Second Midterm Examination, CH110A, Spring 2005
Thursday, 26 May 2005, 10:00 — 10:50 am
NAME: Key
d
This examination is composed of three problems. Do all parts of all the problems. You
have the entire class period to complete the exam. You may use your textbook, one page
of notes (front and back), and a calculator of your choice in working the exam.
Problem 1: of 35 points
Problem 2: of 35 points
Problem 3: of 20 points
TOTAL:1. (35 points) A sample of 1.00 cmn® of liquid water at 300 K and 1 bar undergoes a
process leading to a final state at 360 K and 40 bar. Determine AS for this process,
Some or all of the following may be useful in working this problem. The density of
water at 300 K and 1 bar is p = 0.995 g em™*. The thermal expansion coefficient,
a, the isothermal compressibility, «, and the molar constant-pressure heat capacity,
Crm, can all be taken to be pressure and temperature independent and to have the
values
= 3.04 x 1074 K“? 4g = 4.50 x 1078 bar?
Cpm = 75.291 J mol“'K~*
[Hint: Pick a convenient path from initial state to final state.]
Holt) —> 40/8)
frocess
30k, harsh he ok, Iba rh
Lepr. oun the peth rr 3 TF,
Lol
Then’ P,
bh , :
AS = ( CeAt ( xVGnP)dP = P&B - «( Von PAP
T H A
T
Ned NTP).
vert, A) = werpemeMe)](Pp
f & ~
“ 5 wn,e)dP = 4 Vein) eon Exle-A)) dP
1 oF B
|
LE
Pauper :
62 Ohh - cep CK(B-P )
AS Gab