CHNG HALOGEN

Bi tp halogen
VD1: Cho kh Cl
2
tc tc dng va vi 0,15 mol kim loi M, thu c 20,025 gam mu!i" M
l#$
A. Mg B. %l C. &' D. Cu
VD2$ M(t dd c) 0,1 mol Cl2 v# 0,0* mol +,2"Cho v#o dd n#- *5g .a/"C0 cn dd 1au 23 thu
c ,4n c) kh!i lng l#
%"15,5*g +"16,7*g C"22,2*g 8"20,29g
VD3: :c 0,* mol Cl2 v#o dd c) ch3a 957g hh g;m .a+, v# .a/"<hi 23 =ong c0 cn dd thu
262,6g mu!i khan"Mu!i thu c g;m
%".aCl,.a+, +".aCl,.a/ C".aCl, 8"% v# C >u ?ng
VD$ Cho @ lt hAn h2 kh % g;m clo v# o=i tc dng va hBt vi hAn h2 + g;m 0,2 mol %l v#
0,1 mol MgthC thu c 25,2 gam hAn h2 mu!i clo,ua v# o=it ca 2 kim loi" :! mol ca Cl
2
c)
t,ong @ lt hAn h2 kh % l#
A" 0,15" B" 0,9" C " 0,2" D" 0,25"
VD5 Sc kh clo d vo dung dch cha mui NaBr v KBr thu c mui Nal v
Kl! "ng th#i th$% khi lng mui gi&m '!'5 gam( )ng clo * tham gia +h&n
ng v,i - mui tr.n l
/( 0!1 mol( B( 0!05 mol( ( 0!0- mol( D(
0!01 mol(
Bi tp !p "#ng
C$% 1" Cho 250g dung dDch +,
2
v#o 1 lt dung dDch ch3a 55,6g </" :au khi 2hEn 3ng kBt th?c
thu c *5,5g mu!i" Fc Dnh n;ng ( G ca dung dDch +,
2
"
%" 5,7 G" +" 10"7 G" C" 90"7G" 8" 76,7 G
C$% 2 B&2''(. Cho 19,** lt kh clo HI ktcJ i Kua 2,5 lt dung dDch <LM I 100
o
C" :au khi 2hEn
3ng =E- ,a ho#n to#n, thu c 9N,25 gam <Cl" 8ung dDch <LM t,On c) n;ng ( l# Hcho Cl P
95,5Q < P 95J
%" 0,2*M" +" 0,*6M" C" 0,*M" 8" 0,2M"
C$% 3 :c kh clo d v#o dung dDch ch3a cc mu!i .a+, v# .a/ Bn 2hEn 3ng ho#n to#n ta thu
c 1,1N gam .aCl" :! mol cua hAn h2 mu!i Ran Su l#$
%" 0,01 mol" +" 0,015 mol" C" 0,02 mol" 8" 0,025 mol"
C$% MTt RCnh cSu ch3a 250 g nc Clo U ngo#i nh 1ng mVt t,Wi cho Bn khi 2hEn 3ng =E-
,a ho#n to#n thC c) 0,112 l kh giEi 2h)ngHktcJ" CG ca nc Clo l#$
%" 0,26*G +" 0,62*G C" 0,*26G 8" 0,*62G"
C$% ) Cho 11,2 lt hAn h2 kh F HktcJ g;m Cl
2
v# L
2
tc dng va vi 17,56 gam hAn h2
X g;m Mg v# %l thu c *2,9*gam hAn h2 Y g;m MgCl
2
Q MgLQ %lCl
9
v# %l
2
L
9
"
ZhSn t,[m thU tch ca o=i t,ong F l#
%" 52" +" *6" C" 25" 8" N5"
C$% * :c kh clo d v#o dung dDch ch3a mu!i .a+, v# <+, thu c mu!i .aCl v# <Cl,
;ng thWi th\- kh!i lng mu!i giEm *,*5 gam" ]ng clo ^ tham gia 2hEn 3ng vi 2 mu!i t,On
l#
%" 0,1 mol" +" 0,05 mol" C" 0,02 mol" 8" 0,01 mol"
"C$% ( _!t m(t kim loi t,ong RCnh kn `ng kh clo, thu c 92,5g mu!i clo,ua v# nhan th\-
thU tch kh clo t,ong RCnh giEm 7,N2 lt HI ktcJ" M^- =c Dnh tOn ca kim loi ^ dbng"
%" _;ng +" Can=i C" .h0m 8" :4t
Bi tp h+p ,h-t halogen
VD1. _U tc dng hBt *,7* gam hAn h2 g;m &'L, &'
2
L
9
, &'
9
L
*
cSn dbng va 170 ml MCl
1M" .Bu khc ho#n to#n *,7* gam hAn h2 t,On cSn REo nhiOu @ lt CLd
A. 1,N52 B. 2,97 C. 2,06 D. *,97
VD2 C) 165,* gam dung dDch MCl 10G" CSn hea tan thOm Rao nhiOu lt kh MCl HI kcJ v#o
dung dDch n#- U thu c MCl c) n;ng ( l# 17,5NGd
A. 11,2 lt B. 5,7 lt C. 9,97 lt D. 6,57 lt
VD3 hea tan ho#n to#n 20 gam hAn h2 Mg, Yn v# &' Rfng dung dDch MCl d" :au 2hEn 3ng thu
c 11,2 lit kh HkcJ v# dung dDch F" C0 cn dung dDch F thC thu c Rao nhiOu gam mu!i
khan$
A. N1,0 gam B. 51,0 gam C. 50,0 gam D. 55,5 gam
VD 2o tan h3n h+ g"m 0!- mol /l4 0!- mol 56 v 0!- mol 56
7
8
'
9:ng dung
dch 2l d thu c dung dch /( ho / t;c dng v,i dung dch Na82 d! r"i
l$% k<t t=a nung trong kh>ng kh <n khi lng kh>ng ?i thu c m gam
ch$t r@n( Ai; tr c=a m l
/( B'!-( B( '-!-( ( C'!0( D( 1-D!0(
VD5E 2o tan hon ton 10!05 gam h3n h+ - mui cac9onat kim loFi ho; tr
GG v GGG vo dung dch 2l thu c dung dch / v 0!CB- lt kh HktcI( Khi
lng mui trong / l
/( 10!7Dgam( B( -0!CCgam( ( 70!JJgam( D( J!7-gam(
B./ 012 32 D4NG
C56 1: Cho m g dd MCl CG tc dng hBt vi m(t lng hh kim loi < v# Mg H dJ, th\- kh!i
lng kh thot ,a l# 0,05m g" gi t,D ca CG l#$
%"N9G +" 15G" C" 22G" 8" 2 n khc
C56 2: Cho hAn h2 g;m &' v# &': tc dng vi dung dDch MCl d thu c 2,2* lit hAn h2
kh I i>u kihn tiOu chuin" MAn h2 kh n#- c) tj kh!i 1o vi hi,o l# 5" kh#nh 2hSn G th'o 1!
mol ca hAn h2 &' v# &': Ran Su l#$
%" *0G v# 70G" +" 50G v# 50G" C" 95G v# 75G"
8" *5G v# 55G"
C$% 3 A&2''7. _U ho# tan ho#n to#n 2,92 gam hAn h2 g;m &'L, &'
9
L
*
v# &'
2
L
9
Ht,ong ) 1!
mol &'L Rfng 1! mol &'
2
L
9
J, cSn dbng va @ lt dung dDch MCl 1M" gi t,D ca @ l#
%" 0,17" +" 0,16" C" 0,06" 8" 0,29"
C$% B&2''(. Cho 1,7N gam hAn h2 g;m hai kim loi I 2 chu kl liOn tiB2 thu(c nh)m //%
H2hmn nh)m chnh nh)m //J tc dng hBt vi dung dDch MCl HdJ, thot ,a 0,7N2 lt kh M
2
HI
ktcJ" Mai kim loi ) l# Hcho +' P 5, Mg P 2*, Ca P *0, :, P 6N, +a P 19NJ
%" +' v# Mg" +" Mg v# Ca" C" :, v# +a" 8" Ca v#
:,"
C$% ). B&2''7. Cho 5,12 gam hAn h2 g;m &'L, &'
2
L
9
, &'
9
L
*
tc dng vi dung dDch MCl
HdJ" :au khi cc 2hEn 3ng =E- ,a ho#n to#n, c dung dDch XQ c0 cn X thu c N,72 gam
&'Cl
2
v# m gam &'Cl
9
" gi t,D ca m l#
%" 5,N5" +" 6,N5" C" N,60" 8" 7,50"
C$% * CD&2''8. Cho m gam hAn h2 F g;m &'L, &'
2
L
9
, &'
9
L
*
v#o m(t lng va dung
dDch MCl 2M, thu c dung dDch X c) tn lh 1! mol &'
2o
v# &'
9o
l# 1 $ 2" Chia X th#nh hai 2hSn
Rfng nhau" C0 cn 2hSn m(t thu c m
1
gam mu!i khan" :c kh clo HdJ v#o 2hSn hai, c0 cn
dung dDch 1au 2hEn 3ng thu c m
2
gam mu!i khan" +iBt m
2
p m
1
P 0,N1" khU tch dung dDch MCl
^ dbng l#
%" 2*0 ml" +" 60 ml" C" 920 ml" 8" 170
ml"
C$% ( CD&2''(. <hi cho 100ml dung dDch <LM 1M v#o 100ml dung dDch MCl thu c dung dDch
c) ch3a 7,525 gam ch\t tan" .;ng ( mol HhoVc molqlJ ca MCl t,ong dung dDch ^ dbng l# HCho M P 1Q
L P 17Q Cl P 95,5Q
< P 95J
%" 1M" +" 0,5M" C" 0,N5M" 8" 0,25M"
C$% 7 CD&2''(. Mo# tan ho#n to#n hAn h2 F g;m &' v# Mg Rfng m(t lng va dung dDch
MCl 20G, thu c dung dDch X" .;ng ( ca &'Cl
2
t,ong dung dDch X l# 15,N7G" .;ng (
2hSn t,[m ca MgCl
2
t,ong dung dDch X l# HCho M P 1Q Mg P 2*Q Cl P 95,5Q &' P 57J
%" 11,N5G" +" 26,21G" C" 15,N7G" 8" 2*,2*G"
9C$% 8 DHB&2'1'. Mea tan ho#n to#n 2,*5 gam hAn h2 F g;m hai kim loi ki>m thr v#o 200
ml dung dDch MCl 1,25M, thu c dung dDch X ch3a cc ch\t tan c) n;ng ( mol Rfng nhau" Mai
kim loi t,ong F l#
A. Mg v# :," B. +' v# Mg" C. Mg v# Ca" D. +' v# Ca"
C$% 1' Mea tan 10 gam hAn h2 hai mu!i cacRonat kim loi h)a t,D // Rfng dung dDch MCl d
ta thu c dung dDch % v# 2,2* lt kh Ra- ,a HktcJ" Msi c0 cn dung dDch % thC thu c Rao
nhiOu gam mu!i khand
%" N,55 gam +" 11,1 gam C" 12,2 gam 8" 19,55 gam
C$% 11 Mea tan 2,2* lt kh MCl HktcJ v#o *7,95 gam nc thu c dung dDch MCl c) n;ng (
l#$
%" N,9G +" 5,6NG C" " 15,6G 8" " 15,2G
C$% 12:. Zha t,(n 200 ml dung dDch MCl 2M vi 900 ml dung dDch MCl 1M c dung dDch
mi c) n;ng ( molql l# HthU tch kh0ng tha- riJ$
%" 1,99 M +" 1,*0 M C" 1,50 M 8" _2 n khc
C$% 13 _un n)ng 7,125 gam <ClL
9
vi MCl Vc" +iBt hihu 1u\t 2hEn 3ng l# 65G" khU tch Cl
2
thu c I i>u kihn tiOu chuin l#$
%" 1,12 lt +" 2,57 lt C" 2,657 lt 8" 9,97 lt
C$% 1 Mea tan ho#n to#n 29,6 gam hAn h2 g;m m(t mu!i cacRonat ca m(t kim loi h)a t,D
/ v# m(t mu!i cacRonat ca m(t kim loi h)a t,D // t,ong a=it MCl d thi to th#nh *,*6 lit kh
HktcJ v# dung dDch F" C0 cn dung dDch F thC thu c Rao nhiOu gam mu!i khand
%" 27,0 gam +" 22,*5 gam C" 16,5 gam 8" kBt KuE khc
C$% 1) :. m gam hAn h2 F g;m cc kim loi %l, Mg, &', Yn, tc dng va vi dung dDch
MCl to ,a 0,075 mol M
2
" Ctng m gam hAn h2 F tc dng vi kh clo d to ,a Hm o *,5NJ gam
hAn h2 cc mu!i" HCho$ &' P 57J" <h!i lng &' c) t,ong m gam hAn h2 F l#
%" 0,57 gam" +" 0,6* gam" C" *,20 gam" 8" 0,26 gam"
C$% 1* Cho 25,* gam hAn h2 R(t %l, Mg, &' tc dng va hBt vi dung dDch MCl th\- c) 1,7
gam kh M
2
thot ,a" H Cho$ &' P 57Q %l P 2NQ Mg P 2*, M P 1Q Cl P 95,5J"]ng mu!i clo,ua to
,a t,ong dung dDch l#$
%" 62,6 gam" +" 66,2 gam" C" 62,2 gam" 8" 59,6 gam"
C$% 1( ChT 2,*g kim loi F h)a t,D // v#o 200m dung dDch MCl 0,N5M, th\- 1au 2hEn 3ng vun
cen m(t 2hSn kim loi cha tan hBt" Ctng 2,*g nBu tc dng vi 250ml dung dDch MCl 1M th\-
1au 2hEn 3ng vun cen a=it d" <im loi % l#
%" Ca" +" Mg" C" &'" 8"Cu"
C$% 17 Cho 27,6 gam hAn h2 2 mu!i vCL
9
, FCL
9
tan t,ong dung dDch MCl va , 1au 2hEn
3ng thu c 7,N2 lit khHktcJ"+iBt v, F l# 2 kim loi thu0 wc cbng 1 2hmn nh)m % v# I 2 chu kC
liOn tiB2 t,ong REng tuSn ho#n" v, F l#
%" +', Mg" +" Ca, +a" C" Mg, Ca" 8" Ca, :,"
C$% 18:. Mo# tan 2,06g m(t mu!i halog'nua ca kim loi ho t,D // v#o M
2
L, 1au ) chia l#m 2
2hSn Rfng nhau" M(t 2hSn cho tc dng vi %g.L
9
HdJ thu c 1,*95g kBt ta" M(t 2hSn cho
tc dng vi .a
2
CL
9
HdJ thu c 0,565g kBt ta" Fc Dnh c0ng th3c ca mu!i"
%" MgCl
2
" +" +aCl
2
" C" Mg+,
2
" 8" CaCl
2
C$% 2' Cho hAn h2 .aCl v# .a+, tc dng vi dung dDch %g.L
9
thu c lng kBt ta c)
kh!i lng g\2 hai lSn kh!i lng hAn h2 Su" knh G kh!i lng ca .aCl t,ong hAn h2 Ran
Su"
%" 26,06G +" 5N,6NG C" 5,6NG 8" " 25,6G
C$% 21 Cho 91,6* gam hAn h2 .aF, .aX HX, Y l hai Halogen 2 chu k lin tipJ v#o dung
dDch %g.L
9
d thu c 5N,9* gam kBt ta" kCm c0ng th3c ca .aF, .aX v# tnh kh!i lng
mAi mu!i"
% .a+, v# .a/ +.aCl v# .a+, C .a& v# .aCl 8 .a+, v# .a&
C$% 22 . A&2''8. .Bu cho 1 mol mAi ch\t$ CaLCl
2
, <MnL
*
, <
2
C,
2
L
N
, MnL
2
lSn lt 2hEn 3ng
vi lng d dung dDch MCl Vc, ch\t to ,a lng kh Cl
2
nhi>u nh\t l#
%" CaLCl
2
" +" <MnL
*
" C" MnL
2
" 8" <
2
C,
2
L
N
"
C$% 23. Cho 90 gam <MnL
*
Hc) lun t2 ch\t J tc dng vi dung dDch MCl d, to#n R( kh clo
thu c dun v#o dung dDch </ thC c) 77,* gam </ tan t,ong nc ^ 2hEn 3ng" kh#nh 2hSn 2hSn
t,[m <MnL
*
t,ong 90 gam Ran Su l#
%" 50G" +" *2,19G" C" N5G" 8" *5,6G"
C$% 2. _U i>u chB 1,95 kg dung dDch a=it xlohi,ic c) n;ng ( 96G Hhihu 1u\t 2hEn 3ng l#
60GJ" HCho $ Ca P *0 Q & P 15 Q M P 1J" <h!i lng Ca&
2
cSn dbng l#$
%" 1,15kg" +" 1,16kg" C" 1,25kg 8" 1,27kg"
C$% 2) Cho kali iotua tc dng vi kali 2'manganat t,ong dung dDch M
2
:L
*
ngWi ta thu c
15,92 gam mangan H//J 1unxat" Hcho .k< ca Mn P 55, < P 95, L P 17, : P 92, / P 12N J" :!
gam iot to th#nh v# kh!i lng kali iotua 2hEn 3ng lSn lt l#
%" 55,70 v# 15,05" +" 61,27 v# 107,2*"
C" *5,60 v# 96,10" 8" 15,05 v# *5,60"
C$% 2* Mea tan ho#n to#n 10,6 gam m(t 0=it 14t ngWi ta cSn dbng va 5*,N5g dung dDch
MCl 20G" Fc Dnh c0ng th3c 2hmn tc ca 0=t 14t t,Ond
%" &'L" +" &'
9
L
*
"C" &'
2
L
9
8" &'
2
L
9
v# " &'
9
L
*
Bi tp halogen
1. A.
2. A
3. C
. A.
). A
*. B
(. D
Bi tp h+p ,h-t halogen
1. A
2. B
3. C.
. B
). A
*. B.
(. B
7. A
8. D
1'. B
11. A
12. B
13. D
1. A
1). A
1*. B
1(. B
17. C
18. B
2'. A
21. A
22. D
23. B
2. C
2). B
2*. A