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S GD&T HI DNG
TRNG THPT ON THNG



THI TH I HC LN 1
NM HC 2013-2014
Mn: HA HC
Thi gian lm bi: 90 pht;
H, tn th sinh:................................................................. SBD: .............................

M thi
150
Cho bit nguyn t khi ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; P = 31; Li = 7; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5;
K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108.

Cu 1: Mui X c cc tnh cht sau:
-X tc dng vi dung dch HCl to ra kh Y, kh Y lm c nc vi trong, khng lm mt mu dung
dch brom
-X tc dng vi Ba(OH)
2
c th to 2 mui. Chn cng thc ph hp ca X
A. NaHCO
3
B. Na
2
SO
3
C. Na
2
CO
3
D. Na
2
S
Cu 2: S cht n chc ng vi cng thc C
3
H
6
O
2
l
A. 2. B. 1. C. 4. D. 3.
Cu 3: Hp cht hu c X c cng thc phn t l C
7
H
8
O. S ng phn cha vng benzen ca X tc
dng c vi Na v NaOH l: A. 2 B. 3 C. 4 D. 5
Cu 4: Cho cc phn ng sau trong iu kin thch hp :
(1) NH
3
d + dd AlCl
3
(2) NaHCO
3
+ ddBaCl
2
v un nng
(3) NH
3
d + dd CuSO
4
(4) H
2
S + ddZnCl
2

(5) Zn
3
P
2
+ dd HCl d

(6) K
3
PO
4
+ dd CaCl
2

S th nghim thu c kt ta sau phn ng A. 5 B. 3 C. 4 D. 2
Cu 5: Xt cc h cn bng sau y trong mt bnh kn
(1) 2NaHCO
3

(r)
Na
2
CO
3(r)
+ H
2
O
(k)
+ CO
2(k)
(3) CO
2(k)
+ CaO
(r)
CaCO
3(r)

(2) C
(r)
+ CO
2(k)
2CO
(k)
(4) CO
(k)
+ H
2
O
(k)
CO
2(k)
+ H
2

(k)

Khi thm CO
2
vo h th s cn bng chuyn dch theo chiu thun l:
A. 2. B. 4. C. 1. D. 3.
Cu 6: t chy hon ton m gam hn hp G gm 2 amino axit: no, mch h, hn km nhau 2 nguyn t
C(1 NH
2
; 1 COOH) bng 8,4 lt O
2
(va , ktc) thu c hn hp sn phm X. Cho X li t t qua
dung dch NaOH d nhn thy khi lng dung dch tng ln 19,5 gam. Gi tr gn ng nht ca %khi
lng amino axit ln trong G l.
A. 44, 5% B. 54, 5% C. 56, 7% D. 50%.
Cu 7: Cho 2,721 gam cao su buna-S tc dng va ht vi dung dch cha 3,53 gam brom trong CCl
4
. T
l s mt xch gia butaien v stiren trong loi cao su l
A. 1 : 2. B. 2 : 1. C. 1 : 1. D. 3 : 2.
Cu 8: Cht trong phn t va cha lin kt cng ha tr va cha lin kt ion l
A. CO
2
. B. MgCl
2
. C. HNO
3
. D. NH
4
Cl.
Cu 9: Ho tan hon ton m gam Al vo dung dch NaOH va thu c dung dch X. Chia X thnh 2
phn bng nhau. Phn 1: Nh 200 ml HCl 1,3M vo thu c 1,8a gam cht rn. Phn 2: Nh 200 ml
HCl 2,5M vo thu c a gam cht rn. Gi tr ca m l
A. 2,7 B. 5,4 C. 10,8 D. 8,1
Cu 10: C cc cp dung dch sau :
(1) NaCl v AgNO
3
; (2) NaHSO
4
v BaCl
2
(3) Na
2
CO
3
v HCl;
(4) NaOH v MgCl
2
; (5) BaCl
2
v NaOH; (6) CaCl
2
v NaHCO
3

Nhng cp no khng xy ra phn ng khi trn cc dung dch trong cc cp vi nhau?
A. 2, 4,5, B. 2, 4,5, C. 5,6 D. 2,5,6
Cu 11: S lin kt n trong phn t metyl oleat l
A. 56 B. 52 C. 54 D. 58
Cu 12: Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc
dng vi dung dch NaHCO
3
. X c th l:
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A. metyl axetat. B. axit acrylic. C. phenol. D. anilin.
Cu 13: S cht lm mt mu nc brm trong cc cht sau l bao nhiu?
(1) cumen (2) benzyl amin (3) anehit axetic (4) ancol anlylic (5) phenol
(6) Vinyl axetat (7) fructoz (8) axit stearic (9) axit fomic
A. 7. B. 4. C. 6. D. 5.
Cu 14: Cho 2,67 gam mt amino axit X (cha 1 nhm axit) vo 100 ml HCl 0,2M thu c dung dch
Y. Y phn ng va vi 200 ml KOH 0,25M. Cng thc ca X l
A. H
2
N C
2
H
4
COOH B. (H
2
N)CHCOOH C. H
2
N C
5
H
10
COOH D. (H
2
N)C
4
H
7
COOH
Cu 15: Dy gm cc kim loi c th iu ch bng phng php in phn dung dch l
A. Zn, Fe, Ni, Na. B. Cu, Zn, Mg, Ag. C. Pb, Sn, Al, Ag. D. Cu, Fe, Ag, Sn.
Cu 16: Trong y hc, hp cht no sau y c dng lm thuc tr bnh d dy
A. NaCl B. Na
2
SO
4
C. NaHSO
3
D. NaHCO
3

Cu 17: Cho cc cht: Al, ZnO, Al
2
(SO
4
)
3
, Al(OH)
3
, NaHSO
4
, CH
3
COONH
4
, axit glutamic, KHCO
3;
CH
3
NH
3
Cl; Alanin
. S cht lng tnh l
A. 5. B. 6. C. 4. D. 7.
Cu 18: Cng thc ho hc ca amophot, mt loi phn bn phc hp l:
A. (NH
4
)
2
HPO
4
v Ca(H
2
PO
4
)
2
. B. NH
4
H
2
PO
4
v (NH
4
)
2
HPO
4
.
C. NH
4
H
2
PO
4
v Ca(H
2
PO
4
)
2
. D. Ca(H
2
PO
4
)
2
.
Cu 19: Cho (CH
3
)
2
C=CH- CH
3
cng nc thu c sn phm chnh c tn l
A. 1,1-imetylpropan-2-ol. B. 2-metylbutan-2-ol.
C. 3-metylbutan-2-ol. D. 1,1-imetylpropan-1-ol.
Cu 20: Ha tan ht 38,4 gam Mg trong dung dch HNO
3
long, d. Sau phn ng thu c 8,96 lt kh Z
c cng thc N
x
O
y
(sn phm kh duy nht ktc). Kh Z l
A. N
2
O B. NO
2
C. N
2
D. NO
Cu 21: Cho 4,0 gam hn hp A gm Fe v 3 oxit st trong dung dch axit HCl (d) thu c dung dch
X. Sc kh Cl
2
cho n d vo X thu c dung dch Y cha 9,75 gam mui tan. Nu cho 4 gam A tc
dng vi dung dch HNO
3
long d th thu c V lt NO(sn phm kh duy nht, ktc). Gi tr ca V l
A. 0,896. B. 1,120. C. 0,726. D. 0,747.
Cu 22: Cation X
2+
c tng s ht c bn (p, n, e) bng 80, trong t s ht electron so vi ht ntron l
5
4
. Trong bng tun hon cc nguyn t ho hc, nguyn t X thuc
A. chu k 4, nhm VIIIB. B. chu k 4, nhm VIA.
C. chu k 4, nhm IIA. D. chu k 4, nhm IIB.
Cu 23: in phn dung dch hn hp gm: ZnCl
2
; CuSO
4
v Fe
2
(SO
4
)
3
, thu c cht rn catt theo
th t ln lt l:
A. Cu, Fe, Zn. B. Fe, Zn, Cu. C. Cu, Zn, Fe. D. Fe, Cu, Zn.
Cu 24: S ancol bc I ng vi cng thc C
4
H
10
O l
A. 3. B. 5. C. 4. D. 2.
Cu 25: Cho 2,2 gam anehit n chc Y tc dng vi mt lng d AgNO
3
/NH
3
thu c 10,8 gam
Ag. Xc nh CTCT ca Y ?
A. C
2
H
3
CHO B. HCHO C. CH
3
CHO D. C
2
H
5
CHO
Cu 26: Cho p: Fe
3
O
4
+ H
2
SO
4
(c) ....+ SO
2
+ ....
Tng h s nguyn ti gin ca cc cht sn phm trong phn ng sau l
A. 14. B. 21. C. 26. D. 12.
Cu 27: Mt loi phn ur c 10% tp cht tr khng cha N. dinh dng ca phn ny l
A. 21% B. 23,335% C. 42% D. 46,67%
Cu 28: Cho cn bng sau trong bnh kn: 2NO
2
(k) N
2
O
4


(k).

(mu nu ) (khng mu)
Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c:
A. H > 0, phn ng ta nhit B. H > 0, phn ng thu nhit
C. H < 0, phn ng thu nhit D. H < 0, phn ng ta nhit
Cu 29: t chy hon ton a mol axit cacboxylic Y thu c 2a mol CO
2
. Mt khc trung ha ht a
mol Y cn 2a mol NaOH. Gi tn Y ?
A. Axit metacrylic B. Axit oleic C. Axit oxalic D. Axit acrylic
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Cu 30: S amin ng vi cng thc phn t C
4
H
11
N m khi cho vo dung dch HNO
2
khng c kh bay ra l
A. 3. B. 2. C. 5. D. 4.
Cu 31: X. Y l hai nguyn t thuc thuc cng mt phn nhm v 2 chu k lin tip trong bng tun
hon. Bit Z
X
+ Z
Y
= 32. S proton trong nguyn t nguyn t X, Y ln lt l :
A. 7 v 25 B. 8 v 24 C. 12 v 20 D. 15 v 17
Cu 32: Nh 147,5 ml dung dch H
2
SO
4
2M vo 200ml dung dch Y gm: KAlO
2
1M v NaOH 1,5M
thu c a gam kt ta. Xc nh
A. 13,26 B. 15,8 C. A. 4,46 D. 8,58
Cu 33: Tin hnh cc th nghim sau:
- Cho Cu vo dung dch Fe
2
(SO
4
)
3
.
- Cho dung dch AgNO
3
d vo dung dch FeCl
2
.
- Cho Fe
3
O
4
vo dung dch H
2
SO
4
long d.
- Sc H
2
S vo dung dch CuCl
2
.
- Sc H
2
S vo dung dch FeCl
3
.
- Cho Fe
2
O
3
vo dung dch HI.
S th nghim xy ra phn ng oxi ha kh l A. 4. B. 3. C. 5. D. 2.
Cu 34: S th nghim xy ra n mn in ha trong cc th nghim sau l bao nhiu?
(1) Nhng thanh Zn vo dung dch AgNO
3
.
(2) Cho vt bng gang vo dung dch HCl.
(3) Cho Na vo dung dch CuSO
4
.
(4) ming tn( Fe trng Zn) c vt xc su ngoi khng kh m
(5) Cho inh st vo dung dch H
2
SO
4
2M.
(6) Cho Mg vo dung dch FeCl
3
d
A. 3 B. 2 C. 4 D. 5
Cu 35: S cht tc dng c vi H
2
trong iu kin thch hp trong cc cht sau l bao nhiu?
(1) Stiren (2) propoilen (3) Glucoz (4) Vinyl axetilen (5) saccaroz
(6) metyl acrylat (7) etyl xiclopropan (8) xiclohexan (9) axit fomic
A. 6. B. 8. C. 7. D. 5.
Cu 36: Nung 16 gam hn hp G gm: Al, Mg, Zn, Cu trong bnh ng oxi d thu c m gam hn hp
oxit X. Ha tan hon ton m gam hn hp oxit cn 160 ml dung dch HCl 3,5M. Gi tr m l
A. 27,6. B. 20,48. C. 18,24. D. 24,96.
Cu 37: Chia m gam hn hp G gm: 0,01 mol fomanehit; 0,02 mol anehit oxalic; 0,04 mol axit
acrylic; 0,02 mol Vinyl fomat thnh 2 phn bng nhau.
Phn 1: Cho vo AgNO
3
/NH
3
(d, un nng) thu c a gam Ag.
Phn 2: Lm mt mu va b lt nc Br
2
0,5M.
Cc phn ng u xy ra hon ton, gi tr ca a, b ln lt l
A. 8,64 v 0,16 B. 8,64 v 0,14 C. 10,8 v 0,16 D. 10,8 v 0,14
Cu 38: in phn c mng ngn 100 ml dung dch cha hn hp gm CuCl
2
0,5M v NaCl 2,5M
(in cc tr, hiu sut in phn 100%) vi cng dng in 7,5A trong 3860 giy thu c dg X.
X c kh nng ho tan m gam Zn. Gi tr ln nht ca m l
A. 6,5. B. 13. C. 3,25. D. 9,75.
Cu 39: Cho 1 ancol n chc X vo H
2
SO
4
c, un nng thu c sn phm hu c Y (khng cha S). T khi
ca X so vi Y l 4/3. Cng thc phn t ca X l
A. C
3
H
6
O B. C
3
H
8
O C. C
4
H
8
O D. C
4
H
10
O
Cu 40: Ln men m gam glucoz thnh ancol etylic th thu c 100 ml ancol 46
0
. Khi lng ring ca ancol
nguyn cht l 0,8 gam/ml. Hp th ton b kh CO
2
sinh ra trong qu trnh ln men vo dung dch NaOH d thu
c a gam mui (cc phn ng xy ra hon ton). Gi tr ca a l
A. 106 gam. B. 84,8 gam. C. 169,6 gam. D. 212 gam.
Cu 41: Dy gm cc kim loi tc dng nhiu c vi hi nc khi nung nng l:
A. Ca, Zn, Mg, Ag. B. Mg, Be, Sn, K. C. Pb, Sn, Al, Zn. D. Zn, Fe, Ba, Na.
Cu 42: E l este thun chc, mch khng nhnh. un nng m gam E vi 150 ml dung dch NaOH 2M
n hon ton thu c dung dch X. Trung ho X cn 200 ml dung dch HCl 0,3M thu c dung dch
Y. C cn Y thu c 22,95 gam hn hp hai mui khan v 11,04 gam hn hp 2 ancol n chc. Cng
thc cu to ca E l
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A. CH
3
-CH
2
-OOC-CH
2
COOCH
3
B. HCOOCH
3
v CH
3
COOC
2
H
5

C. C
2
H
5
-COO-C
2
H
5
D. CH
3
CH
2
CH
2
-OOC-CH
2
CH
2
COOCH
3

Cu 43: Ha tr cao nht trong hp cht vi oxi ca nguyn t R gp 3 ln ha tr ca n trong hp cht kh
vi hiro. Phn trm khi lng ca R trong hp cht kh vi hiro nhiu hn trong hp cht c ha tr cao
nht vi oxi l 54,11%. Nguyn t R l
A. P. B. S. C. N. D. Cl.
Cu 44: Cho 1,792 lt hn hp X gm: propin, H
2
( ktc, t khi ca X so vi H
2
bng 65/8) i qua xc
tc nung nng trong bnh kn thu c hn hp kh Y c t khi ca Y so vi He bng a. Y lm mt mu
va 160 gam nc brom 2%. Gi tr gn ng nht ca a l
A. 8,12 B. 32,58 C. 10,8 D. 21,6
Cu 45: Cho 7, 46 gam 1 pept i t c cng t hc: Al a-Gl y-Val -Lys vo 200 ml HCl 0, 45M
un nng n phn ng hon t on t hu c dung d ch X. C cn X t hu c a gam
cht rn khan Y. Gi t r ca a l
A. 11, 717 B. 10, 745 C. 10, 971 D. 11, 825
Cu 46: Cho 9, 27 gam pept i t X c cng t hc: Val -Gl y-Val vo 200 ml NaOH 0, 33M
un nng n phn ng hon t on t hu c dung d ch Y. C cn Y t hu c m gam
cht rn khan Z. Gi t r ca m l
A. 11, 802 B. 11, 514 C. 11, 37 D. 11, 3286
Cu 47: Cho 8, 88 gam 1 cht cha nhn t hm A c cng t hc
C
2
H
3
OOCC
6
H
3
(OH)OOCCH
3
vo 200 ml KOH 0, 9M un nng n phn ng hon t on
t hu c dung d ch B. C cn B t hu c b gam cht rn khan. Gi t r ca b l
A. 17, 2 B. 15, 76 C. 16, 08 D. 14, 64
Cu 48: Sc 6,72 lt CO
2
(ktc) vo 100ml dung dch X gm: Na
2
ZnO
2
1M v NaOH 2M thu c a
gam kt ta. Gi tr ca a l. A. 14,85 B. 4,95 C. 7,8 D. 9,9
Cu 49: Tn quc t (theo IUPAC) ca hp cht c cng thc CH
3
CH(C
2
H
5
)CH(OH)CH
3
l
A. 3-etyl hexan-5-ol. B. 4-etyl pentan-2-ol.
C. 3-metyl pentan-2-ol. D. 2-etyl butan-3-ol.
Cu 50: Cho 16,8 gam Fe vo 2 lt dung dch AgNO
3
, phn ng xy ra hon ton th thy to thnh
86,4 gam kt ta. Nng ca AgNO
3
trong dung dch ban u l
A. 0,35M B. 0,3 M C. 0,2 M D. 0,4M

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P N THI TH I HC MN HA LN 1
M 150 M 210 M 375 M 458 M 575
Cu A Cu A Cu A Cu A Cu A
1 A 1 C 1 A 1 C 1 A
2 D 2 D 2 C 2 A 2 D
3 B 3 B 3 D 3 A 3 A
4 B 4 A 4 A 4 D 4 A
5 A 5 C 5 A 5 D 5 D
6 C 6 C 6 A 6 D 6 B
7 D 7 B 7 B 7 B 7 B
8 D 8 D 8 A 8 B 8 B
9 C 9 C 9 D 9 A 9 B
10 C 10 B 10 D 10 B 10 D
11 C 11 D 11 B 11 B 11 A
12 C 12 D 12 B 12 B 12 A
13 C 13 D 13 C 13 D 13 A
14 A 14 B 14 C 14 A 14 C
15 D 15 C 15 A 15 A 15 A
16 D 16 D 16 C 16 C 16 A
17 B 17 A 17 A 17 A 17 B
18 B 18 B 18 A 18 C 18 D
19 B 19 D 19 C 19 D 19 A
20 A 20 A 20 A 20 C 20 C
21 D 21 B 21 A 21 A 21 B
22 A 22 A 22 C 22 C 22 B
23 A 23 A 23 B 23 B 23 B
24 A 24 B 24 B 24 B 24 C
25 C 25 A 25 B 25 C 25 D
26 A 26 D 26 B 26 C 26 A
27 C 27 D 27 C 27 C 27 D
28 D 28 D 28 B 28 C 28 A
29 C 29 C 29 C 29 A 29 C
30 D 30 B 30 D 30 B 30 D
31 C 31 D 31 D 31 D 31 C
32 A 32 D 32 D 32 C 32 B
33 A 33 D 33 C 33 D 33 B
34 A 34 B 34 B 34 B 34 A
35 A 35 B 35 A 35 A 35 A
36 B 36 A 36 C 36 B 36 B
37 C 37 C 37 D 37 A 37 A
38 A 38 C 38 A 38 A 38 A
39 C 39 A 39 A 39 C 39 B
40 B 40 B 40 D 40 40 D
41 D 41 B 41 D 41 A 41 C
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42 D 42 D 42 C 42 D 42 D
43 B 43 B 43 D 43 A 43 C
44 A 44 D 44 A 44 C 44 B
45 D 45 A 45 D 45 A 45 C
46 A 46 C 46 A 46 C 46 D
47 B 47 A 47 D 47 D 47 B
48 B 48 C 48 C 48 B 48 C
49 C 49 B 49 C 49 C 49 D
50 D 50 A 50 B 50 B 50 B