:

:
4/5-1/5
:

1116188

92/2/16:
92/2/23:

118


.
.
:
b cm
c .
P0 P .
.
T P
P0

.
:
A = - log T = log P
P0

.

:
A = abc

 a b
. .
.
mol/L b cm
. :
A = bc

l/cm.mol.
P, P0
.
.
.

. .
4

.


.

A = log P log Psolvent

P0
Psolute

P0 P
.

. b
.
.
.
.
.
.
.
.
.

.

 .
.
0.01M
.
.
n
. 0.01M
.
:
5 55 05
055 5 0
25 05 5 2 .
0 5
5 .
455 555
.
.

:
505 .
0.7

0.6
0.5

y = 5.2970x - 5.530
R = 5.9986

0.4

0.2
0.1
0
2.5

1.5
)C(ppm

0.5

-0.1

0.3