Chemistry 112 Bama Name: Key ‘Show all of your work! € = €'~ (0.0591/n}logia) Volt~1/c, Amp ~C/sec, F=96485 C/mole e” R= 8.3141/K mole 41, Will the reaction will be spontaneous inthe forward or reverse direction? (+ AS ) (A) Na(g) + 2 Hale) > NoHa(!), —revecse 4 aad high T (8) MECo.(s) > MgO) + cone) _—fprw acd ‘3 ‘What isthe sign of AS universe when aliquid freezes? 2. Estimate the melting point of sodium chloride if ASpan = 28.1 1/K mole and AMgwon = 30.7 ki/mole. AG+=AhU~TAS pos > QK- TAS ome ALT aes as ete 3. Calculate AG* and Kat 100° forthe react GiHue) + HOU) —> HOH) the reaction spontaneous at 100°C? 3733.1. 8.26 “23%? “Wp eb = eg-b = (237.25 O¥.BLV> 24 Tyg 4 eT 8 -e Tine == Wes ViaM I We —A 4. For the reaction:_2 SOa(g] + Og) —> 2 SO,(g) Calculate AG*, Calculate AG at 25°Cwhen Pressures are PSO; = 100. atm, P 0; = 100. atm and PSO, = 1.0 atm, ¢ Benn ° 3 gou Pye T Ing Be ( oH ~(@b-sev 2) +8 nos Ke waar Boe “INNES (ode CN bbs ~1NIboo tea tase Inge aod 333 as 5. CaCO, decomposes spontneousy upon heating C30 and Os, (0) What the sgn or thes forthe reaction? oe (0) What isthe sgn ofthe a for hs reation? = (©) What isthe sgn ofthe 25 for this reaction? (0) Is this reaction more favorable at high or low temperature? _1y igh 6.23.6 grams of zine was plated out ofa solution of ZnCl, in 3.00 hour, how much current (Amps) were used? - 2 mee ~ | /Tb4RS SC > obbs[ Asean ae Es Vrae = Var boa SN 36005 wes 14.3 Aing half reactions: AI/AI* and cl, /cr- pris 7. Draw the cell diagram for the Galvanic cell based on the fob es Write the line diagram, Alon | AP [| Gz) cr [eres Calculate €. ca 13bY—-(-L.bbV\ © 3.02 8. (A) What can oxidize Hgbut not Br? _ NO. (8) What can reduce H* but not Ni"? Sn 9. A Galvanic cell consists cf Ag’/Ag and Cu/Cu solution. ‘What is the voltage if the [Ag’] = 3.0 Mand teteasan ge - -0S4m. ten Q te =) Z[Asé se- 5 ay\ > = + & Ox => Cy? yde7 -234V Bagh eos hy Ag £2 Hc 10. caelate and Go the ganic ci based onthe wp al esclow! 22 HAWS Ade” DDO hoy rors} (4% 3 yer, 9% 08 V 7 \.o0 V NEL CE” 2/96 485)( 1.000) ios Uy Balance the folowing reaction in acid. $,0;* (aq) + Cig) > $0,* (aq) + cF{aq) Sere 12. Matching: Unwanted redox reaction, {A) Not in summer schoo! Maximum available work (@) 446% Where reduction occurs (0) Corrosion ‘Thermodynamically unstable“ (0) Electrolysis (Great way to spend your summer AY (€) Cathode (F) Gibb’s Free Energy