1. .....................................................................................................................................

3
2. ............................................................................................... 3
3. ............................................................................................................ 4
3.1. .................... 5
3.2. ............................................................................................................ 5
3.3. ....................................................................... 6
3.4. .............................................................. 8
4. ................................................................................... 9
4.1. ......................................................................................... 10
4.2. .......................................................................................... 11
5. ........................................................................................................................... 11

1.

6 18 .
,
, 1886. .
-. 1906.
y
.
1100 . , ,
.
,
.
,
. .

.
.

2.
.
pH ,
.
:
1. O3 + H2O 2HO* + O2

k2 = 1.1 10 4M 1s-1

*2. O3 + OH O2 + HO2*

k2 = 70M-1 s-1

*
3. O3 + HO O2 + HO2*

4. O3 + HO2* 2O2 + HO
5. 2HO2*

k2 = 1.9 x 109 M 1 s 1

O2 + H2O2
O3 + 2H+ + 2e- O2 + H2O

EO = 2,07V

1
3

3.

:
,
,
,
,
.

2 12%
. 80 90 % ,
.
.
.
, , UV
.
, .
, .

0.4mg/lit. ,
1g/m . ,
, 13g/m,
.
1-2g/m,
.
,
.
,
.
,
.

. 350C. ,
200m/h
. 0.1 mg/l .

.
600 Hz,
50 Hz.
:
18 kWh /kg 50Hz
;
13 kWh/kg 600Hz
;
6 kWh/kg 600Hz
;

.

3.1.

,
- , 95%
, , ,
.
.
(),
, , ,
.
2 .

3.2.

(,
, ),
. , ,
,

( ).
(),
. 3 .

3
5

 : (50 60Hz) 10kV 20kV, -

(60-1000Hz) (8-14kV)
, - (1000-2000Hz) . 4
w .

Slika 4 Generatori ozona u postrojenju za tretman

3.3.

- - .
(),
. .
Rastvorljivost ozona u vodi prema Henry-jevom moe se definisati jednainom:

pi = He C*
:
pi - parcijalni pritisak ozona u gasnoj fazi;
He - Henry- konstanta;
C* - ravnotena koncentracija ozona u tenoj fazi, koja se moe izraunati na osnovu jednaine:
C*=K Cq P/Pa
:
K - ;
Cq - ;
P - ;
Pa - .


. 5 .

5
6
.

 1 Henry- .
1 Henry-

(mg3/lit)
(ppm)
(atm/mol)
(C)
0
5
10
15
20
25
30
0
5
10
15
20
25
30
0
5
10
15
20
25
30
0
5
10
15
20
25
30

1,940
2,180
2,480
2,880
3,760
4,570
5,980
1,940
2,180
2,480
2,880
3,760
4,570
5,980
1,940
2,180
2,480
2,880
3,760
4,570
5,980
1,940
2,180
2,480
2,880
3,760
4,570
5,980

12,07
12,07
12,07
12,07
12,07
12,07
12,07
18,11
18,11
18,11
18,11
18,11
18,11
18,11
24,14
24,14
24.14
24,14
24.14
24,14
24,14
36.21
36,21
36,21
36,21
36,21
36,21
36,21

(mg3/lit)

6,044
6,044
6,044
6,044
6,044
6,044
6,044
9,069
9,069
9,069
9,069
9,069
9,069
9,069
12,088
12,088
12,088
12,088
12,088
12,088
12,088
18,132
18,132
18,132
18,132
18,132
18,132
18,132

8,31
7,39
6,50
5,60
4,29
3,53
2,70
12,47
1 1,09
9,75
8,40
6,43
5,29
1.04
16,62
14,79
13,00
11,19
8.57
7,05
5,39
24,92
22,18
19,50
16,79
12,86
10,58
8,09

20C 101kPa.

3.4.

:
,
,
.

 7 .

7

,
. ,
,
. 8
.

4.
, ,
(0,1mg/l).
, .

. 10
2 3 . ,
, , 0
30 ,
.
pH .
pH .
9

 pH,
.
,
, ,
. ,
.
- . .
,
.
,
10mg/lit, .

4.1.

( ,
);
, ;

;
;
, -
Cryptosporidium i Giardia;
;
() .
8
.

10

4.2.

-: ,
-;
;
();
.

5.
,
.
, .
,
,
.
,
,
, .

11