THI TH I HC CAO NG

S 1
(Thi gian lm bi: 90 pht)
Cu 1: Phn ng no sau y khng to ra hn hp hai mui?
A. CO2 + NaOH (d)
B. NO2 + NaOH (d)
C. Fe3O4 + HCl (d)
D. Ca(HCO3)2 + NaOH (d)
Cu 2: Cho hn hp X gm hai kim loi kim tan ht trong 200 ml dung dch cha BaCl2 0,3M v
Ba(HCO3)2 0,8M thu c 2,8 lt kh H2 (ktc) v m gam kt ta. Gi tr ca m l
A. 43,34
B. 49,25
C. 31,52
D. 39,4
Cu 3: Cho 6,4 gam hn hp CuO v Fe2O3 tc dng va vi 100 ml dung dch HCl thu c hai
mui c t l mol l 1 : 1. Nng mol ca dung dch HCl dng l
A. 1M
B. 2M
C. 3M
D. 4M
Cu 4: nhn bit cc kh: CO2, SO2, H2S, NH3, cn dng cc dung dch
A. nc brom v dung dch NaOH
B. dung dch NaOH v dung dch Ca(OH)2
C. dung dch KMnO4 v dung dch NaOH
D. nc brom v dung dch Ca(OH)2
Cu 5: Cho 3,76 gam hn hp X gm Mg v MgO c t l mol tng ng l 14:1 tc dng ht vi dung
dch HNO3 th thu c 0,448 lt mt kh duy nht ( ktc) v dung dch Y. C cn cn thn dung dch Y
thu c 23 gam cht rn khan T. S mol HNO3 phn ng l
A. 0,28
B. 0,36
C. 0,32
D. 0,34
Cu 6: C 4 l ha cht b mt nhn ng ring bit trong 4 dung dch khng mu sau y: NH4Cl,
NaCl, BaCl2 v Na2CO3. C th s dng thuc th no sau y phn bit cc dung dch trn?
A. HCl
B. H2SO4
C. NaOH
D. qu tm
Cu 7: Nhit si ca ancol etylic (I), anehit axetic (II), axit axetic (III) v axit propionic (IV) sp
xp theo th t gim dn l
A. (I) > (II) > (III) > (IV)
B. (IV) > (III) > (I) > (II)
C. (II) > (III) > (I) > (IV)
D. (IV) > (I) > (III) > (II)
Cu 8: Cho s sau: X ancol A bc 2 Y ancol B bc 3. Bit rng X c cng thc phn t C5H10
v A, Y, B u l cc sn phm chnh. Vy cng thc cu to ca X l
A. CH2=C(CH3)CH2CH3 B. CH3CH=CHCH2CH3
C. CH3C(CH3)=CHCH3
D. CH3CH(CH3)CH=CH2
Cu 9: Hy cho bit nhng cht no trong s cc cht: FeSO4 (I); SO2 (II); KI (III); CO2 (IV), cht no
c th lm mt mu dung dch thuc tm trong mi trng axit?
A. (I), (II), (III)
B. (II), (III), (IV)
C. (I), (II)
D. (I), (II), (III), (IV)
Cu 10: Cho cc dung dch mui: NaCl, FeSO4, KHCO3, NH4Cl, K2S, Al2(SO4)3, Ba(NO3)2. Khng nh
no sau y l ng?
A. c 4 dung dch lm qu tm ha
B. c 3 dung dch lm qu tm ha xanh
C. c 3 dung dch lm qu tm ha
D. c 4 dung dch khng lm i mu qu tm
Cu 11: t chy hon ton 3,02 gam mui natri ca 2 axit ankanoic lin tip, thu c Na2CO3, H2O
v 0,085 mol CO2. Cng thc ca 2 mui l
A. HCOONa v CH3COONa
B. C2H5COONa v C3H7COONa
C. C3H7COONa v C4H9COONa
D. CH3COONa v C2H5COONa

Cu 12: Nguyn t X trng thi c bn c cu hnh electron phn lp ngoi cng l 3p4. iu no
sau y khng ng khi ni v nguyn t X?
A. Lp ngoi cng ca nguyn t X c 6 electron B. Ht nhn nguyn t X c 16 proton
C. X nhm IVA trong bng tun hon
D. X thuc chu k 3 ca bng tun hon
Cu 13: C bao nhiu ng phn cu to, mch h, c cng thc phn t C5H8 tc dng vi H2 (xc
tc thch hp) thu c sn phm l isopentan?
A. 4
B. 2
C. 6
D. 3
Cu 14: Cho 0,06 mol Fe phn ng vi O2 un nng, thu c hn hp cht rn X. Ha tan X trong
dung dch HNO3 long d, thu c dung dch Y v 0,02 mol kh NO. S mol O2 phn ng l
A. 0,03
B. 0,04
C. 0,05
D. 0,06
Cu 15: Cho hn hp Cu v Fe vo dung dch HNO3 long, n khi phn ng xy ra hon ton thu
c dung dch X v cht rn Y. Cht rn Y tc dng vi dung dch HCl thy c hin tng si bt kh.
Cho dung dch NaOH vo dung dch X thu c kt ta Z. Kt ta Z l
A. Fe(OH)3 v Cu(OH)2 B. Fe(OH)2
C. Cu(OH)2
D. Fe(OH)2 v Cu(OH)2
Cu 16: Chn pht biu ng
A. Ancol a chc ha tan Cu(OH)2 to dung dch xanh lam.
B. Phng php chung iu ch ancol no, n chc, bc 1 l cho anken hp nc.
C. un nng ancol metylic vi H2SO4 c 170oC thu c ete.
D. Khi oxi ha ancol no, n chc th thu c anehit.
Cu 17: Cho 14,5 gam andehit A tc dng vi dung dch AgNO3/NH3 thu c 108 gam Ag. A c cng
thc l
A. CH3CHO
B. (CHO)2
C. HCHO
D. C2H5CHO
Cu 18: in phn 2 lt dung dch CuSO4 (vi in cc tr) n khi kh thot ra c hai in cc u
bng 0,02 mol th dng li. Dung dch sau in phn c pH bng
A. 1,0
B. 1,7
C. 2,0
D. 2,3
Cu 19: Pht biu no sau y khng ng?
A. Phenol l cht rn, tinh th khng mu, c mi c trng.
B. lu ngoi khng kh, phenol b oxi ha mt phn nn c mu hng.
C. Phenol d tan trong nc lnh.
D. Phenol rt c, d gy bng nng i vi da.
Cu 20: Mt hidrocacbon X c cng thc n gin l (CH)n (n < 7). Cho 0,01 mol X tc dng vi dung
dch AgNO3 trong NH3 thu c 2,92 gam kt ta. Vy
A. c 2 cng thc cu to tha mn vi X
B. c 3 cng thc cu to tha mn vi X
C. c 2 cng thc phn t tng ng vi X
D. cng thc phn t ca X l C2H2
Cu 21: Hn hp X gm hai axit cacboxylic. trung ha ht m gam X cn 400 ml dung dch NaOH
1,25M. t chy hon ton m gam X thu c 11,2 lt kh CO2 (ktc). Cng thc cu to thu gn ca 2
axit trn l
A. HCOOH v CH3COOH
B. HCOOH v HOOC-COOH
C. CH3COOH v HOOC-CH2-COOH
D. CH3COOH v HOOC-COOH
Cu 22: Hp cht X ch cha loi chc andehit. Khi t chy hon ton X bng O2 thy t l s mol O2
phn ng so vi s mol CO2 v hi nc to thnh tng ng l 9 : 8 : 6. Nhn xt no sau y v X l
hp l?
A. X l anehit 2 chc, no, mch h.
2

B. X l anehit n chc, mch h, c 1 lin kt i C=C.

C. X l ankanal.
D. X l anehit 2 chc, mch h, c 1 lin kt i C=C.
Cu 23: Chn nhn xt ng
A. Khi thay i bt k 1 trong 3 yu t: p sut, nhit hay nng ca mt h cn bng ha
hc th h s chuyn dch sang mt trng thi cn bng mi.

N2O4 khng mu . Nu ngm bnh trn vo nc

B. Trong bnh kn tn ti cn bng 2NO2 nu

thy mu nu trong bnh nht dn. iu chng t chiu nghch ca phn ng l chiu thu nhit.

2SO3 trng thi cn bng. Thm SO2 vo ,

C. Trong bnh kn, phn ng 2SO2 O2

trng thi cn bng mi, ch c SO3 l c nng cao hn so vi trng thi cn bng c.

2NH3 s tng ln.

D. Khi thm cht xc tc, hiu sut phn ng tng hp NH3: N2 3H2

Cu 24: Cho cc nhn xt sau

(1) Sc ozon vo dung dch KI s thu c dung dch c kh nng lm h tinh bt ha xanh.
(2) Hidropeoxit v hidrosunfua c th lm mt mu dung dch thuc tm trong mi trng H2SO4
long.
(3) Sc kh hidrosunfua vo dung dch FeCl3 s thy xut hin kt ta mu vng.
(4) Dung dch H2S lu trong khng kh s c vn c mu vng.
(5) Hidropeoxit l cht kh mnh v khng c tnh oxi ha.
Cc nhn xt ng l
A. (1), (3), (4)
B. (1), (2), (4), (5)
C. (1), (2), (3), (4)
D. (2), (4), (5)
Cu 25: Cho 11 gam dung dch NaOH 20% vo 5 gam dung dch axit H3PO4 39,2%. Mui thu c
trong dung dch l
A. NaH2PO4
B. Na3PO4 v NaH2PO4 C. Na2HPO4 v NaH2PO4 D. Na3PO4 v Na2HPO4
Cu 26: Cho hn hp gm khng kh d v hi ca 24 gam metanol i qua cht xc tc Cu nung nng,
sn phm thu c c th to 40 ml dung dch fomalin 38% (d = 1,1g/ml). Hiu sut ca phn ng oxi
ha metanol l
A. 80,4%
B. 74,3%
C. 65,5%
D. 76,6%
Cu 27: in phn nng chy a gam mui halogenua ca kim loi M, thu c 0,96 gam kim loi
catot v 0,896 lt kh (ktc) anot. Mt khc, dung dch cha a gam mui halogenua ni trn tc dng
vi AgNO3 d thu c 11,48 gam kt ta. Cng thc mui halogenua l
A. CaCl2
B. MgCl2
C. CaBr2
D. MgBr2
Cu 28: Hn hp X gm FeO, Fe2O3, Fe3O4 nng 6,96 gam v s mol FeO bng s mol Fe2O3. Cho hn
hp X tan ht trong dung dch HNO3 long, thu c V lt kh NO (ktc) duy nht. Gi tr ca V l
A. 0,224/3 lt
B. 0,224 lt
C. 2,24 lt
D. 2,24/3 lt
Cu 29: Nung nng AgNO3 c cht rn X v kh Y. Dn kh Y vo cc nc c dung dch Z. Cho
ton b X vo Z thy X tan mt phn v thot ra kh NO duy nht. Gi thit cc phn ng xy ra hon
ton. Phn trm khi lng ca X khng tan trong Z l
A. 20%
B. 25%
C. 30%
D. 40%
Cu 30: Cho 0,81 gam Al v 2,8 gam Fe tc dng vi 200 ml dung dch X cha AgNO3 v Cu(NO3)2.
Sau khi cc phn ng xy ra hon ton thu c dung dch Y v 8,12 gam hn hp 3 kim loi. Cho hn
hp kim loi ny tc dng vi dung dch HCl d, kt thc phn ng thy thot ra 0,672 lt kh H2
(ktc). Nng mol/l ca AgNO3 v Cu(NO3)2 ln lt l
A. 0,15M v 0,25M
B. 0,10M v 0,20M
C. 0,25M v 0,15M
D. 0,25M v 0,25M
3

Cu 31: Cho 5,7 gam hn hp bt X gm Mg, Al, Zn tc dng hon ton vi oxi d thu c hn hp
rn Y c khi lng l 7,86 gam. Th tch dung dch HCl 1M ti thiu cn dng ha tan hn hp X l
A. 180 ml
B. 270 ml
C. 300 ml
D. 360 ml
Cu 32: Cho cc cht: FeCO3, Fe(NO3)2, Fe2(SO4)3, FeSO4, FeS, FeS2, CuS. S lng cht c th c kh
thot ra khi cho vo dung dch HCl v un nng nh l
A. 7
B. 4
C. 5
D. 6
Cu 33: C cc dung dch ring r sau: AlCl3, NaCl, MgCl2 v H2SO4. Ch dng thm mt thuc th no
sau y phn bit c 4 dung dch trn
A. NaOH
B. qu tm
C. AgNO3
D. BaCl2
Cu 34: Hp cht X cha C, H, O, trong phn t c cha mt nhm anehit. Cho 0,52 gam cht X
phn ng vi dung dch AgNO3 trong NH3 thu c 1,08 gam Ag. Mt khc, 3,12 gam cht X phn ng
ht vi Na gii phng 672 ml kh H2 (ktc). S hp cht X tha mn cc tnh cht trn l
A. 3
B. 4
C. 5
D. 6
Cu 35: Cho phn ng sau: FeS2 + HNO3 + HCl FeCl3 + H2SO4 + NO + H2O. Vi h s cc cht
trong phng trnh l cc s nguyn n gin nht khng gin c cho nhau. Tng i s cc h s ca
chng l
A. 20
B. 19
C. 22
D. 15
Cu 36: Cho cc cht tc dng vi nhau tng i mt, trong iu kin thch hp
(1) Mg + CO2
(2) Mg + SO2
(3) Mg + Si
(4) Si + NaOH + H2O
(5) F2 + H2O
(6) CuS + HCl
(7) BaCl2 + NaHSO4
(8) NaHSO4 + NaHCO3
S cp xy ra phn ng l
A. 8
B. 5
C. 7
D. 4
Cu 37: Cho dy cc phn t sau: C4H10O, C4H9Cl, C4H11N, C4H8. Cht c s lng ng phn ln nht
l
A. C4H10O
B. C4H9Cl
C. C4H11N
D. C4H8
Cu 38: T Al4C3, cn ti thiu bao nhiu phn ng iu ch cao su Buna?
A. 5
B. 3
C. 4
D. 6
Cu 39: Khi un nng mi cht: benzen, toluen, stiren, cumen vi dung dch KMnO4 th s phn ng
ha hc xy ra l
A. 1
B. 2
C. 3
D. 4
Cu 40: Cho dung dch AgNO3 tc dng vi dung dch cha cht X thy to kt ta T mu vng. Cho
kt ta T tc dng vi dung dch HNO3 d thy kt ta tan. Cht X l
A. KI
B. KCl
C. KBr
D. K3PO4
Cu 41: Cho cc n cht: Al, Zn, Cl2, Br2, Si. S cht tc dng c vi dung dch NaOH l
A. 2
B. 5
C. 3
D. 4
Cu 42: Cho 3 gam hn hp X gm Fe3O4 v Cu vo dung dch HCl d. Sau khi cc phn ng xy ra
hon ton thy cn li 0,04 gam cht rn khng tan. Phn trm khi lng ca Cu trong hn hp X l
A. 13,33%
B. 22,67%
C. 77,33%
D. 98,67%
4

Cu 43: t chy hon ton hn hp X gm nhng lng bng nhau v s mol ca FeS2 v Ag2S thu
c hn hp cht rn Y v kh SO2. Ton b lng kh SO2 lm mt mu va ht 300 ml dung dch
KMnO4 0,2M. Tnh khi lng ca hn hp Y
A. 15,6 gam
B. 15,2 gam
C. 14,8 gam
D. 13,6 gam
Cu 44: Cho cc phn ng sau
(1) MnO2 + HCl
(3) KClO3 + HCl
Cc phn ng c th to ra kh Cl2 l
A. (1) v (2)
B. (1) v (3)

(2) KMnO4 + HCl

(4) NaClO + HCl
C. (1), (2), v (3)

D. (1), (2), (3) v (4)

Cu 45: C mt dung dch hn hp gm Al(NO3)3, Cu(NO3)2, AgNO3 v Zn(NO3)2. Thm lng d dung
dch NH3 vo dung dch th kt ta to ra l
A. Al(OH)3
B. Ag2O v Al(OH)3
C. Zn(OH)2
D. Ag2O, Zn(OH)2 v Al(OH)3
Cu 46: tch v gi nguyn c lng bc kim loi trong hn hp gm Fe, Cu v Ag c th dng
mt ha cht l
A. HNO3
B. NaHCO3
C. Fe(NO3)3
D. HCl
Cu 47: Cho axit HCl tc dng vi dung dch CaCO3 iu ch kh CO2. Kh CO2 sinh ra c ln kh
hidroclorua. Cht c th dng lm sch kh CO2 m khng lm thay i lng kh CO2 l
A. dung dch NaOH
B. dung dch NaHCO3
C. dung dch nc vi
D. dung dch AgNO3
Cu 48: Cho hn hp X gm 1 anken v H2, trong H2 chim 60% th tch. Dn X qua ng s cha
Ni un nng, thu c hn hp Y. t chy hon ton hn hp Y v hp th sn phm chy vo bnh
ng nc vi trong d, trong bnh to ra 4 gam kt ta, v khi lng dung dch gim 0,98 gam.
Cng thc anken X v th tch dung dch X (ktc) l
A. C2H4 v 3,36 lt
B. C3H6 v 2,24 lt
C. C2H4 v 1,12 lt
D. C3H6 v 3,36 lt
Cu 49: Cho s sau:
xt
X H2
X1 ancol
to
xt
X O2
X2 axit cacboxylic
to
xt
X1 X2
C6H10O2 H2O
to

Cng thc cu to ca X l
A. CH3CH2CHO
B. CH2=CHCHO

C. CH2=C(CH3)CHO

D. CH3CHO

Cu 50: Hp cht X c khi lng mol phn t bng 74, t chy hon ton X ch thu c CO2 v
H2O. S cng thc phn t c th c ca X l
A. 1
B. 2
C. 3
D. 4
===HT===