S GD v T TP Cn Th

KIM TRA MT TIT - Nm hc 2013-2014

Trng THPT Chu Vn Lim

MN HA HC Khi 11
(Thi gian lm bi 45 pht, khng k pht )
________________
M : 132

H v tn:..
Lp: ..
Ch : Hc sinh khng c s dng bng h thng tun hon
(Cho: H=1; O= 16; C=12 ; Br = 80; Ag=108,Cu=64,Ca=40, N=14)
Hc sinh in cu tr li vo bng sau:

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
Cu 1: Thy phn 7,85 gam propyl clorua vi NaOH long, t 0 (va ) thu c dung dch X. Nh
dung dch AgNO3 d vo X thu c m(g) kt ta. Gi tr ca m l:
A. 14,35

B. 1,435

C. 1,345

D. 14,53

Cu 2: Hp cht CH3CH2CH(Cl)CH3 l dn xut halogen bc :

A. 2.

B. 3

C. 1

D. 4.

Cu 3: Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh
CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a v V l:
A. m = 2a V/22,4.

B. m = 2a V/11,2.

C. m = a V/5,6

D. m = a + V/5,6.

Cu 4: Cho Na tc dng vi etanol d sau chng ct ui ht etanol d ri nc vo cht

rn cn li trong bnh, sau thm vo bnh vi git dung dch qu tm thy dung dch:
A. c mu .

B. c mu xanh.

C. c mu tm.

D. c mu hng.

Cu 5: Tch nc hon ton m(g) etanol khan iu kin thch hp thu c 3,36 lt kh etilen
(ktc). Gi tr ca m l:
A. 6,9

B. 4,6

C. 9,2

D. 11,5

Cu 6: Cho hn hp X gm ancol metylic, etylen glicol v glixerol. t chy hon ton m gam X
thu c 6,72 lt kh CO2 (ktc). Cng m gam X trn cho tc dng vi Na d thu c ti a V lt
kh H2 (ktc). Gi tr ca V l
A. 3,36

B. 11,20

C. 5,60

D. 6,72

Cu 7: Chia hn hp gm hai ancol n chc X v Y (phn t khi ca X nh hn ca Y) l ng

ng k tip thnh hai phn bng nhau:
- t chy hon ton phn 1 thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O.

Trang 1/4 - M thi 132

- un nng phn 2 vi H2SO4 c 1400C to thnh 1,25 gam hn hp ba ete. Ha hi hon ton
hn hp ba ete trn, thu c th tch ca 0,42 gam N 2 (trong cng iu kin nhit , p sut).
Hiu sut ca phn ng to ete ca X, Y ln lt l:
A. 30% v 30%

B. 25% v 35%

C. 40% v 20%

D. 35% v 25%

Cu 8: Trong cc cht sau cht no khng phi phenol

A.

B.

C.

D.

Cu 9: S cht ng vi cng thc phn t C 7H8O (l dn xut ca benzen) va tc dng c vi

Na v va b oxi ha bi CuO, t0 to anehit l:
A. 2.

B. 1.

C. 3.

D. 4.

Cu 10: Hp cht M l dn xut ca benzen c cng thc phn t C8H9Cl v c phn ng vi dung
dch NaOH long, un nng. S cng thc cu to tha mn iu kin trn ca M l:
A. 4

B. 7

C. 5

D. 6

Cu 11: Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b
qu trnh l 90%. Hp th ton b lng CO 2 sinh ra khi ln men m gam tinh bt vo nc vi
trong, thu c 330 gam kt ta v dung dch X. Bit khi lng X gim i so vi khi lng nc
vi trong ban u l 132 gam. Vy gi tr ca m l
A. 297.

B. 405.

C. 324.

D. 486.

Cu 12: Hin tng th nghim no di y c m t khng ng ?

A. Cho dung dch Br2 vo dung dch phenol, xut hin kt ta trng.
B. Cho qu tm vo dung dch phenol, qu chuyn sang mu .
C. Cho phenol vo dung dch NaOH thu c dung dch ng nht.
D. Nh axit HCl vo dung dch natri phenolat thy dung dch b vn c.
Cu 13: Cho dy chuyn ha sau :
0

2SO4
CH3CH2CH2OH
H
,170 C

H2O (H2SO4lo ng)

Bit X, Y l sn phm chnh. Vy cng thc cu to ca X v Y ln lt l

A. CH3CH=CH2, CH3CH(OH)CH3.

B. CH3CH=CH2, CH3CH2CH2OH.

C. CH3CH=CH2, CH3CH2CH2OSO3H.

D. C3H7OC3H7, CH3CH2CH2OSO3H.

Cu 14: Cho cc cht: (1) catechol; (2) cumen; (3) phenol; (4) 1,2-ihiroxi-4-metylbenzen; (5)
4-metylphenol. S cht thuc loi phenol l:
A. 5.

B. 4.

C. 3.

D. 2.

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Cu 15: Pht biu no sau y ng?

A. Khi un C2H5Br vi dung dch KOH thu c etilen.
B. un ancol etylic 1400C (xc tc H2SO4 c) thu c imetyl ete.
C. Dung dch phenol lm phenolphtalein khng mu chuyn thnh mu hng.
D. Dy cc cht: C2H5Cl, C2H5Br, C2H5I c nhit si tng dn t tri sang phi
Cu 16: Hp cht no di y c dng tng hp ra PVC ?
A. C6H5Cl

B. CH2=CHCH2Cl

C. CH2=CHBr

D. CH2=CHCl

Cu 17: Cho s phn ng sau :

But1en

+ HCl

+NaOH
to

H2SO4

c
180o C

+ Br2

+NaOH
to

Bit X, Y, Z, T, U u l sn phm chnh ca tng giai on. Cng thc cu to thu gn ca U l

A. CH3CH2CH(OH)CH2OH.

B. CH3CH2CH(OH)CH3.

C. CH2(OH)CH2CH2CH2OH.

D. CH3CH(OH)CH(OH)CH3.

Cu 18: Cht hu c X mch h, bn c ng phn cis trans c cng thc phn t C 4H8O, X lm
mt mu dung dch Br2 v tc dng vi Na gii phng kh H2. X l:
A. CH2=CHCH2CH2OH

B. CH2=C(CH3)CH2OH

C. CH3CH2CH=CHOH

D. CH3CH=CHCH2OH

Cu 19: Cng thc chung ca ancol no, n chc, mch h l:

A. CnH2n+1OH (n1)

B. RCH2OH

C. CnH2n+2-x(OH)x (n1, x1, xn)

D. ROH

Cu 20: nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia
phenol vi
A. nc Br2.

B. H2 (Ni, nung nng).

C. dung dch NaOH.

D. Na kim loi.

Cu 21: Cht hu c X c cng thc phn t C6H6O2. Bit X tc dng vi KOH theo t l mol 1 : 2.
Vy s ng phn cu to ca X l
A. 2.

B. 1.

C. 3.

D. 4.

Cu 22: Cho ancol no, n chc, mch h X qua bnh ng CuO (d), nung nng. Sau khi phn
ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. S mol ancol b oxi ha l:
A. 0,03.

B. 0,01.

C. 0,04

D. 0,02.

Cu 23: Cho 13,74 gam axit picric vo bnh kn ri un nng nhit cao. Sau khi phn ng xy
ra hon ton, thu c x mol hn hp kh gm: CO2, CO, N2 v H2. Gi tr ca x l
A. 0,60.

B. 0,36.

C. 0,54.

D. 0,45.

Cu 24: Trong s cc pht biu sau:

Trang 3/4 - M thi 132

1) Phenol c tnh axit mnh hn etanol v nhn benzen ht electron ca nhm -OH bng hiu
ng lin hp, trong khi nhm -C2H5 li y electron vo nhm -OH.
2) Phenol c tnh axit mnh hn etanol v c minh ho bng phn ng phenol tc dng vi
dung dch NaOH, cn C2H5OH th khng.
3) Tnh axit ca phenol yu hn axit cacbonic, v sc CO 2 vo dung dch C6H5ONa ta s c
C6H5OH v Na2CO3.
4) Phenol cn c tn gi khc l axit phenoic
Cc pht biu ng l:
A. 2 v 3

B. 1, 2, 3 v 4

C. 1 v 2.

D. 1, 2 v 3

Cu 25: Cho cc cht: benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat,
anlyl clorua. S cht tc dng c vi dung dch NaOH long, un nng l:
A. 3.

B. 4.

C. 6.

D. 5.

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