S Gio Dc & o To NGh an K thi chn i tuyn d thi

hc inh !i"i #u$c !ia %&' () T*+T

n,- hc ).(. / ).((

01n thi2 *o hc
Ngy thi: .34(.4).(.
Thi gian: (3. pht (khng k thi gian giao )

Cu 1 (4,0 im).
1. T CH
4
, cc cht v c v iu kin cn thit, vit s phn ng (ghi r iu kin) iu
ch cc h cht c! cng th"c cu t#$ %&u'

(
C
)
C(
*
&+
)H
)CH
*
,+
(( -
.
H)

2. Ch$ % / ,in h!&'

A
F B (C
0
H
12
))
1+)
*
.+ 3n4H
.
)
.
I X (C
1*
H
15
6
4
C-)
D
7-
.
)
*
4t
2
G (C
8
H
9
))
I4H
.
)
Q (C
8
H
9
)
.
)
E
D
H (C
8
H
12
6C-)
HC-4C
.
H
:
)H
6H
*
;
.
Cr
.
)
8
4H
.
<)
4
6H
*
1+ C
9
H
:
=g>r
.+ H
.
)
;
.
Cr
.
)
8
4H
.
<)
4 T
(C
8
H
0
))
1+ CH
*
=g?
.+ H
.
)

H@A Bc Cnh cng thc cu to cD& cc cht hEu c Fc kG hiu ,Hng cc chE A, B, D, E, F,
G, H, I, Q, X.
Cu 2 (3,0 im).
1+ H cht hEu c A c! 85,:5ICJ 1.,.:IH v khKi -Fng, cLn -#i - $Bi+ )M$n hNn A thu
Fc H)CH
.
CH)J CH
*
(CH
.
)
.
C)CH
*
v CH
*
CH
.
C)(CH
.
)
.
CH)+ 6u ch$ A tc OPng vQi ,r$R
thS$ tT - R$- 1'1 r/i RQi $M$n hNn %Un hVR chGnh, thW chT thu Fc h&i %Un hVR hEu c tr$ng
! c! RXt BSt$n+ Yun n!ng A vQi Oung OCch &Bit OZ Ong thu Fc %Un hVR B c! c[ng cng th"c
hNn t\ vQi A, nhFng khi $M$n hNn B chT ch$ RXt %Un hVR hEu c OuA nht+
&+ ]c Cnh cng th"c cu t#$ v g^i t_n A+ >it tr$ng hNn t\ A c! RXt nguA_n t\ $Bi+
,+ ]c Cnh cng th"c cu t#$ cD& B v vit c ch hUn "ng chuA`n h!& A thnh B+
2. ;hi ch$ .aRStA-$ct&a.,9aOiSn tc OPng vQi Oung OCch &Bit %b BUA r& hUn "ng !ng vLng
t#$ r& ,Kn %Un hVR+ cit c ch hUn "ng t#$ ,Kn %Un hVR !+
Cu 3 (4,0 im).
1. H cht hEu c A (C
5
H
12
)
.
) hUn "ng vQi Oung OCch 6&HC)
*
giUi h!ng khG C)
.
+ A
khng -R Rt Ru Oung OCch nFQc ,r$R, khng hUn "ng vQi CH
*
)H khi c! Rdt H
.
<)
4
dc+
1
5 ch6nh th7c
thi c 2 trang
=dt khc, khi ch$ H
.
<)
4
dc v$ A, %&u ! ch$ hen h v$ CH
*
)H @ Fc -R -#nh thW Fc
h cht B (C
12
H
1.
)
.
)+ fg -ugn tWR cng th"c cu t#$ cD& A+ hiUi thGch %i t#$ r& B+
2. TrXn RXt hiOr$c&c,$n khG X v $Bi thS$ tT - th` tGch tFng "ng - 1' 5 r/i ch$ v$ ,Wnh
kGn, thA %ut tr$ng ,Wnh - 1 &tR j 2
$
C+ >gt ti& -\& in ` X chA ht, hen h %&u hUn "ng
c! %ut - 1,:8: &tR j 1*9,:
$
C+
&+ TWR cng th"c hNn t\ cD& X+
,+ cit cng th"c cu t#$ c! th` c! cD& X, ,it tt cU cc nguA_n t\ c&c,$n tr$ng X c[ng
RXt tr#ng thi -&i h!&+
c+ T RXt cht X j tr_n (c! cu O#ng h[ h) v cc cht v c, vit % /
tkng h cht Y c! cng th"c cu t#$ +
Cu 4 (3,0 im).
1. )Bi h!& RStA- g-Ac$Mit Q ,Hng H?)
4
t#$ thnh %Un hVR giKng nhF %Un hVR thu Fc khi
tin hnh hUn "ng nA vQi RXt RStA- lag-Ac$Mit cD& (a&nO$hSB$M+ TuA nhi_n, hUn "ng cD& Q
chT O[ng RXt hNn t\ H?)
4
v %Un hVR khng c! HC))H+ =StA- h!& Q, thDA hNn, %&u ! $Bi
h!& R@nh -it ,Hng H6)
*
thW %inh r& Oia)aRStA- StS cD& &Bit (a)at&rt&ric+ <\ OPng cng th"c
H&m$rth ` ,i`u OiZn cu hWnh cD& Q+
C))H
H H)
)H H
C))H
&Bit (a)at&rt&ric
2. Ch$ ,it O#ng i$n -Fnng cic chGnh cD& -A%in v &Bit g-ut&Ric+ hiUi thGch+
Cu 5. (4,0 im).
1. T RXt -$#i thic vgt ngFoi t& tch Fc cht A c! cng th"c hNn t\ C
12
H
1.
)
.
+ A hUn "ng
vQi Oung OCch 6&)H t#$ thnh h cht B c! cng th"c hNn t\ C
12
H
11
)
.
6&+ B hUn "ng Fc vQi
CH
*
? t#$ thnh cht C c! cng th"c C
12
H
11
)()CH
*
) v 6&?+ Hi cD& C hUn "ng vQi H
.
(Bpc tc)
Fc cht D c! cng th"c C
12
H
1*
)()CH
*
)+ Cht D hUn "ng vQi Oung OCch ;=n)
4
tr$ng H
.
<)
4
t#$ thnh &Bit *,4aOiRSt$Bi,SnM$ic v &Bit &BStic+ cit cng th"c cu t#$ cD& A, B, C ,it chpng
khng c! /ng hNn hWnh h^c+
2. HiOr$c&c,$n X c! cng th"c hNn t\ - C
0
H
0
+ X khng -R Rt Ru Oung OCch >r
.
4CC-
4
,
khi ch$ X tc OPng vQi C-
.
(&%kt) chT thu Fc 1 Oqn But R$n$c-$ OuA nht+
&+ ]c Cnh cng th"c cu t#$ cD& X+
,+ C! ,&$ nhi_u %Un hVR th c-$ cD& X c! hNn t\ khKi ,r thu& 102+ cit cng th"c cu t#$ cD& chpng+
Cu 6 (2,0 im).
Ch$ h cht thR A c! cng th"c hNn t\ - C
5
H
12
)+ >it rHng khi $Bi h!& R#nh cht A vQi
Oung OCch ;=n)
4
gR dc thu Fc h&i &Bit c! cng th"c hNn t\ C
8
H
9
)
.
v C
.
H
4
)
.
+ CLn khi ch$
A hUn "ng vQi RStA- R&giS ,r$Ru& r/i thDA hNn thu Fc &nc$- ,gc ,& B c! RXt nguA_n t\
c&c,$n ,t Ki+
1+ cit cng th"c cu t#$ cD& A v g^i t_n+
2+ Ch$ A tc OPng vQi RStA- i$Ou& tr$ng Ri trFong kiR R#nh ngFoi t& thu Fc cht C
(C
11
H
14
))+ H@A ch$ ,it t_n cD& c ch hUn "ngJ cng th"c cu t#$ v t_n g^i cD& C+
Cho bit: H=1 C=12 !=1" C#=3$,$.
- - - *8t - - -
H v tn th sinh:............................................................................................ S bo
danh:........................................
.