l
A. 12,6 gam. B. 19 gam. C. 15,9 gam. D. 7,95 gam.
Cu 17: Trong cc cht sau: HCHO, CH
3
Cl, CH
3
COOCH
3
, CH
3
ONa, CH
3
OCH
3
, CO, CH
2
Cl
2
c bao nhiu cht to ra
metanol bng 1 phn ng ?
A. 5 B. 6 C. 4 D. 3
Cu 18: Kh m gam Fe
3
O
4
bng kh H
2
thu c hn hp X gm Fe v FeO, hn hp X tc dng va ht vi 3 lt dung
dch H
2
SO
4
0,2M (long). Gi tr ca m l
A. 23,2 gam B. 34,8 gam C. 11,6 gam D. 46,4 gam
Cu 19: Dy gm cc cht m khi cho tng cht tc dng vi dung dch HI u sinh ra sn phm c it l
A. Fe
2
O
3
, Fe
3
O
4
, Fe
2
(SO
4
)
3
, Cl
2
. B. Fe(OH)
3
, FeO, FeCl
3
, Fe
3
O
4
.
C. AgNO
3
, Na
2
CO
3
, Fe
2
O
3
, Br
2
. D. Fe
3
O
4
, FeO, AgNO
3
, FeS.
Cu 20: Khng nh khng ng v cht bo l
A. Cht bo l trieste ca glixerol vi axit bo.
B. un cht bo vi dung dch NaOH th thu c sn phm c kh nng ha tan Cu(OH)
2
.
C. Cht bo v du m bi trn my c cng thnh phn nguyn t.
D. Cht bo nh hn nc.
Cu 21: Dung dch c kh nng ha tan Ag
2
S l
A. HCl. B. NaCN. C. H
2
SO
4
(long). D. NaOH (c).
Cu 22: Cho 100 ml dung dch FeCl
2
1M vo 500 ml dung dch AgNO
3
1M, sau phn ng hon ton khi lng kt ta thu
c l
A. 39,5 gam. B. 71,75 gam. C. 28,7 gam. D. 10,8 gam.
Cu 23: Cho cc dung dch c cng nng mol/lit: CH
3
COOH; KHSO
4
; CH
3
COONa; NaOH. Th t sp xp cc dung
dch theo chiu pH tng dn l
A. CH
3
COOH; CH
3
COONa; KHSO
4
; NaOH. B. KHSO
4
; CH
3
COOH; NaOH; CH
3
COONa .
C. CH
3
COOH; KHSO
4
; CH
3
COONa; NaOH. D. KHSO
4
; CH
3
COOH; CH
3
COONa; NaOH.
Cu 24: Cho cc cht sau: CH
3
-CH
2
-CHO (1), CH
2
=CH-CHO (2), (CH
3
)
2
CH-CHO (3), CH
2
=CH-CH
2
-OH (4). Nhng cht phn ng
hon ton vi lng d H
2
(Ni, t
0
C) cng to ra mt sn phm l:
A. (1),(3) , (4). B. (1),(2) , (4). C. (2),(3), (4). D. (1),(2) , (3).
Cu 25: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na
2
O v Al
2
O
3
; Cu v FeCl
3
; BaCl
2
v
CuSO
4
; Ba v NaHCO
3
. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l
A. 4. B. 1. C. 3. D. 2.
Cu 26: Cho 4,3 gam hn hp BaCl
2
v CaCl
2
vo 100 ml dung dch hn hp Na
2
CO
3
0,1M v (NH
4
)
2
CO
3
0,25M thy to
thnh 3,97 gam kt ta R. Tnh s mol ca mi cht trong R
A. 0,01 mol BaCO
3
v 0,02 mol CaCO
3
B. 0,015 mol BaCO
3
v 0,01 mol CaCO
3

C. 0,01 mol BaCO
3
v 0,015 mol CaCO
3
D. 0,02 mol BaCO
3
v 0,01 mol CaCO
3

Cu 27: Mt loi nc cng c cha Ca
2+
0,004 M ; Mg
2+
0,003 M v HCO
-
3
. Hy cho bit cn ly bao nhiu ml dung dch
Ca(OH)
2
0,02 M bin 1 lt nc cng thnh nc mm (cc phn ng xy ra hon ton v kt ta thu c gm CaCO
3
v
Mg(OH)
2
).
A. 300 ml. B. 200 ml. C. 500 ml. D. 400 ml.
Cu 28: Trong cc loi t sau: t visco, t xenluloz axetat, t nitron, T lapsan, nilon-6,6. S t c iu ch bng
phng php trng ngng l
A. 3 B. 2 C. 4 D. 1
Cu 29: Este n chc X c t khi hi so vi metan bng 6,25. Cho 20 gam tc dng 300ml dung dch KOH 1M (un
nng), c cn dung dch thu c 28 gam cht rn khan. Cng thc cu to ca X l
A. CH
3
-CH
2
-COO-CH=CH
2
. B. CH
3
-COO-CH=CH-CH
3
.
C. CH
2
=CH-CH
2
-COOH. D. CH
2
=CH-COO-CH
2
-CH
3

Cu 30: Cho phn ng ha hc sau: [-CH
2
-CH(OCOCH
3
)-]
n
+ nNaOH
t
[-CH
2
-CH(OH)-]
n
+ nCH
3
COONa
Trang 3/4 - M thi 570- KHI B
Phn ng ny thuc loi phn ng
A. phn ct mch polime. B. gi nguyn mch polime. C. khu mch polime. D. iu ch polime.
Cu 31: Nhng mt thanh Magie vo dung dch c cha 0,8 mol Fe(NO
3
)
3
v 0,05 mol Cu(NO
3
)
2
, sau mt thi gian ly
thanh kim loi ra cn li thy khi lng tng 11,6 gam. Khi lng Magie phn ng l
A. 6,96 gam B. 24 gam C. 20,88 gam D. 25,2 gam
Cu 32: phn bit hai dung dch Ba(HCO
3
)
2
, C
6
H
5
ONa v hai cht lng C
6
H
6
, C
6
H
5
NH
2
ta c th dng ha cht no sau
y
A. Kh CO
2
B. Dung dchphenolphtalein. C. Qu tm. D. dung dch H
2
SO
4
.
Cu 33: Hn hp A gm glucoz v mantoz. Chia A lm 2 phn bng nhau:
- Phn 1: Ho tan vo nc, lc ly dung dch ri cho tc dng vi AgNO
3
/NH
3
d c 0,02 mol Ag.
- Phn 2: un vi dung dch H
2
SO
4
long. Hn hp sau phn ng c trung ho bi dung dch NaOH, sau cho ton
b sn phm tc dng vi lng d dung dch AgNO
3
/NH
3
c 0,03 mol Ag.
S mol ca glucoz v mantoz trong A ln lt l
A. 0,005 v 0,005. B. 0,0035 v 0,0035. C. 0,01 v 0,01. D. 0,0075 v 0,0025.
Cu 34: un nng 5,8 gam hn hp A gm C
2
H
2
v H
2
trong bnh kn vi xc tc thch hp sau phn ng c hn hp
kh X. Dn hn hp X qua bnh ng dung dch Br
2
d thy bnh tng ln 1,4 gam v cn li hn hp kh Y. Tnh khi
lng ca hn hp Y.
A. 5,4 gam. B. 6.2 gam. C. 3,4 gam. D. 4,4 gam.
Cu 35: Hai hp cht hu c mch h c cng thc phn t ln lt l C
2
H
8
O
3
N
2
v C
3
H
7
O
2
N u tc dng vi dung dch
NaOH un nng, cho hai amin n chc bc 1 thot ra. Nhn xt no sau y ng v hai hp cht hu c trn?
A. Chng u l cht lng tnh. B. Chng u tc dng vi dung dch brom.
C. Phn t ca chng u c lin kt ion. D. Chng u tc dng vi H
2
(xc tc Ni, un nng).
Cu 36: tch c CH
3
COOH t hn hp gm CH
3
COOH v C
2
H
5
OH ta dng ho cht no sau y?
A. Ca(OH)
2
v dung dch H
2
SO
4
B. CuO (t
o
) v AgNO
3
/NH
3
d
C. Na v dung dch HCl D. H
2
SO
4
c
Cu 37: Cho cc monome sau: stiren, toluen, metylaxetat, etilenoxit, vinylaxetat, caprolactam, metylmetacrylat,
metylacrylat, propilen, benzen, axt etanoic, axt -aminocaproic, acrilonitrin. S monome tham gia phn ng trng
hp l
A. 8. B. 7. C. 6. D. 9.
Cu 38: Trong phng th nghim, ngui ta thng iu ch HNO
3
t
A. NaNO
3
rn v H
2
SO
4
c. B. NaNO
3
rn v HCl c. C. NaNO
2
rn v H
2
SO
4
c. D. NH
3
v O
2
.
Cu 39: Cho Xenluloz phn ng vi anhirit axetic (H
2
SO
4
l xc tc) thu c 11,10 gam hn hp X gm xenluloz
triaxetat v xenluloz iaxetat v 6,60 gam axit axetic. Thnh phn phn % theo khi lng ca xenluloz triaxetat v
xenluloz iaxetat trong X ln lt l
A. 76,84%; 23,16%. B. 70,00%; 30,00%. C. 77,84%; 22,16%. D. 77,00%; 23,00%.
Cu 40: Kim loi Al phn ng c tt c cc cht trong nhm no sau y nhit thng?
A. dung dch H
2
SO
4
long, dung dch NaOH, dung dch MgCl
2

B. dung dch Ba(OH)
2
, dung dch KHSO
4
, dung dch FeSO
4

C. HNO
3
c ngui, dung dch CH
3
COOH, dung dch CuSO
4

D. dung dch FeCl
3
, dung dch CrCl
3
, Fe
3
O
4


II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B)
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)

Cu 41: Ha tan m gam hh X gm CuCl
2
v FeCl
3
trong nc c dung dch Y. Chia Y thnh 2 phn bng nhau. Phn 1:
cho kh H
2
S d vo c 1,28g kt ta. Phn 2: cho Na
2
S d vo c 3,04g kt ta. Gi tr ca m l:
A. 14,6 g B. 8,4 g C. 10,2 g D. 9,2 g
Cu 42: X c cng thc C
4
H
14
O
3
N
2
. Khi cho X tc dng vi dung dch NaOH th thu c hn hp Y gm 2 kh iu
kin thng v u c kh nng lm xanh qu tm m. S CTCT ph hp ca X l:
A. 5 B. 3 C. 4 D. 2
Cu 43: Dy cc kim loi c cu trc mng tinh th lp phng tm khi l:
A. Na, K, Mg B. Na, K, Ba C. Ca, Sr, Ba D. Mg, Ca, Ba
Cu 44: C hai th nghim sau:
TN1: Cho 6g ancol no h n chc X tc dng vi m gam Na, sau phn ng thu c 0,075 gam H
2
.
TN 2: Cho 6g ancol no h n chc X tc dng vi 2m gam Na, sau phn ng thu khng ti 0,1gam H
2
.
X c cng thc l:
A. C
4
H
9
OH. B. C
3
H
7
OH. C. C
2
H
5
OH. D. CH
3
OH.
Cu 45: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 50 ml dung dch NaOH
1M. Mt khc, nu t chy hon ton m gam X th thu c 19,04 lt kh CO
2
( ktc) v 14,76 gam H
2
O. % s mol ca
axit linoleic trong m gam hn hp X l:
A. 60% B. 31,25% C. 62,5% D. 30%
Cu 46: Saccaroz v glucoz u c phn ng
A. thu phn trong mi trng axit. B. vi Cu(OH)2
nhit thng.
C. vi dung dch NaCl. D. AgNO
3
trong dung dch NH
3
.
Trang 4/4 - M thi 570- KHI B
Cu 47: Hn hp X gm hai anken c t khi so vi H
2
bng 16,625. Ly hn hp Y cha 26,6 gam X v 2 gam H
2
. Cho
Y vo bnh kn c dung tch V lt ( ktc) c cha Ni xc tc. Nung bnh mt thi gian sau a v 0
0
C thy p sut
trong bnh bng 7/9 at. Bit hiu sut phn ng hiro ho ca cc anken bng nhau v th tch ca bnh khng i. Hiu
sut phn ng hiro ho l
A. 40%. B. 50%. C. 75%. D. 77,77%.
Cu 48: Cho cc cht sau: axetilen, axit oxalic, axit acrylic, fomanehit, phenyl fomat, vinyl axetilen, glucz, anehit
axetic, metyl axetat, saccaroz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l
A. 8 B. 6 C. 7 D. 5
Cu 49: Hin tng ln lt xy ra khi cho t t n d dung dch NaOH vo dung dch CrCl
3
, thm tip H
2
O
2
d, ri
cho dung dch BaCl
2
vo l:
A. To kt ta trng ri tan, thnh dung dch mu xanh, sau c kt ta mu vng.
B. To kt ta xanh lc ri tan, thnh dung dch mu vng, sau c kt ta da cam.
C. To kt ta xanh lc ri tan, thnh dung dch da cam, sau c kt ta mu vng.
D. To kt ta xanh lc ri tan, thnh dung dch mu vng, sau c kt ta mu vng.
Cu 50: Xt phn ng: CO
(kh)
+ H
2
O
(kh)

CO
2(kh)
+ H
2(kh)
. Trong iu kin ng nhit, khi tng p sut
ca h th
tc phn ng nghch nh th no?

A. Tng. B. Gim. C. C th tng hoc gim D. Khng i.

---------------------------------------------
----------- HT ----------

1D
2C
3B
4C
5C
6D
7C
8A
9D

10C
11D
12C
13A
14C
15B
16B
17A
18D
19A
20C
21B

22A
23D
24B
25B
26A
27C
28B
29A
30B
31D
32D
33A
34D
35C
36A
37A
38A
39C

40B
41D
42B
43B
44A
45D
46B
47B
48D
49D
50A