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Ideal Plug Flow Reactor
Ideal Plug Flow Reactor
Q
CO
Q
CL
time
time
1
Q
Cx
and
Q
Cx+dx
dV = Adx
x x+dx
Cx
t
Adx
Cx
t
Cx
t
Cx+dx = Cx + dCx
Q(Cx Cx dCx) + dVrC = dV
Cx
V
rC
Cx
t
Cx
V
Q
Cx
t
rC
since Q is constant
(V/Q) =
Cx
rC
Cx
t
Cx
t
And the ordinary differential can be substituted for the partial differential
Comments
dCx
d
rC
dC
rC
d
dC
Ideal batch :
rC
dt
Position in a PFR is equivalent to time in a batch reactor
Ideal PFR :
dC
d
kC
CL
dC
Co C
kd
0
CL = C0exp(-k )
Ideal PFR, steady-state 1st order reaction profile
1.2
C/Co
1
0.8
0.6
0.4
0.2
0
0
Example:
Chlorine contact basin for disinfection
Q,
Co
Xo
Q,
Ce,
Xe
Where
Q = 0.25 m3/s
A = channel cross section between baffles = 18 m2
rd = rate of microorganism kill in presence of chlorine = -kdX
X = concentration of microorganisms at any point in contact reactor
Xo = influent concentration of microorganisms = 106 E. coli/100 ml
kd = 5 hr-1
rc = rate of chlorine decay (from microorganism Cl-demand) = -kcX
kc = 10-5 (mg-chlorine/L)(#/100mL)-1hr-1
2 rate expressions, 2 constituents, 2 coupled mass balances
find:
1. reactor volume and flow path length, L, such that XL < 103 cells/100
ml
2. chlorine concentration which must be added to insure that there is
detectable chlorine at PFR exit (detection level = CL = 0.05 mg/L)
1. Steady-state mass balance on cells
XL = Xoexp(-kd )
= (1/kd)ln(Xo/XL) = (1/5)(hr)ln(106/103) = 1.4 hr
V = Q = 0.25 m3/s*3600 s/hr*1.4 hr = 1,260 m3
L = V/A = 1,260 m3/18 m2 = 70 m
3. Steady state mass balance on chlorine
dC c
d
k cX
k c X o exp( k d d )
CL
dC c
k c X o exp( k d )d
Cco
CL
C co
(k c X o )
kd
k c X o exp( k d )
kd
CL
C co
(k c X o )
(1 exp( k d ))
kd
1.0E+05
3.00
1.0E+04
2.00
1.0E+03
1.00
1.0E+02
Cc (mg-chlorine/L)
1.0E+06
0.00
0
0.2
0.4
0.6
0.8
1.2
1.4
1.6
= x/v (hr)