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Nuan. 25/4 pojey,. This booklet contains 24 printed pages PAPER - 1 : PHYSICS, CHEMISTRY & MATHEMATICS ‘Test Booklet Code Do not open this Test Booklet until you are asked to do so. Read carefully the Instructions on the Back Cover of this Test Booklet, Important Instructions : 1. Immediately fill in the particulars on this page of the Test Booklet with Blue/Black Ball Polnt Pen Use of pencil is strictly prohibited. 2. The Answer’Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take out the Answer Sheet and fill in the particulars carefully, 3. The test is of 3 hours duration. The Test Booklet consists of 90 questions. The maximum marks are 360. 5. There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics having 30 questions in each part of equal weightage. Each question. is allotted 4 (four) marks for each correct response, © Cantidates wil be aoarded marks as stated above in instruction No.5 for correct response ofeach question. Plone fourth) marks willbe deducted for indicating incorrect response ofeach question. No deduction from the total score will be made if no response is indicated for an item in the answer sheet. 7. There is only one correct response for each question. Filling up more than one response in each question will be treated as wrong response and marks for wrong response will be deducted accordingly as per instruction 6 above. 8. Use Blue/Black Ball Point Pen only for writing particulars/marking responses on Side-1 and Side-2 of the Answer Sheet. Use of pencil is strictly prohibited. 9. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone, any electronic device, etc., except the Admit Card inside the examination hall/room. 10. Rough work is to be done on the space provided for this purpose in the Test Booklet only. This Space is given at the bottom of each page and in 3 pages (Pages 21 - 23) at the end of the booklet 11. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them. 12. The CODE for this Booklet is A. Make sure that the CODE printed on Side-2 of the Answer Sheet is the same as that on this booklet. In case of discrepancy, the candidate should immediately report the matter to the Invigilator for replacement of both the Test Booklet and the Answer Sheet, 13. Do not fold or make any stray marks on the Answer Sheet, Examination Centre Number: Name of Examination Centre (in Capitalletters):— Candidate's Signature: Invigilator’s Signature : SEAL PART A — PHysIcs 1. Two electric bulbs marked 25W-220V. and 100W-220V are connected in series to a 440V supply. Which of the bulbs will fuse ? (1) 100w. 2) 25w (3) neither (4) both 2. A boy can throw a stone up to a maximum, height of 10 m. The maximum horizontal distance that the boy can throw the same stone up to will be : (10m (2) 10VZ2 m Q) 20m 4) 202 m Truth table for system of four NAND gates as shown in figure is : ay =! 4) o]o] 5 m1 om] ol oy a1] ofl. 1 @) HH] olof> alo} a} oc] asl of ofe} a}. 0 8) rH} 4] of of >. HL} me} of oy ual @ rH] oof y| Ho] Hlole of} H] a} A/Page2 ‘SPACEFOR ROUGH WORK 4. This question has Statement 1 and | 5. In Young's double slit experiment, one of Statement 2. Of the four choices given after the slit is wider than other, so that the the Statements, choose the one that best amplitude of the light from one slit is describes the two Statements, double of that from other slit. If Ty be the ‘maximum intensity, the resultant intensity Twhen they interfere at phase difference 6 is given by : a ‘o (+2008?) Statement 1 : Davisson - Germer experiment established the wave nature of 2) Im Ct4cos?® ) electrons, 5 2 |, 2 *™ (148c0s (3) 9 @ By) Statement 2: If electrons have wave L nature, they can interfere and show (4) “445 cos6) diffraction, 6. If a simple pendulum has significant (1) Statement 1 is true, Statement 2 is amplitude (up toa factor of 1/¢ of original) false only in the period between t=0s to t=1s, then + may be called the average life of the Pendulum. When the spherical bob of the 2) Stolament 1 ts rue, Sttement 2 i pendulum suffers a retardation (due to ement : ; true, Statement 2 is the correct Viscous drag) proportional to its velocity, eee with ‘b’ as the constant of proportionality, i the average life time of the pendulum is (assuming damping is small) in seconds : (3) Statement 1 is true, Statement 2 is Ore ‘ true, Statement 2 is not the correct 1 explanation of Statement 1 ) 5 2 ORs (Statement 1 is false, Statement 2 is — true. o A/Page3 ‘SPACE FOR ROUGH WORK 7. This question has Statement 1 and Statement 2, Of the four choices given after the Statements, choose the one that best describes the two Statements. If two springs S, and S, of force constants k, and ky, respectively, are streched by the same force, it is found that more work is done on spring $, than on spring S,. Statement 1 : If stretched by the same amount, work done on S,, will be more than that on S, Statement 2: k, tp Q) t= a> Tp (4) 27SYaAT (4) A/Paged ‘SPACEFOR ROUGH WORK, 28. A charge Q is uniformly distributed over | 29. An electromagnetic wave in vacuum has the surface of non- conducting disc of Pee pieninmh Paice ee the electric and magnetic fields E and B, radius R. The disc rotates about an axis . i which are always perpendicular to each perpendicular to its plane and passing : rae a other. The direction of polarization is through its centre with an angular velocity : ©. Asa result of this rotation a magnetic given by X and that of wave propagation field of induction B is obtained at the centre by &. Then of the disc. If we keep both the amount of charge placed on the disc and its angular ae . velocity to be constant and vary the radius (1) XE and k|ExB of the disc then the variation of the ‘magnetic induction at the centre of the dise 2) XB and KIExs will be represented by the figure : @) X|[E and KBE @) ] o12 4 (4) X |B and KI|Bxé a ' 30. A Carnot engine, whose efficiency is 40%, (2) ss takes in heat from a source maintained at a temperature of 500 K. It is desired to — a have an engine of efficiency 60%. Then, the intake temperature for the same exhaust (sink) temperature must be t 3) B (1) 1200 K Ro 2) 750K (3) 600K @ I (4) _ efficiency of Carnot engine cannot I bbe made larger than 50% ‘A/Page 10 SPACEFOR ROUGH WORK PART B — CHEMISTRY 35. The incorrect expression among the 31, 2 - Hexyne gives trans - 2 - Hexene on following is treatment with (1) _ In isothermal process, (1) Li/NH, Vv; iB Wpnersthe = ART ING, (2) Pd/BaSO, i (3) LiAIHy ») awk BETAS" (4) PH, Qe 32. Which of the following on thermal- ®) decomposition yields a basic as well as an acidic oxide ? @) (@) KCIO; (2), cages. 36. Which branched chain isomer of the (3) NH,NO3 hydrocarbon with molecular mass 72u (4) NaNO, gives only one isomer of mono substituted alkyl halide ? 33. Which one of the following, statements is A (1) Neopentane (1) All amino acids are optically active. (2) Isohexane (2) All amino acids except glycine are (3) Neohexane optically active. ny per ueees 3) _Allamino acids except glutamic acid — 37. According to Freundlich adsorption (4) All amino acids except lysine are isotherm, which of the following is optically active. ae 34, The density of a solution prepared by i dissolving 120 g of urea (mol. mass =60 u) m in 1000 g of water is 1.15 g/mL. The x ayn molarity of this solution is : Qn? ' () 178M : @ Zep (2) 102M m (3) 205M (4) Allthe above are correct for different (4) 050M ranges of pressure. A/Page 11 ‘SPACE FOR ROUGH WORK 38. In which of the following pairs the two | 43. In the given transformation, which of species are not isostructural ? the following is the most appropriate (2) PCI,* and Sicl, reagent ? 2) PR, and BrF, CH=CHCOCH, (@) AIFS and SF, Ly Reagent (4) CO,?> and NO,~ BY : CH= CHCH,CH, 39. How many chiral compounds are se) possible on monochlorination of 2~ methyl Ho: butane ? (1) Zn-Hg/Hict @ 2 (2) Na, Lig. NH; @) 4 @) 6 (@) NaBH, @) 8 (NH, NH, 6H 40. The ing order of the ionic radii of ay aoe ea eis (OA) ache oh body centred cubic A ee Cle, cat a . structure. The length of the side of its unit 0 eek aaa cellis351 pm. Atomic radius of the lithium @ Gt, Kar, § perp @) K*,8?>, cad, cl (4) C1, Ca2*, Kt, g2- (1) 300 pm 2) 240 pm 41. The compressibility factor for a real gas at high pressure is : ©). 152 pm qi (4) 75 pm (2) 1+pb/RT (@) 1-pbyrt 45. K; for water is 1.86 K kg mol~. If your (@) 14Rtyp automobile radiator holds 1.0 kg of water, ie how many grams of ethylene glycol 42. Which among the following will be named (CH.O,) must ybu add to get the freezing as dibromidobis(ethylene diamine) Point of the solution lowered to -2.8°C ? chromium ({I1) bromide ? @) 3% (1) [Cr (en), Bry] Br 0) %% 2) [Cr (en) Br) @) [Cr (en) Brg] Br eae (4) [Cr (en)] Bry @ 725 A/Page 12 SPACE FOR ROUGH WORK 46. The molecule having smallest bond angle | 51. Which of the following compounds can be is: detected by Molisch’s test ? (Ql) AsCl, (1) Sugars (2) SbCl, (2) Amines @) PCh (@) Primary alcohols (4) NCI, (4) Nitro compounds 47. What is DDT among the following : 52. The standard reduction potentials for ()) A fertilizer Zn?* /Zn, Ni?*/Ni, and Fe?* /Fe are i peeetiele pala 0,76, -0.23 and -0.44 V respectively. ‘The reaction X+Y?*-X?* +Y will be (3) Non - biodegradable pollutant cious (2)) Greenhouse’ eas, (1) X=Ni, Y=Zn | 48, ‘The pH of a 0.1 molar solution of the acid Q) X=Fe, Y=Zn | HQ is 3. The value of the ionization (3) X=Zn, Y=Ni | constant, Ka of this acid is : (4) X=Ni, Y=Fe OR 53. Ortho - Nitrophenolis less soluble in water (2) 1x1078 than p - and m - Nitrophenols because : @) 1x1077 (1) 0 = Nitrophenol shows (4) 310-7 Intramolecular H - bonding || 49. Very pure hydrogen (999%) can be made @ masa scares ee by which of the following processes ? ete tens (1) Mixing natural hydrocarbons of high molecular weight lower than those of m ~ and | p- isomers. (2))7 Blactrolvase ce watee (4) 0 - Nitrophenol is more volatile in | (8) Reaction of salt like hydrides with ee eee ad | water p~ teenie. | (4) Reaction of methane with steam | 54, Todoform can be prepared from all 50. Aspirin is known as : except : i (1) Phenyl salicylate (1) _ Isopropyl alcohol (2) Acetyl salicylate (2) 3~ Methyl - 2 - butanone (3) Methyl salicylic acid 3) Isobutyl alcohol (4) Acetyl salicylic acid (4) Ethyl methyl ketone ‘A/Page13 ‘SPACE FOR ROUGH WORK 55. The species which can best serve as | 59. Iron exhibits +2 and +3 oxidation states. an initiator for the cationic polymerization Which of the following statements about is iron is incorrect ? (1) HNO, @) Aicl (1) Ferrous compounds are relatively ey) bare ‘more ionic than the corresponding AIK, ferric compounds. 56. The equilibrium constant (K,) for the (2) Ferrous compounds are less volatile reaction N,(g)+O,(g)->2NO(g) at than the corresponding ferric temperature T is 4x 10-4, The value of K, compounds. forthe ice een nae eee) @) Ferrous compounds are more easily ogee beanperatare in hydrolysed than the corresponding, @) 28x10 ferric compounds. (2) 4x1074 (@) 50.0 (4) Ferrous oxide is more basic in nature (4) 0.02 than the ferric oxide. 57. For a first order reaction, (A)-sproducts, the concentration of A changes from | go rpg electrons identified by quantum 0.1 M to 0.025 M in 40 minutes. ‘The rate fae eer of reaction when the concentration of A is O.01M, is : (a) n=4,1=1 (1) 3.47x10-* M/min Q) 347x107 M/min ©) n=4 1-0 (3) 1.73%10~4 M/min () n=3,1=2 (4) 1.73x10-5 M/min ane. @) n=3,1=1 58. Which method of purification is represented by the following equation : can be placed in érder of increasing energy Ti @)+21p(g) BK , Ty 14(g) OK, as: Ti @)}#2In(g) ® @<®

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