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aU,
(4) aU; < aU,
Resonance
dating for bets tonartow29.
‘The temperature-entropy diagram of a reversible engine cycle is given in the figure. Its efficiency is
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1
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30. Two rigid boxes containing different ideal gases are placed on a table. Box A contains one mole of nitrogen at
temperature T,, while box B contains one mole of helium at temperature (7/3)T,,. The boxes are then put into
thermal contact wth each other, and heat flows between them until the gases reach a common final temperature.
(Ignore the heat capacity of boxes). Then, the final temperature ofthe gases, T, in terms of T, is
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‘wee BH TET (TIS), eR aT et cea | aR aT a ew AES Tt eae eM oT 8 she UAT
we 8 QR 4 aa ae wales ah ¢ ora ae fe Gre GRO ao WER Tel el Te 8 | Ga BH GET TREAT
srg ar) | ta i ar ifs aTeraPT TT, ae AB
7 3 5
OT= 7m Qy= a @MW=57 @T=57
PART-B
Atomic masses (sey 4k): [H = 1, D=2, Li=7, C= 12, N= 14, O= 16, F= 19, Na=23, Mg = 24,
Al=27, Si= 28, P=31, S= 32, Cl=35.5, K= 39,Ca 2, Mn = 55, Fe = 58, Cu=63.5
Zn=65, As = 75, Br= 80, Ag = 108, 200, Pb = 207]
Straight Objective Type
This section contains 30 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4)
for its answer, out of which ONLY ONE is correct.
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ga ws 4 30 ag-famet met &| Wet wer H 4 fees (1), (2), (3) em (4) & Sra Re ye GAS)
34. Which of the following is a redox reaction Fie 4 @ GureRD aifhifear Sra & 77
(1) NaCl + KNO, —> NaNO, + KCI
(2) CaC,0, + 2 HCI —> CaCl, + H,C,0,
(8) Ca(OH), + 2 NH,Cl —> CaCl, + 2 NH, +2H,O
(4) 2K [Ag(CN),] + Zn —+ 2g + K,{Zn(CN),]
32, For anideal gas, number of moles per ltre in terms of its pressure P, temperature T, gas constant R
is:
ye sree te & fed ala hex ae a tren gud cra P, tu, Pact Rok ay TS gel Fe
(1) PTR (2) pRT (3) RT (4) RTIp
Resonance
dating for bets tonartow33.
36.
36.
37.
38.
39.
KO, (potassium super oxide) is used in oxygen cylinders in space and submarines because it
KO, (sTefrey ERR sia) sake F sitaior Rretese H gen org herd | Soe Ay creT OTe Seah
®
(1) Absorbs CO, and increases O, concentrations. (CO, aiviiwe & ce O, Are # ere 8)
(2) Absorbs moisture. (FH @t srazhfia Fe & |)
(3) Absorbs CO, (CO, sa8iI9% & |)
(4) Produces ozone. (sitwilt ated BH 8 |)
In an organic compound of molar mass 108 g mol" C.H and N atoms are present in 9: 1: 3.5 by
weight. Molecular formula can be
ow ard aha Aorerar ree RATATAT 108 aT ra, fore CH Te N& WHT 9:1: 3.5 GR A)
waftera & | ger ares as eee
(1) CHAN, 2) CH oN (3) C.H.N, (4) C.H,N,
In Bohr series of lines of hydrogen spectrum, the third line from the red end corresponds to which
one of the following inner-orbit jumps of the electron for Bohr orbits in an atom of hydrogen ?
aggior aga a ade Soh ot Sarat Fara RR & cia gets tear gaagia a aise ewe ete?
(N32 (52 (3451 (4255
os
The orbital angular momentum for an electron revolving in an orbit is given by JZ(@+1) >. This
momentum for an s-electron will be given by
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3 fag ae eam fear oir 81
ah h h
)+9-28 (2) Zero (a2) (3) (4) 2-3
‘An ethers more volatile than an alcohol having the same molecular formula. This is due to :
(1) dipolar character of ethers.
(2) alcohols having resonance structures
(3) inter-molecular hydrogen bonding in ethers.
(4) inter-molecular hydrogen bonding in alcohols.
We ER GT ww Vomlefa 8 ake arava & firrar siflaw Ya WA F | SHI GR
(1) &r wm fagaa aftrcerr | (2) qowletar GH srqardt Geer eh e1
(3) €or 4 ornenftaw esto Ter | (4) wear # ore ona erggrer wr |
Which of the following set of quantum numbers is correct for an electron in 4f orbital ?
Af mare A eH gcagia & fore aaien Gem oT Gre Ve WEE?
(1) n=4,1=3,m=+4,s= 41/2 (2)n=4,1=4,m=-4,s=-12
(Q)n=4,1=3,m=41,s= 412 (4)n= =2,s= 412
Which one of the following ions has the highest value of ionic radius?
fet arr a 8 feed arate free affect 8?
(Lr (2) B (3) OF (4) F
DR Rescrence40.
41.
42.
43.
45.
The correct order of bond angles (smallest first) in H,S, NH, BF, and SiH, is :
H,S\NH,,BF, site Sika aan atoi ao eel wea een Ser gem)
(1) H.S < SiH, < NH, < BF, (2) NH, < H,S < SiH, < BF,
(3) HS < NH, < SiH, < BF, (4) H,S < NH, < BF, < SiH,
Which of the following oxides is amphoteric in nature ?
fe aa aire alters oaeert mph a 8?
(1) Cao, (2) Co, (3) SiO, (4) Sno,
Which one of the following species Is diamagnetic in nature 7
aephe 8 Pre ay ahareh mos afagera 8 ?
(1)He, Q)H, (3)H. (4) Hy
How many moles of magnesium phosphate, Mg,(PO, ), will contain 0.25 mole of oxygen atoms?
Sehr whee, Mg,(PO,), % Per ater # sifeetiort aeArysit 1 0.25 re Sle?
(1) 0.02 (2) 3.125 x 102 (3) 1.25 x 102 (4)2.5 102
The equilibrium constants Kp, and Kp. for the reactions X = 2Y and Z = P+ Q, respectively
are in the ratio of 1 : 9. If the degree of dissociation of X and Z be equal then the ratio of total
pressures at these equilibria is
X = 2Y ven Z —= P+ Qaitransll & fig Het eTFUTaeeN Reis Kp, den Kp, } Aa 1:9 a
organ 8 1 aft XaenZ & Reto WA aay ae vi, oh gs TRAN aT ores A QE ar S Aro
agua é
(ast 21:3 (31:9 (4) 1:38
Oxidising power of chlorine in aqueous solution can be determined by the parameters indicated
below
FoL@— = scl 2 scr (@ #1 a)
the energy involved inthe conversation of 4 CL(g) to Cl (aq) (using the data,
Ages Hey, = 240 kJ mol" eyHe) = 349k mol yg, =-381 kd mot") will be
wiely Rees a aes A sraitore ured ot Ae defied @ sna feat on wea &
FeL@ 22" 04g) st scr @) 20” set (aa)
FOLD cr (aq) & warcRE A ea Tt (HRT, Ay H
= 240kJ mol", A. Hi, =-349kJ mor
4, yg HS. =-381kJ mob) #1 su aed By arf
(1)+162kJ mor! (2)—610kJ mor! (3) 850 kJ mol? (4) + 120 kJ mot
DR Rescrence46.
47.
48.
49.
50.
51.
Ina fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is.
we Sr a 4 erie der & wa oie steer orate & wy A wet A rar one 8 | offre Se
wo eres
CH,OH() + 3 ©, (g) —+ CO) + 2H,0(0)
At 298 K standard Gibb’s energies of formation for CH,OH(¥), H,O(¢) and CO, (g) are -166.2, —
237.2 and 394.4 kJ mol respectively. If standard enthalpy of combustion of methanol is -726kJ
mot", efficiency of the fuel cell will be
298 K wR Prater a array Pron Gite CH,OH(0), H,O(0) ae CO, (g) & fry wHeT: 166.2, -237.2 ae
A204.4 kJ mals & 1 af ashettar ah erect oA ure lea 728k) mal &, at dora das ah mara Shh:
(1) 87% (2) 90% (3) 97% (4) 80%
The standard enthalpy of formation of NH, is 46.0 kJ mol. If the enthalpy of formation of H, from
its atoms is — 436 kJ mol-* and that of N, is 712 kJ mol, the average bond enthalpy of N—H bond
in NH, is
NH, & Guay # as GAN - 46.0 kJ mor! #1 aft gad ges a MPa HH Hay Gee
436 kJ mol a aie si WHR N, #7 -712kJ mola, al NH, % N-H ae BH itera ore were
&
(1)-964kJ mor! (2) + 352kJ mol? (3) + 1056 kJ mol? (4) ~ 1102 kJ mot"
Which one of the following orders presents the correct sequence of the increasing basic nature of
the given oxides ?
Peifefaa 4 ele wy fea 12 sifeergel S wae: asd ata wera H) oeda ae & ?
(1) Al,0, < MgO < Na,O 2Ag+Zn(CN),
ae
(3) Hint: Use ideal gas equation.
corecah Are weer ar iT FTE |
ole
Vv" RT
(1) 4KO, + 2CO, > 2K,CO, + 30, . It absorbs CO, and release O,
4KO, + 2CO, > 2K,CO,+30,. 78 CO, #1 saenffa wear 8 cen O, a FeErad oem 31
(1) Molar mass = 108 gm/mole
Element [WE Ratio Wt ratio/Atomic mas{Simple Ratio [Simple Integer ratio
ox _ 3x
c ox | %-% 3 3
a 1 a a
n | asx 1 1
©. CH.N
Empirical mass = 12 x 3+ 4+ 14=54
n= 108,
54
Molecular Formula = C,H,N,
HER HATA = 108 a/c
we hr agua [ar squa/armr faa agua [ava yofes agua
ce xe e 3 3
4
H 1x 7 4 4
N asx | 3% 1 1
1
CAHN
Yorgi Rar = 12 «344+ 14=54
n= 108_»
54
~. amonfa Yat = C,H,N,
DR Rescrence35.
36.
37.
38.
39.
(2) The electron has minimum eneray in the first orbit and its energy increases as n increases. Here
n represents number of orbit, ie., 1%, 2%, 3 The third line from the red end corresponds to
yellow region i.e., 5. In order to obtain less energy electron tends to come 1* or 2 orbit. So jump
may be involved either 5 > 1 or 5 > 2. Thus option (1) is correct here.
ver mat A sdagla =H Gol Waal 8 denn awa S Grey Geil wa 8 ae n Hey A) Hew]
aaa & | Garey 144, 24, gre AR Sar are TW wraPaa f cen def wera Sa | gael
A or Gal wea wel & fore ge 1 aT 2 wan A ara afey| gafery GH a a 51415 >
24 e) weal 81 ge veHR ewes (2) wal BI
(2) The value of ¢ (azimuthal quantum number) for s -electron is equal to zero.
Orbital angular momentum = E+).
h
Substituting the value of | for s-electron = yO +1).>-=0
e(Reish waver den) wr a s -eag ie fore Bea tar
waite arity tar = yet +1).
2n
s-gcagia & fay ¢ a1 ar was qy= J+).
anh
2e
(4) The reason for the lesser volatility of alcohol than ethers is the intermolecular association of a
large number of molecules due to hydrogen bonding
Rhy dad
Oho ty ee
\
hydrogen bénding
No such kind of hydrogen bonding is present in ethers.
venldia & ger FA gern 4 oa aera eh @ SR se sated sysil @1 sreRoTfaw Hata 8, vit
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0 -H-< O-Hy~ 0-H O-
N 7
EIggIort ay
or ter Hea wafer a 81
(3) For 47 orbital electrons, n= 4
€=3 (because $794) m=+3,+2,+1,0,—
4; veile gaa & fea, n=4
=3 (wife SP 94) m=
0123
3,42, +1,0,-1,-2,-38=+ 1/2.
(3) O% has the highest value of ionic radii as this can be explained on the basis of z/e
Resonance Pag
dating for bets tonartow40.
41.
42.
43.
hucieus charge | iy oe Swnenle ratio .
no of elections |- When z/e ratio increases, the size decreases and when z/e ratio decreases the
size increases
aria sir
OF #8 sn Pe son 8 9 ve { RL
| ser a sare a 8 2
SAUTE wT APT AEE S GTO VET 8 eM Te Zle TYME UAT & oH Tw B
(@) The coneet order of bond angle (smallest ist) is
au air ar wal A (Bae Bret Be)
H,S <.NH, < SiH, < BF,
92.6°< 107° < 109°28’ < 120°
4
9 , 10829"
QD wry
asm
Wore HHH
Puprepulsion 1s se repulsion F’
(4) CaO - basic, CO, and SiO, - acidic, SnO,, - amphoteric, as it reacts with both acids and bases.
nO, + 4HCI-> SnCl, + 2H,O SnO, + 2NaOH -> Na,SnO, + H,0
CaO - aia, CO, st SiO, - sre4, SnO, - Grae, wifes ae sm gene St S sip wear B
SnO, + 4HCI> SnCl, + 2H,O SnO, + 2NaQH -> Na,SnO, + H,0
(2) He,” > 0 (1s)®o* (1s)', one unpaired electron.
H, > (15)? , o* (15), no unpaired electron.
H," > a (18), of (1s)°, one unpaired electron.
~ -»« (18), a* (18)', one unpaired electron.
He," >a (18)o* (18), ym sraftra seat |
H, > (1s)? o° (15)°, aig A oraaa seagate 81
Hy > 0 (18)?, of (15), ww orgfine gctagts 81
Ho (18), o* (18)', Ue sryftra goats & |
(2") 1 mole of Mg, (PO,),
> 3mole of Mg atom + 2 mole of P atom + 8 mole of © atom. 8 mole of oxygen atoms are
10.25
8
presentin = 1 mole of Mg, (PO,),, 0.26 mole of oxygen atoms are present in = 3.125 x10"
joles of Mg, (PO,),.
Mg, (PO,), 1 1 Iai = Mg Term, & 3 ats + P oenTa, & Qare + sitar eT, 8 are 0.25 ae
; 10.28
sitar wera, GaRera &
= 3.125 « 10° Mg, (PO,), ® Hla 41
Resonance
dating for bets tonartow46.
46.
47.
(4) X—=2 & Z—pP+Q
t=0 P, P,
P(t) 2Pa Pt) Pa Pw
Pra? P22
P= Py =
a) cr)
HSPiEeslee eet Eraeta
Kea OlntP = P, 36
Pr Pitino) +P a 1
and Plz Paltma)+2P2a ~ 36
(2) H= ; AH, (Cl,) + AH, Cl + AH, (Ch)
= 240 349-381
2
=-610kJ mol"
(3) CHOH(») + 3 0, (g) —>C0,(9) + 24,0)
AG, = AG, (CO, ,g) + 2aG, (H,O,
394.4 -474.4 + 166.2
(0) 86, (CH0H, (0) = 2 46,0,
-394.4 + 2 (-237.2) —(-166.2) -0
% efficiency (% aeran) = 722°.100 = 97%,
(2) No) * & Ho) —> NH, (9): 46.0 kJ mot"
2H(g) — H,(9) 436 kJ mol
2N(g) —> N,(g) 712 kJ mol
1 3
NH,(g) —> 5 N.(9) + 5H, (9) AH=+46
3 3
3H. —>3H AH = +436 x
1 eerie!
3 N, oN aH =+712% 5
NH,(g) ——+ N(g) + 3H (9)
AH= + 1056 kJ mol
Resonance
dating for bets tonartow
Page -¢11056
‘Average bond enthalpy of N-H bond (N-H sire 3 sera sri rate = “PP = + 362 ky mor
(1) As metallic character of element attached to oxygen atom increases, the difference between the
electronegativity values of element and oxygen increases and thus basic character of oxides in-
creases and vice-versa. Hence the increasing correct order of basic nature is Al,O, < MgO < Na,O