CHEMCAD 6.0.

Page 1

Job Name: Untitled

Date: 12/18/2013

Time: 11:11:45

FLOWSHEET SUMMARY
Equipment
1
2
3
4
5

Label

Stream Numbers

MIXE
REAC
REAC
CSEP
TOWR

2
1
3
4 -6
6 -8
8 -5 -11
11 -13 -14

-4

Stream Connections
Stream
1
2
3
4

Equipment
From
To
1
1
1
1
2

Stream
5
6
8
11

Calculation mode : Sequential

Flash algorithm : Normal
Equipment Calculation Sequence
1
2
3
4
5
No recycle loops in the flowsheet.
*
*
*
*

Uop
Uop
Uop
Uop

1,
2,
4,
5,

Check
Check
Check
Check

mass
mass
mass
mass

balance.
balance.
balance.
balance.

Equipment
From
To
4
2
3
3
4
4
5

Stream
13
14

Equipment
From
To
5
5

CHEMCAD 6.0.1
Job Name: Untitled
Overall Mass Balance

Page 2
Date: 12/18/2013

Time: 11:11:46

Propylene
Oxygen
Water
Carbon Dioxide
Acrylic Acid
Acetic Acid
Acrolein

kmol/h
Input
Output
0.000
0.000
1.000
0.000
0.000
0.000
0.000
0.000
0.000
693828.000
0.000
0.000
0.000
0.000

kg/h
Input
Output
0.000
0.000
31.999
0.000
0.000
0.000
0.000
0.000
0.000 50000001.674
0.000
0.000
0.000
0.000

Total

1.000

32.000 50000002.226

693828.000

Warning: Overall mass balance not good enough. Need lower flow tolerance.

CHEMCAD 6.0.1

Page 3

Job Name: Untitled

COMPONENTS
1
2
3
4
5
6
7

ID #
23
47
62
49
253
130
252

Date: 12/18/2013
Name
Propylene
Oxygen
Water
Carbon Dioxide
Acrylic Acid
Acetic Acid
Acrolein

Time: 11:11:46
Formula
C3H6
O2
H2O
CO2
C3H4O2
C2H4O2
C3H4O

THERMODYNAMICS
K-value model

Enthalpy model
Liquid density

:
:

UNIFAC
No correction for vapor fugacity
Latent Heat
Library

Std vapor rate reference temperature is 0 C.

Atmospheric pressure is
1.0000 atm.
* Component ID
47 does not have UNIFAC subgroups.
* Component ID
49 does not have UNIFAC subgroups.

CHEMCAD 6.0.1
Job Name: Untitled
EQUIPMENT SUMMARIES

Page 4
Date: 12/18/2013

Time: 11:11:47

Mixer Summary
Equip. No.
Name

Reactor Summary
Equip. No.
Name
Thermal mode
Temperature C
Key Component
Frac. Conversion
Stoichiometrics:
Propylene
Oxygen
Water
Acrylic Acid
Acrolein

2
1

7
1.0000

2
300.0000
5
0.1100

-1.000
-1.000
1.000
0.000E+000
1.000

0.000E+000
-0.500
0.000E+000
1.000
-1.000

Component Separator Summary

Equip. No.
Name
Component No. 3
Component No. 5

4
0.5000
0.5000

Towr Rigorous Distillation Summary

Equip. No.
Name
Initial flag
Optimization flag

5
6
1

CHEMCAD 6.0.1
Job Name: Untitled
STREAM PROPERTIES
Stream No.
Name
- - Overall - Molar flow kmol/h
Mass flow kg/h
Temp C
Pres atm
Vapor mole fraction
Enth MJ/h
Tc C
Pc atm
Std. sp gr. wtr = 1
Std. sp gr. air = 1
Degree API
Average mol wt
Actual dens kg/m3
Actual vol m3/h
Std liq m3/h
Std vap 0 C m3/h
- - Vapor only - Molar flow kmol/h
Mass flow kg/h
Average mol wt
Actual dens kg/m3
Actual vol m3/h
Std liq m3/h
Std vap 0 C m3/h
Cp J/kmol-K
Z factor
Visc Pa-sec
Th cond W/m-K
- - Liquid only - Molar flow kmol/h
Mass flow kg/h
Average mol wt
Actual dens kg/m3
Actual vol m3/h
Std liq m3/h
Std vap 0 C m3/h
Cp J/kmol-K
Z factor
Visc Pa-sec
Th cond W/m-K
Surf tens N/m

Page 5
Date: 12/18/2013

Time: 11:11:47

1
Propileno

2
Aire(Oxigeno

3
Vapor

4
mezcla

0.0000
0.0004
25.0000
4.4016
1.000
0.00019015
91.6100
45.5200
0.522
1.453
139.5728
42.0810
8.0842
0.0001
0.0000
0.0002

1.0000
31.9990
218.0000
4.0170
1.000
5.5864
-118.5700
50.1000
1.128
1.105
-6.0011
31.9990
3.1868
10.0412
0.0284
22.4136

0.0000
0.0002
160.0000
6.0000
1.000
-0.0023779
374.2000
218.2900
1.000
0.622
10.0000
18.0150
3.1492
0.0001
0.0000
0.0002

0.0000
0.0003
0.0000
0.0000
0.0000
0.00000
74.1294
85.3944
1.002
0.929
9.6662
26.9095
0.0000
-1.#IND
0.0000
0.0002

0.0000
0.0004
42.0810
8.0842
0.0001
0.0000
0.0002
65020.4280
0.9366
8.812e-006
0.0178

1.0000
31.9990
31.9990
3.1868
10.0412
0.0284
22.4136
30989.7791
1.0010
2.983e-005
0.0410

0.0000
0.0002
18.0150
3.1492
0.0001
0.0000
0.0002
34550.8506
0.9658
1.470e-005
0.0306
0.0000
0.0003
26.9095
0.0000
0.0002
0.0000
1.000e-030

CHEMCAD 6.0.1
Job Name: Untitled
STREAM PROPERTIES

Page 6
Date: 12/18/2013

Stream No.
5
Name
Al incinerad
- - Overall - Molar flow kmol/h
0.0000
Mass flow kg/h
0.0003
Temp C
0.0000
Pres atm
0.0000
Vapor mole fraction
0.0000
Enth MJ/h
0.00000
Tc C
74.1294
Pc atm
85.3944
Std. sp gr. wtr = 1
1.002
Std. sp gr. air = 1
0.929
Degree API
9.6662
Average mol wt
26.9095
Actual dens kg/m3
0.0000
Actual vol m3/h
-1.#IND
Std liq m3/h
0.0000
Std vap 0 C m3/h
0.0002
- - Liquid only - Molar flow kmol/h
0.0000
Mass flow kg/h
0.0003
Average mol wt
26.9095
Actual dens kg/m3
Actual vol m3/h
Std liq m3/h
0.0000
Std vap 0 C m3/h
0.0002
Cp J/kmol-K
Z factor
0.0000
Visc Pa-sec
1.000e-030
Th cond W/m-K
Surf tens N/m

Time: 11:11:47

6
Prod. interm

8
producto fin

11
Al destilado

0.0270
1.0000
0.0000
0.0000
0.0000
0.00000
267.3033
71.1640
0.879
1.279
29.3998
37.0395
0.0000
-1.#IND
0.0011
0.6051

0.0139
1.0000
0.0000
0.0000
0.0000
0.00000
341.8500
55.8599
1.059
2.488
2.1485
72.0640
0.0000
-1.#IND
0.0009
0.3110

0.0000
0.0000
0.0000
0.0000
0.0000
0.00000
0.0000
0.0000
0.000
0.000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

0.0270
1.0000
37.0395

0.0139
1.0000
72.0640

0.0011
0.6051

0.0009
0.3110

0.0000
1.000e-033

0.0000
1.000e-033

CHEMCAD 6.0.1

Page 7

Job Name: Untitled

STREAM PROPERTIES

Date: 12/18/2013

Stream No.
Name
- - Overall - Molar flow kmol/h
Mass flow kg/h
Temp C
Pres atm
Vapor mole fraction
Enth MJ/h
Tc C
Pc atm
Std. sp gr. wtr = 1
Std. sp gr. air = 1
Degree API
Average mol wt
Actual dens kg/m3
Actual vol m3/h
Std liq m3/h
Std vap 0 C m3/h
- - Liquid only - Molar flow kmol/h
Mass flow kg/h
Average mol wt
Actual dens kg/m3
Actual vol m3/h
Std liq m3/h
Std vap 0 C m3/h
Cp J/kmol-K
Z factor
Visc Pa-sec
Th cond W/m-K
Surf tens N/m

13
Acido acrili
693828.0000
50000002.2260
0.0000
0.0000
0.0000
0.00000
341.8500
55.8599
1.059
2.488
2.1485
72.0640
0.0000
-1.#IND
47225.6864
15551209.8226
693828.0000
50000002.2260
72.0640
47225.6864
15551209.8226
0.0000
1.000e-033

Time: 11:11:47
14
0.0000
0.0000
0.0000
0.0000
0.0000
0.00000
0.0000
0.0000
0.000
0.000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

CHEMCAD 6.0.1
Job Name: Untitled
FLOW SUMMARIES

Page 8
Date: 12/18/2013

Time: 11:11:47

Stream No.
Stream Name
Temp C
Pres atm
Enth MJ/h
Vapor mole fraction
Total kmol/h
Flowrates in kmol/h
Propylene
Oxygen
Water
Carbon Dioxide
Acrylic Acid
Acetic Acid
Acrolein

1
Propileno
25.0000
4.4016
0.00019015
1.0000
0.0000

2
Aire(Oxigeno
218.0000
4.0170
5.5864
1.0000
1.0000

3
Vapor
160.0000
6.0000
-0.0023779
1.0000
0.0000

4
mezcla
0.0000
0.0000
0.00000
0.00000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

0.0000
1.0000
0.0000
0.0000
0.0000
0.0000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

Stream No.
Stream Name
Temp C
Pres atm
Enth MJ/h
Vapor mole fraction
Total kmol/h
Flowrates in kmol/h
Propylene
Oxygen
Water
Carbon Dioxide
Acrylic Acid
Acetic Acid
Acrolein

5
Al incinerad
0.0000
0.0000
0.00000
0.00000
0.0000

6
Prod. interm
0.0000
0.0000
0.00000
0.00000
0.0270

8
producto fin
0.0000
0.0000
0.00000
0.00000
0.0139

11
Al destilado
0.0000
0.0000
0.00000
0.00000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

0.0000
0.0000
0.0135
0.0000
0.0000
0.0000
0.0135

0.0000
0.0000
0.0000
0.0000
0.0139
0.0000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

Stream No.
Stream Name
Temp C
Pres atm
Enth MJ/h
Vapor mole fraction
Total kmol/h
Flowrates in kmol/h
Propylene
Oxygen
Water
Carbon Dioxide
Acrylic Acid
Acetic Acid
Acrolein

13
Acido acrili
0.0000
0.0000
0.00000
0.00000
693828.0000

14
0.0000
0.0000
0.00000
0.00000
0.0000

0.0000
0.0000
0.0000
0.0000
693828.0000
0.0000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

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