1 Chemistry 249 ~ F2014 Quantitative Analysis Exam #1 extra eredit AOL 10 oo! 5 rat ‘ YourName:_flacison _ \ich =e Section_‘e" 1.(G points). What is the correct answer with correct number of significant figures to the following. calculation? 2 (2.667x10° + 45.0) + 1.240 x 10° 1. % x IC a. Ixl0® c. 1360x10 b. 1.4x107 (@)1- 36x10" 2. (6 points). An ore sample contains 3.674g of gold and has a relative uncertainty of 1.4 parts per thousand. What is the absolute uncertainty? (1g ~10°mg) Ww a. 51g @)5mg b. 50mg 4. 0.4 mg data point will have a value greater than 48.77? a. 45% © 225% b. 47.75% d. 50% 4, (12 points). Given the following information for the weak acid H2A: 42 HA gy HA + Hays PK, = 3.00 2 HAjy 2 AG, +Higs PK a = 9.00 ! a Give the correct balanced chemical reaction and equilibrium expression (include the correct value for — K,) for when the base A® is added to pure water. Only consider the first association reaction. vob A +H20.@ HA +OH so [A*]/ [OH][HA]= Ix 10° 2 HA + OH © A*+H20 so [A*Y [OH THA] = Lx 10° ©) at +H20 OHA'+OH so {(OH][HAJ}/ =1x 10" © HA'+OH @ A*+H20 so {OHJ[HAT}/ = 1x 10°5. (15 points). A 0.504 g sample of finely ground limestone was placed in an Erlenmeyer flask, and 50.00 mL of 0.250 M HCI was added using a volumetric pipet. The mixture was heated and stirred until all the CaCOs was dissolved (no more bubbles of CO. evolved). The unreacted acid in the flask was titrated to a phenolphthalein endpoint with 28.09 mL of NaOH that was 0.1041 M. What is the mass% of CaCOs in the limestone? ie 3 SO») 16°» 250 CaCO) +2Hiy —>Cazs, +CO yg) HO = 2012S eed He} 2B. r10? «Jory = 60292 wal NaOH Reecked owl Hel: .699S 75S) * [mG Cs , Ieooth yen ol orn, , Worthen OM rel He] ol Ct 1 fneasurements were made on the percentage of chlorine in a sample. 7912,)32.7888, 32.7855. One of these appears to be anomalous, is it permissible to exclude it at the 90% confidence level? 6. (10 points) The followin, 32.7865, 32,7895, 32, should it be included a+ ley: ar ae fangs 0009 or § Gate & Bene = Weep CHa 084 0826 oz on g Se a ae \2 ~S 37. (10 points) Below isa sketch of the titration of phosphoric acid H3POs Label points “a” through “g” (midpoints, equivalence points, etc.) ‘Voume of NaQH Added —P (@) Initial pH of solution, (b) first equivalence point, (c) Kal, first midpoint , (4) second equivalence point, (e) Ka2, second midpoint, (f) third equivalence point, (g) third midpoint Ka3 (@) G) Initial pH of solution, (b) Kal, first midpoint, (c),firstquivalence point, (d) Ka2, second ‘midpoint (e) second equivalence point, (f) third midpoint Ka3, (g) third equivalence point (© @) Initial pH of solution, (b) Ka3, third midpoint, (¢), third equivalence point, (d) Ka2, second midpoint (e) second equivalence point, (f) frst midpoint Kal, (g) first equivalence point (PI(@) Final pH of solution, (b) Ka3, third midpoint, (c), third equivalence point, (d) Ka2, second midpoint (¢) second equivalence point, (f) first midpoint Kal, (g) first equivalence point 8. (10 points). Draw the Lewis structure of phosphoric acid. 9. (10 points) 1f8.016 g of phosphoric acid diluted into 20 mL of water is titrated with 1.104 M KOH, how many mL of the titrant will be needed to peach the second equivalence point? Wan, Te) Oa = (a) 74 mL (6) 37 mL (c) 288 mL Ou Retreat = 1036 wel Kon Ke WON KONE9. (10 points). For any weak acid HA and its conjugate base A’, the sum of pK. and pK equals: a. Ixia @)4 c. Ixlo!* 40 10. (5 points), What is the pH ofa solution containing 1.0 MH"? @D) b. 10