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vn
71 BI TRC NGHIM AMINOAXITPEPTITPROTEIN
Cu 1! chng minh tnh lng tnh ca H
2
NCH
2
COOH (X) , ta cho X tc dng !i
"# HCl, NaOH# $# Na
2
CO
%
, HCl# C# HNO
%
, CH
%
COOH# &# NaOH, NH
%
#
Cu " ! "minoa'it n(o )a* +,- c. hai nh.m amino#
"# "'it /l*tamic# $# 0-)in# C# "lanin# &# 1alin#
Cu # ! C. 2ao nhi3* t3n g4i 5h6 h75 !i c8ng thc c9* t:o;
(<)# H
2
NCH
2
COOH ; "'it amino a'=tic#
(2)# H
2
N>CH
2
?
@
COOH ; a'it amino ca5Aoic#
(%)# H
2
N>CH
2
?
B
COOH ; a'it amino =nantoic#
(C)# HOOC>CH
2
?
2
CH(NH
2
)COOH ; "'it amino gl*taAic#
(@)# H
2
N>CH
2
?
C
CH (NH
2
)COOH ; "'it , +iamino ca5Aoic#
"# 2 $# % C# C &#@
Cu $ ! Cho cc nhDn +Enh )a*;
(<)# "lanin l(m F*G tm h.a 'anh#
(2)# "'it /l*tamic l(m F*G tm h.a +H#
(%)# 0-)in l(m F*G tm h.a 'anh#
(C)# "'it amino ca5Aoic l( ng*-3n liI* + )Jn '*9t nilon B#
KL nhDn +Enh +Mng l(;
"# < $# 2 C#% &#C
Cu %! Cho cc c,* )a* +,-;
(<)# Nhi cho a'it gl*tamic tc dng !i NaOH d thO t:o )Jn 5hPm l( 2Qt ng4t, mO chnh#
(2)# Rh,n tS cc amino a'it chT c. mQt nh.m NH
2
( mQt nh.m COOH#
(%)# &*ng dEch ca cc amino a'it +U* c. VhJ nWng l(m F*G tm ch*-n m(*#
(C)# Cc mino a'it +U* l( ch9t AXn Y nhiIt +Q thZng#
(@)# Nhi cho amino a'it tc dng !i h[n h75 NaNO
2
( CH
%
COOH Vh thot Aa l( N
2
#
KL nhDn +Enh +Mng l(;
"# < $# 2 C# % &#C
Cu &!; < th*Lc thS c. th nhDn 2i\t % ch9t h]* c^ ; a'it aminoa'=tic, a'it 5Ao5ionic, =t-lamin l(
"# NaOH# $# HCl# C# _*O tm# &# CH
%
OH`HCl#
Cu 7! $AadiVinin c. tc dng l(m giJm h*-\t 5, +. l( mQt nona5=5tit c. c8ng thc l( ;
"Ag RAo RAo /l-Rh=K=ARAoRh="Ag#
Nhi th- 5h,n Vh8ng ho(n to(n 5=5tit n(- c. th th* +7c 2ao nhi3* tAi 5=5tit m( th(nh 5han c. cha 5h=n-l
alanin ( 5h=)#
"#% $#C C#@ &#B
Cu '! Cho cc c8ng thc )a*; KL CbCb ng !i t3n g4i +Mng
(<)# H
2
N CH
2
COOH ; /l-'in
(2)# CH
%
CHNH
2
COOH ; "lanin#
(%)# HOOC CH
2
CH
2
CH(NH
2
)COOH ; "'it /l*tamic#
(C)# H
2
N (CH
2
)
C
CH(NH
2
)COOH ; 0icin#
"# < $#2 C#% &#C
Cu (! "mino a'it c. 2ao nhi3* 5hJn ng cho )a* +,- ; 5hJn ng !i a'it, 5hJn ng !i 2ac^, 5hJn ng tAng
2:c, 5hJn ng tA6ng h75, 5hJn ng tA6ng ngng, 5hJn ng !i ancol, 5hJn ng !i Vim lo:i ViUm#
"# % $#C C#@ &#B
Cu 1)! "lanin c. th 5hJn ng +7c !i 2ao nhi3* ch9t tAong cc ch9t cho )a* +,-;
$a(OH)
2
d CH
%
OH d H
2
NCH
2
COOHd HCl, C*, CH
%
NH
2
, C
2
H
@
OH, Na
2
KO
C
, H
2
KO
C
#
"# C $#@ C#B &#e
Cu 11! bh*Lc thS thch h75 + nhDn 2i\t % d*ng dEch )a* +,-; "'it fomic, /l-'in,
a'it , diamino2*t-Aic#
"# "gNO
%
`NH
%
$# C*(OH)
2
C# Na
2
CO
%
&# _*G tm#
Cu 1"! C. C d*ng dEch logng Vh8ng m(* +hng tAong 2Ln Lng nghiIm Ai3ng 2iIt, Vh8ng dn nhgn; "2*min,
/li'=Aol, CH
%
COOH, NaOH# Ch4n mQt tAong cc th*Qc thS )a* + 5h,n 2iIt C ch9t tA3n;
"# _*G tm $# Rh=nol 5htal=in# C# HNO
%
+ic# &# C*KO
C
#
Cu 1#! < mol

aminoa'it X tc dng a h\t !i < mol HCl t:o Aa m*Li j c. h(m l7ng clo l( 2k,2kel#
CbCb ca X l(
"# CH
%
CH(NH
2
) COOH# $# H
2
N CH
2
CH
2
COOH#
C# H
2
N CH
2
COOH# &# H
2
N CH
2
CH(NH
2
) COOH#
Cu 1$! Nhi tA6ng ngng m g a'it aminoca5Aoic !i hiI* )*9t kml, ngo(i aminoa'it cnn d ngZi ta th*
+7c 5 gam 5olim= ( <,CCg n!c# /i tAE m l(
"# <m,Ckg# $# o,mCg# C# <<,m2g# &# <%,<g#
Cu 1%! p)t= X +7c +iU* ch\ tq aminoa'it " ( ancol =t-lic# 2,mB gam X h.a h^i ho(n to(n chi\m th tch
2rng th tch ca m,@B gam N
2
Y c6ng +iU* ViIn nhiIt +Q, 5 )*9t # N\* cho 2,mB gam X tc dng qa + !i
d*ng dEch NaOH )s th* +7c d*ng dEch cha 2ao nhi3* gam m*Lit
"#2,2 gam $# <,oC gam C# 2,Ck gam &# m,oB gam
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Cu 1& ! uQt h75 ch9t X c. c8ng thc 5h,n tS C
%
H
e
O
2
N# X khng 5hJn ng !i d*ng dEch 2Aom, khng tham
gia 5hJn ng tA6ng ngng# X c. c8ng thc c9* t:o n(o )a* +,-t
"# H
2
NCH
2
CH
2
COOH $# CH
2
vCHCOONH
C
C# H
2
NCH(CH
%
)COOH&# CH
%
CH
2
CH
2
NO
2
Cu 17 ! C. F* tAOnh ch*-n ho )a*;
C
B
H
<2
O
%
N
2

j +
X
w +
C
%
H
B
NO
2
N
X, j, w l( nh]ng ch9t n(o )a* +,-t
"#

amino 2*tanoic, NaOH, HCl# (<) $# CJ (<), (2), (%) +U* )ai#
C#

amino a'=tic, NOH, HCl# (%) &#

amino 5Ao5anoic, HCl, NOH# (2)

Cu 1'! Lt ch9- h\t a mol amino a'it X +7c 2a mol CO
2
( a`2 mol N
2
# "minoa'it tA3n c. c8ng thc c9* t:o
l(;
"# H
2
NCH
2
COOH $# H
2
NCH
2
CH
2
COOH C# H
2
NCH
2
CH
2
CH
2
COOH &# H
2
NCH(COOH)
2
Cu 1(! Lt ch- ho(n to(n <e,C gam amino a'it X (a'it +^n chc) thO th* +7c m,B mol CO
2d
m,@ mol H
2
O (
m,< mol N
2
# X c. c8ng thc c9* t:o l(;
"# H
2
NCH
2
CH
2
COOH hoic CH
%
CH(NH
2
)COOH
$# H
2
NCH v CHCOOH hoic CH
2
v C(NH
2
)COOH
C# H
2
NCH
2
COOH
&# H
2
NCH
2
CH(NH
2
)COOH#
Cu ")! uQt h75 ch9t h]* c^ X m:ch thxng c. C8ng thc 5h,n tS l( C
%
H
<m
O
2
N
2
# X tc dng !i d*ng dEch
ViUm t:o ch9t Vh l(m F*G tm Pm ho 'anh, mit Vhc X tc dng !i d*ng dEch a'it t:o th(nh m*Li amin 2Dc
mQt# X c. C8ng thc 5h,n tS n(o )a* +,-t
"# H
2
NCH
2
CH
2
COONH
C
$# CH
%
CH(NH
2
)COONH
C

C# CH
%
CH
2
CH(NH
2
)COONH
C
# &# " ( $ +Mng
Cu "1! nhDn 2i\t cc ch9t lHng da* hoJ, da* my, gi9m Wn ( lnng tAXng tAng ta c. th ti\n h(nh th=o th th
n(o )a* +,-;
"# &6ng F*G tm, d6ng (i gi4t HNO
%
+ic, d6ng d*ng dEch NaOH#
$# &6ng d*ng dEch Na
2
CO
%
, d6ng d*ng dEch HCl, d6ng d*ng dEch NaOH#
C# &6ng d*ng dEch Na
2
CO
%
, d6ng d*ng dEch iot, d6ng C*(OH)
2
#
&# &6ng 5h=nol5htal=in, d6ng HNO
%
+ic, d6ng H
2
KO
C
+ic#
Cu ""! Cc amino a'it no c. th 5hJn ng !i t9t cJ cc ch9t tAong nh.m n(o )a* +,-;
"# &*ng dEch NaOH, d*ng dEch HCl, C
2
H
@
OH, C
2
H
@
COOH#
$# &*ng dEch NaOH, d*ng dEch HCl, CH
%
OH, d*ng dEch 2Aom#
C# &*ng dEch H
2
KO
C
, d*ng dEch HNO
%
, CH
%
OC
2
H
@
, d*ng dEch th*Lc tm#
&# &*ng dEch Na
2
KO
C
, d*ng dEch HNO
%
, CH
%
OH, d*ng dEch 2Aom#
Cu "#! *n n.ng <mmml d*ng dEch mQt aminoa'it m,2 u tc dng qa + !i kmml d*ng dEch NaOH m,2@u#
Ka* 5hJn ng ngZi ta c8 c:n d*ng dEch th* +7c 2,@ g m*Li Vhan# uit Vhc, l9- <mmg d*ng dEch aminoa'it
tA3n c. nzng +Q 2m,B l 5hJn ng qa + !i Cmmml d*ng dEch HCl m,@ u# C8ng thc 5h,n tS ca aminoa'it l(;
"# H
2
NCH
2
COOH $# CH
%
CH(NH
2
)COOH
C# CH
%
CH
2
CH(NH
2
)COOH# &# CH
%
COONH
C

Cu "$! Nhi +Lt ch- ho(n to(n mQt +zng +xng ca gli'in th* +7c
2 2
; e ; B
H O CO
n n =
(5hJn ng ch- )inh Aa Vh
N
2
)# X c. c8ng thc c9* t:o l(;
"# H
2
NCH
2
COOH $# CH
%
CH(NH
2
)COOH C# NH
2
CH
2
CH
2
COOH# &# $ ( C +Mng#
Cu "% ! bT lI th tch CO
2
; H
2
O (h^i) )inh Aa Vhi +Lt ch- ho(n to(n mQt +zng +xng (X) ca gli'in l( B;e (5hJn
ng ch- )inh Aa Vh N
2
)# (X) tc dng !i gli'in cho )Jn 5hPm l( mQt +i5=5tit (X) l(;
"# H
2
N CH
2
CH
2
COOH (<) $# C
2
H
@
CH(NH
2
) COOH (%)
C# CH
%
CH(NH
2
) COOH(2) &# (<) ( (2) +Mng
Cu "& ! Cho cc ch9t; <) NatAi gl*tamat, 2) /li'in hi+AocloA*a, %) 0icin, C) NatAi alanat, @) "'it a)5actic, B)
inatAi gl*tamat ( e) "lanin# Ch9t 5hJn ng +7c !i NOH l(;
"# <, 2, %, @ ( e# $# Nh8ng c. ch9t n(o# C# 2, %, C, @, ( B# &# <, %, C, @, B ( e#
Cu "7!;H[n h75 X gzm hai aminoa'it m:ch hY no +^n chc +zng +xng V\ ti\5 c. 5han tAWm VhLi l7ng o'i
l( %e,C2el# Cho m gam X tc dng !i Bmmml d*ng dEch NOH <u (d) )a* Vhi 5hJn ng V\t thMc c8 c:n d*ng
dEch th* +7c Bm,Bgam ch9t AXn Vhan# m c. gi tAE l(
"# %C,2 gam $#%k,B@ gam C# 2B,e gam &# %e,k gam
Cu "' ! Vhi th- 5h,n cc 5=nta5=5tit d!i +,- ;
(<) ; "la/li"la/l*1al (2) ; /l*/li1al"la/l*
(%) ; "la/li1al1al/l* (C) ; /li/li1al"la"la
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5=nta5=5tit n(o d!i +,- c. th t:o Aa +i5=5tit c. VhLi l7ng 5h,n tS 2rng <kkt
"# (<), (%) $# (2),(%) C# (<),(C) &# (2),(C)
Cu "( ! tAi5=5tit X t:o th(nh tq % amino a'it no +^n chc m:ch hY ( c. 5h,n tS VhLi nhH nh9t# bh- 5h,n
@@,CC gam X 2rng 2mm ml d*ng dEch NaOH C,ku +*n n.ng, )a* +. c8 c:n d*ng dEch th* +7c 2ao nhi3* gam
ch9t AXn Vhant
"# ko,@2m gam $# o2,moB gam C# o%,B<k gam &# e%,<C gam
Cu #) ! H[n h75 u gzm hai amino a'it X ( j +U* cha < nh.mCOOH ( < nh.m NH
2
(tT lI mol n
X
;n
j
v
%;2)# Cho <e,2C gam u tc dng h\t !i <<m ml d*ng dEch HCl 2u +7c d*ng dEch w# tc dng h\t !i cc
ch9t tAong w can 2<m ml d*ng dEch NOH 2u# C8ng thc c9* t:o ca X ( j l( ;
"# H
2
NC
2
H
C
COOH, H
2
NC
%
H
B
COOH $# H
2
NCH
2
COOH, H
2
NC
2
H
C
COOH
C# H
2
NCH
2
COOH, H
2
NC
%
H
B
COOH &# H
2
NCH
2
COOH, H
2
NC
C
H
k
COOH
Cu #1 ! Cho < +i5=5tit 5hJn ng !i NaOH +ic +*n n.ng#
H
2
NCH
2
CONHCH
2
COOH { 2NaOH j{ H
2
O # j l( h75 ch9t h]* c^ gOt
"# NatAi aminoa'=tat $# NatAi a'=tat C# u=t-lamin &# "moniac
Cu #" ! Cho m,m<2 mol aminoa'it X 5hJn ng qa + !i HCl t:o Aa <,@mB g m*Li j# C8ng thc c9* t:o ca X
l(;
"# H
2
NCH
2
COOH# $# H
2
NCH
2
CH(NH
2
)COOH#
C# H
2
NCH
2
CH
2
COOH# &# HOOCCH
2
CH
2
CH(NH
2
)COOH#
Cu ## ! *n n.ng ch9t H
2
NCH
2
CONHCH(CH
%
)CONHCH
2
COOH tAong d*ng dEch NaOH (d), )a*
Vhi cc 5hJn ng V\t thMc th* +7c )Jn 5hPm l(;
"# H
2
NCH
2
COOH, H
2
NCH(CH
%
)COOH# $# H
2
NCH
2
COOH, H
2
NCH
2
CH
2
COOH#
C# H
2
NCH
2
COONa, H
2
NCH(CH
%
)COONa &# H
2
NCH
2
COONa, H
2
NCH
2
CH
2
COONa
Cu #$ ! tA*ng ho( 2mm ml d*ng dEch aminoa'it u m,@u can <mm gam d*ng dEch NamH kl, c8 c:n d*ng
dEch )a* 5hJn ng +7c <B,% gam m*Li Vhan# u c. c8ng thc c9* t:o;
"# H
2
NCH
2
COOH $# H
2
NCH(COOH)
2
C# H
2
NCH
2
CH(COOH)
2
&# (H
2
N)
2
CHCOOH
Cu #% ! Cho cc d*ng dEch Ai3ng 2iIt )a* ; ClH
%
NCH
2
CH
2
NH
%
Cl, C
B
H
@
ONa, CH
%
COOH, NaOOCCH
2

CH
2
CH(NH
2
)COONa, H
2
NCH
2
CH
2
CH(NH
2
)COOH, H
2
NCH
2
COONa, Na
2
CO
%
, NaOOCCOONa,
NNO
2
# KL l7ng cc d*ng dEch c. 5H|e l( ;
"#@ $# B C# e &#k
Cu #& ! Cho <ml an2*min (lnng tAXng tAng) (o mQt Lng nghiIm, th3m (o +. m,@ml HNO
%
+ic# HiIn t7ng
F*an )t +7c l(;
"# d*ng dEch ch*-n tq Vh8ng m(* th(nh m(* (ng#
$# d*ng dEch ch*-n tq Vh8ng m(* th(nh m(* da cam#
C# d*ng dEch ch*-n tq Vh8ng m(* th(nh m(* 'anh tm#
&# d*ng dEch ch*-n tq Vh8ng m(* th(nh m(* +=n#
Cu #7 ! H75 ch9t h]* c^ " c. u v ko cha C, H, O, N# H75 ch9t " qa tc dng !i NaOH, qa tc dng !i
HCl, c. tham gia 5hJn ng tA6ng ngng# " c. tAong th nhi3n# C8ng thc c9* t:o th* g4n ca " l(;
"# H
2
NCH
2
CH
2
COOH $# CH
%
CH(NH
2
)COOH
C# C
%
H
e
NHCOOH &# HCOO H
%
NCH
%

Cu #' ! H75 ch9t h]* c^ X c. c8ng thc t}ng F*t C
'
H
-
O
c
N
t
c. l N v <@,e%m%l d
lO v %@,o@@<l# $i\t X tc dng HCl t:o m*Li c. d:ng ~(O
c
) NH
%
Cl# $i\t X c. tnh lng tnh ( tham gia
5hJn ng tA6ng ngng# 1D- CbCb ca X l(;
"# H
2
N(CH
2
)
2
COOH d CH
%
CH(NH
2
)COOH
$# H
2
N (CH
2
)
%
COOH d CH
%
CH
2
CH(NH)
2
COOH
C# H
2
N CH v CH COOH d CH
2
v C(NH
2
) COOH
&# b9t cJ +U* )ai
Cu #( ! uQt h[n h75 (X) gzm 2 aminoa'it c. c6ng )L mol# 09- m gam (X) cho 5hJn ng !i H
2
KO
C
thO th*
+7c 2 m*Li c. VhLi l7ng 2rng m { o,kg# uit Vhc, l9- c6ng VhLi l7ng m gam (X) 5hJn ng !i NaOH t:o
Aa 2 m*Li c. t}ng VhLi l7ng 2rng m { %,%g# Xc +Enh )L mol ca m[i aminoa'it# Hai aminoa'it n(- th*Qc lo:i
aminoa'it tA*ng tnh, 2ac^ ha- a'itt
"# m#m@mol# mQt aminoa'it tA*ng tnh, m#m@ mol aminoa'it l( a'it
$# m#2mol# mQt aminoa'it tA*ng tnh, m,2 mol aminoa'it l( a'it
C# m#<mol cJ hai l( aminoa'it tA*ng tnh
&# m#2mol# mQt aminoa'it 2ac^, mQt aminoa'it l( a'it
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Cu $) ! bh- 5h,n e%,k gam mQt 5=5tit chT th* +7c om gam gli'in (a'it aminoa'=tic)# R=5tit 2an +a* l( ;
"# &i5=5tit $# bAi5=5tit C# b=tAa5=5tit &# R=nta5=5tit
Cu $1 ! uQt 5oli 5=5tit +7c t:o Aa tq gl-'in ( alanin c. 5h,n tS VhLi @ke +C# HHi c. 2ao nhi3* mXt 'ch
t:o Aa tq gl-'in ( alanin tAong ch*[i 5=5tit tA3nt
"# @ ( C $# 2 ( B C# C ( @ &# C ( C
Cu $" ! Lt ch- ho(n to(n C@,< gam h[n h75 X gzm CH
%
CH(NH
2
)COOH ( CH
%
COONH
%
CH
%
th* +7c
CO
2
, H
2
O ( N
2
c. t}ng VhLi l7ng l( <mo,o gam# Rhan tAWm VhLi l7ng m[i ch9t tAong h[n h75 X lan l7t l( ;
(Cv<2d Hv<d Ov<Bd Nv<C)
"# @o,2ml ( Cm,kml $# Co,%%l ( @m,Bel C# %o,Cel ( Bm,@%l &# %@,@2l ( BC,Ckl
Cu $# ! Cho <2,@@ gam m*Li CH
%
CH(NH
%
Cl)COOH tc dng !i <@m ml d*ng dEch $a(OH)
2
<u# C8 c:n
d*ng dEch )a* 5hJn ng th* +7c m gam ch9t AXn# /i tAE ca m l( ;
"# <@,B@ $# 2B,m@ C# %C,B &# %@,@
Cu $$ ! bh- 5h,n ho(n to(n <C,Bg mQt +i5=5tit thi3n nhi3n X 2rng d*ng dEch NaOH, th* +7c )Jn 5hPm
tAong +. c. <<,<g mQt m*Li cha 2m,e2l Na U VhLi l7ng# C8ng thc ca X l( ;
"# H
2
N CH
2
CO NH CH
2
COOH#
$# H
2
N CH(CH
%
) CO NH CH(CH
%
) COOH#
C# H
2
N CH(CH
%
) CO NH CH
2
COOH
hoic H
2
N CH
2
CO NH CH(CH
%
) COOH#
&# H
2
N CH(C
2
H
@
) CO NH CH
2
COOH
hoic H
2
N CH
2
CO NH CH(C
2
H
@
) COOH#
Cu $% ! Nhi th* 5h,n mQt ch9t 5Aot=in (") ta th* +7c mQt h[n h75 % amino a'it V\ ti\5 tAong dg- +zng
+xng# u[i amino a'it cha mQt nh.m amino, mQt nh.m cac2o'-l# N\* +Lt ch- m,2 mol h[n h75 % amino a'it
tA3n Azi cho )Jn 5hPm ch- F*a 2Onh +hng d*ng dEch NaOH +ic, VhLi l7ng 2Onh tWng %2,k g, 2i\t Arng )Jn
5hPm ch- c. Vh N
2
# Cc amino a'it +. l(;
"#CH
@
O
2
N, C
2
H
@
O
2
N, C
2
H
e
O
2
N $#CH
%
O
2
N, C
2
H
@
O
2
N, C
%
H
e
O
2
N
C#C
2
H
@
O
2
N, C
%
H
e
O
2
N, C
C
H
o
O
2
N &#C
2
H
e
O
2
N, C
%
H
o
O
2
N, C
C
H
<<
O
2
N
Cu $& ! (X) l( h75 ch9t h]* c^ c. c8ng thc 5h,n tS C
@
H
<<
O
2
N# *n X !i dd NaOH th* +7c mQt h[n h75
ch9t c. c8ng thc 5h,n tS C
2
H
C
O
2
NNa ( ch9t h]* c^ (j), cho h^i (j) F*a C*O`t
m
th* +7c ch9t h]* c^ (w) c.
VhJ nWng tham gia 5hJn ng tAng g^ng# C8ng thc c9* t:o ca (X) l(;
"#CH
%
(CH
2
)
C
NO
2
$# H
2
N CH
2
COO CH
2
CH
2
CH
%
C# H
2
N CH
2
COO CH(CH
%
)
2
&#H
2
N CH
2
CH
2
COOC
2
H
@
Cu $7 ! X l( < amino a'it chT c. < nh.m amino NH
2
( < nh.m cac2o'-l COOH# Cho BB,e@ gam X 5hJn
ng qa + !i HCl t:o Aa oC,<2@ gam m*Li# 1D- c8ng thc c9* t:o ca X l( ;
"# H
2
NCH
2
COOH $# H
2
NCHvCHCOOH
C# H
2
NCH(CH
%
)COOH &# CH
%
CH(NH
2
)CH
2
COOH
Cu $' ! X l( mQt aminoa'it no chT cha < nh.m NH
2
( < nh.m COOH# Cho <@,< gam X tc dng !i
HCl d th* +7c <k,e@ gam m*Li# C8ng thc c9* t:o ca X l(; (Cv<2d Hv<d Ov<Bd Nv<C)
"# H
2
N CH
2
COOH $# CH
%
CH(NH
2
) COOH
C# C
B
H
@
CH(NH
2
) COOH &# C
%
H
e
CH(NH
2
) COOH
Cu $( ! X c. c8ng thc 5h,n tS l( C
C
H
<2
O
2
N
2
# Cho m,< mol X tc dng !i <%@ ml d*ng dEch NaOH <u# C8
c:n d*ng dEch )a* 5hJn ng th* +7c <<,< gam ch9t AXn# X l(;
"# H
2
NC
%
H
B
COONH
C
$# H
2
NCH
2
COONH
%
CH
2
CH
%
C# H
2
NC
2
H
C
COONH
%
CH
%
&# (H
2
N)
2
C
%
H
e
COOH
Cu %) ! Nhi th- 5h,n < 5Aotit X th* +7c h[n h75 gzm 2 amino a'it no V\ ti\5 nha* tAong dg- +zng +xng#
$i\t m[i ch9t +U* cha < nh.m NH
2
( < nh.m COOH# Lt ch- ho(n to(n m,2 mol h[n h75 2 aminoa'it Azi
cho )Jn 5hPm ch- F*a 2Onh +hng d*ng dEch NaOH d , th9- VhLi l7ng 2Onh tWng %2,k gam# C8ng thc c9* t:o
ca 2 aminoa'it l( ;
"#H
2
NCH(CH
%
)COOH ( C
2
H
@
CH(NH
2
)COOH $# H
2
NCH
2
COOH ( H
2
NCH(CH
%
)COOH
C# H
2
NCH(CH
%
)COOH ( N
2
N>CH
2
?
%
COOH &# H
2
NCH
2
COOH ( ( H
2
NCH
2
CH
2
COOH
Cu %1 ! X l( mQt tAi5=5tit c9* th(nh tq cc aminoa'it thi\t -\* ", $ ( C (+U* c. c9* t:o m:ch thxng)# N\t F*J
5h,n tch cc aminoa'it ", $ ( C n(- cho V\t F*J nh )a*;
Ch9t lm
C
lm
H
lm
O
lm
N
u
" %2,mm B,Be C2,BB <k,Be e@
$ Cm,C@ e,ke %@,o@ <@,e% ko
C Cm,k2 B,<2 C%,@% o,@2 <Ce
Chuynhahu.vn
Nhi th- 5h,n Vh8ng ho(n to(n X, ngZi ta th* +7c hai 5h,n tS +i5=5tit l( "C ( C$# 1D- c9* t:o ca X l(;
"# /l-/l*"la $# /l-0-)1al C# 0-)1al/l- &# /l*"la/l-
Cu %" ! H[n h75 " gzm 2 amino a'it no m:ch hY +zng +xng V\ ti\5 , c. cha < nh.m amino ( < nh.m chc
a'it tAong 5h,n tS# 09- 2%,o gam h[n h75 " cho tc dng !i <mm ml d*ng dEch HCl %,@u (c. d)# tc dng
h\t cc ch9t tAong d*ng dEch & can d6ng B@m ml d*ng dEch NaOH <u# C8ng thc hai ch9t tAong h[n h75 " l( ;
"# CH
%
CH(NH
2
)COOH, CH
%
CH
2
CH(NH
2
)COOH
$# CH
%
CH
2
CH(NH
2
)COOH, CH
%
CH
2
CH
2
CH(NH
2
)COOH
C# H
2
NCH
2
COOH, CH
%
CH(NH
2
)COOH
&# CH
%
CH
2
CH
2
CH(NH
2
)COOH, CH
%
CH
2
CH
2
CH
2
CH(NH
2
)COOH
Cu %# ! Cc ch9t tAong dg- n(o )a* +,- +U* c. tnh lng tnh;
"# H
2
NCH
2
COONa, ClH
%
NCH
2
COOH, NH
2
CH
2
COOH#
$# H
2
NCH
2
COOH, H
2
NCH
2
COONH
C
, CH
%
COONH
C
#
C# CH
%
COOCH
%
, H
2
NCH
2
COOCH
%
, ClH
%
NCH
2
CH
2
NH
%
Cl#
&# ClH
%
NCH
2
COOH, NH
2
CH
2
COOCH
%
, H
2
N CH
2
COONH
C
Cu %$ ! X,j,w l( % amino a'it no +^n chc m:ch hY#
Lt ch- X th* +7c h[n h75 )Jn 5hPm CO
2
, h^i H
2
O ( N
2
tAong +.
2 2
CO H O
1 ; 1 k; o =
#
u
j
v<,<@%eu
X
bAong w 5han tAWm VhLi l7ng C l( @C,oBl## R=5tit n(o d!i +,- c. 5h,n tS VhLi l(
2e%t
"#XXXj $# XwX C# XXj &#Xwj
Cu %% ! Ch9t h]* c^ X (cha C,H,O,N) c. 5h,n tS VhLi l( ko# X tc dng !i cJ HCl ( NaOH# Nhi cho m,<
mol X tc dng !i d*ng dEch NaOH d th* +7c o,C gam m*Li# X l( ;
"# "'it amino 5Ao5ionic $ "'it amino 5Ao5ionic# C# u=t-l aminoa'=tat &# amoni acA-lat
Cu %& ! X l( t=tAa5=5tit , j tAi5=5tit +U* t:o n3n tq < lo:i aminoa'it (w) c. < nh.m COOH ( < nh.m
NH
2
( u
X
v<,%<<Cu
j
# Cho m,<2 mol 5=nta5=5tit t:o th(nh tq w tc dng !i d*ng dEch NaOH qa + )a* +.
c8 c:n th* +7c 2ao nhi3* ch9t AXn Vhant
"# e@,m gam $# @k,2 gam C# BB,B gam &# k%,C gam
Cu %7 ! Cho )^ +z 2i\n h.a ;
X
H N O
2
Y
N a O H
Z
N a O H
C a O , t
0
T
X l( < aminoa'it m:ch thxng c. < nh.m NH
2
( < nh.m COOH, b l( < ancol ( l VhLi l7ng o'i tAong b l(
%C,ekl#u l( =)t= ca X ( b c. 5han tAWm VhLi l7ng o'i l( ;
"# %@,o@@l $# 2e,%@ml C# 22,mBol &# <k,Coel
Cu %' ! Cho m,m2 mol ch9t X (X l( mQt amino a'it) 5hJn ng qa h\t !i <Bm ml dd HCl m,<2@u thO t:o Aa
%,Be g m*Li# uit Vhc C,C< gam X Vhi 5hJn ng !i < l7ng NaOH qa + thO t:o Aa @,e%g m*Li Vhan# $i\t X
c. m:ch cac2on Vh8ng 5h,n nhnh# 1D- c8ng thc c9* t:o ca X l(;
"#HOOCCH(NH
2
)CH(NH
2
)COOH $#HOOCCH
2
CH
2
CH(NH
2
)COOH
C#CH
%
CH
2
CH(NH
2
)COOH &#CH
%
CH
2
CH
2
CH(NH
2
)COOH
Cu %( ! Nhi cho %,m g a'it aminoa'=tic tc dng h\t !i d*ng dEch HCOOH, VhLi l7ng m*Li t:o th(nh l( ;
"#%,kCg# $#%,kkg# C#C,kCg# &#C,eBg#
Cu &) ! H[n h75 " gzm hai aminoa'it no cha mQt chc amin, mQt cha a'it, li3n ti\5 nha* tAong dg- +zng
+xng# &6ng Vh8ng Vh d + +Lt ch- ho(n to(n %,2< g h[n h75 "# H[n h75 th* +7c )a* 5hJn ng +=m l(m
Vh8 +7c h[n h75 Vh $# Cho $ F*a d*ng dEch Ca(OH)
2
d th* +7c o,@ g V\t ta# Rhan tAWm )L mol cc amino
a'it tAong h[n h75 " lan l7t l( ;
"# @ml ( @ml $# B2,@l ( %e,@l C# Cml ( Bml &#2e,@l (
e2,@l
Cu &1 ; tc dng qa + !i 2o,oC gam h[n h75 X gzm < )L amino a'it (chT c. nh.m chc
COOH ( NH
2
, Vh8ng c. nh.m chc Vhc) can %km ml d*ng dEch NOH <u# uit Vhc +Lt ch- 2o,oC gam
h[n h75 X can 2C,@2k lt O
2
(+Vtc) th* +7c m gam CO
2
d 5 gam H
2
O ( %,%B lt N
2
(+Vtc)#
a)m c. gi tAE l( ; "#%o,Bm gam $# C2,2C gam C# @2,km gam &#%k,e2 gam
2)5 c. gi tAE l( ; "# <k,@C gam $# <k,e2 gam C# <o,CC gam &# 2m,<B gam
Cu &" H[n h75 X gzm < )L amino a'it no (chT c. nh.m chc COOH ( NH
2
, Vh8ng c. nh.m chc Vhc)
c. tT lI VhLi l7ng m
O
;m
N
vCk;<o# tc dng qa + !i %o,o gam h[n h75 X can %km ml d*ng dEch HCl <u#
uit Vhc +Lt ch- %o,o gam h[n h75 X can C<,eeB lt O
2
(+Vtc) th* +7c m gam CO
2
# m c. gi tAE l( ;
Chuynhahu.vn
"# BB gam $# @o,kC gam C# B<,Bm gam &# B%,%B gam
Cu &# ! X ( j l( 2 t=tAa5=5tit, Vhi th- 5h,n tAong m8i tAZng a'it +U* th* +7c 2 lo:i amino a'it no +^n
chc m:ch hY l( " ( $# Rhan tAWm VhLi l7ng o'i tAong X l( 2%,2@Bl ( tAong j l( 2C,2Cl#
" ( $ lan l7t l( ;
"# alanin ( alin $# gli'in ( alanin C# gli'in ( a'it amino2*tiAic &# alanin ( a'it
amino2*tiAic
Cu &$ ! X ( j lan l7t l( tAi5=5tit ( t=tAa5=5tit t:o th(nh tq < lo:i aminoa'it no m:ch hY c. < nh.m NH
2
(
< nh.m COOH# Lt ch- m,< mol j th* +7c CO
2
, H
2
O ( N
2
tAong +. t}ng VhLi l7ng CO
2
( H
2
O l( Ce,k
gam# N\* +Lt m,< mol X can 2ao nhi3* mol O
2
t
"# m,@Bm mol $# m,koB mol C# m,Be@ mol &# m,%e@ mol
Cu &% ! X l( h='a5=5tit "la/li"la1al/li1al# j l( t=tAa5=5tit /li"la/li/l*
bh- 5h,n m gam h[n h75 gLm X ( j tAong m8i tAZng a'it th* +7c C lo:i aminoa'it tAong +. c. %m gam
gli'in ( 2k,Ck gam alanin# m c. gi tAE l( ;
"# ke,C gam $# e%,C gam C# ee,B gam &# k%,2 gam
Cu && ! " l( mQt aminoa'it# Cho 2i\t < mol " 5hJn ng qa + !i < mol HCl, h(m l7ng clo tAong m*Li
th* +7c l( <o,%CBl# C8ng thc ca " l( ;
"# HOOCCH
2
CH
2
CH(NH
2
)COOH $# CH
%
CH
2
CH(NH
2
)COOH
C# HOOCCH
2
CH
2
CH
2
CH(NH
2
)COOH $# CH
%
CH(NH
2
)COOH
Cu &7 ! Ch9t h]* c^ " c. < nh.m amino ( < chc =)t=# H(m l7ng nit^ tAong " l( <@,e%l#X( 5hnng h.a m
gam ch9t ", h^i ancol 2a- Aa cho +i F*a C*O n*ng n.ng +7c an+=hit $# Cho $ thhc hiIn 5hJn ng tAng 2:c
th9- c. <B,2 gam "g V\t ta# /i tAE ca m l( ;
"# e,e2@ gam $# %,%e@ gam C.B,Be@ gam &# @,B2@ gam
Cu &' ! X l( < 5=nta5=5tit c9* t:o tq < amino a'it no m:ch hY c. < nh.m COOH ( < nh.m NH
2
("), " c.
t}ng 5han tAWm VhLi l7ng o'i ( nit^ l( @<,Bk@l# Nhi th- 5h,n h\t m gam X tAong m8i tAZng a'it th* +7c
%m,2 gam t=tAa5=5titd %m,m% gam tAi5=5titd 2@,B gam +i5=5tit ( kk,<< gam "# m c. gi tAE l( ;
"# <Co,2 gam $# <Be,k@ gam C# <@B,BB gam &# <C<,eC gam
Cu &( ! bh- 5h,n h\t < l7ng 5=nta5=5tit tAong m8i tAZng a'it th* +7c %2,kk gam
"la/li"la/lid <m,k@ gam "la/li"lad <B,2C gam "la/li/lid 2B,2k gam "la/lid k,o gam "lanin cnn l:i
l( /li/li ( /li'in# bT lI )L mol /li/li;/li l( @;C# b}ng VhLi l7ng /li/li ( /li'in tAong h[n h75 )Jn
5hPm l( ;
"# C%,2 gam $# %2,C gam C# <o,CC gam &# 2k,k gam
Cu 7) ! uQt 5=5tit X t:o th(nh tq < aminoa'it no m:ch hY c. < nh.m COOH ( < nh.m NH
2
tAong +. 5han
tAWm VhLi l7ng o'i l( <o,%2Cl# X l( ;
"# +i5=5tit $# tAi5=5tit C# t=tAa5=5tit &# 5=nta5=5tit
Cu 71 ! Nhi th- 5h,n @mm gam mQt 5oli5=5tit th* +7c <em gam alanin# N\* 5oli5=5tit +. c. VhLi l7ng 5h,n
tS l( @mmmm thO c. 2ao nhi3* mXt 'ch ca alanint
"#<e@ $# <em C# <o< &#2<m
H\t