AS.CHEM2.1.

004 24-J ul-08 RiponGrammar School / RWGrime

HESSS LAW 3 USING BOND ENTHALPIES

Name .. Form .




1) Use the following bond enthalpies to calculate H for the following reactions. You may assume that all species
are in the gaseous state.

Bond HH O=O CC C=C CH FF HO BrBr CBr HBr C=O
KJ mol
-1
436 496 348 612 412 158 463 193 276 366 743

a)
H H

Br Br + 2 H Br



b)
H C



H
C
H
C
H
H
H
+ Br Br H C
H
Br Br H
H
H
C
H
C



c) H C
H
C
H
H +
3 O O 2 O C O +
2 H O
H

d) H
c
of methane

2) Calculate the average N-H bond energy in NH
3
(g) using the data below.

H
f
of NH
3
(g) = -46 kJ mol
-1
Bond enthalpies: NN =944; H-H =436 kJ mol
-1


3) Calculate the C=C bond energy in ethene using the data below.

CH
2
=CH
2
(g) + H
2
(g) CH
3
CH
3
(g) H = -138 kJ mol
-1
Bond enthalpies: C-C =348; H-H =436; C-H =412 kJ mol
-1


4) Calculate the average S-F bond energy in SF
6
(g) using the bond data in the table, the H
f
of SF
6
(g) which is
-1100 kJ mol
-1
, and

S(s) S(g) H =223 kJ mol
-1

5) Calculate the CC bond enthalpy in the gas propyne
using the bond enthalpy values in the table above and
the enthalpy changes for the reactions shown below.

C C C H H
H
H



propyne



C(s) C(g)

H =+715 kJ mol
-1

CH
3
CCH(g) H
f
=+185 kJ mol
-1

6) Calculate H
f
for bromomethane, CH
3
Br(g), given the bond data in the table and

C(s) C(g) H =715 kJ mol
-1

Br
2
(l) Br
2
(g) H =15 kJ mol
-1