IIT- JEE QUESTIONS: GOC

ENDEAVIOUR CLASSES_CHEMISTRY
1

10

2
11

3
4

12. STATEMENT-1: p-Hydroxybenzoic acid has a lower boiling point than o-hydroxybenzoic acid.
because
STATEMENT-2: o-Hydroxybenzoic acid has intramolecular hydrogen bonding. [JEE-2007]
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement -2 is False. (D) Statement-1 is False, Statement-2 is True.
13. Among the following, the least stable resonance structure is [JEE-2007]

6
7

14. STATEMENT-1: Molecules that are not superimposable on their mirror images are chiral
because
STATEMENT-2: All chiral molecules have chiral centres. [JEE-2007]
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False (D) Statement-1 is False, Statement-2 is True
15. Hyperconjugation involves overlap of the followingorbitals [JEE-2008]
16. The correct statement(s) concerning the structuresE, F andGis (are) [JEE-2008]

IIT- JEE QUESTIONS: GOC

ENDEAVIOUR CLASSES_CHEMISTRY

(B)

17. The correct stabilityorder for the following species is [2008]

18. The correct acidity order of the following is [JEE-2009]

22. The total number of contributing structures showing hyperconjugation

(involving C-Hbonds) for the following carbocation is [JEE-2011]

23. Among the following compounds, the most acidic is [JEE-2011]

(A) pnitrophenol (B) p-hydroxybenzoic acid
(C) ohydroxybenzoic acid (D) ptoluic acid
24. The hyperconjugative stabilities of tert-butyl cation and 2-butene, respectively, are due to
[JEE-2013]
25. Arrange the following compounds in order of decreasing acidity [JEE-2013]

(A)

19. The correct statement(s) about the compound

is(are) [JEE-2009]
(A)

26. The order of stability of the following carbocations [JEE-2013]

(D)

20. In the following carbocation, H/CH 3 that is most likely to migrate to the positively charged
carbon is [JEE-2009]

27. Considering the basic strength of amines in aqueous solution, which one has the smallest
pKb value? [JEE-2014]
(D)

21. The correct stability order of the following resonance structures is [JEE-2009]

IIT- JEE QUESTIONS: GOC

ENDEAVIOUR CLASSES_CHEMISTRY