103

H3-3 _____

4-5

___________

4 80
(
)1. H2CO3HCO3 (A) (B)
(C) (D)
B

(
)2. pH (A) 0.1 M HCl(aq) 50 mL + 0.1 M
NaOH(aq) 50 mL (B) 0.1 M CH3COOH(aq) 50 mL + 0.1 M NaOH(aq) 50 mL (C) 0.1 M CH3COOH(aq) 50 mL + 0.2 M
KOH(aq) 50 mL (D) 0.1 M HCl(aq) 50 mL + 0.05 M NH3(aq) 50 mL127 (E) 0.1 M H2SO4(aq) 50 mL + 0.01 M NaOH(aq)
50 mL
D
(A)
(B)
(C)
(D) CH3COOH CH3COOK
(D) NaHSO4

)3. (A) (B)

(C) pH (D)

)4. pH (A) 0.1 M NaOH 20 mL0.1 M CH3COOH 15 mL

(B) 0.1 M NaOH 20 mL0.1 M CH3COOH 10 mL (C) 0.1 M NaOH 15 mL0.1 M CH3COOH 20 mL (D) 0.1 M NaOH 20
mL0.1 M HNO3 15 mL
C

)5. (A) (B)

(C) pH (D)
C
(

(C)

)6. HA Ka3105 0.1 M 60 mL 0.3 M NaOH pH5 NaOH

(B) 15

(C) 30

(D) 60

B
[H]Ka

1053105

[HA]
[A]

0.1600.3 V
V15 mL
0.3 V

99 -
1

(A) 10

(
)7. pH9
5

(C)Ka7105

(A) NaHSKa21014 (B)Kb1.810

(D) Mg(OH)2Ksp7.11012

B
pH9pOH1495 Kb105
99 -

(
)8. (A) (B)
(C) pH (D)

(
)9. 80 0.10 M CH3COOH 40 0.10 M NaOH pH
CH3COOH Ka2.0105

(A) 7.7

(B) 6.7 (C) 5.7

(D) 4.7

D
pHpKa4.7

Ka
(
)10. HANaA Ka1104 pH 5.0
[HA]
[NaA]
C
HA

1
(A ) 1000

1
(B) 100

1
(C) 10

(D) 1

(E) 10

HA

[H][A]
[HA]
Ka [HA]
[H]Ka [A]
[HA]
pH5[H]11051104 [A]
[HA]
1
1
[A] 10 10
94-

)11. OH (A) 0.050 M HC2H3O2 0.20 M NaC2H3O2 (B) 0.050 M HCl

0.20 M NaCl (C) 0.050 M HC2H3O2 0.050 NaC2H3O2 (D) 0.10 M NH3 0.010 M NH4Cl (E) 0.10 M HC2H3O2
0.010 M NaC2H3O2

E
OH H(A)0.05 M(B)(C)0.05 M(D)
(E)0.1 M(E)

(
)12. (A) 1 M CH3COOH 1 1 M CH3COONa 1 (B) 2 M NH4OH 1 1 M HCl 1
CH3COONa 1 1 M HCl 1 (D) 1 M CH3COOH 1 1 M NaOH 1 (E) 1 M CH3COO NH4 1
D

(1)
(2)
(3)
(4)
2

(C) 2 M

(5)
(D) CH3COONa

)13. HA Ka2105 0.1 M 60 mL 0.1 M NaOH pH5 NaOH

10

(B) 20

(C) 40

(A)

(D) 80

C
0.1600.1V
1052105
V40mL
0.1V

)14. (A) 100 0.1 M HCl 100 0.1 M NaOH (B) 100 0.1 M HCl
50 0.1 M NH3 (C) 100 0.1 M NH4Cl 50 0.1 M NaOH (D) 100 0.1 M CH3COOH 200
0.1 M NaOH

(
)15. (A) (B)
(C)
(D) (E)

C
(A)(B)(C)
(D)(E)ExCH3COONH4

(
)16. (A) (B) H2CO3 HCO3
(C) (D) pH
D
(D) pH

)17. 0.1 M H2SO4(aq) 0.15 M NaOH(aq)[H +] = ( HSO4 Ka = 1.3 10

2

) (A) 0.05 M

(B) 0.025 M

(C) 1.3 10 2 M

(D) 7.2 10 3 M

(E) 1.3 10 4 M

D
H2SO4 NaOH 0.025 M HSO4
0.025 M SO42
HSO4
0.025 x

H+ +
x

SO42
0.025 + x

x(0.025+ x)
0.025 - x
3
x = 7.2 10 M

(
)18. pH9 (A)Kb1109 (B)Kb110
5
(C)Ka1105 (D)Ka1104
B
1.3 10 2 =

[A]
pHpKalog [HA] [A][HA]1 pHpKa
(B) pKb5 pKa9
3

)19. NH3 NH4Cl

(A) NH3 NH4Cl

(B) NH3 pH NH4 H OH (C) NH3 OH

NH4 H (D) NH3 H NH4 OH
D

)20. Ka2105 CH3COOH CH3COONa pH 5.0 0.1 M CH3COOH

300 mL 0.2 M NaOH mL

(A) 50

(B) 100

(C) 150

(D) 200

B
0.2 M NaOH x mL CH3COOH 300.2 xmmolCH3COONa 0.2 x mmol[H]Ka
2105

nHA
nA

105

300.2 x
0.2 x x100

4 20
1. 1 0.1 mol CH3COOH 0.1 mol CH3COONa CH3COOH Ka1.8105log2.20.34log14.7
1.7
(1) pH
(2) 0.01 mol HCl pH
(3) 0.01 mol NaOH pH
(1) 4.74(2) 4.66(3) 4.83
(1)
[CH3COOH]
0.1
[H]Ka [CH COO] 1.8105 0.1 1.8105
3

pH =log1.81054.74
(2) CH3COOH CH3COOH
0.1mol 0.01
0.01
0.01
0.01
0.09
0.01
0.09 mol 0.11 mol

0.110.1
[CH3COOH]
[H]Ka [CH COO] Ka 0.090.1 2.2105
3

pH log2.2105=4.66
(3) CH3COOHOH CH3COOH2O
0.1
0.01

0.01
0.01

0.01

0.09
0
0.01
0.09 mol 0.11 mol
[CH3COOH]
0.09
[H]= Ka [CH COO] 1.8105 0.11 1.14105
3

pH log1.471054.83

2. 100 mL 0.20 M CH3COOH pH5 NaOH Na23CH3COOH Ka

2105
0.53 g
4

 X mol
CH3COOHOH CH3COOH2O
0.02 mol
X
X
X
X
X
0.02X
X

CH3COOH(aq)
H(aq)CH3COO(aq)
0.02X
0.1 M

X
0.1

[CH3COOH]
[H]Ka [CH COO]
3

0.02X0.1
1052105
X0.1
X0.013 mol
0.01340=0.53 g

3. 4.1 g CH3COONa 90 30ww10 mL 1.00 CH3COOH 1 L

pH C12.0H1.0Na23.0O16.0CH3COOH
CH3COOH Ka104.76 M
1.74 105 M
4.71
[CH3COO]
4.10.9821
pHpKalog [CH COOH] 4.76log 100.3601 4.76log0.94.71
3