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Second Midterm Examination, CH110A, Spring 2005 Thursday, 26 May 2005, 10:00 — 10:50 am NAME: Key d This examination is composed of three problems. Do all parts of all the problems. You have the entire class period to complete the exam. You may use your textbook, one page of notes (front and back), and a calculator of your choice in working the exam. Problem 1: of 35 points Problem 2: of 35 points Problem 3: of 20 points TOTAL: 1. (35 points) A sample of 1.00 cmn® of liquid water at 300 K and 1 bar undergoes a process leading to a final state at 360 K and 40 bar. Determine AS for this process, Some or all of the following may be useful in working this problem. The density of water at 300 K and 1 bar is p = 0.995 g em™*. The thermal expansion coefficient, a, the isothermal compressibility, «, and the molar constant-pressure heat capacity, Crm, can all be taken to be pressure and temperature independent and to have the values = 3.04 x 1074 K“? 4g = 4.50 x 1078 bar? Cpm = 75.291 J mol“'K~* [Hint: Pick a convenient path from initial state to final state.] Holt) —> 40/8) frocess 30k, harsh he ok, Iba rh Lepr. oun the peth rr 3 TF, Lol Then’ P, bh , : AS = ( CeAt ( xVGnP)dP = P&B - «( Von PAP T H A T Ned NTP). vert, A) = werpemeMe)] (Pp f & ~ “ 5 wn,e)dP = 4 Vein) eon Exle-A)) dP 1 oF B | LE Pauper : 62 Ohh - cep CK(B-P ) AS Gab

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