( )

( )
( ) ( ) ( )
( )
( )
( )
( )
( )
( )
( )
( )
2 2
2 2
2 2
2 2
2 2
2 2
2 2
2
2
2
2
2 2
1 1
2
2 2
2
2 2
1 1
2
2
2 2 2 2
1 1
2 2
2
2 2
1 1
2
1
sin
, , ,

+ =

=
+ =
+ =
+ =
+ + = =

h
h
h
h h
h
h
Ze
r r r
r r
R Ze Y R
r r r
r r
R Ze
r r r
r R r Y
R
R r r Y
r
R Ze
R r r r Y
r E
r R r Y
r Y RY ERY
r Y E
r Ze r Y Er
r E Y
Y

( )
( )
( )
( )
( )
( ) ( ) ( )
( )
( )
( )
2
2 2
2 2
2
2
2
2
2
2
2
2
1
sin
2
2
2
1
2
2
sin 1
sin
1
;
,
sin 1 sin
exp ; 0, 1, 2,

+ =
= +
+ + =
= +
=
+ + =
= = =
h
h
L
Y Y
R R
eff
r r
r
l l
Ze
eff
r
r
Y
Y Y l l Y
V R ER
V
Y
l l
k im m

Real Hydrogenic Wavefunctions

( ) ( )
( ) ( ) ( )
( ) ( )
( ) ( )
( ) ( )
( )
( )
( )
( ) ( )
3
2
0 0
3
2
0 0 0
5
2
0 0
5
2
0 0
5
2
0 0
3
2 2
2
2
0 0
0
5
2
0 0
1
1
2
4 2
1
2
4 2
1
2
4 2
1
2
4 2
1
3
81 3
2
81
1 exp
2 2 exp
2 exp cos
2 exp sin cos
2 exp sin sin
3 27 18 2 exp
3 6 exp
Z Zr
a a
Z Zr Zr
a a a
Z Zr
z
a a
Z Zr
x
a a
Z Zr
y
a a
Z Zr Z r
a a
a
Z Zr Zr
z
a a
s
s
p r
p r
p r
s
p r

=
=
=
=
=
= +
=
0
Zr
a

( )
( ) ( ) ( )
( ) ( ) ( )
( ) ( )( )
( ) ( )
( ) ( )
0
5
2
0 0 0
5
2
0 0 0
7
2
2
0 0
7
2
0 0
7
2
3
2
3
81
2
3
81
2 2
1
3
81 6
2
2
3
81
2
2
3
81
cos
3 6 exp sin cos
3 6 exp sin
3 exp 3cos 1
3 exp sin cos cos
3 ex
sin
p sin cos sin
a
Z Zr Zr
x
a a a
Z Zr Zr
y
a a a
Z Zr
a a
z
Z Zr
xz
a a
Z Zr
yz
a a
p r
p r
d r
d r
d r

=
=
=
=
=

Calculation of expectation values:

( )
( ) ( )
( )
( ) ( ) ( )
( ) ( )
1
2
0
3 3
0
0 0
0
3 3
0
0 0
2
!
0
2 3
0
4
3
3 4 2 4
0 0
2 2
0
5
2 4 2
4 2 4
0
2
0
sin 0 ;0 ;0 2
exp 0, 1
1, 0:
exp 3!
exp 4! 3
n
nl
n
n
b
a
r
a
a a
a
r
a
a a
d r dr d d r
x bx dx b n
r r d R r r dr
n l
r r dr a a
r r dr a
Most probabl
2
me


+

=
= > >
= =
= =

= = = =



= = =

h
L
L
L
( )

( ) ( )
0 0 0
2
2 2 2
0
:
0 exp 2 exp 0
dP r
r r
dr a a a
mp
e valueof r
r r
r a
= + =
=

Virial Theorem:
2
~ :
n
n
T V
V r
=