Basis:

Feed input = 10,000 kg/h

1 M feed IPA0.687
1x

x0.687

At 350 co
Ether selectivity :

Propylone selectivity :

Production rate of acetone

358.7 x 0.0060 = moles ether

= 2.153 kmol of ether
358.7 x 0.13 =46.631 kmol of propylene


408.54

358.7

358.7

408.54

358.7

358.7

4.304 2.152 2.152

46.631
Total feed IPA = 459.47 kmol
Unreacted IPA =49.84kmol
Total mole outlet :
358.7+358.7+2.152+2.152+46.631+46.631+208.60+49.84=1073.406kmole
Total feed = 668.8kmol
IPA feed = 459.47

Flash drum:

At bubble point T= 81

Vapor fraction 0.79

dew point pressur 1.43 atm

Liquid fraction 0.21

bubble point pressure 233.28 atm

Acetone

0.334

0.3121 70.352

0.3397 288.062 1.0882

H2

0.334

0.0012 0.270

0.4202 356.325 315.6292

H2o

0.239

0.5988 134.978 0.1458 123.636 0.2434

Propylene

0.043

0.0030 0.6762

0.0534 45.282

17.5573

Ether

0.002

0.0025 0.6535

0.0019 1.611

0.7439

IPA

0.048

0.0622 18.529

0.0391 330156 0.4757

225.415 1

847.99

Absorption :
At steam 13 :

Solubility of H2 in water :
0.0016 g gas /kg water
Solubility of ether in water :
(2g/L) 2000g/m3
Solubility of propylene :
0.16g/m3

At stream 13:
Acetone = 288.062 kmol = 16730.641kg
H2 = 356.325kmol = 712.65 kg
H2o=123.636kmol = 1978.176kg
Propylene =45.202 kmol =1905.446kg
Ether = 10661 kmol =164.595kg
IPA =33.156kmol =1992.675kg
Amount of water to dissolve acetone: 16730.641kg
Amount of water to desolve IPA:1992.675kg
Amount of water at stream 14:
16730.641+1992.695kg =18723.316kg

At stream 15:
H2 = 356.325 kmol =712.65kg
Propylene =45.282kmol =1905.446kg
Ether =1.611kmol =164.595kg
At stream 16:
Acetone=16730.641 kg = 288.062 kmol
H2o = 16730.641kg =288.062 kmol
IPA =1992.675 = 33.156 kmol
Total = 288.062 +1265.658+33.156=1586.876kmol

Water column:
At stream 19:
Acetone19 = acetone 17 +acetone 16 =
70.352 + 288.062= 358.414kmol
H2O 19= H2O 17 +H2O16 =134.978+1265.658 =1400.636
IPA19=IPA17+IPA16=18.529=33.156.685kmol
Total=358.414kmol+1400.636kmol+51.685kmol=1810.735kmol

At stream 22: ( top product)

Acetone: 358.414-2.037=356.376
Since IPA are top product:
IPA =51.685kmol
H2o =715.619-356.376-51.685=307.558
At stream 26:
Acetone =2037kmol
H2O =1095.625-2.037= 1093.588kmol
Mole fraction at stream 22:
Acetone =
IPA =
IPA =

Acetone column:
Feed =715.619
A=356.376kmol
IPA=51.685kmol

x=0.497
x=0.072

H2O =307.558kmol x=0.429

Assume that 0.999 of acetone is top product

(

B=F-D = 715.619- 355.658=359.961 kmol

At stream 23:
Acetone = 355.658 kmol
At stream 25:
IPA = 51.685kmol
H2o = 307.558 kmol
Acetone = 0.718 kmol

IPA column:
At stream 23:
IPA: 51.685 kmol

X= 0.143

H2o : 307.558 kmol x=0.854

Acetone : 0.718 kmol

x= 0.001

Since all IPA at the top product :

At stream 30 :
IPA =51.685 kmol
Acetone = 0.718 kmol

At stream 27:
H2O = 307.685 kmol
And we will add water to stream 30 (recycle stream )
To be same composition of feed stream

Recycle:
Input = output
IPA stream 2 =IPA stream 1 + IPA stream 31
IPA stream 1 = 459.47 -51.685 =407.785

H2O stream2: H2O strean1 +H2O stream 31

H2o stream1: 208.66-23.472 =185.188 kmol

Amount of acetone protection: