S GIO D C V O T O K THI H C SINH GI I GI I TON

TRN MY TNH C M TAY C P T NH

NM H C: 2011 2012
Mn: HA H C
Ngy thi: 27/11/2011
L u : N u th sinh c cch gi i khc h p logic v chnh xc v n h ng s i m.
Cu 1: (5 i ! M t h p ch t AB
2
c t ng s h t (p n !" # ng $%& t'(ng ) s h t
*+ng )i n nhi , h n s h t -hng *+ng )i n . /01 T ng s h t (p n !" t'(ng ng,y2n
t A nhi , h n B c3ng . /01 S -h i c + A . n h n s -h i c + B . 2/1 45c ) nh t2n
h p ch t AB
2
1
C"#$ %i i K & 'u (i
A : 6
A
N
A

B: 6
B
N
B
Th!( ) #i '+ t+ c:
(26
A
7 N
A
" 7 2(26
B
7 N
B
" 8 $%& ($"
(26
A
7 06
B
" 9 (N
A
7 2N
B
" 8 /0 (2"
(26
A
7 N
A
" 9 (26
B
7 N
B
" 8 /0 (/"
(6
A
7 N
A
" 9 (6
B
7 N
B
" 8 2/ (0"
T ($" : (2" t+ gi i ) c:
A B
A B
26 06 ;% (<"
N 2N /& (&"
+ =

+ =
T (/" : (0" t+ gi i ) c:
A B
A B
6 9 6 $$ (;"
N N $2 (="
=

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T (<" : (;" t+ gi i ) c 6
A
8 $> 6
B
8 =
V y h p ch t . ?O
2
: -+.i s,p!(@it
KO
2
K)*i +u,-./i&
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H NG 0 N CH M

Cu 2: (5 i ! M t ng,y2n t -i* .( i M c #5n -Bnh ng,y2n t C 8 $0/ p* : ) n
ch t - t tinh th!( c , t'Dc . p ph ng tE* Fi n c -h i . ng 'i2ng D 8 2; gAc*
/
1 45c
) nh -i* .( i M1
C"#$ %i i K & 'u (i
T'(ng * t * ng c c . p ph ng tE* Fi n s ng,y2n t
# ng:
0 &
2
$
=
=
$
6 =

=
G i + . ) Fi c nh * ng c s 1 ?h( ng c5ch ng n nh t gi +
c5c ng,y2n t . t'2n ) ng chG( c + * t n2n:
p* 0%0
2
$0/ 0
+
0
2 +
C =

= =
T
/
A
+
6
N
M
V
6 *
F

=

=
0
" *(. $% 1 %2 & ( " c* $% 1 0%0 ( " c* A g ; 2 (
6
N + F
M
$ 2/ / $% /
A
/

=

=
*(. A g ;> 2& M =
1
V y M . A.1
( M 8 2&== gA*."
mol g A ;> 2&
$)
$)
2<)
%<
2A$%

Cu 1: ( 5 i ! Ng,y2n t C . phi -i* th, c nh* A t'(ng H th ng t, n h(n1 T
. gi + thnh ph n ph n t'I* ng,y2n t C t'(ng (@it c+( nh t : i thnh ph n ph n t'I*
ng,y2n t C t'(ng h p ch t -hB : i hiF'( .
/0
2< 2%
1
+145c ) nh ng,y2n t C1
#1Ch( 0%<g * t -i* .( i M ch + 'J h+ t' t5c F ng h t : i ) n ch t C t'2n
thK th, ) c 0%%<g *, i1 45c ) nh ng,y2n t M1
C"#$ %i i K & 'u (i
G i @ . s th t nh* A (h+ t' " !
Cng th c (@it c+( nh t: C
2
O
@
CT h p ch t -hB : i H: CH
=9@
T+ c:
/0
2< 2%
=
:
$& 2
2
=
+ + x R
R
x R
R
C 8
< 2;
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C /;2 <$< &<; =%
V y: C . B'
2M 7 +B'
2
2MB'
+
2M 2M 7 $&%+
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2 a M M +
=
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M 8 >+
+ $ 2 /
M > $= 2;
V y: M . A.
C . B'
M . A.
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Cu 2: ( 5 i ! TBnh n ng ) *(.A. c5c i(n : pH c + F,ng F ch N+ #
2
CO
/
%%$ML
Bi t CO
/
29
c ?
#$
8 $%
9/;&
M ?
#2
8 $%
9;&<

1
C"#$ %i i K & 'u (i
N+
2
CO
/
2N+
7
7 CO
/
29
($" CO
/
29

7 H
2
O


HCO
/
9
7 OH
9

&; /
$%
$

=
b
K
(2" HCO
/
9

7 H
2
O


H
2
CO
/
7 OH
9

&< ;
2
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=
b
K
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2
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H
7
7 OH
9
?
N
8 $%
9$0
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b
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2
b OO ?
N
n2n
CEn # ng ($" . ch y ,
CO
/
29

7 H
2
O


HCO
/
9
7 OH
9

&; /
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$

=
b
K
PB)Q %1%$
PR1 ngQ @
PCBQ %1%$ S @ @ @
$
b
K
8
;& /
2
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=
x
x
@ 8 $2/01$%
9/
pOH 8 2>%=
pH 8 $$%>2
PN+
7
Q 8 %%2M
PCO
/
29
Q 8 %%$ S $2/01$%
9/
8 =;&&1$%
9/
M
PHCO
/
9
Q 8 $2/01$%
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PN+
7
Q 8
%%2M
PCO
/
29
Q
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/
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Cu 5: (5 i ! $%%
%
C h ng s cEn # ng c + ph n ng
N
2
O
0



2NO
2

(-hB" (-hB"
. 01 TBnh thnh ph n ph n t'I* s *(. c + h n h p -hi 5p s, t ch,ng c + h . n . t $
. 2+t* : 2% +t*1
T ) hTy 'Dt '+ - t ., n : nh h ng c + 5p s, t ) n s ch,y n F ch cEn ! %
# ng1
C"#$ %i i K & 'u (i
Up s, t ch,ng c + h . 2+t*
R
N2O0
7 R
NO2
8 2
R
2
NO2
: R
N2O0
8 0 8O R
N2O0
8
0
2
2
NO P
R
NO2
8 $0&0
R
N2O0
8 %</&
V s *(. NO
2
8 ;/2V
Vs *(. N
2
O
0
8 2&=V
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R
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7 R
NO2
8 2%
R
2
NO2
: R
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8
0
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2
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R
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8 ;$&<
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8 $2=/<
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2
8 /<=/V
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2
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0
8 &0$;V
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2
gi * t
;/2V @, ng cWn /<=/V 8O CEn # ng ch,y n F ch th!( %
chi , ngh ch1
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Cu 6: (5 i ! Ng i t+ c th )i , ch N+OH # ng 2 ph ng ph5p -h5c nh+, t N+ %
H
2
: O
2
1 T'Knh #y 2 c5ch )i , ch ) : tBnh hi2, ng nhi t * i c5ch1 $ Bi t:
N+ ('" 7 $A2O
2
(-" X $A2N+
2
O
2
('" YH
$
8 9&%/ ?c+.
H
2
(-" 7 $A2O
2
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2
O (." YH
2
8 9&=/ ?c+.
$A2N+
2
O
2
('" 7 $A2H
2
O (." X N+OH ('" 7 $A0O
2
(-" YH
/

8 9;& ?c+.
N+ ('" 7 H
2
O (." X N+OH ('" 7 $A2H
2
(-" YH
0

8 9//;< ?c+.
C"#$ %i i K & 'u (i
C5ch $:
N+(! 7 $A2O
2
(k! $A2N+
2
O
2
(! H
$
89&%/ -c+.
H
2
(k! 7 $A2O
2
(k! H
2
O(l! H
2
89&=/ -c+.
$A2N+
2
O
2
7 $A2H
2
O(l! N+OH(! 7 $A0O
2
(k!
H
/
8 9;&-c+.
T ng c ng: N+ (! 7 $A2O
2
(k! 7 $A2H
2
(k! N+OH(!
H 8 LL
ThK t+ c: H 8 9&%/ 9 &=/ 9;& 8 9$/&2 -c+.
C5ch 2:
H
2
(k! 7 $A2O
2
(k! H
2
O(l! H
$
8 9 &=/ -c+.
N+ (! 7 H
2
O(l! N+OH 7 $A2H
2
H
2
8 9//;<-c+.
T ng c ng: N+ (! 7 $A2H
2
(k!7$A2O
2
(k! N+OH (! H8LL
T+ c: H8 9&=/ 9 //;< 8 9$%2%<-c+.
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78i 9: (5 i !
HW+ t+n h(n t(n 200 g+* h n h p # t 4 g * Z! $ #
@
O
y
: C, # ng F,ng F ch
H
2
SO
0
) c nng (F " 1S+, -hi ph n ng h(n t(n th, ) c %<%0 .Bt -hB SO
2
( s n ph * &
-h F,y nh t" )i , -i n ch, n : F,ng F ch ch + && g+* h n h p *, i s,n[+t 1 & $
+" TK* cng th c c + Z!
@
O
y
1
#"TBnh ph n t'I* -h i . ng c + * i ch t t'(ng h n h p 41 $ $
CCH GI I K T ;< (I M
Rh ng t'Knh h+ h c:
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+ +@A2 ( /@92y"1+A2
C, 7 2H
2
SO
0
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7 SO
2
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2
O
# # #
T+ c :
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2%%@1+ 7 $&%1# 8 && (/"

+@ 8 %%2<
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# 8 %%$
+" T+ c @Ay 8 $ 8O cng th c Z!
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#"?h i . ng C,: &01%%$ 8 %&0 g+*
Rh n t'I* -h i . ng c + C, .: %&0 1 $%%A200 8 2&2/ V
Rh n t'I* -h i . ng c + Z!
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.: $%% S 2&2/ 8 ;/;; V
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