Emelia Tri Ambarwati 2311100004

Problem1
2.1
Sistem metanol (1)/Water (2)
T=

333.15 K

P1 sat =

84.562

P2 sat =

19.953

600C

1= y1P/x1P1sat
2 = y2P/x2P2sat
GE/rt = x1ln1 + x2ln2
Data
Eksperiment
1*

2*

ln 2*

(GE/RT)*

0.452339

0.013297

0.0873193

0.622935049

1.026389

0.385457

0.026047

0.1039312

0.612292271

1.319847

1.075222

0.277516

0.072527

0.1348229

0.637325489

0.7345

1.245527

1.111502

0.219558

0.105712

0.1476191

0.634641258

0.4461

0.7742

1.162682

1.157443

0.150729

0.146213

0.1482279

0.599882794

60.614

0.5282

0.8085

1.097184

1.233036

0.092747

0.209479

0.1478209

0.593170629

63.998

0.6044

0.8383

1.049702

1.311028

0.048507

0.270811

0.1364504

0.570682036

67.924

0.6804

0.8733

1.030973

1.349537

0.030503

0.299762

0.1165579

0.536007314

70.229

0.7255

0.8922

1.02133

1.382244

0.021106

0.323708

0.10417

0.523073772

72.832

0.7776

0.9141

1.012475

1.409848

0.012398

0.343482

0.0860312

0.497467973

84.562

P* (kPa)

x1*

y1*

19.953

39.223

0.1686

0.5714

1.571984

1.013386

42.984

0.2167

0.6268

1.470285

48.852

0.3039

0.6943

52.784

0.3681

56.652

ln 1*

(GE/x1x2RT)*

Emelia Tri Ambarwati 2311100004

A12 =
A21=

A).
A12 =

0.682
0.475

Cara Grafik dengan menggunakan

ModelMargules
0.682

A21 =

0.475

P1 sat
=
P2 sat
=

84.562
19.953

Emelia Tri Ambarwati 2311100004

ln 1 = x2^2[A12+2(A21A12)x1]
ln 2 = x1^2[A21+2(A12A21)x2]
P = x11P1sat + x22P2sat
y1 = x11p1sat/P
GE/RT = x11+x22
Model
Margules
x1
0
0.1686
0.2167
0.3039
0.3681
0.4461
0.5282
0.6044
0.6804
0.7255
0.7776
1

ln 1
0.682
0.423168
0.363402
0.269503
0.211471
0.152579
0.103134
0.067573
0.04089
0.028757
0.01781
0

ln 2
0
0.023287
0.037534
0.070484
0.099808
0.140162
0.187018
0.233345
0.281153
0.309832
0.342888
0.475

1
1.977829
1.526791
1.438215
1.309313
1.235494
1.164834
1.10864
1.069908
1.041737
1.029174
1.017969
1

2
1
1.02356
1.038247
1.073028
1.104959
1.15046
1.205648
1.262818
1.324656
1.363197
1.409011
1.608014

P
19.953
38.74745
42.58164
48.55082
52.38921
56.65602
60.86789
64.65017
68.38468
70.60593
73.18955
84.562

y1
0
0.561784
0.618921
0.693031
0.734074
0.775578
0.813534
0.845817
0.876474
0.894253
0.91457
1

GE/RT
0
0.0907066
0.1081494
0.1309658
0.1409113
0.1457012
0.1427102
0.1331526
0.1176778
0.1059121
0.0901072
0

GE/x1x2RT
0.6470998
0.6371431
0.6190927
0.6058033
0.5896573
0.5726626
0.5568892
0.5411572
0.5318215
0.5210368

Emelia Tri Ambarwati 2311100004

B).
P*
(kPa)
19.95
3
39.22
3
42.98
4
48.85
2
52.78
4
56.65
2
60.61
4
63.99
8
67.92
4
70.22
9
72.83

Cara Grafik dengan menggunakan

Model Van Laar
x1*

y1*

0.16
86
0.21
67
0.30
39
0.36
81
0.44
61
0.52
82
0.60
44
0.68
04
0.72
55
0.77

0.57
14
0.62
68
0.69
43
0.73
45
0.77
42
0.80
85
0.83
83
0.87
33
0.89
22
0.91

1*

2*

ln 1*

1
1.5719
84
1.4702
85
1.3198
47
1.2455
27
1.1626
82
1.0971
84
1.0497
02
1.0309
73
1.0213
3
1.0124

1.0133
86
1.0263
89
1.0752
22
1.1115
02
1.1574
43
1.2330
36
1.3110
28
1.3495
37
1.3822
44
1.4098

0.4523
39
0.3854
57
0.2775
16
0.2195
58
0.1507
29
0.0927
47
0.0485
07
0.0305
03
0.0211
06
0.0123

ln2*

(GE/RT)
*

0.013297
0.026047
0.072527
0.105712
0.146213
0.209479
0.270811
0.299762

0.08731
93
0.10393
12
0.13482
29
0.14761
91
0.14822
79
0.14782
09
0.13645
04
0.11655
79

(x1x2/
(GE/RT))*

1.605303797
1.633206963
1.569056968
1.575693334
1.666992302
1.685855554
1.752289257
1.865646184

0.323708

0.10417

1.911776222

0.343482

0.08603

2.010179657

Emelia Tri Ambarwati 2311100004

2
84.56
2

76

41

75

48

98

12

A'12 =

0.705

P1 sat =

84.562

A'21 =

0.486

P2 sat =

19.953

ln 1 = A'12((1+(A'12x1/A'21x2))^-2
ln 2 = A'21((1+(A'21x2/A'12x1))^-2
P = x11P1sat + x22P2sat
y1 = x11p1sat/P
Model Van Laar
x1
ln 1
0
0.16
86
0.21
67
0.30
39

0.705
0.4209
26
0.3590
2
0.2642
75

ln2
0.0251
1
0.0398
6
0.0730
68

1
2.0238
47
1.5233
71
1.4319
25
1.3024
86

y1

1
1.0254
28
1.0406
65
1.0758
04

19.953
38.729
69
42.504
18
48.413
93

0
0.5607
83
0.6173
38
0.6913
67

Emelia Tri Ambarwati 2311100004

0.36
81
0.44
61
0.52
82
0.60
44
0.68
04
0.72
55
0.77
76
1

0.2071
02
0.1499
52
0.1023
89
0.0681
53
0.0421
81
0.0301
7
0.0191
22

0.1019
46
0.1410
93
0.1861
6
0.2307
68
0.2773
23
0.3057
21
0.3391
01
0.486

1.2301
08
1.1617
78
1.1078
14
1.0705
29
1.0430
83
1.0306
3
1.0193
06
1

1.1073
24
1.1515
32
1.2046
15
1.2595
67
1.3195
92
1.3576
04
1.4036
86
1.6258

52.251
38
56.552
57
60.821
27
64.656
25
68.429
84
70.664
62
73.253
81
84.562

0.7328
02
0.7749
58
0.8135
52
0.8462
29
0.8770
27
0.8947
74
0.9149
68
1

Emelia Tri Ambarwati 2311100004

D).
P1 sat
=
P2 sat
=

Cara Barker dengan Model

Margules
84.562
19.953

Emelia Tri Ambarwati 2311100004