No

1
2
3
4
5
6
7
8
9
10

Blangko
Kons
Abs
(mg/L)
0.003
0.0042
0.002
0.0033
0.002
0.0033
0.001
0.0025
0.002
0.0033
0.001
0.0025
0.002
0.0033
0.002
0.0033
0.002
0.0033
0.001
0.0025
St dev
LoD
LoQ
MDL
10 MDL
RSD
s/n
baku mutu (mg/L)

Blangko + Std
Kons
Abs
(mg/L)
0.016
0.0157
0.012
0.0121
0.015
0.0148
0.014
0.0139
0.012
0.0121
0.014
0.0139
0.015
0.0148
0.013
0.0130
0.012
0.0121
0.011
0.0113
0.0014
0.0177
0.0278
0.0045
0.0455
0.1083
9.2315
0.3

Kons Std
%R
yang
(mg/L)
115.0
0.0100
114.33
88.0
0.0100
87.94
115.0
0.0100
114.33
114.0
0.0100
114.33
88.0
0.0100
87.94
114.0
0.0100
114.33
115.0
0.0100
114.33
97.0
0.0100
96.74
88.0
0.0100
87.94
88.0
0.0100
87.94
Acceptance Criteria:
Jml
-RSD < HORWITZ
Rata
- s/n (average/SD) = 2,5 - 10
-%R = 80 - 120
- MDL < spike < 10 MDL
st dev
- MDL < Baku mutu
s/n

0.0157
0.0121
0.0148
0.0139
0.0121
0.0139
0.0148
0.0130
0.0121
0.0113
0.1337
0.01337

x-x^
0.0023
-0.0013
0.0014
0.0005
-0.0013
0.0005
0.0014
-0.0004
-0.0013
-0.0021

MDL
0.0014663 10 MDL
LoD
9.1182643 LoQ
RSD

(x-X^)2
5.29E-06
0.00000169
0.00000196
2.5E-07
0.00000169
2.5E-07
0.00000196
1.6E-07
0.00000169
4.41E-06
0.00001935

0.0041
0.0414
0.0178
0.0280
0.110

Repeatbility dan Reproducibility

Repeatbility dan Reproducibility pada konsentrasi 0,4 mg/L
No
Abs
Kons
Rerata
%RPD
%R
1 0.457 0.4035 0.4008
0.01
99.79
0.451 0.3982
2 0.452 0.3991 0.3978
0.01
99.02
0.449 0.3964
3 0.454 0.4008 0.4030
0.01
100.33
0.459 0.4052
4 0.452 0.3991 0.4017
0.01
100.01
0.458 0.4044
5 0.450 0.3973 0.3964
0.00
98.69
0.448 0.3956
6 0.452 0.3991 0.3978
0.01
99.02
0.449 0.3964
7 0.454 0.4008 0.4030
0.01
100.33
0.459 0.4052
Rerata
0.4001
SD
0.0033
%RSD
0.8353
2/3 CV Horwitz
1.53
8.2
CV Horwitz
12.3

ntrasi 0,4 mg/L

Repeatabilitas
0,5 CVHorwitz(21-0,5logC)
1.148
0,5 CVHorwitz(21-0,5logC)
1.149
0,5 CVHorwitz(21-0,5logC)
1.147
0,5 CVHorwitz(21-0,5logC)
1.147
0,5 CVHorwitz(21-0,5logC)
1.149
0,5 CVHorwitz(21-0,5logC)
1.149
0,5 CVHorwitz(21-0,5logC)
1.147

0.40085

100.2125

0.3978

99.4375

0.4030

100.75

0.4018

100.4375

0.3965

99.1125

0.39775

99.4375

0.4030

100.75

Acceptance Criteria = %RSD =< 2/3 CV Horwitz

sd
Rata
%RSD

Jml
Rata
0.0033
0.4001
0.83512601

0.4035
0.3982
0.3991
0.3964
0.4008
0.4052
0.3991
0.4044
0.3973
0.3956
0.3991
0.3964
0.4008
0.4052
5.6011
0.4000786

0.003421
-0.001879
-0.000979
-0.003679
0.000721
0.005121
-0.000979
0.004321
-0.002779
-0.004479
-0.000979
-0.003679
0.000721
0.005121

sd =
%RSDc =

1.17032E-05
3.53064E-06
9.58441E-07
1.3535E-05
5.19841E-07
2.62246E-05
9.58441E-07
1.8671E-05
7.72284E-06
2.00614E-05
9.58441E-07
1.3535E-05
5.19841E-07
2.62246E-05
0.000145124
0.00334116
0.835126021