TRUONG DAI HOC CAN THO KHOA CONG NGHE BQ MON CONG NGHE HOA HOC ---000--- DE TAI PHUONG PHAP QUANG PHO HAP THU NGUYEN TU (AAS) TRONG KIEM NGHIEM DUQC PHAM Luong Ngan 2051823 Vo Chi Nguyén 2051831 Nguyén Hitu Phuée 2051843 Nguyén Dire Phuong 2041653 Gito vién huriing Nguyen Thj Digp Cl CAn Tho, 11 - 2008 ~ \7 : MUC LUC ates PHAN 1: PHUONG PHAP QUANG PHO HAP THY NGUYEN TU'(AAS) 3 1. Nguyén tie iia phép do AAS... 1.1. Nguyén tie sinh phé: 1.2. Nguyén tic cia phép do AAS 1.3, Cac buée chun bj phan tich 2. Thiét bi phin tich bing AAS: 2.1. Nguén phat ra bite xa don 2.2. H@ théng nguyén tir hoa miu: 2.3, H@ thong don sie: . PHAN 2: UNG DUNG CUA PHUONG PHAP AAS TRONG KIEM NGIEM DUQC PHAM: 7 I. DINH LUQNG NGUYEN TO CROM TRONG THUOC VIEN NEN. BANG QUANG PHO HAP THY NGUYEN T 1. Bat van de: 2. Dieu kign va thyc nghiém: . Héa chat va thiét bi: at he 2.1.1 Héa chat 2.1.2. Thiét bj, dung cu 2.2. Déi tung va phuong phép nghi 2.2.1. Doi tung 2.2.2. Phuong php nghién citu 2.2.2.1Chuan bj dung dich chuan 2.2.2.2 Chuan bi dung dich thir 2.2.2.3 Diéu kign phan tich 4 2.2.2.4, Tién hanh; 3) Kétqua ... 3.1. Khio sat khoang tuyén tinh cia phuong phap ... 3.2, Kh do s at inh d ting ¢ tia ph w ong ph dp 3.3. Dinh lugng ham hong Crom tone vin nén Centovit-liver ing phuong phap dung chuan .. pee EEE EEE z 4. Két Inn . TL. DINH LUQNG CAC NGUYEN TO VII LUQNG KHAC CO TRONG THUOC VIEN NANG BAT Ki: 1. Dinh long Magnesi (Mg) 12 2. Dinh lugng Kem (Zn) 13 3. Dinh lugng Calci (Ca) ........ Z 14 KET LUAN ssessssensees TAT LIEU THAM KHAO AuveeRE Ow Sewcoocwwenexe www 10 i ADPHAN I. PHUONG PHAP QUANG PHO HAP THU NGUYEN TU (AAS) se. 1. Nguyén tac ciia phép do AAS: 1.1. Nguyén tie sinh pho: Cée nguyén tir & trang thai binh thudmg thi chting khOng hp thu hay bite xa ning Iugng nhumg khi ching 6 trang thai ty do duéi dang nhiing dim hoi nguyén tir thi ching ‘hap thu va bite xa nang lugng. Méi nguyén tir chi hap thu nhimg birc xa nhdt dinh tuong img v6i nhiing bite xa ma ching ¢6 thé phét ra trong qué tinh phat xq ciia ching. Khi nguyén tir nhn nang Iugng ching chuyén lén mite ning Iugng cao hon goi 1a trang thai kich thich. Qué trinh d6 goi 1a qué trinh bép thu nang Luong cia nguyén tir te do 6 trang thai hoi va tao ra phd ciia nguyen tir 46, Phd sinh ra trong qua trinh nay goi la phé hap thu nguyén tr 1.2. Nguyén tic ctia phép do AAS Phuong phdp quang phé hip thy nguyén tir dya trén sy hap thu chon loc eae bite xa cOng hudng cia nguyén tir & trang thai ty do cia nguyén t6 cin xde dinh. Déi voi méi nguyén té vach cOng huéng thuéng 1a vach quang phé nhay nhat ctia phd phat xa nguyén tir ciia chinh nguyén tir 46, Nhu vay dé thu durge phd hap thu nguyén tir cla mét nguyén t6 nao d6 can phai thye hign céc qua trinh sau: = Thye hign qué tinh héa hoi va nguyén tir hda mau tgo ra ede don nguyén tt, ‘Diéu nay duge thye hién & nhiét 46 cao nhé ngudn nhiét 1 ngon lita dén khi: phun dung dich chita chat phan tich & trang thai aerosol vao ngon lita dén khi, Hoae bing phuong php khong ngon hia: nhi tée dung nhigt cia 10 graphite. ‘Trong diéu kign nhiét 46 khéng qua cao (1500°C + 3000°C) da sé cae nguyén tir tgo thinh 6 trang thai co bin, Dam hoi don nguyén tir ndy chinh 1a méi tru’mg hip thy bite xq va sinh ra phé hép thy nguyén tr. — Chiéu chim tia bite xa dic trumg cua ctia nguyén té can phin tich qua dim hoi nguyén tir vita duge diéu ché. Chim tia bire xa nay duge phat ra tir dén cathode ring (dén